[go: up one dir, main page]
More Web Proxy on the site http://driver.im/
You seem to have javascript disabled. Please note that many of the page functionalities won't work as expected without javascript enabled.
 
 
Sign in to use this feature.

Years

Between: -

Subjects

remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline

Journals

remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline

Article Types

Countries / Regions

remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline

Search Results (2,431)

Search Parameters:
Keywords = battery life

Order results
Result details
Results per page
Select all
Export citation of selected articles as:
17 pages, 4970 KiB  
Article
Multi-Objective Structural Optimization Design for Electric Excavator-Specific Battery Packs with Impact Resistance and Fatigue Endurance
by Zihang Li, Jiao Qin, Ming Zhao, Minmin Xu, Wei Huang and Fangming Wu
Energies 2025, 18(3), 669; https://doi.org/10.3390/en18030669 - 31 Jan 2025
Viewed by 416
Abstract
As the issue of energy scarcity becomes increasingly critical, the adoption of electric construction machinery emerges as a pivotal strategy to address the energy crisis. During the travel and operation of electric construction machinery, the machinery-specific battery packs are subjected to long-term mechanical [...] Read more.
As the issue of energy scarcity becomes increasingly critical, the adoption of electric construction machinery emerges as a pivotal strategy to address the energy crisis. During the travel and operation of electric construction machinery, the machinery-specific battery packs are subjected to long-term mechanical shocks and random vibration loads, leading to resonance and structural damage failure. To address the multi-objective optimization design issues of machinery-specific battery packs for electric construction machinery under the action of random vibration and impact loads and to enhance the fatigue life and reduce the mass of the battery pack, this paper conducts optimization design research on a newly developed battery pack for an electric excavator. Firstly, a finite element model of the battery pack is established to conduct simulation analyses on its impact resistance characteristics and fatigue life. Secondly, through a comprehensive contribution analysis method, key components are identified, with the thickness dimensions of the battery pack parts selected as design parameters. Finally, using maximum stress under mechanical shock conditions and first-order constraint mode as constraint conditions, mass minimization and fatigue life maximization are set as optimization objectives. The Box–Behnken experimental design is employed alongside a Kriging approximation model; subsequently, the NSGA-II algorithm is utilized for multi-objective optimization. The optimization results show that, while meeting the basic static and dynamic performance requirements, the mass of the optimized battery pack outer frame is reduced by 56.8 kg, a decrease of 5.75%. Concurrently, the optimized battery pack’s fatigue life has increased by 1,234,800 cycles, which is an enhancement factor of 1.65 compared to pre-optimization levels. These findings provide significant reference points for optimizing structural performance and achieving lightweight designs in electric excavator battery packs. Full article
(This article belongs to the Special Issue Reliable and Safe Electric Vehicle Powertrain Design and Optimization)
Show Figures

Figure 1

Figure 1
<p>Image of the battery pack: (<b>a</b>) Physical mage of the battery pack; (<b>b</b>) Finite element model diagram of the battery pack; (<b>c</b>) Battery pack structure diagram.</p>
Full article ">Figure 2
<p>Modal diagram of the battery pack: (<b>a</b>) First-order modalities; (<b>b</b>) Second-order modes; (<b>c</b>) Third-order modalities; (<b>d</b>) Fourth-order modes; (<b>e</b>) Fifth-order modalities; (<b>f</b>) Sixth-order modes.</p>
Full article ">Figure 3
<p>Load curve graph.</p>
Full article ">Figure 4
<p>Stress contour map under mechanical impact conditions: (<b>a</b>) +Z direction operating condition; (<b>b</b>) −Z direction operating condition.</p>
Full article ">Figure 5
<p>Frequency response diagram.</p>
Full article ">Figure 6
<p>Fatigue life contour map.</p>
Full article ">Figure 7
<p>Comprehensive contribution chart for components.</p>
Full article ">Figure 8
<p>Structural response <span class="html-italic">R</span><sup>2</sup> graph: (<b>a</b>) Mass <span class="html-italic">R</span><sup>2</sup> <span class="html-italic">chart</span>; (<b>b</b>) Fatigue life <span class="html-italic">R</span><sup>2</sup> <span class="html-italic">chart</span>; (<b>c</b>) First-order mode <span class="html-italic">R</span><sup>2</sup> <span class="html-italic">chart</span>; (<b>d</b>) Maximum stress in the +Z direction <span class="html-italic">R</span><sup>2</sup> <span class="html-italic">chart</span>; (<b>e</b>) Maximum stress in the −Z direction <span class="html-italic">R</span><sup>2</sup> <span class="html-italic">chart</span>.</p>
Full article ">Figure 8 Cont.
<p>Structural response <span class="html-italic">R</span><sup>2</sup> graph: (<b>a</b>) Mass <span class="html-italic">R</span><sup>2</sup> <span class="html-italic">chart</span>; (<b>b</b>) Fatigue life <span class="html-italic">R</span><sup>2</sup> <span class="html-italic">chart</span>; (<b>c</b>) First-order mode <span class="html-italic">R</span><sup>2</sup> <span class="html-italic">chart</span>; (<b>d</b>) Maximum stress in the +Z direction <span class="html-italic">R</span><sup>2</sup> <span class="html-italic">chart</span>; (<b>e</b>) Maximum stress in the −Z direction <span class="html-italic">R</span><sup>2</sup> <span class="html-italic">chart</span>.</p>
Full article ">Figure 9
<p>Pareto optimal solution set diagram.</p>
Full article ">Figure 10
<p>Structural responses after optimization: (<b>a</b>) Optimized frequency response diagram; (<b>b</b>) Optimized fatigue life contour map; (<b>c</b>) Post-optimization +Z mechanical impact maximum stress cloud diagram; (<b>d</b>) Post-optimization −Z mechanical impact maximum stress cloud diagram.</p>
Full article ">Figure 10 Cont.
<p>Structural responses after optimization: (<b>a</b>) Optimized frequency response diagram; (<b>b</b>) Optimized fatigue life contour map; (<b>c</b>) Post-optimization +Z mechanical impact maximum stress cloud diagram; (<b>d</b>) Post-optimization −Z mechanical impact maximum stress cloud diagram.</p>
Full article ">
19 pages, 58062 KiB  
Article
Supporting a Lithium Circular Economy via Reverse Logistics: Improving the Preprocessing Stage of the Lithium-Ion Battery Recycling Supply Chain
by Oluwatosin S. Atitebi, Kalpana Dumre and Erick C. Jones
Energies 2025, 18(3), 651; https://doi.org/10.3390/en18030651 - 30 Jan 2025
Viewed by 363
Abstract
The clean energy transition is a paradigm shift from a carbon-intensive energy system to a renewable energy one. The new energy system requires large amounts of critical minerals, including lithium. However, the mining and extraction of these minerals introduces environmental challenges. Recycling critical [...] Read more.
The clean energy transition is a paradigm shift from a carbon-intensive energy system to a renewable energy one. The new energy system requires large amounts of critical minerals, including lithium. However, the mining and extraction of these minerals introduces environmental challenges. Recycling critical minerals, a critical step for a circular economy, is a potential solution that could reduce the need for new mining, lowering the overall environmental impact. In this experimentally based work, we evaluate the lithium recycling labor- and cost-intensive preprocessing stage that is currently performed by large-scale recycling systems, reducing the efficiency and raising the costs of the downstream stages. We investigate multiple inexpensive and distributed alternatives to the preprocessing tasks that produce black mass (separation, grinding, and shredding techniques) in order to identify methods that improve the efficiency of the downstream recycling process. This work finds that shredding and grinding end-of-life batteries with equipment that can be purchased for under USD 1000 produces viable black mass for a fraction of the cost. Therefore, this work contributes toward the goal of a circular economy for battery energy storage by identifying the technical requirements and measuring the efficacy of redistributing the labor- and time-intensive preprocessing tasks to small-scale recyclers in order to enhance the efficiency of the downstream stages in the lithium-ion battery recycling reverse supply chain. Full article
Show Figures

Figure 1

Figure 1
<p>Overview of experiment flowchart.</p>
Full article ">Figure 2
<p>Collection of spent LIBs from an electric vehicle battery module. (<b>a</b>) Recovered battery pack; (<b>b</b>) Harvested LIBs from battery pack.</p>
Full article ">Figure 3
<p>Safe disassembling of discharged LIBs. (<b>a</b>) Shearing of battery packaging materials; (<b>b</b>) Battery unit with no aluminum encasement; (<b>c</b>) Four distinct units of LIB internal component; (<b>d</b>) Packed layers of foil in each distinct unit.</p>
Full article ">Figure 4
<p>Shredding of disassembled LIBs internal components. (<b>a</b>) LIBs internal layers; (<b>b</b>) Shredding LIBs layers; (<b>c</b>) Shredded LIBs layers.)</p>
Full article ">Figure 5
<p>Black mass produced via manual grinding.</p>
Full article ">Figure 6
<p>Electrical grinding of LIBs internal components. (<b>a</b>) Shredded LIBs; (<b>b</b>) LIBs in electric grinder; (<b>c</b>) Black mass and residue.</p>
Full article ">Figure 7
<p>Microscopic view of black mass generated using both electrical and manual grinding techniques (scale bar = 1000 µm). (<b>a</b>) Electric-grinded black mass; (<b>b</b>) Manual-grinded black mass; (<b>c</b>) Electric-grinded black mass; (<b>d</b>) Manual-grinded black mass.</p>
Full article ">Figure A1
<p>100 µ, <a href="https://www.fishersci.com/shop/products/cell-moicro-sieves-100-mc/NC0548465" target="_blank">https://www.fishersci.com/shop/products/cell-moicro-sieves-100-mc/NC0548465</a> CellMicroSieve Biodesign (accessed on 20 November 2024).</p>
Full article ">Figure A2
<p><a href="https://sepor.com/" target="_blank">https://sepor.com/</a>, Hand crank pulverizer.</p>
Full article ">Figure A3
<p><a href="https://mycgoldenwall.com/" target="_blank">https://mycgoldenwall.com/</a>, Electric grain mill.</p>
Full article ">Figure A4
<p>Small-scale paper shredder. <a href="https://bonsaiishop.com/products/bonsaii-paper-shredder-8-sheet-cross-cut-shredder-with-4-2-gallon-wastebasket-c261-c?srsltid=AfmBOooX-jJXccqrgGFWfKYj2s3k3Ipu4u1B-8Qe7s9yBblM3TC-mXpc" target="_blank">https://bonsaiishop.com/products/bonsaii-paper-shredder-8-sheet-cross-cut-shredder-with-4-2-gallon-wastebasket-c261-c?srsltid=AfmBOooX-jJXccqrgGFWfKYj2s3k3Ipu4u1B-8Qe7s9yBblM3TC-mXpc</a> (accessed on 20 November 2024).</p>
Full article ">
26 pages, 7965 KiB  
Review
Efficient Recycling Processes for Lithium-Ion Batteries
by Sabyasachi Paul and Pranav Shrotriya
Materials 2025, 18(3), 613; https://doi.org/10.3390/ma18030613 - 29 Jan 2025
Viewed by 343
Abstract
Lithium-ion batteries (LIBs) are an indispensable power source for electric vehicles, portable electronics, and renewable energy storage systems due to their high energy density and long cycle life. However, the exponential growth in production and usage has necessitated highly effective recycling of end-of-life [...] Read more.
Lithium-ion batteries (LIBs) are an indispensable power source for electric vehicles, portable electronics, and renewable energy storage systems due to their high energy density and long cycle life. However, the exponential growth in production and usage has necessitated highly effective recycling of end-of-life LIBs to recover valuable resources and minimize the environmental impact. Pyrometallurgical and hydrometallurgical processes are the most common recycling methods but pose considerable difficulties. The energy-intensive pyrometallurgical recycling process results in the loss of critical materials such as lithium and suffers from substantial emissions and high costs. Solvent extraction, a hydrometallurgical method, offers energy-efficient recovery for lithium, cobalt, and nickel but requires hazardous chemicals and careful waste management. Direct recycling is an alternative to traditional methods as it preserves the cathode active material (CAM) structure for quicker and cheaper regeneration. It also offers environmental advantages of lower energy intensity and chemical use. Hybrid pathways, combining hydrometallurgical and direct recycling methods, provide a cost-effective, scalable solution for LIB recycling, maximizing material recovery with minimal waste and environmental risk. The success of recycling methods depends on factors such as battery chemistry, the scalability of recovery processes, and the cost-effectiveness of waste material recovery. Though pyrometallurgical and hydrometallurgical processes have secured their position in LIB recycling, research is proceeding toward newer approaches, such as direct and hybrid methods. These alternatives are more efficient both environmentally and in terms of cost with a broader perspective into the future. In this review, we describe the current state of direct recycling as an alternative to traditional pyrometallurgical and hydrometallurgical methods for recuperating these critical materials, particularly lithium. We also highlight some significant advancements that make these objectives possible. As research progresses, direct recycling and its variations hold great potential to reshape the way LIBs are recycled, providing a sustainable pathway for battery material recovery and reuse. Full article
(This article belongs to the Section Energy Materials)
Show Figures

Graphical abstract

Graphical abstract
Full article ">
41 pages, 571 KiB  
Article
Regulations and Policies on the Management of the End of the Life of Lithium-Ion Batteries in Electrical Vehicles
by Jay N. Meegoda, Daniel Watts and Udaysinh Patil
Energies 2025, 18(3), 604; https://doi.org/10.3390/en18030604 - 27 Jan 2025
Viewed by 453
Abstract
Electrical vehicle (EV) batteries, particularly lithium-ion batteries, pose significant environmental challenges due to their hazardous components, the effects of initial building-material fabrication, and the difficulties of recycling and disposal. Policies and legislative strategies adopted by different governments to solve these issues are investigated [...] Read more.
Electrical vehicle (EV) batteries, particularly lithium-ion batteries, pose significant environmental challenges due to their hazardous components, the effects of initial building-material fabrication, and the difficulties of recycling and disposal. Policies and legislative strategies adopted by different governments to solve these issues are investigated in this manuscript, specifically based on circularity and resource use. Important steps are end-of-life management, safe disposal and transportation, avoidance of hazardous gas emissions, circularity, resource use, fire prevention, and expanded producer accountability. As of February 2024, New Jersey is the first and only state in the United States that has adopted a thorough legislative framework for EV battery management, therefore establishing a standard for other states. California passed major laws encouraging Zero-Emission Vehicle (ZEV) battery manufacture and recycling. Other states are likewise trying to show initiative by implementing and changing laws. Globally, the European Union is leading, while Canada, Australia, China, and others have created strong rules of regulation. This paper looks at and contrasts the environmental problems of lithium-ion electric vehicles with the legislative actions made by different nations and states to solve these problems. By means of a thorough examination of these policies, this paper seeks to present a whole picture of the current scene and the best techniques for lifetime management of EV batteries that can be embraced by different governments. In this manuscript, a comparison is made between two leading legislations, specifically that of the state of New Jersey and the European Union. To achieve the most beneficial outcome, it is the responsibility of stakeholders to promote rules; emphasize battery recycling, secure disposal, and extended producer accountability; promote innovation in sustainable battery technology; and try to build a pragmatic approach to battery management to mitigate environmental impacts based on a hybrid version of the legislations from the state of New Jersey and the European Union. Full article
(This article belongs to the Section A3: Wind, Wave and Tidal Energy)
15 pages, 2717 KiB  
Article
Combination of Phase Change Composite Material and Liquid-Cooled Plate Prevents Thermal Runaway Propagation of High-Specific-Energy Battery
by Weigao Ji, Yongchun Dang, Yongchao Yu, Xunli Zhou and Lei Li
Appl. Sci. 2025, 15(3), 1274; https://doi.org/10.3390/app15031274 - 26 Jan 2025
Viewed by 402
Abstract
Ternary lithium-ion batteries (LIBs) have the advantages of high energy density and high charging efficiency, and they are the preferred energy source for long-life new energy vehicles. However, when thermal runaway (TR) occurs in the ternary LIB, an open flame is easily produced. [...] Read more.
Ternary lithium-ion batteries (LIBs) have the advantages of high energy density and high charging efficiency, and they are the preferred energy source for long-life new energy vehicles. However, when thermal runaway (TR) occurs in the ternary LIB, an open flame is easily produced. The burning phenomenon is intense, and the rapid of TR propagation is high; consequently, vehicle-level fire accidents are easily induced. These accidents have become the biggest obstacle restricting the batteries’ development. Therefore, this study investigates the TR behavior of ternary LIBs at the cell and module levels. The addition of an insulation layer alone, including ceramic nano fibers, glass fiber aerogel, and phase-change composite materials, cannot prevent TR propagation. To completely block the TR propagation, we developed a safety prevention strategy, combining the phase-change composite materials with a commercial liquid cooling plate. This approach provides a three-level TR protection mechanism that includes heat absorption, heat conduction, and heat insulation. The use of a 2 mm thick phase change composite material combined with a liquid cooling plate effectively prevents the TR propagation between60 Ah ternary LIBs with 100%SOCs.. The front surface temperature of the adjacent cell is maintained near 90 °C, with its maximum temperature consistently stays below 100 °C. This study successfully demonstrates the blockage of TR propagation and offers valuable insights for the thermal safety design of high-specific-energy LIBs; the aim is to improve the overall safety of battery packs in practical applications. Full article
(This article belongs to the Special Issue Current Updates and Key Techniques of Battery Safety)
Show Figures

Figure 1

Figure 1
<p>(<b>a</b>) Accelerating rate calorimeter (ARC); (<b>b</b>) schematic diagram of the single cell arrangement method used in the test; (<b>c</b>) battery image before test; (<b>d</b>) TR propagation test device; (<b>e</b>) schematic diagram of thermocouple arrangement; (<b>f</b>) schematic diagram of the overall principle and arrangement of the experiment.</p>
Full article ">Figure 2
<p>(<b>a</b>) The center temperature of the cell in the ARC experiment; (<b>b</b>) comparison of simulation and experimental results of ARC experiment; (<b>c</b>) battery module TR propagation process; (<b>d</b>) TR temperature of battery module with different insulation layers; (<b>e</b>) comparison of simulation and experimental results of TR propagation experiment; (<b>f</b>) the dynamic image of TR simulation.</p>
Full article ">Figure 3
<p>(<b>a</b>) Cell-to-cell TR propagation time; (<b>b</b>) TR temperature rise diagram of battery module using nano-ceramic fiber insulation layer; (<b>c</b>) TR temperature rise diagram of battery module using glass aerogel insulation layer; (<b>d</b>) TR temperature rise diagram of battery module using phase change insulation layer; (<b>e</b>) TR propagation phenomenon using different insulation layers; (<b>f</b>) maximum temperature at each measuring point.</p>
Full article ">Figure 4
<p>(<b>a</b>) The physical images of different thermal insulation materials; (<b>b</b>) the SEM images of the three materials; (<b>c</b>) the temperature–time relationship of thermal diffusion of different thermal insulation materials.</p>
Full article ">Figure 5
<p>(<b>a</b>) Comparison of TR blocking experiments with only phase change composites and liquid-cooled plates combined with phase change composites; (<b>b</b>) the temperature characteristics of the TR propagation blocking experiment; (<b>c</b>) maximum temperature characteristic of the TR propagation blocking experiment and the comparison with the previous experiments.</p>
Full article ">
37 pages, 1826 KiB  
Review
Review: Overview of Organic Cathode Materials in Lithium-Ion Batteries and Supercapacitors
by Andekuba Andezai and Jude O. Iroh
Energies 2025, 18(3), 582; https://doi.org/10.3390/en18030582 - 26 Jan 2025
Viewed by 312
Abstract
Organic materials have emerged as promising candidates for cathode materials in lithium-ion batteries and supercapacitors, offering unique properties and advantages over traditional inorganic counterparts. This review investigates the use of organic compounds as cathode materials in energy storage devices, focusing on their application [...] Read more.
Organic materials have emerged as promising candidates for cathode materials in lithium-ion batteries and supercapacitors, offering unique properties and advantages over traditional inorganic counterparts. This review investigates the use of organic compounds as cathode materials in energy storage devices, focusing on their application in lithium-ion batteries and supercapacitors. The review covers various types of organic materials, organosulfur compounds, organic free radical compounds, organic carbonyl compounds, conducting polymers, and imine compounds. The advantages, challenges, and ongoing developments in this area are examined and the potential of organic cathode materials to achieve higher energy density, improved cycling stability, and environmental sustainability is highlighted. The comprehensive analysis of organic cathode materials provides insights into their electrochemical performance, electrode reaction mechanisms, and design strategies such as molecular structure modification, hybridization with inorganic components, porous architectures, conductive additives, electrolyte optimization, binder selection, and electrode architecture to improve their efficiency and performance. In addition, future research in the field of organic cathode materials should focus on addressing current limitations such as low energy density, cycling stability, poor discharge capability, potential safety concerns and improving their performance. To do this, it will be necessary to improve structural stability, conductivity, cycle life, and capacity fading, explore new redox-active organic compounds, and pave the way for the next generation of high-performance energy storage devices. For organic cathode materials to be commercially viable, it is also essential to develop scalable and economical manufacturing processes. Full article
33 pages, 2675 KiB  
Article
Some Critical Thinking on Electric Vehicle Battery Reliability: From Enhancement to Optimization
by Jing Lin and Christofer Silfvenius
Batteries 2025, 11(2), 48; https://doi.org/10.3390/batteries11020048 - 25 Jan 2025
Viewed by 558
Abstract
Electric vehicle (EV) batteries play a crucial role in sustainable transportation, with reliability being pivotal to their performance, longevity, and environmental impact. This study explores battery reliability from micro (individual user), meso (industry), and macro (societal) perspectives, emphasizing interconnected factors and challenges across [...] Read more.
Electric vehicle (EV) batteries play a crucial role in sustainable transportation, with reliability being pivotal to their performance, longevity, and environmental impact. This study explores battery reliability from micro (individual user), meso (industry), and macro (societal) perspectives, emphasizing interconnected factors and challenges across the lifecycle. A novel lifecycle framework is proposed, introducing the concept of “Zero-Life” reliability to expand traditional evaluation methods. By integrating the reliability ecosystem with a dynamic system approach, this research offers comprehensive insights into the optimization of EV battery systems. Furthermore, an expansive Social–Industrial Large Knowledge Model (S-ILKM) is presented, bridging micro- and macro-level insights to enhance reliability across lifecycle stages. The findings provide a systematic pathway to advance EV battery reliability, aligning with global sustainability objectives and fostering innovation in sustainable mobility. Full article
(This article belongs to the Collection Advances in Battery Energy Storage and Applications)
Show Figures

Graphical abstract

Graphical abstract
Full article ">Figure 1
<p>The reliability ecosystem of EV batteries.</p>
Full article ">Figure 2
<p>General asset reliability lifecycle framework.</p>
Full article ">Figure 3
<p>EV battery reliability lifecycle framework with 1st, 2nd, and 3rd life added.</p>
Full article ">Figure 4
<p>EV battery reliability lifecycle framework with zero<sup>th</sup>, 1st, 2nd, and 3rd life added.</p>
Full article ">Figure 5
<p>EV battery reliability lifecycle framework including more details of a “Zero”-Life stage.</p>
Full article ">Figure 6
<p>Operational reliability: lifecycle framework of EV batteries.</p>
Full article ">Figure 7
<p>The reliability system of EV batteries: from point to System of Systems (SoS).</p>
Full article ">Figure 8
<p>Hyperplane projection and intrinsic optimization.</p>
Full article ">Figure 9
<p>Impacts of reliability inconsistency in EV batteries.</p>
Full article ">Figure 10
<p>An expansive Social–Industrial Large Knowledge Model (S-ILKM) [<a href="#B14-batteries-11-00048" class="html-bibr">14</a>].</p>
Full article ">
13 pages, 5950 KiB  
Article
Nickel Stabilized Si/Ni/Si/Ni Multi-Layer Thin-Film Anode for Long-Cycling-Life Lithium-Ion Battery
by Yonhua Tzeng, Yu-Yang Chiou and Aurelius Ansel Wilendra
Batteries 2025, 11(2), 46; https://doi.org/10.3390/batteries11020046 - 25 Jan 2025
Viewed by 311
Abstract
Silicon-based anodes suffer from the loss of physical integrity due to large volume changes during alloying and de-alloying processes with electrolytes. By integrating electrochemically inert, physically strong, ductile nickel layers with a multi-layered thin-film silicon anode, the long-life cycling of the Si/Ni/Si/Ni anode [...] Read more.
Silicon-based anodes suffer from the loss of physical integrity due to large volume changes during alloying and de-alloying processes with electrolytes. By integrating electrochemically inert, physically strong, ductile nickel layers with a multi-layered thin-film silicon anode, the long-life cycling of the Si/Ni/Si/Ni anode was demonstrated. A capacity retention of 82% after 200 cycles was measured, surpassing the performance of conventional silicon thin-film anodes. This is attributed to the effective suppression of internal local stress induced by nonuniform volume expansion by the nickel layers. These findings offer a promising pathway towards the practical implementation of high-capacity silicon-based anodes in advanced lithium-ion batteries. Full article
Show Figures

Figure 1

Figure 1
<p>Schematic diagram of the fabrication processes for a Si-based anode and a Si/Ni/Si/Ni thin-film anode.</p>
Full article ">Figure 2
<p>XRD analysis of (<b>a</b>) a Si anode and a Si/Ni/Si/Ni thin-film anode; (<b>b</b>) magnified intensity of a Si/Ni/Si/Ni thin-film anode.</p>
Full article ">Figure 3
<p>SEM images of the top view of (<b>a</b>) a Si thin-film anode and (<b>b</b>) a Si/Ni/Si/Ni thin-film anode.</p>
Full article ">Figure 4
<p>CV curve of (<b>a</b>) a Si thin-film anode and (<b>b</b>) a Si/Ni/Si/Ni thin-film anode; charge–discharge curves of different cycling numbers for the (<b>c</b>) Si thin-film anode and (<b>d</b>) the Si/Ni/Si/Ni thin-film anode.</p>
Full article ">Figure 5
<p>(<b>a</b>) Cycle performance of a Si thin-film anode and a Si/Ni/Si/Ni thin-film anode under test current density of 0.05 mA/cm<sup>2</sup>; (<b>b</b>) C-rate performance of a Si thin-film anode and a Si/Ni/Si/Ni thin-film anode.</p>
Full article ">Figure 6
<p>Optical microscope images of (<b>a</b>) an anode made of Si thin film and (<b>b</b>) an anode made of multi-layer Si/Ni/Si/Ni structure after 100 cycles of charge–discharge.</p>
Full article ">Figure 7
<p>SEM cross-sectional images of Si/Ni/Si/Ni thin film anode (<b>a</b>) before and (<b>b</b>) after 100 cycles of discharge and charge operations under 1 mA/cm<sup>2</sup>.</p>
Full article ">Figure 8
<p>SEM images of a Si thin-film anode at (<b>a</b>–<b>c</b>) different magnifications after 200 cycles; SEM images of a Si/Ni/Si/Ni thin-film anode (<b>d</b>,<b>e</b>) displayed after different magnifications; (<b>f</b>) shows a different spot from that shown in (<b>e</b>) after 200 cycles.</p>
Full article ">Figure 9
<p>(<b>a</b>,<b>b</b>) C 1s and (<b>c</b>,<b>d</b>) F 1s X-ray photoelectron spectroscopy (XPS) spectra for two different electrodes after 200 cycles of charge and discharge.</p>
Full article ">Figure 10
<p>(<b>a</b>) The Nyquist plots comparing the impedance spectra of Si and Si/Ni/Si/Ni thin-film anode after 200 cycles; (<b>b</b>) the equivalent circuit model used to fit the impedance data.</p>
Full article ">
16 pages, 4281 KiB  
Article
Estimation of Fuel Cell Power Demand on Commercial Vehicles Based on Improved Multiple Grey Prediction Method Considering Dynamic Time Window
by Yuan Wang, Yingjia Li, Jianshan Lu and Hongbo Zhou
Appl. Sci. 2025, 15(3), 1213; https://doi.org/10.3390/app15031213 - 24 Jan 2025
Viewed by 445
Abstract
A frequently large variation in load conditions is of great impact on the service life of fuel cells during the operation of fuel cell vehicles and further increases the maintenance cost of the system. This study proposed a method of power demand prediction [...] Read more.
A frequently large variation in load conditions is of great impact on the service life of fuel cells during the operation of fuel cell vehicles and further increases the maintenance cost of the system. This study proposed a method of power demand prediction of the proton exchange membrane fuel cell (PEMFC) on vehicles in the actual traffic environment. The hybrid power system topology of fuel cells and power battery on commercial vehicles is selected to build a fuel cell model, and the accuracy of the fuel cell model is verified. An improved multiple grey prediction method is then proposed to predict the power demand during the sampling period of the fuel cell while considering a dynamic time window in the prediction period. Comparisons were made between this proposed model and the other two prediction models as a single-step prediction and multi-step prediction. Data of CHTC-HT and field testing working conditions were used to evaluate these three prediction models in fuel cell power demand. Results showed that the multiple grey method showed a better prediction performance than the other models, indicated by the lowest error value of 16.944% under the CHTC-HT condition, the lowest error value of 2.169% under stable conditions with less variable load and 1.930% under dynamic conditions with frequent load changes in field testing. This study of the demand power prediction can be devoted to pre-tuning the fuel cell system to avoid performance degradation caused by unanticipated power fluctuation. Full article
Show Figures

Figure 1

Figure 1
<p>Structure of fuel cell and power battery.</p>
Full article ">Figure 2
<p>Fuel cell model structure.</p>
Full article ">Figure 3
<p>Process of single-step grey prediction.</p>
Full article ">Figure 4
<p>Process of multi-step grey prediction.</p>
Full article ">Figure 5
<p>Process of multiple grey prediction.</p>
Full article ">Figure 6
<p>Comparison of fuel cell monolithic voltage.</p>
Full article ">Figure 7
<p>Process of model input condition.</p>
Full article ">Figure 8
<p>CHTC-HT working condition.</p>
Full article ">Figure 9
<p>Fuel cell power demand under CHTC-HT condition.</p>
Full article ">Figure 10
<p>Prediction curves of fuel cell power demand with three strategies under CHTC-HT.</p>
Full article ">Figure 11
<p>Truck route map in field testing.</p>
Full article ">Figure 12
<p>Prediction curves of fuel cell power demand with three strategies under Working Condition A in field testing.</p>
Full article ">Figure 13
<p>Prediction curves of fuel cell power demand with three strategies under Working Condition B in field testing.</p>
Full article ">
24 pages, 1927 KiB  
Article
Digital Product Passport Design Supporting the Circular Economy Based on the Asset Administration Shell
by Maximilian Kühn, Michael Baumann, Friedrich Volz and Ljiljana Stojanovic
Sustainability 2025, 17(3), 969; https://doi.org/10.3390/su17030969 - 24 Jan 2025
Viewed by 476
Abstract
This paper investigates the design of a digital product passport (DPP) model based on the asset administration shell (AAS) framework to support the circular economy while ensuring cross-industry applicability. In a circular economy, resources are continuously reused, fostering more sustainable manufacturing. The European [...] Read more.
This paper investigates the design of a digital product passport (DPP) model based on the asset administration shell (AAS) framework to support the circular economy while ensuring cross-industry applicability. In a circular economy, resources are continuously reused, fostering more sustainable manufacturing. The European Commission’s initiatives target this issue, with the DPP playing a critical role in sharing product sustainability information, such as product composition and repairability, throughout its lifecycle. However, a widely applicable DPP approach has yet to be established. This study consolidates existing standards, and scientific literature to develop a data model that aligns with circular economy principles. Using the AAS framework initially developed by the Plattform Industrie 4.0, we mapped the data requirements to submodel templates and addressed gaps in the data needed for real-life implementation. The results demonstrate that the proposed DPP data model is specific enough for practical use cases, such as the upcoming EU battery passport, while remaining flexible enough for application across various industries. The AAS framework’s adaptability and comprehensive data exchange capabilities make it a suitable foundation for developing DPPs that support the transition to a circular economy. Full article
24 pages, 5179 KiB  
Review
Powering Future Advancements and Applications of Battery Energy Storage Systems Across Different Scales
by Zhaoyang Dong, Yuechuan Tao, Shuying Lai, Tianjin Wang and Zhijun Zhang
Energy Storage Appl. 2025, 2(1), 1; https://doi.org/10.3390/esa2010001 - 24 Jan 2025
Viewed by 542
Abstract
Battery Energy Storage Systems (BESSs) are critical in modernizing energy systems, addressing key challenges associated with the variability in renewable energy sources, and enhancing grid stability and resilience. This review explores the diverse applications of BESSs across different scales, from micro-scale appliance-level uses [...] Read more.
Battery Energy Storage Systems (BESSs) are critical in modernizing energy systems, addressing key challenges associated with the variability in renewable energy sources, and enhancing grid stability and resilience. This review explores the diverse applications of BESSs across different scales, from micro-scale appliance-level uses to large-scale utility and grid services, highlighting their adaptability and transformative potential. This study also includes advanced applications such as mobile energy storage, second-life battery utilization, and innovative models like Energy Storage as a Service (ESaaS) and energy storage sharing. Additionally, it discusses the integration of machine learning (ML) and large language models (LLMs), including advanced reinforcement learning (RL) algorithms, to optimize BESS operations and ensure safety through dynamic and data-driven decision-making. By examining current technologies, modeling methods, and future trends, this review provides a comprehensive overview of BESSs as a cornerstone technology for sustainable and efficient energy management, leading to a resilient energy future. Full article
Show Figures

Figure 1

Figure 1
<p>A performance comparison of different battery types based on energy density, power density, efficiency, lifespan, cost, safety, and scalability, highlighting the strengths and limitations of each battery technology.</p>
Full article ">Figure 2
<p>BESS applications across variousscales, illustrating BESS applications from appliance-level and behind-the-meter systems to medium-scale installations for distribution networks and renewable integration, as well as utility-level BESSs for large-scale grid stabilization and transmission support.</p>
Full article ">Figure 3
<p>A MESS application framework, presenting the conceptual framework for MESSs and showcasing their applications across base stations, depots, sub-stations, and SESSs.</p>
Full article ">Figure 4
<p>Second-life BESS applications illustrating the repurposing of EV batteries with an SOH below 80%; the batteries can be reused in commercial, residential, and utility-scale applications with SOH analysis.</p>
Full article ">Figure 5
<p>Energy storage sharing as a type of ESaaS illustrating energy storage sharing among residential users, commercial users, industrial users, and EV charging lots through a centralized communication and sharing market.</p>
Full article ">Figure 6
<p>An AI-based optimization framework for BESSs. The figure illustrates a neural network processing BESS features to output the target analysis and control actions.</p>
Full article ">
21 pages, 7669 KiB  
Review
Material Sustainability of Low-Energy Housing Electric Components: A Systematic Literature Review and Outlook
by Francisco A. Carrasco and Johanna F. May
Sustainability 2025, 17(3), 852; https://doi.org/10.3390/su17030852 - 22 Jan 2025
Viewed by 438
Abstract
As part of the energy transition, near-Zero-Energy-Buildings use electric systems that reduce emissions and consumption. Nevertheless, the increased use of such systems comes with the E-waste challenge. Circular Economy concepts try to make more efficient use of these materials, but sustainable evaluations mainly [...] Read more.
As part of the energy transition, near-Zero-Energy-Buildings use electric systems that reduce emissions and consumption. Nevertheless, the increased use of such systems comes with the E-waste challenge. Circular Economy concepts try to make more efficient use of these materials, but sustainable evaluations mainly focus on energy and emissions. The developed automated text analysis tool quantifies the appearance of circularity concepts in open-access literature about different stages of production, use, and end-of-life for heat pumps, Lithium-Ion batteries, photovoltaic modules, and inverters. The energy focus is corroborated in different amounts depending on the component and stage, and when circularity concepts appear, they are centred on waste and recycling. Numerical variables to model environmental impact available in open-access literature are limited, generalised, or present in a wide range. Access to product environmental specifications should be encouraged to ensure that energy transition is sustainable in all its dimensions. Full article
Show Figures

Figure 1

Figure 1
<p>Wordcloud for “life cycle assessment nZEB”, mostly generic words are identified.</p>
Full article ">Figure 2
<p>Workflow of article processing and manual intervention reduced to the minimum possible.</p>
Full article ">Figure 3
<p>The number of article matches by technology and analysis mode. Lithium batteries have an overall number of papers addressing them, while inverters are the least. End-of-Life is the least frequent analysis mode.</p>
Full article ">Figure 4
<p>LCA index frequency by technology and analysis mode. Heat pumps treat more environmental impact categories, and more often, the opposite happens to inverters. Climate change is the most common impact category.</p>
Full article ">Figure 5
<p>Indicator frequency for extended ‘material’ and ‘energy’ concepts by technology and analysis mode, with group average. The ‘energy’ group is higher than the ‘material’ group by around 4 times, with the exception of Lithium-Ion batteries. Stemmed words marked with *, representing multiple possible endings.</p>
Full article ">Figure 6
<p>Indicator frequency for Circular Economy concepts by technology and analysis mode. Recycling is the most quoted term except in heat pumps. Stemmed words marked with *, representing multiple possible endings.</p>
Full article ">Figure 7
<p>Indicator frequency for extended Circular Economy concepts, ‘waste’, ‘regulation’, and ‘business’ top four more frequent concepts by technology and analysis mode, with the group average. Waste the most quoted concepts across all technologies. Stemmed words marked with *, representing multiple possible endings.</p>
Full article ">Figure 8
<p>Indicator frequency for manufacturing: The top five most frequent concepts by technology and analysis mode, with group average. The ‘energy’ group presents most of the occurrences.</p>
Full article ">Figure 9
<p>Indicator frequency for degradation by technology and analysis mode. Efficiency is the most important topic, especially for heat pumps. Stemmed words marked with *, representing multiple possible endings.</p>
Full article ">Figure 10
<p>Indicator frequency for reliability by technology and analysis mode. ‘Fail’ and ‘lifetime’ are the most common concepts. Stemmed words marked with *, representing multiple possible endings.</p>
Full article ">Figure 11
<p>Indicator frequency for End-of-Life by technology and analysis mode. ‘Recycle’ and ‘waste’ are the most common concepts. Alternative CE EoL modes are not relevant in the literature. Stemmed words marked with *, representing multiple possible endings.</p>
Full article ">
19 pages, 5101 KiB  
Article
Promoting Sustainability in the Recycling of End-of-Life Photovoltaic Panels and Li-Ion Batteries Through LIBS-Assisted Waste Sorting
by Agnieszka Królicka, Anna Maj and Grzegorz Łój
Sustainability 2025, 17(3), 838; https://doi.org/10.3390/su17030838 - 21 Jan 2025
Viewed by 762
Abstract
To promote sustainability and reduce the ecological footprint of recycling processes, this study develops an analytical tool for fast and accurate identification of components in photovoltaic panels (PVs) and Li-Ion battery waste, optimizing material recovery and minimizing resource wastage. The laser-induced breakdown spectroscopy [...] Read more.
To promote sustainability and reduce the ecological footprint of recycling processes, this study develops an analytical tool for fast and accurate identification of components in photovoltaic panels (PVs) and Li-Ion battery waste, optimizing material recovery and minimizing resource wastage. The laser-induced breakdown spectroscopy (LIBS) technique was selected and employed to identify fluoropolymers in photovoltaic back sheets and to determine the thickness of layers containing fluorine. LIBS was also used for Li-Ion batteries to reveal the elemental composition of anode, cathode, and separator materials. The analysis not only revealed all the elements contained in the electrodes but also, in the case of cathode materials, allowed distinguishing a single-component cathode (cathode A containing LiCoO2) from multi-component materials (cathode B containing a mixture of LiMn2O4 and LiNi0.5Mn1.5O4). The results of LIBS analysis were verified using SEM-EDS analysis and XRD examination. Additionally, an indirect method for identifying fluoropolymers (polytetrafluoroethylene (PTFE) or poly(vinylidene fluoride) (PVDF)) employed to prepare dispersions of cathode materials was proposed according to the differences in wettability of both polymers. By enabling efficient material identification and separation, this study advances sustainable recycling practices, supporting circular economy goals in the renewable energy sector. Full article
Show Figures

Figure 1

Figure 1
<p>Microscopic images of the back sheet surface of the photovoltaic panel sample after completing the LIBS spectroscopy studies: (<b>a</b>) View of the nine ablation sites for laser pulses of low (ablation A), medium (ablation B), and high (ablation C) power. The ablation sites where fluorine was detected are marked with yellow circles. Two ablation points formed during stratigraphic studies (6 laser pulses in the same place) are visible next to the sampling areas of ablation A and B. (<b>b</b>–<b>d</b>) Three-dimensional representation of samples after ablation with low (<b>b</b>), medium (<b>c</b>), and high (<b>d</b>) power of laser pulses. For ablation C presented in panels (<b>a</b>,<b>d</b>), the craters were numbered 1, 2, and 3 for identification.</p>
Full article ">Figure 2
<p>(<b>a</b>,<b>b</b>) SEM images of the back sheet surface of the photovoltaic panel and the relation of their microstructure to (<b>a</b>) the depth of ablation craters (ablation C) and (<b>b</b>) the diameter of ablation craters A–C. (<b>c</b>) Result of the EDS analysis conducted for the back sheet sample of the photovoltaic panel.</p>
Full article ">Figure 2 Cont.
<p>(<b>a</b>,<b>b</b>) SEM images of the back sheet surface of the photovoltaic panel and the relation of their microstructure to (<b>a</b>) the depth of ablation craters (ablation C) and (<b>b</b>) the diameter of ablation craters A–C. (<b>c</b>) Result of the EDS analysis conducted for the back sheet sample of the photovoltaic panel.</p>
Full article ">Figure 3
<p>(<b>a</b>) SEM microscopic image of the surface of anode A. (<b>b</b>) The results of the EDS analysis of anode A. (<b>c</b>) Diffractograms of anode A and B with identified components (1—graphite, 2—copper).</p>
Full article ">Figure 3 Cont.
<p>(<b>a</b>) SEM microscopic image of the surface of anode A. (<b>b</b>) The results of the EDS analysis of anode A. (<b>c</b>) Diffractograms of anode A and B with identified components (1—graphite, 2—copper).</p>
Full article ">Figure 4
<p>Microscopic image of the anode surface with marked points where LIBS spectroscopy was performed, along with information on the detected elements. Inset: Microscopic image of the surface of the anode after three successive ablations conducted at the same point. The boundaries of the ablation craters are highlighted in yellow.</p>
Full article ">Figure 5
<p>(<b>a</b>) The results of contact angle measurements for separators obtained from batteries A and B, as well as the PTFE block sample. (<b>b</b>,<b>c</b>) LIBS analysis results for the separator A (<b>a</b>) and the Teflon block (<b>c</b>).</p>
Full article ">Figure 5 Cont.
<p>(<b>a</b>) The results of contact angle measurements for separators obtained from batteries A and B, as well as the PTFE block sample. (<b>b</b>,<b>c</b>) LIBS analysis results for the separator A (<b>a</b>) and the Teflon block (<b>c</b>).</p>
Full article ">Figure 6
<p>(<b>a</b>) SEM microscopic image of the surface of cathode B with four regions affected by corrosion initiated by contact of the cathode with water. (<b>b</b>) The results of the EDS analysis conducted at point 1, located in the middle of the area affected by corrosion. (<b>c</b>,<b>d</b>) SEM images of cathode A (<b>c</b>) and cathode B (<b>d</b>). (<b>e</b>–<b>h</b>) Contact angle measurements of cathode A (<b>e</b>,<b>g</b>) and cathode B (<b>f</b>,<b>h</b>) before (<b>e</b>,<b>f</b>) and after (<b>g</b>,<b>h</b>) cleaning of cathodes with DMC followed by sonication in a mixture of water and detergent.</p>
Full article ">Figure 6 Cont.
<p>(<b>a</b>) SEM microscopic image of the surface of cathode B with four regions affected by corrosion initiated by contact of the cathode with water. (<b>b</b>) The results of the EDS analysis conducted at point 1, located in the middle of the area affected by corrosion. (<b>c</b>,<b>d</b>) SEM images of cathode A (<b>c</b>) and cathode B (<b>d</b>). (<b>e</b>–<b>h</b>) Contact angle measurements of cathode A (<b>e</b>,<b>g</b>) and cathode B (<b>f</b>,<b>h</b>) before (<b>e</b>,<b>f</b>) and after (<b>g</b>,<b>h</b>) cleaning of cathodes with DMC followed by sonication in a mixture of water and detergent.</p>
Full article ">Figure 7
<p>(<b>a</b>) Microscopic image of the surface of cathode A after seven successive ablations conducted at the same point. The boundaries of the ablation craters are highlighted in yellow. (<b>b</b>) LIBS spectrum recorded during the analysis of cathode A. (<b>c</b>,<b>d</b>) Results of the LIBS analysis conducted for cathode A (<b>c</b>) and cathode B (<b>d</b>). The red points in <a href="#sustainability-17-00838-f007" class="html-fig">Figure 7</a>c indicate the calculated elemental composition of pure LCO.</p>
Full article ">Figure 8
<p>(<b>a</b>,<b>b</b>) SEM images of cathode A (<b>a</b>) and cathode B (<b>b</b>). (<b>c</b>) Results of the EDS analysis conducted at points 1 and 2 on the surface of the cathodes, with components identified as LCO (cathode A) and LMO or LNMO (cathode B). (<b>d</b>) Diffractograms of cathode A and B with identified components. JCPDS cards used for identification: LCO (PDF #75-0532), LMO (PDF #35-0782), LNMO (PDF #80-2162).</p>
Full article ">Figure 8 Cont.
<p>(<b>a</b>,<b>b</b>) SEM images of cathode A (<b>a</b>) and cathode B (<b>b</b>). (<b>c</b>) Results of the EDS analysis conducted at points 1 and 2 on the surface of the cathodes, with components identified as LCO (cathode A) and LMO or LNMO (cathode B). (<b>d</b>) Diffractograms of cathode A and B with identified components. JCPDS cards used for identification: LCO (PDF #75-0532), LMO (PDF #35-0782), LNMO (PDF #80-2162).</p>
Full article ">
13 pages, 2747 KiB  
Article
Improving Electrochemical Performance of Ultrahigh-Loading Cathodes via the Addition of Multi-Walled Carbon Nanotubes
by Chan Ju Choi, Tae Heon Kim, Hyun Woo Kim, Do Man Jeon and Jinhyup Han
Nanomaterials 2025, 15(3), 156; https://doi.org/10.3390/nano15030156 - 21 Jan 2025
Viewed by 442
Abstract
Achieving high energy densities in lithium-ion batteries requires advancements in electrode materials and design. This study investigated the incorporation of multi-walled carbon nanotubes (MWCNTs) with high commercial viability as conductive additives into two types of high-nickel cathode materials, LiNi0.8Co0.1Mn [...] Read more.
Achieving high energy densities in lithium-ion batteries requires advancements in electrode materials and design. This study investigated the incorporation of multi-walled carbon nanotubes (MWCNTs) with high commercial viability as conductive additives into two types of high-nickel cathode materials, LiNi0.8Co0.1Mn0.1O2 and LiNi0.92Co0.07Mn0.01O2. To ensure a uniform distribution within the electrodes, MWCNTs were uniformly dispersed in the solvent using ultrasonication, the most effective and straightforward dispersion method. This enhancement improved both electronic and ionic conductivity, facilitating the formation of an efficient electron transfer network. Unlike the cells using only carbon black, the electrodes with MWCNTs exhibited lower internal resistances, facilitating higher lithium-ion diffusion. The cells with MWCNTs exhibited a capacity retention of 89.5% over their cycle life, and the cells with 2 wt% MWCNTs exhibited a superior rate capability at a high current density of 1 C. This study highlights that incorporating well-dispersed MWCNTs effectively enhances the electrochemical performance of ultrahigh-loading cathodes in lithium-ion batteries (LIBs), providing valuable insights into electrode design. Full article
Show Figures

Figure 1

Figure 1
<p>Comparison of various types of conductive additives for electrode fabrication and their costs per gram.</p>
Full article ">Figure 2
<p>SEM image of (<b>a</b>) commercial LiNi<sub>0.8</sub>Co<sub>0.1</sub>Mn<sub>0.1</sub>O<sub>2</sub> (NCM811) cathode and (<b>b</b>) commercial Ni92% cathode. (<b>c</b>) XRD patterns of high-Ni cathodes (NCM811, Ni92%).</p>
Full article ">Figure 3
<p>(<b>a</b>) Schematic of ultrasonication for the preparation of MWCNT dispersion solution. (<b>b</b>) Schematic comparison of internal Li<sup>+</sup> and electron transport behavior of electrodes with only carbon black and inserted MWCNTs.</p>
Full article ">Figure 4
<p>(<b>a</b>) SEM image of internal structure of pristine NCM811 electrode; inset: spherical active material particles surrounded by carbon black. (<b>b</b>) SEM image of internal structure of NCM811 electrode incorporated with 2 wt% MWCNTs; inset: spherical active material particles in conductive additive containing MWCNTs.</p>
Full article ">Figure 5
<p>(<b>a</b>) Initial voltage profile at 0.1 C between 2.8 and 4.3 V vs. Li using NCM811 and (<b>b</b>) Ni92% cathode. EIS profiles of the Li half-cell with 0, 1, and 2 wt% MWCNTs using the (<b>c</b>) NCM811 and (<b>d</b>) Ni92% cathode. (<b>e</b>) Cycling performances of electrodes prepared with ratio of 88:2:10 (active material:conductive additive:binder material) in Li half-cell at 0.33 C (first three cycles at 0.1 C) between 2.8 and 4.3 V vs. Li.</p>
Full article ">Figure 6
<p>(<b>a</b>) Rate capability of the Li half-cell with NCM811 from 0.1 to 1 C between 2.8 and 4.3 V. (<b>b</b>) Discharge capacity curves of pristine electrode at various current rates and (<b>c</b>) discharge capacity curves of NCM811 containing 2 wt% MWCNTs. (<b>d</b>) Rate capability of Li half-cell with Ni92% from 0.1 to 1 C between 2.8 and 4.3 V. (<b>e</b>) Discharge capacity curves of pristine electrode at various current rates and (<b>f</b>) discharge capacity curves of Ni92% containing 2 wt% MWCNTs.</p>
Full article ">
28 pages, 9017 KiB  
Article
A Comparative Analysis of Lithium-Ion Batteries Using a Proposed Electrothermal Model Based on Numerical Simulation
by Mohammad Assi and Mohammed Amer
World Electr. Veh. J. 2025, 16(2), 60; https://doi.org/10.3390/wevj16020060 - 21 Jan 2025
Viewed by 531
Abstract
It is necessary to maintain safe, efficient, and compatible energy storage systems to meet the high demand for electric vehicles (EVs). Lithium manganese nickel cobalt (NMC) and lithium ferro phosphate (LFP) batteries are the most commonly used lithium batteries in EVs. It is [...] Read more.
It is necessary to maintain safe, efficient, and compatible energy storage systems to meet the high demand for electric vehicles (EVs). Lithium manganese nickel cobalt (NMC) and lithium ferro phosphate (LFP) batteries are the most commonly used lithium batteries in EVs. It is imperative to note that batteries are classified according to their electrochemical performance. A number of factors play a crucial role in determining how efficiently batteries can be used. These factors include the cell temperature, energy density, self-discharge, current limits, aging, and performance measurements. This paper offers a proposed electrothermal model for comparison between LFP and NMC batteries. This model demonstrates the different behaviors according to their application in EVs. This is carried out through studies of state of charge (SoC), state of health (SoH), thermal runaway, self-discharge, and remaining useful life (RUL) in EVs. According to numerical analysis, this paper examines how these different types of batteries behave in EVs to assist in the selection of the most suitable battery taking into account the operating temperature and discharge current using a helpful thermoelectric model reflecting battery safety and life span effectively. Using MATLAB Simulink, the data selected in the electrothermal model are combined from a number of references that are incorporated into lookup tables that affect the change in values in the electrothermal model. The cells are implemented in an EV system using a current test to examine the measured current that goes in and comes out of the battery cells during charging and discharging processes taking into account motoring and regenerative braking for a specified drive cycle time and a number of discharging cycles. It was found that LFP batteries have better stability for open circuit voltages of 3.34 volts over a wide range of conducted temperatures. NMC batteries, on the other hand, exhibit some open circuit voltage variation of 0.053 volts over the temperature range used. Furthermore, the self-discharging current of LFP batteries was about 12 times lower than that of NMC batteries. Compared to LFP batteries, NMC batteries have a higher energy density per unit of mass of 150%, which reflects their greater discharge range. As a result of temperature effects, it has been revealed that LFP batteries are about two times more stable during discharging than NMC batteries, particularly at higher temperatures, such as 45 degrees. Full article
(This article belongs to the Special Issue Thermal Management System for Battery Electric Vehicle)
Show Figures

Figure 1

Figure 1
<p>Spider figures of LFP and NMC batteries characteristics. The green line is related to the LFP battery cell while the blue one concerns the NMC battery cell.</p>
Full article ">Figure 2
<p>Proposed electrothermal block diagram.</p>
Full article ">Figure 3
<p>Thermal/electric coupling relationship.</p>
Full article ">Figure 4
<p>Proposed electrical model.</p>
Full article ">Figure 5
<p>Entropic coefficient vs. SoC for LFP battery under different temperatures.</p>
Full article ">Figure 6
<p>Entropic coefficient vs. SoC for NMC battery under different temperatures.</p>
Full article ">Figure 7
<p>Research methodology.</p>
Full article ">Figure 8
<p>A schematic diagram of parameter estimation.</p>
Full article ">Figure 9
<p>LFP OCV vs. SoC under different temperatures.</p>
Full article ">Figure 10
<p>NMC OCV vs. SoC under different temperatures.</p>
Full article ">Figure 11
<p>Self-discharge resistance for (<b>a</b>) LFP and (<b>b</b>) NMC batteries.</p>
Full article ">Figure 12
<p>LFP estimated parameters vs. SoC under different current rates and a 0-degree temperature as surface plots. (<b>a</b>) R<sub>s</sub>; (<b>b</b>) R<sub>1</sub>; (<b>c</b>) R<sub>2</sub>; (<b>d</b>) C<sub>1</sub>; (<b>e</b>) C<sub>2</sub>.</p>
Full article ">Figure 13
<p>Parameters vs. SoC under different current rates and a 22.5-degree temperature as surface plots. (<b>a</b>) R<sub>s</sub>; (<b>b</b>) R<sub>1</sub>; (<b>c</b>) R<sub>2</sub>; (<b>d</b>) C<sub>1</sub>; (<b>e</b>) C<sub>2</sub>.</p>
Full article ">Figure 14
<p>LFP estimated parameters vs. SoC under different current rates and a 45-degree temperature as surface plots. (<b>a</b>) R<sub>s</sub>; (<b>b</b>) R<sub>1</sub>; (<b>c</b>) R<sub>2</sub>; (<b>d</b>) C<sub>1</sub>; (<b>e</b>) C<sub>2</sub>.</p>
Full article ">Figure 15
<p>NMC estimated parameters vs. SoC under different current rates and a 0-degree temperature as surface plots. (<b>a</b>) R<sub>s</sub>; (<b>b</b>) R<sub>1</sub>; (<b>c</b>) R<sub>2</sub>; (<b>d</b>) C<sub>1</sub>; (<b>e</b>) C<sub>2</sub>.</p>
Full article ">Figure 16
<p>NMC estimated parameters vs. SoC under different current rates and a 22.5-degree temperature as surface plots. (<b>a</b>) R<sub>s</sub>; (<b>b</b>) R<sub>1</sub>; (<b>c</b>) R<sub>2</sub>; (<b>d</b>) C<sub>1</sub>; (<b>e</b>) C<sub>2</sub>.</p>
Full article ">Figure 17
<p>NMC estimated parameters vs. SoC under different current rates and a 45-degree temperature as surface plots. (<b>a</b>) R<sub>s</sub>; (<b>b</b>) R<sub>1</sub>; (<b>c</b>) R<sub>2</sub>; (<b>d</b>) C<sub>1</sub>; (<b>e</b>) C<sub>2</sub>.</p>
Full article ">Figure 18
<p>Overall simulation model of the battery system for LFP and NMC.</p>
Full article ">Figure 19
<p>Equivalent resistor test results. The figure as managed under 0, 22.5, and 45 degrees for (<b>a</b>) LFP and (<b>b</b>) NMC for the current, SoC, terminal voltage, leakage current, cell temperature and the entropic coefficient.</p>
Full article ">Figure 19 Cont.
<p>Equivalent resistor test results. The figure as managed under 0, 22.5, and 45 degrees for (<b>a</b>) LFP and (<b>b</b>) NMC for the current, SoC, terminal voltage, leakage current, cell temperature and the entropic coefficient.</p>
Full article ">Figure 20
<p>Random discharge current managed at 0, 22.5, and 45 degrees for (<b>a</b>) LFP and (<b>b</b>) NMC for the current, SoC, terminal voltage, leakage current, cell temperature, and the entropic coefficient.</p>
Full article ">Figure 21
<p>HPPC test at a constant discharge current rate of 50 amperes and ambient temperatures of 0, 22.5, and 45 degrees for (<b>a</b>) LFP and (<b>b</b>) NMC at a discharge current pulse time of 0.5 s with a duty cycle of 50% for the current, SoC, terminal voltage, leakage current, cell temperature and the entropic coefficient.</p>
Full article ">Figure 22
<p>HPPC test at variable discharge current rates of maximum magnitudes equal to 25, 40, and 50 amperes with a variable increasable linear ambient temperature of a slope of 5 degrees per second. The time period for the discharging current pulse is 0.5 s with a duty cycle of 50% for (<b>a</b>) LFP and (<b>b</b>) NMC results.</p>
Full article ">
Back to TopTop