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16 pages, 3700 KiB  
Article
Effect of Depth of Cut and Number of Layers on the Surface Roughness and Surface Homogeneity After Milling of Al/CFRP Stacks
by Elżbieta Doluk, Anna Rudawska and Stanisław Legutko
Materials 2025, 18(1), 206; https://doi.org/10.3390/ma18010206 - 6 Jan 2025
Viewed by 43
Abstract
A multilayer structure is a type of construction consisting of outer layers and a core, which is mainly characterized by high strength and specific stiffness, as well as the ability to dampen vibration and sound. This structure combines the high strength of traditional [...] Read more.
A multilayer structure is a type of construction consisting of outer layers and a core, which is mainly characterized by high strength and specific stiffness, as well as the ability to dampen vibration and sound. This structure combines the high strength of traditional materials (mainly metals) and composites. Currently, sandwich structures in any configurations (types of core) are one of the main directions of technology development and research. This paper evaluates the surface quality of II- and III-layer sandwich structures that are a combination of aluminum alloy and CFRP (Carbon Fiber-Reinforced Polymer) after the machining. The effect of depth of cut (ae) on the surface roughness of the II- and III-layer sandwich structures after the milling process was investigated. The surface homogeneity was also investigated. It was expressed by the IRa and IRz surface homogeneity indices formed from the Ra and Rz surface roughness parameters measured separately for each layer of the materials forming the sandwich structure. It was noted that the lowest surface roughness (Ra = 0.03 µm and Rz = 0.20 µm) was obtained after the milling of the II-layer sandwich structure using ae = 0.5 mm, while the highest was obtained for the III-layer structure and ae = 1.0 mm (Ra = 1.73 µm) and ae = 0.5 mm (Rz = 10.98 µm). The most homogeneous surfaces were observed after machining of the II-layer structure and using the depth of cut ae = 2.0 mm (IRa = 0.28 and IRz = 0.06), while the least homogeneous surfaces were obtained after milling of the III-layer structure and the depths of cut ae = 0.5 mm (IRa = 0.64) and ae = 2.0 mm (IRz = 0.78). The obtained results may be relevant to surface engineering and combining hybrid sandwich structures with other materials. Full article
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<p>Shape and dimensions of the research object: (<b>a</b>) II-layer sandwich structure; (<b>b</b>) III-layer sandwich structure.</p>
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<p>Clamping of the sample during the milling process: 1—workpiece, 2—tool, 3—machine vice.</p>
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<p>Surface roughness measurement station.</p>
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<p>Schematic of the overall surface roughness measurement area: (<b>a</b>) location on II-layer structure; (<b>b</b>) location on III-layer structure; (<b>c</b>) measurement points considered (1, 2, 3).</p>
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<p>Schematic of the measurement area for individual layers: (<b>a</b>) location on II-layer structure; (<b>b</b>) location on III-layer structure; (<b>c</b>) measurement points considered (1, 2, 3).</p>
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<p>The overall surface roughness after milling of II-layer sandwich structure depending on the depth of cut a<sub>e</sub>: (<b>a</b>) Ra parameter; (<b>b</b>) Rz parameter.</p>
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<p>The overall surface roughness after milling of III-layer sandwich structure depending on the depth of cut a<sub>e</sub>: (<b>a</b>) Ra parameter; (<b>b</b>) Rz parameter.</p>
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<p>I<sub>Ra</sub> surface homogeneity index.</p>
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<p>I<sub>Rz</sub> surface homogeneity index.</p>
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14 pages, 9593 KiB  
Article
Brewers’ Spent Grain-Derived Arabinoxylan as a Sustainable Filler for Enhanced PHBV Biocomposites
by Ilary Belardi, Fabrizio Sarasini, Jacopo Tirillò, Pietro Russo, Giovanni De Francesco, Ombretta Marconi and Assunta Marrocchi
Polymers 2025, 17(1), 114; https://doi.org/10.3390/polym17010114 - 5 Jan 2025
Viewed by 301
Abstract
Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) is a highly promising biodegradable and bio-based thermoplastic recognized for its environmental benefits and potential versatility. However, its industrial adoption has been limited due to its inherent brittleness and suboptimal processability. Despite these challenges, PHBV’s performance can be tailored for a [...] Read more.
Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) is a highly promising biodegradable and bio-based thermoplastic recognized for its environmental benefits and potential versatility. However, its industrial adoption has been limited due to its inherent brittleness and suboptimal processability. Despite these challenges, PHBV’s performance can be tailored for a wide range of applications through strategic modifications, particularly by blending it with other biodegradable polymers or reinforcing it with natural fibers and bio-based fillers. This study explores the potential of brewers’ spent grain (BSG) as a sustainable source for the development of PHBV biocomposites. The biocomposites were synthesized by incorporating arabinoxylan-bound benzoate, which can be derived from BSG, as a sustainable filler at concentrations of 4% and 10% w/w. The resulting materials were characterized using tensile testing, scanning electron microscopy (SEM), thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC). The findings demonstrate that the incorporation of functionalized arabinoxylan significantly enhances the mechanical properties of PHBV, preserves its thermal stability, and increases its crystallinity (from 59.9% to 67.6%), highlighting a positive impact on both material performance and processing characteristics. Full article
(This article belongs to the Special Issue Biobased and Biodegradable Polymer Blends and Composites II)
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<p>Typical stress vs. strain curves for neat PHBV and PHBV/AX composites.</p>
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<p>SEM micrographs detailing the fracture surface of all PHBV-based formulations and EDS analysis of neat PHBV.</p>
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<p>TGA curves and derivative weight against temperature (<b>a</b>) of the fillers and (<b>b</b>) of the PHBV-based composites.</p>
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<p>DSC thermograms of neat PHBV and PHBV-based composites during (<b>a</b>) cooling run and (<b>b</b>) second heating run.</p>
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14 pages, 4863 KiB  
Article
Investigation of Chitosan-Based Hydrogels and Polycaprolactone-Based Electrospun Fibers as Wound Dressing Materials Based on Mechanical, Physical, and Chemical Characterization
by Barkin Aydin, Nihat Arol, Nimet Burak, Aybala Usta and Muhammet Ceylan
Gels 2025, 11(1), 39; https://doi.org/10.3390/gels11010039 - 4 Jan 2025
Viewed by 417
Abstract
The aim of this project is to fabricate fiber mats and hydrogel materials that constitute the two main components of a wound dressing material. The contributions of boric acid (BA) and zinc oxide (ZnO) to the physical and mechanical properties of polycaprolactone (PCL) [...] Read more.
The aim of this project is to fabricate fiber mats and hydrogel materials that constitute the two main components of a wound dressing material. The contributions of boric acid (BA) and zinc oxide (ZnO) to the physical and mechanical properties of polycaprolactone (PCL) is investigated. These materials are chosen for their antimicrobial and antifungal effects. Additionally, since chitosan forms brittle hydrogels, it is reinforced with polyvinyl alcohol (PVA) to improve ductility and water uptake properties. For these purposes, PCL, BA, ZnO, PVA, and chitosan are used in different ratios to fabricate nanofiber mats and hydrogels. Mechanical, physical, and chemical characteristics are examined. The highest elastic modulus and tensile strength are obtained from samples with 6% BA and 10% ZnO concentrations. ZnO-decorated fibers exhibit a higher elastic modulus than those with BA, though BA-containing fibers exhibit greater elongation before breakage. All fibers exhibit hydrophobic properties, which help to prevent biofilm formation. In compression tests, CS12 demonstrates the highest strength. Increasing the PVA content enhances ductility, while a higher concentration of chitosan results in a denser structure. This outcome is confirmed by FTIR and swelling tests. These findings highlight the optimal combinations of nanofibrous mats and hydrogels, offering guidance for future wound dressing designs that balance mechanical strength, water absorption, and antimicrobial properties. By stacking these nanofibrous mats and hydrogels in different orders, it is expected to achieve a wound care material that is suitable for various applications. The authors encourage experimentation with different configurations of these nanofiber and hydrogel stackings to observe their mechanical behavior under real-life conditions in future studies. Full article
(This article belongs to the Section Gel Analysis and Characterization)
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<p>Stress–Strain graphs of specimens. (<b>a</b>) Stress–Strain graph of the first specimens. (<b>b</b>) Stress–Strain graph of the second specimens. (<b>c</b>) Stress–Strain graph of the third specimens. (<b>d</b>) Tensile test setup for fabricated fibers. (<b>e</b>) Electrospun mat with 6% ZnO.</p>
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<p>Tensile test results of electrospun nanofibers. (<b>a</b>) Ultimate Tensile stress (<b>b</b>) Strain values at failure (<b>c</b>) Elastic module values.</p>
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<p>SEM image of surface morphology. 1 kx magnification (<b>Left</b>), 10 kx magnification (<b>Right</b>).</p>
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<p>Contact angle values of electrospun nanofiber with different amounts of BA and ZnO.</p>
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<p>Contact angle images of electrospun nanofibers at the first contact.</p>
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<p>Contact angle values of hydrogels. Initial contact angle (dashed bars), contact angle of the same drops after 30 s (solid bars).</p>
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<p>Contact angle images of hydrogels. (<b>a</b>) CS12, (<b>b</b>) CS12 after 30 s, (<b>c</b>) CS8, (<b>d</b>) CS8 after 30 s, (<b>e</b>) CS6, (<b>f</b>) CS6 after 30 s, (<b>g</b>) CS4, (<b>h</b>) CS4 after 30 s.</p>
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<p>Stress–Strain graphs of specimens for compression test. (<b>a</b>) Stress–Strain graph of the first specimen. (<b>b</b>) Stress–Strain graph of the second specimen. (<b>c</b>) Stress–Strain graph of the third specimen. (<b>d</b>) Compression test setup for fabricated hydrogels. (<b>e</b>) A sample for compression test.</p>
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<p>Compression test results of hydrogels. (<b>a</b>) Strain values at failure. (<b>b</b>) Ultimate compression stress.</p>
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<p>FTIR Spectra of electrospun nanofiber samples PCL, PCL/BA10%, and PCL/ZnO10%.</p>
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<p>FTIR Spectra of samples CS12, CS8, CS6, and CS4.</p>
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<p>Evaluation of swelling degree of the CS/PVA hydrogels crosslinked with GA.</p>
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19 pages, 1488 KiB  
Article
Frozen Fermented Dairy Snacks with Probiotics and Blueberry Bagasse: Stability, Bioactivity, and Digestive Viability
by Alejandra Hurtado-Romero, Andrea Zepeda-Hernández, Javier Cárdenas-Rangel, Ricardo Aguilar-Márquez, Luis Eduardo Garcia-Amezquita, Danay Carrillo-Nieves and Tomás García-Cayuela
Microorganisms 2025, 13(1), 86; https://doi.org/10.3390/microorganisms13010086 - 4 Jan 2025
Viewed by 317
Abstract
The demand for healthier snack options has driven innovation in frozen dairy products. This study developed and characterized novel frozen dairy snacks fermented with probiotics (Lactobacillus acidophilus LA5; Lacticaseibacillus rhamnosus GG, and Streptococcus thermophilus BIOTEC003) and containing 2% blueberry bagasse. Four formulations [...] Read more.
The demand for healthier snack options has driven innovation in frozen dairy products. This study developed and characterized novel frozen dairy snacks fermented with probiotics (Lactobacillus acidophilus LA5; Lacticaseibacillus rhamnosus GG, and Streptococcus thermophilus BIOTEC003) and containing 2% blueberry bagasse. Four formulations (LA5, LGG, LA5-BERRY, and LGG-BERRY) were analyzed for their nutritional, physicochemical, functional, and sensory properties. High protein content (>17% d.w.) and increased dietary fiber (5.77–5.88% d.w.) were observed in bagasse-containing formulations. Stable technological characteristics were maintained, with melting rates increasing slightly during storage. Probiotic viability remained high (>8.5 log CFU/mL) after freezing and storage at −20 °C for 30 days. Post-simulated digestion, probiotics retained >7.5 log CFU/mL, while blueberry bagasse formulations exhibited significantly higher phenolic content (7.62–8.74 mg/g d.w.) and antioxidant capacity, though anthocyanin content decreased (66–68%). Sensory evaluation by 100 panelists revealed high acceptance scores (>63%), with LGG-BERRY achieving the highest score (78%). These formulations demonstrate significant potential for incorporating probiotics and functional ingredients, providing an innovative solution for probiotic delivery and the sustainable utilization of fruit by-products in the food industry. Full article
(This article belongs to the Special Issue Probiotic Bacteria in Fermented Foods)
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<p>Experimental sequence for developing and evaluating the frozen dairy snacks fermented with probiotics and containing blueberry bagasse.</p>
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<p>Physicochemical parameters (<b>A</b>), viscosity; (<b>B</b>), melting rate; (<b>C</b>), pH; and (<b>D</b>), titratable acidity) of frozen fermented dairy snack formulations immediately on the same day they were prepared (day 0), one day after freezing (day 1), and after 30 days of storage at −20 °C (day 30). Capital letters indicate significant differences (<span class="html-italic">p</span> &lt; 0.05) among days of storage, and lower-case letters indicate significant differences among formulations. The error bars indicate the standard deviation. Frozen snack formulations are described in <a href="#microorganisms-13-00086-t001" class="html-table">Table 1</a>.</p>
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<p>Viability (log CFU/mL) of probiotics <span class="html-italic">Lactobacillus acidophilus</span> LA5 and <span class="html-italic">Lacticaseibacillus rhamnosus</span> GG in MRS medium (<b>A</b>) and <span class="html-italic">Streptococcus thermophilus</span> BIOTEC003 in L-M17 medium (<b>B</b>) within frozen fermented dairy snack formulations before and after in vitro digestion (intestinal phase) on day 1 and day 30 during storage at −20 °C. Error bars indicate the standard deviation. Capital letters represent significant differences before and after in vitro digestion within each formulation. No significant differences were observed between storage days (<span class="html-italic">p</span> &lt; 0.05). Frozen snack formulations are described in <a href="#microorganisms-13-00086-t001" class="html-table">Table 1</a>. CFU, Colony Forming Units.</p>
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<p>Sensory properties of frozen fermented dairy snack formulations were evaluated based on the acceptability index using a 9-point hedonic scale. Capital letters indicate significant differences (<span class="html-italic">p</span> &lt; 0.05) among formulations. The error bars indicate the standard deviation. Frozen snack formulations are described in <a href="#microorganisms-13-00086-t001" class="html-table">Table 1</a>.</p>
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15 pages, 744 KiB  
Article
The Effect of Corn Ensiling Methods on Digestibility and Biogas Yield
by Karol Kupryaniuk, Kamil Witaszek, Iryna Vaskina, Sebastian Filipek-Kaźmierczak, Jakub Kupryaniuk, Piotr Sołowiej and Jacek Dach
Energies 2025, 18(1), 188; https://doi.org/10.3390/en18010188 - 4 Jan 2025
Viewed by 174
Abstract
This study investigates the impact of different corn silage preparation methods, namely the traditional and Shredlage methods, on digestibility and biogas yield in anaerobic digestion and its nutritional value—the first complex study of its kind. Key parameters of both silage types were analyzed, [...] Read more.
This study investigates the impact of different corn silage preparation methods, namely the traditional and Shredlage methods, on digestibility and biogas yield in anaerobic digestion and its nutritional value—the first complex study of its kind. Key parameters of both silage types were analyzed, including chemical composition, fiber content, and elemental makeup. Methane and biogas production were assessed under standardized fermentation conditions. The results showed that the Shredlage method, characterized by more intensive chopping, led to higher biogas and methane yields per unit of organic dry matter compared to traditional silage. This improvement is attributed to enhanced digestibility due to the lower content of neutral detergent fiber (NDF), acid detergent fiber (ADF), and crude fiber in Shredlage. An elemental analysis revealed slight differences in carbon-to-nitrogen (C/N) ratios, with both silages showing values suitable for efficient fermentation. Despite minor variations in mineral content, Shredlage demonstrated greater efficiency in biogas production, particularly for rapid fermentation processes. The findings underscore the importance of silage preparation techniques in optimizing biogas yield and suggest Shredlage as a superior option for enhancing energy recovery in biogas plants. Future work should explore the economic trade-offs and scalability of these methods. Full article
(This article belongs to the Special Issue New Challenges in Biogas Production from Organic Waste)
17 pages, 5679 KiB  
Article
Fiber Bragg Grating Thermometry and Post-Treatment Ablation Size Analysis of Radiofrequency Thermal Ablation on Ex Vivo Liver, Kidney and Lung
by Sanzhar Korganbayev, Leonardo Bianchi, Clara Girgi, Elva Vergantino, Domiziana Santucci, Eliodoro Faiella and Paola Saccomandi
Sensors 2025, 25(1), 245; https://doi.org/10.3390/s25010245 - 3 Jan 2025
Viewed by 361
Abstract
Radiofrequency ablation (RFA) is a minimally invasive procedure that utilizes localized heat to treat tumors by inducing localized tissue thermal damage. The present study aimed to evaluate the temperature evolution and spatial distribution, ablation size, and reproducibility of ablation zones in ex vivo [...] Read more.
Radiofrequency ablation (RFA) is a minimally invasive procedure that utilizes localized heat to treat tumors by inducing localized tissue thermal damage. The present study aimed to evaluate the temperature evolution and spatial distribution, ablation size, and reproducibility of ablation zones in ex vivo liver, kidney, and lung using a commercial device, i.e., Dophi™ R150E RFA system (Surgnova, Beijing, China), and to compare the results with the manufacturer’s specifications. Optical fibers embedding arrays of fiber Bragg grating (FBG) sensors, characterized by 0.1 °C accuracy and 1.2 mm spatial resolution, were employed for thermometry during the procedures. Experiments were conducted for all the organs in two different configurations: single-electrode (200 W for 12 min) and double-electrode (200 W for 9 min). Results demonstrated consistent and reproducible ablation zones across all organ types, with variations in temperature distribution and ablation size influenced by tissue characteristics and RFA settings. Higher temperatures were achieved in the liver; conversely, the lung exhibited the smallest ablation zone and the lowest maximum temperatures. The study found that using two electrodes for 9 min produced larger, more rounded ablation areas compared to a single electrode for 12 min. Our findings support the efficacy of the RFA system and highlight the need for tailored RFA parameters based on organ type and tumor properties. This research provides insights into the characterization of RFA systems for optimizing RFA techniques and underscores the importance of accurate thermometry and precise procedural planning to enhance clinical outcomes. Full article
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<p>Experimental setup of RFA in liver, kidney, and lung. The experimental setup includes the RF generator connected to the water-cooled electrode(s) and the grounding pad; the biological tissue sample (bovine liver, kidney, or lung tissue); the optical interrogation unit connected to the optical fiber(s), embedding a chain of FBG sensors, and a laptop for displaying temperature evolution and distribution measured by the FBG sensors.</p>
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<p>Placement of the electrodes and FBG sensors in the organs and definition of the ablation axes ‘a’ and ‘b’. On the left, the experimental setup is illustrated, while an enlargement of the position of the electrodes and optical fibers in the sample is shown on the right.</p>
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<p>Bovine liver. Single-electrode configuration: (<b>a</b>) trends of maximum temperature variation at distances of 1 cm (blue) and 2 cm (red) from the RF electrode, and 2D temperature evolution maps along the sensor over time at a distance of (<b>b</b>) 1 cm and (<b>c</b>) 2 cm from the electrode. Double-electrode configuration: (<b>d</b>) trends of maximum temperature registered between the electrodes (blue), at 1 cm (red) and 2 cm (yellow) from the RF electrode; 2D temperature evolution maps along the sensor over time (<b>e</b>) between the two electrodes, at a distance of (<b>f</b>) 1 cm and (<b>g</b>) 2 cm from the electrode.</p>
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<p>Bovine kidney. Single-electrode configuration: (<b>a</b>) trends of maximum temperature change at distances of 1 cm (blue) and 2 cm (red) from the RF electrode, and 2D temperature evolution maps along the sensor over time at a distance of (<b>b</b>) 1 cm and (<b>c</b>) 2 cm from the electrode. Double-electrode configuration: (<b>d</b>) trends of maximum temperature registered between the electrodes (blue), at 1 cm (red) and 2 cm (yellow) from the RF electrode; 2D temperature evolution maps along the sensor over time (<b>e</b>) between the two electrodes, at a distance of (<b>f</b>) 1 cm and (<b>g</b>) 2 cm from the electrode.</p>
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<p>Bovine lung. The results of the single-electrode configuration experiments are shown in the upper panel: (<b>a</b>) trends of maximum temperature change at distances of 1 cm (blue) and 2 cm (red) from the electrode, and 2D temperature change maps along the sensor over time at a distance of (<b>b</b>) 1 cm and (<b>c</b>) 2 cm from the electrode. Double-electrode configuration (lower panel): (<b>d</b>) trends of maximum temperature registered between the electrodes (blue), at 1 cm (red) and 2 cm (yellow) from the RF electrode; 2D temperature evolution maps along the sensor over time (<b>e</b>) between the two electrodes, at a distance of (<b>f</b>) 1 cm and (<b>g</b>) 2 cm from the electrode.</p>
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<p>Bovine liver: ablation axes obtained from ex vivo experiments compared with the manufacturer’s data at different settings (i.e., 200 W for 12 min in the case of single-electrode configuration and 200 W for 9 min for the double-electrode configuration).</p>
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<p>Bovine kidney: ablation axes obtained from ex vivo experiments compared with the company’s data at different settings (i.e., 200 W for 12 min in the case of single-electrode configuration and 200 W for 9 min for the double-electrode configuration).</p>
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<p>Bovine lung: ablation axes obtained from ex vivo experiments compared with the company’s data at different settings (i.e., 200 W for 12 min in the case of single-electrode configuration and 200 W for 9 min for the double-electrode configuration).</p>
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24 pages, 3944 KiB  
Article
Biocomposite Active Whey Protein Films with Thyme Reinforced by Electrospun Polylactic Acid Fiber Mat
by Andreea (Lanciu) Dorofte, Iulia Bleoanca, Florentina Ionela Bucur, Gabriel Mustatea, Daniela Borda, Felicia Stan and Catalin Fetecau
Foods 2025, 14(1), 119; https://doi.org/10.3390/foods14010119 - 3 Jan 2025
Viewed by 417
Abstract
Electrospinning is a versatile technique for obtaining nano/micro fibers which are able to significantly change the active properties of composite materials and bring in new dimensions to agri-food applications. Composite bio-based packaging materials obtained from whey proteins, functionalized with thyme essential oil (TEO) [...] Read more.
Electrospinning is a versatile technique for obtaining nano/micro fibers which are able to significantly change the active properties of composite materials and bring in new dimensions to agri-food applications. Composite bio-based packaging materials obtained from whey proteins, functionalized with thyme essential oil (TEO) and reinforced by electrospun polylactic acid (PLA) fibers, represent a promising solution for developing new active food packaging using environmentally friendly materials. The aim of this study is to obtain and characterize one-side-active composite films covered with a PLA fiber mat: (i) WF/G1, WF/G2, and WF/G3 resulting from electrospinning with one needle at different electrospinning times of 90, 150, and 210 min, respectively, and (ii) WF/G4 obtained with two face-to-face needles after 210 min of electrospinning. While TEO bioactivity is mainly related to its antimicrobial and antioxidant properties, the PLA fiber mat uplifted the composite mechanical and barrier properties of films. The bi-layer films obtained were characterized by SEM, showing the distribution of the electrospun fiber mat and an increased thickness of the PLA layer from WF/G1 to WF/G4, while FTIR spectra showed the structural vibrations of the functional groups. The experimental results show that WF/G4 have a FTIR fingerprint resembling PLA, retained ~50% of the volatile compounds present in the uncovered film (WF/TEO), while it only had 1.41 ± 0.14 (%) of the permeability to octanol of the WF/G1 film. WF/G4 exhibited 33.73% of the WVP of WF/G1 and displayed the highest tensile strength, about 2.70 times higher than WF/TEO. All films studied revealed similar antimicrobial effect against Bacillus cereus, Geotrichum candidum, and Rhodotorula glutinis and good antiradical activity, thus demonstrating good prospects to be applied as food packaging materials. WF/G composite materials are good candidates to be used as bioactive flavoring primary packaging in hard cheese making. Full article
(This article belongs to the Special Issue Advances in the Development of Sustainable Food Packaging)
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<p>Electrospinning process.</p>
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<p>Separation of VOCs through the WF/Gs with PLA fiber mat applied during SPME GC/Ms analysis using two glass vials.</p>
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<p>Visual and morphological analysis of WF/G1–G4 fiber layers: (<b>A</b>) macroscopic view (1:2); (<b>B</b>) SEM top view of PLA fiber mats; (<b>C</b>) histograms of minimum Feret fiber distribution evaluated from N = 150 measurements; (<b>D</b>) SEM cross-section with the estimated thickness of the mat given as mean ± standard deviation (SD).</p>
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<p>Aligned FT-IR spectra of (<b>A</b>) WF/G1, WF/G2, WF/G4, WF/TEO, and PLA from 1500 to 3400 cm<sup>−1</sup> wavenumber and PCA scores and clusters; (<b>B</b>) WF/G1, WF/G2, WF/G3, and WF/TEO and (<b>C</b>) WF/G4 and PLA from 600 to 1500 cm<sup>−1</sup> wavenumber; (<b>A1</b>) the principal component analysis (PCA) scores and clusters of WF/G1, WF/G2, WF/G4, WF/TEO, and PLA spectra for 1500 to 3400 cm<sup>−1</sup>; and (<b>B1</b>) the PCA scores and clusters of WF/G1, WF/G2, WF/G4, WF/TEO, and PLA spectra in the fingerprint region (600 to 1500 cm<sup>−1</sup>).</p>
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<p>Heat map describing the retention capacity of WF/G films covered with PLA mat in comparison with the uncovered film (WF/TEO), where the red signifies no VOC retention and green very good barrier properties, while orange and yellow signify medium barrier properties of films.</p>
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<p>Permeability of the WF/G films: (<b>A</b>) 2-octanol determined by diffusion through the WF/G films positioned with PLA mat in comparison with control (WF/TEO) (<span class="html-italic">p</span>-value = 0.000); (<b>B</b>) water vapor (<span class="html-italic">p</span>-value = 0.000); (<b>C</b>) oxygen (<span class="html-italic">p</span>-value = 0.080); and (<b>D</b>) carbon dioxide (<span class="html-italic">p</span>-value = 0.000). Values obtained are the mean of three analyses ± SD. Significant differences among samples (<span class="html-italic">p</span> &lt; 0.05) are indicated by different letters established by ANOVA and Tukey’s post hoc test.</p>
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<p>Representative stress–strain curves for biocomposite films.</p>
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<p>Antiradical activity of film without TEO (control WF) and with TEO (WF/TEO). Values obtained are the mean of three analyzes ± SD; different letters obtained indicate significant differences (<span class="html-italic">p</span> &lt; 0.05) between samples as determined by ANOVA and Tukey’s post hoc test; <span class="html-italic">p</span>-value = 0.000.</p>
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20 pages, 10387 KiB  
Article
Micro-Level Hybridization of Steel, Glass, and Polypropylene Filaments via Air Texturing: Mechanical and Morphological Analysis
by Jan Rehra, Matthias Overberg, Sebastian Schmeer, Anwar Abdkader and Chokri Cherif
J. Compos. Sci. 2025, 9(1), 12; https://doi.org/10.3390/jcs9010012 - 2 Jan 2025
Viewed by 218
Abstract
The increasing application of fiber-reinforced polymer (FRP) composites necessitates the development of composite structures that exhibit high stiffness, high strength, and favorable failure behavior to endure complex loading scenarios and improve damage tolerance. Achieving these properties can be facilitated by integrating conventional FRPCs [...] Read more.
The increasing application of fiber-reinforced polymer (FRP) composites necessitates the development of composite structures that exhibit high stiffness, high strength, and favorable failure behavior to endure complex loading scenarios and improve damage tolerance. Achieving these properties can be facilitated by integrating conventional FRPCs with metallic materials, which offer high ductility and superior energy absorption capabilities. However, there is a lack of effective solutions for the micro-level hybridization of high-performance filament yarns, metal filament yarns, and thermoplastic filament yarns. This study aims to investigate the hybridization of multi-material components at the micro-level using the air-texturing process. The focus is on investigating the morphological and the mechanical properties as well as the damage behavior in relation to the process parameters of the air-texturing process. The process-induced property changes were evaluated throughout the entire process, starting from the individual components, through the hybridization process, and up to the tape production. Tensile tests on multifilament yarns and tape revealed that the strength of the hybrid materials is significantly reduced due to the hybridization process inducing fiber damage. Morphological analyses using 3D scans and micrographs demonstrated that the degree of hybridization is enhanced due to the application of air pressure during the hybridization process. However, this phenomenon is also influenced by the flow movement of the PP matrix during the consolidation stage. The hybrid laminates exhibited a damage behavior that differs from the established behavior of layer-separated metal fiber hybrids, thereby supporting other failure and energy absorption mechanisms, such as fiber pull-out. Full article
(This article belongs to the Special Issue Recent Progress in Hybrid Composites)
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<p>Three general levels of hybridization for laminated composites, according to [<a href="#B14-jcs-09-00012" class="html-bibr">14</a>].</p>
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<p>Manufacturing hybrid multi-material yarns using air jet texturing machine along the direction of the arrow.</p>
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<p>(<b>a</b>) Winding unit and press tool adapted to the tape geometry, (<b>b</b>) process overview of the tape manufacturing, and (<b>c</b>) time–temperature profile of the press process.</p>
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<p>(<b>a</b>) Test setup for single and multifilament testing; (<b>b</b>) setup for laminate testing.</p>
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<p>Qualitative stress–strain behavior of SCFRP, including its characteristic properties.</p>
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<p>Overview of the process for determining the geometry information of hybrid yarn and tape morphologies.</p>
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<p>(<b>a</b>) Local density evaluation for the point pattern of a hybrid yarn and (<b>b</b>) iterative accumulation of the normalized subsection counts for steel fibers and glass fibers over the total number of subsections.</p>
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<p>Exemplary fiber topologies in an ROI of 500 × 500 µm, a subsection size of 100 × 100 µm, and two fiber types (∅<sub>1</sub> = 10 µm and ∅<sub>2</sub> = 50 µm), including the evaluation of the associated degree of hybridization.</p>
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<p>(<b>a</b>) Stress–strain curves of the individual glass fiber (GF) and (<b>b</b>) the stainless-steel fiber (SF), including the characteristic properties.</p>
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<p>(<b>a</b>) Superposed mechanical properties of a hybrid composite with a steel fiber volume fraction of 18.2 vol.%, a glass fiber volume fraction of 40.4 vol.%, and a PP volume fraction of 41.4 vol.%. and (<b>b</b>) superposed characteristic properties of the hybrid composite with the corresponding determination equations.</p>
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<p>Micrographs and the 3D geometries of the hybrid yarns investigated in this study.</p>
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<p>(<b>a</b>) The degree of undulation, (<b>b</b>) fiber orientation, and (<b>c</b>) degree of hybridization of the hybrid yarns investigated in this study.</p>
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<p>(<b>a</b>) Mean curves of the stress–strain behavior of the hybrid yarns, and (<b>b</b>–<b>f</b>) an overview of the characteristic properties in the stress–strain behavior of the hybrid yarns. This includes the tensile stiffness Ex in (<b>b</b>), yield stress σ<sub>yi</sub> in (<b>c</b>), initial failure stress σ<sub>ini</sub> in (<b>d</b>), elongation at break ε<sub>b</sub> in (<b>e</b>), and energy absorption U in (<b>f</b>).</p>
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<p>Three-dimensional scans and micrographs of the morphology of the hybrid tapes investigated in this study.</p>
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<p>(<b>a</b>) The degree of undulation, (<b>b</b>) fiber orientation, and (<b>c</b>) degree of hybridization of the hybrid tapes investigated in this study.</p>
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<p>(<b>a</b>) Mean curves of the stress–strain behavior of the hybrid tapes and (<b>b</b>–<b>f</b>) an overview of the characteristic properties in the stress–strain behavior of the hybrid tapes. This includes the tensile stiffness Ex in (<b>b</b>), yield stress σ<sub>yi</sub> in (<b>c</b>), initial failure stress σ<sub>ini</sub> in (<b>d</b>), elongation at break ε<sub>b</sub> in (<b>e</b>), and energy absorption U in (<b>f</b>).</p>
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<p>(<b>a</b>) Damage occurring in tensile tests of homogeneously hybridized glass and steel fiber-reinforced PP and (<b>b</b>) a radiographic image of a specimen in a state directly after the initial failure.</p>
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13 pages, 5166 KiB  
Article
Fiber Optic Micro-Hole Salinity Sensor Based on Femtosecond Laser Processing
by Chen Li, Chao Fan, Hao Wu, Xxx Sedao and Jiang Wang
Nanomaterials 2025, 15(1), 60; https://doi.org/10.3390/nano15010060 - 2 Jan 2025
Viewed by 364
Abstract
This study presents a novel reflective fiber Fabry–Perot (F–P) salinity sensor. The sensor employs a femtosecond laser to fabricate an open liquid cavity, facilitating the unobstructed ingress and egress of the liquid, thereby enabling the direct involvement of the liquid in light transmission. [...] Read more.
This study presents a novel reflective fiber Fabry–Perot (F–P) salinity sensor. The sensor employs a femtosecond laser to fabricate an open liquid cavity, facilitating the unobstructed ingress and egress of the liquid, thereby enabling the direct involvement of the liquid in light transmission. Variations in the refractive index of the liquid induce corresponding changes in the effective refractive index of the optical path, which subsequently influences the output spectrum. The dimensions and quality of the optical fiber are meticulously regulated through a combination of femtosecond laser cutting and chemical polishing, significantly enhancing the mechanical strength and sensitivity of the sensor’s overall structure. Experimental results indicate that the sensor achieves salinity sensitivity of 0.288 nm/% within a salinity range of 0% to 25%. Furthermore, the temperature sensitivity is measured at a minimal 0.015 nm/°C, allowing us to neglect temperature effects. The device is characterized by its compact size, straightforward structure, high mechanical robustness, ease of production, and excellent reproducibility. It demonstrates considerable potential for sensing applications in the domains of biomedicine and chemical engineering. Full article
(This article belongs to the Special Issue Nonlinear Optics and Ultrafast Lasers in Nanosystems)
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<p>Sensor structure diagram: (<b>a</b>) top view, (<b>b</b>) side view, (<b>c</b>) front view.</p>
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<p>Electric field distribution under different apertures: (<b>a</b>) L<sub>1</sub> = 5 μm, (<b>b</b>) L<sub>1</sub> = 15 μm, (<b>c</b>) L<sub>1</sub> = 25 μm.</p>
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<p>Spectral characteristics of the sensor: (<b>a</b>) reflection spectra, (<b>b</b>) frequency spectra.</p>
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<p>Salinity simulation results of the FP structure: (<b>a</b>) spectra shift, (<b>b</b>) linear fitting.</p>
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<p>Schematic of the fs laser machining system.</p>
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<p>The effect of the repetition rate on micro-hole processing on the surfaces of optical fibers: (<b>a</b>) diameter, (<b>b</b>) depth.</p>
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<p>The effect of single pulse energy on Cavity1 machining: (<b>a</b>) L<sub>1</sub>, (<b>b</b>) K.</p>
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<p>Fabrication process and optical pictures of the sensor: (<b>a</b>) Ablation groove, (<b>b</b>) Processing micro-holes, (<b>c</b>) Cutting Fiber, (<b>d</b>) Etching Fiber, (<b>e</b>) Top view, (<b>f</b>) Side view.</p>
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<p>Schematic diagram of salinity device.</p>
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<p>Salinity experiment results for the FP structure: (<b>a</b>) spectral shift, (<b>b</b>) linear fitting.</p>
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<p>Schematic diagram of temperature device.</p>
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<p>Temperature experiment results for the FP structure: (<b>a</b>) spectral shift, (<b>b</b>) linear fitting.</p>
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18 pages, 2189 KiB  
Article
Biotechnological Effects of Lactobacillus plantarum, Cellulase, and Xylanase on Nutritional Quality and Microbial Community Structure of Corn Stover Silage
by Jianliang Liu, Mingjian Liu, Panjie Sheng, Chaoran Song, Weiqin Ma, Baochao Bai, Jiayu Zhao, Shuai Du, Gentu Ge, Zhijun Wang and Yushan Jia
Fermentation 2025, 11(1), 14; https://doi.org/10.3390/fermentation11010014 - 2 Jan 2025
Viewed by 411
Abstract
As animal husbandry advances, the demand for premium feed has seen substantial growth, while the availability of natural forage resources remains limited. Corn stover, characterized by its high yield and rich nutritional content, has become a vital source of roughage. The application of [...] Read more.
As animal husbandry advances, the demand for premium feed has seen substantial growth, while the availability of natural forage resources remains limited. Corn stover, characterized by its high yield and rich nutritional content, has become a vital source of roughage. The application of silage technology to corn stover enhances its palatability, improves its nutritional value, and exerts positive effects on livestock production performance. This study aims to evaluate the impact of different additives and their proportions on the nutrient composition, fermentation quality, and microbial community structure of corn stover silage. Specifically, Lactobacillus plantarum, cellulase preparations (commercial cellulase enzyme preparations), and xylanase preparations (commercial xylanase enzyme preparations) were employed as additives to investigate their synergistic effects and underlying mechanisms during the silage process. Furthermore, dosage gradients were established to determine the optimal dosage range, providing a robust scientific basis for the optimization of additive applications. In this experiment, corn stover was used as the substrate, with the moisture content maintained at 60%. Treatments with Lactobacillus plantarum, cellulase, and xylanase were applied, and silage samples were analyzed after 30 and 60 days of fermentation to assess fermentation quality, nutritional quality, and microbial community structure. The findings revealed that the nutritional quality of corn stover silage improved progressively with fermentation time. Compared to the control group, the addition of Lactobacillus plantarum, cellulase, and xylanase significantly increased the abundance of lactic acid bacteria, reduced the pH value, and effectively suppressed the proliferation of spoilage microorganisms. Among the treatments, xylanase demonstrated the most pronounced effects, substantially increasing lactic acid and soluble carbohydrate content while reducing levels of neutral detergent fiber (NDF) and acid detergent fiber (ADF). Notably, the incorporation of 20 U/g xylanase into the silage process facilitated the breakdown of xylan in corn stover into soluble carbohydrates, thereby providing essential substrates for lactic acid bacteria and other beneficial microorganisms. This, in turn, inhibited the growth of harmful microorganisms, ultimately improving the nutritional quality, fermentation quality, and microbial community structure of the silage. These findings provide a theoretical framework and practical guidance for optimizing the production of corn stover silage, promoting efficient resource utilization, and supporting the sustainable development of animal husbandry. Full article
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<p>Impacts of different added substances on α-diversity of microorganisms in corn stover silage. The figure shows the significant differences between the selected two groups of samples and marks the two groups with significant differences (0.01 &lt; <span class="html-italic">p</span> ≤ 0.05 marked as *, 0.001 &lt; <span class="html-italic">p</span> ≤ 0.01 marked as **, <span class="html-italic">p</span> ≤ 0.001 marked as ***). The <span class="html-italic">x</span>-axis shows the group names, and the <span class="html-italic">y</span>-axis shows the values of each group’s pointers. FM: fresh material; CK1: CK aging for 30 days; CK2: CK maturation for 60 days; LP1: LP maturation for 30 days; LP2: LP aging for 60 days; CE1: LPCE2 maturation for 30 days; CE2: LPCE2 maturation for 60 days; XE1: LPXE2 aging for 30 days; XE2: LPXE2 maturation for 60 days. These two numbers are the same. (<b>A</b>) Microbial diversity (Ace) of corn straw under different treatment groups, (<b>B</b>) Microbial diversity (Chao) of corn straw under different treatment groups, (<b>C</b>) Microbial diversity (Shannon) of corn straw under different treatment groups, (<b>D</b>) Microbial diversity (Simpson) of corn straw under different treatment groups.</p>
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<p>Effects of different additives on β-diversity of corn stalk silage. Note: FM, fresh material; CK1, CK silage fermented for 30 days; CK2, CK silage fermented for 60 days; LP1, LP silage fermented for 30 days; LP2, LP silage fermented for 60 days; CE1, LPCE2 silage fermented for 30 days; CE2, LPCE2 silage fermented for 60 days; XE1, LPXE2 silage fermented for 30 days; XE2, LPXE2 silage fermented for 60 days. he ellipse represents the within-group differences.</p>
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<p>Impacts of different additive treatments on microbial community structure of corn straw silage at phylum and class levels. (<b>A</b>) Microbial species composition at phylum level; (<b>B</b>) differences in microbial species composition between different treatments at the phylum level; (<b>C</b>) microbial species composition at sort level; (<b>D</b>) differences in microbial species composition between different treatments at the class level.</p>
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<p>Correlation analysis (RDA) of bacterial communities with nutritional and fermentation quality of corn straw silage. A redundancy analysis (RDA) ordination plot of bacteria and the explanatory variables (such as pH, NH<sub>3</sub>-N, LA, AA, DM, NDF, ADF, ADL, CP, WSC) is shown. The variables are represented as arrows. pH: pH value; LA: lactic acid; AA: acetic acid; NH<sub>3</sub>-N: ammonia nitrogen; DM: dry matter; NDF: neutral detergent fiber; ADF: acid detergent fiber; CP: crude protein; WSC: water-soluble carbohydrate.</p>
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<p>Forecast of 16S rRNA quality work of broom sorghum straw crude materials and silage tests after 60 days of aging. (<b>A</b>) Essential pathway level, (<b>B</b>) auxiliary pathway level, (<b>C</b>) tertiary pathway level; FM: fresh material; CK: control group; LP: <span class="html-italic">Lactobacillus plantarum</span> treatment; CE: cellulase treatment; XE: xylanase treatment.</p>
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17 pages, 11853 KiB  
Article
An Experimental Study on the Shear Performance of a CFRP–Steel Composite Component Bushing Bolt Connection
by Bing Guo, Guangxin Luo, Ziyu Wang, Deyi Wang, Qun Zhang, Longbo Zhang and Xingxing Wang
Coatings 2025, 15(1), 35; https://doi.org/10.3390/coatings15010035 - 2 Jan 2025
Viewed by 332
Abstract
Carbon Fiber Reinforced Polymers (CFRPs) are extensively utilized in civil engineering and other domains due to their exceptional mechanical properties. Integrating CFRPs with steel presents an approach to structural design, characterized by enhanced load-bearing capabilities and extended service life. Static tensile and hysteretic [...] Read more.
Carbon Fiber Reinforced Polymers (CFRPs) are extensively utilized in civil engineering and other domains due to their exceptional mechanical properties. Integrating CFRPs with steel presents an approach to structural design, characterized by enhanced load-bearing capabilities and extended service life. Static tensile and hysteretic tests were employed to examine the influence of the bolt diameter and steel plate thickness on the shear resistance of component. The results indicate that under monotonic loading, the load–displacement curves for each component undergo three distinct phases: the linear stage, damage evolution stage, and failure stage, ultimately leading to a bolt pull-off failure in all six groups of components. Under cyclic loading, the component with a 1.5 mm thick steel plate and a 4.6 mm diameter bushing bolt experienced bolt shear failure, primarily caused by the increased steel plate thickness, which enhanced the component’s load-carrying capacity, ultimately leading to the overloading and failure of the M4 bolt. The other five groups of components experienced pull-off failures. The hysteresis curve analysis revealed that enhancements in steel plate thickness and bolt diameter improve the hysteresis behaviour of the connections. However, there was a significant reduction in the strength degradation coefficient and hoop stiffness, which decreased to approximately 55% and 40% of their initial values, respectively. Full article
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<p>Schematic diagram of single lap component.</p>
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<p>Tensile and hysteretic test device for CFRP components.</p>
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<p>Loading system for hysteretic test.</p>
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<p>Measurement method of yield displacement and ultimate displacement.</p>
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<p>Load–displacement curve of 1.0 mm thick steel plate: (<b>a</b>) A-1, (<b>b</b>) A-2, (<b>c</b>) A-3, (<b>d</b>) B-1, (<b>e</b>) B-2, and (<b>f</b>) B-3.</p>
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<p>Tensile-load comprehensive curve.</p>
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<p>Failure mode of CFRP–steel plate components in tensile test: (<b>a</b>) 1.0 mm steel plate and (<b>b</b>) 1.5 mm steel plate.</p>
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<p>Microstructure of tensile shear failure of 1.0 mm thick steel plate.</p>
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<p>Microstructure of tensile shear failure of 1.5 mm thick steel plate.</p>
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<p>Hysteretic curves of six groups of components: (<b>a</b>) AC-1, (<b>b</b>) AC-2, (<b>c</b>) AC-3, (<b>d</b>) BC-1, (<b>e</b>) BC-2, and (<b>f</b>) BC-3.</p>
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<p>Failure mode of CFRP–steel plate components in hysteretic test: (<b>a</b>) 1.0 mm steel plate and (<b>b</b>) 1.5 mm steel plate.</p>
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<p>Microstructure of 1.0 mm thick steel plate failure in hysteretic test.</p>
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<p>Microstructure of 1.5 mm thick steel plate failure in hysteretic test.</p>
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<p>Strength degradation factor of component: (<b>a</b>) 1.0 mm steel plate and (<b>b</b>) 1.5 mm steel plate.</p>
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<p>Strength degradation factor of component: (<b>a</b>) 1.0 mm steel plate and (<b>b</b>) 1.5 mm steel plate.</p>
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<p>Component stiffness degradation curve.</p>
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13 pages, 1461 KiB  
Article
The Use of Bamboo Fiber in the Production of High-Fiber, Low-Carbohydrate, and Gluten-Free Bread: Physicochemical and Spectroscopic Properties
by Monika Wójcik, Arkadiusz Matwijczuk, Lidia Ślusarczyk and Renata Różyło
Processes 2025, 13(1), 83; https://doi.org/10.3390/pr13010083 - 2 Jan 2025
Viewed by 485
Abstract
This study aimed to investigate the effect of adding bamboo fiber on the basic physical properties of gluten-free and low-carbohydrate bread. The control bread was made from buckwheat, flax, and walnut flour. Bamboo fiber was introduced to the bread recipe in proportions ranging [...] Read more.
This study aimed to investigate the effect of adding bamboo fiber on the basic physical properties of gluten-free and low-carbohydrate bread. The control bread was made from buckwheat, flax, and walnut flour. Bamboo fiber was introduced to the bread recipe in proportions ranging from 0 to 10% (every 2%). The results showed that adding from 4 to 6% bamboo fiber to the control bread resulted in a slight rise of around 3% in volume, but a larger addition resulted in a drop in volume. The pH changes were also not significant; after more than 6% addition, the pH increased by about 2%. After adding more than 4% fiber, the color of the crumb changed noticeably (∆E >3), owing mostly to a significant increase in the lightness (L*) coefficient. The incorporation of the fiber had the greatest impact on the textural parameters when the storage time was increased to 48 h. The addition of 6% fiber resulted in unfavorable alterations in the hardness. In conclusion, our findings demonstrate that bamboo fiber can serve as a beneficial component for enriching gluten-free and low-carbohydrate bread, but its proportion should not exceed 4%. This developed bread with 4% addition of bamboo fiber can be classified as a functional bread for special diets; in addition to its very low carbohydrate content (15.3%), it was also characterized by a high fiber content (12.2%) and a low caloric value (176.7 kcal/100 g FM). Full article
(This article belongs to the Special Issue Quality of Plant Raw Materials and Their Processing)
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<p>Appearance of bread with different amounts of BF (from the left, the control bread, and then with 2, 4, 6, 8, and 10% BF addition).</p>
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<p>FTIR spectra of the gluten-free breadcrumbs with bamboo fiber (BF).</p>
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<p>Strong hydrogen bond.</p>
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19 pages, 5154 KiB  
Review
Single-Site Catalyst for the Synthesis of Disentangled Ultra-High-Molecular-Weight Polyethylene
by Jian Chen, Shuzhang Qu, Xinwei Li, Yiming Wei, Qian Li, Zhao Wen and Zifang Guo
Polymers 2025, 17(1), 95; https://doi.org/10.3390/polym17010095 - 1 Jan 2025
Viewed by 291
Abstract
Disentangled ultra-high-molecular-weight polyethylene (d-UHMWPE) solves the problem of the difficult processing of traditional UHMWPE caused by entanglements between molecular chains. In this review, we look into the innovative realm of nascent disentangled UHMWPE, concentrating on the recent advances achieved through the [...] Read more.
Disentangled ultra-high-molecular-weight polyethylene (d-UHMWPE) solves the problem of the difficult processing of traditional UHMWPE caused by entanglements between molecular chains. In this review, we look into the innovative realm of nascent disentangled UHMWPE, concentrating on the recent advances achieved through the in situ polymerization of ethylene by single-site catalysts. The effect of single-site catalysts and polymerization conditions on the molecular characteristics is discussed in detail from the perspective of mechanism and DFT calculations. The key factors to low entanglement are revealed, which have instructive implications for the development of new single-site catalytic systems that can generate d-UHMWPE more efficiently and become closer to industrial production. The progress in the preparation for nascent d-UHMWPE with homogeneous and heterogeneous single-site catalysts is systematically reviewed. Rheology and DSC can be used to characterize the degree of entanglement. High-modulus and high-strength biaxial films, tapes, and fibers are obtained by the solid-state processing of these nascent d-UHMWPE. Full article
(This article belongs to the Section Polymer Chemistry)
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<p>Statistics of the publication and citation of articles related to low-entanglement UHMWPE since 2000. Source: Web of Science (Keywords: “UHMWPE” or “Ultra-high-molecular-weight polyethylene” and “disentangled”).</p>
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<p>Other types of homogeneous catalysts.</p>
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<p>Catalyst-loading process and the diagram of heterogeneous ethylene polymerization.</p>
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<p>Structure of POSS.</p>
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<p>Compound <b>6</b>.</p>
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<p>Self-immobilized FI catalyst.</p>
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<p>Water-soluble Ni(II) complex <b>8</b> and the mechanism of aqueous-phase polymerization.</p>
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<p>Lipophilic Ni(II) complexe <b>9</b>.</p>
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<p>Interaction between ortho-fluorine and <span class="html-italic">β</span>-H.</p>
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<p>Reactions of TMA with the active site and BHT. (<b>a</b>) Interaction between the active site and TMA. (<b>b</b>) Interaction between TMA and BHT.</p>
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<p>Energy profiles for the chain growth and <span class="html-italic">β</span>-H elimination of ethylene polymerization catalyzed by <b>5</b> from the DFT simulation (ΔG, kcal mol<sup>−1</sup>).</p>
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17 pages, 317 KiB  
Review
Dietary Approach in Familial Hypercholesterolemia
by Joanna Popiolek-Kalisz, Klaudia Salamon, Michal Mazur, Klaudia Mikolajczyk and Grzegorz Kalisz
Cardiogenetics 2025, 15(1), 1; https://doi.org/10.3390/cardiogenetics15010001 - 1 Jan 2025
Viewed by 357
Abstract
Introduction: Familial hypercholesterolemia (FH) is a genetic disorder that remains underdiagnosed and undertreated. It is characterized by high levels of low-density lipoprotein cholesterol (LDL-C), which leads to an increased cardiovascular disease risk. Pharmacotherapy of FH is based on high-dose statin therapy, often combined [...] Read more.
Introduction: Familial hypercholesterolemia (FH) is a genetic disorder that remains underdiagnosed and undertreated. It is characterized by high levels of low-density lipoprotein cholesterol (LDL-C), which leads to an increased cardiovascular disease risk. Pharmacotherapy of FH is based on high-dose statin therapy, often combined with ezetimibe and proprotein convertase subtilisin/kexin 9 inhibitors. The dietary approach is an important and supportive part of FH management. Methods: This review aimed to present the available evidence on dietary strategies in FH patients. The analyzed aspects included macronutrients such as fat and carbohydrate intake, as well as the role of dietary fiber, nutraceuticals (omega-3, beta-glucan, phytosterols, and red yeast fermented rice extract), and overall dietary models. Results and Conclusions: Based on the available data, the Mediterranean diet is a dietary model advised in cardiovascular prevention, including patients with FH. Regarding detailed recommendations, the current state of knowledge indicates dietary fat and saturated fatty acids intake limitation as an advised strategy. Supplementation of phytosterols and fiber can be also helpful in FH. Full article
(This article belongs to the Section Rare Disease-Genetic Syndromes)
21 pages, 6246 KiB  
Article
Cleavable Bio-Based Epoxy Matrix for More Eco-Sustainable Thermoset Composite Components
by Ilaria Rossitti, Arianna Bolis, Matteo Sambucci, Fabrizio Sarasini, Jacopo Tirillò and Marco Valente
Polymers 2025, 17(1), 88; https://doi.org/10.3390/polym17010088 - 31 Dec 2024
Viewed by 333
Abstract
Cleavable bio-based epoxy resin systems are emerging, eco-friendly, and promising alternatives to the common thermoset ones, providing quite comparable thermo-mechanical properties while enabling a circular and green end-of-life scenario of the composite materials. In addition to being designed to incorporate a bio-based resin [...] Read more.
Cleavable bio-based epoxy resin systems are emerging, eco-friendly, and promising alternatives to the common thermoset ones, providing quite comparable thermo-mechanical properties while enabling a circular and green end-of-life scenario of the composite materials. In addition to being designed to incorporate a bio-based resin greener than the conventional fully fossil-based epoxies, these formulations involve cleaving hardeners that enable, under mild thermo-chemical conditions, the total recycling of the composite material through the recovery of the fiber and matrix as a thermoplastic. This research addressed the characterization, processability, and recyclability of a new commercial cleavable bio-resin formulation (designed by the R-Concept company) that can be used in the fabrication of fully recyclable polymer composites. The resin was first studied to investigate the influence of the different post-curing regimes (room temperature, 100 °C, and 140 °C) on its thermal stability and glass transition temperature. According to the results obtained, the non-post-cured resin displayed the highest Tg (i.e., 76.6 °C). The same post-curing treatments were also probed on the composite laminates (glass and carbon) produced via a lab-scale vacuum-assisted resin transfer molding system, evaluating flexural behavior, microstructure, and dynamic-mechanical characteristics. The post-curing at 100 °C would enhance the crosslinking of polymer chains, improving the mechanical strength of composites. With respect to the non-post-cured laminates, the flexural strength improved by 3% and 12% in carbon and glass-based composites, respectively. The post-curing at 140 °C was instead detrimental to the mechanical performance. Finally, on the laminates produced, a chemical recycling procedure was implemented, demonstrating the feasibility of recovering both thermoplastic-based resin and fibers. Full article
(This article belongs to the Section Biobased and Biodegradable Polymers)
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<p>Schematic of the cleavage mechanism induced by Recyclamine<sup>®</sup> hardener and conversion to the thermoplastic system (authors’ own figure).</p>
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<p>Chemical structure of (<b>a</b>) Recyclamine<sup>TM</sup> R*101 [<a href="#B17-polymers-17-00088" class="html-bibr">17</a>] and (<b>b</b>) Polar Bear (part A) [<a href="#B4-polymers-17-00088" class="html-bibr">4</a>].</p>
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<p>Vacuum-assisted resin transfer molding system designed for the laminates fabrication: (<b>a</b>) schematic of the system and (<b>b</b>) experimental set-up.</p>
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<p>Schematization of the chemical recycling process.</p>
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<p>TGA curves of bio-epoxy resins post-cured at different conditions: RT, PC100, PC140.</p>
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<p>First (<b>a</b>) and second (<b>b</b>) heating scan DSC curves of bio-epoxy resins post-cured at different conditions: RT, PC100, PC140.</p>
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<p>Flexural test results on composite laminates at different post-curing regimes: (<b>a</b>) flexural strength, (<b>b</b>) elastic modulus, (<b>c</b>) flexural stress-strain curve for glass-reinforced laminates, and (<b>d</b>) flexural stress-strain curve for carbon-reinforced laminates.</p>
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<p>Shore D hardness test results on composite laminates at different post-curing regimes.</p>
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<p>SEM analysis on the composite over PC100 condition: (<b>a</b>) glass laminate (polished surface), (<b>b</b>) carbon laminate (polished surface), (<b>c</b>) detail on the glass-resin interface (polished surface), and (<b>d</b>) fracture surface of carbon-based laminate.</p>
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<p>SEM analysis on the carbon-based composite laminate over PC140 condition: detail on fiber-pull-out.</p>
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<p>DMA test results: tan δ vs. temperature for plain resin, glass, and carbon laminates post-cured under the PC100 regime.</p>
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<p>TGA on recovered polymer from chemical recycling.</p>
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<p>Thermoplastic deriving from the chemical recycling process of the epoxy resin matrix (Polar Bear and Recyclamine<sup>TM</sup> R*101) [<a href="#B4-polymers-17-00088" class="html-bibr">4</a>,<a href="#B17-polymers-17-00088" class="html-bibr">17</a>].</p>
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<p>DSC on recovered polymer from chemical recycling.</p>
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<p>SEM analysis on recycled fibers: (<b>a</b>) glass and (<b>b</b>) carbon fibers.</p>
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