YU29800A - Postupak za dobijanje hlorbenzoksazola - Google Patents
Postupak za dobijanje hlorbenzoksazolaInfo
- Publication number
- YU29800A YU29800A YU29800A YU29800A YU29800A YU 29800 A YU29800 A YU 29800A YU 29800 A YU29800 A YU 29800A YU 29800 A YU29800 A YU 29800A YU 29800 A YU29800 A YU 29800A
- Authority
- YU
- Yugoslavia
- Prior art keywords
- formula
- chiorobenzoxazoles
- preparing
- reacts
- chlorine
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D263/00—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings
- C07D263/52—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings condensed with carbocyclic rings or ring systems
- C07D263/54—Benzoxazoles; Hydrogenated benzoxazoles
- C07D263/58—Benzoxazoles; Hydrogenated benzoxazoles with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached in position 2
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Pronalazak se odnosi na postupak za dobijanje hlorbenzoksazola formule (I) gde su R1, R2 i R4 definisani kao u zahtevu jedan i u slučaju (a) R3 predstavlja vodonik, halogen, CN, NO2 C1-C5-alkil, C1-C5-alkoksi, aril ili ariloksi, pri čemu je svaki od poslednja četiri navedena ostatka supstituisan ili nesupstituisan ili u slučaju (b)R3 je hlor, karakterističan po tome što se benzoksazoli formule (II) kod kojih R1, R2 i R4 imaju isto značenje kao u formuli (I) i R3 u slučaju (a) kao u formuli (I), odnosno R3 je u slučaju (b) vodonik dovode u reakciju u prisustvu nekog kiselog katalizatora sa sredstvom za hlorovanje i prevode u produkt monohlorovanja (I) odnosno u slučaju (b) sa viškom sredstva za hlorovanje u produkt dihlorovanja (I), gde R3 predstavlja hlor.[The invention relates to a method for producing chlorobenzoxazolene of formula (I), wherein R1, R2 and R4 are defined as in Claim 1 and in (a) R3 = H, CN, NO2, C1-C5-alkyl, C1-C5 alkoxy, aryl or aryloxy, whereby each of the four radicals mentioned is unsubstituted or substituted, or in (b) R3 = chlorine. The inventive method is characterized in that benzoxazole of formula (II) wherein R1, R2 and R4 have the same meaning as in formula (I) and R3 in (a) is defined as in formula (I) or R3 in (b) is hydrogen, reacts in the presence of an acid catalyst with a chlorinating agent to form a monochlorination product (I) or in (b) reacts with an excess of a chlorinating agent to form a dichlorination product (I), wherein R3 = chlorine.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19755904A DE19755904C2 (de) | 1997-12-16 | 1997-12-16 | Verfahren zur Herstellung von Chlorbenzoxazolen |
Publications (2)
Publication Number | Publication Date |
---|---|
YU29800A true YU29800A (sh) | 2002-11-15 |
RS49787B RS49787B (sr) | 2008-06-05 |
Family
ID=7852111
Country Status (29)
Country | Link |
---|---|
US (1) | US6274739B1 (sh) |
EP (1) | EP1071674B1 (sh) |
JP (1) | JP4996009B2 (sh) |
KR (1) | KR100647960B1 (sh) |
CN (1) | CN1197851C (sh) |
AR (1) | AR016434A1 (sh) |
AT (1) | ATE273291T1 (sh) |
AU (1) | AU761589B2 (sh) |
BR (1) | BR9813698A (sh) |
CA (1) | CA2311578C (sh) |
CO (1) | CO4980865A1 (sh) |
CZ (1) | CZ297899B6 (sh) |
DE (2) | DE19755904C2 (sh) |
ES (1) | ES2227905T3 (sh) |
HU (1) | HUP0100505A3 (sh) |
ID (1) | ID26842A (sh) |
IL (1) | IL136698A (sh) |
MY (1) | MY122273A (sh) |
NO (1) | NO316617B1 (sh) |
PL (1) | PL195801B1 (sh) |
PT (1) | PT1071674E (sh) |
RS (1) | RS49787B (sh) |
RU (1) | RU2245880C2 (sh) |
SK (1) | SK285239B6 (sh) |
TR (1) | TR200001734T2 (sh) |
TW (1) | TW486473B (sh) |
UA (1) | UA57123C2 (sh) |
WO (1) | WO1999031076A1 (sh) |
ZA (1) | ZA9811499B (sh) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2006022194A1 (en) * | 2004-08-23 | 2006-03-02 | Semiconductor Energy Laboratory Co., Ltd. | Electron injecting composition, and light emitting element and light emitting device using the electron injecting composition |
CN109456282A (zh) * | 2019-01-11 | 2019-03-12 | 江苏快达农化股份有限公司 | 一种2-氯苯并噻唑的合成方法 |
CN109761928B (zh) * | 2019-02-15 | 2023-06-23 | 安徽丰乐农化有限责任公司 | 一种2,6-二氯苯并恶唑的制备方法 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2059725A1 (de) * | 1970-12-04 | 1972-06-08 | Bayer Ag | 2,4,5,6,7-Pentachlor-benzoxazol und Verfahren zu seiner Herstellung |
DE2640730C2 (de) * | 1976-09-10 | 1983-08-25 | Hoechst Ag, 6230 Frankfurt | Benzoxazolyloxy- und Benzothiazolyloxy-phenoxy-Verbindungen und diese enthaltende herbizide Mittel |
DE3234530A1 (de) * | 1982-09-17 | 1984-03-22 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von 2-chlorbenzthiazol |
DE3334417A1 (de) * | 1983-09-23 | 1985-04-04 | Cassella Ag, 6000 Frankfurt | Verfahren zur herstellung von 2-chlorbenzoxazolen |
DE3406909A1 (de) * | 1984-02-25 | 1985-09-05 | Hoechst Ag, 6230 Frankfurt | Verfahren zur herstellung von 2,6-dichlorbenzoxazol |
DE3418168A1 (de) * | 1984-05-16 | 1985-11-21 | Bayer Ag, 5090 Leverkusen | 6-chlorbenzazolyloxyacetamide |
DE4218433A1 (de) * | 1992-06-04 | 1993-12-09 | Bayer Ag | Fluorbenzoxazolyloxyacetamide |
EP0626379B1 (de) * | 1993-04-27 | 2001-03-21 | Bayer Ag | Verfahren zur Herstellung von 2-Chlor-benzothiazolen oder 2-Chlor-benzoxazolen |
-
1997
- 1997-12-16 DE DE19755904A patent/DE19755904C2/de not_active Expired - Fee Related
-
1998
- 1998-08-12 UA UA2000074173A patent/UA57123C2/uk unknown
- 1998-12-08 CN CNB988122421A patent/CN1197851C/zh not_active Expired - Lifetime
- 1998-12-08 IL IL13669898A patent/IL136698A/en not_active IP Right Cessation
- 1998-12-08 KR KR1020007006460A patent/KR100647960B1/ko not_active IP Right Cessation
- 1998-12-08 CA CA002311578A patent/CA2311578C/en not_active Expired - Lifetime
- 1998-12-08 SK SK885-2000A patent/SK285239B6/sk not_active IP Right Cessation
- 1998-12-08 AT AT98964493T patent/ATE273291T1/de not_active IP Right Cessation
- 1998-12-08 TR TR2000/01734T patent/TR200001734T2/xx unknown
- 1998-12-08 RU RU2000118803/04A patent/RU2245880C2/ru active
- 1998-12-08 PL PL98341302A patent/PL195801B1/pl not_active IP Right Cessation
- 1998-12-08 WO PCT/EP1998/007969 patent/WO1999031076A1/de active IP Right Grant
- 1998-12-08 DE DE59811807T patent/DE59811807D1/de not_active Expired - Lifetime
- 1998-12-08 US US09/581,488 patent/US6274739B1/en not_active Expired - Lifetime
- 1998-12-08 EP EP98964493A patent/EP1071674B1/de not_active Expired - Lifetime
- 1998-12-08 PT PT98964493T patent/PT1071674E/pt unknown
- 1998-12-08 RS YUP-298/00A patent/RS49787B/sr unknown
- 1998-12-08 ES ES98964493T patent/ES2227905T3/es not_active Expired - Lifetime
- 1998-12-08 ID IDW20001062A patent/ID26842A/id unknown
- 1998-12-08 BR BR9813698-4A patent/BR9813698A/pt not_active Application Discontinuation
- 1998-12-08 AU AU19667/99A patent/AU761589B2/en not_active Expired
- 1998-12-08 HU HU0100505A patent/HUP0100505A3/hu unknown
- 1998-12-08 CZ CZ20002260A patent/CZ297899B6/cs not_active IP Right Cessation
- 1998-12-08 JP JP2000539003A patent/JP4996009B2/ja not_active Expired - Lifetime
- 1998-12-14 TW TW087120757A patent/TW486473B/zh not_active IP Right Cessation
- 1998-12-14 CO CO98074121A patent/CO4980865A1/es unknown
- 1998-12-15 AR ARP980106363A patent/AR016434A1/es active IP Right Grant
- 1998-12-15 MY MYPI98005647A patent/MY122273A/en unknown
- 1998-12-15 ZA ZA9811499A patent/ZA9811499B/xx unknown
-
2000
- 2000-06-15 NO NO20003077A patent/NO316617B1/no not_active IP Right Cessation
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