WO2020147231A1 - Wipe and manufacturing method therefor - Google Patents
Wipe and manufacturing method therefor Download PDFInfo
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- WO2020147231A1 WO2020147231A1 PCT/CN2019/087403 CN2019087403W WO2020147231A1 WO 2020147231 A1 WO2020147231 A1 WO 2020147231A1 CN 2019087403 W CN2019087403 W CN 2019087403W WO 2020147231 A1 WO2020147231 A1 WO 2020147231A1
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- fiber
- melt
- fiber web
- wood pulp
- blown
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/04—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres having existing or potential cohesive properties, e.g. natural fibres, prestretched or fibrillated artificial fibres
- D04H1/26—Wood pulp
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4382—Stretched reticular film fibres; Composite fibres; Mixed fibres; Ultrafine fibres; Fibres for artificial leather
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4374—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece using different kinds of webs, e.g. by layering webs
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/425—Cellulose series
- D04H1/4258—Regenerated cellulose series
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- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4282—Addition polymers
- D04H1/4291—Olefin series
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- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4326—Condensation or reaction polymers
- D04H1/435—Polyesters
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- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
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- D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
- D04H1/541—Composite fibres, e.g. sheath-core, sea-island or side-by-side; Mixed fibres
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
- D04H1/542—Adhesive fibres
- D04H1/544—Olefin series
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
- D04H1/542—Adhesive fibres
- D04H1/55—Polyesters
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
- D04H1/542—Adhesive fibres
- D04H1/551—Resins thereof not provided for in groups D04H1/544 - D04H1/55
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- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
- D04H1/56—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving in association with fibre formation, e.g. immediately following extrusion of staple fibres
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
- D04H1/593—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives to layered webs
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
- D04H1/60—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in dry state, e.g. thermo-activatable agents in solid or molten state, and heat being applied subsequently
- D04H1/62—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in dry state, e.g. thermo-activatable agents in solid or molten state, and heat being applied subsequently at spaced points or locations
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/70—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres
- D04H1/72—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being randomly arranged
- D04H1/724—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being randomly arranged forming webs during fibre formation, e.g. flash-spinning
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- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/70—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres
- D04H1/74—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being orientated, e.g. in parallel (anisotropic fleeces)
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- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/08—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
- D04H3/16—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic filaments produced in association with filament formation, e.g. immediately following extrusion
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- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
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- D04H5/00—Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length
- D04H5/06—Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length strengthened or consolidated by welding-together thermoplastic fibres, filaments, or yarns
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- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2509/00—Medical; Hygiene
- D10B2509/02—Bandages, dressings or absorbent pads
- D10B2509/026—Absorbent pads; Tampons; Laundry; Towels
Definitions
- the invention relates to the technical field of wipes, and in particular to a wipe with abrasion resistance and anti-fuzzing surface for personal care and infant care and a manufacturing method thereof.
- Wipes are often used in daily life, such as when parents change diapers for babies, or when dining in a restaurant, or when putting on make-up and skin care. Because the wipes are quite convenient to carry and store, and are convenient to use, they are popular among consumers. Therefore, wipes are more and more widely used in personal care and infant care.
- the wipes can be spunlace non-woven products or spunbonded non-woven products. More traditional cloth wipes have convenient production methods, low prices, and can be used dry or wet.
- wood pulp is often added to the wipe to improve the moisture absorption and decontamination ability of the wipe.
- the wood pulp fibers are natural short fibers. The fibers are short and are not affected by temperature and are not easy to be consolidated together. They are only fixed by spunbonding or spunlace processes. When in use, the wood pulp will be rubbed several times. Short fibers are easy to fall off, causing hair loss, which affects service life.
- the purpose of the present invention is to provide a wipe and its manufacturing method for preventing surface fluffing and linting, and to overcome the defects of existing products and production methods.
- a wiper the upper and lower layers of the wiper are meltblown fiber webs, and the middle layer is a wood pulp fiber web, wherein the surface of the meltblown fiber web and the inside of the meltblown fiber web adjacent to the surface are both An adhesive is attached, and the melt-blown fibers of the melt-blown fiber web are interspersed in the wood pulp fiber web.
- the melt-blown fiber web contains single-component melt-blown fibers with a high-melting-point resin on the fiber surface, fibers with a low-melting-point resin on the fiber surface, or a blended fiber of both.
- the difference between the melting point of the high melting point resin and the low melting point resin is ⁇ 20°C.
- the fiber with low melting point resin on the fiber surface is a single-component melt-blown fiber, a two-component melt-blown fiber or a mixture of the two.
- the two-component melt-blown fiber is a two-component sheath-core melt-blown fiber, a two-component orange petal-type melt-blown fiber or a two-component side-by-side melt-blown fiber.
- the adhesive is hot melt glue or solvent glue.
- the weight of the wood pulp fiber web accounts for more than 50% of the total weight of the wipe.
- the percentage of the weight of the wood pulp fiber web to the total weight of the wipe is 65% to 80%.
- the wood pulp fiber web contains hot melt adhesive material.
- the hot-melt adhesive material is low-melting polyester fiber, ES short fiber, two-component spunbond long fiber or a mixture thereof.
- a method for manufacturing wipes includes the following steps:
- thermoplastic resin is heated and melted, and the melt stream of the thermoplastic resin sprayed from the spinneret is blown into fiber bundles with a fiber diameter of less than 10um by using high temperature and high-speed hot air flow.
- the airflow forms a meltblown fiber web, and it intersects with the two sides of the wood pulp fiber web to form a multi-layer structure fiber web with a meltblown fiber web on both sides and a wood pulp fiber web in the middle;
- the multi-layer structure fiber web is consolidated by the heating device to form the upper and lower layers of meltblown fiber web, the middle layer is a wipe of wood pulp fiber web, and the meltblown fiber Adhesive is attached to the surface of the mesh and the inside of the meltblown fiber mesh adjacent to the surface.
- the two thermoplastic resins whose melting point difference is greater than or equal to 20°C are heated and melted, and the thin stream of the thermoplastic resin melt sprayed from the spinneret is blown into fibers by using high temperature and high-speed hot air flow.
- Fiber bundles with a diameter of less than 10um are accompanied by hot air flow to form a melt-blown fiber web, wherein the melt-blown fiber web contains fibers with a high melting point resin on the fiber surface, fibers with a low melting point resin on the fiber surface, or a blended fiber of both.
- the spinneret contains two-component spinneret holes.
- the two-component spinneret holes on the spinneret are of skin-core type, orange petal type or side-by-side type.
- the heating device is a hot air oven, a hot roll or a combination of both.
- the wood pulp is loosened and dispersed by an opening roller, mixed with the hot-melt adhesive material, and then formed into a wood pulp fiber web containing the hot-melt adhesive material through a nozzle under the action of an auxiliary airflow.
- the wiper manufacturing method of the invention can be applied to make the wiper of the invention. Because the meltblown fiber web of the wiper of the invention has small fiber denier and densely arranged, it can effectively prevent the wood in the middle layer. The fall of short pulp fibers.
- adhesive is attached to the interior and surface of the meltblown fiber web, so that the meltblown fiber web forms a layer of adhesive film, so that the wipes can prevent the surface meltblown fibers from being exposed to external forces due to multiple frictions.
- the phenomenon of fluffing and fluffing caused by the mutual separation and bonding under the action also further prevents the short fibers of the wood pulp in the middle layer from falling out, and the problem of "fluffing" during use and unclean wiping.
- Fig. 1 is a schematic diagram of manufacturing a wipe cloth according to embodiment 1 of the present invention.
- Figure 2 is a cross-sectional view of the wiping cloth of Example 1 of the present invention.
- Fig. 3 is a schematic diagram of manufacturing a wipe cloth according to embodiment 2 of the present invention.
- Figure 4 is a cross-sectional view of the wiping cloth of Example 2 of the present invention.
- Figure 5A is a cross-sectional view of the sheath-core meltblown fiber of the present invention.
- 5B is a cross-sectional view of the two-component side-by-side meltblown fiber of the present invention.
- Figure 5C is a cross-sectional view of the two-component orange petal type meltblown fiber of the present invention.
- Wood pulp fiber web 23 Melt blown fiber web 24, 25
- Core-sheath melt blown fiber 31 two-component side-by-side melt blown fiber 32
- the present invention discloses a method for manufacturing wipes, including the following steps:
- thermoplastic resin is heated and melted, and the thermoplastic resin melt trickle sprayed from the spinnerets C1 and C1' is blown into fibers with a fiber diameter of ⁇ 10 ⁇ m using high temperature and high-speed hot air.
- the adhesive is sprayed on both sides through nozzles D1 and D1' under the action of high-pressure hot air flow, which are melt-blown fiber webs 13, 14 and a multilayer structure of wood pulp fiber web 12 in the middle.
- the multi-layer structure fiber web 15 after spraying glue is consolidated by a pair of intermeshing hot rolls F1 to form the upper and lower layers of meltblown fiber webs 13, 14, and the middle layer is wood pulp fiber
- the wipes 16 of the net 11, and the surfaces of the meltblown fiber nets 13, 14 and the meltblown fiber nets 13, 14 adjacent to the surface are all attached with adhesives.
- the weight of the wood pulp fiber net 12 is equal to the total weight of the wipes 16. The percentage is 75%.
- the present invention also discloses a wipe that can be made by the above-mentioned method for manufacturing wipes, which has a layered structure.
- the upper and lower layers of the wipe 16 are meltblown fiber webs 13 14.
- the middle layer is a wood pulp fiber web 12, wherein the surface of the meltblown fiber web 13, 14 and the meltblown fiber web 13, 14 adjacent to the surface are all attached with an adhesive, the meltblown fiber web 13
- the meltblown fibers of, 14 are inserted into the wood pulp fiber web 12, and the adhesive can be hot melt glue or solvent glue.
- Adjacent meltblown fiber webs 13, 14 inside, so that the surface of the meltblown fiber webs 13, 14 and the meltblown fiber webs 13, 14 adjacent to the surface are attached with adhesive, forming a layer on the meltblown fiber webs 13, 14
- Adhesive films 17, 18 not only prevent the surface melt-blown fibers from being fluffed and raised due to friction, but also further prevent the wood pulp short fibers in the middle layer from falling out, and the phenomenon of "fluffing" occurs during use. .
- the present invention discloses a method for manufacturing wipes, including the following steps:
- the wood pulp 21 is loosened and dispersed by the opening roller A2, and mixed with the hot-melt adhesive material 22, and then under the action of the auxiliary air flow, the wood pulp fiber web containing the hot-melt adhesive material 22 is formed through the nozzle B2 twenty three.
- melt-blowing process the two thermoplastic resins are heated separately, then enter the spinning box after melting, and the thermoplastic resin will be sprayed from the spinnerets C2 and C2' in the spinning box using high temperature and high-speed hot air
- the melt-blown stream is blown into fiber bundles with a fiber diameter of ⁇ 10 ⁇ m, and the melt-blown fiber webs 24, 25 are formed with hot air flow.
- the melt-blown fiber webs 24, 25 are composed of single-component melt-blown fibers with high melting point resin on the fiber surface. 20 and the meltblown fiber 20' with low melting point resin on the fiber surface.
- the melt-blown fiber webs 24 and 25 may also contain only single-component melt-blown fibers 20 with high-melting resin on the fiber surface or only melt-blown fibers 20' with low-melting resin on the fiber surface, and the fiber surface contains low-melting resin.
- the melt-blown fiber 20' can be a single-component melt-blown fiber, a two-component melt-blown fiber or a mixture of the two.
- the two-component meltblown fiber may be a sheath-core type meltblown fiber 31, a two-component orange petal type meltblown fiber 33 or a two-component side-by-side type meltblown fiber 32, and the sheath-core type
- the melting point of the skin layer resin 31b in the meltblown fiber 31 is lower than that of the core layer resin 31a.
- the melting point of one of the resins 32b and 33b of the two-component orange petal type melt-blown fiber 33 and the two-component side-by-side melt-blown fiber 32 is low. It is the melting point of another resin 32a, 33a.
- the two-component melt-blown fiber is formed by heating and melting two thermoplastic resins with a difference of ⁇ 20° C. between the melting points, and spraying them from the two-component spinneret holes in the spinneret.
- the two-component spinneret holes on the plate are skin-core, orange-petal or side-by-side; then the meltblown fiber webs 24, 25 are formed at the two sides of the wood pulp fiber web 23 containing the hot-melt adhesive 22 Intersect to form a multi-layer structure fiber web 26 with meltblown fiber webs 24 and 25 containing two-component meltblown fibers on both sides, and a wood pulp fiber web 23 containing hot melt adhesive 22 in the middle.
- the adhesive is sprayed on both sides of the meltblown fiber web 24, 25 through nozzles D2 and D2' under the action of high-pressure hot air flow, and the wood containing the hot melt adhesive material 22 in the middle Pulp fiber web 23 has two sides of a multi-layer structure fiber web 26.
- the multi-layer structure fiber web 26 after spraying glues the fiber web through a hot air oven E2 and a pair of meshing hot rolls F2 to consolidate the fiber web together to form the upper and lower layers of meltblown fiber webs 24 and 25, the middle layer
- the wipe 27 is a wood pulp fiber web 23 containing a hot-melt adhesive material 22, and adhesive is attached to the surface of the meltblown fiber web 24, 25 and the inside of the meltblown fiber web 24, 25 adjacent to the surface.
- the present invention also discloses a wipe that can be made by applying the above-mentioned method for manufacturing wipes, which has a layered structure.
- the upper and lower layers of the wipe 27 are meltblown fiber webs 24.
- the middle layer is a wood pulp fiber web 23 containing a hot melt adhesive material 22, wherein the surface of the melt blown fiber web 24, 25 and the melt blown fiber web 24, 25 adjacent to the surface are all attached with adhesive
- the meltblown fibers of the meltblown fiber webs 24, 25 are interspersed in the wood pulp fiber web 23.
- the meltblown fiber webs 24, 25 consist of a single-component meltblown fiber 20 whose fiber surface is a high melting point resin and the fiber surface contains low Melt-blown fiber 20' blending composition of melting resin.
- the meltblown fiber 20' containing low-melting resin on the fiber surface can be a single-component melt-blown fiber, a two-component melt-blown fiber or a mixture of the two.
- the hot-melt adhesive 22 is a low-melting polyester fiber, ES Short fiber, two-component spun-bonded long fiber or their mixture, and their mixture is formed by mixing low-melting polyester fiber, ES short fiber, two-component spun-bonded long fiber together or optionally a mixture of two.
- the adhesive will not only adhere to the surface of the meltblown fiber webs 24, 25, but also penetrate into the surface during the glue spraying process.
- Adjacent meltblown fiber webs 24, 25 inside, so that the surface of the meltblown fiber webs 24, 25 and the meltblown fiber webs 24, 25 adjacent to the surface are attached with adhesive, forming a layer on the meltblown fiber webs 24, 25
- the adhesive films 28 and 29 not only prevent the surface melt-blown fibers from being fluffed and raised due to friction, but also further prevent the short fibers of the wood pulp in the middle layer from falling out and appearing'fluffing' during use.
- melt-blown fiber webs 24 and 25 contain melt-blown fibers 20' with low-melting resin on the fiber surface.
- the low-melting resin in the melt-blown fibers 20' is melted in a hot-air oven, so that the fibers will stick together, which increases
- the overall strength of the wipes also makes the melt-blown fiber arrangement more dense, and makes the adhesives attached to the surface of the melt-blown fiber webs 24 and 25 stronger.
- a hot-melt adhesive material 22 is added to the wood pulp fiber web 23 of the middle layer.
- the surface of the hot-melt adhesive material 22 starts to melt in the hot-air oven to fix the wood pulp short fibers of the middle layer to a certain extent, so that the wood The short fibers are difficult to move, so as to further prevent the formed wipes from shedding during use, and increase the abrasion resistance of the wipes.
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Abstract
Disclosed is a wipe. Upper and lower layers of the wipe are melt-blow fiber webs (13, 14), and an interlayer thereof is a wood pulp fiber web (12), wherein an adhesive is attached to the surfaces of the melt-blow fiber webs (13, 14) and to the interiors thereof that are adjacent to the surfaces, and the melt-blow fiber of the melt-blow fiber webs (13,14) penetrates into the wood pulp fiber web (12). Also disclosed is a manufacturing method for the wipe. Said method may be used for manufacturing a water absorption wipe. Since the adhesive is attached to the interiors and surfaces of the melt-blow fiber webs, the melt-blow fiber webs form a layer of adhesive film. Therefore, when the wipe is used, fluffiness and piling phenomena are prevented, such phenomena being caused by mutual disengagement of cementation between the melt-blow fibers under the action of external force since the surface melt-blow fibers are subject to multiple instances of friction.
Description
本发明涉及擦拭巾技术领域,尤其涉及应用于个人护理、婴幼儿护理用的一种表面耐磨、防起毛的擦拭巾及其制造方法。
The invention relates to the technical field of wipes, and in particular to a wipe with abrasion resistance and anti-fuzzing surface for personal care and infant care and a manufacturing method thereof.
The
在日常生活中常常需要用到擦拭巾,例如当父母替婴儿更换尿布时,或是餐厅用餐时,或是化妆护理皮肤时。由于擦拭巾携带及收纳相当的方便,且使用便利,因此受到广大消费者的喜爱。所以擦拭巾在个人护理、婴幼儿护理方面应用越来越广泛。Wipes are often used in daily life, such as when parents change diapers for babies, or when dining in a restaurant, or when putting on make-up and skin care. Because the wipes are quite convenient to carry and store, and are convenient to use, they are popular among consumers. Therefore, wipes are more and more widely used in personal care and infant care.
擦拭巾可以是水刺无纺布制品,也可以是纺粘无纺布制品。较传统的布类擦拭巾,其生产方法方便,价格低廉,并且干湿均可使用。为了增加擦拭巾的吸湿性能,在擦拭巾中往往会添加木浆,来提高擦拭巾的吸湿去污能力。但是木浆纤维为天然短纤维,纤维较短且不受温度影响,不易固结在一起,而仅通过纺粘工艺或水刺工艺进行结网固定,在使用时,多次摩擦后使得木浆短纤维容易脱落,造成掉毛现象,掉出影响使用寿命。The wipes can be spunlace non-woven products or spunbonded non-woven products. More traditional cloth wipes have convenient production methods, low prices, and can be used dry or wet. In order to increase the moisture absorption performance of the wipe, wood pulp is often added to the wipe to improve the moisture absorption and decontamination ability of the wipe. However, the wood pulp fibers are natural short fibers. The fibers are short and are not affected by temperature and are not easy to be consolidated together. They are only fixed by spunbonding or spunlace processes. When in use, the wood pulp will be rubbed several times. Short fibers are easy to fall off, causing hair loss, which affects service life.
本发明的目的在于提供一种防止表面起毛、掉毛的擦拭巾及其制造方法,克服现有产品及生产方法的缺陷。The purpose of the present invention is to provide a wipe and its manufacturing method for preventing surface fluffing and linting, and to overcome the defects of existing products and production methods.
为实现上述目的,本发明的解决技术方案是:In order to achieve the above objectives, the technical solution of the present invention is:
一种擦拭巾,所述擦拭巾的上、下两层为熔喷纤维网,中间层为木浆纤维网,其中,所述熔喷纤维网表面及与表面相邻的熔喷纤维网内部均附着有胶粘剂,所述熔喷纤维网的熔喷纤维穿插于木浆纤维网中。A wiper, the upper and lower layers of the wiper are meltblown fiber webs, and the middle layer is a wood pulp fiber web, wherein the surface of the meltblown fiber web and the inside of the meltblown fiber web adjacent to the surface are both An adhesive is attached, and the melt-blown fibers of the melt-blown fiber web are interspersed in the wood pulp fiber web.
所述熔喷纤维网含有纤维表面为高熔点树脂的单组份熔喷纤维、纤维表面含有低熔点树脂的纤维或两者的共混纤维。The melt-blown fiber web contains single-component melt-blown fibers with a high-melting-point resin on the fiber surface, fibers with a low-melting-point resin on the fiber surface, or a blended fiber of both.
所述高熔点树脂和低熔点树脂的熔点之差≥20℃。The difference between the melting point of the high melting point resin and the low melting point resin is ≥20°C.
所述纤维表面含有低熔点树脂的纤维为单组份熔喷纤维、双组份熔喷纤维或两者相混合。The fiber with low melting point resin on the fiber surface is a single-component melt-blown fiber, a two-component melt-blown fiber or a mixture of the two.
所述双组份熔喷纤维为双组份皮芯型熔喷纤维、双组份橘瓣型熔喷纤维或双组份并列型熔喷纤维。The two-component melt-blown fiber is a two-component sheath-core melt-blown fiber, a two-component orange petal-type melt-blown fiber or a two-component side-by-side melt-blown fiber.
所述胶粘剂为热熔胶或溶剂胶。The adhesive is hot melt glue or solvent glue.
所述木浆纤维网的重量占所述擦拭巾总重量的百分比大于50%。The weight of the wood pulp fiber web accounts for more than 50% of the total weight of the wipe.
所述木浆纤维网的重量与所述擦拭巾总重量的百分比为65%~80%。The percentage of the weight of the wood pulp fiber web to the total weight of the wipe is 65% to 80%.
所述木浆纤维网中含有热熔胶粘物质。The wood pulp fiber web contains hot melt adhesive material.
所述热熔胶粘物质为低熔点聚酯纤维,ES短纤维、双组份纺粘长纤维或它们的混合物。The hot-melt adhesive material is low-melting polyester fiber, ES short fiber, two-component spunbond long fiber or a mixture thereof.
一种擦拭巾的制造方法,包括以下步骤:A method for manufacturing wipes includes the following steps:
(1)木浆通过开松辊开松打散,并在辅助气流的作用下通过喷管形成木浆纤维网;(1) The wood pulp is loosened and dispersed by the opening roller, and the wood pulp fiber web is formed through the nozzle under the action of the auxiliary airflow;
(2)采用熔喷法工艺,将热塑性树脂加热,熔融,利用高温、高速热气流将从喷丝板中喷出的热塑性树脂的溶体细流吹散成纤维直径小于10um的纤维束,伴随热气流形成熔喷纤维网,并与木浆纤维网的两个侧面处相交汇,形成两侧为熔喷纤维网,中间为木浆纤维网的多层结构纤维网;(2) Using the melt-blowing process, the thermoplastic resin is heated and melted, and the melt stream of the thermoplastic resin sprayed from the spinneret is blown into fiber bundles with a fiber diameter of less than 10um by using high temperature and high-speed hot air flow. The airflow forms a meltblown fiber web, and it intersects with the two sides of the wood pulp fiber web to form a multi-layer structure fiber web with a meltblown fiber web on both sides and a wood pulp fiber web in the middle;
(3)通过喷胶工艺,将胶粘剂在高压热气流的作用下通过喷管将胶粘剂喷涂在两侧为熔喷纤维网,中间为木浆纤维网的多层结构纤维网的两个侧面;(3) Through the glue spraying process, the adhesive is sprayed on both sides of the melt-blown fiber web through the nozzle under the action of high-pressure hot air flow, and the two sides of the multilayer structure fiber web of wood pulp fiber web in the middle;
(4)喷胶后的多层结构纤维网通过加热装置将纤维网固结在一起,形成上、下两层为熔喷纤维网,中间层为木浆纤维网的擦拭巾,且熔喷纤维网表面及与表面相邻的熔喷纤维网内部均附着有胶粘剂。(4) After spraying, the multi-layer structure fiber web is consolidated by the heating device to form the upper and lower layers of meltblown fiber web, the middle layer is a wipe of wood pulp fiber web, and the meltblown fiber Adhesive is attached to the surface of the mesh and the inside of the meltblown fiber mesh adjacent to the surface.
所述步骤(2)中,分别将两种熔点之差≥20℃的热塑性树脂加热,熔融,利用高温、高速热气流将从喷丝板中喷出的热塑性树脂的溶体细流吹散成纤维直径小于10um的纤维束,伴随热气流形成熔喷纤维网,其中所述熔喷纤维网含有纤维表面为高熔点树脂的纤维、纤维表面含有低熔点树脂的纤维或两者的共混纤维。In the step (2), the two thermoplastic resins whose melting point difference is greater than or equal to 20°C are heated and melted, and the thin stream of the thermoplastic resin melt sprayed from the spinneret is blown into fibers by using high temperature and high-speed hot air flow. Fiber bundles with a diameter of less than 10um are accompanied by hot air flow to form a melt-blown fiber web, wherein the melt-blown fiber web contains fibers with a high melting point resin on the fiber surface, fibers with a low melting point resin on the fiber surface, or a blended fiber of both.
所述喷丝板上含有双组份喷丝孔。The spinneret contains two-component spinneret holes.
所述喷丝板上的双组份喷丝孔为皮芯型、橘瓣型或并列型。The two-component spinneret holes on the spinneret are of skin-core type, orange petal type or side-by-side type.
所述加热装置为热风烘箱、热轧辊或两者相结合。The heating device is a hot air oven, a hot roll or a combination of both.
所述步骤(1)中,木浆通过开松辊开松打散,并与热熔胶粘物质混合后在辅助气流的作用下通过喷管形成含有热熔胶粘物质的木浆纤维网。In the step (1), the wood pulp is loosened and dispersed by an opening roller, mixed with the hot-melt adhesive material, and then formed into a wood pulp fiber web containing the hot-melt adhesive material through a nozzle under the action of an auxiliary airflow.
采用上述技术方案后,可应用本发明的擦拭巾制造方法制得本发明的擦拭巾,由于本发明的擦拭巾的熔喷纤维网的纤维纤度小,排布致密,有效防止了中间层的木浆短纤维的掉落。并且熔喷纤维网内部及表面均附着有胶粘剂,使得熔喷纤维网形成一层胶粘剂膜,使得擦拭巾在使用时既阻止了表面熔喷纤维因多次摩擦而使得熔喷纤维之间在外力作用下相互脱开粘结而引起的起毛、起绒现象,同时也进一步防止了中间层木浆短纤维掉出,在使用过程中出现'掉毛'从而擦拭不干净的问题。After adopting the above technical solution, the wiper manufacturing method of the invention can be applied to make the wiper of the invention. Because the meltblown fiber web of the wiper of the invention has small fiber denier and densely arranged, it can effectively prevent the wood in the middle layer. The fall of short pulp fibers. In addition, adhesive is attached to the interior and surface of the meltblown fiber web, so that the meltblown fiber web forms a layer of adhesive film, so that the wipes can prevent the surface meltblown fibers from being exposed to external forces due to multiple frictions. The phenomenon of fluffing and fluffing caused by the mutual separation and bonding under the action also further prevents the short fibers of the wood pulp in the middle layer from falling out, and the problem of "fluffing" during use and unclean wiping.
图1为本发明实施例1的擦拭布制造示意图;Fig. 1 is a schematic diagram of manufacturing a wipe cloth according to embodiment 1 of the present invention;
图2为本发明实施例1的擦拭布剖面图;Figure 2 is a cross-sectional view of the wiping cloth of Example 1 of the present invention;
图3为本发明实施例2的擦拭布制造示意图;Fig. 3 is a schematic diagram of manufacturing a wipe cloth according to embodiment 2 of the present invention;
图4为本发明实施例2的擦拭布剖面图;Figure 4 is a cross-sectional view of the wiping cloth of Example 2 of the present invention;
图5A为本发明的皮芯型熔喷纤维的截面图;Figure 5A is a cross-sectional view of the sheath-core meltblown fiber of the present invention;
图5B为本发明的双组份并列型熔喷纤维的截面图;5B is a cross-sectional view of the two-component side-by-side meltblown fiber of the present invention;
图5C为本发明的双组份橘瓣型熔喷纤维的截面图。Figure 5C is a cross-sectional view of the two-component orange petal type meltblown fiber of the present invention.
【符号说明】【Symbol Description】
【实施例1】[Example 1]
木浆11木浆纤维网12Wood pulp 11 Wood pulp fiber web 12
熔喷纤维网13、14多层结构纤维网15Meltblown fiber web 13, 14 Multi-layer structure fiber web 15
擦拭巾16胶粘剂膜17、18Wipes 16 Adhesive film 17, 18
开松辊A1喷管B1、D1、D1'Opening roller A1 nozzle B1, D1, D1'
热轧辊F1Hot roll F1
【实施例2】[Example 2]
纤维表面为高熔点树脂的单组份熔喷纤维20Single-component melt blown fiber with high melting point resin on the fiber surface 20
纤维表面含有低熔点树脂的熔喷纤维20'Melt blown fiber with low melting point resin on the fiber surface 20'
木浆21热熔胶粘物质22Wood pulp 21 Hot melt adhesive 22
木浆纤维网23熔喷纤维网24、25Wood pulp fiber web 23 Melt blown fiber web 24, 25
多层结构纤维网26擦拭巾27Multilayer structure fiber mesh 26 Wipes 27
胶粘剂膜28、29Adhesive film 28, 29
皮芯型熔喷纤维31双组份并列型熔喷纤维32Core-sheath melt blown fiber 31 two-component side-by-side melt blown fiber 32
双组份橘瓣型熔喷纤维33Two-component orange petal type meltblown fiber 33
芯层树脂31a皮层树脂31bCore layer resin 31a Skin layer resin 31b
其中一种树脂32b、33bOne of the resins 32b, 33b
另一种树脂32a、33aAnother resin 32a, 33a
开松辊A2喷管B2、D2、D2'Opening roller A2 nozzle B2, D2, D2'
喷丝板C2、C2'热风烘箱E2Spinneret C2, C2' hot air oven E2
热轧辊F2。Hot roll F2.
为了进一步解释本发明的技术方案,下面通过具体实施例来对本发明进行详细阐述。In order to further explain the technical solution of the present invention, the present invention will be described in detail below through specific embodiments.
实施例1Example 1
如图1所示,本发明揭示了一种擦拭巾的制造方法,包括下列步骤:As shown in Figure 1, the present invention discloses a method for manufacturing wipes, including the following steps:
(1)将木浆11通过开松辊A1开松打散,并在辅助气流的作用下通过喷管B1形成木浆纤维网12。(1) The wood pulp 11 is loosened and dispersed by the opening roller A1, and the wood pulp fiber web 12 is formed through the nozzle B1 under the action of the auxiliary airflow.
(2)采用熔喷法工艺,将热塑性树脂加热,熔融,利用高温、高速热气流将从喷丝板C1、C1'中喷出的热塑性树脂的溶体细流吹散成纤维直径≤10μm的纤维束,伴随热气流形成的熔喷纤维网13、14,并与木浆纤维网12的两个侧面处相交汇,形成两侧为熔喷纤维网13、14,中间为木浆纤维网12的多层结构纤维网15,其中,所述熔喷纤维网13、14由纤维表面为高熔点树脂的单组份熔喷纤维组成。(2) Using the melt-blowing process, the thermoplastic resin is heated and melted, and the thermoplastic resin melt trickle sprayed from the spinnerets C1 and C1' is blown into fibers with a fiber diameter of ≤10μm using high temperature and high-speed hot air. Bundles, meltblown fiber webs 13, 14 formed with hot air flow, and intersect with the two sides of the wood pulp fiber web 12 to form a meltblown fiber web 13, 14 on both sides, and a wood pulp fiber web 12 in the middle The multi-layer structure fiber web 15, wherein the melt blown fiber webs 13, 14 are composed of single-component melt blown fibers whose fiber surface is a high melting point resin.
(3)通过喷胶工艺,将胶粘剂在高压热气流的作用下通过喷管D1、D1'将胶粘剂喷涂在两侧为熔喷纤维网13、14,中间为木浆纤维网12的多层结构纤维网15的两个侧面。(3) Through the glue spraying process, the adhesive is sprayed on both sides through nozzles D1 and D1' under the action of high-pressure hot air flow, which are melt-blown fiber webs 13, 14 and a multilayer structure of wood pulp fiber web 12 in the middle. The two sides of the fiber web 15.
(4)喷胶后的多层结构纤维网15通过一对啮合的热轧辊F1将纤维网固结在一起,形成上、下两层为熔喷纤维网13、14,中间层为木浆纤维网11的擦拭巾16,且熔喷纤维网13、14表面及与表面相邻的熔喷纤维网13、14内部均附着有胶粘剂,木浆纤维网12的重量与所述擦拭巾16总重量的百分比为75%。(4) The multi-layer structure fiber web 15 after spraying glue is consolidated by a pair of intermeshing hot rolls F1 to form the upper and lower layers of meltblown fiber webs 13, 14, and the middle layer is wood pulp fiber The wipes 16 of the net 11, and the surfaces of the meltblown fiber nets 13, 14 and the meltblown fiber nets 13, 14 adjacent to the surface are all attached with adhesives. The weight of the wood pulp fiber net 12 is equal to the total weight of the wipes 16. The percentage is 75%.
如图2所示,本发明还揭示了一种可应用上述擦拭巾的制造方法制成的擦拭巾,其为层状结构,所述擦拭巾16的上、下两层为熔喷纤维网13、14,中间层为木浆纤维网12,其中,所述熔喷纤维网13、14表面及与表面相邻的熔喷纤维网13、14内部均附着有胶粘剂,所述熔喷纤维网13、14的熔喷纤维穿插于木浆纤维网12中,所述胶粘剂可以为热熔胶或溶剂胶。As shown in FIG. 2, the present invention also discloses a wipe that can be made by the above-mentioned method for manufacturing wipes, which has a layered structure. The upper and lower layers of the wipe 16 are meltblown fiber webs 13 14. The middle layer is a wood pulp fiber web 12, wherein the surface of the meltblown fiber web 13, 14 and the meltblown fiber web 13, 14 adjacent to the surface are all attached with an adhesive, the meltblown fiber web 13 The meltblown fibers of, 14 are inserted into the wood pulp fiber web 12, and the adhesive can be hot melt glue or solvent glue.
因此,由于喷胶工艺是在熔喷纤维网13、14没有固结之前进行的,所以喷胶过程中,胶粘剂会不仅会粘附在熔喷纤维网13、14表面,也会渗透到与表面相邻的熔喷纤维网13、14内部,使得熔喷纤维网13、14表面及与表面相邻的熔喷纤维网13、14内部附着有胶粘剂,在熔喷纤维网13、14形成一层胶粘剂膜17、18,使得在使用时既阻止了表面熔喷纤维因摩擦而起毛、起绒,而且也进一步防止了中间层的木浆短纤维掉出,在使用过程中出现'掉毛'现象。Therefore, since the glue spraying process is carried out before the meltblown fiber webs 13, 14 are not consolidated, during the glue spraying process, the adhesive will not only adhere to the surface of the meltblown fiber webs 13, 14 but also penetrate into the surface. Adjacent meltblown fiber webs 13, 14 inside, so that the surface of the meltblown fiber webs 13, 14 and the meltblown fiber webs 13, 14 adjacent to the surface are attached with adhesive, forming a layer on the meltblown fiber webs 13, 14 Adhesive films 17, 18 not only prevent the surface melt-blown fibers from being fluffed and raised due to friction, but also further prevent the wood pulp short fibers in the middle layer from falling out, and the phenomenon of "fluffing" occurs during use. .
实施例2Example 2
如图3所示,本发明揭示了一种擦拭巾的制造方法,包括下列步骤:As shown in Figure 3, the present invention discloses a method for manufacturing wipes, including the following steps:
(1)将木浆21通过开松辊A2开松打散,并与热熔胶粘物质22混合后在辅助气流的作用下通过喷管B2形成含有热熔胶粘物质22的木浆纤维网23。(1) The wood pulp 21 is loosened and dispersed by the opening roller A2, and mixed with the hot-melt adhesive material 22, and then under the action of the auxiliary air flow, the wood pulp fiber web containing the hot-melt adhesive material 22 is formed through the nozzle B2 twenty three.
(2)采用熔喷法工艺,将两种热塑性树脂分别加热,熔融后进入纺丝箱,在纺丝箱内利用高温、高速热气流将从喷丝板C2、C2'中喷出的热塑性树脂的溶体细流吹散成纤维直径≤10μm的纤维束,伴随热气流形成熔喷纤维网24、25,其中,熔喷纤维网24、25由纤维表面为高熔点树脂的单组份熔喷纤维20和纤维表面含有低熔点树脂的熔喷纤维20'共混组成。所述熔喷纤维网24、25也可以仅含有纤维表面为高熔点树脂的单组份熔喷纤维20或者仅含有纤维表面含有低熔点树脂的熔喷纤维20',而纤维表面含有低熔点树脂的熔喷纤维20'可以为单组份熔喷纤维、双组份熔喷纤维或两者相混合。如图5A至图5C所示,双组份熔喷纤维可以是皮芯型熔喷纤维31、双组份橘瓣型熔喷纤维33或双组份并列型熔喷纤维32,且皮芯型熔喷纤维31中皮层树脂31b的熔点低于芯层树脂31a的熔点,双组份橘瓣型熔喷纤维33、双组份并列型熔喷纤维32的其中一种树脂32b、33b的熔点低于另一种树脂32a、33a的熔点。该双组份熔喷纤维是将两种熔点之差≥20℃的热塑性树脂加热,熔融,并且由喷丝板上的喷丝孔所含有双组份喷丝孔喷出形成,所述喷丝板上的双组份喷丝孔为皮芯型、橘瓣型或并列型;然后形成的熔喷纤维网24、25在含有热熔胶粘物质22的木浆纤维网23的两个侧面处相交汇,形成两侧是含有双组份熔喷纤维的熔喷纤维网24、25,中间为含有热熔胶粘物质22的木浆纤维网23的多层结构纤维网26。(2) Using the melt-blowing process, the two thermoplastic resins are heated separately, then enter the spinning box after melting, and the thermoplastic resin will be sprayed from the spinnerets C2 and C2' in the spinning box using high temperature and high-speed hot air The melt-blown stream is blown into fiber bundles with a fiber diameter of ≤10μm, and the melt-blown fiber webs 24, 25 are formed with hot air flow. The melt-blown fiber webs 24, 25 are composed of single-component melt-blown fibers with high melting point resin on the fiber surface. 20 and the meltblown fiber 20' with low melting point resin on the fiber surface. The melt-blown fiber webs 24 and 25 may also contain only single-component melt-blown fibers 20 with high-melting resin on the fiber surface or only melt-blown fibers 20' with low-melting resin on the fiber surface, and the fiber surface contains low-melting resin. The melt-blown fiber 20' can be a single-component melt-blown fiber, a two-component melt-blown fiber or a mixture of the two. As shown in Figures 5A to 5C, the two-component meltblown fiber may be a sheath-core type meltblown fiber 31, a two-component orange petal type meltblown fiber 33 or a two-component side-by-side type meltblown fiber 32, and the sheath-core type The melting point of the skin layer resin 31b in the meltblown fiber 31 is lower than that of the core layer resin 31a. The melting point of one of the resins 32b and 33b of the two-component orange petal type melt-blown fiber 33 and the two-component side-by-side melt-blown fiber 32 is low. It is the melting point of another resin 32a, 33a. The two-component melt-blown fiber is formed by heating and melting two thermoplastic resins with a difference of ≥20° C. between the melting points, and spraying them from the two-component spinneret holes in the spinneret. The two-component spinneret holes on the plate are skin-core, orange-petal or side-by-side; then the meltblown fiber webs 24, 25 are formed at the two sides of the wood pulp fiber web 23 containing the hot-melt adhesive 22 Intersect to form a multi-layer structure fiber web 26 with meltblown fiber webs 24 and 25 containing two-component meltblown fibers on both sides, and a wood pulp fiber web 23 containing hot melt adhesive 22 in the middle.
(3)通过喷胶工艺,将胶粘剂在高压热气流的作用下通过喷管D2、D2'将胶粘剂喷涂在两侧为熔喷纤维网24、25,中间为含有热熔胶粘物质22的木浆纤维网23的多层结构纤维网26的两个侧面。(3) Through the spraying process, the adhesive is sprayed on both sides of the meltblown fiber web 24, 25 through nozzles D2 and D2' under the action of high-pressure hot air flow, and the wood containing the hot melt adhesive material 22 in the middle Pulp fiber web 23 has two sides of a multi-layer structure fiber web 26.
(3)喷胶后的多层结构纤维网26通过热风烘箱E2和一对啮合的热轧辊F2将纤维网固结在一起,形成上、下两层为熔喷纤维网24、25,中间层为含有热熔胶粘物质22的木浆纤维网23的擦拭巾27,且熔喷纤维网24、25表面及与表面相邻的熔喷纤维网24、25内部均附着有胶粘剂。(3) The multi-layer structure fiber web 26 after spraying glues the fiber web through a hot air oven E2 and a pair of meshing hot rolls F2 to consolidate the fiber web together to form the upper and lower layers of meltblown fiber webs 24 and 25, the middle layer The wipe 27 is a wood pulp fiber web 23 containing a hot-melt adhesive material 22, and adhesive is attached to the surface of the meltblown fiber web 24, 25 and the inside of the meltblown fiber web 24, 25 adjacent to the surface.
如图4所示,本发明还揭示了一种可应用上述擦拭巾的制造方法制成的擦拭巾,其为层状结构,所述擦拭巾27的上、下两层为熔喷纤维网24、25,中间层为含有热熔胶粘物质22的木浆纤维网23,其中,所述熔喷纤维网24、25表面及与表面相邻的熔喷纤维网24、25内部均附着有胶粘剂,所述熔喷纤维网24、25的熔喷纤维穿插于木浆纤维网23中,熔喷纤维网24、25由纤维表面为高熔点树脂的单组份熔喷纤维20和纤维表面含有低熔点树脂的熔喷纤维20'共混组成。而纤维表面含有低熔点树脂的熔喷纤维20'可以为单组份熔喷纤维、双组份熔喷纤维或两者相混合,所述热熔胶粘物质22为低熔点聚酯纤维,ES短纤维、双组份纺粘长纤维或它们的混合物,它们的混合物是由低熔点聚酯纤维、ES短纤维、双组份纺粘长纤维一起混合或者任选两种混合而成。As shown in Figure 4, the present invention also discloses a wipe that can be made by applying the above-mentioned method for manufacturing wipes, which has a layered structure. The upper and lower layers of the wipe 27 are meltblown fiber webs 24. 25, the middle layer is a wood pulp fiber web 23 containing a hot melt adhesive material 22, wherein the surface of the melt blown fiber web 24, 25 and the melt blown fiber web 24, 25 adjacent to the surface are all attached with adhesive The meltblown fibers of the meltblown fiber webs 24, 25 are interspersed in the wood pulp fiber web 23. The meltblown fiber webs 24, 25 consist of a single-component meltblown fiber 20 whose fiber surface is a high melting point resin and the fiber surface contains low Melt-blown fiber 20' blending composition of melting resin. The meltblown fiber 20' containing low-melting resin on the fiber surface can be a single-component melt-blown fiber, a two-component melt-blown fiber or a mixture of the two. The hot-melt adhesive 22 is a low-melting polyester fiber, ES Short fiber, two-component spun-bonded long fiber or their mixture, and their mixture is formed by mixing low-melting polyester fiber, ES short fiber, two-component spun-bonded long fiber together or optionally a mixture of two.
因此,由于喷胶工艺是在熔喷纤维网24、25没有固结之前进行的,所以喷胶过程中,胶粘剂会不仅会粘附在熔喷纤维网24、25表面,也会渗透到与表面相邻的熔喷纤维网24、25内部,使得熔喷纤维网24、25表面及与表面相邻的熔喷纤维网24、25内部附着有胶粘剂,在熔喷纤维网24、25形成一层胶粘剂膜28、29,使得在使用时既阻止了表面熔喷纤维因摩擦而起毛、起绒,而且也进一步防止了中间层木浆短纤维掉出,在使用过程中出现'掉毛'现象。并且熔喷纤维网24、25含有纤维表面含有低熔点树脂的熔喷纤维20',该熔喷纤维20'中的低熔点树脂在热风烘箱中熔融,使得纤维之间会粘连在一起,既增加了擦拭巾的整体强度,也使得熔喷纤维排列更加致密,并且使得熔喷纤维网24、25表面附着的胶粘剂结合力更强。同时,中间层的木浆纤维网23中添加有热熔胶粘物质22,在热风烘箱中热熔胶粘物质22表面开始熔融,在一定程度上将中间层的木浆短纤维固定,使得木浆短纤难以移动,从而进一步防止所形成的擦拭巾在使用时不会出现'掉毛'的现象,增加擦拭巾的耐磨性。Therefore, since the glue spraying process is performed before the meltblown fiber webs 24 and 25 are not consolidated, the adhesive will not only adhere to the surface of the meltblown fiber webs 24, 25, but also penetrate into the surface during the glue spraying process. Adjacent meltblown fiber webs 24, 25 inside, so that the surface of the meltblown fiber webs 24, 25 and the meltblown fiber webs 24, 25 adjacent to the surface are attached with adhesive, forming a layer on the meltblown fiber webs 24, 25 The adhesive films 28 and 29 not only prevent the surface melt-blown fibers from being fluffed and raised due to friction, but also further prevent the short fibers of the wood pulp in the middle layer from falling out and appearing'fluffing' during use. In addition, the melt-blown fiber webs 24 and 25 contain melt-blown fibers 20' with low-melting resin on the fiber surface. The low-melting resin in the melt-blown fibers 20' is melted in a hot-air oven, so that the fibers will stick together, which increases The overall strength of the wipes also makes the melt-blown fiber arrangement more dense, and makes the adhesives attached to the surface of the melt-blown fiber webs 24 and 25 stronger. At the same time, a hot-melt adhesive material 22 is added to the wood pulp fiber web 23 of the middle layer. The surface of the hot-melt adhesive material 22 starts to melt in the hot-air oven to fix the wood pulp short fibers of the middle layer to a certain extent, so that the wood The short fibers are difficult to move, so as to further prevent the formed wipes from shedding during use, and increase the abrasion resistance of the wipes.
Claims (16)
- 一种擦拭巾,其特征在于:所述擦拭巾的上、下两层为熔喷纤维网,中间层为木浆纤维网,其中,所述熔喷纤维网表面及与表面相邻的熔喷纤维网内部均附着有胶粘剂,所述熔喷纤维网的熔喷纤维穿插于木浆纤维网中。 A wiper, characterized in that the upper and lower layers of the wiper are meltblown fiber webs, and the middle layer is a wood pulp fiber web, wherein the surface of the meltblown fiber web and the meltblown fiber web adjacent to the surface Adhesives are attached to the inside of the fiber web, and the melt-blown fibers of the melt-blown fiber web are inserted into the wood pulp fiber web.
- 如权利要求1所述一种擦拭巾,其特征在于:所述熔喷纤维网含有纤维表面为高熔点树脂的单组份熔喷纤维、纤维表面含有低熔点树脂的纤维或两者的共混纤维。The wipe of claim 1, wherein the melt-blown fiber web contains single-component melt-blown fibers with high melting point resin on the fiber surface, fibers with low melting point resin on the fiber surface, or a blend of both fiber.
- 如权利要求2所述一种擦拭巾,其特征在于:所述高熔点树脂和低熔点树脂的熔点之差≥20℃。The wipe of claim 2, wherein the difference between the melting point of the high melting point resin and the low melting point resin is ≥ 20°C.
- 如权利要求2所述一种擦拭巾,其特征在于:所述纤维表面含有低熔点树脂的纤维为单组份熔喷纤维、双组份熔喷纤维或两者相混合。The wiper according to claim 2, characterized in that the fiber containing low-melting resin on the fiber surface is a single-component melt-blown fiber, a two-component melt-blown fiber or a mixture of both.
- 如权利要求4所述一种擦拭巾,其特征在于:所述双组份熔喷纤维为双组份皮芯型熔喷纤维、双组份橘瓣型熔喷纤维或双组份并列型熔喷纤维。The wipe of claim 4, wherein the two-component meltblown fiber is a two-component sheath-core meltblown fiber, a two-component orange petal type meltblown fiber or a two-component side-by-side meltblown fiber. Spray fiber.
- 如权利要求1所述一种擦拭巾,其特征在于:所述胶粘剂为热熔胶或溶剂胶。The wiper according to claim 1, wherein the adhesive is hot melt glue or solvent glue.
- 如权利要求1所述一种擦拭巾,其特征在于:所述木浆纤维网的重量占所述擦拭巾总重量的百分比大于50%。8. The wipe of claim 1, wherein the weight of the wood pulp fiber web accounts for more than 50% of the total weight of the wipe.
- 如权利要求1所述一种擦拭巾,其特征在于:所述木浆纤维网的重量与所述擦拭巾总重量的百分比为65%~80%。8. The wipe of claim 1, wherein the weight of the wood pulp fiber web is 65% to 80% of the total weight of the wipe.
- 如权利要求1所述一种擦拭巾,其特征在于:所述木浆纤维网中含有热熔胶粘物质。The wipe of claim 1, wherein the wood pulp fiber web contains hot-melt adhesive material.
- 如权利要求9所述一种擦拭巾,其特征在于:所述热熔胶粘物质为低熔点聚酯纤维,ES短纤维、双组份纺粘长纤维或它们的混合物。The wipe of claim 9, wherein the hot-melt adhesive material is low-melting polyester fiber, ES short fiber, two-component spunbond long fiber or a mixture thereof.
- 一种如权利要求1所述擦拭巾的制造方法,其特征在于,包括以下步骤:A method for manufacturing a wipe as claimed in claim 1, characterized in that it comprises the following steps:(1)木浆通过开松辊开松打散,并在辅助气流的作用下通过喷管形成木浆纤维网;(1) The wood pulp is loosened and dispersed by the opening roller, and the wood pulp fiber web is formed through the nozzle under the action of the auxiliary airflow;(2)采用熔喷法工艺,将热塑性树脂加热,熔融,利用高温、高速热气流将从喷丝板中喷出的热塑性树脂的溶体细流吹散成纤维直径小于10um的纤维束,伴随热气流形成熔喷纤维网,并与木浆纤维网的两个侧面处相交汇,形成两侧为熔喷纤维网,中间为木浆纤维网的多层结构纤维网;(2) Using the melt-blowing process, the thermoplastic resin is heated and melted, and the melt stream of the thermoplastic resin sprayed from the spinneret is blown into fiber bundles with a fiber diameter of less than 10um by using high temperature and high-speed hot air flow. The airflow forms a meltblown fiber web, and it intersects with the two sides of the wood pulp fiber web to form a multi-layer structure fiber web with meltblown fiber webs on both sides and wood pulp fiber web in the middle;(3)通过喷胶工艺,将胶粘剂在高压热气流的作用下通过喷管将胶粘剂喷涂在两侧为熔喷纤维网,中间为木浆纤维网的多层结构纤维网的两个侧面;(3) Through the glue spraying process, the adhesive is sprayed on both sides of the melt blown fiber web through a nozzle under the action of high pressure hot air flow, and the two sides of the multi-layer structure fiber web of wood pulp fiber web in the middle;(4)喷胶后的多层结构纤维网通过加热装置将纤维网固结在一起,形成上、下两层为熔喷纤维网,中间层为木浆纤维网的擦拭巾,且熔喷纤维网表面及与表面相邻的熔喷纤维网内部均附着有胶粘剂。(4) After spraying, the multi-layer structure fiber web is consolidated by the heating device to form the upper and lower layers of meltblown fiber web, the middle layer is a wipe of wood pulp fiber web, and the meltblown fiber Adhesive is attached to the surface of the mesh and the inside of the meltblown fiber mesh adjacent to the surface.
- 如权利要求11所述一种擦拭巾的制造方法,其特征在于:所述步骤(2)中,分别将两种熔点之差≥20℃的热塑性树脂加热,熔融,利用高温、高速热气流将从喷丝板中喷出的热塑性树脂的溶体细流吹散成纤维直径小于10um的纤维束,伴随热气流形成熔喷纤维网,其中所述熔喷纤维网含有纤维表面为高熔点树脂的纤维、纤维表面含有低熔点树脂的纤维或两者的共混纤维。A method for manufacturing wipes according to claim 11, characterized in that: in the step (2), two thermoplastic resins with a melting point difference of ≥20°C are heated and melted, and the high temperature, high-speed hot air is used to The melt-blown stream of thermoplastic resin sprayed from the spinneret is blown into fiber bundles with a fiber diameter of less than 10um, and a melt-blown fiber web is formed with hot air flow, wherein the melt-blown fiber web contains fibers with a high melting point resin on the fiber surface , The fiber surface contains low-melting resin fiber or a blend of both fibers.
- 如权利要求11所述一种耐磨擦拭巾的制造方法,其特征在于:所述喷丝板上含有双组份喷丝孔。The method for manufacturing wear-resistant wipes according to claim 11, wherein the spinneret contains two-component spinneret holes.
- 如权利要求13所述一种耐磨擦拭巾的制造方法,其特征在于:所述喷丝板上的双组份喷丝孔为皮芯型、橘瓣型或并列型。The method for manufacturing wear-resistant wipes according to claim 13, wherein the two-component spinneret holes on the spinneret are of skin-core type, orange petal type or side-by-side type.
- 如权利要求11所述一种耐磨擦拭巾的制造方法,其特征在于:所述加热装置为热风烘箱、热轧辊或两者相结合。The method for manufacturing wear-resistant wipes according to claim 11, wherein the heating device is a hot air oven, a hot roll or a combination of both.
- 如权利要求11所述一种擦拭巾的制造方法,其特征在于:所述步骤(1)中,木浆通过开松辊开松打散,并与热熔胶粘物质混合后在辅助气流的作用下通过喷管形成含有热熔胶粘物质的木浆纤维网。A method for manufacturing wipes according to claim 11, characterized in that: in the step (1), the wood pulp is loosened and dispersed by the opening roller, and mixed with the hot-melt adhesive material in the auxiliary air flow Under the action, a wood pulp fiber web containing hot-melt adhesive material is formed through a nozzle.
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US17/262,211 US20210292945A1 (en) | 2019-01-15 | 2019-05-17 | Wipe and manufacturing method thereof |
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CN201910036118.2A CN109667063A (en) | 2019-01-15 | 2019-01-15 | A kind of cloth for cleaning and its manufacturing method |
CN201910036118.2 | 2019-01-15 |
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US (1) | US20210292945A1 (en) |
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WO2022222029A1 (en) | 2021-04-20 | 2022-10-27 | The Procter & Gamble Company | Laminate for use in an absorbent article |
WO2022222030A1 (en) | 2021-04-20 | 2022-10-27 | The Procter & Gamble Company | Fibrous layer with hotmelt coating composition |
WO2024152299A1 (en) | 2023-01-19 | 2024-07-25 | The Procter & Gamble Company | Methods for making three-dimensional webs |
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CN109667063A (en) * | 2019-01-15 | 2019-04-23 | 厦门延江新材料股份有限公司 | A kind of cloth for cleaning and its manufacturing method |
CN109629118A (en) * | 2019-01-15 | 2019-04-16 | 厦门延江新材料股份有限公司 | A kind of cloth for cleaning and its manufacturing method |
CN113445206A (en) * | 2021-07-19 | 2021-09-28 | 厦门延江新材料股份有限公司 | Composite wiping non-woven fabric and manufacturing method thereof |
CN113550068A (en) * | 2021-07-19 | 2021-10-26 | 厦门延江新材料股份有限公司 | Ultra-soft composite wiping non-woven fabric and manufacturing method thereof |
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CN109667063A (en) | 2019-04-23 |
US20210292945A1 (en) | 2021-09-23 |
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