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34 pages, 7433 KiB  
Review
Research Progress on the Surface Modification of Basalt Fibers and Composites: A Review
by Miaomiao Zhu, Mingming Zhu, Ruoxin Zhai, Wuwei Zhu and Jiabei He
Materials 2025, 18(5), 1164; https://doi.org/10.3390/ma18051164 - 5 Mar 2025
Abstract
Fiber-reinforced resin composites (FRRCs) are widely used in several fields such as construction, automotive, aerospace, and power. Basalt fiber (BF) has been increasingly used to replace artificial fibers such as glass fiber and carbon fiber in the production of BF-reinforced resin matrix composites [...] Read more.
Fiber-reinforced resin composites (FRRCs) are widely used in several fields such as construction, automotive, aerospace, and power. Basalt fiber (BF) has been increasingly used to replace artificial fibers such as glass fiber and carbon fiber in the production of BF-reinforced resin matrix composites (BFRRCs). This preference stems from its superior properties, including high temperature resistance, chemical stability, ease of manufacturing, cost-effectiveness, non-toxicity, and its natural, environmentally friendly characteristics. However, the chemical inertness of BF endows it with poor compatibility, adhesion, and dispersion in a resin matrix, leading to poor adhesion and a weak BF–resin interface. The interfacial bonding strength between BF and resin is an important parameter that determines the service performance of BFRRC. Therefore, the interfacial bonding strength between them can be improved through fiber modification, resin–matrix modification, mixed enhancers, etc., which consequently upgrade the mechanical properties, thermodynamic properties, and durability of BFRRC. In this review, first, the production process and properties of BFs are presented. Second, the mechanical properties, thermodynamic properties, and durability of BFRRC are introduced. Third, the modification effect of the non-destructive surface-modification technology of BF on BFRRC is presented herein. Finally, based on the current research status, the future research direction of BFRRC is proposed, including the development of high-performance composite materials, green manufacturing processes, and intelligent applications. Full article
(This article belongs to the Special Issue Synthesis, Sintering, and Characterization of Composites)
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<p>Applications of BF in various sectors [<a href="#B9-materials-18-01164" class="html-bibr">9</a>].</p>
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<p>BF production process flow: 1—silo; 2—feeder; 3—lift conveyor; 4—quantitative feeder; 5—primary melting zone of raw materials; 6—gas nozzle; 7—secondary melting belt (front furnace); 8—platinum–rhodium alloy leakage plate; 9—application of infiltrating agent; 10—buncher; 11—fiber tensioner; 12—automatic winding machine.</p>
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<p>Platinum–rhodium alloy bushing plate.</p>
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<p>Photographs of BFs ((<b>left</b>): filament fiber, (<b>right</b>): chopped fiber).</p>
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<p>Three distinct stiffness reduction zones in the history of fatigue sample [<a href="#B50-materials-18-01164" class="html-bibr">50</a>].</p>
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<p>Tensile strength of basalt/glass hybrid composites [<a href="#B43-materials-18-01164" class="html-bibr">43</a>].</p>
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<p>SEM micrographs detailing the fracture morphology of BF/polyester composite beams for unsized basalt fibers and basalt fibers after polymerization processes. “B” stands for basalt fiber, while the percentage refers to the oxygen fraction in tetravinylsilane mixture [<a href="#B63-materials-18-01164" class="html-bibr">63</a>].</p>
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<p>SEM binary processing images of (<b>a</b>) BF and (<b>b</b>) MBF in cement [<a href="#B73-materials-18-01164" class="html-bibr">73</a>].</p>
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<p>Schematic illustration of the twin screw extrusion process for manufacturing composite [<a href="#B45-materials-18-01164" class="html-bibr">45</a>].</p>
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<p>Green HDPE composites reinforced with BFs and agricultural fillers [<a href="#B86-materials-18-01164" class="html-bibr">86</a>].</p>
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<p>Partial photographs of samples after burning: (<b>a</b>) PP and (<b>b</b>) BFRPPC [<a href="#B98-materials-18-01164" class="html-bibr">98</a>].</p>
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<p>(<b>a</b>) Tensile strength; (<b>b</b>) notched impact strength of pure PA 6, PA6/SEBS blend, and PA 6/SEBS/BF composites [<a href="#B103-materials-18-01164" class="html-bibr">103</a>].</p>
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<p>Tensile strength and modulus of BF/PBS composites with various BF loadings [<a href="#B114-materials-18-01164" class="html-bibr">114</a>].</p>
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<p>Flexural strength and modulus of BF/PBS composites with various BF loadings [<a href="#B114-materials-18-01164" class="html-bibr">114</a>].</p>
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<p>Molecular structure of CE resin monomer.</p>
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<p>Scheme of the treatment process in H<sub>2</sub>SO<sub>4</sub> and KOH solution [<a href="#B121-materials-18-01164" class="html-bibr">121</a>].</p>
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<p>Schematic diagram of La<sup>3+</sup> attached to the BF surface [<a href="#B137-materials-18-01164" class="html-bibr">137</a>].</p>
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<p>Retention rate of mechanical properties of BF/ERCs after hygrothermal aging: (<b>a</b>) retention rate of tensile strength; (<b>b</b>) retention rate of bending strength; and (<b>c</b>) retention rate of ILSS [<a href="#B141-materials-18-01164" class="html-bibr">141</a>].</p>
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29 pages, 9288 KiB  
Article
Machine Learning-Driven Prediction of Composite Materials Properties Based on Experimental Testing Data
by Khrystyna Berladir, Katarzyna Antosz, Vitalii Ivanov and Zuzana Mitaľová
Polymers 2025, 17(5), 694; https://doi.org/10.3390/polym17050694 - 5 Mar 2025
Abstract
The growing demand for high-performance and cost-effective composite materials necessitates advanced computational approaches for optimizing their composition and properties. This study aimed at the application of machine learning for the prediction and optimization of the functional properties of composites based on a thermoplastic [...] Read more.
The growing demand for high-performance and cost-effective composite materials necessitates advanced computational approaches for optimizing their composition and properties. This study aimed at the application of machine learning for the prediction and optimization of the functional properties of composites based on a thermoplastic matrix with various fillers (two types of fibrous, four types of dispersed, and two types of nano-dispersed fillers). The experimental methods involved material production through powder metallurgy, further microstructural analysis, and mechanical and tribological testing. The microstructural analysis revealed distinct structural modifications and interfacial interactions influencing their functional properties. The key findings indicate that optimal filler selection can significantly enhance wear resistance while maintaining adequate mechanical strength. Carbon fibers at 20 wt. % significantly improved wear resistance (by 17–25 times) while reducing tensile strength and elongation. Basalt fibers at 10 wt. % provided an effective balance between reinforcement and wear resistance (by 11–16 times). Kaolin at 2 wt. % greatly enhanced wear resistance (by 45–57 times) with moderate strength reduction. Coke at 20 wt. % maximized wear resistance (by 9−15 times) while maintaining acceptable mechanical properties. Graphite at 10 wt. % ensured a balance between strength and wear, as higher concentrations drastically decreased mechanical properties. Sodium chloride at 5 wt. % offered moderate wear resistance improvement (by 3–4 times) with minimal impact on strength. Titanium dioxide at 3 wt. % enhanced wear resistance (by 11–12.5 times) while slightly reducing tensile strength. Ultra-dispersed PTFE at 1 wt. % optimized both strength and wear properties. The work analyzed in detail the effect of PTFE content and filler content on composite properties based on machine learning-driven prediction. Regression models demonstrated high R-squared values (0.74 for density, 0.67 for tensile strength, 0.80 for relative elongation, and 0.79 for wear intensity), explaining up to 80% of the variability in composite properties. Despite its efficiency, the limitations include potential multicollinearity, a lack of consideration of external factors, and the need for further validation under real-world conditions. Thus, the machine learning approach reduces the need for extensive experimental testing, minimizing material waste and production costs, contributing to SDG 9. This study highlights the potential use of machine learning in polymer composite design, offering a data-driven framework for the rational choice of fillers, thereby contributing to sustainable industrial practices. Full article
(This article belongs to the Section Polymer Physics and Theory)
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<p>Commonly used types of computational methods for solving materials science tasks.</p>
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<p>The microstructures of components used for designing PCMs: (<b>a</b>) sodium chloride; (<b>b</b>) ultra-PTFE; (<b>c</b>) graphite; (<b>d</b>) kaolin; (<b>e</b>) basalt fiber; (<b>f</b>) PTFE (matrix).</p>
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<p>The microstructures of components used for designing PCMs: (<b>a</b>) sodium chloride; (<b>b</b>) ultra-PTFE; (<b>c</b>) graphite; (<b>d</b>) kaolin; (<b>e</b>) basalt fiber; (<b>f</b>) PTFE (matrix).</p>
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<p>Flowchart of the production process for obtaining test samples.</p>
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<p>The microstructure of the composite with 20% carbon fibers.</p>
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<p>The microstructure of composite with 10% basalt fibers.</p>
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<p>The microstructure of the composite with 2% kaolin.</p>
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<p>The microstructure of the composite with 20% coke.</p>
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<p>The microstructure of composite with 10% coke.</p>
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<p>The microstructure of the composite with 2% sodium chloride.</p>
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<p>The microstructure of composite with 5% titanium dioxide.</p>
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<p>The microstructure of composite with 1% ultra-PTFE.</p>
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<p>The functional properties of the designed two-component PCMs based on the filler concentrations: (<b>a</b>) density, (<b>b</b>) tensile strength, (<b>c</b>) relative elongation, (<b>d</b>) wear intensity (for 100% PTFE, the wear intensity is 610 × 10<sup>−6</sup> mm<sup>3</sup>/N·m).</p>
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<p>The functional properties of the designed three-component PCMs based on the filler concentrations: (<b>a</b>) density, (<b>b</b>) tensile strength, (<b>c</b>) relative elongation, (<b>d</b>) wear intensity (for 100% PTFE, the wear intensity is 610 × 10<sup>−6</sup> mm<sup>3</sup>/N·m).</p>
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<p>Boxplot density versus PTFE.</p>
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<p>Box plot tensile strength versus PTFE.</p>
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<p>Box plot of relative elongation versus PTFE.</p>
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<p>Box plot wear intensity versus PTFE.</p>
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31 pages, 19288 KiB  
Article
Mechanical and Microstructural Performance of UHPC with Recycled Aggregates Modified by Basalt Fiber and Nanoalumina at High Temperatures
by Hong Jiang, Liang Luo, Yuan Hou and Yifei Yang
Materials 2025, 18(5), 1072; https://doi.org/10.3390/ma18051072 - 27 Feb 2025
Viewed by 189
Abstract
This study investigates the mechanical properties and microstructure of basalt fiber (BF) and nanoalumina (NA)-modified ultra-high-performance concrete with recycled aggregates (UHPC-RA) under high-temperature conditions. The effects of different replacement rates of recycled aggregates (RAs), BF content, and NA content on the compressive strength, [...] Read more.
This study investigates the mechanical properties and microstructure of basalt fiber (BF) and nanoalumina (NA)-modified ultra-high-performance concrete with recycled aggregates (UHPC-RA) under high-temperature conditions. The effects of different replacement rates of recycled aggregates (RAs), BF content, and NA content on the compressive strength, splitting tensile strength, and elastic modulus were evaluated at ambient temperatures and after exposure to 200 °C, 400 °C, 600 °C, and 800 °C. The results show that mechanical properties decrease with temperature rise, but specimens containing BF exhibited improved crack resistance and better high-temperature integrity. The incorporation of NA enhanced the thermal stability and heat resistance of the concrete. Digital image correlation (DIC) was used to monitor real-time surface deformation, and scanning electron microscopy (SEM) analysis revealed improved microstructure with reduced porosity and cracks. This study demonstrates that the combination of BF and NA significantly enhances the high-temperature performance of UHPC-RA, which holds promising potential for applications in environments subjected to elevated temperatures. Full article
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<p>Chemical composition of cementitious materials: (<b>a</b>) silica fume; (<b>b</b>) slag powder; (<b>c</b>) cement.</p>
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<p>Grading curves: (<b>a</b>) powder material grading; (<b>b</b>) aggregate grading.</p>
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<p>XRD pattern of nanoalumina.</p>
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<p>Mixing procedure and mixer operation parameter.</p>
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<p>Temperature history of the heated sample: (<b>a</b>) residual state heating loading scheme; (<b>b</b>) temperature evolution in the furnace and in the different parts (core/surface) of the sample.</p>
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<p>Schematic diagram of DIC monitoring system.</p>
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<p>The appearance and color changes of BF-reinforced UHPC-RA at the following temperatures: (<b>a</b>) 25 °C; (<b>b</b>) 200 °C; (<b>c</b>) 400 °C; (<b>d</b>) 600 °C; (<b>e</b>) 800 °C.</p>
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<p>Mass loss rate of specimens after high temperature: (<b>a</b>) RA group (r<sub>RA</sub> = 0/50/100%); (<b>b</b>) BF group (r<sub>BF</sub> = 0/1/2%); (<b>c</b>) r<sub>NA</sub> group (rNA = 0/3/5%).</p>
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<p>Experimental results on compressive strength with different temperatures: (<b>a</b>) effect of the r<sub>RA</sub>; (<b>b</b>) effect of the r<sub>BF</sub>; (<b>c</b>) effect of the r<sub>NA</sub>; (<b>d</b>) overall variation trend of compressive strength.</p>
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<p>Experimental results on compressive strength with different temperatures: (<b>a</b>) effect of the r<sub>RA</sub>; (<b>b</b>) effect of the r<sub>BF</sub>; (<b>c</b>) effect of the r<sub>NA</sub>; (<b>d</b>) overall variation trend of compressive strength.</p>
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<p>Experimental results on splitting tensile strength with different temperatures: (<b>a</b>) effect of the r<sub>RA</sub>; (<b>b</b>) effect of the r<sub>BF</sub>; (<b>c</b>) effect of the r<sub>NA</sub>; (<b>d</b>) overall variation trend of splitting tensile strength.</p>
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<p>The relationship between compressive and splitting tensile strength of concrete at different temperatures.</p>
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<p>Comparison of elastic modulus of specimens with temperature: (<b>a</b>) effect of the r<sub>RA</sub>; (<b>b</b>) effect of the r<sub>BF</sub>; (<b>c</b>) effect of the r<sub>NA</sub>; (<b>d</b>) relative modulus.</p>
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<p>Comparison of elastic modulus of specimens with temperature: (<b>a</b>) effect of the r<sub>RA</sub>; (<b>b</b>) effect of the r<sub>BF</sub>; (<b>c</b>) effect of the r<sub>NA</sub>; (<b>d</b>) relative modulus.</p>
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<p>Comparison of relative comprehensive performance (<span class="html-italic">RCP</span>) of different specimens at different temperatures.</p>
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<p>DIC measurement of crack evolution in compression test (R100B2A5 specimen) at room temperature: (<b>a</b>) load–displacement curve; (<b>b</b>) 0.013 mm; (<b>c</b>) 0.066 mm; (<b>d</b>) 0.168 mm; (<b>e</b>) 0.204 mm; (<b>f</b>) 0.244 mm; (<b>g</b>) 0.283 mm; (<b>h</b>) 0.341 mm; (<b>i</b>) 0.447 mm.</p>
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<p>DIC measurement results of R100B2A5 specimen failure at different temperatures: (<b>a</b>) 200 °C; (<b>b</b>) 400 °C; (<b>c</b>) 600 °C; (<b>d</b>) 800 °C.</p>
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<p>SEM images of the sample mortar matrix with different temperatures: (<b>a</b>) 25 °C; (<b>b</b>) 200 °C; (<b>c</b>) 400 °C; (<b>d</b>) 600 °C; (<b>e</b>) 800 °C.</p>
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<p>SEM images of the sample mortar matrix with different temperatures: (<b>a</b>) 25 °C; (<b>b</b>) 200 °C; (<b>c</b>) 400 °C; (<b>d</b>) 600 °C; (<b>e</b>) 800 °C.</p>
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<p>SEM images of the interfacial transition zone for R50B2A0 specimen with different temperatures: (<b>a</b>) 25 °C; (<b>b</b>) 400 °C; (<b>c</b>) 800 °C.</p>
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<p>SEM images of basalt fibers with different BF contents: (<b>a</b>) 1 kg/m<sup>3</sup>; (<b>b</b>) 2 kg/m<sup>3</sup>; (<b>c</b>) fracture surface of pulled BFs.</p>
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<p>Schematic diagram of the cementitious system with different fiber ratios and NA contents: (<b>a</b>) R100B2A0 (0% NA); (<b>b</b>) R100B2A3 (3% NA); (<b>c</b>) R100B2A5 (5% NA).</p>
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21 pages, 3022 KiB  
Article
Carbonated Aggregates and Basalt Fiber-Reinforced Polymers: Advancing Sustainable Concrete for Structural Use
by Rabee Shamass, Vireen Limbachiya, Oluwatoyin Ajibade, Musab Rabi, Hector Ulises Levatti Lopez and Xiangming Zhou
Buildings 2025, 15(5), 775; https://doi.org/10.3390/buildings15050775 - 26 Feb 2025
Viewed by 204
Abstract
In the transition towards a circular economy, redesigning construction materials for enhanced sustainability becomes crucial. To contribute to this goal, this paper investigates the integration of carbonated aggregates (CAs) and basalt fibre-reinforced polymers (BFRPs) in concrete infrastructures as an alternative to natural sand [...] Read more.
In the transition towards a circular economy, redesigning construction materials for enhanced sustainability becomes crucial. To contribute to this goal, this paper investigates the integration of carbonated aggregates (CAs) and basalt fibre-reinforced polymers (BFRPs) in concrete infrastructures as an alternative to natural sand (NS) and steel reinforcement. CA is manufactured using accelerated carbonation that utilizes CO2 to turn industrial byproducts into mineralised products. The structural performance of CA and BFRP-reinforced concrete simply supported slab was investigated through conducting a series of experimental tests to assess the key structural parameters, including bond strength, bearing capacity, failure behavior, and cracking bbehaviour. Carbon footprint analysis (CFA) was conducted to understand the environmental impact of incorporating BFRP and CA. The results indicate that CA exhibits a higher water absorption rate compared to NS. As the CA ratio increased, the ultrasonic pulse velocity (UPV), compressive, tensile, and flexural strength decreased, and the absorption capacity of concrete increased. Furthermore, incorporating 25% CA in concrete has no significant effect on the bond strength of BFRP. However, the load capacity decreased with an increasing CA replacement ratio. Finally, integrating BFRP and 50% of CA into concrete slabs reduced the slab’s CFA by 9.7% when compared with steel-reinforced concrete (RC) slabs. Full article
(This article belongs to the Topic Green Construction Materials and Construction Innovation)
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<p>Particle size distribution.</p>
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<p>(<b>a</b>) The CA used in this study; (<b>b</b>) the BFRP and steel bars.</p>
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<p>Pull-out test. (<b>a</b>) The sample preparation; (<b>b</b>) a schematic of the pull-out specimen.</p>
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<p>(<b>a</b>) The slab mould showing the reinforcement arrangements; (<b>b</b>) a diagram illustrating the elevation and end-view of the slab specimens.</p>
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<p>(<b>a</b>) Ultrasonic pulse velocity testing; (<b>b</b>) the testing arrangement for the pull-out; (<b>c</b>) the testing arrangement of the slabs.</p>
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<p>UPV and absorption capacity for different mixes.</p>
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<p>Mechanical properties of concrete mixes at twenty-eight days.</p>
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<p>Bond–slip curves for steel and BFRP samples with different carbonated aggregate content.</p>
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<p>The load–deflection relationship of the slabs.</p>
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<p>Failure modes of the tested slabs.</p>
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31 pages, 27163 KiB  
Article
Synergistic Use of Nanosilica and Basalt Fibers on Mechanical Properties of Internally Cured Concrete with SAP: An Experimental Analysis and Optimization via Response Surface Methodology
by Said Mirgan Borito, Han Zhu, Yasser E. Ibrahim, Sadi Ibrahim Haruna and Zhao Bo
Fibers 2025, 13(3), 25; https://doi.org/10.3390/fib13030025 - 26 Feb 2025
Viewed by 433
Abstract
This study explores the combined effects of nanosilica (NS) and basalt fibers (BF) on the mechanical and microstructural properties of superabsorbent polymer (SAP)-modified concrete. NS (0–1.5% replaced by cement weight) and BF (0–1.2% by volume fraction) were incorporated to optimize compressive, flexural, and [...] Read more.
This study explores the combined effects of nanosilica (NS) and basalt fibers (BF) on the mechanical and microstructural properties of superabsorbent polymer (SAP)-modified concrete. NS (0–1.5% replaced by cement weight) and BF (0–1.2% by volume fraction) were incorporated to optimize compressive, flexural, and split-tensile strengths using response surface methodology. Digital Image Correlation (DIC) was employed to analyze failure mechanisms. Results show that while SAP alone reduced strength, the addition of NS and BF mitigated this loss through synergistic microstructure enhancement and crack-bridging reinforcement. The optimal mix (0.9% NS and 1.2% BF) increased compressive, flexural, and split-tensile strengths by 15.3%, 10.0%, and 14.0%, respectively. SEM analysis revealed that NS filled SAP-induced pores, while BF limited crack propagation, contributing to improved mechanical strength of SAP-modified concrete. This hybrid approach offers a promising solution for durable and sustainable concrete pavements. Full article
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<p>Particle size distribution of fine and coarse aggregates.</p>
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<p>BFs used (SAP-a) in (<b>a</b>) dry and (<b>b</b>) swollen state.</p>
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<p>NS powder and short chopped BF used in this study: (<b>a</b>) BF and (<b>b</b>) NS.</p>
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<p>Schematic illustration of the mixing process of NSBF-ICC.</p>
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<p>Splitting tensile test equipment illustration.</p>
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<p>Experimental setup of flexural strength test with DIC equipment of concrete specimens under (<b>a</b>) compression and (<b>b</b>) 3-point bending test.</p>
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<p>Central Composite Design structure.</p>
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<p>Compressive strength variation of NSBF-ICC at 7 and 28 days. The dotted lines represent the maximum compressive strength values at 7 and 28 days for S0-A0.0 (blue) and S0-A0.3 (red).</p>
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<p>Failure behavior of NSBF-ICC specimens under compression loading at 28 days.</p>
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<p>Split-tensile strength graph of NSBF-ICC specimens after 7 and 28 days. The dotted lines represent the maximum compressive strength values at 7 and 28 days for S0-A0.0 (blue) and S0-A0.3 (red).</p>
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<p>Fractural behavior of (<b>a</b>) ordinary concrete specimen (S0-A0.0) and (<b>b</b>) NSBF-ICC (NS1.5B1.2) specimen under splitting-tensile test.</p>
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<p>Synergetic influence of NS and BF on the flexural strength properties of internal curing concrete after 7 and 28 days. The dotted lines represent the maximum compressive strength values at 7 and 28 days for S0-A0.0 (blue) and S0-A0.3 (red).</p>
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<p>Failure behavior of NSBF-ICC under flexure loading at 28 days.</p>
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<p>Compressive failure mode of the reference concrete (S0-A0.0) specimen with no additives.</p>
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<p>Compressive failure mode of the NS- and BF-modified internal curing concrete (NS1.5B1.2) specimen.</p>
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<p>Typical failure mode of the reference concrete beam (S0-A0.0) under three-point bending test.</p>
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<p>Failure mode of NSBF-ICC beam (NS1.5B1.2) under three-point bending test.</p>
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<p>SEM observation of NSBF-ICC mixture at 28 days (NS1.5B1.2 mix). (<b>a</b>) SAP pore formation after water release; (<b>b</b>) hydrates inside SAP pore; (<b>c</b>–<b>f</b>) additional C–S–H formation and ettringite due to NS addition; (<b>g</b>) fiber interface with hydrates; (<b>h</b>) crack propagation and BF bridging effect.</p>
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<p>Three-dimensional surface plots of the combined effect of NS and BF on the compressive strength of ICC at (<b>a</b>) 7 days, and (<b>b</b>) 28 days. The color scale represents the variation in compressive strength, with red indicating higher strength values and blue indicating lower strength values.</p>
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<p>Two-dimensional contour plots of synergetic influence of NS and BF on compressive strength of ICC: (<b>a</b>) 7 days, and (<b>b</b>) 28 days. The color scale represents the variation in compressive strength, with red indicating higher strength values and blue indicating lower strength values.</p>
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<p>Three-dimensional surface plots of the combined effect of NS and BF on the flexural strength of NSBF-ICC with NS at (<b>a</b>) 7 days, and (<b>b</b>) 28 days. The color scale represents the variation in flexural strength, with red indicating higher strength values and blue indicating lower strength values.</p>
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<p>Two-dimensional contour plots of synergetic influence of NS AND BF on flexural strength of NSBF-ICC: (<b>a</b>) 7 days, and (<b>b</b>) 28 days. The color scale represents the variation in flexural strength, with red indicating higher strength values and blue indicating lower strength values.</p>
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<p>Three-dimensional surface plots of the combined effect of NS and BF on the split-tensile strength of NSBF-ICC with NS at (<b>a</b>) 7 days, and (<b>b</b>) 28 days. The color scale represents the variation in split-tensile strength, with red indicating higher strength values and blue indicating lower strength values.</p>
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<p>Two-dimensional contour plots of synergetic influence of NS and BF on split-tensile strength of NSBF-ICC: (<b>a</b>) 7 days, and (<b>b</b>) 28 days. The color scale represents the variation in split-tensile strength, with red indicating higher strength values and blue indicating lower strength values.</p>
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<p>Interaction plots of NSBF-ICC mixture from RSM analysis. The red and black curves represent the interaction effects between NS and BF dosages on the mechanical strength, with dashed lines indicating confidence intervals. The color-coded items (red, green, black) correspond to different levels or conditions of the variables analyzed.</p>
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24 pages, 30156 KiB  
Article
Chopped Basalt Fibers Reinforced Mortar for Strengthening the Architectural Heritage
by Micaela Mercuri, Marco Vailati and Amedeo Gregori
Fibers 2025, 13(2), 20; https://doi.org/10.3390/fib13020020 - 11 Feb 2025
Viewed by 401
Abstract
The high seismic vulnerability of unreinforced masonry buildings urgently calls for researchers to develop sustainable reinforcing methods and materials. This paper presents an innovative lime-based mortar reinforced with randomly oriented basalt fibers for the reinforcement of masonry heritage. The main aim of this [...] Read more.
The high seismic vulnerability of unreinforced masonry buildings urgently calls for researchers to develop sustainable reinforcing methods and materials. This paper presents an innovative lime-based mortar reinforced with randomly oriented basalt fibers for the reinforcement of masonry heritage. The main aim of this study is to understand the effect of the content and the length of basalt fibers on the mortar’s mechanical behavior. As a cementitious material made mostly out of lime, the mortar is chemically compatible with the historical substrate and therefore suitable in cases of restoration works on architectural heritage. Moreover, the chopped basalt fibers are randomly oriented, and this characteristic makes the overall layer effective in all directions, as the state of stress induced by seismic action is directionally undetermined. The newly proposed reinforcement system is characterized by a twofold aspect related to sustainability: 30% of the aggregates composing the mortar mix design is a recycled result of the ruins of the 2009 L’Aquila earthquake, and the chopped fibers are made out of basalt, widely known for its environmentally supportable peculiarity. The study consists of testing samples characterized by two fiber lengths and six fiber contents, along with one set of plain mortar samples. Specimens measuring 160 mm × 40 mm × 40 mm are first tested in a three-point bending (TPB) configuration, aiming to determine the flexural strength and the post-peak capacity through the calculation of the fracture energy. Then, the two broken pieces resulting from the TPB tests, each measuring 80 mm × 40 mm × 40 mm, are tested in splitting and compression, respectively, aiming to compute the tensile and compressive strengths. Finally, to provide a trend for the mortar’s mechanical properties, a regression analysis is performed by fitting the experimental data with simple linear, polynomial, and exponential regression models. Results show that: (i) both fiber content and fiber length are responsible for a linear increase of the flexural strength and the fracture energy; (ii) for both short- and long-fiber mortar samples, the tensile strength and the compressive strength parabolically increase with the fiber content; (iii) the increase in fiber content and fiber length always generates a reduction in the conglomerate workability. The fiber content (FC) optimization with respect to the mechanical properties leads to a basalt FC equal to 1.2% for long-fiber samples and an FC equal to 1.9% for short-fiber ones. Full article
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<p>(<b>a</b>) Traditional unreinforced masonry panel. Ordinary FRCM strengthening system on masonry surface: (<b>b</b>) the first layer provides to apply a thin layer of plastering; (<b>c</b>) the second layer consists in applying the textile grid; (<b>d</b>) the third layer provides to apply a second and more massive layer of plastering. (<b>e</b>) Newly proposed FRCM retrofitting system on masonry wall: chopped basalt fibers are randomly placed within the mortar matrix: just one layer of mortar can be applied with a unique phase.</p>
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<p>Chopped basalt plain fibers: (<b>a</b>) with short length equal to 12 mm and denoted by F12; (<b>b</b>) with long length equal to 24 mm and denoted by F24.</p>
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<p>Four phases of the slump test: (<b>a</b>) casting the mortar in molds, (<b>b</b>) removing the cone along vertical direction, avoiding rotational movement, straight up to clear the sample, (<b>c</b>) tamping the mortar with 20 strokes using Hagermann’s table, (<b>d</b>) using a ruler, measuring the diameter of fresh mortar as average of two orthogonal measurements.</p>
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<p>Testing equipment and structural configurations for: three-point bending test in (<b>a</b>,<b>b</b>), splitting (or Brazilian) test in (<b>c</b>,<b>d</b>), compressive test in (<b>e</b>,<b>f</b>).</p>
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<p>Flexural behavior for short fibers in red and long fibers in orange and for the following fiber contents: (<b>a</b>) FC = 0.50%, (<b>b</b>) FC = 0.75%, (<b>c</b>) FC = 1.00%, (<b>d</b>) FC = 1.50%, (<b>e</b>) FC = 2.00%, and (<b>f</b>) FC = 2.50%. The flexural capacity increases with fiber content FC and fiber length FL.</p>
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<p>Tensile behavior for short fibers in red and long fibers in orange and for the following fiber contents: (<b>a</b>) FC = 0.50%, (<b>b</b>) FC = 0.75%, (<b>c</b>) FC = 1.00%, (<b>d</b>) FC = 1.50%, (<b>e</b>) FC = 2.00%, and (<b>f</b>) FC = 2.50%. The tensile capacity increases with FC and FL.</p>
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<p>Compressive behavior for short fibers in red and long fibers in orange and for the following fiber contents: (<b>a</b>) FC = 0.50%, (<b>b</b>) FC = 0.75%, (<b>c</b>) FC = 1.00%, (<b>d</b>) FC = 1.50%, (<b>e</b>) FC = 2.00%, and (<b>f</b>) FC = 2.50%. The compressive capacity increases with FC, but it does not change appreciably with the fiber length.</p>
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<p>Synthetic figure showing the trend of all the analyzed mechanical properties versus the content of basalt fibers for the three different situations of no fibers, low length fibers, and high length fibers: (<b>a</b>) flexural strength versus content of basalt fibers, (<b>b</b>) fracture energy versus content of basalt fibers, (<b>c</b>) tensile strength versus content of basalt fibers, and (<b>d</b>) compressive strength versus content of basalt fibers. Basalt fibers increase all the mortar mechanical properties, above all the fracture energy.</p>
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<p>Synthetic figure showing the trend of the scattering related to all the analyzed mechanical properties with the fiber content and the fiber length: (<b>a</b>) scatter of flexural strength, (<b>b</b>) scatter of the fracture energy, (<b>c</b>) scatter of the tensile strength, and (<b>d</b>) scatter of compressive strength.</p>
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<p>(<b>a</b>) Values related to the slump test for no fiber batches, short basalt fiber batches in red, and long basalt fiber batches in orange. (<b>b</b>) slump value as a function of the fiber content for both short and long fiber mortars: slump decreases almost linearly with the fiber content for both the fiber lengths. The red dashed line individuates the minimum slump value of 15.5 mm for practical purposes.</p>
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<p>(<b>a</b>) coefficients of determination <math display="inline"><semantics> <msup> <mi>r</mi> <mn>2</mn> </msup> </semantics></math> for the flexural strength calculated for the LRL, ERL, and PRL, for both short and long basalt fibers; (<b>b</b>) flexural behavior regression lines as a function of the fiber content; (<b>c</b>) coefficients of determination <math display="inline"><semantics> <msup> <mi>r</mi> <mn>2</mn> </msup> </semantics></math> for the fracture energy calculated with the three mentioned regression models, i.e., with LRL, ERL, and PRL; (<b>d</b>) fracture energy regression lines as a function of the fiber content.</p>
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<p>(<b>a</b>) Coefficients of determination <math display="inline"><semantics> <msup> <mi>r</mi> <mn>2</mn> </msup> </semantics></math> for the tensile strength calculated for the linear (LRL), exponential (ERL), and parabolic (PRL) regression models, for both short and long basalt fibers; (<b>b</b>) tensile behavior regression lines as a function of the fiber content; (<b>c</b>) coefficients of determination <math display="inline"><semantics> <msup> <mi>r</mi> <mn>2</mn> </msup> </semantics></math> for the compressive strength calculated with the three mentioned regression models, i.e., with LRL, ERL, and PRL; (<b>d</b>) compressive strength regression lines as a function of the fiber content.</p>
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13 pages, 3795 KiB  
Article
The Effect of Biocontamination on Mechanical Strength and Moisture Transfer Performance of Epoxy Basalt Fiber Reinforcement Bar Exposed to Arctic Conditions
by Anatoly K. Kychkin, Oleg V. Startsev, Mikhail P. Lebedev, Aisen A. Kychkin and Irina G. Lukachevskaia
Polymers 2025, 17(4), 460; https://doi.org/10.3390/polym17040460 - 10 Feb 2025
Viewed by 455
Abstract
This study involved the exposure of epoxy-coated basalt-plastic rebars, with diameters of 6 and 8 mm, to the open climate conditions of Yakutsk and Tiksi, located in the Arctic region of Russia. The exposure duration was 54 months. Basalt-plastic rebars were tested both [...] Read more.
This study involved the exposure of epoxy-coated basalt-plastic rebars, with diameters of 6 and 8 mm, to the open climate conditions of Yakutsk and Tiksi, located in the Arctic region of Russia. The exposure duration was 54 months. Basalt-plastic rebars were tested both untreated and after contamination with a set of neutral microorganisms resilient to cold climates, including spore-forming bacteria from the genus Bacillus, and mold fungi from the genera Aspergillus. Results showed that after 12, 24, and 54 months of exposure, the tensile strength and modulus of elasticity of untreated rebars increased by 5–14% due to the post-curing of the epoxy matrix. However, in biologically contaminated rebars, these indicators decreased on average by 11%. Bacterial cells and fungal mycelium, which penetrated surface irregularities of the rebars under open climate conditions, contributed to microcrack development, reducing the mechanical properties of the basalt-plastic rebars and causing additional moisture diffusion in the radial direction of the bars. Full article
(This article belongs to the Special Issue Computational and Experimental Approaches in Polymeric Materials)
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<p>Fragments of BFRP bars with provoked biocontamination, 6 mm in diameter, after 54 months of natural exposure in Yakutsk (<b>a</b>) and Tiksi (<b>b</b>).</p>
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<p>Comparison of the distribution of air temperature by month (on the <b>left</b>) and in general (on the <b>right</b>) for the period from 2006 to 2024 for Tiksi and Yakutsk.</p>
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<p>Comparison of the distribution of relative humidity by month (on the <b>left</b>) and in general (on the <b>right</b>) for the period from 2006 to 2024 for Tiksi and Yakutsk.</p>
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<p>Comparison of the climatogram of the dependence of relative and absolute humidity on temperature for Tiksi and Yakutsk for the period from 2006 to 2024.</p>
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<p>Dynamics of changes in the microbial landscape on the surfaces of FRPs exposed at the climatic testing ground (Yakutsk).</p>
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<p>Moisture sorption kinetics in initial BFRP bar samples with a diameter of 6 mm and lengths of H = 50, 70, and 100 mm.</p>
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<p>Moisture sorption modeling of basalt-plastic rebar samples with a length of 100 mm and a diameter of 6 mm using the following equations: (1)—blue curve, (3)—red curve, (4)—green curve.</p>
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<p>Influence of exposure duration on the moisture sorption kinetics of untreated and biologically contaminated basalt-plastic rebar samples with a diameter of 6 mm and a length of H = 50 mm, where: (1) initial state, (2) after 24 months in Tiksi (untreated), (3) after 54 months in Tiksi (untreated), (4) after 24 months in Tiksi (with biological contamination), (5) after 24 months in Yakutsk (with biological contamination).</p>
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<p>Microstructure of BFRP bar with provocative biocontamination after exposure in Yakutsk for 54 months, magnifications: (<b>a</b>) 150×, (<b>b</b>) 3000×.</p>
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22 pages, 6852 KiB  
Article
Experimental Assessment of the Strength and Microstructural Properties of Fly Ash-Containing Basalt Fiber-Reinforced Self-Compacting Sustainable Concrete
by Ala Abu Taqa, Usama A. Ebead, Mohamed O. Mohsen, Mervat O. Aburumman, Ahmed Senouci, Walid Maherzi and Deya Qtiashat
J. Compos. Sci. 2025, 9(2), 79; https://doi.org/10.3390/jcs9020079 - 9 Feb 2025
Viewed by 632
Abstract
This study investigates the influence of basalt fiber on the rheological, mechanical, and microstructural properties of sustainable self-compacting concrete (SCC) incorporating fly ash and microsilica as supplementary cementitious materials (SCMs). Various SCC mixes were prepared, incorporating five different volume fractions of basalt fiber [...] Read more.
This study investigates the influence of basalt fiber on the rheological, mechanical, and microstructural properties of sustainable self-compacting concrete (SCC) incorporating fly ash and microsilica as supplementary cementitious materials (SCMs). Various SCC mixes were prepared, incorporating five different volume fractions of basalt fiber (0.05%, 0.1%, 0.5%, 1%, and 1.5%), along with a control mix. The rheological properties of fresh SCC were evaluated using slump flow and V-funnel flow tests. Subsequently, the mechanical properties, including compressive strength, splitting tensile strength, and flexural strength, were measured after 28 days of curing. Additionally, microstructural analysis was conducted using scanning electron microscopy (SEM) on fractured specimen surfaces. The results indicated that the inclusion of basalt fiber adversely affected the flowability of fresh SCC mixes, with increased fiber volume. However, the hardened concrete exhibited significant improvements in mechanical properties with the addition of basalt fibers. The optimal performance was observed in the SCC70-85/0.10 mix specimens, which demonstrated a 69.90% improvement in flexural strength and a 23.47% increase in splitting tensile strength compared with the control specimen. SEM analysis further revealed enhanced microstructural density in the concrete matrix containing basalt fiber. A two-factor analysis of variance (ANOVA) with repetitions was conducted to evaluate the effects of varying basalt fiber concentrations on the compressive, flexural, and tensile strengths of SCC mixes. The ANOVA results indicated significant effects for both SCC grade and basalt fiber concentration, demonstrating that each factor independently affected the compressive, tensile, and flexural strengths of SCC. These findings suggest that the incorporation of basalt fibers holds promise for extending building lifespans and enhancing concrete quality, representing a valuable advancement in structural engineering applications. Full article
(This article belongs to the Special Issue Novel Cement and Concrete Materials)
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<p>Mix bleeding.</p>
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<p>Slump flow test.</p>
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<p>V-funnel test.</p>
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<p>SCC specimen mixing, casting, and curing.</p>
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<p>Slump values for concrete mixtures.</p>
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<p>V-funnel values for concrete mixtures.</p>
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<p>Temperature values for concrete mixtures.</p>
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<p>Compressive strength results at 28 days.</p>
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<p>Flexural strength results at 28 days.</p>
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<p>Split-tension strength results at 28 days.</p>
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<p>SEM images of mix 40–55/0.00, (<b>a</b>) Scale 2 mm; (<b>b</b>) Scale 50 µm.</p>
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<p>SEM images of mix 40–55/0.10, (<b>a</b>) Scale 2 mm; (<b>b</b>) Scale 100 µm.</p>
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14 pages, 6407 KiB  
Article
Tensile Properties and Constitutive Model of BFRP–Steel–BFRP Composite Plates
by Yirui Zhang, Jiyang Yi, Yang Wei and Hu Zhao
Materials 2025, 18(4), 756; https://doi.org/10.3390/ma18040756 - 8 Feb 2025
Viewed by 542
Abstract
Traditional materials such as steel and concrete often face limitations in terms of corrosion resistance and long-term performance. Over the past few decades, the search for alternative reinforcement solutions has grown, driven by the need for more sustainable, lightweight, and corrosion-resistant materials. Basalt [...] Read more.
Traditional materials such as steel and concrete often face limitations in terms of corrosion resistance and long-term performance. Over the past few decades, the search for alternative reinforcement solutions has grown, driven by the need for more sustainable, lightweight, and corrosion-resistant materials. Basalt fibers, with their superior mechanical properties and resistance to environmental degradation, have emerged as a promising candidate. This study investigated the tensile mechanical properties and constitutive behavior of basalt fiber-reinforced polymer (BFRP)–steel–BFRP composite plates. A total of 12 specimens were fabricated, varying in BFRP layer thickness, and subjected to uniaxial tensile testing. The results reveal that bonding BFRP layers significantly enhances the strengthening stiffness and strength of the steel plates, while maintaining ductility and fracture stability. The stress–strain analysis indicates a bilinear behavior, with the BFRP layers contributing to a higher slope during the strengthening stage and stable fracture strain across specimens. Additionally, a three-segment constitutive model was proposed and validated, demonstrating high accuracy in predicting tensile behavior. The findings highlight the potential of BFRP–steel–BFRP composite plates as efficient reinforcement solutions, offering a balance of strength, flexibility, and cost-effectiveness. This study provides data and modeling insights to guide the design and optimization of composite materials for structural applications. Full article
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<p>(<b>a</b>) FRP sheet reinforcement for the column; (<b>b</b>) FRP plate reinforcement for the beams.</p>
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<p>Dimensional details of composite plates (unit: mm).</p>
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<p>(<b>a</b>) Raw BFRP sheets. (<b>b</b>) Impregnation of sheets. (<b>c</b>) Pasting of sheets. (<b>d</b>) BFRP–steel–BFRP composite plates.</p>
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<p>(<b>a</b>) Tensile test for steel. (<b>b</b>) Tensile test for BFRP sheet.</p>
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<p>Test layout.</p>
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<p>(<b>a</b>) The frontal view of the failed specimens. (<b>b</b>) The cross-sectional surface.</p>
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<p>(<b>a</b>) Initial loading phase of BF2-2. (<b>b</b>) Middle loading phase of BF2-2. (<b>c</b>) Later loading phase of BF2-2.</p>
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<p>(<b>a</b>) BF0 series; (<b>b</b>) BF2 series; (<b>c</b>) BF4 series; (<b>d</b>) BF6 series; (<b>e</b>) all series.</p>
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<p>(<b>a</b>) Zoomed-in view of the yield stage. (<b>b</b>) Zoomed-in view of the strengthening stage.</p>
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<p>(<b>a</b>) Yield stress. (<b>b</b>) Yield strain.</p>
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<p>(<b>a</b>) BFRP fracture stress; (<b>b</b>) BFRP fracture strain.</p>
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<p>Tensile constitutive model of BSBCP.</p>
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<p>(<b>a</b>) Evaluations for BF2 series. (<b>b</b>) Evaluations for BF4 series. (<b>c</b>) Evaluations for BF6 series.</p>
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23 pages, 4356 KiB  
Article
Effects of High Temperature and Water Re-Curing on the Flexural Behavior and Mechanical Properties of Steel–Basalt Hybrid Fiber-Reinforced Concrete
by Zinnur Çelik and Yunus Urtekin
Appl. Sci. 2025, 15(3), 1587; https://doi.org/10.3390/app15031587 - 4 Feb 2025
Viewed by 521
Abstract
Fiber-reinforced concrete (FRC) has become increasingly important in recent decades due to its superior mechanical properties, especially flexural strength and toughness, compared to normal concrete. FRC has also received significant attention because of its superior fire resistance performance compared to non-fiber concrete. In [...] Read more.
Fiber-reinforced concrete (FRC) has become increasingly important in recent decades due to its superior mechanical properties, especially flexural strength and toughness, compared to normal concrete. FRC has also received significant attention because of its superior fire resistance performance compared to non-fiber concrete. In recent years, studies on the mechanical performance, fire design, and post-fire repair of thermally damaged fibrous and non-fibrous concrete have gained importance. In particular, there are very few studies in the literature on the mechanical performance and flexural behavior of steel and basalt hybrid fiber concretes after high temperature and water re-curing. This study aims to determine the mechanical properties and toughness of concrete containing steel fiber (SF) and basalt fiber (BF) after ambient and high temperature (400 °C, 600 °C, and 800 °C). Additionally, this study aimed to examine the changes in fire-damaged FRCs as a result of water re-curing. In this context, high temperature and water re-curing were carried out on non-fibrous concrete (control) and four different fiber compositions: in the first mixture, only steel fibers were used, and in the other two mixtures, basalt fibers were substituted at 25% and 50% rates instead of steel fibers. Furthermore, in the fifth mixture, basalt fibers were replaced by polypropylene fibers (PPFs) to make a comparison with the steel and basalt hybrid fiber-reinforced mixture. This study examined the effects of different fiber compositions on the ultrasonic pulse velocity (UPV) and compressive and flexural strength of the specimens at ambient temperature and after exposure to elevated temperatures and water re-curing. Additionally, the load–deflection curves and toughness of the mixtures were determined. The study results showed that different fiber compositions varied in their healing effect at different stages. The hybrid use of SF and BF can improve the flexural strength before elevated temperature and particularly after 600 °C. However, it caused a decrease in the recovery rates, especially after re-curing with water in terms of toughness. Water re-curing provided remarkable improvement in terms of mechanical and toughness properties. This improvement was more evident in steel–polypropylene fiber-reinforced concretes. Full article
(This article belongs to the Section Civil Engineering)
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<p>Types of fibers.</p>
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<p>Test set-up of specimen and schematic diagram of a specimen.</p>
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<p>Crack distribution on the surface after high temperature and re-curing.</p>
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<p>Relative residual compressive strength results after heating and re-curing.</p>
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<p>Bridging effect of fibers after flexural test of M4 sample.</p>
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<p>Relative residual flexural strength results.</p>
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<p>Load–mid-span deflection curves for all test series.</p>
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<p>Effect of fiber mixture series on flexural properties of concrete before heating: (<b>a</b>) load carrying capacity; (<b>b</b>) toughness.</p>
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<p>Effect of fiber mixture series on flexural properties of concrete after 400 °C and re-curing: (<b>a</b>) load carrying capacity; (<b>b</b>) toughness.</p>
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<p>Effect of fiber mixture series on flexural properties of concrete after 600 °C and re-curing: (<b>a</b>) load carrying capacity; (<b>b</b>) toughness.</p>
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<p>Effect of fiber mixture series on flexural properties of concrete after 800 °C and re-curing: (<b>a</b>) load carrying capacity; (<b>b</b>) toughness.</p>
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<p>Section features of specimens.</p>
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17 pages, 4248 KiB  
Article
Determination of Basalt Fiber Reinforcement in Kaolin Clay: Experimental and Neural Network-Based Analysis of Liquid Limit, Plastic Limit, and Unconfined Compressive Strength
by Yasemin Aslan Topçuoğlu, Zeynep Bala Duranay, Zülfü Gürocak and Hanifi Güldemir
Processes 2025, 13(2), 377; https://doi.org/10.3390/pr13020377 - 30 Jan 2025
Viewed by 617
Abstract
The use of basalt fibers, which are employed in various fields, such as construction, automotive, chemical, and petrochemical industries, the sports industry, and energy engineering, is also increasingly common in soil reinforcement studies, another application area of geotechnical engineering, alongside their use in [...] Read more.
The use of basalt fibers, which are employed in various fields, such as construction, automotive, chemical, and petrochemical industries, the sports industry, and energy engineering, is also increasingly common in soil reinforcement studies, another application area of geotechnical engineering, alongside their use in concrete. With this growing application, scientific studies on soil reinforcement with basalt fiber have also gained momentum. This study establishes the effects of basalt fiber on the liquid limit, plastic limit, and strength properties of soils, and the relationships among the liquid limit, plastic limit, and unconfined compressive strength of the soil. For this purpose, 12 mm basalt fiber was used as a reinforcement material in kaolin clay at ratios of 1.0%, 1.5%, 2.0%, 2.5%, and 3.0%. The prepared samples were subjected to liquid limit, plastic limit, and unconfined compressive strength tests. As a result of the experimental studies, the fiber ratio that provided the best improvement in the soil properties was determined, and the relationships among the liquid limit, plastic limit, and unconfined compressive strength were established. The experimental results were then used as input data for an artificial intelligence model. The used neural network (NN) was trained to obtain basalt fiber-to-kaolin ratios based on the liquid limit, plastic limit, and unconfined compressive strength. This model enabled the prediction of the fiber ratio that provides the maximum improvement in the liquid limit, plastic limit, and compressive strength without the need for experiments. The NN results were in great agreement with the experimental results, demonstrating that the fiber ratio providing the maximum improvement in the soil properties can be identified using the NN model without requiring experimental studies. Moreover, the performance and reliability of the NN model were evaluated using 5-fold cross-validation and compared with other AI methods. The ANN model demonstrated superior predictive accuracy, achieving the highest correlation coefficient (R = 0.82), outperforming the other models in terms of both accuracy and reliability. Full article
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<p>Used in experimental studies: (<b>a</b>) K; (<b>b</b>) unseparated BF; (<b>c</b>) BF separated by compressor.</p>
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<p>(<b>a</b>,<b>b</b>) Conducting the liquid limit test; (<b>c</b>) conducting the plastic limit test.</p>
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<p>(<b>a</b>) Mixing of clay and BF samples with a mixer; (<b>b</b>) compacted sample with compaction test; (<b>c</b>,<b>d</b>) sample before and after unconfined compression test.</p>
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<p>Core elements of NN system.</p>
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<p>Basic flowchart of NN.</p>
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<p>Changes in the LL, PL, PI, and q<sub>u</sub> values of the soil depending on the BF ratio.</p>
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<p>The structure of the NN model used in this study.</p>
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<p>ANN results of LL.</p>
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<p>ANN results of PL.</p>
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<p>ANN results of q<sub>u</sub>.</p>
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<p>The regression curves of the model.</p>
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<p>The test regression curve of the model.</p>
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<p>R and RMSE values of different AI techniques obtained from cross-validation.</p>
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23 pages, 9874 KiB  
Article
Sustainable Approach to Utilization of Waste Glass Fibers and Basalt Powder as Potential Additives in Epoxy-Based Composites for Reparation of Concrete Structures
by Krzysztof Adam Ostrowski, Marcin Piechaczek, Michał Lach, Oliwia Sikora, Kazimierz Furtak, Katarzyna Sajdak and Martyna Radecka-Trzop
Sustainability 2025, 17(3), 1064; https://doi.org/10.3390/su17031064 - 28 Jan 2025
Viewed by 938
Abstract
The growing production of glass fibers is a major challenge due to the later problem of their sustainable recycling. This article reports the potential use of post-production waste glass fibers and basalt powder as additives in resin compounds designed for repairing concrete elements. [...] Read more.
The growing production of glass fibers is a major challenge due to the later problem of their sustainable recycling. This article reports the potential use of post-production waste glass fibers and basalt powder as additives in resin compounds designed for repairing concrete elements. The aim of this research was to develop a repair compound based on epoxy resin with the addition of waste materials, offering a competitive alternative to currently available repair compounds on the market by utilizing lower-cost materials and addressing pro-environmental aspects through waste reuse. The prepared research samples were characterized by varying proportions of basalt powder (0–20%), ground HP 12 fibers (40/60%), and HP 6 fibers (10/20%). A series of tests, including tensile strength tests, were conducted as part of this study to determine the effect of the applied additives on the ultimate tensile force and maximum deformations. Abrasion resistance tests were also carried out to evaluate the impact of basalt powder as a filler on enhancing the abrasion resistance of the designed repair compound. Additionally, SEM and EDS analyses were used to evaluate the uniformity and distribution of the additives within the sample. This study examined samples containing varying percentages of basalt powder and fibers, both virgin and milled. The most significant reinforcement effect was observed for sample E/20HP/20bp, where its tensile strength decreased by 8%, while its abrasion resistance increased by 44% compared to the reference sample. The obtained results confirm that incorporating waste materials as additives into epoxy resin can significantly enhance the mechanical properties of repair compounds while reducing cost and promoting environmental protection. In addition, the repair compound developed complies with the selected principles within the 6Rs environmental regulations: RECYCLING (reuse of waste glass fibers), RETHINK (reduce environmental impact by avoiding landfill), REDUCE (minimize the use of virgin glass fibers in the production of repair compounds) and REPAIR (increase the efficiency of repairing damaged concrete structures). Furthermore, as the percentage of basalt powder increases, the abrasion resistance of the repair compound improves. The obtained repair compounds may serve as an alternative to currently used compounds for the repair of bridges and factory floors. Full article
(This article belongs to the Section Waste and Recycling)
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<p>Visualization of the incidence and relationship of individual keywords (accessed on 21 October 2024).</p>
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<p>Milled materials: (<b>a</b>) 12 mm HP fiberglass; (<b>b</b>) waste basalt powder.</p>
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<p>Dimensions of test specimen type 1A for tensile strength test.</p>
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<p>Testing stand for tensile strength—Zwick/Roell Z050.</p>
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<p>Testing stand for abrasion testing—Schopper–Schlobach apparatus.</p>
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<p>Components of the Schopper–Schlobach apparatus.</p>
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<p>Average tensile strength of (40/60)mHP samples depending on the basalt powder content.</p>
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<p>Average tensile strength of (10/20)HP samples depending on the basalt powder content.</p>
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<p>Samples after the tensile strength test. From the left: reference sample, E/20HP/5bp, E/20HP/10bp, E/20HP/15bp, E/20HP/20bp.</p>
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<p>Cubic specimens for abrasion resistance testing (E/20HP/10bp).</p>
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<p>SEM images of (<b>a</b>) reference sample; (<b>b</b>) E/20HP/5bp; (<b>c</b>) E/20HP/10bp; (<b>d</b>) E/20HP/15bp; (<b>e</b>) E/20HP/20bp, blue: glass fiber fragments, yellow: basalt powder fragments; (<b>f</b>) glass fiber (E/20HP/20bp sample); (<b>g</b>) basalt powder (E/20HP/20bp sample).</p>
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<p>SEM images of (<b>a</b>) reference sample; (<b>b</b>) E/20HP/5bp; (<b>c</b>) E/20HP/10bp; (<b>d</b>) E/20HP/15bp; (<b>e</b>) E/20HP/20bp, blue: glass fiber fragments, yellow: basalt powder fragments; (<b>f</b>) glass fiber (E/20HP/20bp sample); (<b>g</b>) basalt powder (E/20HP/20bp sample).</p>
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<p>Results of EDS test of sample E/20HP/20bp: (<b>a</b>) surface area of test sample; (<b>b</b>) carbon; (<b>c</b>) oxygen; (<b>d</b>) silicon; (<b>e</b>) aluminum; (<b>f</b>) sodium; (<b>g</b>) zirconium; (<b>h</b>) calcium; (<b>i</b>) chlorine; (<b>j</b>) magnesium; (<b>k</b>) iron.</p>
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23 pages, 12763 KiB  
Article
Bond Performance of GFRP Bars in Glass and Basalt Fiber-Reinforced Geopolymer Concrete Under Hinged Beam Tests
by Duygu Ertürkmen, Hüsamettin Ürünveren, Ahmet Beycioğlu, Nabi Ibadov, Hüseyin Yılmaz Aruntaş and Andrzej Garbacz
Materials 2025, 18(3), 498; https://doi.org/10.3390/ma18030498 - 22 Jan 2025
Viewed by 355
Abstract
In recent years, researchers have focused on the usability of fiber-reinforced polymer (FRP) bars due to their lightweight, corrosion-resistant, and eco-friendly characteristics. Geopolymers, as low-carbon alternatives to traditional binders, aim to reduce CO2 emissions in concrete production. The bond strength between FRP [...] Read more.
In recent years, researchers have focused on the usability of fiber-reinforced polymer (FRP) bars due to their lightweight, corrosion-resistant, and eco-friendly characteristics. Geopolymers, as low-carbon alternatives to traditional binders, aim to reduce CO2 emissions in concrete production. The bond strength between FRP bars and concrete is critical for the load-bearing capacity and deformation characteristics of reinforced elements. The objectives of this work are to investigate the bond performance of GFRP bars in chopped glass and basalt fiber-added geopolymer concrete using hinged beam tests. Since the hinged beam test accurately represents the behavior of real bending elements, this test method was selected as a main bonding test. Initially, three geopolymer mixtures with Ms modulus values of 1.2, 1.3, and 1.4 were prepared and tested. The mixture with a modulus of 1.2 Ms, achieving a compressive strength of 56.53 MPa, a flexural strength of 3.54 MPa, and a flow diameter of 57 cm, was chosen for beam production due to its optimal workability and strength. After mechanical and workability tests, SEM analysis was performed to evaluate its internal structure. For evaluating the bond performance of GFRP bars, 12 geopolymer beam specimens were prepared, incorporating varying fiber types (chopped glass fiber or basalt fiber) and embedment lengths (5 Ø or 20 Ø). Hinged beam tests revealed that the bond strengths of glass and basalt fiber-added mixtures were up to 49% and 37% higher than that of the control geopolymer concrete, respectively. It was concluded that incorporating fibers positively influenced the bond between geopolymer concrete and GFRP bars, with glass fibers proving more effective than basalt fibers. These findings enhance the understanding of bond mechanisms between GFRP bars and geopolymer concrete, emphasizing their potential for sustainable and durable construction in both industrial and scientific applications. Full article
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<p>Images of chopped glass and basalt fibers.</p>
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<p>Details of the steel rebars used as stirrups in the hinged beam specimens (dimensions are given in mm).</p>
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<p>Stirrup rebars in the hinged beam specimens.</p>
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<p>Details of an example of GFRP bar placement in the formwork.</p>
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<p>Formworks used in the preparation of hinged beam specimens.</p>
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<p>Schematic illustration of the hinged beam test setup and an image of a beam specimen before the test.</p>
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<p>Images from the hinged beam test.</p>
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<p>A specimen image after the hinged beam test.</p>
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<p>Post-test images of some test specimens.</p>
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<p>SEM image of geopolymer concrete sample cured at 100 °C.</p>
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<p>Tensile stress–slip curves of reference geopolymer concrete beams.</p>
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<p>Tensile stress–slip curves of GFRP bars in glass fiber-reinforced geopolymer concrete beams (4 kg/m<sup>3</sup> glass fiber and 5 Ø embedment length).</p>
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<p>Tensile stress–slip curves of GFRP bars in glass fiber-reinforced geopolymer concrete beams (4 kg/m<sup>3</sup> glass fiber and 20 Ø embedment length).</p>
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<p>Tensile stress–slip curves of GFRP bars in basalt fiber-reinforced geopolymer concrete beams (4 kg/m<sup>3</sup> basalt fiber and 5 Ø embedment length).</p>
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<p>Tensile stress–slip curves of GFRP bars in basalt fiber-reinforced geopolymer concrete beams (4 kg/m<sup>3</sup> basalt fiber and 20 Ø embedment length).</p>
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<p>The average ultimate bond stress (τ<sub>u</sub>) values depending on the embedment length.</p>
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<p>The ultimate load values on GFRP bars for basalt and glass fiber geopolymer specimens.</p>
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<p>The load–slip curves for the basalt fiber-reinforced specimens compared to the reference specimens.</p>
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<p>The load–slip curves for the glass fiber-reinforced specimens compared to the reference specimens.</p>
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<p>The load–slip curves of the specimens for 5 Ø embedment length.</p>
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<p>The load–slip curves of the specimens for 20 Ø embedment length.</p>
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<p>Comparison of load-free end slip curves between steel-reinforced additional reference specimens and GFRP-reinforced reference specimens with a 20 Ø embedment length.</p>
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19 pages, 5374 KiB  
Article
Research on Flexural Performance of Basalt Fiber-Reinforced Steel–Expanded Polystyrene Foam Concrete Composite Wall Panels
by Fang Liu, Long Zhao, Longxin Yuan, Gang Wu, Ran Zheng and Yusong Mu
Buildings 2025, 15(2), 285; https://doi.org/10.3390/buildings15020285 - 19 Jan 2025
Viewed by 451
Abstract
This paper presents a novel design of prefabricated steel–EPS foam concrete composite wall panels, which can solve issues such as long curing times, decreased impermeability and durability, easy corrosion of steel reinforcement, and difficult construction under the cold climate conditions in Northeast China. [...] Read more.
This paper presents a novel design of prefabricated steel–EPS foam concrete composite wall panels, which can solve issues such as long curing times, decreased impermeability and durability, easy corrosion of steel reinforcement, and difficult construction under the cold climate conditions in Northeast China. A parametric analysis of the composite wallboard was carried out using the finite-element analysis software ABAQUS 6.12. In-depth exploration was conducted on the contributions of parameters such as the density of foam concrete, the strength of cold-formed thin-walled C-section steel, and the cross-sectional height of cold-formed thin-walled C-section steel compared to the overall flexural bearing capacity of the composite wallboard as well as the impacts of these parameters on the failure modes. The mechanical properties of the composite wallboard were verified through four-point bending tests. The bearing capacity of this composite wallboard can reach up to 100.58 kN at most, and its flexural bearing capacity can reach 30.44 kN·m. Meanwhile, its ductility coefficient of 2.9 is also within the optimal range. The research results confirm the superior mechanical properties of the designed composite wallboard, providing beneficial references for the research on similar composite material structures. Full article
(This article belongs to the Section Building Structures)
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<p>Composite wall panel structure and details.</p>
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<p>Steel–EPS Foam Concrete Wall Panel Models.</p>
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<p>Stress Distribution of EPS Foam Concrete and Cold-Formed C-Shaped Steel.</p>
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<p>Damage Contour Maps of Components.</p>
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<p>Load–Displacement Curves of Components.</p>
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<p>The physical test setup and its schematic diagram and details.</p>
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<p>Crack distribution diagram at the failure of the specimen.</p>
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<p>Comparative analysis of the deflection of specimens using graphical method.</p>
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<p>Load–strain comparison for the top and bottom surfaces of the concrete and the upper and lower flanges of the C-shaped steel.</p>
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<p>Strain Distribution along the Section Height of C-shaped Steel at Midspan.</p>
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<p>Comparison of Load-Deflection Curves Between Numerical Simulation and Experiment. (<b>a</b>) CSC-1; (<b>b</b>) CSC-2.</p>
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22 pages, 8986 KiB  
Article
Study of the Influence of Desert Sand-Mineral Admixture on the Abrasion Resistance of Concrete
by Aoli Cao, Yuwei Ma, Zhiqiang Li, Xixian Du, Gang Li and Aiqin Wang
Materials 2025, 18(2), 446; https://doi.org/10.3390/ma18020446 - 19 Jan 2025
Viewed by 311
Abstract
The incorporation of desert sand-mineral admixture improves the abrasion resistance of concrete. To prolong the service life of assembled concrete channels and mitigate the depletion of river sand resources, the effects of fly ash (FA), silica fume (SF), desert sand (DS), and basalt [...] Read more.
The incorporation of desert sand-mineral admixture improves the abrasion resistance of concrete. To prolong the service life of assembled concrete channels and mitigate the depletion of river sand resources, the effects of fly ash (FA), silica fume (SF), desert sand (DS), and basalt fiber (BF) on the mechanical properties and the abrasion resistance of concrete were examined, alongside an analysis of their microstructures to elucidate the underlying mechanisms of influence. The results indicated that the abrasion resistance strength of concrete mixed with 10% FA and 0.05% BF alone increased by 80.19% and 81.59%, respectively, compared with ordinary concrete (OC). When SF was added to the concrete at a dosage of 10%, it improved the mechanical properties and the abrasion resistance of the concrete. Furthermore, adding SF resulted in a 12.50% increase in compressive strength and a 12.27% increase in abrasion resistance strength compared to OC. The addition of DS did not significantly enhance the concrete’s abrasion resistance. The combination of ingredients for desert sand concrete (DSC) that provides excellent abrasion resistance was determined using an orthogonal experiment. The optimal mixture consisted of 10% FA content, 10% SF content, 40% DS content, and 0.05% BF content, which increased the abrasion resistance strength by 112.95% compared to OC. Through microscopic analysis, it is found that the width of the interfacial transition zone (ITZ) is an important factor in determining the abrasion resistance of concrete, and a narrower ITZ enhances the concrete’s abrasion resistance. The study’s findings could function as a theoretical reference for the engineering design of DSC. Full article
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<p>Impact of various admixtures on the 28 d compressive strength of concrete.</p>
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<p>Impact of various admixtures on the 28 d splitting tensile strength of concrete.</p>
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<p>(<b>a</b>) Abrasion resistance strength, (<b>b</b>) abrasion rate.</p>
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<p>Concrete appearance prior to and subsequent to the completion of abrasion: (<b>a</b>) Prior to abrasion. (<b>b</b>) Following C0 abrasion. (<b>c</b>) Following FA-1 abrasion. (<b>d</b>) Following SF-2 abrasion. (<b>e</b>) Following DS-2 abrasion. (<b>f</b>) Following BF-1 abrasion.</p>
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<p>Concrete SEM microscopic morphology. (<b>a</b>) C0, (<b>b</b>) FA-1, (<b>c</b>) SF-2, (<b>d</b>) DS-2, and (<b>e</b>) BF-1.</p>
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<p>Concrete SEM microscopic morphology. (<b>a</b>) C0, (<b>b</b>) FA-1, (<b>c</b>) SF-2, (<b>d</b>) DS-2, and (<b>e</b>) BF-1.</p>
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<p>XRD patterns of several admixtures.</p>
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<p>Variation trends of each factor at different levels. (<b>a</b>) Compressive strength, (<b>b</b>) splitting tensile strength, (<b>c</b>) abrasion resistance strength, (<b>d</b>) abrasion rate.</p>
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<p>Micro-morphology of concrete SEM. (<b>a</b>) Group C0. (<b>b</b>) Group DSC-1.</p>
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