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ZA200507285B - Submerged entry nozzle with dynamic stabilization - Google Patents

Submerged entry nozzle with dynamic stabilization Download PDF

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Publication number
ZA200507285B
ZA200507285B ZA200507285A ZA200507285A ZA200507285B ZA 200507285 B ZA200507285 B ZA 200507285B ZA 200507285 A ZA200507285 A ZA 200507285A ZA 200507285 A ZA200507285 A ZA 200507285A ZA 200507285 B ZA200507285 B ZA 200507285B
Authority
ZA
South Africa
Prior art keywords
pour tube
exit port
edge
stream
upstream
Prior art date
Application number
ZA200507285A
Inventor
Xu Dong
Heaslip Lawrence
Richaud Johan
Dorricott James
Original Assignee
Vesuvius Crucible Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Vesuvius Crucible Co filed Critical Vesuvius Crucible Co
Publication of ZA200507285B publication Critical patent/ZA200507285B/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D41/00Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like
    • B22D41/50Pouring-nozzles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/10Supplying or treating molten metal
    • B22D11/103Distributing the molten metal, e.g. using runners, floats, distributors
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/16Controlling or regulating processes or operations
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D37/00Controlling or regulating the pouring of molten metal from a casting melt-holding vessel

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Casting Support Devices, Ladles, And Melt Control Thereby (AREA)
  • Continuous Casting (AREA)
  • Molds, Cores, And Manufacturing Methods Thereof (AREA)
  • Jet Pumps And Other Pumps (AREA)
  • Valves And Accessory Devices For Braking Systems (AREA)
  • Chair Legs, Seat Parts, And Backrests (AREA)
  • Nozzles (AREA)

Abstract

The present invention relates to a pour tube for casting molten metal. The pour tube is adapted to reduce turbulence and mold disturbances, thereby producing a more stable, uniform outflow. The pour tube includes an exit port with at least one tongue to provide at least two slots on either side of the tongue. The slots generate counter-rotating flows, which result in a more diffusive and more homogeneous outflow. Advantageously, such an outflow can reduce detrimental asymmetry and alumina clogging in the pour tube.

Description

Submerged Entry Nozzle with Dynamic Stabilization
FIELD OK THE INVENTION
Thais invention relates generally to a refractory article and, moxe particularly, to a refractory pour tube for use in the transfer of molten metal in a continuous casting operation.
BACKGROUND
Imm. the continuous casting of metal, particularly steel, a stream of molten metal is typical ®y transferred via a refractory pour tube from a first metallurgical vessel into asecond metallurgical vessel or mold. Such tubes are commonly referred to as nozzles oer shrouds and possess a bore adapted to transfer molten metal. Pour tubes include s—ubmerged-entry nozzles (SEN) or submerged-entry shrouds (SES), which discharges molten metal below the liquid surface of a receiving vesse=1 or mold.
Liquid metal is discharged from the downstream end of the bore through one or more «outlet ports. One important function of a pour tube is to discharge the molten metal in a smooth and steady manner without interruption or disruption. A smooth, steady discharge facilitates processing and can improve the quality of the finished product. A second important function of a pour tube is to establish proper dynamic conditions within the liquid metal in the receiving vessel or mold in_ order to facilitate further processing. Producing proper dynamic conditions may require the pour tube to posse ss a plurality of exit ports that are arranged so as to cause the stream of molten rmetal to be tumed in one or more directions upon discharge from the tube.
Er actors, which can disrupt a smooth and steady discharge, imclude both physicall and dynamic conditions that result in asymmetrical flow behavior of the molten metal in the bore and in the exit ports. Asymmetries in the etal flow velocit=y distribution and streamlines can result from, for example, (2) an ineffective design of the bore and ports, (b) the presence of upstream flow-rate control devices, and (c)» the non-uniform build-up of clogging material within the bore and ports.
Even im the absence of these factors, turbulent flow in the bore may still cause the develo pment of dynamic flow asymmetries. For example, while flowing through a bore, am molten metal stream may develop higher fluid velocity near the centerline of the bomre than along the sides of the bore, or lower velocity on one side of the centerline as compared to the opposite side, or higher fluid velocity off the centerline.
Such clisparate velocities can cause pulsing and excessive turbulence upon exiting the bore, thereby complicating processing and decreasing the quality o=f the finished product. Throttling devices, such as stopper rods or slide-gate valv-es, can partially obstrnk.ct the entrance to the bore, and cause the steam of molten me=tal to enter the bore off the centerline. The stream can flow preferentially down ome side of the bore, and exit asymmetrically or non-uniformly from the pour tube causing excessive surgimg and turbulence in a mold. Pulsing, surging, turbulence andl asymmetry of the discharged flow are aggravated by port arrangements that cause the stream to turn before: being discharged from the tube. Asymmetries in the streanming flow appro aching an exit port can induce unstable spinning and swirling of the turned flow ast iss discharged through the ports causing instability of the dischwarge direction, instabyility of the pattern of flow induced within the receiving vessel, and thus undessirable dynamic conditions in the receiving vessel.
Precipitates or non-metallic build-ups may also clog or res€rict the bore so as to disrupt steady discharge of molten metal from the tube. In molt=en steel,
precipitates and non-metallic build-ups consist primarily of alumina and other high melting point impurities. Alumina deposits can lead. to restrictions and clogging that can stop or substantially impede the smooth and steady flow of liquid steel.
Asymmetrical non-uniform metal flow can lead to the presence of preferential sites for clogging deposits and can further exacerbate flowv non-uniformity. Tubes may be unclogged using an oxygen lance; however, lancing disrupts the casting process, reduces refractory life, and decreases casting efficiemcy and the quality of the steel produced. Total or substantial blockage of the bore by precipitates decreases the expected life of the pour tube and is very costly and time-consuming to steel producers.
Prior art attempts to improve flow include both chemical and mechanical means. For example, flow may be improved by reducing alumina precipitation and subsequent clogging. Prior art has injected gas to pmressurize the pour tube and reduce alumina clogging. Unfortunately, gas injection requires large volumes of gas, complicated refractory designs, and is not always an effective solution. Gas may also dissolve or become entrapped within the metal caus-ing problems in metal quality including pinhole or porosity defects in the steel. A lternatively or in combination with gas injection, prior art has lined the bore with refractory compositions that are claimed to resist alumina buildup. Compositions in<lude lower melting point refractories, such as Ca0-MgO-Al, Os eutectics, calecium zirconate and calcium silicide, that slough off as alumina deposits on the surface. These compositions tend to crack at high temperature, and, during casting, they may de-hydrate and dissipate.
For these reasons, their useful life is limited. Other surface compositions that claim to inhibit alumina deposition include refractories containing SiAION-graphite, metal diborides, boron nitrides, aluminum nitride, and carbon-free compositions. Such refractories can be expensive, impractical, and ma nufacturing can be both hazardous and time consuming,
Mechanical designs for improving flow include U.S. Pat. No. 5,785,880 to Heaslip et al., which teaches a pour tube having a diffusing geometry that smoothly delivers a stream of molten metal to a mold. Alternative designs include EP 0 765 702 B1, which describes a perforated obstacle insdde the bore that deflects the stream from a preferred trajectory. Both references attenpt to control the introduction of molten metal into a mold by mechanically manipualating the stream of molten metal.
Neither describes alumina clogging or the reductieon of alumina clogging.
Prior art also includes designs that claim teo improve flow by reducing alumina deposition in the bore. These designs include pouar tubes with both conical and “stepped” bores. U.S. Pat. No. 4,566,614 to Fryk endahl teaches an inert gas-injection nozzle having a conical bore intended to reduce ‘““ypulsations” in the gas flow.
Smoother gas flow into the bore is said to reduce clogging. “Stepped” designs include pour tubes that have discontinuous changees in bore diameter. Stepped designs also include pour tubes having a spiral bosre. JP Kokai 61-72361 is illustrative of stepped pour tubes, and describes a pour tube having a bore with at least one convex or concave section that generates turbwulent flow in the molten metal.
Turbulent flow, as contrasted with laminar flow, &s described as reducing alumina clogging. U.S. Pat. No. 5,328,064 to Nanbo et al teaches a bore having a plurality of concave sections separated by steps having a consstant diameter, d. Each section has a diameter greater than d, and preferably the diameters of the sections decrease along the direction of flow. The steps are described a s generating turbulence that reduces alumina clogging.
US 6425505 to Heaslip teaches a pour tube comprising a plurality of fluidly connected sections that improve the flow of molten metal through the bore. The sections reduce asymmetric flow of the molten metal stream and the likelihood of precipitates clogging the bore. Each section comprises a converging portion and a diverging portion. The converging portion deflects the stream toward the center of the bore, while the diverging portion diffuses the stream. The combination of converging and diverging elements produce a smore symmetrical flow in the pour tube.
Prior art attempts to control the flow off molten metal within the bore have done little to control unsteady flow from the exit ports of the pour tube. The exit ports induce unstable flow patterns in the outfJow stream. Non-steady flow from the pour tube into a mold can increase meniscus turbulence and waving. Such flow can also cause the outflow stream to wander in the mold and can bias the flow pattern in the mold. Further, unstable outflow can cause alumina clogging in the lower regions of the pour tube, including the well bottom of" the tube and the lower corners of the ports. Clogging will typically impart an asynnmetrical outflow from the pour tube.
A need persists for a refractory pour teibe that produces a stable outflow and reduces meniscus turbulence, waving, asymmetrical flow patterns, and alumina clogging. Ideally, such a tube would also improve the flow of molten metal into a casting mold and improve the properties of time cast metal.
SUMMARY OF THE INVENTION
The present invention relates to a pout tube for use in the casting of molten metal. The pour tube includes at least one exit port amd, relative to prior art, provides a more stable, uniform outflow of molten metal throumgh and from the exit port.
Improved outflow reduces meniscus turbulence and waving, reduces alumina clogging, and promotes symmetrical outflow. These benefits can result in an improved finished product.
In a broad aspect, the article comprises a pou-r tube having an exit port shape that reduces flow instability, thereby producing a ste adier outflow. This shape reduces the unstable back-and-forth spinning flow pattern that is common in outflow streams from a pour tube, This flow pattern is described as at least partially responsible for mold flow instabilities and poor quaRity castings.
In one aspect, the invention includes an exit port that stabilizes and controls spinning or rotating of the flow as the flow passes tkarough an outlet port and discharges into the mold. Large-scale spinning whe=reby the circumference of the rotating flow approaches the width or height of an o-utlet port is opposed and thereby reduced. Unstable and uncontrolled large-scale spirning of the discharge flow is believed to cause more wandering and instability of the flow pattern generated in the mold or receiving vessel. The exit port includes a pslurality of slots that produce consistent counter-rotating flows in the molten metzal and that oppose large-scale spinning of the flow in a single direction or large-scale flow spinning that oscillates from one direction to the opposite direction. Stable= counter-rotating flows within the outflow from the tube provide a more diffusive, hormogeneous, and less turbulent discharge of molten metal and thereby provide a more consistent flow pattern in the receiving vessel.
"The outflow from a pour tube may form a portion of an upper circulation loop within amold. The upper circulation loop is proximate to the upper surface of the mold and affects, for example, top surface waving and meniscus turbulence. The outflow from an exit port of the present invention can direct more molten metal to the surface of the mold without causing excessive meniscus turbulence or mold level fluctuztion. Thermal distribution within the mold may also be improved. The overall flow pattern within the mold becomes more stable.
In one embodiment, the exit port includes a tongue on its downstream edge.
The tongue, and the downstream edge define slots in the lower corners of the exit port. The presence of these slots opposes large-scale spinning of the dischargse flow and promotes the formation of small-scale counter-rotating flows within the outflow from the tube. An exit port comprising a tongue alters the pressure and flow chara cteristics within an exit port and within the outlet region of the pour tub €, so that alumina clogging and asymmetric flow is reduced.
In a second embodiment, the exit port includes a tongue on its upstream edge.
The tongue, and the upstream edge define slots in the upper corners of the exit port.
The presence of these slots opposes large-scale flow spinning within the outflow.
Large scale spinning is undesirable as such spinning is inherently unstable ard genexally exhibits occasional switching of direction, providing inconsistent direction of discharge and unstable dynamic behavior in the discharge flow and subsequently in the mnold.
In a third embodiment, the exit port includes tongues on both the upstream and dowmstream edges of the port. An exit port comprising both upstream and downstream tongues promotes the formation of steady counter-rotating flows within the outflow with excellent symmetry and of small and controlled scale.
Other details, objects and advantages of thie invention will become apparent as the following description of a present preferred method of practicing the invention proceeds.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 shows a three-dimensional view o= a first embodiment of a pour tube of the current invention.
FIG. 2 shows a view of a first embodimemt of a pour tube of the present invention from a view perpendicular to an exit port.
FIG. 3 shows a view of a pour tube of prior art from a view perpendicular to an exit port and the incident unstable flow pattern.
FIG. 4 shows a view of a first embodime=nt of a pour tube of the present invention including counter-rotating flow patterm.
FIG. 5 shows a view of a first embodiment of a pour tube of the present invention defining the design parameters of a tongue.
FIG. 6 shows a sectional view of a first embodiment of a pour tube of the present invention sectioned transversely definimg the discharge angles of slots and tongue. -~ 20 FIG. 7 shows a view of a second embod.iment of a pour tube of the present invention from a view perpendicular to an exit gport.
FIG. 8 shows a view of a second embodiment of a pour tube of the present invention from a view perpendicular to an exit port including counter-rotating flow pattern. }
FIG. 9 shows a view of a third embodiment of a pour tube of the present invention from a view perpendicular to an exit port.
DETATTED DESCRIPTION OF INVENTION
The invention comprises a pour tube for use in the continuous cas-ting of 5S molten metal. The pour tube comprises a bore fluidly connected to at lea st one exit port. Pour tube means shrouds, nozzles, and other refractory pieces for d_irecting a stream -of molten metal, including, for example, submerged entry shrouds and nozzles. The invention is particularly suited for pour tubes having an exit port adapted to deliver molten metal below the surface of the metal in a receiving vessel suchas amold.
Figs. 1 and 2 show alternative perspectives of a pour tube 1. The pour tube 1 comprises an inlet 11 and an exit port 12 fluidly connected by a bore 13. The pour tube 1 permits a stream of molten metal to pass from an upstream end at “the inlet 11, through the bore and to a downstream end at the exit port 12. The exit port 12 is defined by the perimeter of a hole that extends through the pour tube 1 from its outer surface to its bore 13. The perimeter of the exit port 12 comprises a downstream surface: 21. The perimeter of the exit port may be of any convenient general shape includimg, but not limited to, oval, polygonal or any combination thereof_
Conveniently, the general shape of the exit port is substantially rectanguKar. In one embodiment, the exit port 12 is defined by the downstream surface 21, am upstream surface: 22, and side surfaces 23 connecting the downstream and upstrearm surfaces.
At least one tongue 24 extends from either the downstream surface 21 or- upstream surfaces 22. The tongue 24, downstream surface 21 and side surfaces 23 «define a plurality of slot-shaped openings 25.
Figure 3 shows a pour tube 2 of the prior art with inlet 11 and exit port 12.
During the casting of molten metal, atleast a portion of the kinetic energy ofa downward stream 31 of molt-en metal translates into a rotating outflow 32 having an angular momentum. The remnaining kinetic energy causes the stream to exit the exit port as a high velocity jet. Rotating outflow 32 is shown to be spinning in a counterclockwise direction ams viewed, but the spinning direction of the outflow from a pouring tube of the prior amt is unstable and will exhibit occasional switching of direction. Depending on thes degree of asymmetry of the momentum distribution within downward stream 31 , the scale of the spinning in the outflow can be as great as the width, and the height, or the diameter of the exit port. Unstable large-scale spinning within the outflow and the high velocity jet produced by prior art pour tubes result in turbulence, surfaces waving, flow pattern instability and thermal inhomogeneities within the mold. Further compounding these difficulties, rotational flow 32 causes flow separation within the exit port 12. Flow separation is associated with alumina clogging, whi_ch can block the outflow from the exit port. The combination of a high velocity jet and large-scale rotational flow produces an unstable outflow that can o-scillate and wander within the mold. Exit ports of the prior art do not correct thesse deficiencies.
In contrast, the exit port 12 of the present invention, as shown in Figure 4, redirects the downward stream 31 of molten metal at least partially through the slots 25. The slots translate at least a portion of the kinetic energy of the downward stream 31 into at least two countemr-rotating flows 41 and thus oppose formation of a single large-scale spinning loop within the outflow. The angular momentums of the counter-rotating flows 41 substantially cancel so that the outflow from the exit port
12 has little or no net angular momentum. Simultaneously, the kinetic energy and consequently the velocity of the discharged flow are substantially reduced since the discharged flow is more uniformly distributed throughout exit port 12. Counter- rotating flows 41 permit the velocity of the outflow to be substantially reduced and large-scale spinning, swirling or vortexing in the outflow to be inhibited. Outflow is more diffusive and can be directed closer to the surface without causing surface waving or turbulence. A more diffusive outflow results in better thermal distribution in a mold. Additionally, flow separation in the exit port 12 and the associated alumina clogging are reduced. Flow instabilities inherent in alumina clogging may be substantially avoided.
A tongue should be of a sufficient size to define slots capable of inducing counter-rotating flows in the outflow. Referring to Figure 5, the tongue 24hasa width (w1) 51 and a height (h1) 52. In relation to the width (W) 53 and height (H) 54 of the exit port 12, the width 51 of the tongue will typically be at least about one- eighth of the exit port’s width 53. The height 52 of the tongue will commonly be at least about one-eighth the height 54 of the exit port 12. Obviously, increasing the dimensions of the tongue can reduce the total discharge area. of the exit port, thereby reducing the possible outflow from the pour tube, so the tongue will often be as small as possible to produce the counter-rotating flows. Casting c onditions, including the grade of molten metal, casting temperature, mold geometry, volume of outflow, size of the pour tube, and size of the exit port, will affect the dimensions of the tongue.
Referring to Figure 6, the tongue and its associated slots are designed to turn the discharge flow to a desired angle. Longitudinal axis 61 of the bore 13 is aligned with the general direction of the downward metal flow throrugh the bore.
Perpendicular axis 63 is at a right angle to longitudinal axis 61 and passes generally centrally through an exit port The surface of the tongue away from the edge is defined as the extended surfa ce 64, and is arranged at angle a, to perpendicular axis 63. Downstream surface 65 ©f a slot is arranged at angle a; to perpendicular axis 63.
Angles a; and a; can be cho sen to turn portions of the discharge flow to the desired angles of discharge. As known to those skilled in the art, the desired angles of discharge will depend on thes casting conditions, such as grade of molten metal, casting temperature, mold geometry, volume of outflow, size of the pour tube, and size of the exit port. The angles a; and ay typically range from 45 to +45 degrees.
Fig. 7 shows a secomnd embodiment of a pour tube of the present invention.
The pour tube 1 comprises an inlet 11 and an exit port 12 fluidly connected by a through-flow bore 13. The pour tube 1 is adapted to transport a stream of molten metal from an upstream enc at the inlet 11, through the bore, and to a downstream end comprising the exit port 12. The exit port 12 is defined by an upstream surface 22, a downstream surface 2-1, and side surfaces 23 connecting the downstream and upstream surfaces. The exit port may be of any convenient general shape including, but not limited to, oval, pollygonal or any combination thereof. Conveniently, the general shape of the exit port is substantially rectangular. At least one tongue 24 extends downstream from the upstream surface 22. The tongue 24, upstream surface 22 and side surfaces 23 define a plurality of slot-shaped openings 25.
An exit port 12 of the present invention, as shown in Figure 8, redirects the downward stream 31 of meolten metal at least partially through the slots 25. By opposing formation of a si ngle large-scale spinning loop within the discharging flow, the slots 25 translate at least a portion of the kinetic energy of the spinning flows 32 into counter-rotating flows 41. The angular momentums ef the counter-rotating flows 41 substantially reduce the angular momentum of tae outflow from the exit port 12. Large-scale spinning, swirling or vortexing in th_e outflow is inhibited and the outflow is more symmetric, more diffusive and can bes directed closer to the top surface of the mold or receiving vessel without excessives surface waving or turbulence. Additionally, flow separation in the exit port 12, flow instabilities inherent in alumina clogging may be substantially avoided, and the associated alumina clogging may be reduced. .
Fig. 9 shows a third embodiment of a pour tube Of the present invention. The pour tube 1 comprises an inlet 11 and exit port 12 fluidly connected by a through- flow bore 13. The pour tube 1 is adapted to transport a stream of molten metal from an upstream end at the inlet 11, through the bore, and to- a downstream end comprising the exit port 12. The exit port 12 is defined by an upstream surface 22, a downstream surface 21, and side surfaces 23 connecting the downstream and upstream surfaces. The exit port may be of any convenient general shape including, but not limited to, oval, polygonal or any combination thereof. Conveniently, the general shape of the exit port is substantially rectangular. At least one lower tongue 91 extends upstream from the downstream surface 21 aand at least one upper tongue 02 extends downstream from the upstream surface 22. The lower tongue 91, the upper tongue 92, downstream surface 21, upstream surface 22 and side surfaces 23 define a plurality of slot-shaped openings 25. Molten =metal being discharged from pour tube 1 passes at least partially through the slots 25 with formation of counter- rotating flows of small-scale and very high stability.

Claims (14)

W02004/082871 PCT/US2004/007184 We claim:
1. A pour tube for use in casting a stream of molten metal from an upstream position to a downstream position, the pour tube co mprising an inner surface defining a bore and an outer surface having at least one exit port defined at least partially by an edge and fluidly connected to t'he bore, the exit port characterized by at least one tongue extending from an edge, whereby at least two slots are created in the exit port.
2. The pour tube of claim 1, characterized by the exit —port including a downstream edge and the tongue extending upstream from the downstream edge.
3. The pour tube of claim 1, characterized by the exit port including an upstream edge and the tongue extending downstream from thme upstream edge.
4. The pour tube of claim 1, characterized by the exit port including an upper tongue extending downstream from an upstream edge, and a lower tongue extending upstream from a downstream edge.
5. The pour tube of any one of claims 1-4, characterizzed by the pour tube including a longitudinal axis between the upstream and downstream positions.
6. The pour tube of claim 5, characterized by at least one tongue including an extended surface, and the extended surface defining a tongue plane that intersects the longitudinal axis at an angle from —45 to +45 degrees.
7. The pour tube of any one of claims 5 and 6, characterized by at least one edge including an edge surface defining an edge plane thnat intersects the longitudinal axis at an angle from —45 to +45 degre=es. 15 AMENDED SHEET DATED 6 OCTOBER 2006
8. ‘The pour tube of any one of claims 5-7, characterized by the exit port defining an exit plane substantially parallel to the longitudinal axis.
9. The pour tube of any one of claims 1-8, characterized by the= bore comprising a plurality of fluidly connected sections. Ss
10. The pour tube of claim 9, characterized by a discontinuity separating each section.
11. The pour tube of any one of claims 9 and 10, characterized by the sections including at least one frusto-conical section.
12. A method of casting a stream of molten metal using a pour tube as described in any one of claims 1-11, characterized by: a) flowing a stream of metal through the bore; b) directing the stream towards the exit port; ¢) producing symmetric counter-rotating currents in the str €am as the stream passes through the exit port.
13. A pour tube for use in casting a stream of molten metal fromm an upstream position to a downstream position, substantially as herein described with reference to any one of the embodiments illustrated in Figumres 1, 2 and 4 10 9.
14. A method of casting a stream of metal substantially as herei n described with reference to any one of the embodiments illustrated in Figumres 1,2 and 4 to 9. 16 AMENDED SHEET DATED 6 OCTOBER 2006
ZA200507285A 2003-03-17 2004-03-09 Submerged entry nozzle with dynamic stabilization ZA200507285B (en)

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US (1) US20060169728A1 (en)
EP (1) EP1603697B1 (en)
JP (1) JP2006520694A (en)
KR (1) KR20050113230A (en)
CN (1) CN100346909C (en)
AT (1) ATE336319T1 (en)
AU (1) AU2004221863B2 (en)
BR (1) BRPI0408340A (en)
CA (1) CA2519050A1 (en)
DE (1) DE602004001980T2 (en)
ES (1) ES2267057T3 (en)
MX (1) MXPA05009852A (en)
RU (1) RU2331496C2 (en)
UA (1) UA85179C2 (en)
WO (1) WO2004082871A1 (en)
ZA (1) ZA200507285B (en)

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US6425505B1 (en) * 1999-09-03 2002-07-30 Vesuvius Crucible Company Pour tube with improved flow characteristics

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CN1761543A (en) 2006-04-19
EP1603697A1 (en) 2005-12-14
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CA2519050A1 (en) 2004-09-30
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WO2004082871A1 (en) 2004-09-30
AU2004221863B2 (en) 2009-04-09
RU2005130062A (en) 2006-02-10
US20060169728A1 (en) 2006-08-03
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JP2006520694A (en) 2006-09-14
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RU2331496C2 (en) 2008-08-20
AU2004221863A1 (en) 2004-09-30
UA85179C2 (en) 2009-01-12
MXPA05009852A (en) 2005-12-06
EP1603697B1 (en) 2006-08-16

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