WO2020145743A1 - Emulsion composition for cosmetics and cosmetic composition comprising same - Google Patents

Abstract

An emulsion composition for cosmetics, according to the present invention, comprises: a water phase part including water and a polyol; an oil phase part including oils as a first active ingredient; a polysilsesquioxane powder as a second active ingredient; and a sucrose ester emulsifier and a polyglyceryl emulsifier, alone or in combination.

Description

Cosmetic emulsion composition and cosmetic composition comprising same

The present invention relates to an emulsion composition for an oil-in-water (O/W) type cosmetic composition comprising an active ingredient useful for skin and stably dispersed in a cosmetic composition including a sheet mask and a cosmetic composition comprising the same will be.

1, 4-dioxane is a primary carcinogen produced by combining ethylene oxide or polyethylene glycol with other chemical components, and cannot be added at the time of manufacture, or other substances in cosmetic compositions, such as ethylene Oxide-based or polyethylene-glycol-based surfactants are generated in the process of being synthesized and may be contained in surfactants, so the Ministry of Food and Drug Safety does not allow detection of certain concentrations in each final product by dosage form.

Because 1, 4-dioxane is highly toxic, even short-term exposure can cause severe inflammation of the eyes, nasal mucosa, and throat, and may cause damage to the kidneys and nervous system when exposed to large amounts.

Therefore, research and development of a cosmetic emulsion composition having excellent skin care performance is performed without spilling 1 or 4-dioxine from the cosmetic composition into the skin.

On the other hand, since the cosmetic composition including the sheet mask is usually manufactured by a cold process, it is required that the useful active ingredients are easily dispersed in the cold process and have stability.

One aspect of the present invention provides an O/W type emulsion composition having high dispersibility and stability when mixed with a cosmetic composition including a sheet mask and a cosmetic composition comprising the same, without fear of releasing 1,4-dioxane to the skin when used It is aimed at.

Cosmetic emulsion composition according to the present invention,

An aqueous phase including water and polyol;

An oil phase part comprising oils as a first active ingredient;

Polysilsesquioxane powder as a second active ingredient; And

Characterized in that the sucrose ester-based emulsifier and the polyglyceryl-based emulsifier are contained alone or in combination.

At this time, the emulsion composition, it is preferable that the average particle size of the emulsion is O / W (Oil in Water) type consisting of 100 to 500 nanometers.

In addition, based on 10 parts by weight of the water, the polyol is 20 to 35 parts by weight, the oil phase is 40 to 55 parts by weight, the polysilsesquioxane-based powder is 5 to 20 parts by weight, the emulsifier is 4 to 15 parts by weight It is preferably included as a part.

Further, the oils may be silicone oil or ester oil.

At this time, the polysilsesquioxane (Polysilsesquioxane)-based powder is polypropyl silsesquioxane or polymethylsilsesquioxane, the average particle size is 2 to 15 microns, the specific surface area (specific surface area) is 10 to It is preferably 50 m2/g.

In addition, the sucrose ester-based emulsifier is preferably at least one or more substances selected from the group consisting of sucrose stearate, sucrose palmitate and sucrose laurate.

In addition, the polyglyceryl emulsifier includes polyglyceryl-10 laurate, polyglyceryl-10 myristate, and the weight ratio of the polyglyceryl-10 laurate and polyglyceryl-10 myristate is 40:60 to It is preferably 60:40.

Another aspect of the present invention is a method for preparing a cosmetic emulsion composition,

A first step of forming a first solution by dissolving, heating or dissolving the polyol with water, sucrose ester-based emulsifier and polyglyceryl-based emulsifier alone or mixed;

As a first active ingredient, an oil and a polysilsesquioxane-based powder as a second active ingredient are mixed with the oil to make a second solution, and the weight ratio of the first solution and the second solution is 1.0: 1.0 to 1.0 : Second step to make 3.0;

A third step of cooling the solution after the second step; And

And a fourth step of forming an O/W emulsion while adding water to the solution of the third step.

At this time, in the second step, it is preferable to mix the oils at 70 degrees C for 3 hours or more.

Another aspect of the present invention is a cosmetic composition,

The water phase containing water and polyol, the oil phase containing oil as the first active ingredient, the polysilsesquioxane powder as the second active ingredient, and sucrose ester emulsifier and polyglyceryl emulsifier alone or mixed An emulsion comprising an emulsifier; And

It is characterized by having a composition of a water phase containing at least one or more substances selected from the group consisting of perfumes, preservatives, thickeners, polyols, moisturizers and solubilizers.

At this time, it is preferable to include 0.5 to 3 wt% of the emulsion, and 97 to 99.5 wt% of the composition of the aqueous phase.

Another aspect of the present invention, a method of manufacturing a cosmetic composition,

A first step of forming a first solution by dissolving water and sucrose ester-based emulsifiers and polyglyceryl-based emulsifiers in a polyol alone or after mixing and warming;

As a first active ingredient to be used as a disperse phase, a second solution is prepared by mixing an oil or a polysilsesquioxane-based powder which is a second active ingredient together with the oils, and the ratio of the first solution to the second solution is 1.0: 1.0 to 1.0: a second step of mixing to be 3.0;

A third step of cooling the solution after the second step;

A fourth step of forming an O/W emulsion while adding water to the solution of the third step; And

A fifth mixing the O/W emulsion with a composition of a water phase containing at least one substance selected from the group consisting of fragrances, preservatives, thickeners, polyols, moisturizers, and solubilizers at 35 degrees C or less It characterized in that it comprises a step.

The O/W type emulsion composition according to an embodiment of the present invention is an emulsifier such as sucrose ester, more preferably an edible sucrose ester, so there is no fear of releasing 1,4-dioxane, cosmetic including sheet mask It is stably dispersed even during manufacture, effectively maintaining the activity of oil-soluble active ingredients, and has an effect of providing a skin care feeling excellent in moisturizing power, excellent spreadability, and soft texture.

1 is a sample photograph after preparation of Examples and Comparative Examples of the present invention.

2 and 3 are 200 and 1000 magnification micrographs of the emulsion composition according to Example 1 of the present invention.

4 is a 1000-magnification micrograph of Comparative Example 1 of the present invention.

5 is a 1000-magnification micrograph of Example 2 of the present invention.

Before describing the present invention in detail below, it is understood that the terms used herein are only for describing specific embodiments and are not intended to limit the scope of the present invention, which is limited only by the scope of the appended claims. shall. All technical and scientific terms used in this specification have the same meaning as commonly understood by those skilled in the art unless otherwise stated.

Throughout this specification and claims, the term "comprise, comprises, comprising," unless otherwise stated, means including the recited article, step or group of articles, and steps, and any any other article. It is not meant to exclude a step or group of things or a group of steps.

On the other hand, various embodiments of the present invention can be combined with any other embodiments, unless otherwise indicated. Any feature indicated as particularly preferred or advantageous may be combined with any other feature or features indicated as preferred or advantageous.

The active ingredient in the present specification is a component that imparts functionality to a basic cosmetic composition, and refers to a component that exhibits effects such as spreadability, softness, absorption, stickiness reduction, moisturizing, whitening, and line blurring.

Hereinafter, the O/W type emulsion composition according to an aspect of the present invention will be described in detail.

The O/W type emulsion composition that can be used in the embodiment of the present invention preferably has a particle size of 100 to 500 nanometers, an aqueous phase containing water and polyol, and an oil as a first active ingredient as a dispersed phase. A powder is included as an oil phase part and a second active ingredient, and contains an emulsifier for stabilizing the emulsion.

As the first active ingredient, silicone oil or ester oil may be used as the oil. The oil is stored inside the emulsion and then delivered to the skin epidermal layer upon contact with the skin.

As silicone oils, dimethicones having high refractive index properties such as phenyltrimethicone and diphenyldimethicone or having low viscosity characteristics may be used. For example, the refractive index range is 1.4 to 1.5, and the viscosity is preferably 5 cSt to 20 cSt (20 degrees C).

As the ester oil, triethylhexanoin, ethylhexylhexanoate, caprylyl/capric triglyceride, and the like can be used.

In particular, the embodiment of the present invention may further include a polysilsesquioxane-based powder as a second active ingredient together with the oil. The polysilsesquioxane powder may have an effect of reducing skin wrinkles and increasing the focusing effect.

For example, polypropylsilsesquioxane, polymethylsilsesquioxane, or the like can be used. Polysilsesquioxane-based powders have an average particle size of 2 to 15 microns, a specific surface area of 10 to 50 m2/g, a linseed oil absorption rate of 50 to 100 ml/g, specific gravity (specific gravity) (25℃) is suitable for white spherical powders of about 1.2 to 1.4. Polysilsesquioxane-based powders provide a line blurring and skin brightening effect.

Polysilsesquioxane (Polysilsesquioxane)-based powder may be used in the range of 7.05 to 15.38 wt% based on the total weight fd of the cosmetic emulsion composition.

The emulsifier for forming the emulsion uses a nonionic emulsifier, and either a sucrose ester-based emulsifier or a polyglyceryl-based emulsifier is used alone or in combination. Sucrose ester-based emulsifiers are preferably one or two or more of sucrose stearate, sucrose palmitate, and sucrose laurate, when mixed alone, 5 to 15%, and 4 to 12% when blending the two together It is suitable to use within the range of. The combination of sucrose laurate and sucrose stearate is more preferable, and the blending ratio of the product is preferably between 40:60 and 60:40.

The polyglyceryl nonionic emulsifier synthesizes 1,4-dioxane by reaction such as ethylene oxide or polyethylene glycol so that the release source material is not contained. For example, polyglyceryl-4 laurate, polyglyceryl-10 laurate, polyglyceryl-10 myristate, polyglyceryl-10 diisostearate, polyglyceryl-10 oleate, polyglyceryl- 10 caprylate/caprate) or the like can be used alone or in combination.

The O/W type emulsion composition that can be used in the examples of the present invention is based on 10 parts by weight of water, 20 to 35 parts by weight of polyol, 40 to 55 parts by weight of oil, polysilsesquioxane powder 5 To 20 parts by weight, and 4 to 15 parts by weight of emulsifier.

When the emulsifier contains less than 4, emulsification cannot be formed, and when the emulsifier is 15 or more, the viscosity of the emulsion is too high, and the usability is rather deteriorated.

Since the emulsion prepared as described above has no fear of releasing 1,4-dioxane even after being blended into a cosmetic composition, it is possible to safely apply a cosmetic including a sheet mask to the face, etc., and polysilsesquioxane powder in the composition There is an effect that the active ingredient delivery ability is exerted without change because it does not sink and other useful active ingredients are stably maintained in the cosmetic composition.

In addition, the emulsion composition protects the polymethylsilsesquiionic acid powder by inclusion, and in the process of physically applying it to the skin, the emulsion breaks and the polymethylsilsesquioxane powder spills on the skin surface, and silicone oil or low-viscosity ester oil The back exerts its own function, and is delivered to the skin epidermal layer to provide performance such as softness and silkiness, and it can have a function of alleviating skin wrinkles and increasing the focusing effect with the polymethylsilsesquioxane powder effect.

It has been recognized that it is difficult to inject useful active ingredients into a cosmetic composition including a sheet mask without the concern of releasing 1,4-dioxane, but in the embodiment of the present invention, the particle size is 100 to 500 nanometers, The aqueous phase containing water as the continuous phase, the oil phase containing the oil as the first active ingredient as the dispersed phase, and the powder as the second active ingredient are included, and the emulsion composition using sucrose ester as the emulsifier contains high dispersion and powder. It does not sink and has high stability, and it is possible to prepare a cosmetic composition without being released from 1,4-dioxane.

In addition, the above-described emulsion composition has an advantage that can be mixed in a non-heating process (cold process) required when preparing a cosmetic composition.

The cosmetic composition according to another aspect of the present invention includes the above-described O/W emulsion composition, and a composition of a water phase containing fragrance, extract, adenosine, propylene glycol, water-soluble silicone, ceramide, etc., which are commonly used in cosmetic compositions. do. At this time, as described above, the O/W emulsion composition of the embodiment of the present invention can be mixed in a non-heating process (cold process) when blended in a cosmetic composition.

The cosmetic composition presented in the Examples of the present invention is 0.5 to 3 wt%, 0.7 to 2 wt%, or 1 to 1.5 wt% of the aforementioned O/W emulsion composition, and 97 to 99.5 wt%, 98 to 99.3 wt% of the aqueous phase composition , Or 98.5 to 99 wt%. If it is out of the above range, there is a fear that there is a lack of spreadability, moisture, whitening, soft feeling of use or excessive stickiness.

Hereinafter, a method for manufacturing a cosmetic composition for a sheet mask, which is another aspect of the present invention, will be described. The method of manufacturing a cosmetic composition for a sheet mask includes a first step, a second step, a third step, a fourth step, and a fifth step.

The first step is a step in which water and an emulsifier are added to the polyol to warm and dissolve to form a first solution. At this time, the emulsifier included is a sucrose ester-based emulsifier, it is preferable to mix one or more of sucrose stearate, sucrose palmitate, and sucrose laurate, and when used alone, 5 to 15%, the two together When blending, it is suitable to use within the range of 4 to 12%. In a range lower than the above range, emulsification is not formed, and when the content is higher than the above range, stickiness is excessive and emulsion stability becomes poor.

As an example, a combination of sucrose laurate and sucrose stearate is more preferable, and the compounding weight ratio of the product is preferably between 40:60 and 60:40. If it is out of the above-mentioned range, it is difficult to form an emulsion and the emulsion stability is also poor.

The second step is a step in which a second solution is prepared by mixing an oil component or a powder as an active ingredient to be used as a dispersed phase in the O/W emulsion, and then introduced into the first solution of the first step. At this time, the second solution is warmed and slowly added to the first solution. The oil component is preferably mixed at 65 to 75 degrees C, preferably at 70 degrees for 3 hours or more. The ratio of the first solution and the second solution is preferably 1.0:1.0 to 1.0:3.0.

If it is outside the above range, even if an emulsion is not formed or formed, the phases are unstable due to long-term storage or storage conditions. In addition, it is more preferable to input at a high temperature stage. At this time, diphenyldimethicone, triethylhexanoin, polymethylsilsesquioxane, and the like are used as active ingredients.

The third step is cooling. The first solution and the second solution mixed in the third step are mixed. At this time, the temperature is preferably cooled to 40 degrees C or less.

The fourth step is a step of forming an O/W emulsion while adding purified water. It is desirable to proceed slowly, and a speed of about 1.5 kg per minute is desirable. The emulsion composition prepared by the first to fourth steps is according to the D-phase emulsion manufacturing method.

The fifth step is a step of mixing the oil-in-water (O/W) emulsion formed in the fourth step with the water phase sheet mask contents in a non-heating process. At this time, the content of the sheet mask of the water phase includes commonly used fragrances, preservatives, thickeners, polyols, moisturizers, solubilizers, and the like. Preservatives include phenoxyethanol, hexanediol, ethylhexylglycerin, etc., and thickeners include hydroxyethylcellulose, fibrem/Madecadiene cross polymer, and polyols are dipropylene And glycols, propylene glycol, butylene glycol, and caprylyl glycol. Examples of moisturizing agents include sodium hyaluronate, trehalose, and polyglyceryl-4 caprate and polyglyceryl-6 as solubilizers. Caprate, polyglyceryl-3 cocoate, polyglyceryl-6 ricinoleate alone or mixed, or may further include sorbitan oleate decyl glucoside cross polymer.

The fifth step of mixing the O/W emulsion with the contents of the above-described water phase proceeds with a cold process at a temperature of 35°C or less, and PSQ (polymethylsilsesquioxane), an active ingredient useful in this embodiment. The powder is used with an O/W emulsion to have high dispersion efficiency and can be mixed in the above temperature range.

In addition, the contents of the water phase, carbomer (carbomer), FBM / M-adecadiene cross polymer, etc., 0.1 to 0.3%, polyol may further include 5 to 15% by weight, carbomer, FBM / MADECadiencross polymer may serve to increase the stability of polymethylsilsesquioxane.

At this time, each composition of the contents of the water phase can be made variously according to the characteristics of the cosmetic material including the sheet mask to be manufactured, and is not limited to a specific composition.

As in Examples A and B, O/W emulsions according to examples of the present invention were prepared with the composition shown in Table 1.

Furtherance	Water (parts by weight)	Polyol (parts by weight)	Oil (parts by weight)	PSQ (parts by weight)	Emulsifier (parts by weight)
Example A: Oil: diphenyldimethicone, triethylhexanoin PSQ: polymethylsilsesquioxane powder emulsifier: (combination of 50:50 weight ratio of polyglyceryl-10 laurate and polyglyceryl-10 myristate)	10	23	42	6	4
Example B: oil: diphenyldimethicone, triethylhexanoin PSQ: polymethylsilsesquioxane powder emulsifier: sucrose ester emulsifier (50:50 combination of sucrose laurate and sucrose stearate)	10	34	51	20	15

To compare with Examples A and B, Comparative Examples A and B were prepared with the composition shown in Table 2.

Furtherance	Water (parts by weight)	Polyol (parts by weight)	Oil (parts by weight)	PSQ (parts by weight)	Emulsifier (parts by weight)
Comparative Example A: Oil: Dimethicone, Diphenyldimethicone, Triethylhexanoin PSQ: Polymethylsilsesquioxane powder Emulsifier: PEG-40 Steareth, Steareth-21	50	-	20	15	10
Comparative Example B: Oil: dimethicone, diphenyldimethicone, triethylhexanoin emulsifier: PEG-40 Steareth, Steareth-21	10	34	51	-	15

In addition, by applying to the formulation using the O / W emulsion of Examples A, B and Comparative Examples A, B prepared by the production method of the present invention described above, the cosmetic composition Examples 1, 2 and Comparative Example 1 of the following composition, 2 and 3 were prepared. 1 is a sample photograph of Examples 1 and 2 and Comparative Examples 1 and 2, and FIGS. 2 and 3 are O/W emulsion micrographs containing a nonionic emulsifier and PSQ, and PSQ of 2 to 15 microns (poly It can be seen that the particles of methylsilsesquioxane) are stably dispersed around the emulsified particles. The composition of the prepared Examples 1, 2 and Comparative Examples 1, 2, 3 are shown in Table 3 below.

Ingredient name	Comparative Example 1 (wt%)	Comparative Example 2 (wt%)	Comparative Example 3 (wt%)	Example 1 (wt%)	Example 2 (wt%)
Purified water	76.33	73.33	73.33	74.83	73.33
5M/AMDE Cardien Cross Polymer	0.15	0.15	0.15	0.15	0.15
Xanthan gum	0.05	0.05	0.05	0.05	0.05
1,3-butylene glycol	8.0	8.0	8.0	8.0	8.0
glycerin	5.0	5.0	5.0	5.0	5.0
Betaine	0.3	0.3	0.3	0.3	0.3
Hydroxyacetophenone	0.55	0.55	0.55	0.55	0.55
Caprylyl glycol	0.3	0.3	0.3	0.3	0.3
Dipropylene glycol	2.0	2.0	2.0	2.0	2.0
Niacinamide	2.0	2.0	2.0	2.0	2.0
Hydrolyzed collagen	0.1	0.1	0.1	0.1	0.1
Dipanthenol	0.01	0.01	0.01	0.01	0.01
Tromethamine	0.1	0.1	0.1	0.1	0.1
Dipotassium glyceride	0.01	0.01	0.01	0.01	0.01
Green Tea Extract	5.0	5.0	5.0	5.0	5.0
Spices	0.1	0.1	0.1	0.1	0.1
Emulsion Composition Example A	-	-	-	1.5	-
Emulsion composition example B	-	-	-	-	3.0
Emulsion composition comparative example A	-	3.0	-	-	-
Emulsion composition comparative example B	-	-	3.0	-	-

Experimental Example 1

20 grams of the samples prepared in Examples 1 to 3 were taken and applied to a sheet mask (40 grams, produced at a mixing ratio of 90% Tencel, 10% cotton), and the sheet mask impregnated with the sample was applied to the face about 15 After attaching for a minute, it was peeled off and the usability evaluation was performed. As can be seen from Table 4, it was confirmed that the results of the evaluation of the feeling of use in the formulations of Examples 1 and 2 dominate. For 30 female employees in the company, very bad was evaluated as 1 point, and weekly good was rated at 5 points, and the average value was calculated.

*1: In order to be utilized in the present invention, the inventors directly manufactured and used it.

Evaluation items		Immediately after removal
		Spreadability	Soft	Absorption	Stickiness reduction effect	Moisturizing	Whitening	Line Burring
Comparative example	One	2	2	1.5	2	2	0	One
	2	3.4	3	3	3	3	4	3
	3	4	4	5	3.5	4	One	One
Example	One	4	4	4.5	4.0	4	4	3.5
	2	5	5	5	4.5	5	5	4

Experimental Example 2

After 30 minutes of removing the sheet mask of Experimental Example 1, the usability was evaluated again based on the evaluation items in Table 5. As can be seen from the evaluation table, it was confirmed that the activity of the oil-soluble active ingredients was effectively exerted and maintained.

Evaluation items		after drying
		Spreadability	Soft	Absorption	Stickiness reduction effect	Moisturizing	Whitening	Line Burring
Comparative example	One	2.2	2	One	2	2	0	One
	2	3	3	2	3	3	4	3
	3	4	4	4	3.5	5	One	One
Example	One	4	4	4	4.0	4	4	3.5
	2	5	5	4.5	4.5	5	5	4

Experimental Example 3: Dioxane Detection Experiment

In Experimental Examples 1 to 3 described above, a detection experiment was performed to determine whether 1,4-dioxane was detected in the cosmetic composition of the present invention.

		Storage condition	1,4-dioxane release effect (ppm)
			15 days later	30 days later	60 days later	120 days later
Comparative example	One	Room temperature	Non-detection	Non-detection	Non-detection	Non-detection
	2	Room temperature	7ppm	7ppm	10ppm	10ppm
	3	Room temperature	Non-detection	Non-detection	Non-detection	Non-detection
Example	One	Room temperature	Non-detection	Non-detection	Non-detection	Non-detection
	2	Room temperature	Non-detection	Non-detection	Non-detection	Non-detection

As described above, by using the O/W emulsion of edible sucrose ester in the composition of the present invention, there is no concern about 1,4-dioxane releasing worry and provides excellent skin care feeling with excellent moisturizing power, excellent spreading property, and soft texture after removing the sheet. On the other hand, the conditions of the analytical instrument of 1,4-dioxane are shown in Table 5. The gas chromatograph confirms the detection and the detection limit is 5ppm.

device	Item	Analysis condition/specification
GC	System Column Injector Volume Injection Flow Rate Mobile Phase Oven Temperature Detector	YL 6000 series GCHP-1(30mx0.25mmx0.25㎛) 10μl Split 250℃, Split Ratio 20: 12.0ml/min.Methanol: Water = 70%:30%70℃ for 3min., Ramp 20℃, 150℃ FID 250℃

Features, structures, effects, and the like exemplified in each of the above-described embodiments may be combined or modified with respect to other embodiments by a person having ordinary knowledge in the field to which the embodiments belong. Therefore, the contents related to such combinations and modifications should be interpreted as being included in the scope of the present invention.

For example, the above-described cosmetic emulsion composition of the present invention is selected from a basic cosmetic composition, lipstick, makeup base, or foundation selected from softening lotion, nutrient makeup, lotion, cream, pack, gel, patch or spray (mist). Selected color cosmetics and sunscreen cosmetics, or hair tonics, gels, mousses, and other hairdressers, compositions, shampoos, rinses, body cleansers, toothpastes, cleaning agents selected from mouthwashes, or hair tonics, gels, wools, hair dyes It may be included in a cosmetic composition for hair selected from.

Claims (12)

1. An aqueous phase including water and polyol;

   An oil phase part comprising oils as a first active ingredient;

   Polysilsesquioxane powder as a second active ingredient; And

   A sucrose ester-based emulsifier and a polyglyceryl-based emulsifier are used alone or in mixture for a cosmetic emulsion composition.
2. According to claim 1,

   The emulsion composition is an oil-in-water (O/W, Oil in Water) type emulsion composition for cosmetic having an average particle size of 100 to 500 nanometers.
3. According to claim 2,

   Based on 10 parts by weight of the water, the polyol is 20 to 35 parts by weight, the oil phase is 40 to 55 parts by weight, the polysilsesquioxane-based powder is 5 to 20 parts by weight, and the emulsifier is included in 4 to 15 parts by weight Cosmetic emulsion composition.
4. According to claim 3,

   The oils are silicone oil or ester oil cosmetic emulsion composition.
5. According to claim 4,

   The polysilsesquioxane-based powder is polypropylsilsesquioxane or polymethylsilsesquioxane, the average particle size is 2 to 15 microns, and the specific surface area is 10 to 50 m2/ g cosmetic emulsion composition.
6. The method of claim 5,

   The sucrose ester-based emulsifier is a cosmetic emulsion composition for at least one or more substances selected from the group consisting of sucrose stearate, sucrose palmitate and sucrose laurate.
7. The method of claim 5,

   The polyglyceryl-based emulsifier includes polyglyceryl-10 laurate and polyglyceryl-10 myristate, and the weight ratio of the polyglyceryl-10 laurate and polyglyceryl-10 myristate is 40:60 to 60: 40-person cosmetic emulsion composition.
8. A first step of adding water, sucrose ester-based emulsifier and one or more emulsifiers selected from polyglyceryl-based emulsifiers and heating to dissolve them to form a first solution;

   As a first active ingredient, an oil and a polysilsesquioxane-based powder as a second active ingredient are mixed with the oil to make a second solution, and the weight ratio of the first solution and the second solution is 1.0: 1.0 to 1.0 : Second step to make 3.0;

   A third step of cooling the solution after the second step; And

   Method of manufacturing a cosmetic emulsion composition comprising; a fourth step of forming an O / W emulsion while adding water to the solution of the third step.
9. The method of claim 8,

   In the second step, the oil is a method for preparing a cosmetic emulsion composition for mixing at 70°C for 3 hours or more.
10. Water phase containing water and polyol, oil phase containing oil as the first active ingredient, polysilsesquioxane powder as the second active ingredient, and sucrose ester-based emulsifier and polyglyceryl emulsifier alone or mixed Emulsion comprising an emulsifier; And

    A cosmetic composition having a water phase composition containing at least one or more substances selected from the group consisting of perfumes, preservatives, thickeners, polyols, moisturizers and solubilizers.
11. The method of claim 10,

    0.5 to 3 wt% of the emulsion; And

    A cosmetic composition comprising 97 to 99.5 wt% of the composition of the aqueous phase.
12. A first step of forming a first solution by dissolving water and sucrose ester-based emulsifiers and polyglyceryl-based emulsifiers in a polyol alone or after mixing and warming;

    As a first active ingredient to be used as a disperse phase, a second solution is prepared by mixing an oil or a polysilsesquioxane-based powder that is a second active ingredient together with the oils, and the ratio of the first solution to the second solution is 1.0: 1.0 to 1.0: a second step of mixing to be 3.0;

    A third step of cooling the solution after the second step;

    A fourth step of forming an O/W emulsion while adding water to the solution of the third step; And

    A fifth mixing the O/W emulsion with a composition of a water phase containing at least one or more substances selected from the group consisting of perfumes, preservatives, thickeners, polyols, moisturizers and solubilizers at 35 degrees C or less Method of manufacturing a cosmetic composition comprising a step.

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