WO2023192088A1 - A method of weed control in sugar beet - Google Patents
A method of weed control in sugar beet Download PDFInfo
- Publication number
- WO2023192088A1 WO2023192088A1 PCT/US2023/016009 US2023016009W WO2023192088A1 WO 2023192088 A1 WO2023192088 A1 WO 2023192088A1 US 2023016009 W US2023016009 W US 2023016009W WO 2023192088 A1 WO2023192088 A1 WO 2023192088A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- sugar beet
- benzyl
- florpyrauxifen
- control
- vegetation
- Prior art date
Links
- 241000219310 Beta vulgaris subsp. vulgaris Species 0.000 title claims abstract description 34
- 235000021536 Sugar beet Nutrition 0.000 title claims abstract description 32
- 238000000034 method Methods 0.000 title claims abstract description 16
- 241000196324 Embryophyta Species 0.000 title claims description 25
- WNZCDFOXYNRBRB-UHFFFAOYSA-N florpyrauxifen-benzyl Chemical group COC1=C(Cl)C=CC(C=2C(=C(N)C(Cl)=C(C(=O)OCC=3C=CC=CC=3)N=2)F)=C1F WNZCDFOXYNRBRB-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000002689 soil Substances 0.000 claims abstract description 3
- ZTMKADLOSYKWCA-UHFFFAOYSA-N lenacil Chemical compound O=C1NC=2CCCC=2C(=O)N1C1CCCCC1 ZTMKADLOSYKWCA-UHFFFAOYSA-N 0.000 claims description 6
- VHCNQEUWZYOAEV-UHFFFAOYSA-N metamitron Chemical compound O=C1N(N)C(C)=NN=C1C1=CC=CC=C1 VHCNQEUWZYOAEV-UHFFFAOYSA-N 0.000 claims description 6
- IRCMYGHHKLLGHV-UHFFFAOYSA-N 2-ethoxy-3,3-dimethyl-2,3-dihydro-1-benzofuran-5-yl methanesulfonate Chemical compound C1=C(OS(C)(=O)=O)C=C2C(C)(C)C(OCC)OC2=C1 IRCMYGHHKLLGHV-UHFFFAOYSA-N 0.000 claims description 4
- 239000005572 Lenacil Substances 0.000 claims description 4
- 239000005579 Metamitron Substances 0.000 claims description 4
- 239000000828 canola oil Substances 0.000 claims description 4
- 235000019519 canola oil Nutrition 0.000 claims description 4
- 239000005512 Ethofumesate Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 description 8
- 239000004009 herbicide Substances 0.000 description 7
- 230000002363 herbicidal effect Effects 0.000 description 6
- 240000006122 Chenopodium album Species 0.000 description 5
- 244000044980 Fumaria officinalis Species 0.000 description 4
- 235000006961 Fumaria officinalis Nutrition 0.000 description 4
- 240000006694 Stellaria media Species 0.000 description 4
- 241000394440 Viola arvensis Species 0.000 description 4
- 241000335053 Beta vulgaris Species 0.000 description 3
- 235000009344 Chenopodium album Nutrition 0.000 description 3
- 244000303225 Lamium amplexicaule Species 0.000 description 3
- 235000009198 Lamium amplexicaule Nutrition 0.000 description 3
- 239000004480 active ingredient Substances 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 238000003306 harvesting Methods 0.000 description 3
- 230000000007 visual effect Effects 0.000 description 3
- 235000021533 Beta vulgaris Nutrition 0.000 description 2
- 235000011498 Chenopodium album var missouriense Nutrition 0.000 description 2
- 235000013328 Chenopodium album var. album Nutrition 0.000 description 2
- 235000014052 Chenopodium album var. microphyllum Nutrition 0.000 description 2
- 235000014050 Chenopodium album var. stevensii Nutrition 0.000 description 2
- 235000013012 Chenopodium album var. striatum Nutrition 0.000 description 2
- 244000248416 Fagopyrum cymosum Species 0.000 description 2
- 241001289540 Fallopia convolvulus Species 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 230000000051 modifying effect Effects 0.000 description 2
- 229930192334 Auxin Natural products 0.000 description 1
- 241000520028 Lamium Species 0.000 description 1
- 241000221026 Mercurialis annua Species 0.000 description 1
- 240000000111 Saccharum officinarum Species 0.000 description 1
- 235000007201 Saccharum officinarum Nutrition 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- 241001148683 Zostera marina Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000002363 auxin Substances 0.000 description 1
- 229940000425 combination drug Drugs 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- XFZUQTKDBCOXPP-UHFFFAOYSA-N florpyrauxifen Chemical compound COC1=C(Cl)C=CC(C=2C(=C(N)C(Cl)=C(C(O)=O)N=2)F)=C1F XFZUQTKDBCOXPP-UHFFFAOYSA-N 0.000 description 1
- SEOVTRFCIGRIMH-UHFFFAOYSA-N indole-3-acetic acid Chemical compound C1=CC=C2C(CC(=O)O)=CNC2=C1 SEOVTRFCIGRIMH-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000003278 mimic effect Effects 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 230000008121 plant development Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
- A01P13/00—Herbicides; Algicides
- A01P13/02—Herbicides; Algicides selective
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
Definitions
- the sugar beet crop is a widely grown row crop with 4 million hectares planted in
- 2019 ALS-herbicide-tolerant sugar beet varieties e.g., CONVISO® SMART seeds, available from KWS seed company
- CONVISO® SMART seeds available from KWS seed company
- CONVISO SMART varieties allow the control of weeds in sugar beet by the application of a product named “Conviso® One” that contains two ALS inhibitor herbicides (floramsulfuron 50g/l + thiecarbozone 30g/l) formulated as an oil dispersible formulation (OD).
- Conviso® One provides control of many broadleaf and grass weeds but. has limited control of one very important, weed in sugar beet: Chenopodium album (CHEAL).
- Conviso® One herbicide label recommendation for the control of CHEAL indicates either a single application at 1 L/ha or two applications at 0.5 I ./ha to be applied no later than the 2-leaf growth stage of CHEAL.
- florpyrauxifen-benzyl e.g., RINSKOR® active ingredient
- Florpyrauxifen-benzyl is an auxin-mimic herbicide which provides excellent control of CHEAL
- Florpyrauxifen- benzyl may be applied up to four times and is effective against CHEAL from 2-leaf to 6-8 leaf stages of growth. Florpyrauxifen-benzyl provides excellent control of CHEAL along with application timing flexibility and application dosage flexibility allowing effective control of CHEAL in CONVISO® SMART sugar beets.
- Florpyrauxifen-benzyl has been tested in field trials on conventional sugar beets and on CONVISO® SMART ALS-resistant sugar beets. Surprisingly, fiorpyraxuifen- benzyl demonstrated selectivity on CONVISO® SMART sugar beets, even though the florpyraxuifen-benzyl mode-of- action (auxin mimic) is unrelated to ALS. Flor- pyrauxifen-benzyl was safe on certain conventional sugar beet crop varieties and damaged other varieties. Florpyrauxifen-benzyl was safe on CONVISO® SMART sugar beets at doses from 0.5 g ae/ha to 4 g ae/ha under field conditions.
- sugar beet refers to a plant of the species Beta vulgaris subspecies vulgaris var. Altissima whose root contains a high concentration of sucrose.
- Sugar beet plants and crops may be species, and/or hybrids, and/or genetically modified.
- DAA Days After Treatment Application
- weeds refers to any unwanted vegetation that may interfere with the growth and/or harvesting of a desired crop. Weeds are known to compete for nutrients with crops such as sugarcane, lowering yields. In addition, weeds may interfere with mechanized harvesting machines, lowering harvesting efficiency. Weeds include, but are not limited to, the following: CHEAL ⁇ Chenopodium album. Common lambsquarters), STEME (Stellaria media, Common chickweed), LAMAM ( Lamium ample. xicaule, Henbit), FUMOF (Fumaria officinalis. Common fumitory), POLCO (Polygonum convolvulus, Wild buckwheat), V1OAR (viola arvensis. Field violet), and MERAN ⁇ Mercurialis annua).
- ml pr/ha or 1 pr/ha or g pr/ha refers to the amount of herbicide formulation liquid (nil pr/ha or 1 pr/ha) or herbicide formulation solid (g pr/ha) applied.
- g ai/ha and g ae/ha refer to the amount of an active ingredient (ai) or the amount of an acid equivalent (ae) applied.
- a “herbicidally effective amount” or “vegetation controlling amount” or “weed controlling amount” is an amount of active ingredient(s) which causes an adversely modifying effect to the vegetation, such as a weed, causing deviations from natural development, killing, effecting regulation, causing desiccation, causing retardation, and the like. These terms may be used interchangeably.
- controlling undesirable vegetation or weeds means preventing, reducing, killing, or otherwise adversely modifying the development of plants and vegetation. Described herein are methods of controlling undesirable vegetation through the applica tion of certain herbicide combina tions or compositions. Methods of application include, but are not limited to applications to the vegetation or locus thereof, e.g., application to the area adjacent to the vegetation, as well as pre-emergence, postemergence, foliar (broadcast, directed, banded, spot, mechanical, over-the-top, or rescue), via hand, backpack, machine, tractor, or aerial (airplane and helicopter) ap- plication methods.
- plants and “vegetation” and “weeds” include, but are not limited to, germinant seeds, emerging seedlings, plants emerging from vegetative propagules, immature vegetation and established vegetation.
- BBCH refers to the Biologische Farbweg, Bureausortenamt and CHemische Industrie scale of plant development.
- florpyrauxifen-benzyl provides an effective method of controlling weeds in sugar beet which comprises contacting the vegetation or the locus thereof with or applying to the soil to control the emergence or growth of weeds a herbicidally effective amount of florpyrauxifen-benzyl to a crop of sugar beet in need of weed control.
- Florpyrauxifen-benzyl may be applied at a rate from 0.5 g ai/ ha to 4 g ai/ha. Florpyrauxifen may also be applied as part of a composition comprising other ingredients.
- florpyrauxifen-benzyl may be applied with etho- fumesate at a rate of 125g ai/ha and metamitron at a rate of 350g ai/ha and lenacil at a rate of 80g ai/ha and methylated canola oil at a rate of 0.51 pr/ha, as shown in the examples below.
- Crop Sugar Beet BEAVA, Beta vulgaris subsp. vulgaris var. altissima Biotype: ALS RES (Conviso® Sugar Beet)
- Rinskor® applied at a rate of 2 and 4 g ai/ha caused stem and leaf deformations, and petiole elongation from 53.3 to 63.3 visual percent. Very good control of MERAN and CHEAL was observed and 10% to 40% visual control of VIOAR was observed.
- Rinskor® Florpyrauxifen-benzyl 0.5g ai/ha, 1g ai/ha, 2g ai/ha, 4g ai/ha - [0042] 0.02, 0.04, 0.08, and 0.16 1/ha
- florpyrauxifen-benzyl for the control of CHEAL, and its selectivity on CONVISO® SMART sugar beets, provides a new flexible method for the control of CHEAL in sugar beets.
- CHEAL may be controlled from the 2-leaf to the 6-8 leaf stages of growth.
- florpyrauxifen-benzyl may be applied up to four times the farmer has the application timing and application dosage flexibility to effectively control CHEAL in CONVISO® SMART sugar beets.
- the method also provides effective and flexible control of this key weed for the sugar beet farmers employing certain conventional sugar beet varieties.
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- Life Sciences & Earth Sciences (AREA)
- Environmental Sciences (AREA)
- Zoology (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Chemical & Material Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Health & Medical Sciences (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
A method of controlling unwanted vegetation in sugar beet comprising contacting the vegetation or the locus thereof with or applying to the soil to control the emergence or growth of unwanted vegetation a herbicidally effective amount of florpyrauxifen-benzyl.
Description
A METHOD OF WEED CONTROL IN SUGAR BEET
Background
[0001] The sugar beet crop is a widely grown row crop with 4 million hectares planted in
European countries. Since 2019 ALS-herbicide-tolerant sugar beet varieties (e.g., CONVISO® SMART seeds, available from KWS seed company) have entered the European sugar beet market with a growing presence in sugar-beet-producing European countries.
[0002] CONVISO SMART varieties allow the control of weeds in sugar beet by the application of a product named “Conviso® One” that contains two ALS inhibitor herbicides (floramsulfuron 50g/l + thiecarbozone 30g/l) formulated as an oil dispersible formulation (OD). Conviso® One provides control of many broadleaf and grass weeds but. has limited control of one very important, weed in sugar beet: Chenopodium album (CHEAL).
[0003] Additionally, there is a somewhat narrow period for application of Conviso® One. Experiments have shown that sufficient control of CHEAT., is achieved only when Conviso® One is applied at the 2-leaf growth stage of the weed. However, it is well known that CHEAL emerges in sugar beet at several different times from March to June, which means that control of this weed during the cycle of the sugar beet crop is insufficient.
[0004] The flexibility of herbicide product application is limited with Conviso® One. The Conviso® One herbicide label recommendation for the control of CHEAL indicates either a single application at 1 L/ha or two applications at 0.5 I ./ha to be applied no later than the 2-leaf growth stage of CHEAL.
[0005] As provided herein, florpyrauxifen-benzyl (e.g., RINSKOR® active ingredient) is an auxin-mimic herbicide which provides excellent control of CHEAL,. Florpyrauxifen- benzyl may be applied up to four times and is effective against CHEAL from 2-leaf to 6-8 leaf stages of growth. Florpyrauxifen-benzyl provides excellent control of CHEAL along with application timing flexibility and application dosage flexibility allowing effective control of CHEAL in CONVISO® SMART sugar beets.
Detailed Description
[0006] Florpyrauxifen-benzyl has been tested in field trials on conventional sugar beets and on CONVISO® SMART ALS-resistant sugar beets. Surprisingly, fiorpyraxuifen- benzyl demonstrated selectivity on CONVISO® SMART sugar beets, even though the florpyraxuifen-benzyl mode-of- action (auxin mimic) is unrelated to ALS. Flor-
pyrauxifen-benzyl was safe on certain conventional sugar beet crop varieties and damaged other varieties. Florpyrauxifen-benzyl was safe on CONVISO® SMART sugar beets at doses from 0.5 g ae/ha to 4 g ae/ha under field conditions.
[0007] As used herein “sugar beet” refers to a plant of the species Beta vulgaris subspecies vulgaris var. Altissima whose root contains a high concentration of sucrose. Sugar beet plants and crops may be species, and/or hybrids, and/or genetically modified.
[0008] As used herein, the terms “comprises.” “comprising,” or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus.
[0009] As used herein “DAA” refers to Days After treatment Application.
[0010] As used herein ‘'weed” or “weeds” refers to any unwanted vegetation that may interfere with the growth and/or harvesting of a desired crop. Weeds are known to compete for nutrients with crops such as sugarcane, lowering yields. In addition, weeds may interfere with mechanized harvesting machines, lowering harvesting efficiency. Weeds include, but are not limited to, the following: CHEAL {Chenopodium album. Common lambsquarters), STEME (Stellaria media, Common chickweed), LAMAM ( Lamium ample. xicaule, Henbit), FUMOF (Fumaria officinalis. Common fumitory), POLCO (Polygonum convolvulus, Wild buckwheat), V1OAR (viola arvensis. Field violet), and MERAN {Mercurialis annua).
[0011] As used herein “ml pr/ha or 1 pr/ha or g pr/ha” refers to the amount of herbicide formulation liquid (nil pr/ha or 1 pr/ha) or herbicide formulation solid (g pr/ha) applied.
[0012] As used herein “g ai/ha” and “g ae/ha” refer to the amount of an active ingredient (ai) or the amount of an acid equivalent (ae) applied.
[0013] As used herein, a “herbicidally effective amount” or “vegetation controlling amount” or “weed controlling amount” is an amount of active ingredient(s) which causes an adversely modifying effect to the vegetation, such as a weed, causing deviations from natural development, killing, effecting regulation, causing desiccation, causing retardation, and the like. These terms may be used interchangeably.
[0014] As used herein, “controlling” undesirable vegetation or weeds means preventing, reducing, killing, or otherwise adversely modifying the development of plants and vegetation. Described herein are methods of controlling undesirable vegetation through the applica tion of certain herbicide combina tions or compositions. Methods of application include, but are not limited to applications to the vegetation or locus thereof, e.g., application to the area adjacent to the vegetation, as well as pre-emergence, postemergence, foliar (broadcast, directed, banded, spot, mechanical, over-the-top, or rescue), via hand, backpack, machine, tractor, or aerial (airplane and helicopter) ap-
plication methods.
[0015] As used herein, “plants” and “vegetation” and “weeds” include, but are not limited to, germinant seeds, emerging seedlings, plants emerging from vegetative propagules, immature vegetation and established vegetation.
[0016] As used herein, “BBCH” refers to the Biologische Bundesanstalt, Bundessortenamt and CHemische Industrie scale of plant development.
[0017] It has been surprisingly found that florpyrauxifen-benzyl provides an effective method of controlling weeds in sugar beet which comprises contacting the vegetation or the locus thereof with or applying to the soil to control the emergence or growth of weeds a herbicidally effective amount of florpyrauxifen-benzyl to a crop of sugar beet in need of weed control. Florpyrauxifen-benzyl may be applied at a rate from 0.5 g ai/ ha to 4 g ai/ha. Florpyrauxifen may also be applied as part of a composition comprising other ingredients. For example, florpyrauxifen-benzyl may be applied with etho- fumesate at a rate of 125g ai/ha and metamitron at a rate of 350g ai/ha and lenacil at a rate of 80g ai/ha and methylated canola oil at a rate of 0.51 pr/ha, as shown in the examples below.
Experimental
[0018] Table 1 . Compositions Applied to ALS-Resistant Sugar Beet
[0019] Crop: Sugar Beet BEAVA, Beta vulgaris subsp. vulgaris var. altissima Biotype: ALS RES (Conviso® Sugar Beet)
[0020] Treated at growth stage: BBCH 14-18
[0022] Table 2. Damage to Damage to ALS-Resistant Sugar Beet
[0024] Application of Rinskor® to Non-ALS-Resistant Sugar Beets
Trial 01
[0025] Beta Vulgaris Vulgaris var. altissima var. KWS MILLENIA
[0026] Treatment Composition
[0027] TRAM AT® F Ethofumesate 125g ai/ha
[0028] GOLTIX® ULTRADISPERSIBLE Metamitron 350g ai/ha
[0029] VENZAR® Lenacil 80g ai/ha
[0030] Actirob B® Methylated Canola oil 0.51 pr/ha
[0031] Rinskor® Florpyrauxifen- benzyl 0.5g ai/ha, 1g ai/ha, 2g ai/ha, 4g ai/ha =
[0032] 0.02, 0.04, 0.08, and 0.16 1/ha
[0033] Trial 01 Results
[0034] At 39 days after application, Rinskor® applied at a rate of 2 and 4 g ai/ha caused stem and leaf deformations, and petiole elongation from 53.3 to 63.3 visual percent. Very good control of MERAN and CHEAL was observed and 10% to 40% visual control of VIOAR was observed.
Trial 02
[0035] BEAVA - Beta Vulgaris Vulgaris var. altissima var. LIBELEE
[0036] Treatment Composition
[0037] TRAMAT® F Elhofumesate 125g ai/ha
[0038] GOLTIX® ULTRADIS PERSIBLE Metamitron 350g ai/ha
[0039] VENZAR® Lenacil 80g ai/ha
[0040] Actirob B® Methylated Canola oil 0.51 pr/ha
[0041] Rinskor® Florpyrauxifen-benzyl 0.5g ai/ha, 1g ai/ha, 2g ai/ha, 4g ai/ha - [0042] 0.02, 0.04, 0.08, and 0.16 1/ha
[0043] Trial 02 Results
[0044] No lasting damage to BEAVA was observed, with a maximum of 5 visual % damage, with slight discoloration. Very good control of CHEAL (Chenopodium album, Common lambsquarters), STEME (Stellaria media, Common chickweed), LAMAM (Lamium amplexica ule, Henbit), FUMOF (Fumaria officinalis, Common fumitory), POLCO (Polygonum convolvulus, Wild buckwheat), VIOAR (viola arvensis, Field violet) was observed. Florpyrauxifen-benzyl demonstrated satisfactory control of CHEAL at the dose of 2 g ae/ha (40ml, ha).
[0045] The use of florpyrauxifen-benzyl for the control of CHEAL, and its selectivity on CONVISO® SMART sugar beets, provides a new flexible method for the control of CHEAL in sugar beets. CHEAL may be controlled from the 2-leaf to the 6-8 leaf stages of growth. In addition, since florpyrauxifen-benzyl may be applied up to four times the farmer has the application timing and application dosage flexibility to effectively control CHEAL in CONVISO® SMART sugar beets. The method also provides effective and flexible control of this key weed for the sugar beet farmers employing certain conventional sugar beet varieties.
Claims
[Claim 1] A method of controlling weeds in sugar beet comprising: contacting the vegetation or the locus thereof with or applying to the soil to control the emergence or growth of weeds a herbicidally effective amount of florpyrauxifen-benzyl to a crop of sugar beet in need of weed control.
[Claim 21 The method of claim 1, wherein florpyrauxifen-benzyl is applied at a rate from 0.5 g ai/ha to 4 g ai/ha.
[Claim 3] The method of claim 2, wherein florpyrauxifen-benzyl is applied with ethofumesate at a rate of 125g ai/ha and metamitron at a rate of 350g ai/ha and lenacil at a rate of 80g ai/ha and methylated canola oil at a rate of 0.51 pr/ha.
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US20140031216A1 (en) * | 2012-07-24 | 2014-01-30 | Dow Agrosciences Llc | Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6-(4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid or a derivative thereof and halosulfuron, pyrazosulfuron and esprocarb |
US20140031229A1 (en) * | 2012-07-24 | 2014-01-30 | Dow Agrosciences Llc | Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6-(4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid or a derivative thereof and triazolopyrimidine sulfonamides |
US20140031227A1 (en) * | 2012-07-24 | 2014-01-30 | Dow Agrosciences Llc | Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6-(4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid or a derivative thereof and glyphosate or glufosinate |
US20140031215A1 (en) * | 2012-07-24 | 2014-01-30 | Dow Agrosciences Llc | Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylic acid or a derivative thereof and bromobutide, daimuron, oxaziclomefone or pyributicarb |
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