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YU40117B - Process for obtaining n-phosphonomethyglycine - Google Patents

Process for obtaining n-phosphonomethyglycine

Info

Publication number
YU40117B
YU40117B YU1115/75A YU111575A YU40117B YU 40117 B YU40117 B YU 40117B YU 1115/75 A YU1115/75 A YU 1115/75A YU 111575 A YU111575 A YU 111575A YU 40117 B YU40117 B YU 40117B
Authority
YU
Yugoslavia
Prior art keywords
phosphonomethyglycine
obtaining
Prior art date
Application number
YU1115/75A
Other languages
English (en)
Other versions
YU111575A (en
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Co filed Critical Monsanto Co
Publication of YU111575A publication Critical patent/YU111575A/xx
Publication of YU40117B publication Critical patent/YU40117B/xx

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
    • C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
    • C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
YU1115/75A 1974-05-01 1975-04-30 Process for obtaining n-phosphonomethyglycine YU40117B (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US05/465,976 US3969398A (en) 1974-05-01 1974-05-01 Process for producing N-phosphonomethyl glycine
KR7500924A KR790000297B1 (en) 1974-05-01 1975-04-30 Process for producing n-phosphono methyl gylcine

Publications (2)

Publication Number Publication Date
YU111575A YU111575A (en) 1982-06-30
YU40117B true YU40117B (en) 1985-08-31

Family

ID=26625851

Family Applications (1)

Application Number Title Priority Date Filing Date
YU1115/75A YU40117B (en) 1974-05-01 1975-04-30 Process for obtaining n-phosphonomethyglycine

Country Status (27)

Country Link
US (1) US3969398A (xx)
JP (1) JPS5330690B2 (xx)
KR (1) KR790000297B1 (xx)
AR (1) AR215840A1 (xx)
AT (1) AT336637B (xx)
BE (1) BE828599A (xx)
BG (1) BG26398A3 (xx)
BR (1) BR7502651A (xx)
CA (1) CA1030157A (xx)
CH (1) CH613210A5 (xx)
CS (1) CS179938B2 (xx)
DD (1) DD119241A5 (xx)
DE (1) DE2519388C3 (xx)
DK (1) DK138655B (xx)
EG (1) EG11700A (xx)
ES (1) ES437154A1 (xx)
FR (1) FR2269533B1 (xx)
GB (1) GB1467778A (xx)
IE (1) IE41118B1 (xx)
IT (1) IT1037766B (xx)
MY (1) MY7800280A (xx)
NL (1) NL161763C (xx)
PH (1) PH12324A (xx)
RO (1) RO70907A (xx)
SE (1) SE427752B (xx)
YU (1) YU40117B (xx)
ZA (1) ZA752792B (xx)

Families Citing this family (93)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4100275A (en) * 1975-01-27 1978-07-11 Hoffmann-La Roche Inc. Compositions having antibiotic properties
US4127649A (en) * 1975-01-27 1978-11-28 Hoffmann-La Roche Inc. Compositions having antibiotic properties
IL48835A (en) * 1975-01-27 1979-05-31 Sparamedica Ag Amino acyl and peptidyl derivatives of phophonic acids, their preparation and pharmaceutical compositions containingthem
US4134972A (en) * 1976-07-21 1979-01-16 Hoffmann-La Roche Inc. Compositions having antibiotic properties
MX4703E (es) * 1976-12-20 1982-08-04 Monsanto Co Procedimiento mejorado para la preparacion de mono y disales de n-fosfonometilglicina
HU184168B (en) * 1979-05-11 1984-07-30 Mta Koezponti Kemiai Kutato In Process for producing n-bracket-phosphono-methyl-bracket closed-glycine
US4454043A (en) * 1980-11-17 1984-06-12 Monsanto Company Column switching procedure
IL65187A (en) * 1982-03-08 1985-03-31 Geshuri Lab Ltd N-phosphonomethylglycine derivatives,processes for their preparation and herbicidal compositions containing them
IL66824A0 (en) * 1982-06-25 1982-12-31 Geshuri Lab Ltd Process for producing n-phosphonomethylglycine derivatives and herbicidal compounds and compositions prepared thereby
US4442041A (en) * 1982-06-30 1984-04-10 Stauffer Chemical Company Method for preparation of N-phosphonomethylglycine
IL68716A (en) * 1983-05-17 1987-03-31 Geshuri Lab Ltd Process for producing n-phosphonomethylglycine
US4654429A (en) * 1983-12-02 1987-03-31 Monsanto Company Process for the preparation of a glyphosate product
US4617415A (en) * 1983-12-02 1986-10-14 Monsanto Company α-Substituted N-phosphonomethyliminodiacetic acid
US4624937A (en) * 1984-05-10 1986-11-25 Monsanto Company Process for removing surface oxides from activated carbon catalyst
US5874612A (en) * 1984-12-28 1999-02-23 Baysdon; Sherrol L. Process for the preparation of glyphosate and glyphosate derivatives
US5068404A (en) * 1984-12-28 1991-11-26 Monsanto Company Thermal dealkylation of N-alkyl N-phosphonomethylglycine
US4582650A (en) * 1985-02-11 1986-04-15 Monsanto Company Oxidation with encapsulated co-catalyst
US4579689A (en) * 1985-02-11 1986-04-01 Monsanto Company Oxidation with coated catalyst
US4696772A (en) * 1985-02-28 1987-09-29 Monsanto Company Amine oxidation using carbon catalyst having oxides removed from surface
DE3532344A1 (de) * 1985-09-11 1987-03-19 Hoechst Ag Verfahren zur herstellung von n-phosphonomethylglycin
US4657705A (en) * 1985-09-23 1987-04-14 Monsanto Company Process for the preparation of N-substituted aminomethylphosphonic acids
US4694082A (en) * 1985-09-23 1987-09-15 Monsanto Company Compound 1,4-diisopropyl-2,5-diketopiperazine
US4684483A (en) * 1985-09-23 1987-08-04 Monsanto Company Preparation of N-substituted amino acids
US4740608A (en) * 1985-10-09 1988-04-26 Monsanto Company (Phosphonomethyl)trifluoromethyl sulfonates
US4853159A (en) * 1987-10-26 1989-08-01 Monsanto Company Process for producing N-phosphonomethylglycine
US4898972A (en) * 1988-09-26 1990-02-06 Monsanto Company Process for producing N-phosphonomethylglycine
US4965403A (en) * 1988-11-07 1990-10-23 Monsanto Company Oxidation/dealkylation process
US4937376A (en) * 1989-05-25 1990-06-26 Monsanto Company Process for producing N-phosphonomethylglycine
US4952723A (en) * 1989-07-31 1990-08-28 Monsanto Company Process for producing N-phosphonomethylglycine
US5095140A (en) * 1990-06-25 1992-03-10 Monsanto Company Peroxide process for producing N-phosphonomethylglycine
US5312973A (en) * 1993-03-25 1994-05-17 Finchimica S.P.A. Process for producing n-phosphono-methyl-imino-diacetic acid
GB9410524D0 (en) * 1993-06-21 1994-07-13 Zeneca Ltd Manufacture of n- phosphonomethylglycine and its salts
SI9400449A (en) * 1994-12-20 1996-06-30 Pinus D D Process for preparing N-phosphonomethyl glycin
DE19500121A1 (de) * 1995-01-04 1996-07-11 Bayer Ag Verfahren zur Herstellung von N-Phosphonomethylglycin
TW322481B (xx) * 1995-03-07 1997-12-11 Sankyo Co
EP0963350A1 (en) * 1995-03-14 1999-12-15 Monsanto Company Treatment of a formaldehyde-containing waste stream
US6365772B1 (en) * 1995-05-30 2002-04-02 Hampshire Chemical Corp. Facile synthesis of phosphonomethylglycine from phosphonomethyliminodiacetic acid
US6054608A (en) 1997-05-05 2000-04-25 Monsanto Company Method for preparing formylphosphonic acid
US6232494B1 (en) 1998-02-12 2001-05-15 Monsanto Company Process for the preparation of N-(phosphonomethyl)glycine by oxidizing N-substituted N-(phosphonomethyl)glycine
IL129840A0 (en) * 1998-02-12 2000-02-29 Monsanto Co Process for making glyphosate by oxidizing n-substituted glyphosates
US6417133B1 (en) 1998-02-25 2002-07-09 Monsanto Technology Llc Deeply reduced oxidation catalyst and its use for catalyzing liquid phase oxidation reactions
JP4633255B2 (ja) 1998-03-09 2011-02-16 モンサント テクノロジー エルエルシー グリホセート耐性大豆中の雑草防除用混合剤
US5942643A (en) * 1998-05-14 1999-08-24 Calgon Carbon Corporation Method for the manufacture of N-phosphonomethylglycine from N-phosphonomethyliminodiacetic acid using a low temperature catalytic carbon
US5962729A (en) * 1998-05-14 1999-10-05 Calgon Carbon Corporation Method for the manufacture of N-phosphonomethylglycine from N-phosphonomethyliminodiacetic acid using a catalytic carbon
IES980552A2 (en) 1998-07-09 1999-08-11 Agritech Chemical Ltd Improved process for preparing N-phosphonomethyl iminodiacetic acid
WO2000009520A1 (en) 1998-08-12 2000-02-24 Monsanto Company Continuous process for the preparation of n-(phosphonomethyl) iminodiacetic acid
AU6024599A (en) * 1998-09-08 2000-03-27 Hampshire Chemical Corp. Synthesis of phosphonomethyliminodiacetic acid with reduced effluent
US6194604B1 (en) 1998-12-10 2001-02-27 Monsanto Company Process for producing phosphorous acid
BR0012653A (pt) 1999-07-23 2002-04-09 Basf Ag Processo para a preparação de n-fosfono-metil-glicina ou de um seu sal
ES2222267T3 (es) * 1999-12-21 2005-02-01 Monsanto Technology Llc Uso de un catalizador suplementario en combinacion con un catalizador que contiene metal noble soportado en carbono en reacciones de oxidacion en fase liquida.
DE10007702A1 (de) * 2000-02-19 2001-08-23 Sueddeutsche Kalkstickstoff Verfahren zur Herstellung von N-(Phosphonomethyl)glycin
US6274760B1 (en) 2000-03-14 2001-08-14 Monsanto Co. Preparation of formylphosphonic acid from tertiary aminomethylphosphonic acid N-oxides
US6376708B1 (en) * 2000-04-11 2002-04-23 Monsanto Technology Llc Process and catalyst for dehydrogenating primary alcohols to make carboxylic acid salts
AR028571A1 (es) 2000-05-15 2003-05-14 Monsanto Technology Llc Proceso para preparar compuestos de acido iminodiacético a partir de sustratos de monoetanolamina
US6927304B2 (en) 2000-05-22 2005-08-09 Monsanto Technology Llc De-oxygenation treatment for noble metal on carbon catalysts used in liquid phase oxidation reactions
BR0111041A (pt) * 2000-05-22 2004-06-15 Monsanto Technology Llc Sistemas de reação para produzir compostos de n-(fosfonometil)glicina
CN101311183B (zh) * 2000-05-22 2011-08-31 孟山都技术有限责任公司 制备n-(膦酰基甲基)甘氨酸化合物的反应系统
US6441223B1 (en) 2000-11-30 2002-08-27 Monsanto Technology Llc Method of making phosphorus-containing compounds and products thereof
US6818450B2 (en) 2001-05-22 2004-11-16 Monsanto Technology Llc Use of infrared spectroscopy for on-line process control and endpoint detection
DE10130136A1 (de) * 2001-06-22 2003-01-02 Basf Ag Verfahren zur Gewinnung von N-Phosphonomethylglycin
US7126024B2 (en) 2001-10-18 2006-10-24 Monsanto Technology Llc Process and catalyst for dehydrogenating primary alcohols to make carboxylic acid salts
US7390920B2 (en) * 2002-02-14 2008-06-24 Monsanto Technology Llc Oxidation catalyst and process
US7129373B2 (en) * 2002-02-14 2006-10-31 Monsanto Technology Llc Oxidation catalyst and process
US6921834B2 (en) 2002-05-22 2005-07-26 Dow Agrosciences Llc Continuous process for preparing N-phosphonomethyl glycine
JP4202047B2 (ja) * 2002-05-24 2008-12-24 富士通株式会社 ヘッド位置制御方法及びデイスク記憶装置
CN1674986A (zh) * 2002-06-28 2005-09-28 孟山都技术公司 碲在液相氧化反应用碳担载的含贵金属催化剂中的应用
EP1684900B1 (en) 2003-08-14 2013-02-27 Monsanto Technology LLC Process for oxidation of N-(phosphonomethyl)iminodiacetic acid or salt thereof
US7179936B2 (en) * 2003-09-17 2007-02-20 Monsanto Technology Llc Process for recovering a crystalline product from solution
FR2865468B1 (fr) * 2004-01-22 2006-04-28 Ceca Sa Charbon actif a resistance mecanique amelioree, ses utilisations, notamment comme support de catalyseur.
MXPA06011412A (es) 2004-03-30 2007-01-23 Monsanto Technology Llc Metodos para controlar patogenos en plantas utilizando n-fosfonometilglicina.
CN100372857C (zh) * 2004-05-12 2008-03-05 江苏好收成韦恩农药化工有限公司 N-膦酰基甲基甘氨酸的生产方法
JP5129961B2 (ja) * 2004-09-06 2013-01-30 日本エンバイロケミカルズ株式会社 酸化反応触媒およびそれを用いた化合物の製法
US8703639B2 (en) * 2004-09-15 2014-04-22 Monsanto Technology Llc Oxidation catalyst and its use for catalyzing liquid phase oxidation reactions
AR054096A1 (es) * 2004-11-12 2007-06-06 Monsanto Technology Llc Recuperacion de metales nobles de corrientes de proceso acuosas y proceso de preparacion de n-(fosfonometil)-glicina
AU2006214086B2 (en) 2005-02-17 2012-01-19 Monsanto Technology Llc Transition metal-containing catalysts and catalyst combinations including transition metal-containing catalysts and processes for their preparation and use as oxidation catalysts
CN101170907B (zh) 2005-03-04 2012-10-03 孟山都技术公司 减轻用除草剂草甘膦制剂处理的草甘膦耐受性转基因棉花植物内的坏死
CN101427406A (zh) * 2006-02-17 2009-05-06 孟山都技术公司 含过渡金属的催化剂、其制备方法及其作为燃料电池催化剂的用途
CN100460408C (zh) * 2007-01-26 2009-02-11 捷马化工股份有限公司 资源再利用的催化氧化制备草甘膦方法
US7771494B2 (en) * 2007-01-31 2010-08-10 Monsanto Technology Llc Process for selective removal of water and impurities from N-(phosphonomethyl)glycine
US8252953B2 (en) 2008-05-01 2012-08-28 Monsanto Technology Llc Metal utilization in supported, metal-containing catalysts
CN101337978B (zh) * 2008-05-13 2011-06-29 浙江新安化工集团股份有限公司 一种利用富氧气体催化氧化双甘膦制取草甘膦的方法
CN101481387B (zh) * 2008-11-27 2012-02-01 浙江新安化工集团股份有限公司 一种催化氧化合成草甘膦的制备方法
CN101508701B (zh) * 2008-12-10 2012-09-05 上海泰禾(集团)有限公司 一种活性碳作催化剂氧气氧化双甘膦制备草甘膦的方法
CN102459091B (zh) 2009-05-18 2014-06-18 孟山都技术公司 含水废物流中磷有用成分和盐杂质的回收
CN101781332B (zh) * 2010-03-02 2012-10-24 广西壮族自治区化工研究院 活性炭催化空气氧化双甘膦制备草甘膦的方法
CN102241703B (zh) * 2011-05-07 2014-05-07 安徽国星生物化学有限公司 一种改进的双甘膦制备草甘膦的方法
RU2015103314A (ru) 2012-07-17 2016-09-10 Страйтмарк Холдинг Аг Способ синтеза N-фосфонометилиминодиуксусной кислоты
BR112015000966B1 (pt) 2012-07-17 2020-04-28 Monsanto Technology Llc método para a síntese de n-(fosfonometil)glicina ou um de seus derivados selecionados a partir do grupo que consiste em seus sais, seus ésteres de fosfonato e seus sais de éster de fosfonato
WO2014012991A1 (en) 2012-07-17 2014-01-23 Straitmark Holding Ag Method for the synthesis of n-(phosphonomethyl)glycine
CN104812766B (zh) 2012-07-17 2017-06-06 斯特雷特马克控股股份公司 用于合成氨基亚烷基膦酸的方法
RU2674022C9 (ru) 2012-07-17 2019-01-24 МОНСАНТО ТЕКНОЛОДЖИ ЭлЭлСи Способ синтеза альфа-аминоалкиленфосфоновой кислоты
BR112019027682A2 (pt) 2017-06-26 2020-09-15 Monsanto Technology Llc controle de fósforo para fluxos de resíduos provenientes de processos de produção de glifosato
CN115215900A (zh) * 2022-07-01 2022-10-21 安徽东至广信农化有限公司 一种草甘膦的节能生产方法

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Also Published As

Publication number Publication date
BG26398A3 (bg) 1979-03-15
DE2519388B2 (de) 1977-07-14
RO70907A (ro) 1980-04-15
BE828599A (fr) 1975-10-30
DK188175A (xx) 1975-11-02
FR2269533B1 (xx) 1978-02-24
AR215840A1 (es) 1979-11-15
FR2269533A1 (xx) 1975-11-28
DE2519388C3 (de) 1978-03-09
CA1030157A (en) 1978-04-25
NL161763C (nl) 1980-03-17
US3969398A (en) 1976-07-13
JPS50160222A (xx) 1975-12-25
GB1467778A (en) 1977-03-23
NL161763B (nl) 1979-10-15
ZA752792B (en) 1976-04-28
DD119241A5 (xx) 1976-04-12
ES437154A1 (es) 1977-01-16
SE7505040L (sv) 1975-11-03
DE2519388A1 (de) 1975-11-13
KR790000297B1 (en) 1979-04-23
AT336637B (de) 1977-05-10
IE41118B1 (en) 1979-10-24
CH613210A5 (xx) 1979-09-14
NL7505071A (nl) 1975-11-04
IT1037766B (it) 1979-11-20
AU8070175A (en) 1976-11-04
IE41118L (en) 1975-11-01
CS179938B2 (en) 1977-12-30
DK138655B (da) 1978-10-09
ATA333975A (de) 1976-09-15
EG11700A (en) 1977-10-31
JPS5330690B2 (xx) 1978-08-29
SE427752B (sv) 1983-05-02
PH12324A (en) 1979-01-16
MY7800280A (en) 1978-12-31
YU111575A (en) 1982-06-30
DK138655C (xx) 1979-02-26
BR7502651A (pt) 1976-03-16

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