Search Results (3,417)

Asphalt modified with treated waste tires has good environmental protection and application value. However, the nano-modification mechanism of crumb rubber (CR) with asphalt is still unclear. This research investigates the mechanism, aging, and interfacial interaction with the aggregate of CR modification asphalt (CRMA). The base asphalt and CRMA (original and aged) and two typical aggregate models were constructed. The accuracy of the model was verified through multiple indicators. The effects of CR and aging on the physical properties (density, compatibility, and diffusion coefficient), mechanical properties, component interaction behavior, and interfacial interactions with aggregates of CRMA were systematically analyzed. The results showed that the CR reduced the diffusion coefficient of asphalt by about 31%. The CR inhibited the movement of the components of asphalt (especially saturate and aromatic), which significantly improved the mechanical properties of asphalt. The compatibility between asphalt and CR significantly deteriorated after aging. The difference in the solubility parameter was about four times that before aging. It is instructive for the regeneration of CRMA. Aging led to a decrease in the shear modulus and Young’s modulus of both base asphalt and CRMA, which verified and quantified the adverse effects of aging on the mechanical properties. Comparing the two aggregates, CaCO₃ had a greater adhesion with asphalt than SiO₂. The difference ranged from 22.5% to 39.9%, which quantified the difference in the adhesion properties of acid base aggregates with asphalt. This study can provide theoretical guidance for the modification and application of CRMA. Full article

Fiber hybridization can effectively solve the localized brittle fracture problem of composite honeycomb, but the interaction between different fibers leads to a very complex failure mechanism. Hence, 3D-printed hybrid continuous fiber composite honeycombs with a combination of carbon and Kevlar fibers are designed to study the structural failure behaviors by the experiment and simulation method. The experimental samples, including Onyx, carbon, Kevlar, carbon/Kevlar, and Kevlar/carbon composites, are fabricated based on Markforged 3D printing technology, and the crushing tests are conducted to evaluate the failure behaviors. An equivalence finite element modeling method to replace the heterogeneous microstructure of hybrid composites is proposed to analyze the failure behaviors. Results indicate that carbon/Kevlar honeycomb exhibits the highest energy absorption and cost effectiveness, while CFRP honeycomb demonstrates the highest load-carrying capacity. It is found that carbon/Kevlar and Kevlar/carbon honeycombs have significant hybrid effects compared to single-fiber honeycombs, which also reveals the hybrid mechanisms between carbon and Kevlar fibers. Furthermore, the Onyx honeycomb, lacking long fibers, exhibits brittle collapse, whereas other honeycombs show ductile collapse due to the presence of Kevlar fibers. Combining the simulation studies, the damage evolution mechanisms of honeycombs, including fiber/matrix tension and compression, shear damage, interface damage, etc., are further revealed. This work provides valuable insights into the design and failure analysis of 3D-printed hybrid fiber composite honeycombs. Full article

The development of biocompatible hydrogels for 3D bioprinting is essential for creating functional tissue models and advancing preclinical drug testing. This study investigates the formulation, printability, mechanical properties, and biocompatibility of a novel Alg-Gel hydrogel blend (alginate and gelatin) for use in extrusion-based 3D bioprinting. A range of hydrogel compositions were evaluated for their rheological behavior, including shear-thinning properties, storage modulus, and compressive modulus, which are crucial for maintaining structural integrity during printing and supporting cell viability. The printability assessment of the 7% alginate–8% gelatin hydrogel demonstrated that the 27T tapered needle achieved the highest normalized Printability Index (POI_normalized = 1), offering the narrowest strand width (0.56 ± 0.02 mm) and the highest printing accuracy (97.2%) at the lowest printing pressure (30 psi). In contrast, the 30R needle, with the smallest inner diameter (0.152 mm) and highest printing pressure (80 psi), resulted in the widest strand width (0.70 ± 0.01 mm) and the lowest accuracy (88.8%), resulting in a POI_normalized of 0.274. The 30T and 27R needles demonstrated moderate performance, with POI_normalized values of 0.758 and 0.558, respectively. The optimized 7% alginate and 8% gelatin blend demonstrated favorable printability, mechanical strength, and cell compatibility with MDA-MB-213 breast cancer cells, exhibiting high cell proliferation rates and minimal cytotoxicity over a 2-week culture period. This formulation offers a balanced approach, providing sufficient viscosity for precision printing while minimizing shear stress to preserve cell health. This work lays the groundwork for future advancements in bioprinted cancer models, contributing to the development of more effective tools for drug screening and personalized medicine. Full article

Infilled joints or faults are often subjected to long-term stable shear forces, and nature surface processes of normal unloading can change the frictional balance. Therefore, it is essential to study the sliding behavior of such granular materials under such unloading conditions, since they are usually the filling matter. We conducted two groups of normal unloading direct shear tests considering two variables: unloading rate and the magnitude of constant shear force. Dry sands may slide discontinuously during normal unloading, and the slip velocity does not increase uniformly with unloading time. Due to horizontal particle interlacing and normal relaxation, there will be sliding velocity fluctuations and even temporary intermissions. At the stage of sliding acceleration, the normal force decreases with a higher unloading rate and increases with a larger shear force at the same sliding velocity. The normal forces obtained from the tests are less than those calculated by Coulomb’s theory in the conventional constant-rate shear test. Under the same unloading rate, the range of apparent friction coefficient variation is narrower under larger shear forces. This study has revealed the movement patterns of natural granular layers and is of enlightening significance in the prevention of corresponding geohazards. Full article

Understanding lubrication at the nanoscale is essential for reducing friction. While alkanes, the primary component in most lubricants, have been studied for their molecular structure’s impact on rheology and behavior when confined by solid surfaces, the influence of confining surface texture remains underexplored. This research uses molecular dynamics simulations to investigate the rheological behavior of thin film lubrication between various patterned rough surfaces. The study focuses on sinusoidal, sawtooth, and squaretooth wave-patterned surfaces, using hexadecane as the lubricant. The simulations examine the effects under different normal loads and shear rates. Surface patterns significantly influence the formation and structure of crystalline bridges, depending on shear rates and normal loads. The sawtooth wave-patterned surface exhibits the highest viscosity under low normal load and shear rate conditions, forming crystalline bridges with a molecular orientation perpendicular to the shear direction. The squaretooth patterns exhibit the lowest viscosities due to the nematic order in crystalline bridges with molecules aligned in the shearing direction. The sinusoidal wave-patterned surface shows intermediary viscosity with disordered crystalline bridge groups formed with random molecular orientation. The lowest viscosity provided by the squaretooth pattern surface persists across various conditions, including both transitory and steady states, under high and low loads, and over a wide range of shear rates. However, the difference in shear viscosity is reduced at higher normal loads. This research provides valuable insights for designing nanoelectromechanical systems (NEMS) and other applications where boundary conditions are critical to lubrication. Full article

This study presents a comprehensive investigation into the cyclic shear behavior of sand–fly ash mixtures through experimental and data-driven modeling approaches. Cyclic direct shear tests were conducted on mixtures containing fly ash at 0%, 2.5%, 5%, 10%, 15%, and 20% by weight to examine the influence of fly ash content on the shear behavior under cyclic loading conditions. The tests were carried out under a constant stress of 100 kPa to simulate field-relevant stress conditions. Results revealed that the fly ash content initially reduces shear strength at lower additive contents, but shear strength increases and reaches a maximum at 20% fly ash content. The findings highlight the trade-offs in mechanical behavior associated with varying fly ash proportions. To enhance the understanding of cyclic shear behavior, a Nonlinear Autoregressive Model with External Input (NARX) model was employed. Using data from the loading cycles as input, the NARX model was trained to predict the final shear response under cyclic conditions. The model demonstrated exceptional predictive performance, achieving a coefficient of determination (R²) of 0.99, showcasing its robustness in forecasting the cyclic shear performance based on the composition of the mixtures. The insights derived from this research underscore the potential of incorporating fly ash in sand mixtures for soil stabilization in geotechnical engineering. Furthermore, the integration of advanced machine learning techniques such as NARX models offers a powerful tool for predicting the behavior of soil mixtures, facilitating more effective and data-driven decision-making in geotechnical applications. Evidently, this study not only advances the understanding of cyclic shear behavior in fly ash–sand mixtures but also provides a framework for employing data-driven methodologies to address complex geotechnical challenges. Full article

Palm and palm kernel oils are preferred ingredients in industrial food processing for baked goods and chocolate-based desserts due to their unique properties, such as their distinctive melting behaviors. However, ongoing concerns about the social and environmental sustainability of palm oil production, coupled with consumer demands for palm oil-free products, have prompted the industry to seek alternatives which avoid the use of other tropical or hydrogenated fats. This project investigated replacing palm oils with chemically unhardened Swiss sunflower or rapeseed oils. Target applications were cookies and chocolate fillings. These oils were physically modified through emulsification, stabilized with finely ground oil press cake particles and crystallized waxes. Findings indicated that the emulsification of the oils increased viscosity and that the addition of wax was beneficial for long-term stability; however, the extent of this effect depended on the combination of oil and wax types. Furthermore, wax pre-crystallization and low shear during crystallization significantly improved emulsion stability. Despite these improvements, the resulting emulsions did not achieve sufficient stability and exhibited lower viscosity than palm oil. Future experiments should explore higher wax concentrations (1% or more) and develop analytical methods to better understand the wax composition and its role in oleogel formation. Full article

This research explores the physical properties of refractory high-entropy alloys Ti₃Zr_yNbV_x (0.5 ≤ x ≤ 3.5; 1 ≤ y ≤ 2), utilizing the first-principles exact muffin-tin orbitals method, in addition to the coherent potential approximation. We examine the atomic size difference (δ), the valence electron concentration (VEC) and the total energy of the body-centered cubic (bcc), the face-centered cubic (fcc) and the hexagonal close-packed (hcp) lattices, revealing a disordered solid solution with a bcc lattice as the stable phase of these alloys. The stability of the bcc Ti₃Zr_yNbV_x alloys increases with the addition of vanadium, and slightly decreases with increasing Zr concentration. All the investigated RHEAs have densities less than 6.2 g/cm³. Adding V to the Ti-Zr-Nb-V system reduces the volume and slightly enhances the density of the studied alloys. Our results show that increasing V content increases the tetragonal shear modulus C′, which assures that V enhances the mechanical stability of the bcc phase, and also increases the elastic moduli. Moreover, all the examined alloys are ductile. Vickers hardness and bond strength increase as V concentration increases. In contrast, decreasing Zr content reduces the density and increases the hardness and the bond strength of the present RHEAs, potentially resulting in systems with desirable mechanical properties and lower densities. These findings provide theoretical insights into the behavior of RHEAs, and emphasize the necessity for additional experimental investigations. Full article

Background/Objectives: The demand for a safe compound for hyperpigmentation is continuously increasing. Bioactive compounds such as thymoquinone (TQ) and ascorbic acid (AA) induce inhibition of melanogenesis with a high safety profile. The aim of this study was to design and evaluate spanlastics gel loaded with bioactive agents, TQ and AA, for the management of hyperpigmentation. Methods: Several spanlastics formulations were successfully fabricated and characterized in terms of morphology, vesicle size, zeta potential, and release. Results: The optimized TQ-loaded spanlastic formulation showed an average size of 223.40 ± 3.50 nm, and 133.00 ± 2.80 nm for AA-loaded spanlastic formulation. The optimized spanlastics formulation showed the highest entrapment efficiency (EE%) of 97.18 ± 2.02% and 93.08 ± 1.95%, for TQ and AA, respectively. Additionally, the edge activator concentration had a significant effect (p < 0.05) on EE%; it was found that by increasing the amount of EA, the EE% increases. Following that, the optimal spanlastics fomulation loaded with TQ and AA were incorporated into gel and explored for appearance, pH, spreadability, stability, rheology, in vitro release, ex vivo permeation study, and MTT cytotoxicity. The formulated spanlastics gel (R-1) has a pH of 5.53. Additionally, R-1 gel was significantly (p < 0.05) more spreadable than control gel, and exhibited a shear thinning behavior. Most importantly, ex vivo skin deposition studies confirmed superior skin deposition of TQ and AA from spanlastic gels. Additionally, results indicated that tyrosinase inhibition was primarily due to TQ. When comparing TQ alone with the TQ-AA combination, inhibition ranged from 18.35 to 42.73% and 24.28 to 42.53%, respectively. Both TQ spanlastics and the TQ-AA combination showed a concentration-dependent inhibition of tyrosinase. Conclusions: Spanlastic gel might represent a promising carrier for the dermal delivery of TQ and AA for the management of hyperpigmentation conditions. Full article

Major earthquakes and rainfall may occur at the same time, necessitating further investigation into the dynamic characteristics and responses of reinforced soil retaining walls subjected to the combined forces of rainfall and seismic activity. Three sets of shaking table tests on model retaining walls were designed, a modular reinforced earth retaining wall was utilized as the subject of this study, and a custom-made device was made to simulate rainfall conditions of varying intensities. These tests monitored the rainwater infiltration pattern, macroscopic phenomena, panel displacement, tension behavior, dynamic characteristics, and acceleration response of the modular reinforced earth retaining wall during vibration under different rainfall intensities. The results indicated the following. (1) Rainwater infiltration can be categorized into three stages: rapid rise, rapid decline, and slow decline to stability. The duration for infiltration to reach stability increases with greater rainfall. (2) An increase in rainfall intensity enhances the seismic stability of the retaining wall panel, as higher rainfall intensity results in reduced sand leakage from the panel, thereby diminishing panel deformation during vibration. (3) Increased rainfall intensity decreases the shear strength of the soil, leading to a greater load on the reinforcement. (4) The natural vibration frequencies of the three groups of retaining walls decreased by 0.21%, 0.54%, and 2.326%, respectively, indicating some internal damage within the retaining walls, although the degree of damage was not severe. Additionally, the peak displacement of the panel increased by 0.91 mm, 0.63 mm, and 0.61 mm, respectively. (5) The amplification effect of rainfall on internal soil acceleration is diminished, with this weakening effect becoming more pronounced as rainfall intensity increases. These research findings can provide a valuable reference for multi-disaster risk assessments of modular reinforced soil retaining walls. Full article

Understanding the behavior of fluid flow and solute transport in fractured rock is of great significance to geoscience and engineering. The discrete fracture network is the predominate channel for fluid flow through fractured rock as the permeability of fracture is several magnitudes higher than that of the rock matrix. As the basic components of the fracture network, investigating the fluid flow in crossed fractures is the prerequisite of understanding the fluid flow in fractured rock. First, a program based on the successive random addition algorithm was developed to generate rough fracture surfaces. Next, a series of fracture models considering shear effects and different surface roughness were constructed. Finally, fluid dynamic analyses were performed to understand the role of flowrate and surface roughness in the evolution of flow field, concentration field, solute breakthrough, and solute mixing inside the crossed fractures. Results indicated that the channeling flow at the fracture intersection became more pronounced with the increasing Péclet number (Pe) and Joint Roughness Coefficient (JRC), the evolution of the concentration field was influenced by Pe and the distribution of the concentration field was influenced by JRC. For Pe < 10, the solute transport process was dominated by molecular diffusion. For 100 > Pe > 10, the solute transport process was in the complete mixing mode. In addition, for Pe > 100, the solute transport process was in the streamline routing mode. The concentration distribution was affected by the local aperture at the fracture intersection corresponding to different surface roughness. Meanwhile, the solute mixing equation was improved based on this result. The research results are beneficial for further revealing the mechanism of fluid flow and solute transport phenomenon in fractured rock. Full article

In this work, a hydrophobically associative polymer (HAP) was mixed with β-cyclodextrin and epichlorohydrin polycondensate (β-CDP) in an aqueous solution to enhance the intermolecular interaction through host–guest inclusion between hydrophobes and cyclodextrins. Results showed that the host–guest interaction improved the thickening ability and viscoelasticity of the HAP solution and maintained its shear thinning behavior. The host–guest inclusion system demonstrated special viscosity–temperature curves and variable activation energy. Enhanced oil recovery (EOR) performance tests showed that the oil increment produced by the host–guest inclusion system was 5.5% and 9.3% higher than that produced by the HAP and the partially hydrolyzed polyacrylamide solution, respectively. Compared with pure HAP, β-CDP/HAP has a better comprehensive performance and is more attractive for EOR in high-temperature reservoirs. Full article

The development of a constitutive model for soil–structure contact surfaces remains a pivotal area of research within the field of soil–structure interaction. Drawing from the Gudehus–Bauer sand hypoplasticity model, this paper employs a technique that reduces the stress tensor and strain rate tensor components to formulate a hypoplastic model tailored for sand–structure interfaces. To capture the influence of initial anisotropy, a deposition direction peak stress coefficient is incorporated; meanwhile, a friction parameter is introduced to address the surface roughness of the contact. Consequently, a comprehensive hypoplastic constitutive model is developed that takes into account both initial anisotropy and roughness. Comparative analysis with experimental data from soils on contact surfaces with diverse boundary conditions and levels of roughness indicates that the proposed model accurately forecasts shear test outcomes across various contact surfaces. Utilizing the finite element software ABAQUS 2021, an FRIC subroutine was developed, which, through simulating direct shear tests on sand–structure contact surfaces, has proven its efficacy in predicting the shear behavior of these interfaces. Full article

This investigation attempts to estimate time-averaged shear wave velocity in the upper 30 m of surficial material, V_S30, from the horizontal-to-vertical spectral ratios, HVSRs, of seismic observatory stations in the South Korean region. From 2016 to 2023, a collection of 783 three-component ground motions were obtained from 19 stations operated by the Korea Institute of Geoscience and Mineral Resources. HVSRs were extracted from 5% damped acceleration and velocity RotD50 response spectra at each site. Peak HVSR frequencies and amplitudes were extracted and regressed to field-measured V_S30s at available sites. An evaluation of different frequency and amplitude conditions was made to ascertain any effects on the regression. Findings included confirmation on minimum frequency and having amplitude conditions were unnecessary. Additionally, another peak frequency to V_S30 relationship derived from Central and Eastern North America captured most of the behavior found in the Korean dataset. Full article

This study examines the flow behavior as well as the cuttings transport of non-Newtonian drilling fluid in the geometry of an eccentric annulus, accounting for what impacts drill pipe rotation might have on fluid velocity, as well as annular eccentricity on axial and tangential distributions of velocity. A two-phase Eulerian–Eulerian model was developed by using computational fluid dynamics to simulate drilling fluid flow and cuttings transport. The kinetic theory of granular flow was used to study the dynamics and interactions of cuttings transport. Non-Newtonian fluid properties were modeled using power law and Bingham plastic formulations. The simulation results demonstrated a marked improvement in efficiency, as much as 45%, in transport by increasing the fluid inlet velocity from 0.54 m/s to 2.76 m/s, reducing the amount of particle accumulation and changing axial and tangential velocity profiles dramatically, particularly at narrow annular gaps. At a 300 rpm rotation, the drill pipe brought on a spiral flow pattern, which penetrated tangential velocities in the narrow gap that had increased transport efficiency to almost 30% more. Shear-thinning behavior characterizes fluid of which the viscosity, at nearly 50% that of the central core low-shear regions, was closer to the wall high-shear regions. Fluid velocity and drill pipe rotation play a crucial role in optimizing cuttings transport. Higher fluid velocities with controlled drill pipe rotation enhance cuttings removal and prevent particle build-up, thereby giving very useful guidance on how to clean the wellbore efficiently in drilling operations. Full article