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WO2019138631A1 - Beer-like effervescent beverage and production method thereof - Google Patents

Beer-like effervescent beverage and production method thereof Download PDF

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Publication number
WO2019138631A1
WO2019138631A1 PCT/JP2018/038492 JP2018038492W WO2019138631A1 WO 2019138631 A1 WO2019138631 A1 WO 2019138631A1 JP 2018038492 W JP2018038492 W JP 2018038492W WO 2019138631 A1 WO2019138631 A1 WO 2019138631A1
Authority
WO
WIPO (PCT)
Prior art keywords
beer
beverage
foamable
bitterness
carbon dioxide
Prior art date
Application number
PCT/JP2018/038492
Other languages
French (fr)
Japanese (ja)
Inventor
順 久保田
慎介 伊藤
Original Assignee
アサヒビール株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by アサヒビール株式会社 filed Critical アサヒビール株式会社
Publication of WO2019138631A1 publication Critical patent/WO2019138631A1/en

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Classifications

    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L2/00Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L2/00Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
    • A23L2/52Adding ingredients
    • A23L2/54Mixing with gases
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L2/00Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
    • A23L2/52Adding ingredients
    • A23L2/56Flavouring or bittering agents
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12CBEER; PREPARATION OF BEER BY FERMENTATION; PREPARATION OF MALT FOR MAKING BEER; PREPARATION OF HOPS FOR MAKING BEER
    • C12C11/00Fermentation processes for beer
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12GWINE; PREPARATION THEREOF; ALCOHOLIC BEVERAGES; PREPARATION OF ALCOHOLIC BEVERAGES NOT PROVIDED FOR IN SUBCLASSES C12C OR C12H
    • C12G3/00Preparation of other alcoholic beverages
    • C12G3/02Preparation of other alcoholic beverages by fermentation
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12GWINE; PREPARATION THEREOF; ALCOHOLIC BEVERAGES; PREPARATION OF ALCOHOLIC BEVERAGES NOT PROVIDED FOR IN SUBCLASSES C12C OR C12H
    • C12G3/00Preparation of other alcoholic beverages
    • C12G3/04Preparation of other alcoholic beverages by mixing, e.g. for preparation of liqueurs

Definitions

  • the present invention relates to a beer-like effervescent beverage having good bitterness and good crispness despite having a high bitterness value, and a method for producing the same.
  • Priority is claimed on Japanese Patent Application No. 2018-004543, filed January 15, 2018, the content of which is incorporated herein by reference.
  • Beer-like effervescent beverages such as beer and low-malt beer have a unique bitter taste and flavor, and are characterized mainly by thirst and drinkability (the ability to keep drinking many glasses without getting tired).
  • Many methods have been reported to improve the flavor and quality of a beer-like effervescent beverage by changing the types and combinations of raw materials typified by malt and hop, and the production method.
  • exhilaration is an important quality for beer drinkability, and attempts have been made to enhance exhilaration.
  • Patent Document 1 discloses a method that can enhance the carbonation stimulation of a carbonated beverage without increasing the carbon dioxide pressure by adjusting the content of a specific hydroxy acid ester.
  • the bitter bitter beer withdraws its bitterness and remains in the mouth, resulting in loss of beer refreshing feeling, refreshing aftertaste, crispness, etc., and the beer's palatability and drinkability decline.
  • a method for improving the bitterness to be followed in a beer with strong bitterness for example, in Patent Document 2, for beer having a bitterness value of 30 BU or more, by setting the VDK concentration to a specific range, the aftertaste is crispy and clear It is described that the well-balanced taste, bitterness and crispness can be improved and the drinkability can be enhanced.
  • An object of the present invention is to provide a beer-like effervescent beverage having good bitterness and good crispness despite the high bitterness value, and a method for producing the same.
  • the present inventors have found that, in a beer-like effervescent beverage having a high bitterness value of 10 BU or more, the post-bitter taste can be improved by increasing the carbon dioxide content, and the present invention has been completed.
  • the beer-like foamable beverage, the method for producing a beer-like foamable beverage, and the method for improving the aftertaste of bitterness of the beer-like foamable beverage according to the present invention are the following [1] to [13].
  • [1] A beer-like effervescent beverage having a bitter taste value of 10 BU or more and a carbon dioxide gas content at 20 ° C. of 3.7 GV or more.
  • [2] The beer-like foamy beverage according to the above [1], which has a bitterness value of 30 BU or less.
  • a method for producing a beer-like foamable beverage having a bitterness value of 10 BU or more A method for producing a beer-like foamy beverage, wherein the carbon dioxide gas content at 20 ° C. of the beverage is adjusted to 3.7 GV or more.
  • beer-like means a taste pronounced of flavored beers regardless of the product name and display. That is, a beer-like effervescent beverage (beer-like effervescent beverage) has an alcohol content, presence or absence of use of malt and hop, and a flavor / taste equivalent to or similar to beer, regardless of the presence or absence of fermentation. It refers to an effervescent beverage having a texture and high thirst and drinkability. That is, the beer-like effervescent beverage according to the present invention may be an alcoholic beverage, and may be a so-called non-alcoholic beverage or a low alcoholic beverage having an alcohol content of less than 1% by volume.
  • the beverage may be malt-based, beverage may not be malt-based, or may be a beverage produced through a fermentation process, or beverage produced without a fermentation process.
  • beer-like effervescent beverages include beer, low-malt beer using malt as a raw material, effervescent alcoholic beverages that do not use malt, low alcohol effervescent beverages, non-alcohol beer and the like.
  • it may be a liqueur obtained by mixing a beverage produced from malt as a raw material through a fermentation process with an alcohol-containing distillate.
  • the alcohol-containing distillate is a solution containing an alcohol obtained by a distillation operation, and may be, for example, a raw material alcohol, and may be a distillation of spirits, whiskey, brandy, vodka, lamb, tequila, gin, shochu, etc. Alcohol can be used.
  • bitter taste after squeaky means that the bitter taste has a crisp aftertaste, that is, the bitterness remaining difficulty after drinking.
  • Good after bitter taste means that no bitter taste remains after drinking, and “bad after bitter taste” means that bitter taste remains in the mouth for a long time after drinking.
  • the beer-like foamable beverage according to the present invention has a bitterness value of 10 BU or more, and a carbon dioxide gas content at 20 ° C. of 3.5 GV or more. Beer-like effervescent beverages with high bitter value are poor in crispiness after bitter taste, and the refreshing property is impaired and the drinkability tends to be low.
  • the bitterness value is high by setting the carbon dioxide content to a higher gas pressure than the carbon dioxide content (about 2.9 GV) of a general beer. After being bitter, the crispness is improved, and the feeling of exhilaration and drinkability are high.
  • the carbon dioxide gas content of the beer-like foamable beverage according to the present invention is not particularly limited as long as the carbon dioxide gas content at 20 ° C. is 3.5 GV or more.
  • As the carbon dioxide gas content at 20 ° C. of the beer-like effervescent beverage according to the present invention is more preferably 3.7 GV or more, and more preferably 3.8 GV or more, since the aftertaste improvement effect of bitter taste is more sufficiently obtained.
  • 5.0 GV or less is preferable and, as for the carbon dioxide gas content in 20 degreeC of the beer-like foamable drink which concerns on this invention, 4.4 GV or less is more preferable.
  • the carbon dioxide content of the beer-like effervescent beverage can be adjusted to 3.5 GV or more by injecting carbon dioxide directly into the beverage or by producing more carbon dioxide in fermentation.
  • the carbon dioxide gas content of the beer-like foamable beverage can be measured, for example, using a beverage analyzer “Orbisphere 6110 Beverage Analyzer” (manufactured by HACH).
  • the bitterness value of the beer-like foamable beverage according to the present invention is not particularly limited as long as it is 10 BU or more, and can be appropriately adjusted according to the required product quality. If the bitter taste of the beer-like foamable beverage is too strong, the bitter taste value of the beer-like foamable beverage according to the present invention may be 10 BU or more, because it may be difficult to obtain an improvement effect after the bitter taste due to high gas pressure. 33 BU or less is preferable, 10 BU or more and 30 BU or less is more preferable, 13 BU or more and 28 BU or less is more preferable, 15 BU or more and 28 BU or less is more preferable, and 15 BU or more and 25 BU or less is particularly preferable.
  • the bitterness value is an index of bitterness given by hop-derived substances containing isohumulone as a main component, and the bitterness value of the beer-like effervescent beverage can be determined, for example, by the EBC method (Beer Brewery Association: “Beer analysis method” 8 .15 1990). Specifically, acid was added to the sample, followed by extraction with isooctane, and the absorbance at 275 nm of the isooctane layer obtained after centrifugation was measured using pure isooctane as a control multiplied by a constant (50) (BU) (BU) ).
  • a bitterness component mainly derived from hops such as iso- ⁇ acid is preferable, and one having iso- ⁇ acid as a main component of bitterness is more preferable.
  • hops or processed hops as a raw material, it is possible to produce a beer-like foamy beverage containing bitter taste components derived from hops.
  • the hops used as the raw material may be raw hops, dry hops or hop pellets.
  • the hop extract which extracted the bitterness component from the hop may be sufficient.
  • it may be a processed hop product containing a component obtained by isocyanation of a bitter taste component in hops such as isophized hop extract, tetrahydroisohumulone, hexahydroisohumulone and the like.
  • the beer-like effervescent beverage according to the present invention preferably contains an isoated hop extract.
  • the isopinated hop extract is a product obtained by performing an isotropization treatment in which a magnesium salt is added as a catalyst to hop extract and heating is performed, and an iso-body such as iso- ⁇ -acid obtained is purified.
  • a beer-like effervescent beverage containing an isopinated hop extract is more than a beer-like effervescent beverage containing a hop extract or a beer-like effervescent beverage containing a bitter taste component derived from hops by boiling treatment using hops as a raw material. The rest is strong after bitter taste in the oral cavity, and poor after bitter taste. For this reason, in the beer-like effervescent beverage manufactured using the isocyanicized hop extract as a bitter taste agent, the after-taste improvement effect of the bitter taste by the high gas pressure of the present invention is more fully exhibited.
  • the bitter taste component contained in the beer-like foamable beverage according to the present invention is not particularly limited as long as it exhibits a bitter taste similar to or similar to beer.
  • the beer-like effervescent beverage according to the present invention may contain, in addition to or in place of the bitter component derived from hop, a bitter component other than the bitter component derived from hop.
  • bittering agent containing a bitterness component other than a bitterness component derived from hop magnesium salt, calcium salt, tributyl citrate, triethyl citrate, naringin, quassin, iso alpha acid, tetra iso alpha acid, beta acid Oxides, quinine, momordesine, quercitrin, theobromine, caffeine and other bitter taste imparting ingredients, and bitter gourd, sembry tea, bitter green tea, bitter melon tea extract, niga yogi extract, gentiana extract, kuwasha extract, quina extract (quinine extract) Etc. are typically mentioned.
  • the bitterness value of the beer-like effervescent beverage according to the present invention can be adjusted by appropriately adjusting the amounts of hop, processed hop product and bittering agent other than hop as raw materials.
  • the beer-like effervescent beverage according to the present invention is a fermented beer-like effervescent beverage manufactured through a fermentation step with yeast and hops are used as a raw material, the amount of hops used is increased, or iso ⁇ This can be enhanced by using hop varieties with relatively high acid content as raw materials.
  • the bitterness value of the malt-fermented beverage can also be increased by adding hop during or after the fermentation process to extract the bitter component.
  • the beer-like effervescent beverage according to the present invention may be an alcoholic beverage or a non-alcoholic beverage.
  • alcohol slightly alleviates the bitter taste.
  • the alcohol concentration of the beer-like foamable beverage according to the present invention is 1% by volume or less, preferably 0.5 volume Less than% is more preferable, less than 0.05% by volume is more preferable, and 0% by volume (containing no alcohol as a raw material) is particularly preferable.
  • the beer-like effervescent beverage according to the present invention may be a beverage manufactured using malt as a raw material, or may be a beverage manufactured without using malt as a raw material.
  • the beer-like effervescent beverage manufactured using malt as a raw material contains a large amount of various flavor substances derived from malt, and the taste is thicker than a beverage manufactured using malt as a raw material, and this taste
  • the bitterness is somewhat alleviated by the thickness.
  • the bitter taste is somewhat alleviated by the thick taste.
  • the beer-like foamable beverage according to the present invention preferably has a small amount of malt as a raw material, since the effect of improving the aftertaste after bitterness due to the high gas pressure of the present invention is more sufficiently exhibited. More preferred are beverages which are produced without.
  • the content of proline in the beer-like effervescent beverage can be measured by, for example, the AccQ-Tag Ultra labeling method using an Acquity UPLC analyzer manufactured by Waters (US). In addition, it is also possible to measure using an amino acid automatic analyzer JLC-500 / V type manufactured by JEOL.
  • the beer-like foamable beverage according to the present invention is a container-packed beverage, a foamable beverage having a carbon dioxide gas content of 3.5 GV or more at 20 ° C. as a container for filling the beer-like foamable beverage according to the present invention
  • the container is not particularly limited as long as it can be filled with Specifically, glass bottles, cans, flexible containers and the like can be mentioned.
  • a flexible container the container formed by shape
  • the flexible container may be made of a single layer resin or may be made of a multilayer resin. It is preferable that the container for filling the beer-like effervescent beverage according to the present invention is a flexible container such as a plastic bottle, since it is relatively easy to increase the pressure resistance.
  • the beer-like effervescent beverage according to the present invention adjusts the amount of hops, hop processed products and bitter taste agents other than hops used as raw materials to have a bitterness value of 10 BU or more, and the final beverage It can manufacture similarly to a general fermented beer-like foamable beverage and a non-fermented beer-like foamable beverage except that the carbon dioxide content at 20 ° C. is adjusted to 3.5 GV or more.
  • a fermented beer-like effervescent beverage produced through a fermentation process can be produced by a process of preparation (fermentation material liquid preparation), fermentation, storage, and filtration.
  • a fermentation raw material liquid is prepared from one or more kinds of fermentation raw materials selected from the group consisting of grain raw materials and sugar raw materials. Specifically, a mixture containing a fermentation raw material and a raw material water is heated to saccharify the starch to prepare a sugar solution, and then the obtained sugar solution is boiled and then at least a part of the solid content is removed To prepare a fermentation material solution.
  • a mixture containing at least one of a grain raw material and a sugar raw material and raw material water is prepared and heated, and starch such as grain raw material is saccharified to prepare a sugar liquid.
  • a raw material of a sugar liquid only a grain raw material may be used, only a sugar raw material may be used, or both may be mixed and used.
  • grain raw materials include barley and wheat, barley such as malt thereof, beans such as rice, corn and soybean, potato and the like.
  • a grain raw material can also be used as a grain syrup, a grain extract, etc., it is preferable to use as a grain ground material obtained by grinding.
  • the grinding treatment of grains can be performed by a conventional method.
  • the ground grain product may be a ground malt material, corn starch, corn grits or the like, which has been subjected to a treatment which is usually carried out before or after the grinding treatment.
  • the ground cereals used be ground malts.
  • a malt ground material By using a malt ground material, it is possible to produce a fermented beer-like effervescent beverage having a clearer beer-like character.
  • the ground malt may be barley, for example, two-row barley, which is germinated by a conventional method, dried, and then ground to a predetermined particle size.
  • a grain material used in the present invention one kind of grain material may be used, or a mixture of plural kinds of grain materials may be used.
  • ground malt may be used as the main raw material, and ground rice or corn may be used as the auxiliary raw material.
  • saccharide sugar raw material, saccharides, such as liquid sugar, are mentioned, for example.
  • the usage ratio of malt to the total amount of the raw materials is preferably 66% by mass or less, since the post-bitter taste post-dampening effect of the present invention is more effectively exhibited.
  • the content is more preferably 50% by mass or less, further preferably 25% by mass or less, and particularly preferably not using malt as a raw material.
  • the malt use ratio is measured in accordance with the provisions of the Liquor Tax Act.
  • Grain materials and the like and auxiliary materials other than water may be added to the mixture.
  • auxiliary material include hops, dietary fiber, yeast extract, fruit juice, bittering agents, coloring agents, herbs, and perfumes.
  • saccharifying enzymes such as ⁇ -amylase, glucoamylase and pullulanase and enzyme agents such as protease can be added.
  • the saccharification treatment is performed using an enzyme derived from grain raw materials and the like and an enzyme added separately.
  • the temperature and time of the saccharification treatment take into consideration the type of grain raw material used, the ratio of grain raw material to the whole raw material, the type of enzyme added and the amount of mixture, and the quality of the target fermented beer-like foamable beverage etc. And adjusted accordingly.
  • the saccharification treatment can be carried out by a conventional method such as maintaining a mixture containing grain raw materials and the like at 35 to 70 ° C. for 20 to 90 minutes.
  • Boiling (boiling product of sugar liquid) can be prepared by boiling the sugar liquid obtained after the saccharification treatment.
  • the sugar solution is preferably filtered before boiling and the resulting filtrate is preferably boiled.
  • malt extract with hot water may be used to boil it.
  • the boiling method and its conditions can be determined suitably.
  • a fermented beer-like foamable beverage having a desired flavor By adding a herb or the like as appropriate before or during the boiling treatment, a fermented beer-like foamable beverage having a desired flavor can be produced.
  • a fermented beer-like foamable beverage having a desired flavor For example, by adding hops before or during boiling treatment and boiling treatment in the presence of hops, it is possible to efficiently boil the flavor and aroma components of hops, in particular, the bitter taste components.
  • the addition amount of hops, the addition mode (for example, addition in several times, etc.) and the boiling conditions can be appropriately determined.
  • the broth obtained after the boiling process contains a cocoon such as a protein produced by precipitation. Therefore, at least a portion of solid matter such as salmon is removed from the broth.
  • the removal of soot may be carried out by any solid-liquid separation treatment, but generally, a precipitate called a whirlpool is used to remove the precipitate.
  • the temperature of the soup at this time may be 15 ° C. or higher, and generally, it is carried out at about 50 to 100 ° C.
  • the broth (filtrate) is cooled to an appropriate fermentation temperature by a plate cooler or the like. Boiled juice after removing the cocoons becomes a fermentation raw material liquid.
  • the fermented raw material liquid that has been cooled is inoculated with yeast to carry out fermentation.
  • the cooled fermentation raw material liquid may be subjected to the fermentation process as it is, or may be subjected to the fermentation process after being adjusted to a desired extract concentration.
  • the yeast used for fermentation is not particularly limited, and usually can be selected appropriately from yeasts used for producing alcoholic beverages. It may be a top surface fermentation yeast or a bottom surface fermentation yeast, but is preferably a bottom surface fermentation yeast because application to large-scale brewing equipment is easy.
  • the obtained fermentation broth is aged in a storage tank, stored and stabilized under low temperature conditions of about 0 ° C., and then, as a filtration step, the fermentation broth after aging is filtered. Yeast and proteins insoluble in the temperature range can be removed to obtain the desired fermented beer-like effervescent beverage.
  • the filtration process may be any method that can filter and remove yeast, and examples thereof include diatomaceous earth filtration and filter filtration with a filter having an average pore diameter of about 0.4 to 1.0 ⁇ m.
  • a non-fermented beer-like effervescent beverage produced without undergoing a fermentation step can generally be produced by a method (formulation method) of mixing the respective raw materials. For example, specifically, by mixing each raw material, it can manufacture by the preparation process of preparing a preparation liquid, and the gas introduction process of adding carbon dioxide gas to the obtained preparation liquid.
  • the preparation solution is prepared by mixing the raw materials.
  • the preparation step it is preferable to prepare a preparation solution in which all the raw materials other than carbon dioxide gas are mixed.
  • the order of mixing the respective raw materials is not particularly limited. All the raw materials may be added simultaneously to the raw material water, or the raw materials may be added sequentially, such as adding the raw materials remaining after dissolving the previously added raw materials.
  • the raw material water may be mixed with solid (for example, powder or granular) raw material and alcohol, and the solid raw material is previously made into an aqueous solution, and these aqueous solutions and alcohol, if necessary, raw material water It may be mixed.
  • what heated the raw material may be put into raw material water, and the prepared liquid preparation may be heated.
  • bitter taste agent As a raw material, a bitter taste agent, an acidulant, a sweetener, a water-soluble dietary fiber, caramel pigment, a flavor agent, ethanol, a foaming agent, a protein or its degradation product, a yeast extract and the like can be mentioned.
  • the bitter taste agent include hops, hop extracts, processed hop products containing a component obtained by isocyanating the bitter taste component in hop, and bitter taste agents other than the bitter taste components derived from hops mentioned above.
  • the bitter taste agent contained in the beer-like foamable beverage according to the present invention is preferably a hop extract or a hop processed product, particularly preferably an iso-ized hop extract.
  • Examples of the acidulant include organic acids such as citric acid, gluconic acid, tartaric acid, malic acid, succinic acid, phosphoric acid, lactic acid, adipic acid, and fumaric acid.
  • Sweeteners include sucrose, liquid sugar, oligosaccharides, dextrin, starch, sweet amino acids, high sensitivity sweeteners and the like.
  • sweetening-type amino acids include alanine and glycine, with alanine being preferred.
  • high sensitivity sweetener include acesulfame potassium, aspartame, stevia, enzyme-treated stevia, sucralose and the like.
  • water soluble dietary fiber a carbohydrate which is soluble in water and which is not or hardly digested by human digestive enzymes.
  • water-soluble dietary fiber examples include soybean dietary fiber, polydextrose, indigestible dextrin, galactomannan, inulin, guar gum degradation products, pectin, gum arabic and the like.
  • Examples of the flavor include beer extract, beer flavor, hop flavor and the like.
  • Examples of the foaming agent include soy peptide, soy saponin, alginate, quillaja saponin and the like.
  • the use ratio of malt to the total amount of the solid material is 66% by mass or less as the non-fermented beer-like effervescent beverage according to the present invention. Is more preferably 50% by mass or less, still more preferably 25% by mass or less, and it is particularly preferable that malt is not used as a raw material.
  • the malt use ratio is measured in accordance with the provisions of the Liquor Tax Act.
  • insoluble matter When insoluble matter is generated in the preparation liquid prepared in the preparation process, it is preferable to carry out a process of removing the insoluble matter such as filtration to the preparation liquid prior to the gas introduction step.
  • the insoluble matter removal treatment is not particularly limited, and can be carried out by methods commonly used in the relevant technical field such as filtration method and centrifugation method.
  • insolubles are preferably removed by filtration, and more preferably removed by diatomaceous earth filtration.
  • carbon dioxide gas is added to the preparation liquid obtained by the preparation process as a gas introduction process.
  • carbonation By adding carbonation, the same refreshing feeling as beer is provided.
  • the addition of carbon dioxide gas can be performed by a conventional method.
  • the preparation liquid obtained by the preparation process and carbonated water may be mixed, or carbon dioxide gas may be directly added to and dissolved in the preparation liquid obtained by the preparation process.
  • the obtained non-fermented beer-like effervescent beverage may be further subjected to a treatment for removing insoluble matter such as filtration.
  • the insoluble matter removing process is not particularly limited, and can be performed by a method commonly used in the relevant technical field.
  • the proline content of the beer-like effervescent beverage was measured by the AccQ-Tag Ultra labeling method using an Acquity UPLC analyzer manufactured by Waters (US).
  • the calibration curve was prepared using an amino acid mixed standard solution H type (manufactured by Wako Pure Chemical Industries, Ltd.).
  • bitterness strength of beer-like effervescent beverages and the sensory evaluation of the remaining bitterness were carried out as follows.
  • the intensity of bitterness refers to the intensity at the highest point where the bitterness derived from hops is felt when the solution is contained in the mouth, and the remainder of bitterness is defined as the intensity of bitterness remaining several seconds after swallowing. .
  • ten trained beer specialist panels were used to evaluate the bitterness intensity and bitterness remainder of the beer-like effervescent beverage as compared to the control sample.
  • the evaluation of the intensity of bitter taste was made such that one point was weaker in bitterness than the control sample, two points were similar in bitterness intensity to the control, and three points were stronger in bitter taste than the control sample.
  • the evaluation of the remaining bitter taste was made that one point remained bitter compared to the control sample, two points were bitter remaining similar to the control, and three points remained no bitter taste compared to the control sample.
  • the score for each sample was the average of the scores of 10 trained beer specialist panels. When the score of each sample was 1.5 points or less or 2.5 points or more, it was judged that the sample was different from the control sample.
  • Example 1 Among non-fermented beer-like effervescent beverages, the influence of the content of carbon dioxide gas on the residual bitterness in non-alcohol beer containing no alcohol was investigated.
  • a mixture of 1 g of water with 25 g of dextrin, 10 g of liquid sugar, 0.3 g of caramel, 0.7 g of phosphoric acid, and 1.0 g of a fragrance is added with isoated hop extract (manufactured by John I. Haas, Inc.).
  • a carbon dioxide gas-free raw material solution was prepared which was added such that the bitterness value of the beer-like foamable beverage obtained as above became 17 BU.
  • Example 2 The influence of carbon dioxide content on the bitterness residue in non-alcohol beer with different bitterness was investigated.
  • a carbon dioxide gas-free material solution was prepared in the same manner as in Example 1 except that the amount of the isotroped hop extract was added so that the bitterness value of the finally obtained beer-like effervescent beverage was 5 to 35 BU. .
  • a carbon dioxide gas was dissolved in the obtained carbon dioxide gas-free raw material solution so as to be 2.9 GV (control sample) or 4.0 GV (test sample) to produce a non-alcohol beer.
  • the test samples of 4.0 GV were compared with the control samples of 2.9 GV with equal bitter value, respectively, to make a sensory evaluation of the strength of bitterness and the remaining bitterness.
  • Example 3 The effect of carbon dioxide gas content on the remaining bitter taste in non-alcohol beer was investigated using hop extract instead of isoated hop extract.
  • hop extract John I. Haas, Inc. was prepared by mixing 25 g of dextrin, 10 g of liquid sugar, 2 g of soybean protein hydrolyzate, 0.3 g of caramel, 0.7 g of phosphoric acid, and 1.0 g of flavor in 1 L of water. Made to adjust the bitterness value of the beer-like effervescent beverage finally obtained to 17 BU to adjust the raw material liquid.
  • This raw material solution is boiled at 100 ° C. for 1 hour, and the water for evaporation is added and cooled, filtration using diatomaceous earth and filtration using a filter are carried out, and a flavor addition is further performed to be 1.0 g / L. Then, a carbon dioxide-free raw material solution was prepared.
  • the non-alcohol beer of the control 1 is similar in bitterness strength to the control 2 (non-alcohol beer boiled with the addition of hop extract)
  • the remaining bitterness score was 1.5, and the bitterness remained stronger than Control 2. That is, it was confirmed that the beer-like effervescent beverage blended with the iso-ized hop extract has a stronger bitterness remaining than the beer-like effervescent beverage to which the hop extract is added and subjected to boiling treatment.
  • Example 4 The influence of the content of carbon dioxide gas on the remainder of the bitter taste in fermented beer-like effervescent beverages with different malt use ratios was investigated.
  • Test liquid A was prepared by dissolving carbon dioxide gas so as to be 4.1 GV in this fermented beer-like foamable beverage.
  • the obtained fermentation broth was transferred to a aging tank, aged for 7 days, cooled to about -1 ° C., and stabilized for 14 days.
  • Degassed water was added to the fermented liquid after stabilization to dilute, and then the obtained diluted liquid was filtered using diatomaceous earth to produce a clear fermented beer-like effervescent beverage (malt usage ratio 0 mass%) .
  • a liquid obtained by dissolving carbon dioxide gas so as to be 4.1 GV in this fermented beer-like foamable beverage was used as a test solution B.
  • test solution A When the proline content of the test solution A and the test solution B was measured, the test solution A was 45 mg / 100 mL, and the test solution B was 5 mg / 100 mL.
  • test solution A By mixing the test solution A and the test solution B as appropriate, samples having a proline content as described in Table 4 were prepared. A sensory evaluation of the remaining bitterness of each sample was performed. As a control sample in the sensory evaluation, a fermented beer-like effervescent beverage in which carbon dioxide gas was dissolved so as to be 2.9 GV (Control 3) was used before preparing the test solution B.
  • the beer-like foamable beverage having a low malt usage ratio and a small taste thickness (taste volume) can obtain a stronger effect of improving the aftertaste after bitter taste due to high gas pressure.

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Abstract

A beer-like effervescent beverage, and a production method thereof, are provided, characterized in that the bitterness value is greater than or equal to 10 BU and the carbon dioxide gas content at 20°C is greater than or equal to 3.7 GV.

Description

ビール様発泡性飲料及びその製造方法Beer-like effervescent beverage and method for producing the same
 本発明は、苦味価が高いにもかかわらず、苦味の後キレが良好なビール様発泡性飲料及びその製造方法に関する。
 本願は、2018年1月15日に、日本に出願された特願2018-004543号に基づき優先権を主張し、その内容をここに援用する。
The present invention relates to a beer-like effervescent beverage having good bitterness and good crispness despite having a high bitterness value, and a method for producing the same.
Priority is claimed on Japanese Patent Application No. 2018-004543, filed January 15, 2018, the content of which is incorporated herein by reference.
 ビールや発泡酒等のビール様発泡性飲料は、独特の苦味や香味を有しており、止渇感・ドリンカビリティー(飽きずに何杯も飲み続けられる性質)を主たる特徴とする。麦芽、ホップに代表される原料の種類や配合、製造方法等を変えることにより、ビール様発泡性飲料の香味や品質を改善する方法が多数報告されている。特に、爽快感は、ビールのドリンカビリティーに重要な品質であり、爽快感を高める試みがなされている。例えば、特許文献1には、特定のヒドロキシ酸エステル類の含有量を調整することによって、炭酸ガス圧を高めることなく、炭酸飲料の炭酸刺激を増強し得る方法が開示されている。 Beer-like effervescent beverages such as beer and low-malt beer have a unique bitter taste and flavor, and are characterized mainly by thirst and drinkability (the ability to keep drinking many glasses without getting tired). Many methods have been reported to improve the flavor and quality of a beer-like effervescent beverage by changing the types and combinations of raw materials typified by malt and hop, and the production method. In particular, exhilaration is an important quality for beer drinkability, and attempts have been made to enhance exhilaration. For example, Patent Document 1 discloses a method that can enhance the carbonation stimulation of a carbonated beverage without increasing the carbon dioxide pressure by adjusting the content of a specific hydroxy acid ester.
 苦味の強いビールは、その苦味が後を引いて口の中に残り、ビールの爽快感、後味のさっぱり感、キレのよさ等を損なう結果となり、ビールの嗜好性やドリンカビリティーが低下するといった問題があった。苦味の強いビールにおいて、後を引く苦味を改善する方法としては、例えば特許文献2には、苦味価が30BU以上のビールについて、VDK濃度を特定の範囲とすることにより、後味のキレ、すっきりとした味感、苦味とキレのバランスを良好にし、ドリンカビリティーを高められることが記載されている。 The bitter bitter beer withdraws its bitterness and remains in the mouth, resulting in loss of beer refreshing feeling, refreshing aftertaste, crispness, etc., and the beer's palatability and drinkability decline. There was a problem. As a method for improving the bitterness to be followed in a beer with strong bitterness, for example, in Patent Document 2, for beer having a bitterness value of 30 BU or more, by setting the VDK concentration to a specific range, the aftertaste is crispy and clear It is described that the well-balanced taste, bitterness and crispness can be improved and the drinkability can be enhanced.
特許第6153633号公報Patent No. 6153633 特開2017-12092号公報JP, 2017-12092, A
 本発明は、苦味価が高いにもかかわらず、苦味の後キレが良好なビール様発泡性飲料及びその製造方法を提供することを目的とする。 An object of the present invention is to provide a beer-like effervescent beverage having good bitterness and good crispness despite the high bitterness value, and a method for producing the same.
 本発明者らは、苦味価が10BU以上と高いビール様発泡性飲料において、炭酸ガス含有量を高めることによって、苦味の後キレを改善できることを見出し、本発明を完成させた。 The present inventors have found that, in a beer-like effervescent beverage having a high bitterness value of 10 BU or more, the post-bitter taste can be improved by increasing the carbon dioxide content, and the present invention has been completed.
 本発明に係るビール様発泡性飲料、ビール様発泡性飲料の製造方法、及びビール様発泡性飲料の苦味の後キレを向上させる方法は、下記[1]~[13]である。
[1] 苦味価が10BU以上であり、20℃における炭酸ガス含有量が3.7GV以上であることを特徴とする、ビール様発泡性飲料。
[2] 苦味価が30BU以下である、前記[1]のビール様発泡性飲料。
[3] 20℃における炭酸ガス含有量が3.8GV以上である、前記[1]又は[2]のビール様発泡性飲料。
[4] ホップ中の苦味成分をイソ化した成分を含むホップ加工品を含有する、前記[1]~[3]のいずれかのビール様発泡性飲料。
[5] 前記ホップ加工品が、イソ化ホップエキスである、前記[4]のビール様発泡性飲料。
[6] プロリン含有量が30mg/100mL以下である、前記[1]~[5]のいずれかのビール様発泡性飲料。
[7] ノンアルコール飲料である、前記[1]~[6]のいずれかのビール様発泡性飲料。
[8] 苦味価が10BU以上であるビール様発泡性飲料を製造する方法であって、
 飲料の20℃における炭酸ガス含有量が3.7GV以上となるように調整することを特徴とする、ビール様発泡性飲料の製造方法。
[9] ホップ又はホップ加工品を原料とする、前記[8]のビール様発泡性飲料の製造方法。
[10] 麦芽を原料として用いない、前記[8]又は[9]のビール様発泡性飲料の製造方法。
[11] 麦芽の使用比率が66質量%以下である、前記[8]又は[9]のビール様発泡性飲料の製造方法。
[12] 製造されたビール様発泡性飲料がノンアルコール飲料である、前記[8]~[11]のいずれかのビール様発泡性飲料の製造方法。
[13] 苦味価が10BU以上であるビール様発泡性飲料の20℃における炭酸ガス含有量が3.7GV以上となるように調整することを特徴とする、ビール様発泡性飲料の苦味の後キレを向上させる方法。
The beer-like foamable beverage, the method for producing a beer-like foamable beverage, and the method for improving the aftertaste of bitterness of the beer-like foamable beverage according to the present invention are the following [1] to [13].
[1] A beer-like effervescent beverage having a bitter taste value of 10 BU or more and a carbon dioxide gas content at 20 ° C. of 3.7 GV or more.
[2] The beer-like foamy beverage according to the above [1], which has a bitterness value of 30 BU or less.
[3] The beer-like foamy beverage according to the above [1] or [2], wherein the carbon dioxide content at 20 ° C. is 3.8 GV or more.
[4] The beer-like foamy beverage according to any one of the above [1] to [3], which contains a processed hop product containing a component obtained by isotyping a bitter component in hops.
[5] The beer-like foamy beverage according to the above [4], wherein the processed hop product is an isoated hop extract.
[6] The beer-like foamy beverage according to any one of the above [1] to [5], wherein the proline content is 30 mg / 100 mL or less.
[7] The beer-like foamy beverage according to any one of the above [1] to [6], which is a non-alcoholic beverage.
[8] A method for producing a beer-like foamable beverage having a bitterness value of 10 BU or more,
A method for producing a beer-like foamy beverage, wherein the carbon dioxide gas content at 20 ° C. of the beverage is adjusted to 3.7 GV or more.
[9] The method for producing a beer-like foamy beverage according to the above [8], which uses hops or hop products as a raw material.
[10] The method for producing a beer-like foamy beverage according to the above [8] or [9], wherein malt is not used as a raw material.
[11] The method for producing a beer-like foamy beverage according to the above [8] or [9], wherein the use ratio of malt is 66% by mass or less.
[12] The method for producing a beer-like foamable beverage according to any one of the above [8] to [11], wherein the produced beer-like foamable beverage is a non-alcoholic beverage.
[13] The bitter taste is adjusted so that the content of carbon dioxide gas at 20 ° C. of the beer-like foamable beverage having 10 BU or more is 3.7 GV or more, after the bitter taste of the beer-like foamable beverage How to improve
 本発明により、苦味価が10BU以上と高いにもかかわらず、苦味の後キレが良好なビール様発泡性飲料を提供することができる。 According to the present invention, it is possible to provide a beer-like effervescent beverage having a good bitter aftertaste despite the high bitterness value of 10 BU or more.
 本発明及び本願明細書においては、「ビールらしさ」とは、製品名称・表示にかかわらず、香味上ビールを想起させる呈味のことを意味する。つまり、ビールらしさを有する発泡性飲料(ビール様発泡性飲料)とは、アルコール含有量、麦芽及びホップの使用の有無、発酵の有無に関わらず、ビールと同等の又はそれと似た風味・味覚及びテクスチャーを有し、高い止渇感・ドリンカビリティーを有する発泡性飲料を意味する。すなわち、本発明に係るビール様発泡性飲料は、アルコール飲料であってもよく、アルコール含量が1容量%未満であるいわゆるノンアルコール飲料又はローアルコール飲料であってもよい。また、麦芽を原料とする飲料であってもよく、麦芽を原料としない飲料であってもよく、発酵工程を経て製造される飲料であってもよく、発酵工程を経ずに製造される飲料であってもよい。ビール様発泡性飲料としては、具体的には、ビール、麦芽を原料とする発泡酒、麦芽を使用しない発泡性アルコール飲料、ローアルコール発泡性飲料、ノンアルコールビール等が挙げられる。その他、麦芽を原料とし、発酵工程を経て製造された飲料を、アルコール含有蒸留液と混和して得られたリキュール類であってもよい。アルコール含有蒸留液とは、蒸留操作により得られたアルコールを含有する溶液であり、例えば、原料用アルコールであってもよく、スピリッツ、ウィスキー、ブランデー、ウオッカ、ラム、テキーラ、ジン、焼酎等の蒸留酒等を用いることができる。 In the present invention and in the specification of the present application, "beer-like" means a taste reminiscent of flavored beers regardless of the product name and display. That is, a beer-like effervescent beverage (beer-like effervescent beverage) has an alcohol content, presence or absence of use of malt and hop, and a flavor / taste equivalent to or similar to beer, regardless of the presence or absence of fermentation. It refers to an effervescent beverage having a texture and high thirst and drinkability. That is, the beer-like effervescent beverage according to the present invention may be an alcoholic beverage, and may be a so-called non-alcoholic beverage or a low alcoholic beverage having an alcohol content of less than 1% by volume. Also, the beverage may be malt-based, beverage may not be malt-based, or may be a beverage produced through a fermentation process, or beverage produced without a fermentation process. It may be Specific examples of beer-like effervescent beverages include beer, low-malt beer using malt as a raw material, effervescent alcoholic beverages that do not use malt, low alcohol effervescent beverages, non-alcohol beer and the like. In addition, it may be a liqueur obtained by mixing a beverage produced from malt as a raw material through a fermentation process with an alcohol-containing distillate. The alcohol-containing distillate is a solution containing an alcohol obtained by a distillation operation, and may be, for example, a raw material alcohol, and may be a distillation of spirits, whiskey, brandy, vodka, lamb, tequila, gin, shochu, etc. Alcohol can be used.
 本発明及び本願明細書において、「苦味の後キレ」とは、苦味の後味にキレがあること、すなわち、飲んだ後に苦味の残り難さを意味する。「苦味の後キレが良い」とは、飲んだ後に苦味が残らないことを意味し、「苦味の後キレが悪い」とは、飲んだ後に口腔内に苦味が長く残ることを意味する。 In the present invention and the specification of the present invention, "bitter taste after squeaky" means that the bitter taste has a crisp aftertaste, that is, the bitterness remaining difficulty after drinking. "Good after bitter taste" means that no bitter taste remains after drinking, and "bad after bitter taste" means that bitter taste remains in the mouth for a long time after drinking.
 本発明に係るビール様発泡性飲料は、苦味価が10BU以上であり、20℃における炭酸ガス含有量が3.5GV以上である。苦味価が高いビール様発泡性飲料では、苦味の後キレが悪く、爽快さが損なわれてドリンカビリティーが低くなりやすい。本発明に係るビール様発泡性飲料では、炭酸ガス含有量を、一般的なビールの炭酸ガス含有量(2.9GV程度)よりも高ガス圧にすることにより、苦味価が高いにもかかわらず、苦味の後キレが向上されており、爽快感とドリンカビリティーが高い。 The beer-like foamable beverage according to the present invention has a bitterness value of 10 BU or more, and a carbon dioxide gas content at 20 ° C. of 3.5 GV or more. Beer-like effervescent beverages with high bitter value are poor in crispiness after bitter taste, and the refreshing property is impaired and the drinkability tends to be low. In the beer-like foamable beverage according to the present invention, the bitterness value is high by setting the carbon dioxide content to a higher gas pressure than the carbon dioxide content (about 2.9 GV) of a general beer. After being bitter, the crispness is improved, and the feeling of exhilaration and drinkability are high.
 本発明に係るビール様発泡性飲料の炭酸ガス含有量は、20℃における炭酸ガス含有量が3.5GV以上となる量であれば特に限定されるものではない。苦味の後キレ向上効果がより十分に得られることから、本発明に係るビール様発泡性飲料の20℃における炭酸ガス含有量は、3.7GV以上が好ましく、3.8GV以上がより好ましい。本発明に係るビール様発泡性飲料の20℃における炭酸ガス含有量は、5.0GV以下が好ましく、4.4GV以下がより好ましい。ビール様発泡性飲料の炭酸ガス含有量は、炭酸ガスを直接飲料に注入することや、発酵においてより多くの炭酸ガスを産生させることにより、3.5GV以上に調整することができる。なお、ビール様発泡性飲料の炭酸ガス含有量は、例えば、飲料分析装置「Orbisphere 6110 Beverage Analyzer」(HACH社製)を用いて測定することができる。 The carbon dioxide gas content of the beer-like foamable beverage according to the present invention is not particularly limited as long as the carbon dioxide gas content at 20 ° C. is 3.5 GV or more. As the carbon dioxide gas content at 20 ° C. of the beer-like effervescent beverage according to the present invention is more preferably 3.7 GV or more, and more preferably 3.8 GV or more, since the aftertaste improvement effect of bitter taste is more sufficiently obtained. 5.0 GV or less is preferable and, as for the carbon dioxide gas content in 20 degreeC of the beer-like foamable drink which concerns on this invention, 4.4 GV or less is more preferable. The carbon dioxide content of the beer-like effervescent beverage can be adjusted to 3.5 GV or more by injecting carbon dioxide directly into the beverage or by producing more carbon dioxide in fermentation. The carbon dioxide gas content of the beer-like foamable beverage can be measured, for example, using a beverage analyzer “Orbisphere 6110 Beverage Analyzer” (manufactured by HACH).
 本発明に係るビール様発泡性飲料の苦味価は、10BU以上であれば特に限定されるものではなく、求められる製品品質に応じて適宜調整することができる。ビール様発泡性飲料の苦味が強すぎる場合には、高ガス圧による苦味の後キレ向上効果が得られ難い場合があることから、本発明に係るビール様発泡性飲料の苦味価は、10BU以上33BU以下が好ましく、10BU以上30BU以下がより好ましく、13BU以上28BU以下がさらに好ましく、15BU以上28BU以下がよりさらに好ましく、15BU以上25BU以下が特に好ましい。 The bitterness value of the beer-like foamable beverage according to the present invention is not particularly limited as long as it is 10 BU or more, and can be appropriately adjusted according to the required product quality. If the bitter taste of the beer-like foamable beverage is too strong, the bitter taste value of the beer-like foamable beverage according to the present invention may be 10 BU or more, because it may be difficult to obtain an improvement effect after the bitter taste due to high gas pressure. 33 BU or less is preferable, 10 BU or more and 30 BU or less is more preferable, 13 BU or more and 28 BU or less is more preferable, 15 BU or more and 28 BU or less is more preferable, and 15 BU or more and 25 BU or less is particularly preferable.
 なお、苦味価とは、イソフムロンを主成分とするホップ由来物質群により与えられる苦味の指標であり、ビール様発泡性飲料の苦味価は、例えばEBC法(ビール酒造組合:「ビール分析法」8.15 1990年)により測定することができる。具体的には、サンプルに酸を加えた後イソオクタンで抽出し、遠心分離処理後に得られたイソオクタン層の、純粋なイソオクタンを対照に測定した275nmにおける吸光度に定数(50)を乗じた値(BU)である。 The bitterness value is an index of bitterness given by hop-derived substances containing isohumulone as a main component, and the bitterness value of the beer-like effervescent beverage can be determined, for example, by the EBC method (Beer Brewery Association: “Beer analysis method” 8 .15 1990). Specifically, acid was added to the sample, followed by extraction with isooctane, and the absorbance at 275 nm of the isooctane layer obtained after centrifugation was measured using pure isooctane as a control multiplied by a constant (50) (BU) (BU) ).
 本発明に係るビール様発泡性飲料が含有する苦味成分としては、イソα酸等の主にホップに由来する苦味成分が好ましく、イソα酸を苦味の主成分とするものがより好ましい。例えば、原料としてホップ又はホップ加工品を用いることにより、ホップに由来する苦味成分を含むビール様発泡性飲料を製造できる。原料として用いるホップとしては、生ホップであってもよく、乾燥ホップであってもよく、ホップペレットであってもよい。また、原料として用いるホップ加工品としては、ホップから苦味成分を抽出したホップエキスであってもよい。また、イソ化ホップエキス、テトラハイドロイソフムロン、ヘキサハイドロイソフムロン等のホップ中の苦味成分をイソ化した成分を含むホップ加工品であってもよい。 As the bitterness component contained in the beer-like foamable beverage according to the present invention, a bitterness component mainly derived from hops such as iso-α acid is preferable, and one having iso-α acid as a main component of bitterness is more preferable. For example, by using hops or processed hops as a raw material, it is possible to produce a beer-like foamy beverage containing bitter taste components derived from hops. The hops used as the raw material may be raw hops, dry hops or hop pellets. Moreover, as a hop processed product used as a raw material, the hop extract which extracted the bitterness component from the hop may be sufficient. In addition, it may be a processed hop product containing a component obtained by isocyanation of a bitter taste component in hops such as isophized hop extract, tetrahydroisohumulone, hexahydroisohumulone and the like.
 本発明に係るビール様発泡性飲料は、イソ化ホップエキスを含有することが好ましい。イソ化ホップエキスとは、ホップエキスに触媒としてマグネシウム塩を添加して加熱するイソ化処理を行い、得られたイソα酸等のイソ体を精製したものである。イソ化ホップエキスを含有するビール様発泡性飲料は、ホップエキスを含有するビール様発泡性飲料やホップを原料として煮沸処理によりホップに由来する苦味成分を含有させたビール様発泡性飲料よりも、口腔内に苦味の後残りが強く、苦味の後キレが悪い。このため、苦味料としてイソ化ホップエキスを用いて製造されたビール様発泡性飲料では、本発明の高ガス圧による苦味の後キレ向上効果がより十分に発揮される。 The beer-like effervescent beverage according to the present invention preferably contains an isoated hop extract. The isopinated hop extract is a product obtained by performing an isotropization treatment in which a magnesium salt is added as a catalyst to hop extract and heating is performed, and an iso-body such as iso-α-acid obtained is purified. A beer-like effervescent beverage containing an isopinated hop extract is more than a beer-like effervescent beverage containing a hop extract or a beer-like effervescent beverage containing a bitter taste component derived from hops by boiling treatment using hops as a raw material. The rest is strong after bitter taste in the oral cavity, and poor after bitter taste. For this reason, in the beer-like effervescent beverage manufactured using the isocyanicized hop extract as a bitter taste agent, the after-taste improvement effect of the bitter taste by the high gas pressure of the present invention is more fully exhibited.
 本発明に係るビール様発泡性飲料が含有する苦味成分としては、ビールと同質若しくは近似する苦味を呈するものであれば特に限定されるものではない。本発明に係るビール様発泡性飲料は、ホップに由来する苦味成分に加えて、又はこれにかえて、ホップに由来する苦味成分以外の苦味成分を含有していてもよい。ホップに由来する苦味成分以外の苦味成分を含む苦味料としては、具体的には、マグネシウム塩、カルシウム塩、クエン酸トリブチル、クエン酸トリエチル、ナリンジン、クワシン、イソα酸、テトライソα酸、β酸の酸化物、キニーネ、モモルデシン、クエルシトリン、テオブロミン、カフェイン等の苦味付与成分、及びゴーヤ、センブリ茶、苦丁茶、ニガヨモギ抽出物、ゲンチアナ抽出物、クワッシャ抽出物、キナ抽出物(キニーネ抽出物)等の苦味付与素材が代表的に挙げられる。 The bitter taste component contained in the beer-like foamable beverage according to the present invention is not particularly limited as long as it exhibits a bitter taste similar to or similar to beer. The beer-like effervescent beverage according to the present invention may contain, in addition to or in place of the bitter component derived from hop, a bitter component other than the bitter component derived from hop. Specifically, as a bittering agent containing a bitterness component other than a bitterness component derived from hop, magnesium salt, calcium salt, tributyl citrate, triethyl citrate, naringin, quassin, iso alpha acid, tetra iso alpha acid, beta acid Oxides, quinine, momordesine, quercitrin, theobromine, caffeine and other bitter taste imparting ingredients, and bitter gourd, sembry tea, bitter green tea, bitter melon tea extract, niga yogi extract, gentiana extract, kuwasha extract, quina extract (quinine extract) Etc. are typically mentioned.
 本発明に係るビール様発泡性飲料の苦味価は、原料とするホップ、ホップ加工品、及びホップ以外の苦味料の使用量を適宜調整することによって調整できる。本発明に係るビール様発泡性飲料が酵母による発酵工程を経て製造された発酵ビール様発泡性飲料であり、かつ原料としてホップを使用する場合には、ホップの使用量を増大させたり、イソα酸含有量の比較的多いホップ品種を原料として用いることにより高めることができる。また、発酵工程中や発酵工程後にホップを添加し、苦味成分を抽出させることによっても、麦芽発酵飲料の苦味価を高めることができる。 The bitterness value of the beer-like effervescent beverage according to the present invention can be adjusted by appropriately adjusting the amounts of hop, processed hop product and bittering agent other than hop as raw materials. When the beer-like effervescent beverage according to the present invention is a fermented beer-like effervescent beverage manufactured through a fermentation step with yeast and hops are used as a raw material, the amount of hops used is increased, or iso α This can be enhanced by using hop varieties with relatively high acid content as raw materials. The bitterness value of the malt-fermented beverage can also be increased by adding hop during or after the fermentation process to extract the bitter component.
 本発明に係るビール様発泡性飲料は、アルコール飲料であってもよく、ノンアルコール飲料であってもよい。アルコール濃度が高いビール様発泡性飲料では、アルコールにより苦味がやや緩和される。このため、本発明の高ガス圧による苦味の後キレ向上効果がより十分に発揮されることから、本発明に係るビール様発泡性飲料のアルコール濃度は、1容量%以下好ましく、0.5容量%未満がより好ましく、0.05容量%未満がさらに好ましく、0容量%(アルコールを原料として含有していない)が特に好ましい。 The beer-like effervescent beverage according to the present invention may be an alcoholic beverage or a non-alcoholic beverage. In a beer-like effervescent beverage having a high alcohol concentration, alcohol slightly alleviates the bitter taste. For this reason, since the improvement effect after the bitter taste by the high gas pressure of the present invention is more fully exhibited, the alcohol concentration of the beer-like foamable beverage according to the present invention is 1% by volume or less, preferably 0.5 volume Less than% is more preferable, less than 0.05% by volume is more preferable, and 0% by volume (containing no alcohol as a raw material) is particularly preferable.
 本発明に係るビール様発泡性飲料は、麦芽を原料として製造された飲料であってもよく、麦芽を原料とせずに製造された飲料であってもよい。麦芽を原料として製造されたビール様発泡性飲料には、麦芽に由来する各種香味物質が多く含まれており、麦芽を原料とせずに製造された飲料よりも味に厚みがあり、この味の厚みにより苦味がやや緩和される。味の厚みのあるビール様発泡性飲料では、味の厚みにより苦味がやや緩和される。このため、本発明の高ガス圧による苦味の後キレ向上効果がより十分に発揮されることから、本発明に係るビール様発泡性飲料は、原料とした麦芽が少ない方が好ましく、麦芽を原料とせずに製造された飲料がより好ましい。 The beer-like effervescent beverage according to the present invention may be a beverage manufactured using malt as a raw material, or may be a beverage manufactured without using malt as a raw material. The beer-like effervescent beverage manufactured using malt as a raw material contains a large amount of various flavor substances derived from malt, and the taste is thicker than a beverage manufactured using malt as a raw material, and this taste The bitterness is somewhat alleviated by the thickness. In a thick beer-like sparkling beverage with a thick taste, the bitter taste is somewhat alleviated by the thick taste. Therefore, the beer-like foamable beverage according to the present invention preferably has a small amount of malt as a raw material, since the effect of improving the aftertaste after bitterness due to the high gas pressure of the present invention is more sufficiently exhibited. More preferred are beverages which are produced without.
 麦芽は、比較的プロリンの含有量が多い。このため、ビール様発泡性飲料においては、原料として用いた麦芽の使用量が多くなるほど、プロリンの含有量が多くなる。本発明に係るビール様発泡性飲料のプロリンの含有量としては、30mg/100mL以下が好ましく、20mg/100mL以下がより好ましい。なお、ビール様発泡性飲料中のプロリンの含有量は、例えば、(米国)ウォーターズ社製Acquity UPLC分析装置を用いて、アキュタグウルトラ(AccQ-Tag Ultra)ラベル化法により測定することができる。また、日本電子社製アミノ酸自動分析装置JLC―500/V型などを用いて測定することも可能である。 Malt has a relatively high content of proline. For this reason, in the beer-like effervescent beverage, the content of proline increases as the amount of malt used as the raw material increases. As content of proline of the beer-like foamable drink which concerns on this invention, 30 mg / 100 mL or less is preferable, and 20 mg / 100 mL or less is more preferable. The content of proline in the beer-like effervescent beverage can be measured by, for example, the AccQ-Tag Ultra labeling method using an Acquity UPLC analyzer manufactured by Waters (US). In addition, it is also possible to measure using an amino acid automatic analyzer JLC-500 / V type manufactured by JEOL.
 本発明に係るビール様発泡性飲料が容器詰飲料である場合、本発明に係るビール様発泡性飲料を充填する容器としては、20℃における炭酸ガス含有量が3.5GV以上である発泡性飲料を充填可能な容器であれば特に限定されるものではない。具体的には、ガラス瓶、缶、可撓性容器等が挙げられる。可撓性容器としては、PE(ポリエチレン)、PP(ポリプロピレン)、EVOH(エチレン・ビニルアルコール共重合体)、PET(ポリエチレンテレフタレート)等の可撓性樹脂を成形してなる容器が挙げられる。可撓性容器は、単層樹脂からなるものであってもよく、多層樹脂からなるものであってもよい。耐圧性を高めることが比較的容易であることから、本発明に係るビール様発泡性飲料を充填する容器としては、ペットボトル等の可撓性容器であることが好ましい。 When the beer-like foamable beverage according to the present invention is a container-packed beverage, a foamable beverage having a carbon dioxide gas content of 3.5 GV or more at 20 ° C. as a container for filling the beer-like foamable beverage according to the present invention The container is not particularly limited as long as it can be filled with Specifically, glass bottles, cans, flexible containers and the like can be mentioned. As a flexible container, the container formed by shape | molding flexible resin, such as PE (polyethylene), PP (polypropylene), EVOH (ethylene-vinyl alcohol copolymer), PET (polyethylene terephthalate), is mentioned. The flexible container may be made of a single layer resin or may be made of a multilayer resin. It is preferable that the container for filling the beer-like effervescent beverage according to the present invention is a flexible container such as a plastic bottle, since it is relatively easy to increase the pressure resistance.
 本発明に係るビール様発泡性飲料は、苦味価が10BU以上となるように原料として用いる原料とするホップ、ホップ加工品、及びホップ以外の苦味料の使用量を調整し、かつ最終的な飲料中の20℃における炭酸ガス含有量が3.5GV以上となるように調整する以外は、一般的な発酵ビール様発泡性飲料や非発酵ビール様発泡性飲料と同様にして製造できる。 The beer-like effervescent beverage according to the present invention adjusts the amount of hops, hop processed products and bitter taste agents other than hops used as raw materials to have a bitterness value of 10 BU or more, and the final beverage It can manufacture similarly to a general fermented beer-like foamable beverage and a non-fermented beer-like foamable beverage except that the carbon dioxide content at 20 ° C. is adjusted to 3.5 GV or more.
 発酵工程を経て製造される発酵ビール様発泡性飲料は、一般的には、仕込(発酵原料液調製)、発酵、貯酒、濾過の工程で製造することができる。 In general, a fermented beer-like effervescent beverage produced through a fermentation process can be produced by a process of preparation (fermentation material liquid preparation), fermentation, storage, and filtration.
 まず、仕込工程(発酵原料液調製工程)として、穀物原料及び糖質原料からなる群より選択される1種以上の発酵原料から発酵原料液を調製する。具体的には、発酵原料と原料水とを含む混合物を加温し、澱粉質を糖化して糖液を調製した後、得られた糖液を煮沸し、その後固体分の少なくとも一部を除去して発酵原料液を調製する。 First, as a charging step (fermentation raw material liquid preparation step), a fermentation raw material liquid is prepared from one or more kinds of fermentation raw materials selected from the group consisting of grain raw materials and sugar raw materials. Specifically, a mixture containing a fermentation raw material and a raw material water is heated to saccharify the starch to prepare a sugar solution, and then the obtained sugar solution is boiled and then at least a part of the solid content is removed To prepare a fermentation material solution.
 まず、穀物原料と糖質原料の少なくともいずれかと原料水とを含む混合物を調製して加温し、穀物原料等の澱粉質を糖化させて糖液を調製する。糖液の原料としては、穀物原料のみを用いてもよく、糖質原料のみを用いてもよく、両者を混合して用いてもよい。穀物原料としては、例えば、大麦や小麦、これらの麦芽等の麦類、米、トウモロコシ、大豆等の豆類、イモ類等が挙げられる。穀物原料は、穀物シロップ、穀物エキス等として用いることもできるが、粉砕処理して得られる穀物粉砕物として用いることが好ましい。穀物類の粉砕処理は、常法により行うことができる。穀物粉砕物としては、麦芽粉砕物、コーンスターチ、コーングリッツ等のように、粉砕処理の前後において通常なされる処理を施したものであってもよい。本発明においては、用いられる穀物粉砕物は、麦芽粉砕物であることが好ましい。麦芽粉砕物を用いることにより、ビールらしさがよりはっきりとした発酵ビール様発泡性飲料を製造することができる。麦芽粉砕物は、大麦、例えば二条大麦を、常法により発芽させ、これを乾燥後、所定の粒度に粉砕したものであればよい。また、本発明において用いられる穀物原料としては、1種類の穀物原料であってもよく、複数種類の穀物原料を混合したものであってもよい。例えば、主原料として麦芽粉砕物を、副原料として米やトウモロコシの粉砕物を用いてもよい。糖質原料としては、例えば、液糖等の糖類が挙げられる。 First, a mixture containing at least one of a grain raw material and a sugar raw material and raw material water is prepared and heated, and starch such as grain raw material is saccharified to prepare a sugar liquid. As a raw material of a sugar liquid, only a grain raw material may be used, only a sugar raw material may be used, or both may be mixed and used. Examples of grain raw materials include barley and wheat, barley such as malt thereof, beans such as rice, corn and soybean, potato and the like. Although a grain raw material can also be used as a grain syrup, a grain extract, etc., it is preferable to use as a grain ground material obtained by grinding. The grinding treatment of grains can be performed by a conventional method. The ground grain product may be a ground malt material, corn starch, corn grits or the like, which has been subjected to a treatment which is usually carried out before or after the grinding treatment. In the present invention, it is preferable that the ground cereals used be ground malts. By using a malt ground material, it is possible to produce a fermented beer-like effervescent beverage having a clearer beer-like character. The ground malt may be barley, for example, two-row barley, which is germinated by a conventional method, dried, and then ground to a predetermined particle size. In addition, as a grain material used in the present invention, one kind of grain material may be used, or a mixture of plural kinds of grain materials may be used. For example, ground malt may be used as the main raw material, and ground rice or corn may be used as the auxiliary raw material. As a saccharide | sugar raw material, saccharides, such as liquid sugar, are mentioned, for example.
 本発明の苦味の後キレ向上効果がより効果的に奏されるため、本発明に係るビール様発泡性飲料としては、原料の全量に対する麦芽の使用比率が66質量%以下であることが好ましく、50質量%以下であることがより好ましく、25質量%以下であることがさらに好ましく、麦芽を原料として使用していないことが特に好ましい。なお、麦芽使用比率は、酒税法の規定に則り測定される。 In the beer-like effervescent beverage according to the present invention, the usage ratio of malt to the total amount of the raw materials is preferably 66% by mass or less, since the post-bitter taste post-dampening effect of the present invention is more effectively exhibited. The content is more preferably 50% by mass or less, further preferably 25% by mass or less, and particularly preferably not using malt as a raw material. The malt use ratio is measured in accordance with the provisions of the Liquor Tax Act.
 当該混合物には、穀物原料等と水以外の副原料を加えてもよい。当該副原料としては、例えば、ホップ、食物繊維、酵母エキス、果汁、苦味料、着色料、香草、香料等が挙げられる。また、必要に応じて、α-アミラーゼ、グルコアミラーゼ、プルラナーゼ等の糖化酵素やプロテアーゼ等の酵素剤を添加することができる。 Grain materials and the like and auxiliary materials other than water may be added to the mixture. Examples of the auxiliary material include hops, dietary fiber, yeast extract, fruit juice, bittering agents, coloring agents, herbs, and perfumes. In addition, if necessary, saccharifying enzymes such as α-amylase, glucoamylase and pullulanase and enzyme agents such as protease can be added.
 糖化処理は、穀物原料等由来の酵素や、別途添加した酵素を利用して行う。糖化処理時の温度や時間は、用いた穀物原料等の種類、原料全体に占める穀物原料の割合、添加した酵素の種類や混合物の量、目的とする発酵ビール様発泡性飲料の品質等を考慮して、適宜調整される。例えば、糖化処理は、穀物原料等を含む混合物を35~70℃で20~90分間保持する等、常法により行うことができる。 The saccharification treatment is performed using an enzyme derived from grain raw materials and the like and an enzyme added separately. The temperature and time of the saccharification treatment take into consideration the type of grain raw material used, the ratio of grain raw material to the whole raw material, the type of enzyme added and the amount of mixture, and the quality of the target fermented beer-like foamable beverage etc. And adjusted accordingly. For example, the saccharification treatment can be carried out by a conventional method such as maintaining a mixture containing grain raw materials and the like at 35 to 70 ° C. for 20 to 90 minutes.
 糖化処理後に得られた糖液を煮沸することにより、煮汁(糖液の煮沸物)を調製することができる。糖液は、煮沸処理前に濾過し、得られた濾液を煮沸処理することが好ましい。また、この糖液の濾液に替わりに、麦芽エキスに温水を加えたものを用い、これを煮沸してもよい。煮沸方法及びその条件は、適宜決定することができる。 Boiling (boiling product of sugar liquid) can be prepared by boiling the sugar liquid obtained after the saccharification treatment. The sugar solution is preferably filtered before boiling and the resulting filtrate is preferably boiled. Also, instead of the filtrate of the sugar solution, malt extract with hot water may be used to boil it. The boiling method and its conditions can be determined suitably.
 煮沸処理前又は煮沸処理中に、香草等を適宜添加することにより、所望の香味を有する発酵ビール様発泡性飲料を製造することができる。例えば、ホップを煮沸処理前又は煮沸処理中に添加し、ホップの存在下で煮沸処理することにより、ホップの風味・香気成分、特に苦味成分を効率よく煮出することができる。ホップの添加量、添加態様(例えば数回に分けて添加するなど)及び煮沸条件は、適宜決定することができる。 By adding a herb or the like as appropriate before or during the boiling treatment, a fermented beer-like foamable beverage having a desired flavor can be produced. For example, by adding hops before or during boiling treatment and boiling treatment in the presence of hops, it is possible to efficiently boil the flavor and aroma components of hops, in particular, the bitter taste components. The addition amount of hops, the addition mode (for example, addition in several times, etc.) and the boiling conditions can be appropriately determined.
 煮沸処理後に得られた煮汁には、沈殿により生じたタンパク質等の粕が含まれている。そこで、煮汁から粕等の固体分の少なくとも一部を除去する。粕の除去は、いずれの固液分離処理で行ってもよいが、一般的には、ワールプールと呼ばれる槽を用いて沈殿物を除去する。この際の煮汁の温度は、15℃以上であればよく、一般的には50~100℃程度で行われる。粕を除去した後の煮汁(濾液)は、プレートクーラー等により適切な発酵温度まで冷却する。この粕を除去した後の煮汁が、発酵原料液となる。 The broth obtained after the boiling process contains a cocoon such as a protein produced by precipitation. Therefore, at least a portion of solid matter such as salmon is removed from the broth. The removal of soot may be carried out by any solid-liquid separation treatment, but generally, a precipitate called a whirlpool is used to remove the precipitate. The temperature of the soup at this time may be 15 ° C. or higher, and generally, it is carried out at about 50 to 100 ° C. After removing the koji, the broth (filtrate) is cooled to an appropriate fermentation temperature by a plate cooler or the like. Boiled juice after removing the cocoons becomes a fermentation raw material liquid.
 次いで、発酵工程として、冷却した発酵原料液に酵母を接種して、発酵を行う。冷却した発酵原料液は、そのまま発酵工程に供してもよく、所望のエキス濃度に調整した後に発酵工程に供してもよい。発酵に用いる酵母は特に限定されるものではなく、通常、酒類の製造に用いられる酵母の中から適宜選択して用いることができる。上面発酵酵母であってもよく、下面発酵酵母であってもよいが、大型醸造設備への適用が容易であることから、下面発酵酵母であることが好ましい。 Next, in the fermentation step, the fermented raw material liquid that has been cooled is inoculated with yeast to carry out fermentation. The cooled fermentation raw material liquid may be subjected to the fermentation process as it is, or may be subjected to the fermentation process after being adjusted to a desired extract concentration. The yeast used for fermentation is not particularly limited, and usually can be selected appropriately from yeasts used for producing alcoholic beverages. It may be a top surface fermentation yeast or a bottom surface fermentation yeast, but is preferably a bottom surface fermentation yeast because application to large-scale brewing equipment is easy.
 さらに、貯酒工程として、得られた発酵液を、貯酒タンク中で熟成させ、0℃程度の低温条件下で貯蔵し安定化させた後、濾過工程として、熟成後の発酵液を濾過することにより、酵母及び当該温度域で不溶なタンパク質等を除去して、目的の発酵ビール様発泡性飲料を得ることができる。当該濾過処理は、酵母を濾過除去可能な手法であればよく、例えば、珪藻土濾過、平均孔径が0.4~1.0μm程度のフィルターによるフィルター濾過等が挙げられる。 Furthermore, as a storage step, the obtained fermentation broth is aged in a storage tank, stored and stabilized under low temperature conditions of about 0 ° C., and then, as a filtration step, the fermentation broth after aging is filtered. Yeast and proteins insoluble in the temperature range can be removed to obtain the desired fermented beer-like effervescent beverage. The filtration process may be any method that can filter and remove yeast, and examples thereof include diatomaceous earth filtration and filter filtration with a filter having an average pore diameter of about 0.4 to 1.0 μm.
 発酵工程を経ずに製造される非発酵ビール様発泡性飲料は、一般的には、各原料を混合する方法(調合法)によって製造できる。例えば、具体的には、各原料を混合することにより、調合液を調製する調合工程と、得られた調合液に炭酸ガスを加えるガス導入工程と、により製造することができる。 A non-fermented beer-like effervescent beverage produced without undergoing a fermentation step can generally be produced by a method (formulation method) of mixing the respective raw materials. For example, specifically, by mixing each raw material, it can manufacture by the preparation process of preparing a preparation liquid, and the gas introduction process of adding carbon dioxide gas to the obtained preparation liquid.
 まず、調合工程において、原料を混合することにより、調合液を調製する。調合工程においては、炭酸ガス以外の全ての原料を混合した調合液を調製することが好ましい。各原料を混合する順番は特に限定されるものではない。原料水に、全ての原料を同時に添加してもよく、先に添加した原料を溶解させた後に残る原料を添加する等、順次原料を添加してもよい。また、例えば、原料水に、固形(例えば粉末状や顆粒状)の原料及びアルコールを混合してもよく、固形原料を予め水溶液としておき、これらの水溶液、及びアルコール、必要に応じて原料水を混合してもよい。さらに、原料水に原料を加熱したものを入れてもよく、調製した調合液を加熱してもよい。 First, in the preparation step, the preparation solution is prepared by mixing the raw materials. In the preparation step, it is preferable to prepare a preparation solution in which all the raw materials other than carbon dioxide gas are mixed. The order of mixing the respective raw materials is not particularly limited. All the raw materials may be added simultaneously to the raw material water, or the raw materials may be added sequentially, such as adding the raw materials remaining after dissolving the previously added raw materials. In addition, for example, the raw material water may be mixed with solid (for example, powder or granular) raw material and alcohol, and the solid raw material is previously made into an aqueous solution, and these aqueous solutions and alcohol, if necessary, raw material water It may be mixed. Furthermore, what heated the raw material may be put into raw material water, and the prepared liquid preparation may be heated.
 原料としては、苦味料、酸味料、甘味料、水溶性食物繊維、カラメル色素、香味料、エタノール、起泡剤、タンパク質若しくはその分解物、酵母エキス等が挙げられる。
 苦味料としては、ホップ、ホップエキス、ホップ中の苦味成分をイソ化した成分を含むホップ加工品、及び前記で挙げたホップに由来する苦味成分以外の苦味料が挙げられる。本発明に係るビール様発泡性飲料が含む苦味料としては、ホップエキス又はホップ加工品が好ましく、イソ化ホップエキスが特に好ましい。
As a raw material, a bitter taste agent, an acidulant, a sweetener, a water-soluble dietary fiber, caramel pigment, a flavor agent, ethanol, a foaming agent, a protein or its degradation product, a yeast extract and the like can be mentioned.
Examples of the bitter taste agent include hops, hop extracts, processed hop products containing a component obtained by isocyanating the bitter taste component in hop, and bitter taste agents other than the bitter taste components derived from hops mentioned above. The bitter taste agent contained in the beer-like foamable beverage according to the present invention is preferably a hop extract or a hop processed product, particularly preferably an iso-ized hop extract.
 酸味料としては、クエン酸、グルコン酸、酒石酸、リンゴ酸、コハク酸、リン酸、乳酸、アジピン酸、及びフマル酸等の有機酸が挙げられる。 Examples of the acidulant include organic acids such as citric acid, gluconic acid, tartaric acid, malic acid, succinic acid, phosphoric acid, lactic acid, adipic acid, and fumaric acid.
 甘味料としては、ショ糖、液糖、オリゴ糖、デキストリン、でんぷん、甘味系アミノ酸、高感度甘味料等が挙げられる。甘味系アミノ酸としては、アラニンやグリシンが挙げられ、アラニンが好ましい。当該高感度甘味料としては、アセスルファムカリウム、アスパルテーム、ステビア、酵素処理ステビア、スクラロース等が挙げられる。 Sweeteners include sucrose, liquid sugar, oligosaccharides, dextrin, starch, sweet amino acids, high sensitivity sweeteners and the like. Examples of sweetening-type amino acids include alanine and glycine, with alanine being preferred. Examples of the high sensitivity sweetener include acesulfame potassium, aspartame, stevia, enzyme-treated stevia, sucralose and the like.
 水溶性食物繊維とは、水に溶解し、かつヒトの消化酵素により消化されない又は消化され難い炭水化物を意味する。水溶性食物繊維としては、例えば、大豆食物繊維、ポリデキストロース、難消化性デキストリン、ガラクトマンナン、イヌリン、グアーガム分解物、ペクチン、アラビアゴム等が挙げられる。 By water soluble dietary fiber is meant a carbohydrate which is soluble in water and which is not or hardly digested by human digestive enzymes. Examples of the water-soluble dietary fiber include soybean dietary fiber, polydextrose, indigestible dextrin, galactomannan, inulin, guar gum degradation products, pectin, gum arabic and the like.
 香味料としては、ビール抽出物、ビール香料、ホップ香料等が挙げられる。
 起泡剤としては、例えば、大豆ペプチド、大豆サポニン、アルギン酸エステル、キラヤサポニン等が挙げられる。
Examples of the flavor include beer extract, beer flavor, hop flavor and the like.
Examples of the foaming agent include soy peptide, soy saponin, alginate, quillaja saponin and the like.
 本発明の苦味の後キレ向上効果がより効果的に奏されるため、本発明に係る非発酵ビール様発泡性飲料としては、固形原料の全量に対する麦芽の使用比率が66質量%以下であることが好ましく、50質量%以下であることがより好ましく、25質量%以下であることがさらに好ましく、麦芽を原料として使用していないことが特に好ましい。なお、麦芽使用比率は、酒税法の規定に則り測定される。 Since the post-bittering effect of the present invention is more effectively exhibited, the use ratio of malt to the total amount of the solid material is 66% by mass or less as the non-fermented beer-like effervescent beverage according to the present invention. Is more preferably 50% by mass or less, still more preferably 25% by mass or less, and it is particularly preferable that malt is not used as a raw material. The malt use ratio is measured in accordance with the provisions of the Liquor Tax Act.
 調合工程において調製された調合液に、不溶物が生じた場合には、ガス導入工程の前に、当該調合液に対して濾過等の不溶物を除去する処理を行うことが好ましい。不溶物除去処理は、特に限定されるものではなく、濾過法、遠心分離法等の当該技術分野で通常用いられている方法で行うことができる。本発明においては、不溶物は濾過除去することが好ましく、珪藻土濾過により除去することがより好ましい。 When insoluble matter is generated in the preparation liquid prepared in the preparation process, it is preferable to carry out a process of removing the insoluble matter such as filtration to the preparation liquid prior to the gas introduction step. The insoluble matter removal treatment is not particularly limited, and can be carried out by methods commonly used in the relevant technical field such as filtration method and centrifugation method. In the present invention, insolubles are preferably removed by filtration, and more preferably removed by diatomaceous earth filtration.
 次いで、ガス導入工程として、調合工程により得られた調合液に炭酸ガスを加える。これにより、非発酵ビール様発泡性飲料を得る。炭酸を加えることによって、ビールと同様の爽快感が付与される。なお、炭酸ガスの添加は、常法により行うことができる。例えば、調合工程により得られた調合液、及び炭酸水を混合してよく、調合工程により得られた調合液に炭酸ガスを直接加えて溶け込ませてもよい。 Subsequently, carbon dioxide gas is added to the preparation liquid obtained by the preparation process as a gas introduction process. This gives a non-fermented beer-like effervescent beverage. By adding carbonation, the same refreshing feeling as beer is provided. The addition of carbon dioxide gas can be performed by a conventional method. For example, the preparation liquid obtained by the preparation process and carbonated water may be mixed, or carbon dioxide gas may be directly added to and dissolved in the preparation liquid obtained by the preparation process.
 炭酸ガスを添加した後、得られた非発酵ビール様発泡性飲料に対して、さらに濾過等の不溶物を除去する処理を行ってもよい。不溶物除去処理は、特に限定されるものではなく、当該技術分野で通常用いられている方法で行うことができる。 After carbon dioxide gas is added, the obtained non-fermented beer-like effervescent beverage may be further subjected to a treatment for removing insoluble matter such as filtration. The insoluble matter removing process is not particularly limited, and can be performed by a method commonly used in the relevant technical field.
 次に実施例等を示して本発明をさらに詳細に説明するが、本発明は以下の実施例等に限定されるものではない。 EXAMPLES The present invention will next be described in more detail by way of examples, which should not be construed as limiting the invention thereto.
<苦味価>
 以降の実験において、ビール様発泡性飲料の苦味価は、EBC法に準じて測定した。
<Bitterness value>
In the subsequent experiments, the bitterness value of the beer-like effervescent beverage was measured according to the EBC method.
<炭酸ガス含有量>
 以降の実験において、ビール様発泡性飲料の炭酸ガス含有量は、飲料分析装置「Orbisphere 6110 Beverage Analyzer」(HACH社製)を用いて20℃で測定した。
<CO2 content>
In the subsequent experiments, the carbon dioxide content of the beer-like effervescent beverage was measured at 20 ° C. using a beverage analyzer “Orbisphere 6110 Beverage Analyzer” (manufactured by HACH).
<プロリン含有量>
 以降の実験において、ビール様発泡性飲料のプロリン含有量は、(米国)ウォーターズ社製Acquity UPLC分析装置を用いて、アキュタグウルトラ(AccQ-Tag Ultra)ラベル化法により測定した。検量線は、アミノ酸混合標準液H型(和光純薬社製)を用いて作成した。
<Proline content>
In the following experiments, the proline content of the beer-like effervescent beverage was measured by the AccQ-Tag Ultra labeling method using an Acquity UPLC analyzer manufactured by Waters (US). The calibration curve was prepared using an amino acid mixed standard solution H type (manufactured by Wako Pure Chemical Industries, Ltd.).
<官能評価>
 以降の実験において、ビール様発泡性飲料の苦味の強さと苦味の残りの官能評価は、次のようにして実施した。なお、苦味の強さとは、液を口に含んだ際にホップ由来の苦みを感じる最高点での強さを表し、苦味の残りとは、飲み込んで数秒後に残っている苦味の強度と定義した。
<Sensory evaluation>
In the subsequent experiments, the bitterness strength of beer-like effervescent beverages and the sensory evaluation of the remaining bitterness were carried out as follows. In addition, the intensity of bitterness refers to the intensity at the highest point where the bitterness derived from hops is felt when the solution is contained in the mouth, and the remainder of bitterness is defined as the intensity of bitterness remaining several seconds after swallowing. .
 具体的には、10名の訓練されたビール専門パネルにより、ビール様発泡性飲料の苦味の強さと苦味の残りを、対照サンプルと比較して評価した。苦味の強さの評価は、1点が対照サンプルに比べて苦味が弱い、2点が苦味の強さが対照と同等である、3点が対照サンプルに比べて苦味が強い、とした。苦味の残りの評価は、1点が対照サンプルに比べて苦味が残る、2点が苦味の残りが対照と同等である、3点が対照サンプルに比べて苦味が残らない、とした。各サンプルの評価点は、10名の訓練されたビール専門パネルの評価点の平均値とした。各サンプルの評価点が1.5点以下又は2.5点以上の場合に、当該サンプルは対照サンプルと差があると判断した。 Specifically, ten trained beer specialist panels were used to evaluate the bitterness intensity and bitterness remainder of the beer-like effervescent beverage as compared to the control sample. The evaluation of the intensity of bitter taste was made such that one point was weaker in bitterness than the control sample, two points were similar in bitterness intensity to the control, and three points were stronger in bitter taste than the control sample. The evaluation of the remaining bitter taste was made that one point remained bitter compared to the control sample, two points were bitter remaining similar to the control, and three points remained no bitter taste compared to the control sample. The score for each sample was the average of the scores of 10 trained beer specialist panels. When the score of each sample was 1.5 points or less or 2.5 points or more, it was judged that the sample was different from the control sample.
[実施例1]
 非発酵ビール様発泡性飲料のうち、アルコールを全く含有しないノンアルコールビールにおける苦味の残りへの炭酸ガスの含有量の影響を調べた。
 まず、デキストリン25g、液糖10g、カラメル0.3g、リン酸0.7g、及び香料1.0gを1Lの水に混合したものに、イソ化ホップエキス(John I. Haas, Inc製)を最終的に得られるビール様発泡性飲料の苦味価が17BUとなるように添加した炭酸ガス非含有原料液を調製した。
Example 1
Among non-fermented beer-like effervescent beverages, the influence of the content of carbon dioxide gas on the residual bitterness in non-alcohol beer containing no alcohol was investigated.
First, a mixture of 1 g of water with 25 g of dextrin, 10 g of liquid sugar, 0.3 g of caramel, 0.7 g of phosphoric acid, and 1.0 g of a fragrance is added with isoated hop extract (manufactured by John I. Haas, Inc.). A carbon dioxide gas-free raw material solution was prepared which was added such that the bitterness value of the beer-like foamable beverage obtained as above became 17 BU.
 この炭酸ガス非含有原料液に、2.9GV(対照1)、3.2GV(試験1)、3.5GV(試験2)、3.8GV(試験3)、4.1GV(試験4)、又は4.4GV(試験5)となるように炭酸ガスを溶解させて、ノンアルコールビールを製造し、苦味の強さと苦味の残りの官能評価を行った。 In this carbon dioxide gas-free raw material solution, 2.9 GV (Control 1), 3.2 GV (Test 1), 3.5 GV (Test 2), 3.8 GV (Test 3), 4.1 GV (Test 4), or Carbon dioxide gas was dissolved so as to be 4.4 GV (Test 5) to produce a non-alcohol beer, and the strength of bitter taste and the sensory evaluation of the remaining bitter taste were performed.
Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000001
 各サンプルの評価結果を表1に示す。試験1~5のノンアルコールビールでは、炭酸ガスの含有量にかかわらず、苦みの強さは対照1のノンアルコールビールと同程度であった。一方で、苦みの残りの評点は、炭酸ガスの含有量依存的に大きくなっており、炭酸ガスの含有量が多くなるほど苦味の後キレが向上していた。 The evaluation results of each sample are shown in Table 1. In the non-alcohol beer of trials 1 to 5, regardless of the carbon dioxide content, the bitterness intensity was comparable to that of the control 1 non-alcohol beer. On the other hand, the remaining scores of bitterness were increased depending on the content of carbon dioxide gas, and as the content of carbon dioxide gas was increased, the aftertaste of bitter taste was improved.
[実施例2]
 苦みの異なるノンアルコールビールにおける苦味の残りへの炭酸ガスの含有量の影響を調べた。
Example 2
The influence of carbon dioxide content on the bitterness residue in non-alcohol beer with different bitterness was investigated.
 イソ化ホップエキスの使用量を、最終的に得られるビール様発泡性飲料の苦味価が5~35BUとなるように添加した以外は実施例1と同様にして炭酸ガス非含有原料液を調製した。
 得られた炭酸ガス非含有原料液に、2.9GV(対照サンプル)又は4.0GV(試験サンプル)となるように炭酸ガスを溶解させて、ノンアルコールビールを製造した。4.0GVの試験サンプルに対して、苦味価が等しい2.9GVの対照サンプルをそれぞれ比較して、苦味の強さと苦味の残りの官能評価を行った。
A carbon dioxide gas-free material solution was prepared in the same manner as in Example 1 except that the amount of the isotroped hop extract was added so that the bitterness value of the finally obtained beer-like effervescent beverage was 5 to 35 BU. .
A carbon dioxide gas was dissolved in the obtained carbon dioxide gas-free raw material solution so as to be 2.9 GV (control sample) or 4.0 GV (test sample) to produce a non-alcohol beer. The test samples of 4.0 GV were compared with the control samples of 2.9 GV with equal bitter value, respectively, to make a sensory evaluation of the strength of bitterness and the remaining bitterness.
Figure JPOXMLDOC01-appb-T000002
Figure JPOXMLDOC01-appb-T000002
 各サンプルの評価結果を表2に示す。なお、表2には試験サンプルの欄しかないが、これらの結果は全て、それぞれの対照サンプルと比較した結果である。苦味の強さは、試験6~12のノンアルコールビールのいずれも、評点が1.5超2.5未満であり、それぞれの対照サンプルとの差がなく、炭酸ガス含有量は苦味の強さには影響しないことがわかった。一方で、苦味の残りは、苦味価が5BUの試験6のノンアルコールビールは対照サンプルと差がなかったものの、苦味価が10~30BUの試験7~11のノンアルコールビールでは、評点が2.5超であり、2.9GVの対照サンプルよりも4.0GVの試験サンプルのほうが苦味の残りが少なく、苦味の後キレが明らかに向上していた。 The evaluation results of each sample are shown in Table 2. In addition, although there is only a column of a test sample in Table 2, all these results are the results compared with each control sample. The bitterness intensity was rated at more than 1.5 and less than 2.5 for all the non-alcohol beer in trials 6 to 12, and there was no difference from the respective control samples, and the carbon dioxide content was bitterness intensity. It did not affect the On the other hand, the remaining bitterness was not different from the control sample in the non-alcohol beer of Test 6 having a bitterness value of 5 BU, but the non-alcohol beer of Trial 7 to 11 having a bitterness value of 10 to 30 BU had a score of 2. The test sample with 4.0 GV was more than 5 and had less bitter taste remaining than the control sample with 2.9 GV, and the post-bitter taste was clearly improved.
[実施例3]
 イソ化ホップエキスにかえてホップエキスを用いた場合のノンアルコールビールにおける苦味の残りへの炭酸ガスの含有量の影響を調べた。
[Example 3]
The effect of carbon dioxide gas content on the remaining bitter taste in non-alcohol beer was investigated using hop extract instead of isoated hop extract.
 まず、デキストリン25g、液糖10g、大豆タンパク質分解物2g、カラメル0.3g、リン酸0.7g、及び香料1.0gを1Lの水に混合したものに、ホップエキス(John I. Haas, Inc製)を最終的に得られるビール様発泡性飲料の苦味価が17BUとなるように添加して原料液を調整した。この原料液を100℃で1時間煮沸した後、蒸発分の水を加えて冷却し、珪藻土を用いた濾過及びフィルターを用いた濾過を実施し、さらに1.0g/Lとなるように香料添加して、炭酸ガス非含有原料液を調製した。 First, hop extract (John I. Haas, Inc.) was prepared by mixing 25 g of dextrin, 10 g of liquid sugar, 2 g of soybean protein hydrolyzate, 0.3 g of caramel, 0.7 g of phosphoric acid, and 1.0 g of flavor in 1 L of water. Made to adjust the bitterness value of the beer-like effervescent beverage finally obtained to 17 BU to adjust the raw material liquid. This raw material solution is boiled at 100 ° C. for 1 hour, and the water for evaporation is added and cooled, filtration using diatomaceous earth and filtration using a filter are carried out, and a flavor addition is further performed to be 1.0 g / L. Then, a carbon dioxide-free raw material solution was prepared.
 この炭酸ガス非含有原料液に、2.9GV(対照2)、3.2GV(試験13)、3.5GV(試験14)、3.8GV(試験15)、4.1GV(試験16)、又は4.4GV(試験17)となるように炭酸ガスを溶解させて、ノンアルコールビールを製造し、苦味の強さと苦味の残りの官能評価を、対照2のサンプル(ホップエキスを添加して煮沸させたノンアルコールビール)を対照サンプルとして用いて行った。 In this carbon dioxide gas-free raw material solution, 2.9 GV (Control 2), 3.2 GV (Test 13), 3.5 GV (Test 14), 3.8 GV (Test 15), 4.1 GV (Test 16), or Carbon dioxide gas is dissolved so as to be 4.4 GV (Test 17) to produce a non-alcohol beer, and the bitterness strength and the sensory evaluation of the remaining bitter taste are compared with samples of Control 2 (add hop extract and boil (Non-alcohol beer) was used as a control sample.
Figure JPOXMLDOC01-appb-T000003
Figure JPOXMLDOC01-appb-T000003
 各サンプルの評価結果を、実施例1の対照1のノンアルコールビールの結果と共に表3に示す。この結果、実施例1のイソ化ホップエキスを用いた場合と同様に、試験13~17のノンアルコールビールはいずれも苦みの強さの評点が1.5超2.5未満であり、炭酸ガスの含有量にかかわらず、苦みの強さは対照2のノンアルコールビールと同程度であった。また、苦みの残りについても、実施例1の結果と同様に、炭酸ガスの含有量依存的に苦みの残りの評点が大きくなっており、炭酸ガスの含有量が多くなるほど苦味の後キレが向上していた。 The evaluation results of each sample are shown in Table 3 together with the results of the non-alcohol beer of Control 1 of Example 1. As a result, as in the case of using the isoated hop extract of Example 1, all of the non-alcohol beers of Tests 13 to 17 have bitterness strength scores of more than 1.5 and less than 2.5, and carbon dioxide gas The bitterness was similar to that of Control 2 non-alcohol beer, regardless of its content. Further, with regard to the remainder of bitterness, as in the case of Example 1, the score of the remaining bitterness is increased depending on the content of carbon dioxide gas, and as the content of carbon dioxide gas increases, the aftertaste of bitter taste improves Was.
 一方で、対照1のノンアルコールビール(イソ化ホップエキスを含有させたノンアルコールビール)は、苦味の強さは対照2(ホップエキスを添加して煮沸させたノンアルコールビール)と同程度であったが、苦味の残りの評点1.5であり、対照2よりも苦味がより強く残っていた。つまり、イソ化ホップエキスを配合したビール様発泡性飲料は、ホップエキスを添加して煮沸処理されたビール様発泡性飲料よりも、苦味の残りが強いことが確認された。 On the other hand, the non-alcohol beer of the control 1 (non-alcohol beer containing isopinated hop extract) is similar in bitterness strength to the control 2 (non-alcohol beer boiled with the addition of hop extract) However, the remaining bitterness score was 1.5, and the bitterness remained stronger than Control 2. That is, it was confirmed that the beer-like effervescent beverage blended with the iso-ized hop extract has a stronger bitterness remaining than the beer-like effervescent beverage to which the hop extract is added and subjected to boiling treatment.
[実施例4]
 麦芽使用比率の異なる発酵ビール様発泡性飲料における苦味の残りへの炭酸ガスの含有量の影響を調べた。
Example 4
The influence of the content of carbon dioxide gas on the remainder of the bitter taste in fermented beer-like effervescent beverages with different malt use ratios was investigated.
 仕込槽に、40kgの粉砕麦芽と温水100Lを投入し、50℃から76℃の範囲の温度でタンパク休止及び糖化を行った。得られた糖化液を濾過槽であるロイターにて濾過した後、煮沸釜に移した。煮沸釜に、ホップエキス(John I. Haas, Inc製)を最終的に得られるビールの苦味価が17BUとなるように添加し、液量を160Lにした上で60分間煮沸した。煮沸後、蒸発分の温水を追加し、ワールプール槽にて熱トルーブを除去した後、プレートクーラーを用いて8℃まで冷却して、170Lの冷麦汁を得た。この冷麦汁を発酵槽に移し、酵母を接種させて7日間10℃前後で発酵させた後、酵母を除去した。得られた発酵液を熟成用槽に移し替え、7日間熟成させた後、-1℃付近まで冷却して14日間安定化させた。安定化後の発酵液に脱気水を加えて希釈した後、得られた希釈液を珪藻土を用いて濾過することによって清澄な発酵ビール様発泡性飲料(麦芽使用比率100質量%)を製造した。この発酵ビール様発泡性飲料に4.1GVとなるように炭酸ガスを溶解させたものを、試験液Aとした。 40 kg of ground malt and 100 L of warm water were charged into a feed tank, and protein rest and saccharification were performed at a temperature in the range of 50 ° C to 76 ° C. The obtained saccharified solution was filtered by Reuters which is a filter tank, and then transferred to a boiling kettle. The hop extract (manufactured by John I. Haas, Inc.) was added to a boiling kettle so that the bitterness value of the finally obtained beer became 17 BU, and the solution volume was adjusted to 160 L and boiled for 60 minutes. After boiling, warm water of the evaporation was added, and after removing the heat torube with a whirlpool tank, it was cooled to 8 ° C. using a plate cooler to obtain 170 L of cold wort. The cold wort was transferred to a fermenter, inoculated with yeast, fermented at about 10 ° C. for 7 days, and then the yeast was removed. The obtained fermentation broth was transferred to a aging tank, aged for 7 days, cooled to about -1 ° C., and stabilized for 14 days. Degassed water was added to the fermented liquid after stabilization to dilute, and the obtained diluted liquid was filtered using diatomaceous earth to produce a clear fermented beer-like foamable beverage (malt usage ratio 100 mass%). . Test liquid A was prepared by dissolving carbon dioxide gas so as to be 4.1 GV in this fermented beer-like foamable beverage.
 煮沸釜にて、液糖35kg、酵母エキス0.5kg、大豆タンパク質0.1kg、カラメル0.05kg、及びホップエキス(John I. Haas, Inc製)を添加し、液量を160Lにした上で60分間煮沸した。ホップエキスは、最終的に得られるビールの苦味価が17BUとなるように添加した。煮沸後、蒸発分の温水を追加し、ワールプール槽にて熱トルーブを除去した後、プレートクーラーを用いて8℃まで冷却して、170Lの冷麦汁を得た。この冷麦汁を発酵槽に移し、酵母を接種させて7日間10℃前後で発酵させた後、酵母を除去した。得られた発酵液を熟成用槽に移し替え、7日間熟成させた後、-1℃付近まで冷却して14日間安定化させた。安定化後の発酵液に脱気水を加えて希釈した後、得られた希釈液を珪藻土を用いて濾過することによって清澄な発酵ビール様発泡性飲料(麦芽使用比率0質量%)を製造した。この発酵ビール様発泡性飲料に4.1GVとなるように炭酸ガスを溶解させたものを、試験液Bとした。 In a boiling kettle, add 35 kg of liquid sugar, 0.5 kg of yeast extract, 0.1 kg of soy protein, 0.1 kg of caramel, and hop extract (manufactured by John I. Haas, Inc.) to make the liquid volume 160 L. Boiled for 60 minutes. Hop extract was added so that the bitterness value of the finally obtained beer would be 17 BU. After boiling, warm water of the evaporation was added, and after removing the heat torube with a whirlpool tank, it was cooled to 8 ° C. using a plate cooler to obtain 170 L of cold wort. The cold wort was transferred to a fermenter, inoculated with yeast, fermented at about 10 ° C. for 7 days, and then the yeast was removed. The obtained fermentation broth was transferred to a aging tank, aged for 7 days, cooled to about -1 ° C., and stabilized for 14 days. Degassed water was added to the fermented liquid after stabilization to dilute, and then the obtained diluted liquid was filtered using diatomaceous earth to produce a clear fermented beer-like effervescent beverage (malt usage ratio 0 mass%) . A liquid obtained by dissolving carbon dioxide gas so as to be 4.1 GV in this fermented beer-like foamable beverage was used as a test solution B.
 試験液Aと試験液Bのプロリン含有量を測定したところ、試験液Aは45mg/100mL、試験液Bは5mg/100mLであった。 When the proline content of the test solution A and the test solution B was measured, the test solution A was 45 mg / 100 mL, and the test solution B was 5 mg / 100 mL.
 この試験液Aと試験液Bを適宜混合することにより、プロリン含有量が表4に記載の通りのサンプルを調製した。各サンプルの苦味の残りの官能評価を行った。官能評価における対照サンプルは、試験液Bを調製する前の発酵ビール様発泡性飲料に2.9GVとなるように炭酸ガスを溶解させたもの(対照3)を用いた。 By mixing the test solution A and the test solution B as appropriate, samples having a proline content as described in Table 4 were prepared. A sensory evaluation of the remaining bitterness of each sample was performed. As a control sample in the sensory evaluation, a fermented beer-like effervescent beverage in which carbon dioxide gas was dissolved so as to be 2.9 GV (Control 3) was used before preparing the test solution B.
Figure JPOXMLDOC01-appb-T000004
Figure JPOXMLDOC01-appb-T000004
 各サンプルの評価結果を表4に示す。対照3の発酵ビール様発泡性飲料と試験18の発酵ビール様発泡性飲料を比較したところ、実施例1の非発酵ビール様発泡性飲料と同様に、炭酸ガス含有量が多い試験18の発酵ビール様発泡性飲料では、苦味の後キレが明らかに向上していた。 The evaluation results of each sample are shown in Table 4. When the fermented beer-like foamable drink of Control 3 was compared with the fermented beer-like foamable drink of Test 18, similar to the non-fermented beer-like foamable beverage of Example 1, the fermented beer of Test 18 having a high carbon dioxide gas content In the effervescent beverage, the bitter taste was clearly improved after the bitter taste.
 また、試験18~試験23の発酵ビール様発泡性飲料では、プロリン含有量が少ないほど、すなわち麦芽使用比率が低いほど、苦味の残りの評点が高く、苦味の後キレが良好であった。この結果から、麦芽使用比率が低く、味の厚み(味ボリューム)の小さいビール様発泡性飲料のほうが、高ガス圧による苦味の後キレ向上効果がより強く得られることがわかった。 In addition, in the fermented beer-like effervescent beverages of Tests 18 to 23, the lower the proline content, that is, the lower the malt usage ratio, the higher the score of the remaining bitter taste is, and the better the bitter taste is after being crisp. From this result, it was found that the beer-like foamable beverage having a low malt usage ratio and a small taste thickness (taste volume) can obtain a stronger effect of improving the aftertaste after bitter taste due to high gas pressure.

Claims (13)

  1.  苦味価が10BU以上であり、20℃における炭酸ガス含有量が3.7GV以上であることを特徴とする、ビール様発泡性飲料。 A beer-like foamable beverage characterized in that the bitterness value is 10 BU or more and the carbon dioxide content at 20 ° C. is 3.7 GV or more.
  2.  苦味価が30BU以下である、請求項1に記載のビール様発泡性飲料。 The beer-like foamable beverage according to claim 1, having a bitterness value of 30 BU or less.
  3.  20℃における炭酸ガス含有量が3.8GV以上である、請求項1又は2に記載のビール様発泡性飲料。 The beer-like foamable drink of Claim 1 or 2 whose carbon dioxide content in 20 degreeC is 3.8 GV or more.
  4.  ホップ中の苦味成分をイソ化した成分を含むホップ加工品を含有する、請求項1~3のいずれか一項に記載のビール様発泡性飲料。 The beer-like foamy beverage according to any one of claims 1 to 3, which comprises a processed hop product containing a component obtained by isolateing a bitter taste component in hops.
  5.  前記ホップ加工品が、イソ化ホップエキスである、請求項4に記載のビール様発泡性飲料。 The beer-like effervescent beverage according to claim 4, wherein the processed hop product is an isoated hop extract.
  6.  プロリン含有量が30mg/100mL以下である、請求項1~5のいずれか一項に記載のビール様発泡性飲料。 The beer-like foamable beverage according to any one of claims 1 to 5, wherein the proline content is at most 30 mg / 100 mL.
  7.  ノンアルコール飲料である、請求項1~6のいずれか一項に記載のビール様発泡性飲料。 The beer-like foamy beverage according to any one of claims 1 to 6, which is a non-alcoholic beverage.
  8.  苦味価が10BU以上であるビール様発泡性飲料を製造する方法であって、
     飲料の20℃における炭酸ガス含有量が3.7GV以上となるように調整することを特徴とする、ビール様発泡性飲料の製造方法。
    A method for producing a beer-like foamy beverage having a bitterness value of 10 BU or more,
    A method for producing a beer-like foamy beverage, wherein the carbon dioxide gas content at 20 ° C. of the beverage is adjusted to 3.7 GV or more.
  9.  ホップ又はホップ加工品を原料とする、請求項8に記載のビール様発泡性飲料の製造方法。 The manufacturing method of the beer-like foamable drink of Claim 8 which uses a hop or a hop processed product as a raw material.
  10.  麦芽を原料として用いない、請求項8又は9に記載のビール様発泡性飲料の製造方法。 The manufacturing method of the beer-like foamable drink of Claim 8 or 9 which does not use a malt as a raw material.
  11.  麦芽の使用比率が66質量%以下である、請求項8又は9に記載のビール様発泡性飲料の製造方法。 The manufacturing method of the beer-like foamable drink of Claim 8 or 9 whose use ratio of malt is 66 mass% or less.
  12.  製造されたビール様発泡性飲料がノンアルコール飲料である、請求項8~11のいずれか一項に記載のビール様発泡性飲料の製造方法。 The method for producing a beer-like foamable beverage according to any one of claims 8 to 11, wherein the produced beer-like foamable beverage is a non-alcoholic beverage.
  13.  苦味価が10BU以上であるビール様発泡性飲料の20℃における炭酸ガス含有量が3.7GV以上となるように調整することを特徴とする、ビール様発泡性飲料の苦味の後キレを向上させる方法。 The bitter taste of the beer-like foamable beverage having a bitterness value of 10 BU or more is adjusted so that the carbon dioxide content at 20 ° C. is 3.7 GV or more. Method.
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