WO2023028864A1 - 泄压装置、电池单体、电池及用电设备 - Google Patents
泄压装置、电池单体、电池及用电设备 Download PDFInfo
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- WO2023028864A1 WO2023028864A1 PCT/CN2021/115766 CN2021115766W WO2023028864A1 WO 2023028864 A1 WO2023028864 A1 WO 2023028864A1 CN 2021115766 W CN2021115766 W CN 2021115766W WO 2023028864 A1 WO2023028864 A1 WO 2023028864A1
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- Prior art keywords
- groove
- pressure relief
- scoring
- segment
- grooves
- Prior art date
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Images
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/30—Arrangements for facilitating escape of gases
- H01M50/342—Non-re-sealable arrangements
- H01M50/3425—Non-re-sealable arrangements in the form of rupturable membranes or weakened parts, e.g. pierced with the aid of a sharp member
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16K—VALVES; TAPS; COCKS; ACTUATING-FLOATS; DEVICES FOR VENTING OR AERATING
- F16K17/00—Safety valves; Equalising valves, e.g. pressure relief valves
- F16K17/40—Safety valves; Equalising valves, e.g. pressure relief valves with a fracturing member, e.g. fracturing diaphragm, glass, fusible joint
- F16K17/403—Safety valves; Equalising valves, e.g. pressure relief valves with a fracturing member, e.g. fracturing diaphragm, glass, fusible joint with a fracturing valve member
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/102—Primary casings; Jackets or wrappings characterised by their shape or physical structure
- H01M50/103—Primary casings; Jackets or wrappings characterised by their shape or physical structure prismatic or rectangular
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/14—Primary casings; Jackets or wrappings for protecting against damage caused by external factors
- H01M50/143—Fireproof; Explosion-proof
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/147—Lids or covers
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/147—Lids or covers
- H01M50/148—Lids or covers characterised by their shape
- H01M50/15—Lids or covers characterised by their shape for prismatic or rectangular cells
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/20—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
- H01M50/247—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders specially adapted for portable devices, e.g. mobile phones, computers, hand tools or pacemakers
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/20—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
- H01M50/249—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders specially adapted for aircraft or vehicles, e.g. cars or trains
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- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2200/00—Safety devices for primary or secondary batteries
- H01M2200/20—Pressure-sensitive devices
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2220/00—Batteries for particular applications
- H01M2220/20—Batteries in motive systems, e.g. vehicle, ship, plane
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2220/00—Batteries for particular applications
- H01M2220/30—Batteries in portable systems, e.g. mobile phone, laptop
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Definitions
- the present application relates to the technical field of batteries, in particular, to a pressure relief device, a battery cell, a battery and electrical equipment.
- Batteries are widely used in electronic equipment, such as mobile phones, laptop computers, battery cars, electric cars, electric airplanes, electric ships, electric toy cars, electric toy ships, electric toy airplanes and electric tools, etc.
- a pressure relief device In battery technology, in order to ensure the safety of the battery cell, a pressure relief device is generally installed in the battery cell. When the inside of the battery cell or when the temperature reaches a threshold, the pressure relief device breaks at the position where the notch groove is set, so that Release the pressure inside the battery cell. For a general pressure relief device, pressure relief may also occur when the internal pressure of the battery cell is within a normal range, and the long-term reliability is poor.
- Embodiments of the present application provide a pressure relief device, a battery cell, a battery, and electrical equipment, which can effectively improve the long-term reliability of the pressure relief device.
- the embodiment of the present application provides a pressure relief device, including: a pressure relief body, including a pressure relief portion, the pressure relief portion has opposite first and second surfaces in its thickness direction; Score grooves are sequentially arranged on the pressure relief part along the direction from the first surface to the second surface, and among the two adjacent score grooves in the thickness direction, the score grooves far away from the first surface The maximum width of the scored grooves is smaller than the minimum width of the scored grooves proximate to the first surface.
- the pressure relief part is provided with a plurality of scoring grooves, and the multiple scoring grooves are arranged on the pressure relief part in sequence along the direction from the first surface to the second surface of the pressure relief part, and the thickness of the pressure relief part Among the two adjacent scoring grooves in the direction, the maximum width of the scoring groove far away from the first surface is smaller than the minimum width of the scoring groove close to the first surface.
- the pressure relief device of this structure adopts a multi-level scoring groove structure , can reduce the forming force on the pressure relief part when forming each level of scoring groove, and reduce the risk of cracks in the pressure relief part. Long-term reliability of pressure relief devices.
- the plurality of scoring grooves include a first scoring groove and a second scoring groove extending in the same direction, and the first scoring groove is disposed on a bottom surface of the second scoring groove.
- the extension direction of the first notch groove is consistent with the extension direction of the second notch groove, and the first notch groove is arranged on the bottom surface of the second notch groove.
- this structure is convenient for the first notch groove Forming ensures the length of the first scoring groove, on the other hand, it can ensure that the maximum width of the first scoring groove is smaller than the minimum width of the second scoring groove.
- the plurality of scoring grooves further include a third scoring groove, the third scoring groove is disposed on the first surface, and the second scoring groove is disposed on the third groove. bottom of the groove.
- the plurality of scoring grooves further includes a third scoring groove arranged on the first surface, and the second scoring groove is arranged on the bottom surface of the third scoring groove, that is to say, three grooves are arranged on the pressure relief part.
- Level scoring grooves ensure that the forming force on the pressure relief part will not be too large when forming each level of score grooves, reducing the risk of cracks in the pressure relief part.
- the bottom surface of the third scoring groove is provided with a plurality of second scoring grooves.
- a plurality of second notch grooves are provided on the bottom surface of the third notch groove, so that the pressure relief part can be ruptured at the position of each second notch groove to realize pressure relief, which has a better pressure relief effect, Increased pressure release rate.
- one third scoring groove corresponds to multiple second scoring grooves, the molding process can be simplified and the molding cost can be reduced.
- the plurality of second scoring grooves include a first groove segment, a second groove segment and a third groove segment, the first groove segment and the second groove segment are arranged at intervals, the first groove segment Both a groove section and the second groove section intersect with the third groove section;
- the pressure relief part includes an opening area jointly defined by the first groove section, the second groove section and the third groove section, the The opening area is configured to open with the first groove segment, the second groove segment and the third groove segment as boundaries.
- the first groove section and the second groove section are arranged at intervals, the second groove section and the second groove section both intersect the third groove section, and the first groove section, the second groove section and the third groove section jointly define Out of the opening area, after the pressure relief part breaks at the position of the first groove section, the second groove section and the second groove section, the part of the pressure relief part located in the opening area will open for pressure relief, increasing the pressure relief area of the pressure relief part , improving the pressure relief rate of the pressure relief part.
- the plurality of second scoring grooves further includes a fourth groove segment, and in the extending direction of the third groove segment, the fourth groove segment is located between the first groove segment and the Between the second slot segments, the fourth slot segment intersects the third slot segment.
- the fourth groove section located between the first groove section and the second groove section intersects with the third groove section, and the stress of the pressure relief part is more concentrated at the intersection of the third groove section and the fourth groove section, and more It is easy to break, so that the pressure relief part breaks along the third groove segment from the position where the third groove segment intersects with the fourth groove segment during the pressure relief process, and along the first groove segment and the second groove segment after the third groove segment is broken. Slot sections rupture for quick pressure relief.
- the distance from the intersection of the fourth slot segment and the third slot segment to the first slot segment is equal to the distance between the fourth slot segment and the The distance from the intersection position of the third slot segment to the second slot segment.
- the distance from the intersection of the fourth groove segment and the third groove segment to the first groove segment is equal to the distance from the intersection position of the fourth groove segment and the third groove segment to the second groove segment, so that the pressure relief part can After the position where the fourth groove segment intersects with the third groove segment is broken along the third groove segment, it is simultaneously broken along the first groove segment and the second groove segment.
- the first groove segment, the second groove segment and the third groove segment define two open areas, and the two open areas are respectively located on two sides of the third groove segment.
- the first groove section, the second groove section and the third groove section define two opening areas, and the two opening areas are respectively located on both sides of the third groove section.
- the parts of the pressure part in the two pressure relief areas can be opened for pressure relief in a split manner, which can effectively increase the pressure relief rate of the pressure relief part.
- the second surface is provided with a notch groove located in the opening area, and there is a distance between the notch groove and the third groove segment along the extending direction of the first groove segment.
- the gap groove has a distance from the third groove segment in the extension direction of the first groove segment, and at least part of the gap groove is located in the opening area, so that the pressure relief part is in the pressure relief process, and the pressure relief part is located in the opening area
- a part of the pressure relief part can be turned around with the position of the pressure relief part in the notch groove as an axis, so that it is easier to open the pressure relief.
- the distance between the first surface and the second surface is H0
- the distance from the bottom surface of the scoring groove closest to the second surface to the second surface is H1
- H0 and H1 satisfy Relational formula: H1/H0 ⁇ 0.2.
- the ratio of the distance from the bottom surface of the scoring groove closest to the second surface to the second surface to the distance from the first surface to the second surface is less than 0.2, so that the bottom surface of the scoring groove closest to the second surface and The thickness of the portion between the second surfaces accounts for a relatively small proportion of the total thickness of the pressure relief portion, so that the portion between the bottom surface of the scoring groove closest to the second surface and the second surface can be normally ruptured to realize pressure relief .
- the distance from the bottom surface of the scoring groove closest to the second surface to the second surface is H1, and H1 satisfies the relationship H1 ⁇ 0.5 mm.
- the distance from the bottom surface of the scoring groove closest to the second surface to the second surface is less than 0.5mm, so that the part between the bottom surface of the scoring groove closest to the second surface and the second surface
- the thickness is small, easy to rupture and release pressure.
- the depth of the scoring groove disposed on the first surface is H2, and H2 satisfies the relationship H2 ⁇ 1mm.
- the depth of the score groove provided on the first surface is less than 1mm, so that the depth of the score groove on the outermost side of the pressure relief part is smaller, which reduces the pressure relief part during the forming process of the score groove.
- the molding force received reduces the risk of cracks in the pressure relief part.
- the depth of the notch groove between the notch groove closest to the second surface and the notch groove disposed on the first surface is H3, and H3 satisfies the relationship H3 ⁇ 1.5 mm.
- the depth of the notch groove between the notch groove closest to the second surface and the notch groove provided on the first surface is less than 1.5 mm, so that all but the notch closest to the second surface on the pressure relief part.
- the grooves and the grooves other than the grooves arranged on the first surface have a smaller depth, which reduces the molding force on the pressure relief part during the molding process and reduces the risk of cracks in the pressure relief part.
- an accommodation space is formed inside the pressure relief body, the pressure relief body has a plurality of walls defining the accommodation space, the accommodation space is used to accommodate the electrode assembly, and the plurality of walls One of the walls is formed with the pressure relief portion.
- a plurality of walls of the pressure relief body define an accommodation chamber for accommodating the electrode assembly, and one of the plurality of walls is formed with a pressure relief portion, so that the pressure relief device not only has the accommodation function of accommodating the electrode assembly, but also With pressure relief function.
- the multiple walls include a peripheral wall and a bottom wall, the peripheral wall surrounds the edge of the bottom wall, the peripheral wall and the bottom wall jointly define the accommodation space, and the bottom wall The pressure relief portion is formed.
- the bottom wall of the pressure relief body is formed with a pressure relief portion, so that the bottom wall has a good pressure relief function.
- the peripheral wall and the bottom wall are integrally formed.
- the surrounding wall and the bottom wall are integrally formed, so that the surrounding wall and the bottom wall with the pressure relief function have good firmness.
- This integrated design can simplify the molding process. reduce manufacturing cost.
- the first surface is an outer surface of the bottom wall.
- the first surface is the outer surface of the bottom wall, which is convenient for processing scoring grooves on the pressure relief body.
- an embodiment of the present application provides a battery cell, including the pressure relief device provided in any one embodiment of the first aspect.
- a battery in a third aspect, includes: the battery cell provided in any one embodiment of the second aspect; and a box for accommodating the battery cell.
- an electric device includes the battery provided in any one embodiment of the third aspect.
- an embodiment of the present application provides a method for manufacturing a pressure relief device, the method including: providing a pressure relief body, the pressure relief body includes a pressure relief portion, and the pressure relief portion has opposite thicknesses in its thickness direction.
- the first surface and the second surface of the pressure relief part; a plurality of scoring grooves are sequentially processed along the direction from the first surface to the second surface on the pressure relief part; two adjacent in the thickness direction Among the scoring grooves, the maximum width of the scoring groove far away from the first surface is smaller than the minimum width of the scoring groove close to the first surface.
- sequentially processing a plurality of scoring grooves on the pressure relief part along the direction from the first surface to the second surface comprises: on the pressure relief part along the first surface A plurality of scoring grooves are sequentially punched from the first surface to the second surface.
- a plurality of scoring grooves are sequentially formed on the pressure relief part in the direction from the first surface to the second surface by stamping. Reduce the risk of cracks in the pressure relief part.
- the embodiment of the present application provides a manufacturing equipment of a pressure relief device, including: a first providing device for providing a pressure relief body, the pressure relief body includes a pressure relief part, and the pressure relief part has a thickness of There are opposite first surfaces and second surfaces in the direction; and a processing device is used to sequentially process a plurality of scoring grooves on the pressure relief part along the direction from the first surface to the second surface; wherein , among the two adjacent scoring grooves in the thickness direction, the maximum width of the scoring groove far away from the first surface is smaller than the minimum width of the scoring groove close to the first surface.
- Fig. 1 is a schematic structural diagram of a vehicle provided by some embodiments of the present application.
- Fig. 2 is a schematic structural diagram of a battery provided by some embodiments of the present application.
- Fig. 3 is an exploded view of a battery cell provided by some embodiments of the present application.
- Fig. 4 is a schematic structural diagram of a pressure relief device provided by some embodiments of the present application.
- Fig. 5 is a cross-sectional view of the pressure relief part shown in Fig. 4;
- Fig. 6 is a partial view of a pressure relief device provided in some other embodiments of the present application.
- Fig. 7 is a cross-sectional view of the pressure relief part shown in Fig. 6;
- Fig. 8 is a positional relationship diagram of the first notch groove, the second notch groove and the third notch groove shown in Fig. 6;
- Fig. 9 is a schematic structural diagram of a pressure relief device provided in some other embodiments of the present application.
- Fig. 10 is a flowchart of a manufacturing method of a pressure relief device provided by some embodiments of the present application.
- Fig. 11 is a schematic block diagram of the manufacturing equipment of the pressure relief device provided by some embodiments of the present application.
- Icons 10-box; 11-first part; 12-second part; 20-battery unit; 21-housing; 22-electrode assembly; 221-positive tab; 222-negative tab; 23-end cover 231-positive electrode terminal; 232-negative electrode terminal; 24-insulator; 25-pressure relief device; 251-pressure relief body; 2511-pressure relief part; 2511a-first surface; 2512-surrounding wall; 2513-bottom wall; 252-scoring groove; 2521-the first scoring groove; 2522-the second scoring groove; 2522a-the first groove segment; 2522b-the second groove segment; 2522c- 2522d-the fourth groove section; 2523-the third scoring groove; 253-notched groove; 26-collecting member; 100-battery; 200-controller; 300-motor; 1000-vehicle; Manufacturing equipment; 2100-providing device; 2200-processing device.
- connection In the description of this application, it should be noted that, unless otherwise clearly stipulated and limited, the terms “installation”, “connection”, “connection” and “attachment” should be understood in a broad sense, for example, it may be a fixed connection, It can also be detachably connected or integrally connected; it can be directly connected or indirectly connected through an intermediary, and it can be internal communication between two components. Those of ordinary skill in the art can understand the specific meanings of the above terms in this application according to specific situations.
- “Plurality” in this application refers to two or more (including two).
- the battery cells may include lithium-ion secondary batteries, lithium-ion primary batteries, lithium-sulfur batteries, sodium-lithium-ion batteries, sodium-ion batteries, or magnesium-ion batteries, which are not limited in the embodiments of the present application.
- the battery cell can be in the form of a cylinder, a flat body, a cuboid or other shapes, which is not limited in this embodiment of the present application.
- Battery cells are generally divided into three types according to packaging methods: cylindrical battery cells, square battery cells and pouch battery cells, which are not limited in this embodiment of the present application.
- the battery mentioned in the embodiments of the present application refers to a single physical module including one or more battery cells to provide higher voltage and capacity.
- the battery mentioned in this application may include a battery module or a battery pack, and the like.
- Batteries generally include a case for enclosing one or more battery cells. The box can prevent liquid or other foreign objects from affecting the charging or discharging of the battery cells.
- the battery cell includes an electrode assembly and an electrolyte, and the electrode assembly is composed of a positive pole piece, a negative pole piece and a separator.
- a battery cell works primarily by moving metal ions between the positive and negative pole pieces.
- the positive electrode sheet includes a positive electrode current collector and a positive electrode active material layer, the positive electrode active material layer is coated on the surface of the positive electrode current collector, and the positive electrode collector without the positive electrode active material layer protrudes from the positive electrode collector coated with the positive electrode active material layer. Fluid, the positive electrode current collector not coated with the positive electrode active material layer is used as the positive electrode tab.
- the material of the positive electrode current collector can be aluminum, and the positive electrode active material can be lithium cobaltate, lithium iron phosphate, ternary lithium or lithium manganate.
- the negative electrode sheet includes a negative electrode current collector and a negative electrode active material layer, the negative electrode active material layer is coated on the surface of the negative electrode current collector, and the negative electrode collector without the negative electrode active material layer protrudes from the negative electrode collector coated with the negative electrode active material layer. Fluid, the negative electrode current collector not coated with the negative electrode active material layer is used as the negative electrode tab.
- the material of the negative electrode current collector may be copper, and the negative electrode active material may be carbon or silicon.
- the number of positive pole tabs is multiple and stacked together, and the number of negative pole tabs is multiple and stacked together.
- the material of the isolation film may be PP (polypropylene, polypropylene) or PE (polyethylene, polyethylene).
- the electrode assembly may be a wound structure or a laminated structure, which is not limited in the embodiment of the present application.
- the pressure relief device on the battery cell has an important impact on the safety of the battery. For example, when a short circuit, overcharge, etc. occur, it may cause thermal runaway inside the battery cell, resulting in a sudden increase in pressure or temperature. In this case, the internal pressure and temperature can be released to the outside through the actuation of the pressure relief mechanism, so as to prevent the battery cells from exploding and igniting.
- the pressure relief device will also release pressure when the internal pressure of the battery cell is within a normal range, resulting in failure of the battery cell.
- the pressure relief device is generally provided with notched grooves on the pressure relief body. In order to ensure that the pressure relief device can release the pressure normally when the internal pressure or temperature of the battery cell reaches the threshold value, the notched groove needs to be processed deeper. After the notched groove on the pressure relief body is formed, cracks are likely to occur, and the internal pressure of the battery cell is within the normal range (not reaching the threshold) and the pressure relief device releases the pressure.
- an embodiment of the present application provides a pressure relief device, in which a plurality of scoring grooves are sequentially arranged on the pressure relief part of the pressure relief body in the direction from the first surface to the second surface, and in the thickness direction of the pressure relief part Among the two adjacent scoring grooves, the maximum width of the scoring groove far away from the first surface is smaller than the minimum width of the scoring groove close to the first surface.
- the multi-stage notched groove structure can reduce the forming force on the pressure relief part when forming the notched grooves of each stage, and reduce the risk of cracks in the pressure relief part.
- the pressure part fails due to cracks at the position where the notch groove is set, which improves the long-term reliability of the pressure relief device.
- Electrical devices can be vehicles, mobile phones, portable devices, laptops, ships, spacecraft, electric toys and power tools, etc.
- Vehicles can be fuel vehicles, gas vehicles or new energy vehicles, and new energy vehicles can be pure electric vehicles, hybrid vehicles or extended-range vehicles;
- spacecraft include airplanes, rockets, space shuttles and spacecraft, etc.;
- electric toys include fixed Type or mobile electric toys, such as game consoles, electric car toys, electric boat toys and electric airplane toys, etc.;
- electric tools include metal cutting electric tools, grinding electric tools, assembly electric tools and railway electric tools, for example, Electric drills, electric grinders, electric wrenches, electric screwdrivers, electric hammers, impact drills, concrete vibrators, electric planers, and more.
- the embodiment of the present application does not impose special limitations on the above electric equipment.
- FIG. 1 is a schematic structural diagram of a vehicle 1000 provided by some embodiments of the present application;
- the battery 100 can be used for power supply of the vehicle 1000 , for example, the battery 100 can be used as an operating power source of the vehicle 1000 .
- the vehicle 1000 may further include a controller 200 and a motor 300 , the controller 200 is used to control the battery 100 to supply power to the motor 300 , for example, for starting, navigating and running the vehicle 1000 .
- the battery 100 can not only be used as an operating power source for the vehicle 1000, but also can be used as a driving power source for the vehicle 1000, replacing or partially replacing fuel or natural gas to provide driving power for the vehicle 1000.
- FIG. 2 is a schematic structural diagram of a battery 100 provided by some embodiments of the present application.
- the battery 100 includes a box body 10 and a battery cell 20 .
- the box body 10 is used to accommodate the battery cell 20 .
- the box body 10 is a component for accommodating the battery cell 20
- the box body 10 provides a storage space for the battery cell 20
- the box body 10 may have various structures.
- the box body 10 may include a first part 11 and a second part 12 , and the first part 11 and the second part 12 cover each other to define a storage space for accommodating the battery cells 20 .
- the first part 11 and the second part 12 can be in various shapes, such as cuboid, cylinder and so on.
- the first part 11 can be a hollow structure with one side open, and the second part 12 can also be a hollow structure with one side open.
- the open side of the second part 12 is covered with the open side of the first part 11 to form a box with accommodating space.
- first part 11 is a hollow structure with one side open
- second part 12 is a plate-like structure
- the second part 12 covers the open side of the first part 11 to form a box body 10 with a receiving space.
- the first part 11 and the second part 12 can be sealed by a sealing element, and the sealing element can be a sealing ring, a sealant, or the like.
- the battery 100 there may be one or a plurality of battery cells 20 . If there are multiple battery cells 20 , the multiple battery cells 20 may be connected in series, in parallel or in parallel.
- the mixed connection means that the multiple battery cells 20 are both in series and in parallel.
- a plurality of battery cells 20 may be connected in series or in parallel or mixed to form a battery module, and then a plurality of battery modules may be connected in series or in parallel or mixed to form a whole and accommodated in the box 10 . It is also possible that all the battery cells 20 are directly connected in series, parallel or mixed together, and then all the battery cells 20 are housed in the case 10 as a whole.
- the battery 100 may further include a confluence component, through which the plurality of battery cells 20 may be electrically connected, so as to realize series connection, parallel connection or mixed connection of the plurality of battery cells 20 .
- the bus component may be a metal conductor, such as copper, iron, aluminum, stainless steel, aluminum alloy, and the like.
- FIG. 3 is an exploded view of a battery cell 20 provided by some embodiments of the present application.
- the battery cell 20 includes a casing 21 , an electrode assembly 22 , an end cap 23 , an insulator 24 and a pressure relief device 25 .
- the casing 21 is a component for accommodating the electrode assembly 22, and the casing 21 may be a hollow structure with an opening formed at one end.
- the housing 21 can be in various shapes, such as cylinder, cuboid and so on.
- the housing 21 can be made of various materials, such as copper, iron, aluminum, steel, aluminum alloy and so on.
- Electrodes assemblies 22 there may be one or more electrode assemblies 22 in the housing 21 .
- there are a plurality of electrode assemblies 22 and the plurality of electrode assemblies 22 are stacked and arranged in the casing 21 .
- the electrode assembly 22 is a part where electrochemical reactions occur in the battery cell 20 .
- the electrode assembly 22 may include a positive electrode tab, a negative electrode tab, and a separator.
- the electrode assembly 22 may be a coiled structure formed by winding a positive pole piece, a separator and a negative pole piece, or a laminated structure formed by stacking a positive pole piece, a separator and a negative pole piece.
- the positive electrode sheet may include a positive electrode collector and a positive electrode active material layer coated on opposite sides of the positive electrode collector.
- the negative electrode sheet may include a negative electrode current collector and a negative electrode active material layer coated on opposite sides of the negative electrode current collector.
- the electrode assembly 22 has a positive pole tab 221 and a negative pole tab 222.
- the positive pole tab 221 can be the part of the positive pole piece that is not coated with the positive active material layer
- the negative pole tab 222 can be the part that is not coated with the negative pole active material layer on the negative pole piece. part.
- the end cap 23 is a component that covers the opening of the casing 21 to isolate the internal environment of the battery cell 20 from the external environment.
- the end cap 23 covers the opening of the casing 21 , and the end cap 23 and the casing 21 jointly define a sealed space for accommodating the electrode assembly 22 , electrolyte and other components.
- the shape of the end cap 23 can be adapted to the shape of the housing 21.
- the housing 21 is a rectangular parallelepiped structure
- the end cap 23 is a rectangular plate-shaped structure compatible with the housing 21.
- the housing 21 is a cylinder.
- the body structure, the end cover 23 is a circular plate-shaped structure suitable for the housing 21.
- the material of the end cover 23 can also be various, for example, copper, iron, aluminum, steel, aluminum alloy, etc.
- the material of the end cover 23 and the material of the shell 21 can be the same or different.
- Electrode terminals can be provided on the end cap 23 , and the electrode terminals are used for electrical connection with the electrode assembly 22 to output the electric energy of the battery cell 20 .
- the electrode terminals may include a positive electrode terminal 231 and a negative electrode terminal 232 , the positive electrode terminal 231 is used for electrical connection with the positive electrode tab 221 , and the negative electrode terminal 232 is used for electrically connecting with the negative electrode tab 222 .
- the positive electrode terminal 231 and the positive tab 221 may be directly connected or indirectly connected, and the negative electrode terminal 232 and the negative tab 222 may be directly connected or indirectly connected.
- the positive electrode terminal 231 is electrically connected to the positive electrode tab 221 through a current collecting member 26
- the negative electrode terminal 232 is electrically connected to the negative electrode tab 222 through another current collecting member 26 .
- the insulator 24 is a part separating the casing 21 from the electrode assembly 22 , and the insulation and isolation of the casing 21 and the electrode assembly 22 are realized through the insulator 24 .
- the insulating member 24 is an insulating material, and the insulating member 24 may be an insulating material such as plastic or rubber.
- the insulating member 24 covers the outer circumference of the electrode assembly 22 in the circumferential direction. It can be understood that, in the case of multiple electrode assemblies 22 , the insulating member 24 covers the entire outer circumference of the plurality of electrode assemblies 22 in the circumferential direction.
- the pressure relief device 25 is a component for releasing the pressure inside the battery cell 20 , and when the pressure or temperature inside the battery cell 20 reaches a threshold value, the pressure inside the battery cell 20 is released through the pressure relief device 25 .
- the pressure relief device 25 may be a component provided on the end cover 23 , or the housing 21 may act as the pressure relief device 25 . The specific structure of the pressure relief device 25 will be described in detail below with reference to the accompanying drawings.
- Figure 4 is a schematic structural diagram of a pressure relief device 25 provided by some embodiments of the present application
- Figure 5 is a cross-sectional view of the pressure relief part 2511 shown in Figure 4
- the pressure relief device 25 includes a pressure relief body 251 and a plurality of scoring grooves 252.
- the pressure relief body 251 includes a pressure relief portion 2511 having a first surface 2511 a and a second surface 2511 b opposite to each other in a thickness direction thereof.
- a plurality of scoring grooves 252 are sequentially arranged in the pressure relief portion 2511 along the direction from the first surface 2511a to the second surface 2511b, and in the two adjacent scoring grooves 252 in the thickness direction of the pressure relief portion 2511, away from the first surface
- the maximum width of the scoring groove 252 of 2511a is smaller than the minimum width of the scoring groove 252 close to the first surface 2511a.
- the maximum width of the scoring groove 252 away from the first surface 2511a is smaller than the minimum width of the scoring groove 252 close to the first surface 2511a, that is, That is, the widths of the plurality of scoring grooves 252 decrease step by step along the direction from the first surface 2511a to the second surface 2511b.
- the maximum width of the scoring groove 252 away from the first surface 2511a and the minimum width of the scoring groove 252 close to the first surface 2511a are the dimensions of two adjacent scoring grooves 252 in the same direction.
- the maximum width of the scoring groove 252 far away from the first surface 2511a does not limit the width of the scoring groove 252 far away from the first surface 2511a among two adjacent scoring grooves 252 to be gradual.
- the width of the scored groove 252 away from the first surface 2511 a may also be referred to as the maximum width.
- the minimum width of the scoring groove 252 close to the first surface 2511a does not limit the width of the scoring groove 252 close to the first surface 2511a among the two adjacent scoring grooves 252 to be gradual.
- the width of the score groove 252 near the first surface 2511 a can also be referred to as the minimum width. That is to say, in the case where the width of the scoring groove 252 does not change along the thickness direction of the pressure relief portion 2511, “in the two adjacent scoring grooves 252 in the thickness direction of the pressure relief portion 2511, the distance away from the first The maximum width of the scoring groove 252 on the surface 2511a is smaller than the minimum width of the scoring groove 252 close to the first surface 2511a", which can be understood as "in the two adjacent scoring grooves 252 in the thickness direction of the pressure relief part 2511, away from The width of the scoring groove 252 on the first surface 2511a is smaller than the width of the scoring groove 252 close to the first surface 2511a".
- the number of scoring grooves 252 sequentially provided on the pressure relief portion 2511 along its thickness direction may be two, three, four, and so on.
- the multiple scoring grooves 252 on the pressure relief part 2511 can be formed in various ways, such as stamping, milling and so on. Taking forming a plurality of scoring grooves 252 by stamping as an example, a plurality of scoring grooves 252 can be punched and formed on the pressure relief portion 2511 in sequence along the direction from the first surface 2511 a to the second surface 2511 b.
- three scoring grooves 252 are sequentially arranged on the pressure relief part 2511 along its thickness direction, and the first scoring groove 252 can be stamped and formed on the first surface 2511a first, and then the bottom surface of the first scoring groove 252 The second scoring groove 252 is punched and formed on the top, and the third scoring groove 252 is stamped and formed on the bottom surface of the second scoring groove 252 .
- the first surface 2511a and the second surface 2511b of the pressure relief portion 2511 are two opposite surfaces of the pressure relief portion 2511 in its thickness direction, and the distance between the first surface 2511a and the second surface 2511b is the distance between the pressure relief portion 2511 thickness.
- the pressure relief body 251 may be a component installed on the end cover 23 , for example, the pressure relief body 251 is a burst disk installed on the end cover 23 .
- the pressure relief body 251 may also be the casing 21 for accommodating the electrode assembly 22 .
- a part of the pressure relief body 251 may be the pressure relief portion 2511 , or the entirety of the pressure relief body 251 may be the pressure relief portion 2511 .
- the pressure relief body 251 is an explosion-proof plate installed on the end cover 23, and the pressure relief body 251 may be a pressure relief part 2511 as a whole;
- the pressure portion 2511 can be a wall or a part of a wall of the casing 21 .
- the pressure relief device 25 since the pressure relief part 2511 is provided with a plurality of scoring grooves 252, the plurality of scoring grooves 252 are sequentially arranged on the pressure relief part 2511 along the direction from the first surface 2511a to the second surface 2511b. part 2511, and among the two score grooves 252 adjacent in the thickness direction of the pressure relief part 2511, the maximum width of the score groove 252 away from the first surface 2511a is smaller than the minimum width of the score groove 252 close to the first surface 2511a width, the pressure relief device 25 of this structure adopts a multi-stage notch groove 252 structure, which can reduce the forming force on the pressure relief part 2511 when forming each stage of notch groove 252, and reduce the risk of cracks in the pressure relief part 2511.
- the pressure relief device 25 is less likely to fail due to cracks in the pressure relief portion 2511 at the position where the notch groove 252 is provided, which improves the long-term reliability of the pressure relief device 25 .
- the scoring grooves 252 can be formed on the pressure relief part 2511 pole by pole from the direction from the first surface 2511a to the second surface 2511b.
- the relatively shallow depth makes the pressure relief portion 2511 subjected to less forming force, which can reduce the risk of cracks in the pressure relief portion 2511 and improve the flatness of the first surface 2511a.
- the pressure relief part 2511 can form a larger crack after breaking at the position of the scoring groove 252, which has the advantages of Very good pressure relief effect.
- the plurality of scoring grooves 252 include a first scoring groove 2521 and a second scoring groove 2522 extending in the same direction, and the first scoring groove 2521 is arranged on the second scoring groove. 2522 underside.
- the plurality of scoring grooves 252 includes a first scoring groove 2521 and a second scoring groove 2522, that is to say, among the plurality of scoring grooves 252, one scoring groove 252 is the first scoring groove 2521, and the other scoring groove 252 is the first scoring groove 2521.
- One scoring groove 252 is a second scoring groove 2522 .
- there may be only two scoring grooves 252 among the plurality of scoring grooves 252 and the two scoring grooves 252 are respectively the first scoring groove 2521 and the second scoring groove 2522 .
- the extending directions of the first scoring groove 2521 and the second scoring groove 2522 are consistent, that is, the length direction of the first scoring groove 2521 is consistent with the length direction of the second scoring groove 2522 .
- the bottom surface of the second scoring groove 2522 refers to the surface closest to the second surface 2511b among the groove wall surfaces of the second scoring groove 2522 , that is, the surface connected to the groove side of the second scoring groove 2522 .
- the first scoring groove 2521 is disposed on the bottom surface of the second scoring groove 2522. It can be understood that, in the thickness direction of the pressure relief portion 2511, the first scoring groove 2521 is closer to the second surface than the second scoring groove 2522.
- the first scoring groove 2521 is recessed from the bottom surface of the second scoring groove 2522 in a direction close to the second surface 2511b.
- One first scoring groove 2521 may be provided on the bottom surface of the second scoring groove 2522 , and multiple first scoring grooves 2521 may also be provided.
- one first notch groove 2521 is provided on the bottom surface of the second notch groove 2522 , that is, one second notch groove 2522 is correspondingly provided with one first notch groove 2521 .
- the first scoring groove 2521 may be disposed at a middle position of the bottom surface of the second scoring groove 2522 in the width direction of the second scoring groove 2522 .
- the second scoring groove 2522 is arranged on the first surface 2511a, that is, the second scoring groove 2522 It is recessed from the first surface 2511a toward the direction close to the second surface 2511b.
- the distance between the two opposite groove sides of the second scoring groove 2522 in its width direction gradually increases and decreases from the first surface 2511a to the second surface 2511b, that is, the width of the second scoring groove 2522 is along the first surface 2511a
- the direction to the second surface 2511b gradually decreases.
- the two groove sides opposite to each other in the width direction of the second scoring groove 2522 may be inclined surfaces.
- the distance between the two opposite groove sides of the first scoring groove 2521 in its width direction gradually decreases from the first surface 2511a to the direction of the second surface 2511b, that is, the width of the first scoring groove 2521 is along the direction of the first surface.
- the direction from 2511a to the second surface 2511b gradually decreases.
- the two opposite groove sides of the first scoring groove 2521 in its width direction may also be inclined surfaces.
- the first scoring groove 2521 is arranged on the bottom surface of the second scoring groove 2522.
- this structure It is convenient to form the first scoring groove 2521 and ensure the length of the first scoring groove 2521 .
- it can ensure that the maximum width of the first scoring groove 2521 is smaller than the minimum width of the second scoring groove 2522 .
- FIG. 6 is a partial view of the pressure relief device 25 provided in some other embodiments of the present application
- FIG. 7 is a cross-sectional view of the pressure relief part 2511 shown in FIG. 6.
- the first scoring groove 252 further includes a third scoring groove 2523 , the third scoring groove 2523 is disposed on the first surface 2511 a , and the second scoring groove 2522 is disposed on the bottom surface of the third scoring groove 2523 .
- the plurality of scoring grooves 252 also includes a third scoring groove 2523. It can be understood that the plurality of scoring grooves 252 may only include the first scoring groove 2521, the second scoring groove 2522 and the third scoring groove 2523. , it may also include other scoring grooves 252 besides the first scoring groove 2521, the second scoring groove 2522 and the third scoring groove 2523, for example, the bottom surface of the first scoring groove 2521 is continuously set Score groove 252 .
- the third scoring groove 2523 is disposed on the first surface 2511a, that is, the second scoring groove 2522 is recessed from the first surface 2511a toward the second surface 2511b.
- the third scoring groove 2523 is the scoring groove 252 closest to the first surface 2511a.
- the bottom surface of the third scoring groove 2523 refers to the surface closest to the second surface 2511b among the groove wall surfaces of the third scoring groove 2523 , that is, the surface connected to the groove side of the third scoring groove 2523 .
- the second scoring groove 2522 is disposed on the bottom surface of the third scoring groove 2523. It can be understood that, in the thickness direction of the pressure relief portion 2511, the second scoring groove 2522 is closer to the second surface than the third scoring groove 2523.
- the second scoring groove 2522 is recessed from the bottom surface of the third scoring groove 2523 in a direction close to the second surface 2511b.
- the bottom surface of the third scoring groove 2523 may be provided with one second scoring groove 2522 , or even a plurality of second scoring grooves 2522 .
- the plurality of scoring grooves 252 further include a third scoring groove 2523 disposed on the first surface 2511a, and the second scoring groove 2522 is disposed on the bottom surface of the third scoring groove 2523, that is, pressure relief
- the portion 2511 is provided with three-level scoring grooves 252 to ensure that the pressure relief portion 2511 will not be subjected to excessive forming force when forming each level of scoring grooves 252, thereby reducing the risk of cracks in the pressure relief portion 2511.
- the bottom surface of the third scoring groove 2523 is provided with a plurality of second scoring grooves 2522 .
- the shape of the third scoring groove 2523 can be various, for example, the third scoring groove 2523 is a circular groove, a rectangular groove and the like. Exemplarily, in FIG. 6 , the third scoring groove 2523 is a rectangular groove.
- the plurality of second scoring grooves 2522 arranged on the bottom surface of the third scoring groove 2523 can be arranged in various ways, for example, a plurality of second scoring grooves 2522 are arranged in parallel, and for another example, as shown in Figure 6, multiple The second scoring groove 2522 constitutes an approximately "H"-shaped structure.
- the pressure relief part 2511 can be ruptured at the position of each second notch groove 2522 to realize pressure relief, which has a better performance. Good pressure relief effect improves the pressure relief rate.
- one third scoring groove 2523 corresponds to a plurality of second scoring grooves 2522, the molding process can be simplified and the molding cost can be reduced.
- FIG. 8 is a positional relationship diagram of the first notch groove 2521 , the second notch groove 2522 and the third notch groove 2523 shown in FIG. 6 , a plurality of second notch grooves
- the groove 2522 includes a first groove segment 2522a, a second groove segment 2522b and a third groove segment 2522c, the first groove segment 2522a and the second groove segment 2522b are arranged at intervals, and the first groove segment 2522a and the second groove segment 2522b are connected to the third groove segment 2522b. Slot segments 2522c intersect.
- the pressure relief part 2511 includes an opening area 2511c defined by the first groove segment 2522a, the second groove segment 2522b and the third groove segment 2522c, and the opening area 2511c is configured as the first groove segment 2522a, the second groove segment 2522b and the third groove segment 2522c.
- the three-slot segment 2522c is open for the border.
- the plurality of second scoring grooves 2522 includes a first groove segment 2522a, a second groove segment 2522b and a third groove segment 2522c, that is, among the plurality of second scoring grooves 2522, one second scoring groove 2522 is The first groove segment 2522a, another second scoring groove 2522 is a second groove segment 2522b, and another second scoring groove 2522 is a third groove segment 2522c.
- the opening area 2511c is an area defined by the first slot section 2522a , the second slot section 2522b and the third slot section 2522c of the pressure relief portion 2511 .
- the opening area 2511c defined by the first groove segment 2522a, the second groove segment 2522b and the third groove segment 2522c may be one or two.
- the first groove section 2522a, the second groove section 2522b and the third groove section 2522c form an approximately " ⁇ "-shaped structure, and there is one opening area 2511c;
- the three groove segments 2522c form an approximately "H"-shaped structure, and there are two opening regions 2511c.
- the opening area 2511c is the area where the pressure relief part 2511 releases pressure.
- the part of the pressure relief part 2511 in the opening area 2511c will form a first groove section 2522a, second slot segment 2522b, and third slot segment 2522c are bordered open for pressure relief.
- the first groove section 2522a, the second groove section 2522b and the third groove section 2522c are all arranged on the bottom surface of the third scoring groove 2523,
- the opening area 2511c is located in the range of the third scoring groove 2523, and the third scoring groove 2523 can be the part of the pressure relief part 2511 located in the opening area 2511c, with the first groove segment 2522a, the second groove segment 2522b and the third groove Segment 2522c provides clearance during border opening.
- both the second groove segment 2522b and the second groove segment 2522b intersect the third groove segment 2522c, the first groove segment 2522a, the second groove segment Segment 2522b and third groove segment 2522c together define an opening area 2511c, this structure makes the pressure relief part 2511 rupture after the first groove segment 2522a, the second groove segment 2522b and the second groove segment 2522b, the pressure relief part 2511 The part located in the opening area 2511c will be opened for pressure relief, which increases the pressure relief area of the pressure relief portion 2511 and improves the pressure relief rate of the pressure relief portion 2511 .
- the plurality of second scoring grooves 2522 further include a fourth groove segment 2522d, and in the extending direction of the third groove segment 2522c, the fourth groove segment 2522d is located at the first groove segment 2522a Between the second slot segment 2522b, the fourth slot segment 2522d intersects the third slot segment 2522c.
- the plurality of second scoring grooves 2522 includes a fourth groove segment 2522d. Understandably, the plurality of second scoring grooves 2522 may only include the first groove segment 2522a, the second groove segment 2522b, the third groove segment 2522c and The fourth slot segment 2522d may also include other slot segments in addition to the first slot segment 2522a, the second slot segment 2522b, the third slot segment 2522c and the fourth slot segment 2522d. Exemplarily, the fourth slot segment 2522d may be parallel to the first slot segment 2522a and the second slot segment 2522b, and perpendicular to the third slot segment 2522c.
- the fourth groove section 2522d located between the first groove section 2522a and the second groove section 2522b intersects with the third groove section 2522c
- the pressure relief part 2511 is located between the third groove section 2522c and the fourth groove section 2522d.
- the stress at the intersection position is more concentrated, and it is easier to break, so that the pressure relief part 2511 breaks along the third groove segment 2522c from the position where the third groove segment 2522c and the fourth groove segment 2522d intersect during the pressure relief process, and breaks in the third groove segment 2522c. After the segment 2522c breaks, it ruptures along the first groove segment 2522a and the second groove segment 2522b, so as to realize rapid pressure relief.
- the depth of the first groove segment 2522a is equal to the depth of the second groove segment 2522b
- the depth of the third groove segment 2522c is equal to the depth of the fourth groove segment 2522d
- the depth of the first groove segment 2522a is smaller than that of the third groove segment
- the depth of 2522c makes it easier for the pressure relief portion 2511 to rupture along the third groove section 2522c from the intersection of the third groove section 2522c and the fourth groove section 2522d during the pressure relief process.
- the depth of the first groove section 2522a, the depth of the second groove section 2522b and the depth of the third groove section 2522c are all smaller than the depth of the fourth groove section 2522d, which can also ensure that the pressure part is in the pressure relief process. It is easier to break along the third groove segment 2522c from the position where the third groove segment 2522c intersects the fourth groove segment 2522d.
- the distance from the intersection of the fourth slot segment 2522d and the third slot segment 2522c to the first slot segment 2522a is equal to that between the fourth slot segment 2522d and the third slot segment 2522c The distance from the intersection location to the second slot segment 2522b.
- the distance from the intersection of the fourth groove segment 2522d and the third groove segment 2522c to the first groove segment 2522a is the distance between the third groove segment 2522c and the first groove segment 2522d.
- the distance from the intersection of the fourth groove segment 2522d and the third groove segment 2522c to the second groove segment 2522b is the distance between the third groove segment 2522c and the second groove segment 2522d.
- the distance from the intersection of the fourth groove segment 2522d and the third groove segment 2522c to the first groove segment 2522a is equal to the distance from the intersection position of the fourth groove segment 2522d and the third groove segment 2522c to the second groove segment 2522b , so that the pressure relief part 2511 can break along the third groove segment 2522c at the intersection of the fourth groove segment 2522d and the third groove segment 2522c, and then simultaneously rupture along the first groove segment 2522a and the second groove segment 2522b.
- the first groove segment 2522a, the second groove segment 2522b and the third groove segment 2522c define two opening regions 2511c, and the two opening regions 2511c are respectively located at the sides of the third groove segment 2522c. sides.
- the first slot section 2522a, the second slot section 2522b and the third slot section 2522c jointly define two open areas 2511c, and the first slot section 2522a, the second slot section 2522b and the third slot section 2522c can form an approximate "H" shape structure.
- the two opening areas 2511c are respectively located on both sides of the third groove section 2522c, so that the two opening areas 2511c are bounded by the third groove section 2522c. After the pressure relief part 2511 is broken at the position of the third groove section 2522c, the two opening areas 2511c It will open in half along the first slot section 2522a and the second slot section 2522b for pressure relief.
- the first groove segment 2522a , the second groove segment 2522b and the third groove segment 2522c may define two opening regions 2511c.
- the two opening areas 2511c are respectively located on both sides of the third slot section 2522c, and the pressure relief During the pressure relief process of the pressure relief portion 2511, the parts of the pressure relief portion 2511 in the two pressure relief areas can be opened in half for pressure relief, which can effectively increase the pressure relief rate of the pressure relief portion 2511.
- the second surface 2511b is provided with a notch groove 253 at least partially located in the opening area 2511c, and in the extending direction of the first groove segment 2522a, the notch groove 253 Slot segment 2522c has a distance.
- the second surface 2511b is provided with a notch groove 253 at least partially located in the opening area 2511c. It can be understood that the notch groove 253 is recessed from the second surface 2511b in a direction facing the first surface 2511a, and the notch groove 253 is at least partially located in the opening area 2511c. Certainly, the notch groove 253 may be completely located in the opening area 2511c, or the notch groove 253 may be partially located in the opening area 2511c.
- the notch groove 253 can extend along the extension direction of the third groove segment 2522c, so that the notch groove 253 is parallel to the third groove segment 2522c.
- the first surface 2511a may be provided with a corresponding notch groove 253 .
- the first surface 2511a can be provided with two notch grooves 253 correspondingly , one open area 2511c is correspondingly provided with one notch groove 253 .
- the notch groove 253 and the third groove segment 2522c there is a distance between the notch groove 253 and the third groove segment 2522c in the extending direction of the first groove segment 2522a, and at least part of the notch groove 253 is located in the opening area 2511c, so that the pressure relief part 2511 is in the pressure relief process.
- the part of the pressure relief part 2511 located in the opening area 2511c can be turned around with the position of the pressure relief part 2511 located in the notch 253 as an axis, so that it is easier to open the pressure relief.
- the distance between the first surface 2511a and the second surface 2511b is H0
- the distance from the bottom surface of the scoring groove 252 closest to the second surface 2511b to the second surface 2511b is H1
- H0 and H1 satisfy the relational expression: H1/H0 ⁇ 0.2.
- the distance between the first surface 2511a and the second surface 2511b is the thickness of the pressure relief portion 2511 .
- the distance from the bottom surface of the scoring groove 252 closest to the second surface 2511b to the second surface 2511b is the thickness of the portion between the bottom surface of the scoring groove 252 closest to the second surface 2511b and the second surface 2511b.
- the first scoring groove 2521 is the groove closest to the second surface 2511b. Trace groove 252 .
- the ratio of the distance from the bottom surface of the scoring groove 252 closest to the second surface 2511b to the second surface 2511b to the distance from the first surface 2511a to the second surface 2511b is less than 0.2, so that the closest to the second surface 2511b
- the thickness of the part between the bottom surface of the scoring groove 252 and the second surface 2511b accounts for a relatively small proportion in the total thickness of the pressure relief part 2511, so that the bottom surface of the scoring groove 252 closest to the second surface 2511b and the second surface
- the part between 2511b can rupture normally to achieve pressure relief.
- the distance from the bottom surface of the scoring groove 252 closest to the second surface 2511b to the second surface 2511b is H1, and H1 satisfies the relationship H1 ⁇ 0.5mm.
- the distance between the bottom surface of the scoring groove 252 closest to the second surface 2511b and the second surface 2511b is less than 0.5mm, so that the distance between the bottom surface of the scoring groove 252 closest to the second surface 2511b and the second surface 2511b The thickness of the part between them is small, which is easy to rupture and release pressure.
- the depth of the scoring groove 252 disposed on the first surface 2511a is H2, and H2 satisfies the relationship H2 ⁇ 1 mm.
- the depth of the scoring groove 252 disposed on the first surface 2511a is the distance from the bottom surface of the scoring groove 252 disposed on the first surface 2511a to the first surface 2511a.
- the third scoring groove 2523 is a scoring provided on the first surface 2511a Slot 252.
- the depth of the scoring groove 252 provided on the first surface 2511a is less than 1 mm, so that the depth of the scoring groove 252 on the outermost side of the pressure relief part 2511 is relatively small, reducing the pressure of the pressure relief part 2511 on the scoring groove.
- the molding force 252 receives during the molding process reduces the risk of cracks in the pressure relief portion 2511 .
- the depth of the scoring groove 252 between the scoring groove 252 closest to the second surface 2511b and the scoring groove 252 disposed on the first surface 2511a is H3, and H3 satisfies the relationship H3 ⁇ 1.5mm.
- the plurality of scoring grooves 252 includes at least three scoring grooves 252 .
- the scoring groove 252 closest to the second surface 2511b is the first scoring groove 2521
- the notch groove 252 provided on the first surface 2511a is the third notch groove 2523
- the groove 252 is the second scoring groove 2522 .
- the depth of the notch groove 252 between the notch groove 252 closest to the second surface 2511b and the notch groove 252 disposed on the first surface 2511a is less than 1.5mm, so that the pressure relief part 2511 except the most
- the score grooves 252 near the second surface 2511b and the score grooves 252 other than the score grooves 252 provided on the first surface 2511a have a smaller depth, which reduces the molding force on the pressure relief part 2511 during the molding process and reduces the pressure relief part. 2511 Risk of cracking.
- FIG. 9 is a schematic structural diagram of a pressure relief device 25 provided in some other embodiments of the present application.
- An accommodation space is formed inside the pressure relief body 251 .
- a plurality of walls, the accommodating space is used for accommodating the electrode assembly 22 , and a pressure relief portion 2511 is formed on one of the plurality of walls.
- One of the multiple walls is formed with a pressure relief portion 2511 , and a part of one wall may be the pressure relief portion 2511 , or the whole of one wall may be the pressure relief portion 2511 .
- the first surface 2511a of the pressure relief part 2511 may be the outer surface of the wall, or the inner surface of the wall.
- the outer surface of the wall is the surface of the wall facing away from the electrode assembly 22
- the inner surface of the wall is the surface of the wall facing the electrode assembly 22 .
- the pressure relief body 251 can be in various shapes, such as a cuboid, a cylinder, and the like.
- a plurality of walls of the pressure relief body 251 define an accommodation chamber for accommodating the electrode assembly 22, and one of the walls is formed with a pressure relief portion 2511, so that the pressure relief device 25 has the function of accommodating the electrode assembly.
- the accommodation function of 22 has pressure relief function again.
- the multiple walls of the pressure relief body 251 include a peripheral wall 2512 and a bottom wall 2513 , the peripheral wall 2512 surrounds the edge of the bottom wall 2513 , and the peripheral wall 2512 and the bottom wall 2513 jointly define an accommodation space. , the bottom wall 2513 is formed with a pressure relief portion 2511 .
- the peripheral wall 2512 surrounds the edge of the bottom wall 2513 , so that the pressure relief body 251 forms an opening at the opposite end of the bottom wall 2513 , and the end cap 23 is used to cover the opening.
- the pressure relief body 251 may have two walls, one wall is the bottom wall 2513 and the other wall is the peripheral wall 2512 . As shown in FIG. 9 , in the embodiment where the pressure relief body 251 is a cuboid, the pressure relief body 251 may have five walls, a bottom wall 2513 and four side walls, and the four side walls are connected end to end to form a peripheral wall 2512 .
- the peripheral wall 2512 and the bottom wall 2513 are integrally formed.
- peripheral wall 2512 and the bottom wall 2513 are integrally formed, that is to say, the peripheral wall 2512 and the bottom wall 2513 are integrally formed together.
- the peripheral wall 2512 and the bottom wall 2513 are integrally formed, so that the peripheral wall 2512 and the bottom wall 2513 with a pressure relief function have good firmness.
- the formula design can simplify the molding process and reduce the production cost.
- the first surface 2511a is the outer surface of the bottom wall 2513, that is to say, the plurality of scoring grooves 252 on the pressure relief portion 2511 are arranged sequentially from the outer surface of the bottom wall 2513 to the inner surface of the bottom wall 2513, It is convenient to process the scoring groove 252 on the pressure relief body 251 .
- the embodiment of the present application provides a battery cell 20 including the pressure relief device 25 provided in any one of the above embodiments.
- a battery 100 includes a box body 10 and a battery cell 20 provided in any one of the above embodiments, and the box body 10 is used to accommodate the battery cell 20 .
- an electrical device includes the battery 100 provided in any one of the above embodiments.
- the electric device may be any of the above-mentioned devices using the battery 100 .
- the embodiment of the present application also provides a casing 21, the casing 21 includes a plurality of walls, and the plurality of walls jointly define the accommodation space for accommodating the electrode assembly 22, at least one of the walls is provided with A plurality of scoring grooves 252, the wall has opposite first surface 2511a and second surface 2511b in its thickness direction, and a plurality of scoring grooves 252 are sequentially arranged on the wall along the direction from the first surface 2511a to the second surface 2511b , among two adjacent scoring grooves 252 in the wall thickness direction, the maximum width of the scoring groove 252 away from the first surface 2511a is smaller than the minimum width of the scoring groove 252 close to the first surface 2511a.
- the shell 21 of this structure integrates the pressure relief function and the containment function, and adopts a multi-stage scoring groove 252 structure, which can reduce the molding force on the shell 21 when forming each level of scoring groove 252, and reduce the pressure on the shell 21. The risk of cracks is eliminated, increasing the long-term reliability of the pressure relief device 25.
- Fig. 10 is a flow chart of the manufacturing method of the pressure relief device 25 provided by some embodiments of the present application, the method includes:
- S100 Provide a pressure relief body 251, the pressure relief body 251 includes a pressure relief portion 2511, and the pressure relief portion 2511 has opposite first surfaces 2511a and second surfaces 2511b in its thickness direction;
- S200 sequentially process a plurality of scoring grooves 252 on the pressure relief part 2511 along the direction from the first surface 2511a to the second surface 2511b;
- the maximum width of the scoring groove 252 on the surface 2511a is smaller than the minimum width of the scoring groove 252 near the first surface 2511a.
- sequentially processing a plurality of scoring grooves 252 on the pressure relief portion 2511 along the direction from the first surface 2511a to the second surface 2511b includes: on the pressure relief portion 2511 along the first surface 2511a to the second surface A plurality of scoring grooves 252 are sequentially punched in the direction of 2511b.
- a plurality of scoring grooves 252 are sequentially formed on the pressure relief portion 2511 in the direction from the first surface 2511a to the second surface 2511b by stamping, the forming process is simple, and the pressure relief portion 2511 can be reduced when stamping each level of scoring groove 252 The received pressing force reduces the risk of cracks in the pressure relief portion 2511 .
- FIG. 11 is a schematic block diagram of the manufacturing equipment 2000 of the pressure relief device 25 provided by some embodiments of the present application.
- a first providing device 2100 and a processing device 2200 The first providing device 2100 is used for providing a pressure relief body 251, the pressure relief body 251 includes a pressure relief portion 2511, and the pressure relief portion 2511 has a first surface 2511a and a second surface 2511b opposite to each other along its thickness direction.
- the processing device 2200 is used to sequentially process a plurality of scoring grooves 252 on the pressure relief portion 2511 along the direction from the first surface 2511a to the second surface 2511b. Among the two adjacent scoring grooves 252 in the thickness direction, the maximum width of the scoring groove 252 away from the first surface 2511a is smaller than the minimum width of the scoring groove 252 close to the first surface 2511a.
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Abstract
Description
Claims (23)
- 一种泄压装置,其中,包括:泄压本体,包括泄压部,所述泄压部在其厚度方向上具有相对的第一表面和第二表面;多个刻痕槽,沿所述第一表面到所述第二表面的方向依次布置于所述泄压部,在所述厚度方向上相邻的两个刻痕槽中,远离所述第一表面的刻痕槽的最大宽度小于靠近所述第一表面的刻痕槽的最小宽度。
- 根据权利要求1所述的泄压装置,其中,所述多个刻痕槽包括延伸方向一致的第一刻痕槽和第二刻痕槽,所述第一刻痕槽设置于所述第二刻痕槽的底面。
- 根据权利要求2所述的泄压装置,其中,所述多个刻痕槽还包括第三刻痕槽,所述第三刻痕槽设置于所述第一表面,所述第二刻痕槽设置于所述第三刻痕槽的底面。
- 根据权利要求3所述的泄压装置,其中,所述第三刻痕槽的底面设置有多个第二刻痕槽。
- 根据权利要求4所述的泄压装置,其中,所述多个第二刻痕槽包括第一槽段、第二槽段和第三槽段,所述第一槽段和所述第二槽段间隔设置,所述第一槽段和所述第二槽段均与所述第三槽段相交;所述泄压部包括由所述第一槽段、第二槽段和第三槽段共同界定出开启区,所述开启区被配置为以第一槽段、第二槽段和第三槽段为边界打开。
- 根据权利要求5所述的泄压装置,其中,所述多个第二刻痕槽还包括第四槽段,在所述第三槽段的延伸方向上,所述第四槽段位于所述第一槽段与所述第二槽段之间,所述第四槽段与所述第三槽段相交。
- 根据权利要求6所述的泄压装置,其中,在所述第三槽段的延伸方向上,所述第四槽段与所述第三槽段相交位置到第一槽段的距离等于所述第四槽段与所述第三槽段相交位置到第二槽段的距离。
- 根据权利要求5-7任一项所述的泄压装置,其中,所述第一槽段、所述第二槽段和所述第三槽段界定出两个开启区,两个开启区分别位于所述第三槽段的两侧。
- 根据权利要求5-8任一项所述的泄压装置,其中,所述第二表面上设有位于所述开启区的缺口槽,在第一槽段的延伸方向上,所述缺口槽与所述第三槽段存在距离。
- 根据权利要求1-9任一项所述的泄压装置,其中,所述第一表面与所述第二表面的距离为H0,最靠近所述第二表面的刻痕槽的底面到所述第二表面的距离为H1,H0与H1满足关系式:H1/H0<0.2。
- 根据权利要求1-10任一项所述的泄压装置,其中,最靠近所述第二表面的刻痕槽的底面到所述第二表面的距离为H1,H1满足关系式H1<0.5mm。
- 根据权利要求1-11任一项所述的泄压装置,其中,设置于所述第一表面的刻痕槽的深度为H2,H2满足关系式H2<1mm。
- 根据权利要求1-12任一项所述的泄压装置,其中,最靠近所述第二表面的刻痕槽与设置于所述第一表面的刻痕槽之间的刻痕槽的深度为H3,H3满足关系式H3<1.5mm。
- 根据权利要求1-13任一项所述的泄压装置,其中,所述泄压本体内部形成有容纳空间,所述泄压本体具有界定出所述容纳空间的多个壁,所述容纳空间用于收容电极组件,所述多个壁中的一个壁形成有所述泄压部。
- 根据权利要求14所述的泄压装置,其中,所述多个壁包括周壁和底壁,所述周壁围设于所述底壁的边缘,所述周壁与所述底壁共同限定出所述容纳空间,所述底壁形成有所述泄压部。
- 根据权利要求15所述的泄压装置,其中,所述周壁与所述底壁为一体成型结构。
- 根据权利要求15或16所述的泄压装置,其中,所述第一表面为所述底壁的外表面。
- 一种电池单体,包括根据权利要求1-17任一项所述的泄压装置。
- 一种电池,包括:根据权利要求18所述的电池单体;以及箱体,用于容纳所述电池单体。
- 一种用电设备,包括根据权利要求19所述的电池。
- 一种泄压装置的制造方法,所述方法包括:提供泄压本体,所述泄压本体包括泄压部,所述泄压部在其厚度方向上具有相对的第一表面和第二表面;在所述泄压部上沿所述第一表面到所述第二表面的方向依次加工出多个刻痕槽;在所述厚度方向上相邻的两个刻痕槽中,远离所述第一表面的刻痕槽的最大宽度小于靠近所述第一表面的刻痕槽的最小宽度。
- 根据权利要求21所述的泄压装置的制造方法,其中,所述在所述泄压部上沿所述第一表面到所述第二表面的方向依次加工出多个刻痕槽包括:在所述泄压部上沿所述第一表面到所述第二表面的方向上依次冲压出多个刻痕槽。
- 一种泄压装置的制造设备,包括:第一提供装置,用于提供泄压本体,所述泄压本体包括泄压部,所述泄压部在其厚度方向上具有相对的第一表面和第二表面;以及加工装置,用于在所述泄压部上沿所述第一表面到所述第二表面的方向依次加工出多个刻痕槽;其中,在所述厚度方向上相邻的两个刻痕槽中,远离所述第一表面的刻痕槽的最大宽度小于靠近所述第一表面的刻痕槽的最小宽度。
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JP2023502626A JP7514380B2 (ja) | 2021-08-31 | 2021-08-31 | 圧力解放装置、電池セル、電池及び電気デバイス |
EP21948694.1A EP4167368A4 (en) | 2021-08-31 | 2021-08-31 | DECOMPRESSION DEVICE, BATTERY CELL, BATTERY AND POWER CONSUMPTION DEVICE |
PCT/CN2021/115766 WO2023028864A1 (zh) | 2021-08-31 | 2021-08-31 | 泄压装置、电池单体、电池及用电设备 |
CA3183528A CA3183528A1 (en) | 2021-08-31 | 2021-08-31 | Pressure relief apparatus, battery cell, battery, and electrical device |
CN202180066181.6A CN116438702A (zh) | 2021-08-31 | 2021-08-31 | 泄压装置、电池单体、电池及用电设备 |
KR1020237003696A KR20230035342A (ko) | 2021-08-31 | 2021-08-31 | 압력 완화 장치, 배터리 셀, 배터리 및 전기 기기 |
KR1020237015526A KR20230084541A (ko) | 2021-08-31 | 2022-08-31 | 압력 완화 장치, 배터리 셀, 배터리 및 전기 기기 |
KR1020237016596A KR20230088468A (ko) | 2021-08-31 | 2022-08-31 | 감압 장치, 배터리 셀, 배터리 및 전기 설비 |
EP22863534.8A EP4340112A1 (en) | 2021-08-31 | 2022-08-31 | Pressure relief apparatus, battery cell, battery and electrical device |
CN202280009602.6A CN116711134A (zh) | 2021-08-31 | 2022-08-31 | 泄压装置、电池单体、电池及用电设备 |
PCT/CN2022/116298 WO2023030404A1 (zh) | 2021-08-31 | 2022-08-31 | 泄压装置、电池单体、电池及用电设备 |
CN202280010076.5A CN116783763A (zh) | 2021-08-31 | 2022-08-31 | 泄压装置、电池单体、电池及用电设备 |
CN202222326423.5U CN218769952U (zh) | 2021-08-31 | 2022-08-31 | 泄压装置、电池单体、电池及用电设备 |
KR1020237016558A KR20230088460A (ko) | 2021-08-31 | 2022-08-31 | 감압 장치, 배터리 셀, 배터리 및 전기 설비 |
PCT/CN2022/116275 WO2023030399A1 (zh) | 2021-08-31 | 2022-08-31 | 泄压装置、电池单体、电池及用电设备 |
EP22863540.5A EP4287380A1 (en) | 2021-08-31 | 2022-08-31 | Pressure relief device, battery cell, battery, and power consumption apparatus |
CN202280005459.3A CN116075964A (zh) | 2021-08-31 | 2022-08-31 | 泄压装置、电池单体、电池及用电设备 |
JP2023528257A JP2023549795A (ja) | 2021-08-31 | 2022-08-31 | 圧力解放装置、電池セル、電池及び電気装置 |
JP2023530008A JP2023549907A (ja) | 2021-08-31 | 2022-08-31 | 放圧装置、電池セル、電池及び電力消費機器 |
CN202222314334.9U CN218414924U (zh) | 2021-08-31 | 2022-08-31 | 泄压装置、电池单体、电池及用电设备 |
CN202222314407.4U CN218414925U (zh) | 2021-08-31 | 2022-08-31 | 泄压装置、电池单体、电池及用电设备 |
EP22863539.7A EP4239777A1 (en) | 2021-08-31 | 2022-08-31 | Pressure relief apparatus, battery cell, battery and electrical device |
JP2023530006A JP2023549906A (ja) | 2021-08-31 | 2022-08-31 | 放圧装置、電池セル、電池及び電力消費機器 |
PCT/CN2022/116299 WO2023030405A1 (zh) | 2021-08-31 | 2022-08-31 | 泄压装置、电池单体、电池及用电设备 |
US18/187,207 US20230223644A1 (en) | 2021-08-31 | 2023-03-21 | Pressure relief apparatus, battery cell, battery, and electrical device |
US18/333,167 US20230327275A1 (en) | 2021-08-31 | 2023-06-12 | Pressure relief apparatus, battery cell, battery, and electrical device |
US18/464,845 US20230420793A1 (en) | 2021-08-31 | 2023-09-11 | Pressure relief apparatus, battery cell, battery, and power consuming device |
US18/413,080 US20240154240A1 (en) | 2021-08-31 | 2024-01-16 | Pressure relief apparatus, battery cell, battery, and power consuming device |
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PCT/CN2021/115766 WO2023028864A1 (zh) | 2021-08-31 | 2021-08-31 | 泄压装置、电池单体、电池及用电设备 |
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PCT/CN2022/116275 WO2023030399A1 (zh) | 2021-08-31 | 2022-08-31 | 泄压装置、电池单体、电池及用电设备 |
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PCT/CN2022/116298 WO2023030404A1 (zh) | 2021-08-31 | 2022-08-31 | 泄压装置、电池单体、电池及用电设备 |
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PCT/CN2022/116299 WO2023030405A1 (zh) | 2021-08-31 | 2022-08-31 | 泄压装置、电池单体、电池及用电设备 |
PCT/CN2022/116298 WO2023030404A1 (zh) | 2021-08-31 | 2022-08-31 | 泄压装置、电池单体、电池及用电设备 |
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EP (4) | EP4167368A4 (zh) |
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CN116207434B (zh) * | 2023-05-06 | 2024-02-20 | 宁德时代新能源科技股份有限公司 | 泄压部件、电池单体、电池及用电装置 |
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US20200328399A1 (en) * | 2017-12-13 | 2020-10-15 | Byd Company Limited | Battery cover plate assembly, cell, battery module, power battery, and electric vehicle |
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JP2016157570A (ja) * | 2015-02-24 | 2016-09-01 | 東芝照明プレシジョン株式会社 | 封口板、封口板の製造方法、及び、密閉型電池 |
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JP7514380B2 (ja) | 2024-07-10 |
WO2023030405A1 (zh) | 2023-03-09 |
JP2023542593A (ja) | 2023-10-11 |
WO2023030404A1 (zh) | 2023-03-09 |
WO2023030399A1 (zh) | 2023-03-09 |
KR20230035342A (ko) | 2023-03-13 |
CA3183528A1 (en) | 2023-02-28 |
US20230223644A1 (en) | 2023-07-13 |
KR20230088460A (ko) | 2023-06-19 |
EP4167368A4 (en) | 2024-05-15 |
JP2023549906A (ja) | 2023-11-29 |
US20230327275A1 (en) | 2023-10-12 |
KR20230084541A (ko) | 2023-06-13 |
KR20230088468A (ko) | 2023-06-19 |
EP4287380A1 (en) | 2023-12-06 |
JP2023549907A (ja) | 2023-11-29 |
EP4340112A1 (en) | 2024-03-20 |
EP4167368A1 (en) | 2023-04-19 |
CN116711134A (zh) | 2023-09-05 |
CN116783763A (zh) | 2023-09-19 |
CN218414924U (zh) | 2023-01-31 |
EP4239777A1 (en) | 2023-09-06 |
CN116438702A (zh) | 2023-07-14 |
US20230420793A1 (en) | 2023-12-28 |
CN116075964A (zh) | 2023-05-05 |
CN218414925U (zh) | 2023-01-31 |
US20240154240A1 (en) | 2024-05-09 |
JP2023549795A (ja) | 2023-11-29 |
CN218769952U (zh) | 2023-03-28 |
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