WO2023087884A1 - Magnetic sensor and manufacturing method therefor - Google Patents
Magnetic sensor and manufacturing method therefor Download PDFInfo
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- WO2023087884A1 WO2023087884A1 PCT/CN2022/119594 CN2022119594W WO2023087884A1 WO 2023087884 A1 WO2023087884 A1 WO 2023087884A1 CN 2022119594 W CN2022119594 W CN 2022119594W WO 2023087884 A1 WO2023087884 A1 WO 2023087884A1
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- tunnel junction
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 15
- 238000000034 method Methods 0.000 claims abstract description 28
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
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- 229910052715 tantalum Inorganic materials 0.000 description 5
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 5
- 229910000521 B alloy Inorganic materials 0.000 description 4
- ZDZZPLGHBXACDA-UHFFFAOYSA-N [B].[Fe].[Co] Chemical compound [B].[Fe].[Co] ZDZZPLGHBXACDA-UHFFFAOYSA-N 0.000 description 4
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- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 4
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- 229910052707 ruthenium Inorganic materials 0.000 description 4
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 description 3
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N50/00—Galvanomagnetic devices
- H10N50/01—Manufacture or treatment
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N50/00—Galvanomagnetic devices
- H10N50/10—Magnetoresistive devices
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N59/00—Integrated devices, or assemblies of multiple devices, comprising at least one galvanomagnetic or Hall-effect element covered by groups H10N50/00 - H10N52/00
Definitions
- the present application relates to the technical field of magnetic sensors, in particular to a magnetic sensor and a manufacturing method thereof.
- the magnetic sensor is basically prepared by using the Tunneling Magnetoresistance (TMR) effect of the Magnetic Tunneling Junction (MTJ), and it is set in the form of a Wheatstone bridge (full bridge or half bridge). To improve the sensitivity of the induced magnetic field.
- TMR Tunneling Magnetoresistance
- MTJ Magnetic Tunneling Junction
- MTJ devices with a specific resistance-magnetic field change mode need to be prepared first, and then multiple identical MTJ devices are connected in series to form a single arm of a Wheatstone bridge. Because the working principle of the Wheatstone bridge requires that the output signals of devices with different bridge arms change in opposite directions with the external magnetic field. In order to realize the form of a full bridge or a half bridge, it is necessary to simultaneously obtain MTJ devices with opposite resistance-magnetic field change modes and integrate them together to form different single arms of the Wheatstone bridge.
- one process can only produce MTJ devices with the same output signal change trend.
- MTJ devices to obtain MTJ devices with opposite characteristics, the area of the magnetic sensor is larger, and the process steps are more and more complicated; the other is to use only one MTJ growth process to grow the same MTJ device, and the MTJ devices in different regions of the chip are Magnetization or annealing in a magnetic field in the opposite direction to obtain an MTJ device with opposite characteristics results in a larger area of the magnetic sensor and it is difficult to precisely control the range of the magnetic field.
- the purpose of this application is to provide a magnetic sensor and its manufacturing method, so as to reduce the area of the magnetic sensor and simplify the process flow.
- the application provides a magnetic sensor, including a chip provided with a bottom electrode, and a device group disposed on the chip, the device group comprising:
- a first magnetic tunnel junction device electrically connected to the bottom electrode
- the second magnetic tunnel junction device and the second mask layer are arranged on the upper surface of the wire layer and stacked in sequence, and the magnetic moment direction of the reference layer in the first magnetic tunnel junction device and the second magnetic tunnel junction device is parallel and the opposite;
- a top electrode disposed on the upper surface of the second mask layer
- a signal lead-out part connected to the wire layer.
- the long axis directions of the first magnetic tunnel junction device and the second magnetic tunnel junction device are the same.
- the shapes of the first magnetic tunnel junction device and the second magnetic tunnel junction device are elliptical cylinders.
- a first insulating layer disposed around the first magnetic tunnel junction device and flush with the first mask layer.
- a plurality of the device groups form a Wheatstone half bridge, and a first preset number of the first magnetic tunnel junction devices in the Wheatstone half bridge are connected in series A second preset number of the second magnetic tunnel junction devices is connected in series, and the first preset number and the second preset number are both smaller than the number of the device groups.
- a plurality of the device groups form a Wheatstone full bridge
- the Wheatstone full bridge includes a parallel first half bridge and a second half bridge, and the first A third preset number of the first magnetic tunnel junction devices in the half bridge and the second half bridge are connected in series, and a fourth preset number of the second magnetic tunnel junction devices are connected in series.
- the present application also provides a method for manufacturing a magnetic sensor, including:
- the first magnetic tunnel junction device or the second magnetic tunnel junction device is magnetized by using a second magnetic field that is opposite to the first magnetic field and has different magnitudes, so that the device magnetized by the second magnetic field
- the magnetic moment direction of the reference layer is parallel and opposite to that of the reference layer of the device not magnetized by the second magnetic field, resulting in a magnetic sensor.
- preparing a first magnetic tunnel junction device electrically connected to the bottom electrode on the upper surface of the bottom electrode includes:
- the first magnetic tunnel junction device to be processed is etched to form the first magnetic tunnel junction device.
- the etching stops to the upper surface of the wire layer to be processed.
- a magnetic sensor provided by the present application includes a chip provided with a bottom electrode, and a device group provided on the chip, the device group including: a first magnetic tunnel junction device electrically connected to the bottom electrode; The wire layer arranged above the first magnetic tunnel junction device; the second magnetic tunnel junction device and the second mask layer arranged on the upper surface of the wire layer and stacked in sequence, the first magnetic tunnel junction device and the The direction of the magnetic moment of the reference layer in the second magnetic tunnel junction device is parallel and opposite; the top electrode arranged on the upper surface of the second mask layer; the signal lead-out part connected with the wire layer.
- the device group in the magnetic sensor of the present application is directly arranged on the chip, and the first magnetic tunnel junction device and the second magnetic tunnel junction device in the device group are distributed in the vertical direction, which can reduce the area of the magnetic sensor;
- the magnetic moment directions of the reference layer in the tunnel junction device and the second magnetic tunnel junction device are parallel and opposite, so that the resistance of the first magnetic tunnel junction device and the second magnetic tunnel junction device change oppositely under the action of the same magnetic field, that is By forming the first magnetic tunnel junction device and the second magnetic tunnel junction device on the same chip, the Wheatstone half bridge can be formed without special equipment or process, and is very simple.
- the present application also provides a method for manufacturing a magnetic sensor with the above-mentioned advantages.
- FIG. 1 is a schematic structural diagram of a magnetic sensor provided in an embodiment of the present application.
- Fig. 2 is a schematic diagram of the relationship between the chip and the z-axis in the embodiment of the present application;
- FIG. 3 is a schematic diagram of resistance changes of the first magnetic tunnel junction device and the second magnetic tunnel junction device under the action of a magnetic field in the embodiment of the present application;
- FIG. 4 is a schematic diagram of resistance changes of the first magnetic tunnel junction device and the second magnetic tunnel junction device under another magnetic field in the embodiment of the present application;
- FIG. 5 is a schematic structural diagram of a Wheatstone half-bridge in a magnetic sensor provided by an embodiment of the present application.
- FIG. 6 is a flow chart of a method for manufacturing a magnetic sensor provided in an embodiment of the present application.
- FIG. 7 to 21 are flow charts of a manufacturing process of a magnetic sensor provided in the embodiment of the present application.
- FIG. 22 is a schematic diagram of two Wheatstone half bridges connected in parallel to form a Wheatstone full bridge.
- two MTJ devices with different resistance characteristics are prepared on two chips respectively, and the two chips are Packaging results in a larger area of the magnetic sensor; when preparing MTJ devices with different resistance characteristics on the same chip, it is necessary to design two MTJ growth processes to obtain MTJ devices with opposite characteristics, and the process steps are more and more complicated, or, Using an MTJ growth process to grow the same MTJ device in different regions of the chip, and then form MTJ devices with opposite characteristics through processing, resulting in a large area of the magnetic sensor and it is difficult to precisely control the magnetic field range.
- the present application provides a magnetic sensor, please refer to FIG. 1 , including a chip provided with a bottom electrode 1, and a device group disposed on the chip, the device group comprising:
- a first magnetic tunnel junction device 2 electrically connected to the bottom electrode 1;
- the directions of the magnetic moments are parallel and opposite;
- top electrode 9 disposed on the upper surface of the second mask layer 7;
- the magnetic sensor also includes:
- a first mask layer 3 disposed on the upper surface of the first magnetic tunnel junction device 2;
- the wiring layer 5 is located on the upper surfaces of the first mask layer 3 and the first insulating layer 4 .
- the first insulating layer 4 includes:
- the second insulating unit layer 42 is disposed on the outer surface of the first insulating unit layer.
- the material of the first insulating unit layer may be silicon nitride, and the second insulating unit layer may be an oxide insulating layer such as silicon dioxide or silicon oxynitride.
- the second insulating layer 8 includes:
- a third insulating unit layer 81 disposed around the second magnetic tunnel junction device 6;
- the fourth insulating unit layer 82 is disposed on the outer surface of the third insulating unit layer.
- the material of the third insulating unit layer may be silicon nitride, and the fourth insulating unit layer may be an oxide insulating layer such as silicon dioxide or silicon oxynitride.
- the conductive film layer of the first mask layer 3 and the second mask layer 7 may be any one of tantalum, tantalum nitride, and titanium nitride.
- the first magnetic tunnel junction device 2 includes a seed layer 21, a first pinning layer 22, a first coupling layer 23, a first reference layer 24, a first barrier layer 25, a first free layer 26, and a layer stacked from bottom to top.
- the first cladding layer 27, the second magnetic tunnel junction device 6 includes a second free layer 61, a second barrier layer 62, a second reference layer 63, a second coupling layer 64, and a second pinning layer 65 stacked from bottom to top and a second cover layer 66 .
- the material of the seed layer 21 includes but not limited to ruthenium, platinum, and nickel-chromium alloy; the first pinning layer 22 and the second pinning layer 65 can be cobalt-iron-boron alloys, cobalt, and cobalt/platinum multilayer films of different compositions.
- the material of 64 includes but not limited to ruthenium, iridium, rhodium; the material of the first barrier layer 25 and the second barrier layer 62 can be magnesium oxide, aluminum oxide, gallium magnesium oxide, etc.; the first reference layer 24 and the second reference layer The material of layer 63 can be the cobalt-iron-boron alloy of different composition; The first free layer 26 and the first free layer 26 materials can be the cobalt-iron-boron alloy of different composition and relevant material, the first free layer 26 and the second free layer The thickness of 61 is between 1.5 nanometers and 3 nanometers; the materials of the first covering layer 27 and the second covering layer 66 can be magnesium oxide, tantalum, tungsten, molybdenum, cobalt-iron-boro
- the thickness of the first barrier layer 25 and the second barrier layer 62 is determined by the width of the first magnetic tunnel junction device 2 and the second magnetic tunnel junction device 6 and the required resistance of the single arm of the Wheatstone bridge. Generally, the first The thickness of the barrier layer 25 and the second barrier layer 62 is between 1 nanometer and 3 nanometers.
- the first free layer 26 and the second free layer 61 have in-plane magnetic anisotropy
- the first coupling layer 23, the second coupling layer 64, the first barrier layer 25, the second barrier layer 62, the seed layer 21 , the first cladding layer 27 and the second cladding layer 66 have no magnetism
- the first pinning layer 22 , the second pinning layer 65 , the first reference layer 24 and the second reference layer 63 have out-of-plane magnetic anisotropy.
- the magnetic moment directions of the reference layers in the first magnetic tunnel junction device 2 and the second magnetic tunnel junction device 6 are parallel and opposite, that is, the magnetic moment directions of the first reference layer 24 and the second reference layer 63 are parallel and opposite, so that the first The magnetic tunnel junction device 2 and the second magnetic tunnel junction device 6 have opposite resistance changes under the same magnetic field.
- the directions of the magnetic moments of the first pinned layer 22 and the second pinned layer 65 are opposite, which can be realized by applying magnetic fields of different magnitudes and opposite directions but perpendicular to the plane of the chip for magnetization.
- the first reference layer 24 Due to interlayer coupling, the first reference layer 24
- the directions of the magnetic moments of the second reference layer 63 and the first pinned layer 22 and the second pinned layer 65 are respectively opposite, so the directions of the magnetic moments of the first reference layer 24 and the second reference layer 63 are also opposite.
- the resistance of the first magnetic tunnel junction device 2 and the second magnetic tunnel junction device 6 is opposite to the change mode of the magnetic field, thereby realizing the benefit Stone half bridge.
- the z axis is perpendicular to the chip surface, when the magnetic field direction is -z, the magnetic moment direction of each layer with magnetism in the first magnetic tunnel junction device 2 and the second magnetic tunnel junction device 6 is shown in the figure 3, at this time, the free layer magnetic moment of the first magnetic tunnel junction is parallel to the magnetic moment of the first reference layer 24, showing a low resistance value, and the free layer magnetic moment of the second magnetic tunnel junction is parallel to the second reference layer 24 magnetic moment.
- the magnetic moment of layer 63 is in an antiparallel state, showing high and low resistance values; when the magnetic field direction turns to +z, the magnetic moment of the free layer of the first magnetic tunnel junction and the magnetic moment of the first reference layer 24 are in an antiparallel state, showing high resistance value, the magnetic moment of the free layer of the second magnetic tunnel junction is parallel to the magnetic moment of the second reference layer 63, showing a low resistance value; thereby realizing two opposite resistance-magnetic field response modes in the same structure, that is, in situ A half-bridge structure of a Wheatstone bridge is realized. At this time, the magnetic sensor can sense the magnetic field in the z direction, that is, the direction perpendicular to the upper surface of the chip.
- FIG. 4 when the magnetic field direction is perpendicular to the z-axis, for example, parallel to the x-axis or y-axis, the magnetic moment direction of each magnetic layer in the first magnetic tunnel junction device 2 and the second magnetic tunnel junction device 6 is shown in FIG.
- the magnetic sensor can sense the magnetic fields in the x and y directions, that is, the directions parallel to the upper surface of the chip.
- the second magnetic tunnel junction device 6 may or may not overlap with the first magnetic tunnel junction device 2 in a direction perpendicular to the chip, which is not limited in this application. When overlapping, it will not affect the signal extraction.
- the shapes of the first magnetic tunnel junction device 2 and the second magnetic tunnel junction device 6 are not limited, and can be set by themselves.
- the long axis directions of the first magnetic tunnel junction device 2 and the second magnetic tunnel junction device 6 are the same.
- the shapes of the first magnetic tunnel junction device 2 and the second magnetic tunnel junction device 6 may be cylindrical or elliptical. When it is cylindrical, the width of the first magnetic tunnel junction device 2 and the second magnetic tunnel junction device 6 is the diameter, and when it is an elliptical cylinder, the width of the first magnetic tunnel junction device 2 and the second magnetic tunnel junction device 6 long or short diameter.
- the major axis width of the elliptical cylinder is generally between 1 micron and 20 microns, and the minor axis width is generally 0.1 micron to 10 microns; the diameter of the cylindrical device is generally 0.1 micron to 10 microns.
- the shape of the first magnetic tunnel junction device 2 and the second magnetic tunnel junction device 6 is an elliptical cylinder, and the long axis direction of the first magnetic tunnel junction device 2 and the second magnetic tunnel junction device 6 same.
- the long axis directions of the first magnetic tunnel junction device 2 and the second magnetic tunnel junction device 6 are both parallel to the z-axis, or both are parallel to the x-axis.
- the absolute value of the width of the first magnetic tunnel junction device 2 and the second magnetic tunnel junction device 6 is determined by the resistance value required by the Wheatstone bridge, and the width difference is determined by the width (diameter) of the signal lead-out part 10 .
- the wire layer 5 is a metal wire layer, and the thickness of the wire layer 5 can be between 1 nanometer and 100 nanometers.
- the material of the metal wire layer is any one or any combination of cobalt, tungsten, ruthenium, molybdenum, and tantalum.
- the material of the bottom electrode 1 can be tantalum nitride or titanium nitride, etc.
- the material of the top electrode 9 can also be tantalum nitride, titanium nitride, etc.
- the device group in the magnetic sensor of the present application is directly arranged on the chip, and the first magnetic tunnel junction device 2 and the second magnetic tunnel junction device 6 in the device group are distributed in the vertical direction, which can reduce the area of the magnetic sensor;
- a wire layer 5 is arranged between the tunnel junction device 2 and the second magnetic tunnel junction device 6, the signal lead-out part 10 is connected to the wire layer 5, and the magnetic field of the reference layer in the first magnetic tunnel junction device 2 and the second magnetic tunnel junction device 6
- the moment directions are parallel and opposite, so that the resistance of the first magnetic tunnel junction device 2 and the second magnetic tunnel junction device 6 change oppositely under the action of the same magnetic field, that is, by forming the first magnetic tunnel junction device 2 on the same chip and the second magnetic tunnel junction device 6, and the first mask layer 3, the first insulating layer 4, the second mask layer 7 and the second insulating layer 8 can be formed to form a Wheatstone half bridge without special equipment Or Craft, very simple.
- the multiple device groups form a Wheatstone half bridge, and the first Wheatstone half bridge in the Wheatstone half bridge A preset number of the first magnetic tunnel junction devices 2 are connected in series, a second preset number of the second magnetic tunnel junction devices 6 are connected in series, the first preset number and the second preset number are less than the set The number of device groups described above.
- a plurality of first magnetic tunnel junction devices 2 can be connected in series through preset metal wiring, and a plurality of second magnetic tunnel junction devices 6 can be connected in series.
- the formed Wheatstone half bridge is shown in the figure As shown in 5, from the left, the first magnetic tunnel junction device 2 in the three device groups on the left is connected in series, and from the right, the second magnetic tunnel junction device 6 in the three device groups on the right is connected in series, and the signal is transmitted from the device group in the middle The signal lead-out part 10 in the output.
- the multiple device groups form a Wheatstone full bridge
- the Wheatstone full bridge includes a parallel connection of the first The half bridge and the second half bridge
- the third preset number of the first magnetic tunnel junction devices 2 in the first half bridge and the second half bridge are connected in series
- the fourth preset number of the second The magnetic tunnel junction devices 6 are connected in series.
- first half bridge and the second half bridge can refer to Figure 4. It should be noted that when the first half bridge and the second half bridge are connected in parallel, the first half bridge and the second half bridge are generally connected head to tail in parallel, as shown in Figure 22.
- the present application also provides a manufacturing method of a magnetic sensor, please refer to FIG. 6, the method includes:
- Step S101 forming a bottom electrode on the chip.
- Step S102 preparing a first magnetic tunnel junction device electrically connected to the bottom electrode on the upper surface of the bottom electrode.
- this step includes:
- Step S1021 preparing a first magnetic tunnel junction device to be processed on the upper surface of the bottom electrode, and forming a first mask layer on the upper surface of the first magnetic tunnel junction device to be processed;
- the first magnetic tunnel junction device 2' to be processed includes a seed layer, a first pinning layer, a first coupling layer, a first reference layer, a first barrier layer, a first free layer, a first overlay.
- Step S1022 using the first mask layer as a mask, etching the first magnetic tunnel junction device to be processed to form the first magnetic tunnel junction device.
- etching the first magnetic tunnel junction device to be processed to form the first magnetic tunnel junction device includes:
- Dry etching is used to etch the first magnetic tunnel junction device to be processed to form the first magnetic tunnel junction device.
- the dry etching can be ion beam etching or reactive ion etching.
- the etching method of the first magnetic tunnel junction device to be processed may also be wet etching, which is not specifically limited in this application. During etching in this step, the etching stops at the interface where the bottom electrode is located, or exceeds the interface by 1 nanometer to 10 nanometers.
- FIG. 8 Please refer to FIG. 8 for a schematic diagram after forming the first magnetic tunnel junction device 2 .
- the first magnetic tunnel junction device after the first magnetic tunnel junction device, it also includes: forming a first insulating layer around the first magnetic tunnel junction device, and the first insulating layer is flush with the upper surface of the first mask layer, specifically including:
- Step S201 forming a first insulating unit layer 41 around the first magnetic tunnel junction device, as shown in FIG. 9 ;
- Step S202 forming a second insulating unit layer 42 on the outer surface of the first insulating unit layer 41, as shown in FIG. 10 ;
- Step S203 use chemical mechanical planarization method to smooth the top surfaces of the first insulating unit layer and the second insulating unit layer until the first mask layer is exposed, as shown in FIG. 11 .
- Step S103 forming a wire layer above the first magnetic tunnel junction device.
- Step S104 preparing sequentially stacked second magnetic tunnel junction devices and a second mask layer on the upper surface of the wire layer.
- Fig. 12 to Fig. 14 form the wire layer 5' to be processed on the upper surface of the first mask layer and the first insulating layer, and prepare the second magnetic tunnel junction device to be processed on the upper surface of the wire layer 5' to be processed , optionally, prepare the second mask layer to be processed on the upper surface of the second magnetic tunnel junction device to be processed, and perform photolithography and etching on the second mask layer to be processed to obtain the second mask layer 7, with the second The mask layer 7 is used as a mask to etch the second magnetic tunnel junction device to be processed to form the second magnetic tunnel junction device.
- the second magnetic tunnel junction device to be processed includes a second free layer, a second potential barrier layer, a second reference layer, a second coupling layer, a second pinning layer and a second covering layer stacked from bottom to top.
- the manner of etching the second magnetic tunnel junction device to be processed may be ion beam etching or reactive ion etching.
- the second magnetic tunnel junction device after forming the second magnetic tunnel junction device, it also includes:
- this application does not specifically limit this.
- the etching exceeds the interface between the wire layer to be processed and the second insulating layer, and the wire layer to be processed is etched.
- the etching depth of the wire layer is between 1 nanometer and 30 nanometers.
- Step S105 forming a top electrode on the upper surface of the second mask layer.
- an interlayer oxide insulating layer 12 is first formed on the third mask layer, and then the chemical mechanical planarization method is used to polish the second mask layer 7 to expose, and the second mask layer 7 form the top electrode.
- Step S106 preparing a signal lead-out portion connected to the wire layer.
- the through hole can be made by Damascene method, and then metal is deposited in the through hole to form the signal lead-out part, and the structural diagram shown in Figure 1 is obtained, and the signal lead-out part is electrically connected with the wire layer.
- Step S107 Using a first magnetic field to magnetize the first magnetic tunnel junction device and the second magnetic tunnel junction device, so that the reference layer in the first magnetic tunnel junction device and the second magnetic tunnel junction device The directions of the magnetic moments are parallel and identical.
- Step S108 Magnetize the first magnetic tunnel junction device or the second magnetic tunnel junction device by using a second magnetic field opposite in direction to the first magnetic field and different in size, so that the magnetic tunnel junction device magnetized by the second magnetic field
- the magnetic moment direction of the reference layer of the device is parallel to and opposite to that of the reference layer of the device not magnetized by the second magnetic field, thereby obtaining a magnetic sensor.
- the MTJ devices in different regions of the chip are magnetized or annealed in the magnetic field in the opposite direction to obtain MTJ devices with opposite characteristics, and the range of the magnetic field is difficult to accurately control.
- two magnetic fields with opposite directions and different sizes are used. All devices on the chip are magnetized twice to obtain the first magnetic tunnel junction device and the second magnetic tunnel junction device with opposite characteristics, which is very simple and convenient, and can also reduce the area of the magnetic sensor.
- one device group is taken as an example for illustration.
- multiple device groups can be formed into Wheatstone half-bridge and full-bridge forms by setting wiring.
- each embodiment in this specification is described in a progressive manner, each embodiment focuses on the difference from other embodiments, and the same or similar parts of each embodiment can be referred to each other.
- the description is relatively simple, and for the related part, please refer to the description of the method part.
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Abstract
A magnetic sensor and a manufacturing method therefor. The magnetic sensor comprises: a chip provided with a bottom electrode and a device group disposed on the chip, the device group comprising a first magnetic tunnel junction device electrically connected to the bottom electrode; a wiring layer disposed above the first magnetic tunnel junction device; a second magnetic tunnel junction device and a second mask layer disposed at the upper surface of the wiring layer and stacked in sequence, magnetic moment directions of reference layers in the first magnetic tunnel junction device and the second magnetic tunnel junction device being parallel and opposite; a top electrode disposed at the upper surface of the second mask layer; and a signal leading-out part connected to the wiring layer. The first magnetic tunnel junction device and the second magnetic tunnel junction device are distributed in a vertical direction, which can reduce the area of a magnetic sensor, and the magnetic moment directions of the reference layers in the two magnetic tunnel junction devices are parallel and opposite, so that the resistances of the two devices vary inversely in the same magnetic field; that is, the first magnetic tunnel junction device and the second magnetic tunnel junction device are formed on the same chip, so that a Wheatstone half-bridge can be formed without requiring a special process is not needed, and the method is very simple.
Description
本申请要求于2021年11月22日提交中国专利局、申请号为202111386714.7、发明名称为“一种磁传感器及其制作方法”的中国专利申请的优先权,其全部内容通过引用结合在本申请中。This application claims the priority of the Chinese patent application with the application number 202111386714.7 and the title of the invention "a magnetic sensor and its manufacturing method" submitted to the China Patent Office on November 22, 2021, the entire contents of which are incorporated by reference in this application middle.
本申请涉及磁传感器技术领域,特别是涉及一种磁传感器及其制作方法。The present application relates to the technical field of magnetic sensors, in particular to a magnetic sensor and a manufacturing method thereof.
目前,磁传感器基本上利用磁隧道结(Magnetic Tunneling Junction,MTJ)的隧穿磁阻效应(Tunneling Magnetoresistance,TMR)制备,并将其设置成惠斯通电桥(全桥或者半桥)的形式,以提高感应磁场的灵敏度。At present, the magnetic sensor is basically prepared by using the Tunneling Magnetoresistance (TMR) effect of the Magnetic Tunneling Junction (MTJ), and it is set in the form of a Wheatstone bridge (full bridge or half bridge). To improve the sensitivity of the induced magnetic field.
现有的磁传感器在制备时需要先制备具有特定的电阻-磁场变化模式的MTJ器件,然后通过串联多个相同的MTJ器件以形成惠斯通电桥的单臂。由于惠斯通电桥的工作原理要求不同桥臂的器件输出信号随着外磁场变化趋势要相反。为了实现全桥或者半桥的形式,需要同时得到具有相反的电阻-磁场变化模式的MTJ器件并集成到一起,以形成惠斯通电桥的不同单臂。In the preparation of existing magnetic sensors, MTJ devices with a specific resistance-magnetic field change mode need to be prepared first, and then multiple identical MTJ devices are connected in series to form a single arm of a Wheatstone bridge. Because the working principle of the Wheatstone bridge requires that the output signals of devices with different bridge arms change in opposite directions with the external magnetic field. In order to realize the form of a full bridge or a half bridge, it is necessary to simultaneously obtain MTJ devices with opposite resistance-magnetic field change modes and integrate them together to form different single arms of the Wheatstone bridge.
目前一次工艺流程只能制备输出信号变化趋势相同的MTJ器件,要得到具有相反电阻-磁场变化模式的MTJ器件可以有两种方式,一种是设计两道MTJ生长工艺,在芯片的不同位置沉积MTJ器件,得到相反特性的MTJ器件,磁传感器的面积较大,工艺步骤较多、比较复杂;另一种是仅用一道MTJ生长工艺,生长相同的MTJ器件,针对芯片不同区域的MTJ器件在相反方向的磁场中磁化或者退火以得到相反特性的MTJ器件,导致磁传感器的面积较大,且难以精确控制磁场范围。At present, one process can only produce MTJ devices with the same output signal change trend. There are two ways to obtain MTJ devices with opposite resistance-magnetic field change modes. One is to design two MTJ growth processes and deposit them at different positions on the chip. MTJ devices, to obtain MTJ devices with opposite characteristics, the area of the magnetic sensor is larger, and the process steps are more and more complicated; the other is to use only one MTJ growth process to grow the same MTJ device, and the MTJ devices in different regions of the chip are Magnetization or annealing in a magnetic field in the opposite direction to obtain an MTJ device with opposite characteristics results in a larger area of the magnetic sensor and it is difficult to precisely control the range of the magnetic field.
因此,如何解决上述技术问题应是本领域技术人员重点关注的。Therefore, how to solve the above technical problems should be the focus of those skilled in the art.
发明内容Contents of the invention
本申请的目的是提供一种磁传感器及其制作方法,以减小磁传感器的面积,简化工艺流程。The purpose of this application is to provide a magnetic sensor and its manufacturing method, so as to reduce the area of the magnetic sensor and simplify the process flow.
为解决上述技术问题,本申请提供磁传感器,包括设有底电极的芯片,和设于所述芯片上的器件组,所述器件组包括:In order to solve the above technical problems, the application provides a magnetic sensor, including a chip provided with a bottom electrode, and a device group disposed on the chip, the device group comprising:
与所述底电极电连接的第一磁隧道结器件;a first magnetic tunnel junction device electrically connected to the bottom electrode;
设于所述第一磁隧道结器件上方的导线层;a wire layer disposed above the first magnetic tunnel junction device;
设于所述导线层上表面、依次层叠的第二磁隧道结器件和第二掩膜层,所述第一磁隧道结器件和所述第二磁隧道结器件中参考层的磁矩方向平行且相反;The second magnetic tunnel junction device and the second mask layer are arranged on the upper surface of the wire layer and stacked in sequence, and the magnetic moment direction of the reference layer in the first magnetic tunnel junction device and the second magnetic tunnel junction device is parallel and the opposite;
设于所述第二掩膜层上表面的顶电极;a top electrode disposed on the upper surface of the second mask layer;
与所述导线层连接的信号引出部。A signal lead-out part connected to the wire layer.
可选的,所述第一磁隧道结器件和所述第二磁隧道结器件的长轴方向相同。Optionally, the long axis directions of the first magnetic tunnel junction device and the second magnetic tunnel junction device are the same.
可选的,所述第一磁隧道结器件和所述第二磁隧道结器件的形状为椭圆柱。Optionally, the shapes of the first magnetic tunnel junction device and the second magnetic tunnel junction device are elliptical cylinders.
可选的,还包括:Optionally, also include:
设于所述第一磁隧道结器件上表面的第一掩膜层;a first mask layer disposed on the upper surface of the first magnetic tunnel junction device;
设于所述第一磁隧道结器件周围且与所述第一掩膜层齐平的第一绝缘层。A first insulating layer disposed around the first magnetic tunnel junction device and flush with the first mask layer.
可选的,还包括:Optionally, also include:
设于所述第二磁隧道结器件周围且与所述第二掩膜层齐平的第二绝缘层;所述信号引出部贯穿所述第二绝缘层。A second insulating layer disposed around the second magnetic tunnel junction device and flush with the second mask layer; the signal lead-out part penetrates through the second insulating layer.
可选的,当所述器件组的数量为多个时,多个所述器件组形成惠斯通半桥,惠斯通半桥中第一预设数量个所述第一磁隧道结器件串联,第二预设数量个所述第二磁隧道结器件串联,所述第一预设数量和所述第二预设数量均小于所述器件组的数量。Optionally, when the number of the device groups is multiple, a plurality of the device groups form a Wheatstone half bridge, and a first preset number of the first magnetic tunnel junction devices in the Wheatstone half bridge are connected in series A second preset number of the second magnetic tunnel junction devices is connected in series, and the first preset number and the second preset number are both smaller than the number of the device groups.
可选的,所述器件组的数量为多个时,多个所述器件组形成惠斯通全桥,惠斯通全桥包括并联的第一半桥和第二半桥,所述第一半桥和所述第 二半桥中第三预设数量个所述第一磁隧道结器件串联,第四预设数量个所述第二磁隧道结器件串联。Optionally, when the number of the device groups is multiple, a plurality of the device groups form a Wheatstone full bridge, and the Wheatstone full bridge includes a parallel first half bridge and a second half bridge, and the first A third preset number of the first magnetic tunnel junction devices in the half bridge and the second half bridge are connected in series, and a fourth preset number of the second magnetic tunnel junction devices are connected in series.
本申请还提供一种磁传感器制作方法,包括:The present application also provides a method for manufacturing a magnetic sensor, including:
在芯片上形成底电极;forming a bottom electrode on the chip;
在所述底电极上表面制备与所述底电极电连接的第一磁隧道结器件;preparing a first magnetic tunnel junction device electrically connected to the bottom electrode on the upper surface of the bottom electrode;
在所述第一磁隧道结器件上方形成导线层;forming a wire layer over the first magnetic tunnel junction device;
在所述导线层上表面制备依次层叠的第二磁隧道结器件和第二掩膜层;preparing sequentially stacked second magnetic tunnel junction devices and a second mask layer on the upper surface of the wire layer;
在所述第二掩膜层上表面形成顶电极;forming a top electrode on the upper surface of the second mask layer;
制备与所述导线层连接的信号引出部;preparing a signal lead-out part connected to the wire layer;
使用第一磁场对所述第一磁隧道结器件和所述第二磁隧道结器件进行磁化处理,使所述第一磁隧道结器件和所述第二磁隧道结器件中参考层的磁矩方向平行且相同;Use the first magnetic field to magnetize the first magnetic tunnel junction device and the second magnetic tunnel junction device, so that the magnetic moment of the reference layer in the first magnetic tunnel junction device and the second magnetic tunnel junction device parallel and identical in direction;
使用与所述第一磁场方向相反、大小不等的第二磁场对所述第一磁隧道结器件或所述第二磁隧道结器件进行磁化处理,使被所述第二磁场磁化的器件的参考层的磁矩方向与未被所述第二磁场磁化的器件的参考层的磁矩方向平行且相反,得到磁传感器。The first magnetic tunnel junction device or the second magnetic tunnel junction device is magnetized by using a second magnetic field that is opposite to the first magnetic field and has different magnitudes, so that the device magnetized by the second magnetic field The magnetic moment direction of the reference layer is parallel and opposite to that of the reference layer of the device not magnetized by the second magnetic field, resulting in a magnetic sensor.
可选的,在所述底电极上表面制备与所述底电极电连接的第一磁隧道结器件包括:Optionally, preparing a first magnetic tunnel junction device electrically connected to the bottom electrode on the upper surface of the bottom electrode includes:
在所述底电极上表面制备待处理第一磁隧道结器件,并在所述待处理第一磁隧道结器件上表面形成第一掩膜层;preparing a first magnetic tunnel junction device to be processed on the upper surface of the bottom electrode, and forming a first mask layer on the upper surface of the first magnetic tunnel junction device to be processed;
以所述第一掩膜层作为掩膜,刻蚀所述待处理第一磁隧道结器件,形成所述第一磁隧道结器件。Using the first mask layer as a mask, the first magnetic tunnel junction device to be processed is etched to form the first magnetic tunnel junction device.
可选的,在刻蚀待处理导线层形成所述导线层时,刻蚀停止至所述待处理导线层的上表面。Optionally, when etching the wire layer to be processed to form the wire layer, the etching stops to the upper surface of the wire layer to be processed.
本申请所提供的一种磁传感器,包括设有底电极的芯片,和设于所述芯片上的器件组,所述器件组包括:与所述底电极电连接的第一磁隧道结器件;设于所述第一磁隧道结器件上方的导线层;设于所述导线层上表面、依次层叠的第二磁隧道结器件和第二掩膜层,所述第一磁隧道结器件和所 述第二磁隧道结器件中参考层的磁矩方向平行且相反;设于所述第二掩膜层上表面的顶电极;与所述导线层连接的信号引出部。A magnetic sensor provided by the present application includes a chip provided with a bottom electrode, and a device group provided on the chip, the device group including: a first magnetic tunnel junction device electrically connected to the bottom electrode; The wire layer arranged above the first magnetic tunnel junction device; the second magnetic tunnel junction device and the second mask layer arranged on the upper surface of the wire layer and stacked in sequence, the first magnetic tunnel junction device and the The direction of the magnetic moment of the reference layer in the second magnetic tunnel junction device is parallel and opposite; the top electrode arranged on the upper surface of the second mask layer; the signal lead-out part connected with the wire layer.
可见,本申请磁传感器中的器件组直接设置在芯片上,器件组中的第一磁隧道结器件和第二磁隧道结器件在垂直方向上分布,可以减小磁传感器的面积;第一磁隧道结器件和第二磁隧道结器件中参考层的磁矩方向平行且相反,使得第一磁隧道结器件和所述第二磁隧道结器件的电阻在相同磁场作用下电阻的变化相反,即通过在同一芯片上形成第一磁隧道结器件和第二磁隧道结器件,即可形成惠斯通半桥,不需要特殊设备或工艺,非常简单。It can be seen that the device group in the magnetic sensor of the present application is directly arranged on the chip, and the first magnetic tunnel junction device and the second magnetic tunnel junction device in the device group are distributed in the vertical direction, which can reduce the area of the magnetic sensor; The magnetic moment directions of the reference layer in the tunnel junction device and the second magnetic tunnel junction device are parallel and opposite, so that the resistance of the first magnetic tunnel junction device and the second magnetic tunnel junction device change oppositely under the action of the same magnetic field, that is By forming the first magnetic tunnel junction device and the second magnetic tunnel junction device on the same chip, the Wheatstone half bridge can be formed without special equipment or process, and is very simple.
此外,本申请还提供一种具有上述优点的磁传感器制作方法。In addition, the present application also provides a method for manufacturing a magnetic sensor with the above-mentioned advantages.
为了更清楚的说明本申请实施例或现有技术的技术方案,下面将对实施例或现有技术描述中所需要使用的附图作简单的介绍,显而易见地,下面描述中的附图仅仅是本申请的一些实施例,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图获得其他的附图。In order to more clearly illustrate the technical solutions of the embodiments of the present application or the prior art, the accompanying drawings that need to be used in the description of the embodiments or the prior art will be briefly introduced below. Obviously, the accompanying drawings in the following description are only For some embodiments of the present application, those of ordinary skill in the art can also obtain other drawings based on these drawings without creative effort.
图1为本申请实施例所提供的一种磁传感器的结构示意图;FIG. 1 is a schematic structural diagram of a magnetic sensor provided in an embodiment of the present application;
图2为本申请实施例中芯片与z轴的关系示意图;Fig. 2 is a schematic diagram of the relationship between the chip and the z-axis in the embodiment of the present application;
图3为本申请实施例中第一磁隧道结器件和第二磁隧道结器件在一种磁场作用下电阻变化示意图;FIG. 3 is a schematic diagram of resistance changes of the first magnetic tunnel junction device and the second magnetic tunnel junction device under the action of a magnetic field in the embodiment of the present application;
图4为本申请实施例中第一磁隧道结器件和第二磁隧道结器件在另一种磁场作用下电阻变化示意图;FIG. 4 is a schematic diagram of resistance changes of the first magnetic tunnel junction device and the second magnetic tunnel junction device under another magnetic field in the embodiment of the present application;
图5为本申请实施例所提供的一种磁传感器中惠斯通半桥的结构示意图;FIG. 5 is a schematic structural diagram of a Wheatstone half-bridge in a magnetic sensor provided by an embodiment of the present application;
图6为本申请实施例所提供的一种磁传感器制作方法的流程图;FIG. 6 is a flow chart of a method for manufacturing a magnetic sensor provided in an embodiment of the present application;
图7至图21为本申请实施例所提供的一种磁传感器制作工艺流程图;7 to 21 are flow charts of a manufacturing process of a magnetic sensor provided in the embodiment of the present application;
图22为两个惠斯通半桥并联形成惠斯通全桥的示意图。FIG. 22 is a schematic diagram of two Wheatstone half bridges connected in parallel to form a Wheatstone full bridge.
为了使本技术领域的人员更好地理解本申请方案,下面结合附图和具体实施方式对本申请作进一步的详细说明。显然,所描述的实施例仅仅是本申请一部分实施例,而不是全部的实施例。基于本申请中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本申请保护的范围。In order to enable those skilled in the art to better understand the solution of the present application, the present application will be further described in detail below in conjunction with the drawings and specific implementation methods. Apparently, the described embodiments are only some of the embodiments of this application, not all of them. Based on the embodiments in this application, all other embodiments obtained by persons of ordinary skill in the art without making creative efforts belong to the scope of protection of this application.
在下面的描述中阐述了很多具体细节以便于充分理解本发明,但是本发明还可以采用其他不同于在此描述的其它方式来实施,本领域技术人员可以在不违背本发明内涵的情况下做类似推广,因此本发明不受下面公开的具体实施例的限制。In the following description, a lot of specific details are set forth in order to fully understand the present invention, but the present invention can also be implemented in other ways different from those described here, and those skilled in the art can do it without departing from the meaning of the present invention. By analogy, the present invention is therefore not limited to the specific examples disclosed below.
正如背景技术部分所述,目前的磁传感器在制作时为了得到具有相反的电阻-磁场变化模式的MTJ器件,将两种不同电阻特性的MTJ器件分别在两块芯片上制备,并将两块芯片进行封装,导致磁传感器的面积较大;当在同一块芯片上制备不同电阻特性的MTJ器件时,需要设计两道MTJ生长工艺得到相反特性的MTJ器件,工艺步骤较多、比较复杂,或者,用一道MTJ生长工艺在芯片不同区域生长相同的MTJ器件,再通过处理形成相反特性的MTJ器件,导致磁传感器的面积较大,且难以精确控制磁场范围。As mentioned in the background technology section, in order to obtain MTJ devices with opposite resistance-magnetic field change modes during the fabrication of current magnetic sensors, two MTJ devices with different resistance characteristics are prepared on two chips respectively, and the two chips are Packaging results in a larger area of the magnetic sensor; when preparing MTJ devices with different resistance characteristics on the same chip, it is necessary to design two MTJ growth processes to obtain MTJ devices with opposite characteristics, and the process steps are more and more complicated, or, Using an MTJ growth process to grow the same MTJ device in different regions of the chip, and then form MTJ devices with opposite characteristics through processing, resulting in a large area of the magnetic sensor and it is difficult to precisely control the magnetic field range.
有鉴于此,本申请提供了一种磁传感器,请参考图1,包括设有底电极1的芯片,和设于所述芯片上的器件组,所述器件组包括:In view of this, the present application provides a magnetic sensor, please refer to FIG. 1 , including a chip provided with a bottom electrode 1, and a device group disposed on the chip, the device group comprising:
与所述底电极1电连接的第一磁隧道结器件2;A first magnetic tunnel junction device 2 electrically connected to the bottom electrode 1;
设于所述第一磁隧道结器件2上方的导线层5;a wire layer 5 disposed above the first magnetic tunnel junction device 2;
设于所述导线层5上表面、依次层叠的第二磁隧道结器件6和第二掩膜层7,所述第一磁隧道结器件2和所述第二磁隧道结器件6中参考层的磁矩方向平行且相反;The second magnetic tunnel junction device 6 and the second mask layer 7 stacked in sequence on the upper surface of the wire layer 5, the reference layer in the first magnetic tunnel junction device 2 and the second magnetic tunnel junction device 6 The directions of the magnetic moments are parallel and opposite;
设于所述第二掩膜层7上表面的顶电极9;a top electrode 9 disposed on the upper surface of the second mask layer 7;
与所述导线层连接的信号引出部10。A signal lead-out part 10 connected to the wire layer.
可选的,磁传感器还包括:Optionally, the magnetic sensor also includes:
设于所述第一磁隧道结器件2上表面的第一掩膜层3;a first mask layer 3 disposed on the upper surface of the first magnetic tunnel junction device 2;
设于所述第一磁隧道结器件2周围且与所述第一掩膜层3齐平的第一绝 缘层4。相应的,导线层5位于所述第一掩膜层3和所述第一绝缘层4上表面。A first insulating layer 4 disposed around the first magnetic tunnel junction device 2 and flush with the first mask layer 3. Correspondingly, the wiring layer 5 is located on the upper surfaces of the first mask layer 3 and the first insulating layer 4 .
设于所述第二磁隧道结器件6周围且与所述第二掩膜层7齐平的第二绝缘层8;所述信号引出部10贯穿所述第二绝缘层8。A second insulating layer 8 disposed around the second magnetic tunnel junction device 6 and flush with the second mask layer 7 ; the signal lead-out portion 10 penetrates through the second insulating layer 8 .
其中,所述第一绝缘层4包括:Wherein, the first insulating layer 4 includes:
设于所述第一磁隧道结器件2周围的第一绝缘单元层41;a first insulating unit layer 41 disposed around the first magnetic tunnel junction device 2;
设于所述第一绝缘单元层外表面的第二绝缘单元层42。The second insulating unit layer 42 is disposed on the outer surface of the first insulating unit layer.
第一绝缘单元层的材料可以为氮化硅,第二绝缘单元层可以为二氧化硅或者氮氧化硅等氧化物绝缘层。The material of the first insulating unit layer may be silicon nitride, and the second insulating unit layer may be an oxide insulating layer such as silicon dioxide or silicon oxynitride.
所述第二绝缘层8包括:The second insulating layer 8 includes:
设于所述第二磁隧道结器件6周围的第三绝缘单元层81;a third insulating unit layer 81 disposed around the second magnetic tunnel junction device 6;
设于所述第三绝缘单元层外表面的第四绝缘单元层82。The fourth insulating unit layer 82 is disposed on the outer surface of the third insulating unit layer.
第三绝缘单元层的材料可以为氮化硅,第四绝缘单元层可以为二氧化硅或者氮氧化硅等氧化物绝缘层。The material of the third insulating unit layer may be silicon nitride, and the fourth insulating unit layer may be an oxide insulating layer such as silicon dioxide or silicon oxynitride.
第一掩膜层3和第二掩膜层7导电膜层,材料可以为钽、氮化钽、氮化钛中的任一种等。The conductive film layer of the first mask layer 3 and the second mask layer 7 may be any one of tantalum, tantalum nitride, and titanium nitride.
第一磁隧道结器件2包括由下至上层叠的晶种层21、第一钉扎层22、第一耦合层23、第一参考层24、第一势垒层25、第一自由层26、第一覆盖层27,第二磁隧道结器件6包括由下至上层叠的第二自由层61、第二势垒层62、第二参考层63、第二耦合层64、第二钉扎层65和第二覆盖层66。The first magnetic tunnel junction device 2 includes a seed layer 21, a first pinning layer 22, a first coupling layer 23, a first reference layer 24, a first barrier layer 25, a first free layer 26, and a layer stacked from bottom to top. The first cladding layer 27, the second magnetic tunnel junction device 6 includes a second free layer 61, a second barrier layer 62, a second reference layer 63, a second coupling layer 64, and a second pinning layer 65 stacked from bottom to top and a second cover layer 66 .
晶种层21的材料包括但不限于钌、铂、镍铬合金;第一钉扎层22和第二钉扎层65可以为不同组分的钴铁硼合金、钴、钴/铂多层膜、钴/镍多层膜等,其中,当为多层膜结构时,第一钉扎层22和第二钉扎层65中重复次数可以不同或者相同;第一耦合层23和第二耦合层64的材料包括但不限于钌、铱、铑;第一势垒层25和第二势垒层62的材料可以为氧化镁、氧化铝、氧化镓镁等;第一参考层24和第二参考层63的材料可以为不同成分的钴铁硼合金;第一自由层26和第一自由层26材料可以是不同组分的钴铁硼合金及相关材料,第一自由层26和第二自由层61厚度在1.5纳米~3纳米之间;第一覆盖层27和第二覆盖层66的材料可以为氧化镁、钽、钨、钼、不同组分的钴铁硼合金、钌、钽、钌/钽多层膜等。第一势垒层25和第二势垒层62的厚 度由第一磁隧道结器件2和第二磁隧道结器件6的宽度和惠斯通电桥单臂所需电阻决定,一般的,第一势垒层25和第二势垒层62的厚度在1纳米~3纳米之间。The material of the seed layer 21 includes but not limited to ruthenium, platinum, and nickel-chromium alloy; the first pinning layer 22 and the second pinning layer 65 can be cobalt-iron-boron alloys, cobalt, and cobalt/platinum multilayer films of different compositions. , cobalt/nickel multilayer film, etc., wherein, when it is a multilayer film structure, the number of repetitions in the first pinning layer 22 and the second pinning layer 65 can be different or the same; the first coupling layer 23 and the second coupling layer The material of 64 includes but not limited to ruthenium, iridium, rhodium; the material of the first barrier layer 25 and the second barrier layer 62 can be magnesium oxide, aluminum oxide, gallium magnesium oxide, etc.; the first reference layer 24 and the second reference layer The material of layer 63 can be the cobalt-iron-boron alloy of different composition; The first free layer 26 and the first free layer 26 materials can be the cobalt-iron-boron alloy of different composition and relevant material, the first free layer 26 and the second free layer The thickness of 61 is between 1.5 nanometers and 3 nanometers; the materials of the first covering layer 27 and the second covering layer 66 can be magnesium oxide, tantalum, tungsten, molybdenum, cobalt-iron-boron alloys of different components, ruthenium, tantalum, ruthenium/ Tantalum multilayer film, etc. The thickness of the first barrier layer 25 and the second barrier layer 62 is determined by the width of the first magnetic tunnel junction device 2 and the second magnetic tunnel junction device 6 and the required resistance of the single arm of the Wheatstone bridge. Generally, the first The thickness of the barrier layer 25 and the second barrier layer 62 is between 1 nanometer and 3 nanometers.
第一自由层26和第二自由层61具有面内的磁各向异性,第一耦合层23、第二耦合层64、第一势垒层25、第二势垒层62、晶种层21、第一覆盖层27和第二覆盖层66没有磁性,第一钉扎层22、第二钉扎层65、第一参考层24和第二参考层63具有面外的磁各向异性。The first free layer 26 and the second free layer 61 have in-plane magnetic anisotropy, the first coupling layer 23, the second coupling layer 64, the first barrier layer 25, the second barrier layer 62, the seed layer 21 , the first cladding layer 27 and the second cladding layer 66 have no magnetism, and the first pinning layer 22 , the second pinning layer 65 , the first reference layer 24 and the second reference layer 63 have out-of-plane magnetic anisotropy.
第一磁隧道结器件2和第二磁隧道结器件6中参考层的磁矩方向平行且相反,即第一参考层24与第二参考层63的磁矩方向平行且相反,从而使得第一磁隧道结器件2和第二磁隧道结器件6在相同磁场作用下电阻变化相反。第一钉扎层22和第二钉扎层65的磁矩方向相反,可以通过施加大小不同、方向相反但垂直于芯片平面的磁场进行磁化来实现,由于层间耦合作用,第一参考层24和第二参考层63的磁矩方向分别与第一钉扎层22和第二钉扎层65相反,所以第一参考层24和第二参考层63的磁矩方向也相反。The magnetic moment directions of the reference layers in the first magnetic tunnel junction device 2 and the second magnetic tunnel junction device 6 are parallel and opposite, that is, the magnetic moment directions of the first reference layer 24 and the second reference layer 63 are parallel and opposite, so that the first The magnetic tunnel junction device 2 and the second magnetic tunnel junction device 6 have opposite resistance changes under the same magnetic field. The directions of the magnetic moments of the first pinned layer 22 and the second pinned layer 65 are opposite, which can be realized by applying magnetic fields of different magnitudes and opposite directions but perpendicular to the plane of the chip for magnetization. Due to interlayer coupling, the first reference layer 24 The directions of the magnetic moments of the second reference layer 63 and the first pinned layer 22 and the second pinned layer 65 are respectively opposite, so the directions of the magnetic moments of the first reference layer 24 and the second reference layer 63 are also opposite.
当第一参考层24与第二参考层63在垂直于芯片表面的磁场下翻转时,第一磁隧道结器件2和第二磁隧道结器件6的电阻与磁场的变化模式相反,从而实现惠斯通半电桥。When the first reference layer 24 and the second reference layer 63 are flipped under the magnetic field perpendicular to the chip surface, the resistance of the first magnetic tunnel junction device 2 and the second magnetic tunnel junction device 6 is opposite to the change mode of the magnetic field, thereby realizing the benefit Stone half bridge.
请参考图2和图3,z轴垂直于芯片表面,当磁场方向是-z时,第一磁隧道结器件2和第二磁隧道结器件6中具有磁性的各个层的磁矩方向如图3中所示,此时,第一磁隧道结的自由层磁矩与第一参考层24磁矩处于平行状态,表现为低电阻值,第二磁隧道结的自由层磁矩与第二参考层63磁矩处于反平行状态,表现高低电阻值;当磁场方向转为+z时,第一磁隧道结的自由层磁矩与第一参考层24磁矩处于反平行状态,表现为高电阻值,第二磁隧道结的自由层磁矩与第二参考层63磁矩处于平行状态,表现低电阻值;从而实现了同一个结构中的两种相反的电阻-磁场响应模式,旋即原位实现了一个惠斯通电桥的半桥结构。此时磁传感器可以感应z方向的磁场,即垂直于芯片上表面方向。Please refer to FIG. 2 and FIG. 3, the z axis is perpendicular to the chip surface, when the magnetic field direction is -z, the magnetic moment direction of each layer with magnetism in the first magnetic tunnel junction device 2 and the second magnetic tunnel junction device 6 is shown in the figure 3, at this time, the free layer magnetic moment of the first magnetic tunnel junction is parallel to the magnetic moment of the first reference layer 24, showing a low resistance value, and the free layer magnetic moment of the second magnetic tunnel junction is parallel to the second reference layer 24 magnetic moment. The magnetic moment of layer 63 is in an antiparallel state, showing high and low resistance values; when the magnetic field direction turns to +z, the magnetic moment of the free layer of the first magnetic tunnel junction and the magnetic moment of the first reference layer 24 are in an antiparallel state, showing high resistance value, the magnetic moment of the free layer of the second magnetic tunnel junction is parallel to the magnetic moment of the second reference layer 63, showing a low resistance value; thereby realizing two opposite resistance-magnetic field response modes in the same structure, that is, in situ A half-bridge structure of a Wheatstone bridge is realized. At this time, the magnetic sensor can sense the magnetic field in the z direction, that is, the direction perpendicular to the upper surface of the chip.
请参考图4,当磁场方向与z轴垂直,例如平行于x轴或者y轴,第一磁隧道结器件2和第二磁隧道结器件6中具有磁性的各个层的磁矩方向如图4 中所示,当第一磁隧道结的自由层磁矩与第一参考层24磁矩处于平行状态,表现为低电阻值,第二磁隧道结的自由层磁矩与第二参考层63磁矩处于反平行状态,表现高低电阻值;当磁场方向转180°后,第一磁隧道结的自由层磁矩与第一参考层24磁矩处于反平行状态,表现为高电阻值,第二磁隧道结的自由层磁矩与第二参考层63磁矩处于平行状态,表现低电阻值。此时磁传感器可以感应x和y方向的磁场,即平行于芯片上表面方向。Please refer to FIG. 4, when the magnetic field direction is perpendicular to the z-axis, for example, parallel to the x-axis or y-axis, the magnetic moment direction of each magnetic layer in the first magnetic tunnel junction device 2 and the second magnetic tunnel junction device 6 is shown in FIG. 4 As shown in , when the magnetic moment of the free layer of the first magnetic tunnel junction is parallel to the magnetic moment of the first reference layer 24, showing a low resistance value, the magnetic moment of the free layer of the second magnetic tunnel junction and the magnetic moment of the second reference layer 63 The moments are in an antiparallel state, showing high and low resistance values; when the direction of the magnetic field is turned 180°, the free layer magnetic moments of the first magnetic tunnel junction and the first reference layer 24 are in an antiparallel state, showing high resistance values, and the second The magnetic moment of the free layer of the magnetic tunnel junction is parallel to the magnetic moment of the second reference layer 63 , showing low resistance. At this time, the magnetic sensor can sense the magnetic fields in the x and y directions, that is, the directions parallel to the upper surface of the chip.
第二磁隧道结器件6与第一磁隧道结器件2在垂直于芯片方向上既可以重叠,也可以不重叠,本申请中不做限定。当重叠时,也并不会影响信号的引出。The second magnetic tunnel junction device 6 may or may not overlap with the first magnetic tunnel junction device 2 in a direction perpendicular to the chip, which is not limited in this application. When overlapping, it will not affect the signal extraction.
需要说明的是,本申请中对第一磁隧道结器件2和第二磁隧道结器件6的形状不做限定,可自行设置。所述第一磁隧道结器件2和所述第二磁隧道结器件6的长轴方向相同。例如,第一磁隧道结器件2和第二磁隧道结器件6的形状可以为圆柱状,或者椭圆柱。当为圆柱状时,第一磁隧道结器件2和第二磁隧道结器件6的宽度即为直径,当为椭圆柱时,第一磁隧道结器件2和第二磁隧道结器件6的宽度为长径或者短径。椭圆柱的长轴宽度一般在1微米~20微米之间,短轴宽度一般在0.1微米~10微米;圆柱状器件直径一般在0.1微米~10微米。It should be noted that, in this application, the shapes of the first magnetic tunnel junction device 2 and the second magnetic tunnel junction device 6 are not limited, and can be set by themselves. The long axis directions of the first magnetic tunnel junction device 2 and the second magnetic tunnel junction device 6 are the same. For example, the shapes of the first magnetic tunnel junction device 2 and the second magnetic tunnel junction device 6 may be cylindrical or elliptical. When it is cylindrical, the width of the first magnetic tunnel junction device 2 and the second magnetic tunnel junction device 6 is the diameter, and when it is an elliptical cylinder, the width of the first magnetic tunnel junction device 2 and the second magnetic tunnel junction device 6 long or short diameter. The major axis width of the elliptical cylinder is generally between 1 micron and 20 microns, and the minor axis width is generally 0.1 micron to 10 microns; the diameter of the cylindrical device is generally 0.1 micron to 10 microns.
进一步的,所述第一磁隧道结器件2和所述第二磁隧道结器件6的形状为椭圆柱,且第一磁隧道结器件2和所述第二磁隧道结器件6的长轴方向相同。例如,第一磁隧道结器件2和所述第二磁隧道结器件6的长轴方向都与z轴平行,或者都与x轴平行。Further, the shape of the first magnetic tunnel junction device 2 and the second magnetic tunnel junction device 6 is an elliptical cylinder, and the long axis direction of the first magnetic tunnel junction device 2 and the second magnetic tunnel junction device 6 same. For example, the long axis directions of the first magnetic tunnel junction device 2 and the second magnetic tunnel junction device 6 are both parallel to the z-axis, or both are parallel to the x-axis.
第一磁隧道结器件2和第二磁隧道结器件6的宽度的绝对值由惠斯通电桥所需的电阻值决定,宽度差值由信号引出部10的宽度(直径)决定。The absolute value of the width of the first magnetic tunnel junction device 2 and the second magnetic tunnel junction device 6 is determined by the resistance value required by the Wheatstone bridge, and the width difference is determined by the width (diameter) of the signal lead-out part 10 .
导线层5为金属导线层,导线层5的厚度可以在1纳米~100纳米之间,所述金属导线层的材料为钴、钨、钌、钼、钽中的任一种或任意组合。The wire layer 5 is a metal wire layer, and the thickness of the wire layer 5 can be between 1 nanometer and 100 nanometers. The material of the metal wire layer is any one or any combination of cobalt, tungsten, ruthenium, molybdenum, and tantalum.
所述底电极1的材料可以为氮化钽或者氮化钛等等,顶电极9的材料也可以是氮化钽、氮化钛等。The material of the bottom electrode 1 can be tantalum nitride or titanium nitride, etc., and the material of the top electrode 9 can also be tantalum nitride, titanium nitride, etc.
本申请磁传感器中的器件组直接设置在芯片上,器件组中的第一磁隧道结器件2和第二磁隧道结器件6在垂直方向上分布,可以减小磁传感器的 面积;第一磁隧道结器件2和第二磁隧道结器件6之间设置有导线层5,信号引出部10与导线层5连接,第一磁隧道结器件2和第二磁隧道结器件6中参考层的磁矩方向平行且相反,使得第一磁隧道结器件2和所述第二磁隧道结器件6的电阻在相同磁场作用下电阻的变化相反,即通过在同一芯片上形成第一磁隧道结器件2和第二磁隧道结器件6,并设置第一掩膜层3、第一绝缘层4、第二掩膜层7和第二绝缘层8,即可形成惠斯通半桥,不需要特殊设备或工艺,非常简单。The device group in the magnetic sensor of the present application is directly arranged on the chip, and the first magnetic tunnel junction device 2 and the second magnetic tunnel junction device 6 in the device group are distributed in the vertical direction, which can reduce the area of the magnetic sensor; A wire layer 5 is arranged between the tunnel junction device 2 and the second magnetic tunnel junction device 6, the signal lead-out part 10 is connected to the wire layer 5, and the magnetic field of the reference layer in the first magnetic tunnel junction device 2 and the second magnetic tunnel junction device 6 The moment directions are parallel and opposite, so that the resistance of the first magnetic tunnel junction device 2 and the second magnetic tunnel junction device 6 change oppositely under the action of the same magnetic field, that is, by forming the first magnetic tunnel junction device 2 on the same chip and the second magnetic tunnel junction device 6, and the first mask layer 3, the first insulating layer 4, the second mask layer 7 and the second insulating layer 8 can be formed to form a Wheatstone half bridge without special equipment Or Craft, very simple.
在上述实施例的基础上,在本申请的一个实施例中,当所述器件组的数量为多个时,多个所述器件组形成惠斯通半桥,惠斯通半桥中第一预设数量个所述第一磁隧道结器件2串联,第二预设数量个所述第二磁隧道结器件6串联,所述第一预设数量和所述第二预设数量均小于所述器件组的数量。On the basis of the above embodiments, in one embodiment of the present application, when the number of the device groups is multiple, the multiple device groups form a Wheatstone half bridge, and the first Wheatstone half bridge in the Wheatstone half bridge A preset number of the first magnetic tunnel junction devices 2 are connected in series, a second preset number of the second magnetic tunnel junction devices 6 are connected in series, the first preset number and the second preset number are less than the set The number of device groups described above.
本申请中对第一预设数量和第二预设数量不做限定,可自行设置。In this application, there is no limitation on the first preset number and the second preset number, which can be set by themselves.
可以通过预设的金属布线实现多个第一磁隧道结器件2串联,多个第二磁隧道结器件6串联,以器件组的数量为5个为例,形成的惠斯通半桥如图5所示,从左起,左边三个器件组中的第一磁隧道结器件2串联,从右起,右边三个器件组中的第二磁隧道结器件6串联,信号从中间的器件组中的信号引出部10输出。A plurality of first magnetic tunnel junction devices 2 can be connected in series through preset metal wiring, and a plurality of second magnetic tunnel junction devices 6 can be connected in series. Taking the number of device groups as 5 as an example, the formed Wheatstone half bridge is shown in the figure As shown in 5, from the left, the first magnetic tunnel junction device 2 in the three device groups on the left is connected in series, and from the right, the second magnetic tunnel junction device 6 in the three device groups on the right is connected in series, and the signal is transmitted from the device group in the middle The signal lead-out part 10 in the output.
在上述实施例的基础上,在本申请的一个实施例中,所述器件组的数量为多个时,多个所述器件组形成惠斯通全桥,惠斯通全桥包括并联的第一半桥和第二半桥,所述第一半桥和所述第二半桥中第三预设数量个所述第一磁隧道结器件2串联,第四预设数量个所述第二磁隧道结器件6串联。On the basis of the above-mentioned embodiments, in one embodiment of the present application, when the number of the device groups is multiple, the multiple device groups form a Wheatstone full bridge, and the Wheatstone full bridge includes a parallel connection of the first The half bridge and the second half bridge, the third preset number of the first magnetic tunnel junction devices 2 in the first half bridge and the second half bridge are connected in series, and the fourth preset number of the second The magnetic tunnel junction devices 6 are connected in series.
本申请中对第三预设数量和第四预设数量不做限定,可自行设置。In this application, there is no limitation on the third preset quantity and the fourth preset quantity, which can be set by themselves.
第一半桥和第二半桥的结构示意图可以参考图4,需要注意的是,当第一半桥和第二半桥并联时,第一半桥和第二半桥总体通过头尾相接的方式并联,如图22所示。The structural diagram of the first half bridge and the second half bridge can refer to Figure 4. It should be noted that when the first half bridge and the second half bridge are connected in parallel, the first half bridge and the second half bridge are generally connected head to tail in parallel, as shown in Figure 22.
本申请还提供一种磁传感器制作方法,请参考图6,该方法包括:The present application also provides a manufacturing method of a magnetic sensor, please refer to FIG. 6, the method includes:
步骤S101:在芯片上形成底电极。Step S101: forming a bottom electrode on the chip.
步骤S102:在所述底电极上表面制备与所述底电极电连接的第一磁隧道结器件。Step S102: preparing a first magnetic tunnel junction device electrically connected to the bottom electrode on the upper surface of the bottom electrode.
可选的,本步骤包括:Optionally, this step includes:
步骤S1021:在所述底电极上表面制备待处理第一磁隧道结器件,并在所述待处理第一磁隧道结器件上表面形成第一掩膜层;Step S1021: preparing a first magnetic tunnel junction device to be processed on the upper surface of the bottom electrode, and forming a first mask layer on the upper surface of the first magnetic tunnel junction device to be processed;
本步骤请参考图7,先制备待处理第一磁隧道结器件2’,然后在上表面制备待处理第一掩膜层,并对待处理第一掩膜层进行光刻和刻蚀得到第一掩膜层3。Please refer to FIG. 7 for this step. First prepare the first magnetic tunnel junction device 2' to be processed, then prepare the first mask layer to be processed on the upper surface, and perform photolithography and etching on the first mask layer to be processed to obtain the first Mask layer 3.
待处理第一磁隧道结器件2’包括由下至上依次层叠的晶种层、第一钉扎层、第一耦合层、第一参考层、第一势垒层、第一自由层、第一覆盖层。The first magnetic tunnel junction device 2' to be processed includes a seed layer, a first pinning layer, a first coupling layer, a first reference layer, a first barrier layer, a first free layer, a first overlay.
步骤S1022:以所述第一掩膜层作为掩膜,刻蚀所述待处理第一磁隧道结器件,形成所述第一磁隧道结器件。Step S1022: using the first mask layer as a mask, etching the first magnetic tunnel junction device to be processed to form the first magnetic tunnel junction device.
可选的,刻蚀待处理第一磁隧道结器件,形成第一磁隧道结器件包括:Optionally, etching the first magnetic tunnel junction device to be processed to form the first magnetic tunnel junction device includes:
采用干法刻蚀,刻蚀待处理第一磁隧道结器件,形成第一磁隧道结器件。其中干法刻蚀可以为离子束刻蚀,或者反应离子刻蚀。待处理第一磁隧道结器件的刻蚀方式还可以采用湿法刻蚀,本申请中不进行具体限定。本步骤中在刻蚀时,刻蚀停止在底电极所在界面,或者超过界面1纳米~10纳米。Dry etching is used to etch the first magnetic tunnel junction device to be processed to form the first magnetic tunnel junction device. The dry etching can be ion beam etching or reactive ion etching. The etching method of the first magnetic tunnel junction device to be processed may also be wet etching, which is not specifically limited in this application. During etching in this step, the etching stops at the interface where the bottom electrode is located, or exceeds the interface by 1 nanometer to 10 nanometers.
形成第一磁隧道结器件2后的示意图请参考图8。Please refer to FIG. 8 for a schematic diagram after forming the first magnetic tunnel junction device 2 .
可选的,在第一磁隧道结器件之后还包括:在第一磁隧道结器件周围形成第一绝缘层,第一绝缘层与第一掩膜层上表面齐平,具体包括:Optionally, after the first magnetic tunnel junction device, it also includes: forming a first insulating layer around the first magnetic tunnel junction device, and the first insulating layer is flush with the upper surface of the first mask layer, specifically including:
步骤S201:在第一磁隧道结器件周围形成第一绝缘单元层41,如图9所示;Step S201: forming a first insulating unit layer 41 around the first magnetic tunnel junction device, as shown in FIG. 9 ;
步骤S202:在第一绝缘单元层41的外表面形成第二绝缘单元层42,如图10所示;Step S202: forming a second insulating unit layer 42 on the outer surface of the first insulating unit layer 41, as shown in FIG. 10 ;
步骤S203:使用化学机械平坦法磨平第一绝缘单元层和第二绝缘单元层上表面至第一掩模层露出,如图11所示。Step S203: use chemical mechanical planarization method to smooth the top surfaces of the first insulating unit layer and the second insulating unit layer until the first mask layer is exposed, as shown in FIG. 11 .
步骤S103:在所述第一磁隧道结器件上方形成导线层。Step S103: forming a wire layer above the first magnetic tunnel junction device.
步骤S104:在所述导线层上表面制备依次层叠的第二磁隧道结器件和第二掩膜层。Step S104: preparing sequentially stacked second magnetic tunnel junction devices and a second mask layer on the upper surface of the wire layer.
本步骤请参考图12至图14,在第一掩膜层和第一绝缘层上表面形成待处理导线层5’,在待处理导线层5’的上表面制备待处理第二磁隧道结器件,可选的,在待处理第二磁隧道结器件上表面制备待处理第二掩膜层,并对待处理第二掩膜层进行光刻和刻蚀得到第二掩膜层7,以第二掩膜层7作为掩膜,刻蚀待处理第二磁隧道结器件,形成第二磁隧道结器件。Please refer to Fig. 12 to Fig. 14 for this step, form the wire layer 5' to be processed on the upper surface of the first mask layer and the first insulating layer, and prepare the second magnetic tunnel junction device to be processed on the upper surface of the wire layer 5' to be processed , optionally, prepare the second mask layer to be processed on the upper surface of the second magnetic tunnel junction device to be processed, and perform photolithography and etching on the second mask layer to be processed to obtain the second mask layer 7, with the second The mask layer 7 is used as a mask to etch the second magnetic tunnel junction device to be processed to form the second magnetic tunnel junction device.
待处理第二磁隧道结器件包括由下至上层叠的第二自由层、第二势垒层、第二参考层、第二耦合层、第二钉扎层和第二覆盖层。The second magnetic tunnel junction device to be processed includes a second free layer, a second potential barrier layer, a second reference layer, a second coupling layer, a second pinning layer and a second covering layer stacked from bottom to top.
刻蚀待处理第二磁隧道结器件的方式可以为离子束刻蚀,或者反应离子刻蚀。The manner of etching the second magnetic tunnel junction device to be processed may be ion beam etching or reactive ion etching.
可选的,形成第二磁隧道结器件之后还包括:Optionally, after forming the second magnetic tunnel junction device, it also includes:
在第二磁隧道结器件周围形成第三绝缘单元层81,如图15所示;Forming a third insulating unit layer 81 around the second magnetic tunnel junction device, as shown in FIG. 15 ;
在第三绝缘单元层81的外表面形成第四绝缘单元层82,如图16所示;Forming a fourth insulating unit layer 82 on the outer surface of the third insulating unit layer 81, as shown in FIG. 16 ;
使用化学机械平坦法磨平第三绝缘单元层81和第四绝缘单元层82上表面,至第二掩模层露出,形成预处理第二绝缘层,如图17所示;Polish the upper surfaces of the third insulating unit layer 81 and the fourth insulating unit layer 82 by chemical mechanical planarization until the second mask layer is exposed to form a pre-treated second insulating layer, as shown in FIG. 17 ;
在第二掩膜层和预处理第二绝缘层的上表面形成待处理第三掩膜层,并根据金属布线图案进行光刻和刻蚀形成第三掩膜层11,如图18所示,然后对预处理第二绝缘层和待处理导线层进行刻蚀,形成第二绝缘层和导线层5,如图19所示。Form a third mask layer to be processed on the upper surface of the second mask layer and the pre-treated second insulating layer, and perform photolithography and etching according to the metal wiring pattern to form a third mask layer 11, as shown in FIG. 18 , Then the pre-treated second insulating layer and the wire layer to be processed are etched to form the second insulating layer and the wire layer 5 , as shown in FIG. 19 .
可选的,刻蚀预处理第二绝缘层和待处理导线层时,刻蚀停止至待处理导线层的上表面,也即刻蚀停止至待处理导线层与第二绝缘层的界面。但是本申请对此并不做具体限定,作为另一种实施方式,刻蚀预处理第二绝缘层和待处理导线层时,刻蚀超过待处理导线层与第二绝缘层的界面,待处理导线层的刻蚀深度在1纳米~30纳米之间。Optionally, when etching the pre-treated second insulation layer and the wire layer to be processed, the etching stops to the upper surface of the wire layer to be processed, that is, the etching stops to the interface between the wire layer to be processed and the second insulation layer. However, this application does not specifically limit this. As another implementation method, when etching the pre-treated second insulating layer and the wire layer to be processed, the etching exceeds the interface between the wire layer to be processed and the second insulating layer, and the wire layer to be processed is etched. The etching depth of the wire layer is between 1 nanometer and 30 nanometers.
步骤S105:在所述第二掩膜层上表面形成顶电极。Step S105: forming a top electrode on the upper surface of the second mask layer.
请参考图20和图21,先在第三掩膜层上形成层间氧化物绝缘层12,然后采用化学机械平坦法磨平至第二掩模层7露出,并在第二掩模层7上形成 顶电极。Please refer to FIG. 20 and FIG. 21 , an interlayer oxide insulating layer 12 is first formed on the third mask layer, and then the chemical mechanical planarization method is used to polish the second mask layer 7 to expose, and the second mask layer 7 form the top electrode.
步骤S106:制备与所述导线层连接的信号引出部。Step S106: preparing a signal lead-out portion connected to the wire layer.
通孔的制作方式可以采用大马士革法,然后在通孔中沉积金属形成信号引出部,得到如图1所示的结构示意图,信号引出部与导线层电连通。The through hole can be made by Damascene method, and then metal is deposited in the through hole to form the signal lead-out part, and the structural diagram shown in Figure 1 is obtained, and the signal lead-out part is electrically connected with the wire layer.
步骤S107:使用第一磁场对所述第一磁隧道结器件和所述第二磁隧道结器件进行磁化处理,使所述第一磁隧道结器件和所述第二磁隧道结器件中参考层的磁矩方向平行且相同。Step S107: Using a first magnetic field to magnetize the first magnetic tunnel junction device and the second magnetic tunnel junction device, so that the reference layer in the first magnetic tunnel junction device and the second magnetic tunnel junction device The directions of the magnetic moments are parallel and identical.
步骤S108:使用与所述第一磁场方向相反、大小不等的第二磁场对所述第一磁隧道结器件或所述第二磁隧道结器件进行磁化处理,使被所述第二磁场磁化的器件的参考层的磁矩方向与未被所述第二磁场磁化的器件的参考层的磁矩方向平行且相反,得到磁传感器。Step S108: Magnetize the first magnetic tunnel junction device or the second magnetic tunnel junction device by using a second magnetic field opposite in direction to the first magnetic field and different in size, so that the magnetic tunnel junction device magnetized by the second magnetic field The magnetic moment direction of the reference layer of the device is parallel to and opposite to that of the reference layer of the device not magnetized by the second magnetic field, thereby obtaining a magnetic sensor.
现有技术中是针对芯片不同区域的MTJ器件在相反方向的磁场中磁化或者退火,得到相反特性的MTJ器件,磁场范围难以精确控制,而本申请中采用两个方向相反、大小不等的磁场分两次对芯片上的所有器件进行磁化处理,从而得到相反特性的第一磁隧道结器件和第二磁隧道结器件,非常简单方便,同时还可以减小磁传感器的面积。In the prior art, the MTJ devices in different regions of the chip are magnetized or annealed in the magnetic field in the opposite direction to obtain MTJ devices with opposite characteristics, and the range of the magnetic field is difficult to accurately control. In this application, two magnetic fields with opposite directions and different sizes are used. All devices on the chip are magnetized twice to obtain the first magnetic tunnel junction device and the second magnetic tunnel junction device with opposite characteristics, which is very simple and convenient, and can also reduce the area of the magnetic sensor.
上述实施例中是以一个器件组为例进行阐述的,当器件的数量为多个时,通过设置布线可以将多个器件组形成惠斯通半桥和全桥的形式。In the above embodiment, one device group is taken as an example for illustration. When there are multiple devices, multiple device groups can be formed into Wheatstone half-bridge and full-bridge forms by setting wiring.
本说明书中各个实施例采用递进的方式描述,每个实施例重点说明的都是与其它实施例的不同之处,各个实施例之间相同或相似部分互相参见即可。对于实施例公开的装置而言,由于其与实施例公开的方法相对应,所以描述的比较简单,相关之处参见方法部分说明即可。Each embodiment in this specification is described in a progressive manner, each embodiment focuses on the difference from other embodiments, and the same or similar parts of each embodiment can be referred to each other. As for the device disclosed in the embodiment, since it corresponds to the method disclosed in the embodiment, the description is relatively simple, and for the related part, please refer to the description of the method part.
以上对本申请所提供的磁传感器及其制作方法进行了详细介绍。本文中应用了具体个例对本申请的原理及实施方式进行了阐述,以上实施例的说明只是用于帮助理解本申请的方法及其核心思想。应当指出,对于本技术领域的普通技术人员来说,在不脱离本申请原理的前提下,还可以对本申请进行若干改进和修饰,这些改进和修饰也落入本申请权利要求的保护范围内。The magnetic sensor provided by the present application and the manufacturing method thereof have been introduced in detail above. In this paper, specific examples are used to illustrate the principles and implementation methods of the present application, and the descriptions of the above embodiments are only used to help understand the methods and core ideas of the present application. It should be pointed out that those skilled in the art can make several improvements and modifications to the application without departing from the principles of the application, and these improvements and modifications also fall within the protection scope of the claims of the application.
Claims (10)
- 一种磁传感器,其特征在于,包括设有底电极的芯片,和设于所述芯片上的器件组,所述器件组包括:A kind of magnetic sensor is characterized in that, comprises the chip that is provided with bottom electrode, and is arranged on the device group on described chip, and described device group comprises:与所述底电极电连接的第一磁隧道结器件;a first magnetic tunnel junction device electrically connected to the bottom electrode;设于所述第一磁隧道结器件上方的导线层;a wire layer disposed above the first magnetic tunnel junction device;设于所述导线层上表面、依次层叠的第二磁隧道结器件和第二掩膜层,所述第一磁隧道结器件和所述第二磁隧道结器件中参考层的磁矩方向平行且相反;The second magnetic tunnel junction device and the second mask layer are arranged on the upper surface of the wire layer and stacked in sequence, and the magnetic moment direction of the reference layer in the first magnetic tunnel junction device and the second magnetic tunnel junction device is parallel and the opposite;设于所述第二掩膜层上表面的顶电极;a top electrode disposed on the upper surface of the second mask layer;与所述导线层连接的信号引出部。A signal lead-out part connected to the wire layer.
- 如权利要求1所述的磁传感器,其特征在于,所述第一磁隧道结器件和所述第二磁隧道结器件的长轴方向相同。The magnetic sensor according to claim 1, wherein the long axis directions of the first magnetic tunnel junction device and the second magnetic tunnel junction device are the same.
- 如权利要求2所述的磁传感器,其特征在于,所述第一磁隧道结器件和所述第二磁隧道结器件的形状为椭圆柱。The magnetic sensor according to claim 2, wherein the shape of the first magnetic tunnel junction device and the second magnetic tunnel junction device is an elliptical cylinder.
- 如权利要求1所述的磁传感器,其特征在于,还包括:The magnetic sensor according to claim 1, further comprising:设于所述第一磁隧道结器件上表面的第一掩膜层;a first mask layer disposed on the upper surface of the first magnetic tunnel junction device;设于所述第一磁隧道结器件周围且与所述第一掩膜层齐平的第一绝缘层。A first insulating layer disposed around the first magnetic tunnel junction device and flush with the first mask layer.
- 如权利要求1所述的磁传感器,其特征在于,还包括:The magnetic sensor according to claim 1, further comprising:设于所述第二磁隧道结器件周围且与所述第二掩膜层齐平的第二绝缘层;所述信号引出部贯穿所述第二绝缘层。A second insulating layer disposed around the second magnetic tunnel junction device and flush with the second mask layer; the signal lead-out part penetrates through the second insulating layer.
- 如权利要求1至5任一项所述的磁传感器,其特征在于,当所述器件组的数量为多个时,多个所述器件组形成惠斯通半桥,惠斯通半桥中第一预设数量个所述第一磁隧道结器件串联,第二预设数量个所述第二磁隧道结器件串联,所述第一预设数量和所述第二预设数量均小于所述器件组的数量。The magnetic sensor according to any one of claims 1 to 5, wherein when the number of said device groups is multiple, a plurality of said device groups form a Wheatstone half-bridge, and in the Wheatstone half-bridge A first preset number of the first magnetic tunnel junction devices are connected in series, a second preset number of the second magnetic tunnel junction devices are connected in series, the first preset number and the second preset number are both less than the set The number of device groups described above.
- 如权利要求1至5任一项所述的磁传感器,其特征在于,所述器件组的数量为多个时,多个所述器件组形成惠斯通全桥,惠斯通全桥包括并联的第一半桥和第二半桥,所述第一半桥和所述第二半桥中第三预设数量 个所述第一磁隧道结器件串联,第四预设数量个所述第二磁隧道结器件串联。The magnetic sensor according to any one of claims 1 to 5, wherein when the number of the device groups is multiple, a plurality of the device groups form a Wheatstone full bridge, and the Wheatstone full bridge includes a parallel connection The first half-bridge and the second half-bridge, the first half-bridge and the second half-bridge have a third preset number of the first magnetic tunnel junction devices connected in series, and a fourth preset number of the first magnetic tunnel junction devices Two magnetic tunnel junction devices are connected in series.
- 一种磁传感器制作方法,其特征在于,包括:A method for manufacturing a magnetic sensor, comprising:在芯片上形成底电极;forming a bottom electrode on the chip;在所述底电极上表面制备与所述底电极电连接的第一磁隧道结器件;preparing a first magnetic tunnel junction device electrically connected to the bottom electrode on the upper surface of the bottom electrode;在所述第一磁隧道结器件上方形成导线层;forming a wire layer over the first magnetic tunnel junction device;在所述导线层上表面制备依次层叠的第二磁隧道结器件和第二掩膜层;preparing sequentially stacked second magnetic tunnel junction devices and a second mask layer on the upper surface of the wire layer;在所述第二掩膜层上表面形成顶电极;forming a top electrode on the upper surface of the second mask layer;制备与所述导线层连接的信号引出部;preparing a signal lead-out part connected to the wire layer;使用第一磁场对所述第一磁隧道结器件和所述第二磁隧道结器件进行磁化处理,使所述第一磁隧道结器件和所述第二磁隧道结器件中参考层的磁矩方向平行且相同;Use the first magnetic field to magnetize the first magnetic tunnel junction device and the second magnetic tunnel junction device, so that the magnetic moment of the reference layer in the first magnetic tunnel junction device and the second magnetic tunnel junction device parallel and identical in direction;使用与所述第一磁场方向相反、大小不等的第二磁场对所述第一磁隧道结器件或所述第二磁隧道结器件进行磁化处理,使被所述第二磁场磁化的器件的参考层的磁矩方向与未被所述第二磁场磁化的器件的参考层的磁矩方向平行且相反,得到磁传感器。The first magnetic tunnel junction device or the second magnetic tunnel junction device is magnetized by using a second magnetic field that is opposite to the first magnetic field and has different magnitudes, so that the device magnetized by the second magnetic field The magnetic moment direction of the reference layer is parallel and opposite to that of the reference layer of the device not magnetized by the second magnetic field, resulting in a magnetic sensor.
- 如权利要求8所述的磁传感器制作方法,其特征在于,在所述底电极上表面制备与所述底电极电连接的第一磁隧道结器件包括:The method for manufacturing a magnetic sensor according to claim 8, wherein preparing a first magnetic tunnel junction device electrically connected to the bottom electrode on the upper surface of the bottom electrode comprises:在所述底电极上表面制备待处理第一磁隧道结器件,并在所述待处理第一磁隧道结器件上表面形成第一掩膜层;preparing a first magnetic tunnel junction device to be processed on the upper surface of the bottom electrode, and forming a first mask layer on the upper surface of the first magnetic tunnel junction device to be processed;以所述第一掩膜层作为掩膜,刻蚀所述待处理第一磁隧道结器件,形成所述第一磁隧道结器件。Using the first mask layer as a mask, the first magnetic tunnel junction device to be processed is etched to form the first magnetic tunnel junction device.
- 如权利要求8或9所述的磁传感器制作方法,其特征在于,在刻蚀待处理导线层形成所述导线层时,刻蚀停止至所述待处理导线层的上表面。The manufacturing method of the magnetic sensor according to claim 8 or 9, characterized in that, when etching the wire layer to be processed to form the wire layer, the etching stops to the upper surface of the wire layer to be processed.
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