WO2021181085A1 - Catalyseur - Google Patents
Catalyseur Download PDFInfo
- Publication number
- WO2021181085A1 WO2021181085A1 PCT/GB2021/050585 GB2021050585W WO2021181085A1 WO 2021181085 A1 WO2021181085 A1 WO 2021181085A1 GB 2021050585 W GB2021050585 W GB 2021050585W WO 2021181085 A1 WO2021181085 A1 WO 2021181085A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- graphene sheets
- fuel cell
- composition according
- catalyst
- typically
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 45
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 93
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 84
- 125000006850 spacer group Chemical class 0.000 claims abstract description 58
- 239000000463 material Substances 0.000 claims abstract description 51
- 239000000446 fuel Substances 0.000 claims abstract description 42
- 238000000034 method Methods 0.000 claims abstract description 17
- 230000003197 catalytic effect Effects 0.000 claims description 43
- 239000000203 mixture Substances 0.000 claims description 43
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 42
- 239000002245 particle Substances 0.000 claims description 34
- 239000000243 solution Substances 0.000 claims description 31
- 229910052751 metal Inorganic materials 0.000 claims description 14
- 229910052697 platinum Inorganic materials 0.000 claims description 14
- 239000002184 metal Substances 0.000 claims description 13
- 239000002105 nanoparticle Substances 0.000 claims description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 10
- 239000012528 membrane Substances 0.000 claims description 10
- 239000010411 electrocatalyst Substances 0.000 claims description 9
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 8
- 239000001257 hydrogen Substances 0.000 claims description 8
- 229910052739 hydrogen Inorganic materials 0.000 claims description 8
- 238000006243 chemical reaction Methods 0.000 claims description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 6
- 229910044991 metal oxide Inorganic materials 0.000 claims description 6
- 150000004706 metal oxides Chemical class 0.000 claims description 6
- 150000002739 metals Chemical class 0.000 claims description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 229910052719 titanium Inorganic materials 0.000 claims description 5
- 239000010936 titanium Substances 0.000 claims description 5
- 229910052725 zinc Inorganic materials 0.000 claims description 5
- 239000011701 zinc Substances 0.000 claims description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
- 239000012670 alkaline solution Substances 0.000 claims description 4
- 238000000576 coating method Methods 0.000 claims description 4
- 229910052802 copper Inorganic materials 0.000 claims description 4
- 239000010949 copper Substances 0.000 claims description 4
- 229910052763 palladium Inorganic materials 0.000 claims description 4
- 238000001179 sorption measurement Methods 0.000 claims description 4
- 239000011248 coating agent Substances 0.000 claims description 3
- 229910052741 iridium Inorganic materials 0.000 claims description 3
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 229910052726 zirconium Inorganic materials 0.000 claims description 3
- 229910052684 Cerium Inorganic materials 0.000 claims description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 2
- 229910052772 Samarium Inorganic materials 0.000 claims description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- 230000002378 acidificating effect Effects 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- 229910017052 cobalt Inorganic materials 0.000 claims description 2
- 239000010941 cobalt Substances 0.000 claims description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
- 230000005611 electricity Effects 0.000 claims description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052737 gold Inorganic materials 0.000 claims description 2
- 239000010931 gold Substances 0.000 claims description 2
- 150000002431 hydrogen Chemical class 0.000 claims description 2
- 229910052748 manganese Inorganic materials 0.000 claims description 2
- 229910052750 molybdenum Inorganic materials 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 229910017604 nitric acid Inorganic materials 0.000 claims description 2
- 229910052762 osmium Inorganic materials 0.000 claims description 2
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- 239000010948 rhodium Substances 0.000 claims description 2
- 229910052703 rhodium Inorganic materials 0.000 claims description 2
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims description 2
- 229910052707 ruthenium Inorganic materials 0.000 claims description 2
- 229910052709 silver Inorganic materials 0.000 claims description 2
- 239000004332 silver Substances 0.000 claims description 2
- 229910052721 tungsten Inorganic materials 0.000 claims description 2
- 229910052727 yttrium Inorganic materials 0.000 claims description 2
- 238000007254 oxidation reaction Methods 0.000 claims 3
- 230000003647 oxidation Effects 0.000 claims 2
- 230000000845 anti-microbial effect Effects 0.000 claims 1
- 239000004599 antimicrobial Substances 0.000 claims 1
- 238000003843 chloralkali process Methods 0.000 claims 1
- 238000006356 dehydrogenation reaction Methods 0.000 claims 1
- 239000011152 fibreglass Substances 0.000 claims 1
- 229930195733 hydrocarbon Natural products 0.000 claims 1
- 150000002430 hydrocarbons Chemical class 0.000 claims 1
- 238000005984 hydrogenation reaction Methods 0.000 claims 1
- 150000001247 metal acetylides Chemical class 0.000 claims 1
- 238000006479 redox reaction Methods 0.000 claims 1
- 238000006722 reduction reaction Methods 0.000 claims 1
- 238000003786 synthesis reaction Methods 0.000 claims 1
- 239000007769 metal material Substances 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 17
- 229910052799 carbon Inorganic materials 0.000 description 9
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 8
- 239000000976 ink Substances 0.000 description 7
- 230000008569 process Effects 0.000 description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
- 238000009792 diffusion process Methods 0.000 description 5
- 238000009826 distribution Methods 0.000 description 5
- 238000005507 spraying Methods 0.000 description 5
- 239000006229 carbon black Substances 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 239000002064 nanoplatelet Substances 0.000 description 4
- 230000010287 polarization Effects 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000000151 deposition Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000011810 insulating material Substances 0.000 description 3
- 241000894007 species Species 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000004891 communication Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000002484 cyclic voltammetry Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000012777 electrically insulating material Substances 0.000 description 2
- 239000008151 electrolyte solution Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 229910021397 glassy carbon Inorganic materials 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 239000011244 liquid electrolyte Substances 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- 230000002101 lytic effect Effects 0.000 description 2
- 150000004767 nitrides Chemical class 0.000 description 2
- 230000036961 partial effect Effects 0.000 description 2
- 239000005518 polymer electrolyte Substances 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 235000011149 sulphuric acid Nutrition 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- FGUUSXIOTUKUDN-IBGZPJMESA-N C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 Chemical compound C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 FGUUSXIOTUKUDN-IBGZPJMESA-N 0.000 description 1
- 102100027085 Dual specificity protein phosphatase 4 Human genes 0.000 description 1
- 229910002621 H2PtCl6 Inorganic materials 0.000 description 1
- 229910003591 H2PtCl6.6H20 Inorganic materials 0.000 description 1
- 101001057621 Homo sapiens Dual specificity protein phosphatase 4 Proteins 0.000 description 1
- 230000010757 Reduction Activity Effects 0.000 description 1
- 241000872198 Serjania polyphylla Species 0.000 description 1
- 229910001308 Zinc ferrite Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000003011 anion exchange membrane Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 230000002902 bimodal effect Effects 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000002322 conducting polymer Substances 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000009878 intermolecular interaction Effects 0.000 description 1
- 239000003273 ketjen black Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000010907 mechanical stirring Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000002082 metal nanoparticle Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000000546 pharmaceutical excipient Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 238000000527 sonication Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/92—Metals of platinum group
- H01M4/925—Metals of platinum group supported on carriers, e.g. powder carriers
- H01M4/926—Metals of platinum group supported on carriers, e.g. powder carriers on carbon or graphite
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
- C01B32/182—Graphene
- C01B32/194—After-treatment
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2204/00—Structure or properties of graphene
- C01B2204/20—Graphene characterized by its properties
- C01B2204/32—Size or surface area
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
- H01G11/32—Carbon-based
- H01G11/36—Nanostructures, e.g. nanofibres, nanotubes or fullerenes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Definitions
- compositions for use in fuel cells comprising: a plurality of catalyst-functionalised graphene sheets; and one or more spacer particles; characterised in that the spacer particles partially disrupt the co-ordination between the graphene sheets; and wherein the spacer particles comprise one or more metals.
- the particle size distribution of the spacers need not be such that all particles have the same dimensions. As one skilled in the art will appreciate, such highly uniform formulations are very difficult to create. However, the particle size distribution may be a normal distribution (i.e. a Gaussian distribution) or a bimodal distribution.
- the spacer will comprise an electrically insulating material. It has surprisingly been found that employing an electrically insulating material appears to improve the electrochemical performance. This is counter-intuitive, not only because it was not expected for an insulating material to augment electrochemical processes but, because the presence of insulating materials in electrochemical systems typically reduces the overall efficiency of charge transfer (making the whole electrochemical process less efficient). Even if such an adverse phenomena is occurring in the present invention, as can be seen from the examples, better results are nevertheless obtained with insulating materials as compared to embodiments employing conducting spacers.
- an electrode comprising the composition according to the first aspect of the invention.
- the electrode is typically a cathode, though anodes are also envisaged.
- the electrode may be part of a membrane electrode assembly (MEA) as would be familiar to one skilled in the art (see, for example, WO213093449).
- the electrodes may be diffusion electrodes, comprising an electrically conducting support with a diffusion material deposited on the surface comprising the complex.
- Figure 2 shows polarization curves (on a 10 cm 2 membrane electrode assembly) of the catalyst according to Example 1 without spacers (identified as “HM10”) compared to the same catalyst with titanium oxide spacers (identified as “HM10 + PO2"). For comparison purposes, this was contrasted with a commercial MEA made using 40 wt.% Pt on carbon black.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Nanotechnology (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Inert Electrodes (AREA)
Abstract
L'invention concerne un catalyseur destiné à être utilisé dans des piles à combustible, des procédés de fabrication dudit catalyseur, des électrodes et des piles à combustible comprenant ledit catalyseur et l'utilisation dudit catalyseur dans des piles à combustible. En particulier, l'invention utilise un graphène fonctionnalisé par catalyseur perturbé, à l'aide d'une série d'éléments d'espacement (typiquement fabriqués à partir de substances non métalliques), pour optimiser les performances des matériaux.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB2003464.1A GB202003464D0 (en) | 2020-03-10 | 2020-03-10 | Catalyst |
| GB2003464.1 | 2020-03-10 | ||
| GB2003617.4 | 2020-03-12 | ||
| GBGB2003617.4A GB202003617D0 (en) | 2020-03-12 | 2020-03-12 | Catalyst |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2021181085A1 true WO2021181085A1 (fr) | 2021-09-16 |
Family
ID=74870845
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/GB2021/050585 WO2021181085A1 (fr) | 2020-03-10 | 2021-03-09 | Catalyseur |
Country Status (1)
| Country | Link |
|---|---|
| WO (1) | WO2021181085A1 (fr) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114864968A (zh) * | 2022-04-06 | 2022-08-05 | 东风汽车集团股份有限公司 | 一种燃料电池用抗反极催化剂及其制备方法和应用 |
| CN114941157A (zh) * | 2022-05-30 | 2022-08-26 | 安徽工业大学 | 一种电催化剂材料及其制备方法 |
| CN115020718A (zh) * | 2022-06-14 | 2022-09-06 | 太原理工大学 | 用于甲醇氧化反应的非贵金属纳米催化剂及其制备方法 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009143405A2 (fr) * | 2008-05-22 | 2009-11-26 | The University Of North Carolina At Chapel Hill | Synthèse de feuillets de graphène et composites nanoparticulaires en comprenant |
| WO2013093449A2 (fr) | 2011-12-20 | 2013-06-27 | Ucl Business Plc | Pile à combustible |
| US20140098461A1 (en) * | 2012-10-09 | 2014-04-10 | Aruna Zhamu | Spacer-modified graphene electrode for supercapacitor |
| CN107394222A (zh) * | 2017-07-10 | 2017-11-24 | 浙江美都墨烯科技有限公司 | 氧化铈/贵金属/石墨烯三元复合材料及其制备方法和应用 |
| WO2019158569A1 (fr) | 2018-02-13 | 2019-08-22 | Ucl Business Plc | Procédé de préparation de nanomatériau |
-
2021
- 2021-03-09 WO PCT/GB2021/050585 patent/WO2021181085A1/fr active Application Filing
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009143405A2 (fr) * | 2008-05-22 | 2009-11-26 | The University Of North Carolina At Chapel Hill | Synthèse de feuillets de graphène et composites nanoparticulaires en comprenant |
| WO2013093449A2 (fr) | 2011-12-20 | 2013-06-27 | Ucl Business Plc | Pile à combustible |
| US20140098461A1 (en) * | 2012-10-09 | 2014-04-10 | Aruna Zhamu | Spacer-modified graphene electrode for supercapacitor |
| CN107394222A (zh) * | 2017-07-10 | 2017-11-24 | 浙江美都墨烯科技有限公司 | 氧化铈/贵金属/石墨烯三元复合材料及其制备方法和应用 |
| WO2019158569A1 (fr) | 2018-02-13 | 2019-08-22 | Ucl Business Plc | Procédé de préparation de nanomatériau |
Non-Patent Citations (3)
| Title |
|---|
| ECE ARICI ET AL.: "An effective electrocatalyst based on platinum nanoparticles supported with graphene nanoplatelets and carbon black hybrid for PEM fuel cells'", INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, vol. 44, no. 27, 24 May 2019 (2019-05-24), pages 14175 - 14183, XP085691804, DOI: 10.1016/j.ijhydene.2018.11.210 |
| SEHKYU PARK ET AL.: "Design of graphene sheets-supported Pt catalyst layer in PEM fuel cells", ELECTROCHEMISTRY COMMUNICATIONS, vol. 13, 3 March 2011 (2011-03-03), pages 258 - 261, XP028147536, DOI: 10.1016/j.elecom.2010.12.028 |
| YANNICK GARSANY ET AL.: "Analytical Procedure for Accurate Comparison of Rotating Disk Electrode Results for the Oxygen Reduction Activity of Pt/C", JOURNAL OF THE ELECTROCHEMICAL SOCIETY, vol. 161, no. 5, 2014, pages F628 - F640 |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114864968A (zh) * | 2022-04-06 | 2022-08-05 | 东风汽车集团股份有限公司 | 一种燃料电池用抗反极催化剂及其制备方法和应用 |
| CN114864968B (zh) * | 2022-04-06 | 2024-04-16 | 东风汽车集团股份有限公司 | 一种燃料电池用抗反极催化剂及其制备方法和应用 |
| CN114941157A (zh) * | 2022-05-30 | 2022-08-26 | 安徽工业大学 | 一种电催化剂材料及其制备方法 |
| CN114941157B (zh) * | 2022-05-30 | 2023-11-28 | 安徽工业大学 | 一种电催化剂材料及其制备方法 |
| CN115020718A (zh) * | 2022-06-14 | 2022-09-06 | 太原理工大学 | 用于甲醇氧化反应的非贵金属纳米催化剂及其制备方法 |
| CN115020718B (zh) * | 2022-06-14 | 2024-02-13 | 太原理工大学 | 用于甲醇氧化反应的非贵金属纳米催化剂及其制备方法 |
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