WO2023217414A1 - Wertdokument mit lumineszenzmerkmal, wertdokumentsystem, herstellungsverfahren und prüfverfahren - Google Patents
Wertdokument mit lumineszenzmerkmal, wertdokumentsystem, herstellungsverfahren und prüfverfahren Download PDFInfo
- Publication number
- WO2023217414A1 WO2023217414A1 PCT/EP2023/025223 EP2023025223W WO2023217414A1 WO 2023217414 A1 WO2023217414 A1 WO 2023217414A1 EP 2023025223 W EP2023025223 W EP 2023025223W WO 2023217414 A1 WO2023217414 A1 WO 2023217414A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- luminescence
- markers
- document
- value
- luminescent
- Prior art date
Links
- 238000004020 luminiscence type Methods 0.000 title claims abstract description 198
- 238000000034 method Methods 0.000 title claims description 24
- 238000004519 manufacturing process Methods 0.000 title claims description 11
- 239000003550 marker Substances 0.000 claims abstract description 90
- 230000003595 spectral effect Effects 0.000 claims abstract description 80
- 238000000295 emission spectrum Methods 0.000 claims abstract description 63
- 230000005284 excitation Effects 0.000 claims abstract description 21
- 238000005259 measurement Methods 0.000 claims description 29
- 238000007639 printing Methods 0.000 claims description 21
- 239000000126 substance Substances 0.000 claims description 20
- 239000000758 substrate Substances 0.000 claims description 14
- 125000002524 organometallic group Chemical group 0.000 claims description 3
- 238000001228 spectrum Methods 0.000 description 24
- 238000011156 evaluation Methods 0.000 description 13
- 238000001514 detection method Methods 0.000 description 8
- 238000012545 processing Methods 0.000 description 8
- 238000013461 design Methods 0.000 description 7
- 238000010586 diagram Methods 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- 230000005855 radiation Effects 0.000 description 6
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 5
- 229910052791 calcium Inorganic materials 0.000 description 5
- 239000011575 calcium Substances 0.000 description 5
- 238000009826 distribution Methods 0.000 description 5
- -1 but not limited to Inorganic materials 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 4
- 229910052566 spinel group Inorganic materials 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 239000010457 zeolite Substances 0.000 description 3
- 229910052691 Erbium Inorganic materials 0.000 description 2
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 229910052779 Neodymium Inorganic materials 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 229910052769 Ytterbium Inorganic materials 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- PSNPEOOEWZZFPJ-UHFFFAOYSA-N alumane;yttrium Chemical compound [AlH3].[Y] PSNPEOOEWZZFPJ-UHFFFAOYSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- UYAHIZSMUZPPFV-UHFFFAOYSA-N erbium Chemical compound [Er] UYAHIZSMUZPPFV-UHFFFAOYSA-N 0.000 description 2
- 229910052733 gallium Inorganic materials 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 239000011265 semifinished product Substances 0.000 description 2
- UBXAKNTVXQMEAG-UHFFFAOYSA-L strontium sulfate Chemical compound [Sr+2].[O-]S([O-])(=O)=O UBXAKNTVXQMEAG-UHFFFAOYSA-L 0.000 description 2
- NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 description 2
- PFNQVRZLDWYSCW-UHFFFAOYSA-N (fluoren-9-ylideneamino) n-naphthalen-1-ylcarbamate Chemical compound C12=CC=CC=C2C2=CC=CC=C2C1=NOC(=O)NC1=CC=CC2=CC=CC=C12 PFNQVRZLDWYSCW-UHFFFAOYSA-N 0.000 description 1
- WUPHOULIZUERAE-UHFFFAOYSA-N 3-(oxolan-2-yl)propanoic acid Chemical compound OC(=O)CCC1CCCO1 WUPHOULIZUERAE-UHFFFAOYSA-N 0.000 description 1
- DJHGAFSJWGLOIV-UHFFFAOYSA-K Arsenate3- Chemical class [O-][As]([O-])([O-])=O DJHGAFSJWGLOIV-UHFFFAOYSA-K 0.000 description 1
- 229910052688 Gadolinium Inorganic materials 0.000 description 1
- 229910052689 Holmium Inorganic materials 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 239000004594 Masterbatch (MB) Substances 0.000 description 1
- HICARRDFVOAELS-UHFFFAOYSA-N O(Cl)Cl.[Y] Chemical compound O(Cl)Cl.[Y] HICARRDFVOAELS-UHFFFAOYSA-N 0.000 description 1
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- 229910052775 Thulium Inorganic materials 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 229910000611 Zinc aluminium Inorganic materials 0.000 description 1
- 239000005083 Zinc sulfide Substances 0.000 description 1
- JEROREPODAPBAY-UHFFFAOYSA-N [La].ClOCl Chemical compound [La].ClOCl JEROREPODAPBAY-UHFFFAOYSA-N 0.000 description 1
- MCVAAHQLXUXWLC-UHFFFAOYSA-N [O-2].[O-2].[S-2].[Gd+3].[Gd+3] Chemical compound [O-2].[O-2].[S-2].[Gd+3].[Gd+3] MCVAAHQLXUXWLC-UHFFFAOYSA-N 0.000 description 1
- 230000009102 absorption Effects 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229910052650 alkali feldspar Inorganic materials 0.000 description 1
- HXFVOUUOTHJFPX-UHFFFAOYSA-N alumane;zinc Chemical compound [AlH3].[Zn] HXFVOUUOTHJFPX-UHFFFAOYSA-N 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- SNAAJJQQZSMGQD-UHFFFAOYSA-N aluminum magnesium Chemical compound [Mg].[Al] SNAAJJQQZSMGQD-UHFFFAOYSA-N 0.000 description 1
- WAKZZMMCDILMEF-UHFFFAOYSA-H barium(2+);diphosphate Chemical compound [Ba+2].[Ba+2].[Ba+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O WAKZZMMCDILMEF-UHFFFAOYSA-H 0.000 description 1
- 229910000416 bismuth oxide Inorganic materials 0.000 description 1
- 229910052810 boron oxide Inorganic materials 0.000 description 1
- 229910052980 cadmium sulfide Inorganic materials 0.000 description 1
- UHYPYGJEEGLRJD-UHFFFAOYSA-N cadmium(2+);selenium(2-) Chemical compound [Se-2].[Cd+2] UHYPYGJEEGLRJD-UHFFFAOYSA-N 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 235000011010 calcium phosphates Nutrition 0.000 description 1
- 229910000420 cerium oxide Inorganic materials 0.000 description 1
- 150000004770 chalcogenides Chemical class 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 description 1
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 1
- 239000002019 doping agent Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 description 1
- KJZYNXUDTRRSPN-UHFFFAOYSA-N holmium atom Chemical compound [Ho] KJZYNXUDTRRSPN-UHFFFAOYSA-N 0.000 description 1
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- DALUDRGQOYMVLD-UHFFFAOYSA-N iron manganese Chemical compound [Mn].[Fe] DALUDRGQOYMVLD-UHFFFAOYSA-N 0.000 description 1
- MTRJKZUDDJZTLA-UHFFFAOYSA-N iron yttrium Chemical compound [Fe].[Y] MTRJKZUDDJZTLA-UHFFFAOYSA-N 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- LQFNMFDUAPEJRY-UHFFFAOYSA-K lanthanum(3+);phosphate Chemical compound [La+3].[O-]P([O-])([O-])=O LQFNMFDUAPEJRY-UHFFFAOYSA-K 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 description 1
- GFKJCVBFQRKZCJ-UHFFFAOYSA-N oxygen(2-);yttrium(3+);trisulfide Chemical compound [O-2].[O-2].[O-2].[S-2].[S-2].[S-2].[Y+3].[Y+3].[Y+3].[Y+3] GFKJCVBFQRKZCJ-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229910052655 plagioclase feldspar Inorganic materials 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 229910052665 sodalite Inorganic materials 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- JOPDZQBPOWAEHC-UHFFFAOYSA-H tristrontium;diphosphate Chemical compound [Sr+2].[Sr+2].[Sr+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O JOPDZQBPOWAEHC-UHFFFAOYSA-H 0.000 description 1
- LSGOVYNHVSXFFJ-UHFFFAOYSA-N vanadate(3-) Chemical class [O-][V]([O-])([O-])=O LSGOVYNHVSXFFJ-UHFFFAOYSA-N 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 229910000164 yttrium(III) phosphate Inorganic materials 0.000 description 1
- UXBZSSBXGPYSIL-UHFFFAOYSA-K yttrium(iii) phosphate Chemical compound [Y+3].[O-]P([O-])([O-])=O UXBZSSBXGPYSIL-UHFFFAOYSA-K 0.000 description 1
- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/36—Identification or security features, e.g. for preventing forgery comprising special materials
- B42D25/378—Special inks
- B42D25/382—Special inks absorbing or reflecting infrared light
-
- G—PHYSICS
- G07—CHECKING-DEVICES
- G07D—HANDLING OF COINS OR VALUABLE PAPERS, e.g. TESTING, SORTING BY DENOMINATIONS, COUNTING, DISPENSING, CHANGING OR DEPOSITING
- G07D7/00—Testing specially adapted to determine the identity or genuineness of valuable papers or for segregating those which are unacceptable, e.g. banknotes that are alien to a currency
- G07D7/004—Testing specially adapted to determine the identity or genuineness of valuable papers or for segregating those which are unacceptable, e.g. banknotes that are alien to a currency using digital security elements, e.g. information coded on a magnetic thread or strip
- G07D7/0043—Testing specially adapted to determine the identity or genuineness of valuable papers or for segregating those which are unacceptable, e.g. banknotes that are alien to a currency using digital security elements, e.g. information coded on a magnetic thread or strip using barcodes
-
- G—PHYSICS
- G07—CHECKING-DEVICES
- G07D—HANDLING OF COINS OR VALUABLE PAPERS, e.g. TESTING, SORTING BY DENOMINATIONS, COUNTING, DISPENSING, CHANGING OR DEPOSITING
- G07D7/00—Testing specially adapted to determine the identity or genuineness of valuable papers or for segregating those which are unacceptable, e.g. banknotes that are alien to a currency
- G07D7/06—Testing specially adapted to determine the identity or genuineness of valuable papers or for segregating those which are unacceptable, e.g. banknotes that are alien to a currency using wave or particle radiation
- G07D7/12—Visible light, infrared or ultraviolet radiation
- G07D7/1205—Testing spectral properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
- B41M3/14—Security printing
- B41M3/144—Security printing using fluorescent, luminescent or iridescent effects
Definitions
- the invention relates to a document of value with a luminescent feature and in particular relates to a flat document of value, such as a banknote, which has a surface area with a longitudinal direction and a transverse direction and which is provided with a luminescence feature in the surface area.
- the invention also relates to a value document system consisting of a plurality of different such documents of value, a method for producing such a flat document of value and a method for checking such a flat document of value.
- a sensor When authenticating or classifying a document of value, for example, a sensor illuminates it with excitation light and detects the light emitted by the document of value in response in order to detect characteristic properties of the feature or a feature intensity. The recorded properties are then compared with reference or threshold values in order to assign the feature and thus the value document to a class.
- the valuable document can, for example, be assigned to one of the classes “genuine” or “suspected of being a counterfeit”.
- luminescent features to a semi-finished product during the production of a document of value in the form of powdery substances or pigments, for example a paper pulp, a master batch/polymer melt, or a printing ink, a clear varnish or a color concentrate.
- the semi-finished product is, for example, in the form of a pulp, a value document substrate in web or sheet form
- Printed product in the form of a web, a sheet or a single use a film element, for example a patch, a thread, a film strip or planchets, a fiber or a printing ink or a color concentrate is further processed into the finished document of value.
- a luminescent feature powder can be added to a printing ink and thus an imprint can be created on a valuable document substrate.
- Combinations of different luminescent substances can be used to create individual codings for different classes of valuable documents.
- the invention is based on the object of providing a document of value of the type mentioned at the outset, which allows reliable checking or classification of the document of value with a high degree of security against forgery.
- the invention is also intended to provide a manufacturing method and a method for checking such documents of value. This task is solved by the features of the independent claims. Further developments of the invention are the subject of the dependent claims.
- the luminescence feature of a generic flat document of value comprises a first luminescence marker in a first partial area and a second luminescence marker in a second, different partial area.
- the first and second luminescence markers can be excited to luminescence at the same wavelength, hereinafter also referred to in places as the excitation wavelength, and, after excitation, luminesce essentially in the same emission band in the infrared spectral range.
- the emission band can preferably be the contiguous wavelength range or the wavelength interval of the emission spectrum around the maximum intensity in the infrared spectral range, in which the intensity is greater than 5% of the maximum intensity of the emission spectrum in the infrared spectral range.
- the emission bands are preferably substantially the same if the emission bands overlap by more than 90% of the width of the broader emission band.
- the first and second luminescent markers have spectrally similar infrared emission spectra, namely infrared emission spectra that have a spectral difference between 0.5% and 15%.
- the spectral difference of the emission spectra of the first and second luminescence markers can in particular be given as the maximum of the amount of the difference spectrum of the two emission spectra, each standardized to the emission maximum, in the spectral range that is formed by or includes the emission bands.
- the first and second partial areas are arranged to overlap each other in the surface area in projection on the longitudinal direction and/or in projection on the transverse direction.
- the surface area is identical to the document of value, i.e. H. the edges of the surface area correspond to the edges of the value document.
- the longitudinal direction denotes the direction of the longer dimension
- the transverse direction the perpendicular direction of the shorter dimension of the surface area.
- the dimensions of the longitudinal and transverse directions are the same.
- the document of value can be designed as a banknote.
- the document of value can also be a page of a book-shaped document of value, such as a passport.
- the first and second subareas can in particular be located on the same page of a book-shaped document of value.
- the longitudinal direction or transverse direction can indicate the direction of the longer or shorter dimension of this side.
- the spectral similarity of the two luminescence markers or their infrared emission spectra ensures that environmental influences and/or variations in the sensors used to record the luminescence emission have a similar effect on the measurement of the two luminescence markers and can therefore be well compensated for by a differential evaluation.
- the small spectral difference between the two emission spectra also leads to an increase in the security against counterfeiting of the document of value, since a potential forger can only use one when analyzing an original document of value within the scope of measurement accuracy will recognize a single, identically appearing luminescence and will at best attempt to recreate this single luminescence.
- the first and second luminescence markers or their infrared emission spectra advantageously have a spectral difference between 1% and 11%, preferably between 2% and 7%.
- the first and second luminescence markers can expediently be excited with a wavelength in the wavelength range from 700 to 2500 nm, preferably in the wavelength range from 900 to 2100 nm.
- the first and second luminescence markers are selected so that they luminesce after excitation in the wavelength range from 700 to 2500 nm, preferably from 900 to 2100 nm.
- the emission wavelength is preferably larger than the excitation wavelength, in particular larger by a maximum of 100 nm.
- the two luminescence markers advantageously show essentially no upconversion and, in particular after excitation, emit essentially no light, for example less than 1% of their total emission power, in the visible spectral range.
- the luminescence of the luminescent feature cannot then be perceived by the unarmed human eye and represents a hidden security feature with a high security effect.
- the first and/or second luminescence marker advantageously contains an organic, organometallic or inorganic luminescent substance.
- luminescent substances are doped inorganic pigments with the dopants neodymium and/or ytterbium and/or erbium and/or thulium and/or holmium or doped with certain transition metals such as manganese.
- organometallic complexes with neodymium and/or ytterbium and/or erbium or certain organic dyes are examples of suitable inorganic matrices: Oxides, especially 3- and 4-valent oxides such as. B.
- B. grenades including z.
- Perovskites including, but not limited to, yttrium aluminum perovskite, lanthanum gallium perovskite;
- Spinels including, but not limited to, zinc-aluminum spinels, magnesium-aluminum spinels, manganese-iron spinels; or mixed oxides such as B.
- ITO indium tin oxide
- Oxyhalides and oxy-chalcogenides especially oxychlorides such as. B. yttrium oxychloride, lanthanum oxychloride; as well as oxysulfides, such as. B. yttrium oxysulfide, gadolinium oxysulfide; Sulphides and other chalcogenides, e.g. B.
- Sulfates especially barium sulfate and strontium sulfate; Phosphates, in particular barium phosphate, strontium phosphate, calcium phosphate, yttrium phosphate, lanthanum phosphate, as well as more complex phosphate-based compounds such as apatites, including, among others, calcium hydroxyapatites, calcium fluoroapatites, calcium chloroapatites; or spodiosite, including e.g. B.
- zeolites such as. B. Zeolite A, Zeolite Y; zeolite-related compounds such as B. Sodalite; Feldspars such as B. alkali feldspars, plagioclase; other inorganic compound classes such as. E.g. vanadates, germanates, arsenates, niobates, tantalates.
- the first and second luminescent markers each contain only a single luminescent substance.
- the first and/or second luminescent markers can also contain several luminescent substances.
- the latter allows very precise differences between the two luminescence markers to be set in a simple manner in terms of production technology.
- the first and second luminescent markers contain a common luminescent substance and at least one of the luminescent markers contains an additional luminescent substance which produces the small spectral difference between the two luminescent markers.
- different luminescent substances with very similar emission spectra can be used for the two luminescence markers, which can be achieved, for example, by slightly different process management during production or by slightly different chemical composition of the starting materials.
- the first and second luminescence markers differ, in addition to the mentioned spectral difference, also by the onset and/or decay times of the emission at one, several or even all emission wavelengths. This further increases the separability of the luminescence markers and thus the number of possible distinguishable codings.
- the first and second luminescent markers are each arranged in a printing ink area printed on the document of value.
- the first and second luminescent markers can be present in visually invisible printing ink areas.
- the first and second luminescent markers are in visually visible printing color areas, advantageously present in infrared-transparent printing color areas. The latter prevents any absorptions in the printing ink from interfering with the measurement of infrared luminescence.
- the combination of a visually invisible printing color area and a visually visible printing color area is also possible. This increases creative freedom.
- the first luminescence marker is arranged in a printing ink area printed on the document of value, while the second luminescence marker is arranged in a security element, in particular a strip or patch, applied to the document of value.
- the first and second subregions can be arranged in various ways.
- the first and second subregions are preferably disjoint, that is, there is no overlap region in which both the first and the second luminescence marker are present. This simplifies both the production, for example the printing process, and the evaluation of a measurement of the luminescence feature.
- each partial area there is an overlap area in which both luminescent markers are present.
- first and second partial areas are only arranged to overlap in a projection in a single direction, this is preferably the shorter transverse direction. This ensures that the same measurement track of a feature sensor can measure both the first luminescence marker in the first sub-area and the second luminescence marker in the second sub-area when the document of value is transported longitudinally past a usual short-edge-leading sensor.
- the first and second subregions are advantageously arranged to overlap one another even in projection in both directions, i.e. longitudinal and transverse directions. This has the advantage that the banknote can be checked on both longitudinal and transverse measuring processing machines and the same measuring track can be used to measure the two luminescence markers.
- the two subareas themselves do not overlap.
- the luminescence feature comprises only a single first subregion and only a single second subregion, wherein the first and second subregions are arranged to overlap each other in the surface region both in projection on the longitudinal direction and in projection on the transverse direction.
- first and/or second sub-area can also each consist of several non-contiguous sub-areas.
- the luminescence feature forms a barcode, the bar elements of which are formed by partial areas with different luminescence markers.
- the barcode can be one-dimensional, multi-line or two-dimensional. If A denotes a first and B a second luminescence marker, the subregions can be designed, for example, in the form ABA, ABBA, ABBAB, etc. For multi-line barcodes, it is advantageous to use the same luminescence marker A as a reference marker in each line.
- a one-dimensional or multi-line barcode can in particular be formed by several, for example three, different luminescence markers A, B, C, with one of the luminescence markers, for example the luminescence marker A, being used as a reference marker for the precise measurement of the spectral signatures of the other luminescence markers B and C.
- the same luminescence marker A is advantageously used as a reference marker in each line. In this case you can For example, only two different luminescence markers can be used per line, for example in the luminescence markers A and B in even lines and the luminescence markers A and C in odd lines.
- the luminescence feature comprises at least a third subregion, different from the first and second subregions, with a third luminescence marker, which has a spectrally similar infrared emission spectrum to the first and in particular also the second luminescence marker has, with a spectral difference between 0.5% and 15%. It goes without saying that further subregions with further luminescence markers can also be provided in the same way.
- the invention also contains a value document system made up of a plurality of different value documents of the type described, in which the value documents of the value document system all have the same luminescence marker in the first sub-area and different luminescence markers in the second sub-area.
- the luminescent marker of the first sub-area serves as a common reference marker, the different luminescent markers of the second sub-area for checking and/or classifying the valuable documents.
- the value document system can, for example, contain the various banknotes of a series with several different denominations.
- Banknotes of different denominations contain different luminescent markers in the second section, but the same reference marker in the first section.
- the banknotes of different denominations can be reliably distinguished from one another despite the spectral similarity of the luminescence markers of the respective second subareas.
- the invention also contains a method for producing a flat document of value of the type described, in which a substrate of value document with an in a surface area extending in a longitudinal direction and a transverse direction is provided.
- the value document substrate is provided with a luminescence feature in the surface area by arranging a first luminescence marker in a first subregion and a second luminescence marker in a second, different subregion in the surface area in such a way that the first and second subregions face each other in projection onto the longitudinal direction and/or or overlap in projection on the transverse direction.
- the first and second luminescence markers can be excited to luminescence at the same wavelength and, after excitation, luminesce essentially in the same emission band in the infrared spectral range. Furthermore, the first and second luminescence markers have spectrally similar infrared emission spectra, namely infrared emission spectra which have a spectral difference between 0.5% and 15%.
- the first and second luminescent markers are printed onto the valuable document substrate, preferably using different printing processes.
- Advantageous printing processes that can be used are, in particular, offset, intaglio, gravure, number, flexo, or screen printing.
- the first and second luminescent markers are printed onto the valuable document substrate using the same printing process.
- the first luminescent marker is printed onto the valuable document substrate.
- the second luminescent marker is in a security element, in particular a strip or patch, arranged, and the security element with the second luminescent marker is applied to the valuable document substrate or introduced into the valuable document substrate.
- the invention also contains a method for testing a flat document of value of the type described, in which the luminescence emissions of the two luminescence markers of the first and second sub-areas are detected together or the flat document of value is transported and during transport the luminescence emissions of the two luminescence markers of the first are detected by means of a sensor and second subregion are recorded, and in which the spectral properties of the second luminescence marker are evaluated relative to the spectral properties of the first luminescence marker.
- an authenticity signal can then be formed and issued, which represents the result of the evaluation.
- the subregions are excited with excitation radiation of the excitation wavelength from a radiation source.
- the radiation source can preferably be part of the sensor.
- the luminescence emissions of the two luminescence markers are advantageously recorded together in that the luminescence emissions of the two luminescence markers are recorded immediately one after the other, for example during a continuous transport of the document of value past a sensor, along a measurement track that covers both partial areas.
- the measuring track is advantageously oriented parallel to the longitudinal direction or to the transverse direction of the surface area.
- the document of value can in particular be transported parallel to the longitudinal direction or to the transverse direction of the document of value.
- the luminescence emission of the two luminescence markers is advantageously detected with a single-track or multi-track luminescence sensor with at least two spectral channels.
- the sensor mentioned can comprise a single-track or multi-track luminescence sensor with at least two spectral channels.
- FIG. 1 is a schematic representation of a banknote that extends in a surface area with a longitudinal direction E and a transverse direction Q,
- FIG. 6 shows a schematic representation of a banknote with a different design of the partial areas with spectrally similar luminescence markers
- Fig. 10 is a schematic representation of a device for checking the banknote in Fig. 1, and
- Fig. 11 is a roughly schematic flowchart of a method for checking the banknote in Fig. 1 using the device in Fig. 10.
- FIG. 1 shows a schematic representation of a banknote 10, which has a surface area with a longitudinal direction L and a transverse direction Q.
- the banknote 10 is provided in the surface area with a luminescent feature 12, which contains a first luminescent marker in a first partial area 14 and a second luminescent marker in a second partial area 16.
- the first and second partial areas 14, 16 are disjoint, i.e. have no overlap, but are arranged at a distance from one another in the surface area. It is important that the two partial areas 14, 16 are arranged in the surface area in such a way that they overlap each other in projection onto the transverse direction Q of the banknote 10.
- the projection 14-P of the partial area 14 and the projection 16-P of the partial area 16 onto the transverse direction Q are shown on the right in FIG. As can be seen, the two projections 14-P, 16-P overlap in an overlap area 18.
- both the partial area 14 with the first luminescent marker and the partial area 16 are included the second luminescence marker is swept one after the other at short intervals.
- the luminescence markers of the subregions 14, 16 can be excited at the same wavelength or excitation wavelength and, after excitation, luminesce essentially in the same emission band in the infrared spectral range.
- the emission bands are each given by the contiguous wavelength range or the wavelength interval of the emission spectrum around the maximum intensity in the infrared spectral range, in which the intensity is greater than 5% of the maximum intensity of the emission spectrum in the infrared spectral range.
- the luminescence markers are coordinated with one another in such a way that their emission spectra are spectrally very similar to one another and are influenced in the same way by the ambient conditions and the measurement conditions.
- the diagram 30 of FIG. 2(a) shows the emission spectrum 34 of the first luminescence marker of the first subregion 14 and the emission spectrum 36 of the second luminescence marker of the second subregion 16, each plotted as an intensity normalized to the emission maximum over the wavelength in arbitrary units .
- the emission spectra 34, 36 are very similar to one another, only the emission maximum of the spectrum 36 of the second luminescence marker is slightly shifted relative to the emission maximum of the spectrum 34 of the first luminescence marker.
- the difference spectrum 38 of the two emission spectra 34, 36 is shown in diagram 32 of FIG.
- the spectral difference between two emission spectra 34, 36 is defined, for example, as the maximum of the magnitude of the difference spectrum 38 of the emission spectra normalized to the emission maximum, expressed in percent.
- the maximum amount of the difference spectrum 38 at the locations of the maximum 38-Max and the minimum 38-Min is 0.1, so that the spectral difference between the two emission spectra is 10%.
- FIG. 3 the emission spectra of another combination of a first and second luminescence marker with an even smaller mutual shift of the peak wavelengths of the emission spectra upon excitation with the excitation wavelength are illustrated in a representation as in Fig. 2.
- the diagram 40 of FIG. 3(a) shows the emission spectrum 44 of the first luminescence marker and the emission spectrum 46 of the second luminescence marker
- the diagram 42 of FIG. 3(b) shows the difference spectrum 48 of the two emission spectra 44, 46.
- the maximum The amount of the difference spectrum 48 for these two luminescence markers is only 0.043, the spectral difference between the two emission spectra is therefore 4.3%.
- FIG. 4 shows in the same representation the emission spectra of a further combination of two luminescence markers, which show an identical main emission 50 and only differ in the position of the maximum of the secondary emission 52.
- Figure 4(a) shows the emission spectrum 54 of a first luminescence marker and the emission spectrum 56 of a second luminescence marker
- Figure 4(b) shows the difference spectrum 58 of the two emission spectra 54, 56. Because of the identical main emission 50 of the two luminescence markers, the difference spectrum 58 differs only in the area of the secondary emission 52 significantly from zero and shows a maximum magnitude deviation of the two spectra of 0.024, i.e. a spectral difference of 2.4%.
- FIG. 5 A further variant is illustrated in FIG. 5, in which the emission spectra of two luminescence markers are shown, which show an identical main emission 60, but a differently intense secondary emission 62.
- Figure 5(a) shows the emission spectrum 64 of the first luminescence marker and the emission spectrum 66 of the second luminescence marker.
- the intensity Int is plotted on the ordinate and the wavelength X is plotted on the abscissa.
- the difference spectrum 68 of the two emission spectra 64, 66 shows the difference spectrum 68 of the two emission spectra 64, 66.
- the difference spectrum 68 essentially only deviates from zero in the area of the secondary emission 62 and shows a maximum absolute deviation of the two spectra from 0 ,1, i.e. a spectral difference of 10%.
- the device for checking flat documents of value illustrated in FIG. 10 can be used.
- This device can be part of a device (not shown) for processing valuable documents.
- This includes a transport device 136 for transporting a document of value 10 in a transport direction T past a sensor 138 for detecting luminescence emissions from the document of value 10.
- the sensor 138 in the example a luminescence sensor, is designed to detect luminescence emissions from the document of value 10, in the example of the banknote in FIG. 1, and to form detection signals which reflect properties, in particular spectral properties, of the detected luminescence emissions.
- An evaluation device 140 is connected to the sensor 138 via a signal connection, which processes detection signals formed by the sensor 138 while the document of value is being transported past the same sensor 138.
- the sensor 138 in particular comprises a radiation source for emitting radiation of the excitation wavelength onto a document of value to be checked and a detector for spectrally resolved detection of the luminescence emissions generated by excitation with the excitation radiation.
- a document of value 10 for example the banknote 10 in FIG. 1, it is transported past the sensor 138 by means of the transport device 136.
- the document of value is aligned relative to the transport device such that the long side of the document of value runs parallel to the transport direction T in which the document of value 10 is transported.
- step S10 at least one luminescence emission of the luminescence marker in the first subregion is detected by means of the sensor 138, since it first enters a detection region of the sensor 138.
- First detection signals are formed which reflect the spectral properties of the detected luminescence emission. These are fed to the evaluation device 140.
- step S12 at least one luminescence emission of the luminescence marker in the second sub-area is detected by means of the sensor 138, i.e. the same sensor, since it enters the detection area of the sensor 138 after the first sub-area. Second detection signals are formed and reflect the spectral properties of the detected luminescence emission. These are also fed to the evaluation device 140.
- step S14 the evaluation device 140 then uses the supplied first and second detection signals to determine the spectral properties of the Emission of the first luminescence marker or the first luminescence marker is evaluated relative to the spectral properties of the emission of the second luminescence marker or the second luminescence marker. Depending on the result of the evaluation, an authenticity signal is then formed and emitted, which represents the result of the evaluation.
- the authenticity signal can be sent to a device that controls further processing of the document of value.
- both partial areas 74, 76 can be swept by a feature sensor, so that the banknote 70 can be used in both longitudinally and transversely measuring banknote processing machines can be checked.
- FIG. 7(a) shows the surface area 80 of a document of value with a plurality of spaced-apart first sub-areas 84 with a first luminescent marker and with a single second sub-area 86 with a second luminescent marker.
- measuring tracks 20, 22 each capture both a first and a second partial area in the longitudinal and transverse directions, so that the document of value with the surface area 80 can be checked both longitudinally and transversely.
- the same effect can be achieved with a design as shown in FIG.
- the measuring tracks 20, 22 each capture both a first and a second partial area in the longitudinal and transverse directions.
- the first and second subregions are not disjoint, but rather overlapping in regions, as shown in Fig. 7(c).
- the surface area 80 contains a first partial area 84 with a first luminescence marker and a second partial area 86 with a second luminescence marker, which overlap in the overlap areas 88. It is important that there are also non-overlapping areas in which only the first or only the second luminescence marker alone is present. 7(c), the measurement tracks 20, 22 each detect non-overlapping areas of the first and second partial areas 84, 86 in the longitudinal and transverse directions and therefore, as in the previously described designs, allow a differential evaluation of the measurement signals .
- Fig. 8(a) shows two comparison banknotes 90, 94, each of which was printed in a partial area 92 and 96, respectively, with an infrared-stimulable luminescent marker that luminesces in the infrared.
- the partial area 92 of the first comparison banknote 90 contains a luminescence marker "B”
- the partial area 96 of the second comparison banknote 94 contains a luminescence marker "C”
- the spectral difference between the two luminescence markers being 3%.
- the comparison banknotes 90, 94 were measured with three identical feature sensors at several transport speeds between 1 m/s and 11 m/s and at several measuring points within the respective sub-area 92, 96 and a measure was created from the measured values for the spectral position, for example the spectral center of gravity of a local emission maximum or an emission band, of the luminescence emission of the two luminescence markers.
- the spectral center of gravity of an emission band for example, the wavelength of the emission maximum or the wavelength of another spectral feature, for example a secondary maximum, a minimum or a shoulder in the emission spectrum, can also be used as a measure of the spectral position.
- Figure 8(b) shows the number N of measurement results in a histogram 100, plotted against the respective determined spectral position for the two luminescence markers “B” and “C”.
- the distributions 102, 104 of the spectral positions determined for the two luminescence markers have a non-negligible overlap, so that a reliable distinction between the two luminescence markers is not possible due to the magnitude of the fluctuations that occur.
- the causes of such fluctuations could be, for example, variations between the nominally identical sensors, or variations in the environmental conditions such as temperature, transport distance, or transport speed.
- FIG. 9(a) shows two banknotes 110, 120 according to the invention, which can, for example, be part of a value document system mentioned above.
- the banknotes 110, 120 each contain a further luminescence marker “A” as a reference marker.
- the emission spectrum of the luminescence marker "A” lies between the emission spectra of the luminescence markers "B” and “C” and is therefore spectrally similar to both luminescence markers with a spectral difference of approximately 0.5% and approximately 3%, respectively.
- the banknote 110 is printed in a configuration as in FIG.
- the banknote 120 is also printed in a configuration as in FIG. 1 in a first partial area 124 with the luminescent marker "A” and in a second partial area 126 with the luminescent marker "C" of the comparison banknote 94.
- the two partial areas 124, 126 overlap in projection onto the transverse direction Q and can both be recorded with a measurement track.
- the banknotes 110, 120 according to the invention were then measured with the same three identical feature sensors and the same transport speeds between 1 m/s and 11 m/s as the comparison banknotes at several measuring points within the respective subareas 114, 116 and 124, 126, respectively.
- the spectral position of the luminescence emission of the second portion 116 of the banknote 110 with the luminescence marker "B” and of the second portion 126 of the banknote 120 with the luminescence marker “C” was not absolute, but relative to the luminescence emission of the luminescence marker "A" of the respective first portion 114 or 124 determined.
- Figure 9(b) shows in a histogram 130 the number N of measurement results obtained, plotted against the respective determined spectral position of the two luminescence markers "B” and “C” relative to the spectral position of the luminescence marker "A” (zero point in Fig. 9(b) ).
- the checking of documents of value according to the invention can be carried out in particular with a single-track or multi-track luminescence sensor with at least 2 spectral channels K1, K2, which can use these spectral channels to detect the differences in the luminescence markers used on a document of value.
- the two spectral channels advantageously capture closely spaced or even directly adjacent spectral regions of the emission spectra. If, for example, the emission band of the two luminescence markers lies spectrally approximately in the middle between the spectral sensitivity ranges of the two spectral channels, small shifts in the peak wavelength can be determined with high precision.
- a spectral channel can be selected at position K1 below the central wavelength X z and a second spectral channel at position K2 above the central wavelength X z at the same distance from the central wavelength. It is also advantageously possible to use spectral channels with a width of several, for example between 2 and 50, nanometers.
- Spectral channels are used to precisely sample the shape of the emission spectra.
- the spectral channels of a luminescence sensor are adapted to certain, more complex emission spectra, so that individual peaks of the emission spectra can be detected through a few different channels.
- a feature sensor with three spectral channels can be used, which detect the luminescence emission at the wavelength positions indicated in the figure, namely on the one hand in the area of the maximum of the main emission 50 at position K1 and on the other hand symmetrically on both sides the maximum of the secondary emission 52 at positions K2 and K3.
- a feature sensor with two spectral channels is sufficient, with which the luminescence emission can be detected in the area of the maximum of the main emission 60 at position K1 and in the area of the maximum of the secondary emission 62 at position K2.
- Luminescent feature 16 partial areas -P, 16-P projections
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Citations (6)
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WO2011082794A1 (de) * | 2009-12-16 | 2011-07-14 | Giesecke & Devrient Gmbh | Echtheitsmerkmal in form von lumineszierenden substanzen |
EP2604441A1 (de) * | 2010-08-09 | 2013-06-19 | Dai Nippon Printing Co., Ltd. | Lichtemittierendes medium |
WO2017102723A1 (en) * | 2015-12-17 | 2017-06-22 | Sicpa Holding Sa | Security element formed from at least two materials present in partially or fully overlapping areas, articles carrying the security element, and authentication methods |
DE102017003746A1 (de) * | 2017-04-18 | 2018-10-18 | Giesecke+Devrient Currency Technology Gmbh | Wertdokument mit Sicherheitsmarkierung mit variierender Abklingzeit und Verfahren zum Identifizieren der Sicherheitsmarkierung |
WO2020052812A1 (de) * | 2018-09-14 | 2020-03-19 | Giesecke+Devrient Currency Technology Gmbh | Wertdokumentsystem |
DE102019006315A1 (de) * | 2019-09-06 | 2021-03-11 | Giesecke+Devrient Currency Technology Gmbh | Optisch variables Sicherheitselement |
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DE102013008507A1 (de) | 2013-05-16 | 2014-11-20 | Giesecke & Devrient Gmbh | Sicherheitselement, Herstellungsverfahren, mit dem Sicherheitselement ausgestatteter Datenträger und Verfahren zum Überprüfen der Echtheit |
CN107148357B (zh) | 2015-01-09 | 2019-04-12 | 大日本印刷株式会社 | 发光介质及发光介质的读取方法 |
CN104988798B (zh) | 2015-07-24 | 2017-06-06 | 中国人民银行印制科学技术研究所 | 一种防伪纤维及其制备方法 |
DE102021002495A1 (de) | 2021-05-11 | 2022-11-17 | Giesecke+Devrient Currency Technology Gmbh | Sicherheitselement mit Lumineszenzmerkmal und Datenträger mit einem solchen Sicherheitselement |
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Patent Citations (6)
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WO2011082794A1 (de) * | 2009-12-16 | 2011-07-14 | Giesecke & Devrient Gmbh | Echtheitsmerkmal in form von lumineszierenden substanzen |
EP2604441A1 (de) * | 2010-08-09 | 2013-06-19 | Dai Nippon Printing Co., Ltd. | Lichtemittierendes medium |
WO2017102723A1 (en) * | 2015-12-17 | 2017-06-22 | Sicpa Holding Sa | Security element formed from at least two materials present in partially or fully overlapping areas, articles carrying the security element, and authentication methods |
DE102017003746A1 (de) * | 2017-04-18 | 2018-10-18 | Giesecke+Devrient Currency Technology Gmbh | Wertdokument mit Sicherheitsmarkierung mit variierender Abklingzeit und Verfahren zum Identifizieren der Sicherheitsmarkierung |
WO2020052812A1 (de) * | 2018-09-14 | 2020-03-19 | Giesecke+Devrient Currency Technology Gmbh | Wertdokumentsystem |
DE102019006315A1 (de) * | 2019-09-06 | 2021-03-11 | Giesecke+Devrient Currency Technology Gmbh | Optisch variables Sicherheitselement |
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