WO2023010884A1 - Ammonia fuel transporting and filling ship - Google Patents
Ammonia fuel transporting and filling ship Download PDFInfo
- Publication number
- WO2023010884A1 WO2023010884A1 PCT/CN2022/086414 CN2022086414W WO2023010884A1 WO 2023010884 A1 WO2023010884 A1 WO 2023010884A1 CN 2022086414 W CN2022086414 W CN 2022086414W WO 2023010884 A1 WO2023010884 A1 WO 2023010884A1
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- WIPO (PCT)
- Prior art keywords
- cabin
- ammonia
- fuel
- pipeline
- hull
- Prior art date
Links
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 title claims abstract description 208
- 239000000446 fuel Substances 0.000 title claims abstract description 126
- 229910021529 ammonia Inorganic materials 0.000 title claims abstract description 91
- 239000007788 liquid Substances 0.000 claims abstract description 60
- 238000005406 washing Methods 0.000 claims abstract description 10
- 238000001514 detection method Methods 0.000 claims abstract description 8
- 238000009423 ventilation Methods 0.000 claims description 12
- 238000007667 floating Methods 0.000 claims description 8
- 238000002955 isolation Methods 0.000 claims description 8
- 230000003472 neutralizing effect Effects 0.000 claims description 5
- 238000002347 injection Methods 0.000 claims description 4
- 239000007924 injection Substances 0.000 claims description 4
- 239000002828 fuel tank Substances 0.000 claims description 2
- 238000009434 installation Methods 0.000 claims 1
- 231100000572 poisoning Toxicity 0.000 abstract description 6
- 230000000607 poisoning effect Effects 0.000 abstract description 6
- 239000007789 gas Substances 0.000 description 33
- 238000006386 neutralization reaction Methods 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 230000008859 change Effects 0.000 description 5
- 229910001220 stainless steel Inorganic materials 0.000 description 5
- 239000010935 stainless steel Substances 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229910000617 Mangalloy Inorganic materials 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 230000005489 elastic deformation Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000005431 greenhouse gas Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- QFGIVKNKFPCKAW-UHFFFAOYSA-N [Mn].[C] Chemical compound [Mn].[C] QFGIVKNKFPCKAW-UHFFFAOYSA-N 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- -1 and at the same time Substances 0.000 description 1
- 238000003287 bathing Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000000110 cooling liquid Substances 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
- B63B—SHIPS OR OTHER WATERBORNE VESSELS; EQUIPMENT FOR SHIPPING
- B63B25/00—Load-accommodating arrangements, e.g. stowing, trimming; Vessels characterised thereby
- B63B25/02—Load-accommodating arrangements, e.g. stowing, trimming; Vessels characterised thereby for bulk goods
- B63B25/08—Load-accommodating arrangements, e.g. stowing, trimming; Vessels characterised thereby for bulk goods fluid
- B63B25/082—Arrangements for minimizing pollution by accidents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
- B63B—SHIPS OR OTHER WATERBORNE VESSELS; EQUIPMENT FOR SHIPPING
- B63B17/00—Vessels parts, details, or accessories, not otherwise provided for
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/54—Nitrogen compounds
- B01D53/58—Ammonia
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/77—Liquid phase processes
- B01D53/78—Liquid phase processes with gas-liquid contact
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
- B63B—SHIPS OR OTHER WATERBORNE VESSELS; EQUIPMENT FOR SHIPPING
- B63B17/00—Vessels parts, details, or accessories, not otherwise provided for
- B63B17/0027—Tanks for fuel or the like ; Accessories therefor, e.g. tank filler caps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
- B63B—SHIPS OR OTHER WATERBORNE VESSELS; EQUIPMENT FOR SHIPPING
- B63B25/00—Load-accommodating arrangements, e.g. stowing, trimming; Vessels characterised thereby
- B63B25/02—Load-accommodating arrangements, e.g. stowing, trimming; Vessels characterised thereby for bulk goods
- B63B25/08—Load-accommodating arrangements, e.g. stowing, trimming; Vessels characterised thereby for bulk goods fluid
- B63B25/12—Load-accommodating arrangements, e.g. stowing, trimming; Vessels characterised thereby for bulk goods fluid closed
- B63B25/14—Load-accommodating arrangements, e.g. stowing, trimming; Vessels characterised thereby for bulk goods fluid closed pressurised
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
- B63B—SHIPS OR OTHER WATERBORNE VESSELS; EQUIPMENT FOR SHIPPING
- B63B25/00—Load-accommodating arrangements, e.g. stowing, trimming; Vessels characterised thereby
- B63B25/02—Load-accommodating arrangements, e.g. stowing, trimming; Vessels characterised thereby for bulk goods
- B63B25/08—Load-accommodating arrangements, e.g. stowing, trimming; Vessels characterised thereby for bulk goods fluid
- B63B25/12—Load-accommodating arrangements, e.g. stowing, trimming; Vessels characterised thereby for bulk goods fluid closed
- B63B25/16—Load-accommodating arrangements, e.g. stowing, trimming; Vessels characterised thereby for bulk goods fluid closed heat-insulated
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
- B63B—SHIPS OR OTHER WATERBORNE VESSELS; EQUIPMENT FOR SHIPPING
- B63B27/00—Arrangement of ship-based loading or unloading equipment for cargo or passengers
- B63B27/24—Arrangement of ship-based loading or unloading equipment for cargo or passengers of pipe-lines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
- B63B—SHIPS OR OTHER WATERBORNE VESSELS; EQUIPMENT FOR SHIPPING
- B63B27/00—Arrangement of ship-based loading or unloading equipment for cargo or passengers
- B63B27/30—Arrangement of ship-based loading or unloading equipment for transfer at sea between ships or between ships and off-shore structures
- B63B27/34—Arrangement of ship-based loading or unloading equipment for transfer at sea between ships or between ships and off-shore structures using pipe-lines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
- B63B—SHIPS OR OTHER WATERBORNE VESSELS; EQUIPMENT FOR SHIPPING
- B63B59/00—Hull protection specially adapted for vessels; Cleaning devices specially adapted for vessels
- B63B59/02—Fenders integral with waterborne vessels or specially adapted therefor, e.g. fenders forming part of the hull or incorporated in the hull; Rubbing-strakes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
- B63H—MARINE PROPULSION OR STEERING
- B63H21/00—Use of propulsion power plant or units on vessels
- B63H21/38—Apparatus or methods specially adapted for use on marine vessels, for handling power plant or unit liquids, e.g. lubricants, coolants, fuels or the like
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
- B63J—AUXILIARIES ON VESSELS
- B63J2/00—Arrangements of ventilation, heating, cooling, or air-conditioning
- B63J2/02—Ventilation; Air-conditioning
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
- B63B—SHIPS OR OTHER WATERBORNE VESSELS; EQUIPMENT FOR SHIPPING
- B63B25/00—Load-accommodating arrangements, e.g. stowing, trimming; Vessels characterised thereby
- B63B25/02—Load-accommodating arrangements, e.g. stowing, trimming; Vessels characterised thereby for bulk goods
- B63B25/08—Load-accommodating arrangements, e.g. stowing, trimming; Vessels characterised thereby for bulk goods fluid
- B63B2025/087—Load-accommodating arrangements, e.g. stowing, trimming; Vessels characterised thereby for bulk goods fluid comprising self-contained tanks installed in the ship structure as separate units
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/30—Use of alternative fuels, e.g. biofuels
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T70/00—Maritime or waterways transport
- Y02T70/50—Measures to reduce greenhouse gas emissions related to the propulsion system
Definitions
- the invention relates to the field of ship clean energy transportation and filling equipment, in particular to an ammonia fuel transportation and filling ship.
- ammonia fuel has a low transportation cost and high safety. It is foreseeable that in the past 10 years, ammonia fuel will become more It is easy to achieve commercialization and large-scale application.
- ammonia Compared with hydrogen, ammonia has the following advantages:
- Ammonia fuel is easy to transport, and can be liquefied and stored when the transport temperature is lower than -34.5 degrees Celsius. At the same time, it can also reach a liquefied storage state under a certain pressure condition (8-10bar) in a normal temperature environment.
- Ammonia fuel has greater energy density. Based on the same ship endurance requirements, the tank capacity required for ammonia fuel is basically three-fifths of hydrogen fuel. The arrangement of the ship can thus be facilitated.
- ammonia fuel enable it to be well stored in various types of independent tanks.
- anhydrous ammonia has a very small flash point range, so it is generally considered to have a very low risk of explosion protection.
- ammonia itself is colorless, transparent, toxic and has a very active molecular structure.
- ammonia fuel if it leaks, it is not easy to find, and it is toxic and will cause irreparable losses to personnel. Therefore, the international bulk The Liquefied Gas Carrier Convention has very strict restrictions on the transportation of ammonia. It must consider minimizing the risk of personnel being poisoned by ammonia leakage. This shortcoming also makes the use of ammonia fuel not common enough.
- the receiving ships (ultra-large container ships, bulk carriers, oil tankers, etc.) are also currently facing the problem of limited resources at the target port.
- An ammonia fuel transportation and filling ship was invented to solve the problem of fast and safe transportation and filling of ammonia fuel for ships.
- the object of the present invention is to provide an ammonia fuel transportation and refueling ship, which is used to solve the problem of ammonia leakage in the prior art that is difficult to detect and cause personnel poisoning, and the safe transportation and refueling of ammonia fuel The problem.
- the present invention provides an ammonia fuel transportation and filling ship, including a hull, several independent tanks fixed on the hull, a liquid cargo manifold connected to each independent tank, and a filling tank. headers, and leakage handling devices installed next to the cargo headers and filling headers on each independent tank, said leakage handling devices including gas detection stations installed next to the cargo headers and filling headers, And a washing tower installed on the hull, the washing range of the washing tower covers the liquid cargo header and the filling header.
- the leakage treatment device further includes a receiving pan arranged under the filling header, and a neutralization tank arranged under the liquid cargo manifold and the filling header, and the neutralizing tank is installed under the receiving tray.
- the receiving plate is provided with a double-layer structure, the upper structure is a mesh stainless steel layer, the lower layer is a solid stainless steel layer, and an isolation water layer is provided between the upper and lower layers , the bottom of the receiving tray is connected with the neutralization cabin through a pipeline.
- the hull is also provided with a fuel self-supply cabin and a fuel power cabin for driving the hull.
- the fuel power cabin is provided with an ammonia fuel main engine, and the fuel passes through between the self-supply cabin and several independent cabins.
- the first gas pipeline is connected, and each first gas pipeline is equipped with a stress valve.
- the fuel supply tank is connected to any independent tank through the first liquid pipeline, and the fuel is self-supplied
- the tank is connected to the main engine of ammonia fuel through a second liquid pipeline and a second gas pipeline to form a loop connection, and emergency isolation valves are installed on the first liquid pipeline and the second liquid pipeline.
- both the second liquid pipeline and the second gas pipeline are double-walled tubes
- the double-walled tubes include an outer tube, an inner tube pierced in the outer tube, and an inner tube formed between the outer tube and the inner tube.
- the inner tube of the second liquid pipeline is used to inject liquid ammonia
- the inner tube of the second gas pipeline is used to output ammonia gas
- the tube gap of the second liquid pipeline and the first The tube gaps of the two gas-direction pipelines are used for the flow of compressed air
- the flow direction of the compressed air in the second liquid-direction pipeline is opposite to the injection direction of liquid ammonia
- the flow direction of the compressed air in the second gas-direction pipeline is the same as Ammonia output in the opposite direction.
- the fuel self-supply cabin includes an inner shell and a bottom structure installed at the bottom of the fuel self-supply cabin, and an insulating layer is laid on the outer surface of the inner shell.
- another structure of the self-fuel supply tank includes an inner shell, an outer shell wrapping the inner shell, and a bottom surface structure installed at the bottom of the self-fuel supply tank, and an insulating layer is laid on the inner surface of the outer shell.
- the bottom surface structure is a double-bottom structure, which can effectively resist the vibration generated when the ammonia fuel main engine installed in the fuel power cabin is running.
- a compressor room and a ventilation tower are also provided on the hull, the compressor room is connected to a first gas pipeline, a pressure sensing device is arranged on the first gas pipeline, and the ventilation tower The tower is connected with the independent cabin.
- a fence is fixed on the hull, and fenders are placed on the fence, and the fenders include a central floating ball, tire pads arranged on the outer wall of the central floating ball, and center pads arranged at both ends of the central floating ball.
- the lock buckle and the chain connecting the center lock buckle and the center of the tire pad; the two ends of the fender are spherical and the middle is cylindrical. A certain pressure needs to be maintained inside the center floating ball; tire pads are used to ensure proper elastic deformation.
- a mooring compartment is provided at the bow of the hull
- a battery compartment is provided at the stern of the hull
- side thrusters are installed on the side walls of the bow and stern of the hull.
- the bow of the hull is provided with a personnel living compartment
- the leakage treatment device also includes a plurality of emergency shower rooms, and the emergency shower rooms are arranged on the top of each independent cabin.
- an intermediate longitudinal bulkhead is arranged inside the independent cabin, and the intermediate longitudinal bulkhead is arranged on the centerline from the bow to the stern to separate the independent cabin.
- ammonia fuel transportation and bunkering ship of the present invention has the following beneficial effects:
- the invention is provided with a plurality of independent cabins for storing and transporting ammonia fuel, and at the same time, liquid cargo headers and filling headers arranged on the independent cabins are convenient for storage of ammonia fuel and filling of gas ships; leakage treatment is provided
- the device can quickly process the leaked ammonia fuel through the leakage treatment device after the ammonia fuel leaks, reducing the risk of personnel poisoning caused by the ammonia fuel leak.
- Fig. 1 is the independent cabin type A and type B structural representations of ammonia fuel transportation and fueling ship of the present invention
- Fig. 2 is the right side view of the independent cabin A type and B type of the ammonia fuel transportation and filling ship of the present invention
- Fig. 3 is the structure diagram of the fuel self-supply cabin A1 type and B1 type of the ammonia fuel transportation and filling ship of the present invention
- Fig. 4 is the top view of the bottom surface structure of the ammonia fuel transportation and filling ship of the present invention.
- Fig. 5 is the structural diagram of the fuel self-supply cabin C1 type of the ammonia fuel transportation and filling ship of the present invention
- Fig. 6 is the top view of the fender of the ammonia fuel transportation and bunkering ship of the present invention.
- Fig. 7 is the left side view of the fender of the ammonia fuel transportation and bunkering ship of the present invention.
- Fig. 8 is the flow chart of the fuel self-supply cabin and the ammonia fuel main engine of the ammonia fuel transportation and filling ship of the present invention
- Fig. 9 is a schematic diagram of the independent cabin C type structure of the ammonia fuel transportation and filling ship of the present invention.
- Fig. 10 is a right side view of the type C independent tank of the ammonia fuel transportation and bunkering ship of the present invention.
- the present invention provides an ammonia fuel transportation and filling ship, including a hull 1, several independent cabins fixed on the hull 1, connected to each independent cabin
- the leakage treatment device includes the liquid cargo header 2 And the gas detection station 4 next to the filling header 3, and the scrubber 5 installed on the hull 1, the washing range of the scrubber 5 covers the liquid cargo header 2 and the filling header 3.
- Each independent cabin is located on the structure of the hull 1 through a support, wherein the diamond-shaped independent cabin includes Type A and Type B, as shown in Figures 1 and 2, the design pressure of the diamond-shaped independent cabin is less than 0.7bar; the spherical column-shaped independent cabin Including Type C, as shown in Figure 9 and Figure 10, the design pressure of the ball column type independent cabin is greater than 0.7bar, which can withstand greater pressure in the cabin.
- the above-mentioned ammonia fuel transportation and filling ship has two functions of transportation and filling through the liquid cargo header 2 and the filling header 3 on each independent tank.
- the liquid cargo header 2 on the second independent tank 102 in the middle of the hull 1 is set as a VLLVVL liquid cargo header or an LVVLLV liquid cargo header, and the liquid cargo header 2 simultaneously satisfies
- the two liquid cargo filling methods of VLLV or LVVL are mainly used for the ammonia fuel filling of the ship’s hull 1 at the source of the port, and can also reversely realize ship-to-ship ammonia fuel filling.
- the filling header 3 is equipped with two liquid-phase pipes and one gas-phase pipe; wherein, L indicates the liquid-directed header, and V indicates the gas-directed header.
- the first independent cabin 101 is used for the bunkering operation when the bunkering ship and the receiving ship are berthed bow-to-bow; when the storage tank of the receiving ship is arranged in the middle When the bunkering ship and the receiving ship are berthing side by side, the second independent cabin 102 is used for filling operation; when the storage tank of the receiving ship is arranged at the stern, the first independent cabin 101 is used for the bunkering ship and the receiving ship to berth bow-to-stern Perform filling operations.
- the bunkering ship and the first bunkering ship berthed head-to-head using the first independent cabin 101 for bunkering operations, and the bunkering ship and the second bunkering ship are berthing stern-to-stern using the third independent cabin 103 carries out filling operation, can realize the simultaneous filling demand to two ships.
- the three independent compartments in the present invention are used to store and transport ammonia fuel, and the liquid cargo manifold 2 and filling manifold 3 on each independent compartment facilitate the storage of external ammonia fuel and filling to ships;
- the gas detection station provided 4 is used to detect the ammonia content in the air, and the alarm value of the ammonia content is set at the ammonia volume concentration of 20-50ppm (parts per million concentration).
- the washing tower 5 releases water for spraying, and relies on the principle that ammonia gas is easily soluble in water to reduce the air content of ammonia gas, thereby preventing personnel from inhaling ammonia gas and causing poisoning.
- the leakage treatment device also includes a receiving plate 6 arranged under the filling manifold 3, and a receiving plate 6 arranged on the liquid cargo manifold 2 and the filling manifold 3
- the neutralized cabin 7 is installed on the hull 1 below the receiving plate 6, and the neutralized cabin 7 has an opening on the side, and the ammonia in the neutralized cabin 7 can be discharged outside the side.
- the receiving plate 6 is arranged under the filling header 3, and if the liquid ammonia is transferred or leaks, it can collect and accept the leaked liquid ammonia; the receiving plate 6 is provided with a double-layer structure, the upper structure is a mesh stainless steel layer, and the lower layer It is a solid stainless steel layer, and an isolation water layer is arranged between the upper and lower layers, and the bottom of the receiving plate 6 is connected with the neutralizing cabin 7 through a pipeline.
- acidic substances are sprinkled in the neutralization cabin 7, and when the washing tower 5 releases water for spraying, the ammonia gas dissolved in water naturally overflows into the neutralization cabin 7 or the receiving plate 6 through the convex deck on the hull 1
- the collected leaked liquid ammonia flows into the neutralization cabin 7 through the piping system, and reacts with the acidic substances in the neutralization cabin 7 to form ammonium salts, so as to avoid ammonia poisoning of personnel.
- a fuel self-supply cabin 8 and a fuel power cabin 9 for driving the hull 1 are also arranged on the hull 1, and an ammonia fuel main engine is arranged in the fuel power cabin 9 10.
- the fuel self-supply cabin 8 is connected to several independent cabins through the first gas pipeline 11, and each first gas pipeline 11 is equipped with a stress valve 1101.
- the fuel self-supply cabin 8 and any The independent tanks are connected through the first liquid pipeline 12 , and the bottom of the fuel supply tank 8 is provided with a bottom structure 804 .
- the bottom structure 804 is a double-bottom structure, which can effectively resist the vibration generated when the ammonia fuel main engine 10 installed in the fuel power cabin 9 is running.
- the fuel self-supply cabin 8 is connected to the ammonia fuel main engine 10 through the second liquid pipeline 13 and the second gas pipeline 1301 to form a loop connection.
- Both the first liquid pipeline 12 and the second liquid pipeline 13 are equipped with emergency Isolation valve 1201.
- the fuel self-supply cabin 8 is arranged in the rear area of the hull 1, and is connected to the third independent cabin 103 through the first liquid direction pipeline 12, and the fuel power cabin 9 is arranged below the fuel self-supply cabin 8, and the fuel is self-supplied
- the material of cabin 8 is low-temperature steel, stainless steel, aluminum alloy, high manganese steel, etc., preferably low-temperature steel; ammonia is corrosive, and it corrodes carbon-manganese steel and nickel steel more strongly. More preferably, a small area directly below the air chamber of the third independent compartment 103 can be designated as the fuel self-supply compartment 8, and there is no need to separately arrange the fuel self-supply compartment 8, which saves costs and materials.
- the emergency isolation valve 1201 is arranged on the first liquid pipeline 12 and the second liquid pipeline 13, and when a liquid ammonia leakage accident occurs, the emergency isolation valve 1201 is automatically closed to avoid further leakage.
- both the second liquid pipeline 13 and the second gas pipeline 1301 are double-walled tubes, and the double-walled tubes include an outer tube, an inner tube pierced in the outer tube, and an inner tube formed on the outer tube. and the pipe gap between the inner pipe, the inner pipe of the second liquid to the pipeline 13 is used to inject liquid ammonia, the inner pipe of the second gas to the pipeline 1301 is used to output ammonia gas, and the compressed air pipeline 1302 injects compressed air into the first In the tube gap of the second liquid pipeline 13 and the tube gap of the second gas pipeline 1301, the flow direction of the compressed air in the second liquid pipeline 13 is opposite to the injection direction of liquid ammonia, and the second gas is compressed in the pipeline 1301 The flow direction of the air is opposite to the output direction of ammonia gas; when there is a gap in the inner pipe of the first liquid pipeline 12 and the second gas pipeline 1301, and when the ammonia fuel leaks due to rupture, the compressed air flowing in the pipe gap can dissipate the ammonia
- the fuel self-supply cabin 8 may be of type A1, type B1, or type C1.
- the C1 type fuel self-supply cabin 8 includes an inner shell 801 and a bottom surface structure 804 installed at the bottom of the fuel self-supply cabin 8 , and an insulating layer 803 is laid on the surface of the inner shell 801 .
- the capacity of the fuel self-supply cabin 8 is less than 5000 cubic meters, only the inner shell 801 can bear the pressure of liquid ammonia, and the surface of the inner shell 801 is laid with a PU insulating layer 803; A layer of thin iron sheet is attached to the outside of the layer 803, which is better for cooling liquid ammonia.
- the A1 type or B1 type fuel self-supply cabin 8 includes an inner shell 801, an outer shell 802 wrapping the inner shell 801, and a bottom surface structure 804 installed at the bottom of the fuel self-supply cabin 8, inside the outer shell 802
- An insulating layer 803 is laid on the surface.
- an outer shell 802 needs to be provided so that when the inner shell 801 fails, the outer shell 802 can rely on the outer shell 802 to carry the leaked liquid, and the inner surface of the outer shell 802 is covered with a PU insulating layer.
- the fuel self-supply cabin 8 has a capacity of 5,000 cubic meters, and can sail about 20,000 nautical miles once it is fully filled.
- the outer shell of the A1-type or B1-type fuel self-supply cabin 8 is also provided with a passage for personnel to enter, so that personnel can check the status of the inner shell 801 and find out the leakage of ammonia fuel in time.
- a compressor chamber 21 and a ventilation tower 14 are also provided on the hull 1, the compressor chamber 21 is connected with the first gas pipeline 11, and on the first gas pipeline 11 A pressure sensing device is provided, and the ventilation tower 14 is connected with the independent cabin.
- the fuel self-supply cabin 8 is connected to several independent cabins through first gas pipelines 11, and a plurality of first gas pipelines 11 share a section of pipeline, and the compressor room 21 is connected to a plurality of first gas pipelines.
- the stress valve 1101 is opened, and the ammonia gas flows into the pressure sensing device in the first gas pipeline 11, and at this time the compressed
- the compressor in the machine room 21 works and starts in the liquefaction system, thereby reducing the pressure in each independent compartment; when the compressor breaks down, that is, when the liquefaction system cannot be started, ammonia will be released from the ventilation tower 14 at this time, reducing The pressure of each independent compartment.
- the number of ventilation towers 14 is one; in other embodiments, the number of ventilation towers 14 can also correspond to the number of independent cabins, that is, each independent cabin is equipped with a ventilation tower 14 alone.
- a fence 1501 is fixed on the hull 1, and a fender 15 is placed on the fence 1501.
- the two ends of the fender 15 are spherical, and the middle is cylindrical.
- the inside of the center float 1502 needs to maintain a certain pressure; the tire pad 1503 ensures proper elastic deformation.
- the number of fenders 15 is set to four, and during normal navigation, the fenders 15 are placed on the fence 1501; when filling the ship, the fenders 15 are passed through the crane The mechanism is placed on the sea surface between the bunkering ship and the bunkering ship to slow down the collision force between the bunkering ship and the bunkering ship, and meet the safety requirements of ship-to-ship ammonia fuel filling.
- a mooring compartment 16 is provided at the bow of the hull 1
- a battery compartment 17 is provided at the stern of the hull 1
- side thrusters are installed on the side walls of the bow and stern of the hull 1. 18.
- the mooring compartment 16 is used to meet the mooring requirements of the ship; when the ship does not turn on the main engine in the port, the battery compartment 17 provides energy to maintain the power demand of the port; the side thruster compartment 18 makes the hull 1 have good maneuverability.
- the bow of the hull 1 is provided with a living quarters 19, and the leakage treatment device also includes a plurality of emergency shower rooms 20, and the emergency shower rooms 20 are arranged on the top of each independent cabin.
- the personnel living compartment 19 is located at the forefront of the ship and has the following functions: the first function is to completely separate the personnel living area and the ammonia fuel work area, which can greatly reduce the risk of ammonia poisoning; (The ship is in any operating state, and the blind area of the ship is less than 1 times the length of the ship); the third function is to make full use of the vast rear deck space. Further, the profile of the personnel living compartment 19 presents an upward angle of 45 degrees, which can reduce wind resistance.
- the emergency bathing room 20 is equipped with devices such as an eyewash pool and a portable ammonia leakage monitor, which can be automatically opened when the gas detection station 4 monitors that the ammonia volume concentration per cubic meter in the air reaches 400ppm, so that personnel can quickly clean the contaminated ammonia. gas.
- devices such as an eyewash pool and a portable ammonia leakage monitor, which can be automatically opened when the gas detection station 4 monitors that the ammonia volume concentration per cubic meter in the air reaches 400ppm, so that personnel can quickly clean the contaminated ammonia. gas.
- the hull 1 has a convex deck, which can increase the capacity of the first independent cabin 101 , the second independent cabin 102 , and the third independent cabin 103 under the condition that the main dimension frame of the hull 1 is limited.
- a convex deck By setting a convex deck at a position higher than the intermediate tank 7, when the main size of the ship is fixed, it breaks through the limitation of the capacity of the liquid tank in the existing design, effectively expands the capacity of the liquid tank, and at the same time ensures that the liquefied gas ship The center of gravity does not change much.
- the hull 1 with a convex deck, the area of the deck surface is effectively extended, and more equipment can be arranged, such as fenders 15 and the like.
- a middle longitudinal bulkhead 104 is arranged inside the independent cabin, and the middle longitudinal bulkhead 104 is arranged on the centerline from the bow to the stern to separate the independent cabin.
- the first independent compartment 101 is divided into the left compartment of the first independent compartment 101 and the right compartment of the first independent compartment 101 by the middle longitudinal bulkhead 104;
- the second independent compartment 102 is separated by the middle longitudinal bulkhead 104 .
- the third independent compartment 103 is divided into the third independent compartment 103 left compartment and the third independent compartment 103 right compartment by the middle longitudinal bulkhead 104.
- the set middle longitudinal bulkhead 104 can effectively reduce the influence of the sloshing of the independent tank on the structure of the hull 1 .
- a single cabin left cabin or right cabin
- the ammonia fuel transportation and filling ship disclosed in the present invention fills ammonia into the first independent tank 101, the second independent tank 102, the third independent tank 103, and the self-fuel supply tank 8 through the liquid cargo header 2 before sailing Fuel, the fuel is transported from the supply tank 8 to the ammonia fuel main engine 10 through the fuel supply pipeline system, the first liquid pipeline 12 and the second gas pipeline 1301, and the ammonia fuel burns to propel the hull 1 to sail.
- the fender 15 is first put on the sea surface to slow down the collision force between the ship and the ship, and then the ammonia fuel is added to the injected ship through the filling header 3 on the independent cabin.
- the gas detection station 4 monitors the ammonia concentration in the air, and when it detects that the ammonia concentration exceeds the standard, emergency treatment is carried out for the leaked ammonia gas through equipment such as the scrubber 5, the neutralization cabin 7, and the emergency shower room 20 ; When the pressure in the independent cabin was too large, equipment such as compressor room 21 and ventilation tower 14 could release the pressure urgently in the independent cabin to avoid the occurrence of accidents.
- the present invention effectively overcomes various shortcomings in the prior art and has high industrial application value.
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- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- Ocean & Marine Engineering (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
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Abstract
Description
Claims (10)
- 一种氨燃料运输与加注船,其特征在于:包括船体(1)、固定在船体(1)上的若干个独立舱、连接在每个独立舱上的液货集管(2)和加注集管(3)、以及安装在每个独立舱上的液货集管(2)和加注集管(3)旁边的泄漏处理装置,所述泄漏处理装置包括安装在液货集管(2)和加注集管(3)旁边的气体探测站(4)、以及安装在船体(1)上的洗涤塔(5),所述洗涤塔(5)的洗涤范围覆盖液货集管(2)和加注集管(3)。An ammonia fuel transportation and bunkering ship is characterized in that it includes a hull (1), several independent tanks fixed on the hull (1), a liquid cargo header (2) connected to each independent tank, and a fuel tank The injection header (3), and the leakage treatment device installed next to the liquid cargo header (2) and filling header (3) on each independent tank, the leakage treatment device includes installation on the liquid cargo header ( 2) and the gas detection station (4) next to the filling header (3), and the scrubber (5) installed on the hull (1), the washing range of the scrubber (5) covers the liquid cargo header ( 2) and fill header (3).
- 根据权利要求1所述的氨燃料运输与加注船,其特征在于:所述泄漏处理装置还包括设置在加注集管(3)下方的承接盘(6)、以及设置在液货集管(2)和加注集管(3)下方的中合舱(7),所述中合舱(7)安装在承接盘(6)下方的船体(1)上、且中合舱(7)在舷侧具有开口;所述承接盘(6)底部通过管路与中合舱(7)连接。The ammonia fuel transportation and bunkering ship according to claim 1, characterized in that: the leakage treatment device also includes a receiving plate (6) arranged under the filling header (3), and a receiving plate (6) arranged under the liquid cargo header (2) and the neutralizing cabin (7) below the filling header (3), the neutralizing cabin (7) is installed on the hull (1) below the receiving plate (6), and the neutralizing cabin (7) There is an opening on the side; the bottom of the receiving tray (6) is connected with the intermediate cabin (7) through a pipeline.
- 根据权利要求1所述的氨燃料运输与加注船,其特征在于:所述船体(1)上还设置有燃料自供应舱(8)、以及驱动船体(1)的燃料动力舱(9),所述燃料动力舱(9)内设置有氨燃料主机(10),所述燃料自供应舱(8)与若干个独立舱之间各通过第一气向管路(11)连接、且每根第一气向管路(11)上均安装有应力阀(1101),所述燃料自供应舱(8)与任一独立舱之间通过第一液向管路(12)连接,所述燃料自供应舱(8)与氨燃料主机(10)通过第二液向管路(13)和第二气向管路(1301)构成回路连接,所述第一液向管路(12)与第二液向管路(13)上均安装有应急隔离阀(1201)。The ammonia fuel transportation and filling ship according to claim 1, characterized in that: the hull (1) is also provided with a fuel self-supply cabin (8) and a fuel power cabin (9) for driving the hull (1) , the fuel power cabin (9) is provided with an ammonia fuel host (10), the fuel supply cabin (8) is connected to several independent cabins through a first gas pipeline (11), and each Stress valves (1101) are installed on each of the first gas pipelines (11), and the fuel is connected between the self-supply cabin (8) and any independent cabin through the first liquid pipeline (12). The fuel self-supply cabin (8) is connected to the ammonia fuel main engine (10) through a second liquid pipeline (13) and a second gas pipeline (1301) to form a loop connection, and the first liquid pipeline (12) and An emergency isolation valve (1201) is installed on the second liquid direction pipeline (13).
- 根据权利要求3所述的氨燃料运输与加注船,其特征在于:所述第二液向管路(13)和第二气向管路(1301)都为双壁管,所述双壁管包括外管、穿设在外管中的内管、以及形成在外管和内管之间的管间隙,所述第二液向管路(13)的内管用于注入液氨,所述第二气向管路(1301)的内管用于输出氨气,所述第二液向管路(13)的管间隙和第二气向管路(1301)的管间隙都用于压缩空气的流动,所述第二液向管路(13)中压缩空气的流向与液氨注入方向相反,所述第二气向管路(1301)中压缩空气的流向与氨气输出方向相反。The ammonia fuel transportation and filling ship according to claim 3, characterized in that: both the second liquid pipeline (13) and the second gas pipeline (1301) are double-walled pipes, and the double-walled The pipe includes an outer pipe, an inner pipe pierced in the outer pipe, and a pipe gap formed between the outer pipe and the inner pipe, the inner pipe of the second liquid to the pipeline (13) is used for injecting liquid ammonia, the second The inner pipe of the gas pipeline (1301) is used to output ammonia gas, and the tube gap of the second liquid pipeline (13) and the tube gap of the second gas pipeline (1301) are used for the flow of compressed air, The flow direction of compressed air in the second liquid direction pipeline (13) is opposite to the direction of liquid ammonia injection, and the flow direction of compressed air in the second gas direction pipeline (1301) is opposite to the direction of ammonia gas output.
- 根据权利要求3所述的氨燃料运输与加注船,其特征在于:所述燃料自供应舱(8)包括内壳(801)、以及安装在燃料自供应舱(8)底部的底面结构(804),所述内壳(801)外表面敷设有绝缘层(803)。The ammonia fuel transportation and filling ship according to claim 3, characterized in that: the fuel self-supply cabin (8) includes an inner shell (801), and a bottom surface structure ( 804), the outer surface of the inner shell (801) is coated with an insulating layer (803).
- 根据权利要求3所述的氨燃料运输与加注船,其特征在于:所述燃料自供应舱(8)包括 内壳(801)、包裹内壳(801)的外壳(802)、以及安装在燃料自供应舱(8)底部的底面结构(804),所述外壳(802)内表面敷设有绝缘层(803)。The ammonia fuel transportation and filling ship according to claim 3, characterized in that: the fuel self-supply cabin (8) comprises an inner shell (801), an outer shell (802) wrapping the inner shell (801), and a The fuel is supplied from the bottom structure (804) at the bottom of the tank (8), and an insulating layer (803) is laid on the inner surface of the casing (802).
- 根据权利要求3所述的氨燃料运输与加注船,其特征在于:所述船体(1)上还设置有压缩机室(21)、以及透气塔(14),所述压缩机室(21)与第一气向管路(11)连接,所述第一气向管路(11)上设置有压力传感装置,所述透气塔(14)与独立舱连接。Ammonia fuel transportation and filling ship according to claim 3, characterized in that: said hull (1) is also provided with a compressor room (21) and a ventilation tower (14), said compressor room (21 ) is connected with the first gas pipeline (11), the first gas pipeline (11) is provided with a pressure sensing device, and the ventilation tower (14) is connected with the independent cabin.
- 根据权利要求1所述的氨燃料运输与加注船,其特征在于:所述船体(1)上固定有围栅(1501),所述围栅(1501)上放置有碰垫(15),所述碰垫(15)包括中心浮球(1502)、设置在中心浮球(1502)外壁上的轮胎垫(1503)、设置在中心浮球(1502)两端的中心锁扣(1504)、以及连接中心锁扣(1504)与轮胎垫(1503)中心的锁链(1505);所述碰垫(15)的两端部为球形、中间为圆柱形。The ammonia fuel transportation and bunkering ship according to claim 1, characterized in that: a fence (1501) is fixed on the hull (1), and fenders (15) are placed on the fence (1501), The fender (15) includes a central floating ball (1502), a tire pad (1503) arranged on the outer wall of the central floating ball (1502), a central lock (1504) arranged at both ends of the central floating ball (1502), and The chain (1505) connecting the center lock (1504) and the center of the tire pad (1503); the two ends of the fender (15) are spherical and the middle is cylindrical.
- 根据权利要求1所述的氨燃料运输与加注船,其特征在于:所述船体(1)的船首处设置有系泊舱(16),所述船体(1)的船尾处设置有蓄电池舱(17),所述船体(1)的船首和船尾的侧壁均安装有侧推舱(18);所述船体(1)的船首设置有人员居住舱(19),所述泄漏处理装置还包括多个紧急沐浴室(20),所述紧急沐浴室(20)设置在各独立舱的顶部。The ammonia fuel transportation and filling ship according to claim 1, characterized in that: a mooring compartment (16) is provided at the bow of the hull (1), and a battery compartment is provided at the stern of the hull (1) (17), the side walls of the bow and stern of the hull (1) are equipped with side thrusters (18); the bow of the hull (1) is provided with a personnel cabin (19), and the leakage treatment device is also provided with It includes a plurality of emergency shower rooms (20), and the emergency shower rooms (20) are arranged on the top of each independent cabin.
- 根据权利要求1所述的氨燃料运输与加注船,其特征在于:所述独立舱内部设置有中纵舱壁(104),所述中纵舱壁(104)设置在船头至船尾的中线上将独立舱隔开。The ammonia fuel transportation and bunkering ship according to claim 1, characterized in that: an intermediate longitudinal bulkhead (104) is arranged inside the independent compartment, and the intermediate longitudinal bulkhead (104) is arranged at the bow to the stern. Separate compartments are separated on the center line.
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JP2024506279A JP2024528952A (en) | 2021-08-02 | 2022-04-12 | Ammonia fuel transport and supply ship |
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CN113619734B (en) * | 2021-08-02 | 2022-07-05 | 江南造船(集团)有限责任公司 | Ammonia fuel transportation and filling ship |
CN114348171A (en) * | 2022-01-11 | 2022-04-15 | 上海外高桥造船有限公司 | Ammonia fuel powered bulk cargo ship |
CN114368449A (en) * | 2022-02-28 | 2022-04-19 | 广船国际有限公司 | Chemical ship with ammonia fuel tank |
CN114715330B (en) * | 2022-04-25 | 2023-05-05 | 广船国际有限公司 | Dual-fuel oil ship |
CN115384746A (en) * | 2022-09-13 | 2022-11-25 | 中国船舶集团有限公司第七○八研究所 | Near-zero emission logistics system of large container ship |
CN115571317A (en) * | 2022-10-19 | 2023-01-06 | 中国船舶集团有限公司第七○八研究所 | Mechanical ventilation system for fuel place of ammonia fuel ship |
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2021
- 2021-08-02 CN CN202110879180.5A patent/CN113619734B/en active Active
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2022
- 2022-04-12 KR KR1020247004508A patent/KR20240032109A/en active Search and Examination
- 2022-04-12 JP JP2024506279A patent/JP2024528952A/en active Pending
- 2022-04-12 WO PCT/CN2022/086414 patent/WO2023010884A1/en active Application Filing
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CN113619734A (en) | 2021-11-09 |
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