[go: up one dir, main page]
More Web Proxy on the site http://driver.im/

WO2017200036A1 - Scrubbing agent and skin cleansing composition comprising same - Google Patents

Scrubbing agent and skin cleansing composition comprising same Download PDF

Info

Publication number
WO2017200036A1
WO2017200036A1 PCT/JP2017/018632 JP2017018632W WO2017200036A1 WO 2017200036 A1 WO2017200036 A1 WO 2017200036A1 JP 2017018632 W JP2017018632 W JP 2017018632W WO 2017200036 A1 WO2017200036 A1 WO 2017200036A1
Authority
WO
WIPO (PCT)
Prior art keywords
wax particles
hydrocarbon wax
scrub
composition
agent
Prior art date
Application number
PCT/JP2017/018632
Other languages
French (fr)
Japanese (ja)
Inventor
輝礁 松元
Original Assignee
株式会社マンダム
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 株式会社マンダム filed Critical 株式会社マンダム
Priority to JP2018518348A priority Critical patent/JPWO2017200036A1/en
Publication of WO2017200036A1 publication Critical patent/WO2017200036A1/en

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/31—Hydrocarbons
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations

Definitions

  • the present invention relates to a scrub agent and a composition for a skin cleanser containing the scrub agent.
  • various scrub agents are blended from the viewpoint of enhancing the effect of removing dirt on the skin and from the viewpoint of moderately stimulating the skin and imparting a massage effect.
  • a scrubbing agent which is a hard material scrubbing agent such as polyethylene beads, walnut shell particles, and crystalline cellulose powder is used, and among them, polyethylene beads that are remarkably excellent in the above effects are most widely used.
  • the above-mentioned hard scrub agent is excellent in the effect of removing dirt on the skin and the effect of stimulating and massaging the skin, but may feel uncomfortable skin irritation and foreign body feeling when used. In addition, there is a risk of damaging the eyeball when it enters the eye during washing. Furthermore, in recent years, there has been a movement in the cosmetics industry to refrain from using hard scrub agents such as polyethylene beads that are not biodegradable in consideration of environmental pollution.
  • soft scrub agents which are scrub agents made of a softer material than the hard scrub agent, are also used in conventional skin cleansing compositions. Specifically, agar, polyacrylate, alginate and the like are used. Such soft scrubbing agents do not feel uncomfortable skin irritation or foreign body feeling during use and are excellent in use feeling, but have a problem that they are inferior in scrubbing effect.
  • An object of the present invention is to provide a scrubbing agent that is excellent in feeling of use without an unpleasant skin irritation or foreign body feeling at the time of use, exhibits an appropriate scrubbing effect, and contains the scrubbing agent in consideration of the influence on environmental pollution. It is providing the composition for skin cleansing agents.
  • the present invention provides a scrub agent characterized by being hydrocarbon wax particles.
  • the average particle diameter of the hydrocarbon wax particles is preferably 100 to 1,000 ⁇ m.
  • the hydrocarbon wax particles are preferably selected from the group of petroleum-derived hydrocarbon wax particles and synthetic hydrocarbon wax particles.
  • the present invention also provides a composition for a skin cleanser comprising the scrub agent described above.
  • the content of the scrub agent in the composition for skin cleanser is preferably 0.1 to 30% by mass.
  • composition for skin cleanser contains a higher fatty acid salt.
  • the scrub agent of the present invention Since the scrub agent of the present invention has biodegradability, it does not have an adverse effect on environmental pollution. Moreover, the composition for skin cleansing agents of the present invention containing the scrub agent exhibits an excellent scrub effect and also exhibits an excellent effect on the feeling of use with no unpleasant skin irritation or foreign body sensation during use.
  • the scrub agent of the present invention is hydrocarbon wax particles.
  • Hydrocarbon wax particles are particles mainly composed of hydrocarbon waxes such as linear hydrocarbons (normal paraffins), branched hydrocarbons (isoparaffins), saturated cyclic hydrocarbons (cycloparaffins), and are biodegradable. have. That is, there is no adverse effect on environmental pollution.
  • the scrub agent of this invention means that it is a scrub agent comprised only with the said hydrocarbon wax particle,
  • the hydrocarbon wax particle is used as a use of a scrub agent, It is characterized by the above-mentioned.
  • the particle diameter of the hydrocarbon wax particles is not particularly limited, but from the viewpoint of exhibiting an excellent scrub effect without unpleasant skin irritation, it is preferable to use particles having an average particle diameter in the range of 100 to 1,000 ⁇ m. More preferably, the thickness is 200 to 900 ⁇ m.
  • hydrocarbon wax particles examples include petroleum-derived hydrocarbon wax particles and synthetic hydrocarbon wax particles.
  • the “petroleum-derived hydrocarbon wax particles” may be referred to as “component a1”.
  • the “synthetic hydrocarbon wax particles” may be referred to as “component a2”.
  • the component a1 and the component a2 one type may be used alone, or two or more types may be used in appropriate combination.
  • the component a1 include paraffin wax particles and microcrystalline wax particles.
  • the melting point of the paraffin wax particles is not particularly limited, but is preferably 40 to 80 ° C., more preferably 60 to 80 ° C.
  • the melting point of the microcrystalline wax particles is not particularly limited, but is preferably 60 to 105 ° C.
  • the granulation method of component a1 is not particularly limited as long as it is a known method. For example, a method of separating and extracting hydrocarbons with good crystallinity from a crude oil vacuum distillation distillate part, a crude oil vacuum distillation residue oil part, The method of taking out is mentioned.
  • specific examples of the component a2 include Fischer-Tropsch wax particles.
  • the Fischer-Tropsch wax particles are obtained by the Fischer-Tropsch manufacturing method.
  • the melting point of the Fischer-Tropsch wax particles is not particularly limited, but is preferably 35 to 115 ° C, and more preferably 60 to 115 ° C.
  • the granulation method of component a2 is not particularly limited as long as it is a known method, and examples thereof include a Fischer-Tropsch manufacturing method.
  • the above Fischer-Tropsch production method uses a steam reforming method or partial oxidation method from natural gas and air to produce a synthesis gas of carbon monoxide and hydrogen, and in a high temperature and high pressure state, iron, cobalt, nickel, etc. This refers to a production method obtained by synthesizing by using a catalyst to cause a catalytic reaction, purifying and reforming (molding) after fractional distillation.
  • the scrub agent which is the said hydrocarbon wax particle can use a commercial item.
  • paraffin wax particles include trade name “Paraffin Wax-155” (manufactured by Nippon Seiwa Co., Ltd.), trade name “HNP-51” (manufactured by Nippon Seiwa Co., Ltd.), and the like.
  • microcrystalline wax particles include trade name “Hi-Mic-1080” (manufactured by Nippon Seiwa Co., Ltd.), trade name “Hi-Mic-2065” (manufactured by Nippon Seiwa Co., Ltd.), and the like.
  • Fischer-Tropsch wax particles include trade name “Synscrub 20PC” (manufactured by Micro Powders), trade name “Synscrub 50PC” (manufactured by Micro Powders), and the like.
  • composition for skin cleanser of the present invention contains a scrub agent that is the above hydrocarbon wax particles. That is, the present invention is characterized in that the hydrocarbon wax particles are blended in the composition for skin cleanser as a scrub agent.
  • composition for skin cleanser of the present invention contains the scrub agent which is the hydrocarbon wax particles described above, thereby exhibiting an excellent scrubbing effect and excellent in usability without unpleasant skin irritation and foreign body sensation during use. The effect can be demonstrated. Therefore, the composition for skin cleanser of the present invention can be suitably used as a skin cleanser in the form of a face cleanser (face cleanser scrub), body shampoo (body scrub) or the like.
  • the scrub is the hydrocarbon wax particle described above from the viewpoint of exhibiting an optimal scrub effect without uncomfortable skin irritation and foreign body sensation during use.
  • the average particle diameter of the agent is preferably in the range of 100 to 800 ⁇ m, more preferably 150 to 600 ⁇ m.
  • the average particle diameter of the scrub agent as the hydrocarbon wax particles is 200 from the viewpoint of exerting an optimal scrub effect. It is preferable to use those in the range of ⁇ 1,000 ⁇ m, more preferably 250 to 900 ⁇ m.
  • the content of the scrubbing agent that is the hydrocarbon wax particles in the skin cleansing composition of the present invention is not particularly limited, but is 0 in 100% by weight of the skin cleansing composition from the viewpoint of exerting a scrubbing effect. It is preferably 1% by mass or more, and more preferably 0.5% by mass or more. Further, the content of the scrub agent which is the hydrocarbon wax particles in the composition for skin cleanser of the present invention is not particularly limited, but from the viewpoint of skin irritation and maintaining foaming, the composition for skin cleanser It is preferable that it is 30 mass% or less in 100 mass% of things, and it is more preferable that it is 20 mass% or less.
  • the content of the scrub agent as the hydrocarbon wax particles is the total content of the scrub agent as all the hydrocarbon wax particles blended in the skin cleansing composition of the present invention.
  • the composition for skin cleanser of the present invention preferably contains a higher fatty acid salt from the viewpoint of imparting a clean feeling and further enhancing the scrub effect of the scrub agent.
  • the higher fatty acid salt may be used alone or in combination of two or more.
  • any higher fatty acid used as a cosmetic raw material can be used.
  • the salt of the higher fatty acid a salt obtained by saponifying or neutralizing the higher fatty acid with an alkaline agent can be used.
  • the alkali agent include alkali metals and organic alkalis. Specific examples of the alkali metal include sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate and the like. Specific organic alkalis include, for example, triethanolamine, isopropanolamine, arginine and the like.
  • the higher fatty acid and the alkaline agent may be blended after preparing as a higher fatty acid salt in advance. It is good also as a higher fatty acid salt in a composition by mix
  • the content of the higher fatty acid salt in the composition for skin cleanser of the present invention is not particularly limited, but from the viewpoint of imparting detergency and more efficiently exerting the scrub effect, it is used as a higher fatty acid for skin cleanser. In 100% by mass of the composition, it is preferably 0.5% by mass or more, and more preferably 1% by mass or more. Further, the content of the higher fatty acid salt in the composition for skin cleanser of the present invention is not particularly limited, but from the viewpoint of stability of the preparation, 80% of the composition for skin cleanser as a higher fatty acid is 80% by mass. The content is preferably at most mass%, more preferably at most 60 mass%. In addition, content as the said higher fatty acid is a total amount of content as all the higher fatty acids mix
  • composition for skin cleansing agent of the present invention components usually used in cosmetics can be blended in addition to the above-described components within the range where the effects of the present invention are not impaired.
  • Other components include, for example, nonionic surfactants, anionic surfactants, cationic surfactants, amphoteric surfactants, polyhydric alcohols, fatty acid ester oils, vegetable oils, thickening polymers, higher alcohols. , Refreshing agents, lipids, fragrances, antiseptic / bactericidal agents, moisturizing agents, scrubbing agents other than the scrubbing agent that is the hydrocarbon wax particles, and the like.
  • the said other component can be mix
  • nonionic surfactant examples include sorbitan fatty acid ester, glycerin fatty acid ester, castor oil, hydrogenated castor oil, and alkylene oxide adducts thereof, polyglycerin fatty acid ester, polyoxyalkylene alkyl ether, polyoxyalkylene fatty acid ester. , Polyoxyalkylene alkylphenol, polyoxyethylene sorbite fatty acid ester, polyoxyethylene alkylphenyl formaldehyde condensate, polyoxyethylene sterol and its derivatives, polyoxyethylene lanolin and its derivatives, polyoxyethylene beeswax derivatives, sugar esters, etc. It is done.
  • anionic surfactant examples include alkyl sulfates, alkyl phosphates, polyoxyethylene alkyl ether sulfates, polyoxyethylene alkyl phenyl ether sulfates, alkyl ether phosphates, alkyl ether carboxylates.
  • N-acyl-N-methyl- ⁇ -alanine N-acyl glycine
  • N-acyl glutamate polyoxyethylene alkyl carboxylate, alkyl phenyl ether sulfonate, alkyl sulfosuccinic acid and And salts thereof, N-acyl sarcosine and its salts, polyoxyethylene coconut oil fatty acid monoethanolamide sulfate and the like.
  • Examples of the cationic surfactant include amine salts such as alkylamine salts, fatty acid amide amine salts, and ester-containing tertiary amine salts, monoalkyl quaternary ammonium salts, dialkyl quaternary ammonium salts, and trialkyl type 4 salts.
  • Examples include quaternary ammonium salts, alkyl quaternary ammonium salts such as benzalkonium-type quaternary ammonium salts, cyclic quaternary ammonium salts such as alkyl pyridinium salts, and benzethonium chloride.
  • amphoteric surfactant examples include glycine-type amphoteric surfactants such as alkyl glycine salt, carboxymethyl glycine salt, N-acylaminoethyl-N-2-hydroxyethyl glycine salt, alkylaminopropionate, alkylimino.
  • Aminopropionic acid type amphoteric surfactants such as dipropionate
  • aminoacetic acid betaine type amphoteric surfactants such as alkyldimethylaminoacetic acid betaine, fatty acid amidopropyldimethylaminoacetic acid betaine, and sulfobetaine type amphoteric interfaces such as alkylhydroxysulfobetaine An active agent etc. are mentioned.
  • the surfactants such as the nonionic surfactant, the anionic surfactant, the cationic surfactant and the amphoteric surfactant may be used alone or in combination of two or more. It may be used.
  • polyhydric alcohol examples include ethylene glycol, propylene glycol, dipropylene glycol, polyethylene glycol, 1,3-butylene glycol, glycerin, concentrated glycerin, diglycerin, triglycerin, glucose, maltose, maltitol, sucrose, and mannitol. Sorbitol, 1,2-pentanediol, 1,2-hexanediol, 1,2-octanediol and the like.
  • the said polyhydric alcohol may be used individually by 1 type, and may be used in combination of 2 or more type as appropriate.
  • fatty acid ester oil examples include ethyl oleate, isopropyl myristate, isopropyl palmitate, butyl stearate, myristyl myristate, cetyl myristate, cetyl palmitate, stearyl stearate, decyl oleate, oleyl oleate, myristine Octyldodecyl acid, octyldodecyl oleate, ethyl isostearate, isocetyl stearate, isopropyl isostearate, isocetyl isostearate, propylene glycol isostearate, cetyl 2-ethylhexanoate, cetostearyl 2-ethylhexanoate, neopentyl glycol dicaprate , Neopentyl glycol dioctanoate, glyceryl tri-2-ethylhexanoate,
  • Examples of the vegetable oil include orange oil, olive oil, camellia oil, macadamia nut oil, jojoba oil, rose oil, lavender oil, and tea tree oil.
  • the said vegetable oil may be used individually by 1 type, and may be used in combination of 2 or more type as appropriate.
  • thickening polymer examples include natural polymers, semi-synthetic polymers, synthetic polymers, and clay minerals. One of these thickening polymers may be used alone, or two or more thereof may be used in appropriate combination.
  • Examples of the natural polymer include gum arabic, gum tragacanth, guar gum, xanthan gum, locust bean gum, karaya gum, iris moss, quince seed, gelatin, shellac, rosin, and casein.
  • Examples of the semi-synthetic polymer include sodium carboxymethyl cellulose, hydroxyethyl cellulose, methyl cellulose, ethyl cellulose, sodium alginate, ester gum, nitrocellulose, hydroxypropyl cellulose, hydroxypropyl methylcellulose, and crystalline cellulose.
  • Examples of the synthetic polymer include acrylic acid / alkyl methacrylate copolymer, acrylic acid / polyoxyethylene alkyl itaconic acid copolymer, alkyl acrylate / polyoxyethylene alkyl ether copolymer, acrylic acid / Examples include hydroxyalkyl acrylate copolymers, acrylic acid / polyoxyethylene alkyl ether cross-polymers of methacrylic acid, acrylic acid / vinyl neodecanoate cross-polymers, polyvinyl alcohol, sodium polyacrylate, carboxyvinyl polymer, polyvinyl methyl cellulose, polyamide resins, etc. It is done.
  • Examples of the clay mineral include fluorosilicic acid (sodium / magnesium) and synthetic silicic acid (sodium / magnesium).
  • Examples of the higher alcohol include lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, oleyl alcohol, and behenyl alcohol.
  • the above higher alcohols may be used alone or in combination of two or more.
  • Examples of the refreshing agent include l-menthol, menthyl glyceryl ether, menthyl lactate, 1-menthyl-3-hydroxybutyrate, dl-camphor, eugenol, menthone, mint, menthyl salicylate, and eucalyptus oil.
  • the said refreshing agent may be used individually by 1 type, and may be used in combination of 2 or more type as appropriate.
  • composition for skin cleanser of the present invention can be prepared in various dosage forms such as paste, cream, emulsion, gel, and liquid. Among these, it is preferable to prepare a paste-like, cream-like, or gel-like skin cleansing composition from the viewpoint of excellent dispersion state of the scrub agent that is the hydrocarbon wax particles.
  • the method for producing the composition for skin cleanser of the present invention is not particularly limited as long as it is a known production method.
  • the above components are mixed as appropriate and stirred using a disper mixer, homomixer, disper mill or the like. A method is mentioned.
  • the hydrocarbon wax particles are used as a scrub agent. That is, in the present invention, in order to exert the scrub effect, it is necessary to be present as hydrocarbon wax particles in the skin cleansing composition. Therefore, as a suitable method for producing the composition for skin cleanser of the present invention, for example, a composition is prepared by heating and mixing and stirring components other than the hydrocarbon wax particles at a temperature of about 70 ° C. or higher. Examples thereof include a method in which the hydrocarbon wax particles are added in a state where the temperature of the composition is about 40 ° C. or less and then stirred to prepare.
  • the blending amount represents “% by mass” unless otherwise specified, and all blending components were converted to pure. All the evaluations were performed under constant conditions of 23 ° C. and 60% humidity.
  • Scrub agent 1 paraffin wax particles: trade name “HNP-51” (manufactured by Nippon Seiwa Co., Ltd., average particle size: about 250 ⁇ m)
  • Scrub agent 2 Fischer-Tropsch wax particles: trade name “Synscrub 50PC” (manufactured by Micro Powders, particle diameter: 180-297 ⁇ m)
  • Scrub agent 3 paraffin wax particles: trade name “Paraffin Wax-155” (manufactured by Nippon Seiwa Co., Ltd., average particle size: about 900 ⁇ m)
  • Scrub agent 4 microcrystalline wax particles: trade name “Hi-Mic-1080” (manufactured by Nippon Seiwa Co., Ltd., average particle size: about 900 ⁇ m)
  • Scrub agent 5 Fischer-Tropsch wax particles: trade name “Synscrub 20PC” (manufactured by Micro Powders, particle diameter: 500 to 840 ⁇ m)
  • Apricot kernel 1 Trade name “AP grid ⁇ spherical># 40-60” (manufactured by Ichimaru Falcos, particle size: 177 ⁇ m to 420 ⁇ m)
  • Apricot kernel 2 Trade name “AP grid ⁇ spherical># 60-80” (manufactured by Ichimaru Falcos, particle size: 149 ⁇ m to 297 ⁇ m)
  • Polyethylene beads trade name “Microscrub 1435PC” (manufactured by Micro Powders, particle size: 500-1410 ⁇ m)
  • Silica beads Trade name “SCRUB SILICA 850G” (manufactured by JGC Catalysts & Chemicals, average particle size: about 720 ⁇ m)
  • the skin cleansing composition of each example which is a facial cleanser, is superior to the feeling of use without giving an unpleasant skin irritation or foreign body feeling, as compared with those of each comparative example. It can be seen that the optimum scrubbing effect is exhibited.

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)

Abstract

The present invention addresses the problem of providing a scrubbing agent, which gives an excellent feeling in using without any unpleasant skin irritation or discomfort feeling of foreign body, exerts an appropriate scrubbing effect and is eco-friendly, and a skin cleansing composition comprising the scrubbing agent. The scrubbing agent according to the present invention is characterized by comprising hydrocarbon wax particles, preferably hydrocarbon wax particles selected from the group consisting of petroleum-derived hydrocarbon wax particles and synthetic hydrocarbon wax particles. The skin cleansing composition according to the present invention is characterized by comprising the scrubbing agent.

Description

スクラブ剤および当該スクラブ剤を含有する皮膚洗浄剤用組成物Scrub agent and composition for skin cleanser containing the scrub agent
　本発明は、スクラブ剤および当該スクラブ剤を含有する皮膚洗浄剤用組成物に関する。 The present invention relates to a scrub agent and a composition for a skin cleanser containing the scrub agent.
　皮膚洗浄剤用組成物中には、皮膚上の汚れを除去する効果を高める観点と、適度に皮膚を刺激してマッサージ効果を付与する観点から、種々のスクラブ剤が配合されている。このようなスクラブ剤としては、ポリエチレンビーズ、クルミ殻粒、結晶セルロース粉末などの硬い材質のスクラブ剤である硬スクラブ剤が用いられ、中でも、上記効果に格段に優れるポリエチレンビーズが最も汎用されている。 In the composition for skin cleanser, various scrub agents are blended from the viewpoint of enhancing the effect of removing dirt on the skin and from the viewpoint of moderately stimulating the skin and imparting a massage effect. As such a scrubbing agent, a hard scrubbing agent which is a hard material scrubbing agent such as polyethylene beads, walnut shell particles, and crystalline cellulose powder is used, and among them, polyethylene beads that are remarkably excellent in the above effects are most widely used. .
　しかしながら、上記硬スクラブ剤は、皮膚上の汚れを除去する効果や皮膚を刺激してマッサージする効果に優れる反面、使用時に不快な皮膚刺激や異物感を感じたりする場合がある。また、洗浄時に目に入ると眼球を傷つける危険性もある。更に、近年では化粧品業界内において、環境汚染への配慮から生分解性のないポリエチレンビーズなどの硬スクラブ剤の使用を敬遠する動きもある。 However, the above-mentioned hard scrub agent is excellent in the effect of removing dirt on the skin and the effect of stimulating and massaging the skin, but may feel uncomfortable skin irritation and foreign body feeling when used. In addition, there is a risk of damaging the eyeball when it enters the eye during washing. Furthermore, in recent years, there has been a movement in the cosmetics industry to refrain from using hard scrub agents such as polyethylene beads that are not biodegradable in consideration of environmental pollution.
　一方、従来の皮膚洗浄剤用組成物には、上記硬スクラブ剤に比べて軟らかい材質のスクラブ剤である軟スクラブ剤も用いられている。具体的には、寒天、ポリアクリル酸塩、アルギン酸塩などが用いられている。このような軟スクラブ剤は、使用時に不快な皮膚刺激や異物感を感じることがなく使用感に優れる反面、スクラブ効果に劣るといった問題がある。 On the other hand, soft scrub agents, which are scrub agents made of a softer material than the hard scrub agent, are also used in conventional skin cleansing compositions. Specifically, agar, polyacrylate, alginate and the like are used. Such soft scrubbing agents do not feel uncomfortable skin irritation or foreign body feeling during use and are excellent in use feeling, but have a problem that they are inferior in scrubbing effect.
　これまでにも、軟スクラブ剤の一形態として、パラフィンワックス、キャンデリラワックスおよびカルナウバロウの複数の油性基剤を混合し、酵素を内包させたワックスカプセルを使用する技術も提案されている（例えば、特許文献１～２を参照）。しかしながら、このようなワックスカプセルを調製するためには時間とコストがかかるといった問題がある。 In the past, as one form of the soft scrub agent, a technique of using a wax capsule in which a plurality of oily bases of paraffin wax, candelilla wax and carnauba wax are mixed and encapsulated with an enzyme has been proposed (for example, (See Patent Documents 1 and 2). However, there is a problem that it takes time and cost to prepare such a wax capsule.
　上記した技術背景と従来技術を鑑みると、使用時に不快な皮膚刺激や異物感がなく使用感に優れ、かつ、適度なスクラブ効果を発揮するとともに、環境汚染への影響を考慮した新たなスクラブ剤の開発が急務であった。 In view of the above technical background and conventional technology, there is no unpleasant skin irritation or foreign body sensation at the time of use, it is excellent in usability and exhibits a moderate scrub effect, and a new scrub agent considering the influence on environmental pollution The development of was urgent.
特開平８－０７３３４４号公報JP-A-8-073344 特開平９－２４９５２９号公報JP-A-9-249529
　本発明の目的は、使用時に不快な皮膚刺激や異物感がなく使用感に優れ、かつ、適度なスクラブ効果を発揮するとともに、環境汚染への影響を考慮したスクラブ剤および当該スクラブ剤を含有する皮膚洗浄剤用組成物を提供することにある。 An object of the present invention is to provide a scrubbing agent that is excellent in feeling of use without an unpleasant skin irritation or foreign body feeling at the time of use, exhibits an appropriate scrubbing effect, and contains the scrubbing agent in consideration of the influence on environmental pollution. It is providing the composition for skin cleansing agents.
　即ち、本発明は、炭化水素ワックス粒子であることを特徴とするスクラブ剤を提供する。 That is, the present invention provides a scrub agent characterized by being hydrocarbon wax particles.
　上記炭化水素ワックス粒子の平均粒子径は、１００～１，０００μｍであることが好ましい。 The average particle diameter of the hydrocarbon wax particles is preferably 100 to 1,000 μm.
　上記炭化水素ワックス粒子は、石油由来炭化水素ワックス粒子および合成炭化水素ワックス粒子の群から選ばれることが好ましい。 The hydrocarbon wax particles are preferably selected from the group of petroleum-derived hydrocarbon wax particles and synthetic hydrocarbon wax particles.
　また、本発明は、上記スクラブ剤を含有することを特徴とする皮膚洗浄剤用組成物を提供する。 The present invention also provides a composition for a skin cleanser comprising the scrub agent described above.
　上記皮膚洗浄剤用組成物中の上記スクラブ剤の含有量は、０．１～３０質量％であることが好ましい。 The content of the scrub agent in the composition for skin cleanser is preferably 0.1 to 30% by mass.
　さらに、上記皮膚洗浄剤用組成物は、高級脂肪酸塩を含有することが好ましい。 Furthermore, it is preferable that the composition for skin cleanser contains a higher fatty acid salt.
　本発明のスクラブ剤は、生分解性を有していることから、環境汚染への悪影響がないものである。また、上記スクラブ剤を含有する本発明の皮膚洗浄剤用組成物は、優れたスクラブ効果を発揮するとともに、使用時に不快な皮膚刺激や異物感がなく使用感に優れた効果を発揮する。 Since the scrub agent of the present invention has biodegradability, it does not have an adverse effect on environmental pollution. Moreover, the composition for skin cleansing agents of the present invention containing the scrub agent exhibits an excellent scrub effect and also exhibits an excellent effect on the feeling of use with no unpleasant skin irritation or foreign body sensation during use.
　以下、本発明のスクラブ剤および当該スクラブ剤を含有する皮膚洗浄剤用組成物について説明する。 Hereinafter, the scrub agent of the present invention and the composition for skin cleanser containing the scrub agent will be described.
［スクラブ剤］
　本発明のスクラブ剤は、炭化水素ワックス粒子である。炭化水素ワックス粒子とは、直鎖状炭化水素（ノルマルパラフィン）、分岐炭化水素（イソパラフィン）、飽和環状炭化水素（シクロパラフィン）などの炭化水素ワックスを主な成分とする粒子であり、生分解性を有している。即ち、環境汚染への悪影響がないものである。なお、本発明のスクラブ剤は、上記炭化水素ワックス粒子のみで構成されたスクラブ剤であることを意味し、炭化水素ワックス粒子をスクラブ剤の用途として使用することを特徴としている。 [Scrubbing agent]
The scrub agent of the present invention is hydrocarbon wax particles. Hydrocarbon wax particles are particles mainly composed of hydrocarbon waxes such as linear hydrocarbons (normal paraffins), branched hydrocarbons (isoparaffins), saturated cyclic hydrocarbons (cycloparaffins), and are biodegradable. have. That is, there is no adverse effect on environmental pollution. In addition, the scrub agent of this invention means that it is a scrub agent comprised only with the said hydrocarbon wax particle, The hydrocarbon wax particle is used as a use of a scrub agent, It is characterized by the above-mentioned.
　上記炭化水素ワックス粒子の粒子径は、特に限定されないが、不快な皮膚刺激がなく優れたスクラブ効果を発揮する観点から、平均粒子径が、１００～１，０００μｍの範囲のものを用いることが好ましく、より好ましくは２００～９００μｍである。 The particle diameter of the hydrocarbon wax particles is not particularly limited, but from the viewpoint of exhibiting an excellent scrub effect without unpleasant skin irritation, it is preferable to use particles having an average particle diameter in the range of 100 to 1,000 μm. More preferably, the thickness is 200 to 900 μm.
　上記炭化水素ワックス粒子としては、例えば、石油由来炭化水素ワックス粒子、合成炭化水素ワックス粒子などが挙げられる。本発明では、石油由来炭化水素ワックス粒子および合成炭化水素ワックス粒子の群から選ばれる少なくとも１種を用いることが好ましい。なお、本明細書においては、上記「石油由来炭化水素ワックス粒子」を「成分ａ１」と称する場合がある。また、上記「合成炭化水素ワックス粒子」を「成分ａ２」と称する場合がある。成分ａ１および成分ａ２は、１種を単独で用いても良く、２種以上を適宜組み合わせて用いても良い。 Examples of the hydrocarbon wax particles include petroleum-derived hydrocarbon wax particles and synthetic hydrocarbon wax particles. In the present invention, it is preferable to use at least one selected from the group of petroleum-derived hydrocarbon wax particles and synthetic hydrocarbon wax particles. In the present specification, the “petroleum-derived hydrocarbon wax particles” may be referred to as “component a1”. Further, the “synthetic hydrocarbon wax particles” may be referred to as “component a2”. As the component a1 and the component a2, one type may be used alone, or two or more types may be used in appropriate combination.
　具体的な上記成分ａ１としては、例えば、パラフィンワックス粒子、マイクロクリスタリンワックス粒子などが挙げられる。上記パラフィンワックス粒子の融点は特に限定されいが、４０～８０℃であることが好ましく、６０～８０℃であることがより好ましい。また、マイクロクリスタリンワックス粒子の融点は特に限定されないが、６０～１０５℃であることが好ましい。 Specific examples of the component a1 include paraffin wax particles and microcrystalline wax particles. The melting point of the paraffin wax particles is not particularly limited, but is preferably 40 to 80 ° C., more preferably 60 to 80 ° C. The melting point of the microcrystalline wax particles is not particularly limited, but is preferably 60 to 105 ° C.
　成分ａ１の造粒方法は公知の方法であれば特に限定されないが、例えば、原油の減圧蒸留留出油部分から、結晶性の良い炭化水素を分離抽出する方法、原油の減圧蒸留残渣油部分から取り出す方法などが挙げられる。 The granulation method of component a1 is not particularly limited as long as it is a known method. For example, a method of separating and extracting hydrocarbons with good crystallinity from a crude oil vacuum distillation distillate part, a crude oil vacuum distillation residue oil part, The method of taking out is mentioned.
　一方、具体的な上記成分ａ２としては、例えば、フィッシャー・トロプシュワックス粒子などが挙げられる。上記フィッシャー・トロプシュワックス粒子とは、フィッシャー・トロプシュ製法により得られる。上記フィッシャー・トロプシュワックス粒子の融点は特に限定されいが、３５～１１５℃であることが好ましく、６０～１１５℃であることがより好ましい。 On the other hand, specific examples of the component a2 include Fischer-Tropsch wax particles. The Fischer-Tropsch wax particles are obtained by the Fischer-Tropsch manufacturing method. The melting point of the Fischer-Tropsch wax particles is not particularly limited, but is preferably 35 to 115 ° C, and more preferably 60 to 115 ° C.
　成分ａ２の造粒方法は公知の方法であれば特に限定されないが、例えば、フィッシャー・トロプシュ製法などが挙げられる。上記フィッシャー・トロプシュ製法とは、天然ガスと空気から水蒸気改質法、若しくは部分酸化法を用いて、一酸化炭素と水素の合成ガスを生成し、高温高圧状態で、鉄、コバルト、ニッケルなどの触媒を用いて、触媒反応を起すことにより合成し、分別蒸留後、精製、改質（成形）することで得られる製法のことを言う。 The granulation method of component a2 is not particularly limited as long as it is a known method, and examples thereof include a Fischer-Tropsch manufacturing method. The above Fischer-Tropsch production method uses a steam reforming method or partial oxidation method from natural gas and air to produce a synthesis gas of carbon monoxide and hydrogen, and in a high temperature and high pressure state, iron, cobalt, nickel, etc. This refers to a production method obtained by synthesizing by using a catalyst to cause a catalytic reaction, purifying and reforming (molding) after fractional distillation.
　なお、上記炭化水素ワックス粒子であるスクラブ剤は、市販品を用いることができる。パラフィンワックス粒子の市販品としては、例えば、商品名「Ｐａｒａｆｆｉｎ　Ｗａｘ－１５５」（日本精蝋社製）、商品名「ＨＮＰ－５１」（日本精蝋社製）などが挙げられる。マイクロクリスタリンワックス粒子の市販品としては、例えば、商品名「Ｈｉ－Ｍｉｃ－１０８０」（日本精蝋社製）、商品名「Ｈｉ－Ｍｉｃ－２０６５」（日本精蝋社製）などが挙げられる。フィッシャー・トロプシュワックス粒子の市販品としては、例えば、商品名「Ｓｙｎｓｃｒｕｂ　２０ＰＣ」（マイクロパウダーズ社製）、商品名「Ｓｙｎｓｃｒｕｂ　５０ＰＣ」（マイクロパウダーズ社製）などが挙げられる。 In addition, the scrub agent which is the said hydrocarbon wax particle can use a commercial item. Examples of commercially available paraffin wax particles include trade name “Paraffin Wax-155” (manufactured by Nippon Seiwa Co., Ltd.), trade name “HNP-51” (manufactured by Nippon Seiwa Co., Ltd.), and the like. Examples of commercially available microcrystalline wax particles include trade name “Hi-Mic-1080” (manufactured by Nippon Seiwa Co., Ltd.), trade name “Hi-Mic-2065” (manufactured by Nippon Seiwa Co., Ltd.), and the like. Examples of commercially available Fischer-Tropsch wax particles include trade name “Synscrub 20PC” (manufactured by Micro Powders), trade name “Synscrub 50PC” (manufactured by Micro Powders), and the like.
　本発明の皮膚洗浄剤用組成物は、上記炭化水素ワックス粒子であるスクラブ剤を含有する。すなわち、本発明では、皮膚洗浄剤用組成物中に上記炭化水素ワックス粒子をスクラブ剤の用途として配合することを特徴としている。 The composition for skin cleanser of the present invention contains a scrub agent that is the above hydrocarbon wax particles. That is, the present invention is characterized in that the hydrocarbon wax particles are blended in the composition for skin cleanser as a scrub agent.
　本発明の皮膚洗浄剤用組成物は、上記炭化水素ワックス粒子であるスクラブ剤を含有することにより、優れたスクラブ効果を発揮させるとともに、使用時に不快な皮膚刺激や異物感がなく使用感に優れた効果を発揮させることができる。したがって、本発明の皮膚洗浄剤用組成物は、洗顔剤（洗顔スクラブ）、ボディシャンプー（ボディスクラブ）などの形態の皮膚洗浄剤として好適に用いることができる。 The composition for skin cleanser of the present invention contains the scrub agent which is the hydrocarbon wax particles described above, thereby exhibiting an excellent scrubbing effect and excellent in usability without unpleasant skin irritation and foreign body sensation during use. The effect can be demonstrated. Therefore, the composition for skin cleanser of the present invention can be suitably used as a skin cleanser in the form of a face cleanser (face cleanser scrub), body shampoo (body scrub) or the like.
　本発明の皮膚洗浄剤用組成物を洗顔スクラブの形態として用いる場合には、使用時に不快な皮膚刺激や異物感がなく、最適なスクラブ効果を発揮させる観点から、上記炭化水素ワックス粒子であるスクラブ剤の平均粒子径は、１００～８００μｍの範囲のものを用いることが好ましく、より好ましくは１５０～６００μｍである。一方、ボディスクラブの形態として用いる場合には、使用時に不快な皮膚刺激や異物感がなく、最適なスクラブ効果を発揮させる観点から、上記炭化水素ワックス粒子であるスクラブ剤の平均粒子径は、２００～１，０００μｍの範囲のものを用いることが好ましく、より好ましくは２５０～９００μｍである。 When the composition for skin cleanser of the present invention is used as a facial scrub form, the scrub is the hydrocarbon wax particle described above from the viewpoint of exhibiting an optimal scrub effect without uncomfortable skin irritation and foreign body sensation during use. The average particle diameter of the agent is preferably in the range of 100 to 800 μm, more preferably 150 to 600 μm. On the other hand, when used as a form of body scrub, there is no unpleasant skin irritation or foreign body sensation during use, and the average particle diameter of the scrub agent as the hydrocarbon wax particles is 200 from the viewpoint of exerting an optimal scrub effect. It is preferable to use those in the range of ˜1,000 μm, more preferably 250 to 900 μm.
　本発明の皮膚洗浄剤用組成物中の上記炭化水素ワックス粒子であるスクラブ剤の含有量は、特に限定されないが、スクラブ効果を発揮させる観点から、皮膚洗浄剤用組成物１００質量％中、０．１質量％以上であることが好ましく、０．５質量％以上であることがより好ましい。また、本発明の皮膚洗浄剤用組成物中の上記炭化水素ワックス粒子であるスクラブ剤の含有量は、特に限定されないが、皮膚刺激の観点、並びに泡立ちを維持する観点から、皮膚洗浄剤用組成物１００質量％中、３０質量％以下であることが好ましく、２０質量％以下であることがより好ましい。なお、上記炭化水素ワックス粒子であるスクラブ剤の含有量は、本発明の皮膚洗浄剤用組成物中に配合される全ての炭化水素ワックス粒子であるスクラブ剤の含有量の合計量である。 The content of the scrubbing agent that is the hydrocarbon wax particles in the skin cleansing composition of the present invention is not particularly limited, but is 0 in 100% by weight of the skin cleansing composition from the viewpoint of exerting a scrubbing effect. It is preferably 1% by mass or more, and more preferably 0.5% by mass or more. Further, the content of the scrub agent which is the hydrocarbon wax particles in the composition for skin cleanser of the present invention is not particularly limited, but from the viewpoint of skin irritation and maintaining foaming, the composition for skin cleanser It is preferable that it is 30 mass% or less in 100 mass% of things, and it is more preferable that it is 20 mass% or less. The content of the scrub agent as the hydrocarbon wax particles is the total content of the scrub agent as all the hydrocarbon wax particles blended in the skin cleansing composition of the present invention.
［高級脂肪酸塩］
　本発明の皮膚洗浄剤用組成物には、洗浄実感を付与し、上記スクラブ剤によるスクラブ効果をさらに高める観点から、高級脂肪酸塩を含有させることが好ましい。高級脂肪酸塩は、１種を単独で用いても良く、２種以上を適宜組み合わせて用いても良い。 [Higher fatty acid salt]
The composition for skin cleanser of the present invention preferably contains a higher fatty acid salt from the viewpoint of imparting a clean feeling and further enhancing the scrub effect of the scrub agent. The higher fatty acid salt may be used alone or in combination of two or more.
　上記高級脂肪酸塩を構成する高級脂肪酸としては、化粧品原料として用いられる高級脂肪酸であればいずれも使用することができる。具体的には、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、オレイン酸、ベヘニン酸、ウンデシレン酸、オキシステアリン酸、リノール酸、ラノリン脂肪酸、イソステアリン酸、イソパルミチン酸、イソトリデカン酸、イソノナン酸、２－エチルヘキサン酸などの高級脂肪酸が挙げられる。 As the higher fatty acid constituting the higher fatty acid salt, any higher fatty acid used as a cosmetic raw material can be used. Specifically, lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, behenic acid, undecylenic acid, oxystearic acid, linoleic acid, lanolin fatty acid, isostearic acid, isopalmitic acid, isotridecanoic acid, isononanoic acid, 2 -Higher fatty acids such as ethylhexanoic acid.
　上記高級脂肪酸の塩としては、上記高級脂肪酸をアルカリ剤でケン化又は中和したものを用いることができる。アルカリ剤としては、例えば、アルカリ金属、有機アルカリなどが挙げられる。具体的なアルカリ金属としては、例えば、水酸化ナトリウム、水酸化カリウム、炭酸ナトリウム、炭酸カリウムなどが挙げられる。また、具体的な有機アルカリとしては、例えば、トリエタノールアミン、イソプロパノールアミン、アルギニンなどが挙げられる。 As the salt of the higher fatty acid, a salt obtained by saponifying or neutralizing the higher fatty acid with an alkaline agent can be used. Examples of the alkali agent include alkali metals and organic alkalis. Specific examples of the alkali metal include sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate and the like. Specific organic alkalis include, for example, triethanolamine, isopropanolamine, arginine and the like.
　本発明の皮膚洗浄剤用組成物中に高級脂肪酸塩を含有させるには、上記高級脂肪酸と上記アルカリ剤とを予め高級脂肪酸塩として調製した後に配合しても良く、また、上記高級脂肪酸と上記アルカリ剤とを配合して組成物中で高級脂肪酸塩としても良い。 In order to contain the higher fatty acid salt in the composition for skin cleanser of the present invention, the higher fatty acid and the alkaline agent may be blended after preparing as a higher fatty acid salt in advance. It is good also as a higher fatty acid salt in a composition by mix | blending an alkaline agent.
　本発明の皮膚洗浄剤用組成物中の上記高級脂肪酸塩の含有量は、特に限定されないが、洗浄力を付与し、スクラブ効果をより効率的に発揮させる観点から、高級脂肪酸として皮膚洗浄剤用組成物１００質量％中、０．５質量％以上であることが好ましく、１質量％以上であることがより好ましい。また、本発明の皮膚洗浄剤用組成物中の上記高級脂肪酸塩の含有量は、特に限定されないが、製剤の安定性の観点から、高級脂肪酸として皮膚洗浄剤用組成物１００質量％中、８０質量％以下であることが好ましく、６０質量％以下であることがより好ましい。なお、上記高級脂肪酸としての含有量は、本発明の皮膚洗浄剤用組成物中に配合される全ての高級脂肪酸としての含有量の合計量である。 The content of the higher fatty acid salt in the composition for skin cleanser of the present invention is not particularly limited, but from the viewpoint of imparting detergency and more efficiently exerting the scrub effect, it is used as a higher fatty acid for skin cleanser. In 100% by mass of the composition, it is preferably 0.5% by mass or more, and more preferably 1% by mass or more. Further, the content of the higher fatty acid salt in the composition for skin cleanser of the present invention is not particularly limited, but from the viewpoint of stability of the preparation, 80% of the composition for skin cleanser as a higher fatty acid is 80% by mass. The content is preferably at most mass%, more preferably at most 60 mass%. In addition, content as the said higher fatty acid is a total amount of content as all the higher fatty acids mix | blended in the composition for skin cleansing agents of this invention.
［その他成分］
　本発明の皮膚洗浄剤用組成物には、本発明の効果が損なわれない範囲内において、上記した成分の他に通常化粧料に用いられる成分を配合することができる。他成分としては、例えば、非イオン性界面活性剤、陰イオン性界面活性剤、陽イオン性界面活性剤、両性界面活性剤、多価アルコール、脂肪酸エステル油、植物油、増粘性高分子、高級アルコール、清涼剤、脂質、香料、防腐・殺菌剤、保湿剤、上記炭化水素ワックス粒子であるスクラブ剤以外のスクラブ剤などが挙げられる。上記他成分は、適宜、その用途、目的に応じて配合することができる。 [Other ingredients]
In the composition for skin cleansing agent of the present invention, components usually used in cosmetics can be blended in addition to the above-described components within the range where the effects of the present invention are not impaired. Other components include, for example, nonionic surfactants, anionic surfactants, cationic surfactants, amphoteric surfactants, polyhydric alcohols, fatty acid ester oils, vegetable oils, thickening polymers, higher alcohols. , Refreshing agents, lipids, fragrances, antiseptic / bactericidal agents, moisturizing agents, scrubbing agents other than the scrubbing agent that is the hydrocarbon wax particles, and the like. The said other component can be mix | blended suitably according to the use and the objective.
　上記非イオン性界面活性剤としては、例えば、ソルビタン脂肪酸エステル、グリセリン脂肪酸エステル、ヒマシ油、硬化ヒマシ油およびこれらのアルキレンオキシド付加物、ポリグリセリン脂肪酸エステル、ポリオキシアルキレンアルキルエーテル、ポリオキシアルキレン脂肪酸エステル、ポリオキシアルキレンアルキルフェノール、ポリオキシエチレンソルビット脂肪酸エステル、ポリオキシエチレンアルキルフェニルホルムアルデヒド縮合物、ポリオキシエチレンステロールおよびその誘導体、ポリオキシエチレンラノリンおよびその誘導体、ポリオキシエチレンミツロウ誘導体、シュガーエステル類などが挙げられる。 Examples of the nonionic surfactant include sorbitan fatty acid ester, glycerin fatty acid ester, castor oil, hydrogenated castor oil, and alkylene oxide adducts thereof, polyglycerin fatty acid ester, polyoxyalkylene alkyl ether, polyoxyalkylene fatty acid ester. , Polyoxyalkylene alkylphenol, polyoxyethylene sorbite fatty acid ester, polyoxyethylene alkylphenyl formaldehyde condensate, polyoxyethylene sterol and its derivatives, polyoxyethylene lanolin and its derivatives, polyoxyethylene beeswax derivatives, sugar esters, etc. It is done.
　上記陰イオン性界面活性剤としては、例えば、アルキル硫酸エステル塩、アルキルリン酸塩、ポリオキシエチレンアルキルエーテル硫酸塩、ポリオキシエチレンアルキルフェニルエーテル硫酸塩、アルキルエーテルリン酸エステル、アルキルエーテルカルボン酸塩、アシルメチルタウリン塩、Ｎ－アシル－Ｎ－メチル－β－アラニン塩、Ｎ－アシルグリシン塩、Ｎ－アシルグルタミン酸塩、ポリオキシエチレンアルキルカルボン酸塩、アルキルフェニルエーテルスルホン酸塩、アルキルスルホコハク酸およびその塩、Ｎ－アシルサルコシンおよびその塩、ポリオキシエチレンヤシ油脂肪酸モノエタノールアミド硫酸塩などが挙げられる。 Examples of the anionic surfactant include alkyl sulfates, alkyl phosphates, polyoxyethylene alkyl ether sulfates, polyoxyethylene alkyl phenyl ether sulfates, alkyl ether phosphates, alkyl ether carboxylates. Acylmethyl taurate, N-acyl-N-methyl-β-alanine, N-acyl glycine, N-acyl glutamate, polyoxyethylene alkyl carboxylate, alkyl phenyl ether sulfonate, alkyl sulfosuccinic acid and And salts thereof, N-acyl sarcosine and its salts, polyoxyethylene coconut oil fatty acid monoethanolamide sulfate and the like.
　上記陽イオン性界面活性剤としては、例えば、アルキルアミン塩、脂肪酸アミドアミン塩、エステル含有３級アミン塩などのアミン塩、モノアルキル型４級アンモニウム塩、ジアルキル型４級アンモニウム塩、トリアルキル型４級アンモニウム塩、ベンザルコニウム型４級アンモニウム塩などのアルキル４級アンモニウム塩、アルキルピリジニウム塩などの環式４級アンモニウム塩、塩化ベンゼエトニウムなどが挙げられる。 Examples of the cationic surfactant include amine salts such as alkylamine salts, fatty acid amide amine salts, and ester-containing tertiary amine salts, monoalkyl quaternary ammonium salts, dialkyl quaternary ammonium salts, and trialkyl type 4 salts. Examples include quaternary ammonium salts, alkyl quaternary ammonium salts such as benzalkonium-type quaternary ammonium salts, cyclic quaternary ammonium salts such as alkyl pyridinium salts, and benzethonium chloride.
　上記両性界面活性剤としては、例えば、アルキルグリシン塩、カルボキシメチルグリシン塩、Ｎ－アシルアミノエチル－Ｎ－２－ヒドロキシエチルグリシン塩などのグリシン型両性界面活性剤、アルキルアミノプロピオン酸塩、アルキルイミノジプロピオン酸塩などのアミノプロピオン酸型両性界面活性剤、アルキルジメチルアミノ酢酸ベタイン、脂肪酸アミドプロピルジメチルアミノ酢酸ベタインなどのアミノ酢酸ベタイン型両性界面活性剤、アルキルヒドロキシスルホベタインなどのスルホベタイン型両性界面活性剤などが挙げられる。 Examples of the amphoteric surfactant include glycine-type amphoteric surfactants such as alkyl glycine salt, carboxymethyl glycine salt, N-acylaminoethyl-N-2-hydroxyethyl glycine salt, alkylaminopropionate, alkylimino. Aminopropionic acid type amphoteric surfactants such as dipropionate, aminoacetic acid betaine type amphoteric surfactants such as alkyldimethylaminoacetic acid betaine, fatty acid amidopropyldimethylaminoacetic acid betaine, and sulfobetaine type amphoteric interfaces such as alkylhydroxysulfobetaine An active agent etc. are mentioned.
　上記非イオン性界面活性剤、陰イオン性界面活性剤、陽イオン性界面活性剤、両性界面活性剤などの界面活性剤は、１種を単独で用いても良く、２種以上を適宜組み合わせて用いても良い。 The surfactants such as the nonionic surfactant, the anionic surfactant, the cationic surfactant and the amphoteric surfactant may be used alone or in combination of two or more. It may be used.
　上記多価アルコールとしては、例えば、エチレングリコール、プロピレングリコール、ジプロピレングリコール、ポリエチレングリコール、１，３－ブチレングリコール、グリセリン、濃グリセリン、ジグリセリン、トリグリセリン、グルコース、マルトース、マルチトール、スクロース、マンニトール、ソルビトール、１，２－ペンタンジオール、１，２－ヘキサンジオール、１，２－オクタンジオールなどが挙げられる。上記多価アルコールは、１種を単独で用いても良く、２種以上を適宜組み合わせて用いても良い。 Examples of the polyhydric alcohol include ethylene glycol, propylene glycol, dipropylene glycol, polyethylene glycol, 1,3-butylene glycol, glycerin, concentrated glycerin, diglycerin, triglycerin, glucose, maltose, maltitol, sucrose, and mannitol. Sorbitol, 1,2-pentanediol, 1,2-hexanediol, 1,2-octanediol and the like. The said polyhydric alcohol may be used individually by 1 type, and may be used in combination of 2 or more type as appropriate.
　上記脂肪酸エステル油としては、例えば、オレイン酸エチル、ミリスチン酸イソプロピル、パルミチン酸イソプロピル、ステアリン酸ブチル、ミリスチン酸ミリスチル、ミリスチン酸セチル、パルミチン酸セチル、ステアリン酸ステアリル、オレイン酸デシル、オレイン酸オレイル、ミリスチン酸オクチルドデシル、オレイン酸オクチルドデシル、イソステアリン酸エチル、ステアリン酸イソセチル、イソステアリン酸イソプロピル、イソステアリン酸イソセチル、イソステアリン酸プロピレングリコール、２－エチルヘキサン酸セチル、２－エチルヘキサン酸セトステアリル、ジカプリン酸ネオペンチルグリコール、ジオクタン酸ネオペンチルグリコール、トリ２－エチルヘキサン酸グリセリル、トリオクタン酸グリセリル、トリイソパルミチン酸グリセリル、トリイソステアリン酸グリセリル、トリ２－エチルヘキサン酸トリメチロールプロパン、トリイソステアリン酸トリメチロールプロパン、テトラ２－エチルヘキサン酸ペンタエリスリトール、オクタン酸セチル、オクタン酸イソセチル、オクタン酸イソステアリル、セバシン酸イソステアリル、イソステアリン酸オクチルドデシル、ジメチルオクタン酸オクチルドデシルなどが挙げられる。上記脂肪酸エステル油は、１種を単独で用いても良く、２種以上を適宜組み合わせて用いても良い。 Examples of the fatty acid ester oil include ethyl oleate, isopropyl myristate, isopropyl palmitate, butyl stearate, myristyl myristate, cetyl myristate, cetyl palmitate, stearyl stearate, decyl oleate, oleyl oleate, myristine Octyldodecyl acid, octyldodecyl oleate, ethyl isostearate, isocetyl stearate, isopropyl isostearate, isocetyl isostearate, propylene glycol isostearate, cetyl 2-ethylhexanoate, cetostearyl 2-ethylhexanoate, neopentyl glycol dicaprate , Neopentyl glycol dioctanoate, glyceryl tri-2-ethylhexanoate, glyceryl trioctanoate, triisopa Glyceryl mycinate, glyceryl triisostearate, trimethylolpropane tri-2-ethylhexanoate, trimethylolpropane triisostearate, pentaerythritol tetra2-ethylhexanoate, cetyl octoate, isocetyl octoate, isostearyl octoate, sebacic acid Examples include isostearyl, octyldodecyl isostearate, and octyldodecyl dimethyloctanoate. The said fatty acid ester oil may be used individually by 1 type, and may be used in combination of 2 or more type as appropriate.
　上記植物油としては、例えば、オレンジ油、オリーブ油、ツバキ油、マカデミアナッツ油、ホホバ油、ローズ油、ラベンダー油、ティーツリー油などが挙げられる。上記植物油は、１種を単独で用いても良く、２種以上を適宜組み合わせて用いても良い。 Examples of the vegetable oil include orange oil, olive oil, camellia oil, macadamia nut oil, jojoba oil, rose oil, lavender oil, and tea tree oil. The said vegetable oil may be used individually by 1 type, and may be used in combination of 2 or more type as appropriate.
　上記増粘性高分子としては、例えば、天然高分子、半合成高分子、合成高分子、粘土鉱物などが挙げられる。上記増粘性高分子は、１種を単独で用いても良く、２種以上を適宜組み合わせて用いても良い。 Examples of the thickening polymer include natural polymers, semi-synthetic polymers, synthetic polymers, and clay minerals. One of these thickening polymers may be used alone, or two or more thereof may be used in appropriate combination.
　上記天然高分子としては、例えば、アラビアゴム、トラガントガム、グアガム、キサンタンガム、ローカストビーンガム、カラヤガム、アイリスモス、クインスシード、ゼラチン、セラック、ロジン、カゼインなどが挙げられる。上記半合成高分子としては、例えば、カルボキシメチルセルロースナトリウム、ヒドロキシエチルセルロース、メチルセルロース、エチルセロース、アルギン酸ナトリウム、エステルガム、ニトロセルロース、ヒドロキシプロピルセルロース、ヒドロキシプロピルメチルセルロース、結晶セルロースなどが挙げられる。上記合成高分子としては、例えば、アクリル酸・メタクリル酸アルキル共重合体、アクリル酸・ポリオキシエチレンアルキルイタコン酸共重合体、アクリル酸アルキル・メタクリル酸ポリオキシエチレンアルキルエーテル共重合体、アクリル酸・アクリル酸ヒドロキシアルキル共重合体、アクリル酸・メタクリル酸ポリオキシエチレンアルキルエーテルクロスポリマー、アクリル酸・ネオデカン酸ビニルクロスポリマー、ポリビニルアルコール、ポリアクリル酸ナトリウム、カルボキシビニルポリマー、ポリビニルメチルセルロース、ポリアミド樹脂などが挙げられる。上記粘土鉱物としては、例えば、フルオロケイ酸（ナトリウム／マグネシウム）、合成ケイ酸（ナトリウム／マグネシウム）などが挙げられる。 Examples of the natural polymer include gum arabic, gum tragacanth, guar gum, xanthan gum, locust bean gum, karaya gum, iris moss, quince seed, gelatin, shellac, rosin, and casein. Examples of the semi-synthetic polymer include sodium carboxymethyl cellulose, hydroxyethyl cellulose, methyl cellulose, ethyl cellulose, sodium alginate, ester gum, nitrocellulose, hydroxypropyl cellulose, hydroxypropyl methylcellulose, and crystalline cellulose. Examples of the synthetic polymer include acrylic acid / alkyl methacrylate copolymer, acrylic acid / polyoxyethylene alkyl itaconic acid copolymer, alkyl acrylate / polyoxyethylene alkyl ether copolymer, acrylic acid / Examples include hydroxyalkyl acrylate copolymers, acrylic acid / polyoxyethylene alkyl ether cross-polymers of methacrylic acid, acrylic acid / vinyl neodecanoate cross-polymers, polyvinyl alcohol, sodium polyacrylate, carboxyvinyl polymer, polyvinyl methyl cellulose, polyamide resins, etc. It is done. Examples of the clay mineral include fluorosilicic acid (sodium / magnesium) and synthetic silicic acid (sodium / magnesium).
　上記高級アルコールとしては、例えば、ラウリルアルコール、ミリスチルアルコール、セチルアルコール、ステアリルアルコール、オレイルアルコール、ベヘニルアルコールなどが挙げられる。上記高級アルコールは、１種を単独で用いても良く、２種以上を適宜組み合わせて用いても良い。 Examples of the higher alcohol include lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, oleyl alcohol, and behenyl alcohol. The above higher alcohols may be used alone or in combination of two or more.
　上記清涼剤としては、例えば、ｌ－メントール、メンチルグリセリルエーテル、メンチルラクテート、１－メンチル－３－ヒドロキシブチレート、ｄｌ－カンファ、オイゲノール、メントン、ミント、サリチル酸メンチル、ユーカリ油などが挙げられる。上記清涼剤は、１種を単独で用いても良く、２種以上を適宜組み合わせて用いても良い。 Examples of the refreshing agent include l-menthol, menthyl glyceryl ether, menthyl lactate, 1-menthyl-3-hydroxybutyrate, dl-camphor, eugenol, menthone, mint, menthyl salicylate, and eucalyptus oil. The said refreshing agent may be used individually by 1 type, and may be used in combination of 2 or more type as appropriate.
　本発明の皮膚洗浄剤用組成物は、例えば、ペースト状、クリーム状、乳液状、ジェル状、液状などの様々な剤型に調製することができる。中でも、上記炭化水素ワックス粒子であるスクラブ剤の分散状態に優れる観点から、ペースト状、クリーム状、ジェル状の剤型の皮膚洗浄剤用組成物に調製することが好ましい。 The composition for skin cleanser of the present invention can be prepared in various dosage forms such as paste, cream, emulsion, gel, and liquid. Among these, it is preferable to prepare a paste-like, cream-like, or gel-like skin cleansing composition from the viewpoint of excellent dispersion state of the scrub agent that is the hydrocarbon wax particles.
　本発明の皮膚洗浄剤用組成物の製造方法は、公知の製造方法であれば特に限定されないが、例えば、上記構成成分を適宜混合し、ディスパーミキサー、ホモミキサー、ディスパーミルなどを用いて攪拌する方法が挙げられる。 The method for producing the composition for skin cleanser of the present invention is not particularly limited as long as it is a known production method. For example, the above components are mixed as appropriate and stirred using a disper mixer, homomixer, disper mill or the like. A method is mentioned.
　本発明の皮膚洗浄剤用組成物では、上記炭化水素ワックス粒子をスクラブ剤の用途として用いることを特徴とする。すなわち、本発明では、スクラブ効果を発揮させるために、皮膚洗浄剤用組成物中に炭化水素ワックス粒子として存在させる必要がある。そのため、本発明の皮膚洗浄剤用組成物の好適な製造方法としては、例えば、上記炭化水素ワックス粒子以外の構成成分を約７０℃以上の温度で加熱混合攪拌して組成物を調製し、当該組成物の温度が約４０℃以下になった状態で上記炭化水素ワックス粒子を投入後、攪拌して調製する方法などが挙げられる。 In the composition for skin cleanser of the present invention, the hydrocarbon wax particles are used as a scrub agent. That is, in the present invention, in order to exert the scrub effect, it is necessary to be present as hydrocarbon wax particles in the skin cleansing composition. Therefore, as a suitable method for producing the composition for skin cleanser of the present invention, for example, a composition is prepared by heating and mixing and stirring components other than the hydrocarbon wax particles at a temperature of about 70 ° C. or higher. Examples thereof include a method in which the hydrocarbon wax particles are added in a state where the temperature of the composition is about 40 ° C. or less and then stirred to prepare.
　以下、本発明を実施例に基づいて更に詳細に説明するが、本発明はこれら実施例にのみ限定されるものではない。尚、配合量は特記しない限り「質量％」を表し、配合成分は全て純分に換算した。また、評価はすべて２３℃、湿度６０％の恒温恒湿の一定条件下で実施した。 Hereinafter, the present invention will be described in more detail based on examples, but the present invention is not limited only to these examples. The blending amount represents “% by mass” unless otherwise specified, and all blending components were converted to pure. All the evaluations were performed under constant conditions of 23 ° C. and 60% humidity.
　実施例および比較例で用いたスクラブ剤は、下記成分を用いた。 The following components were used for the scrub agent used in Examples and Comparative Examples.
　スクラブ剤１（パラフィンワックス粒子）：商品名「ＨＮＰ－５１」（日本精蝋社製、平均粒子径：約２５０μｍ）
　スクラブ剤２（フィッシャー・トロプシュワックス粒子）：商品名「Ｓｙｎｓｃｒｕｂ　５０ＰＣ」（マイクロパウダーズ社製、粒子径：１８０～２９７μｍ）
　スクラブ剤３（パラフィンワックス粒子）：商品名「Ｐａｒａｆｆｉｎ　Ｗａｘ－１５５」（日本精蝋社製、平均粒子径：約９００μｍ）
　スクラブ剤４（マイクロクリスタリンワックス粒子）：商品名「Ｈｉ－Ｍｉｃ－１０８０」（日本精蝋社製、平均粒子径：約９００μｍ）
　スクラブ剤５（フィッシャー・トロプシュワックス粒子）：商品名「Ｓｙｎｓｃｒｕｂ　２０ＰＣ」（マイクロパウダーズ社製、粒子径：５００～８４０μｍ） Scrub agent 1 (paraffin wax particles): trade name “HNP-51” (manufactured by Nippon Seiwa Co., Ltd., average particle size: about 250 μm)
Scrub agent 2 (Fischer-Tropsch wax particles): trade name “Synscrub 50PC” (manufactured by Micro Powders, particle diameter: 180-297 μm)
Scrub agent 3 (paraffin wax particles): trade name “Paraffin Wax-155” (manufactured by Nippon Seiwa Co., Ltd., average particle size: about 900 μm)
Scrub agent 4 (microcrystalline wax particles): trade name “Hi-Mic-1080” (manufactured by Nippon Seiwa Co., Ltd., average particle size: about 900 μm)
Scrub agent 5 (Fischer-Tropsch wax particles): trade name “Synscrub 20PC” (manufactured by Micro Powders, particle diameter: 500 to 840 μm)
　アンズ核粒１：商品名「ＡＰグリッド＜球状＞＃４０－６０」（一丸ファルコス社製、粒子径：１７７μｍ～４２０μｍ）
　アンズ核粒２：商品名「ＡＰグリッド＜球状＞＃６０－８０」（一丸ファルコス社製、粒子径：１４９μｍ～２９７μｍ） Apricot kernel 1: Trade name “AP grid <spherical># 40-60” (manufactured by Ichimaru Falcos, particle size: 177 μm to 420 μm)
Apricot kernel 2: Trade name “AP grid <spherical># 60-80” (manufactured by Ichimaru Falcos, particle size: 149 μm to 297 μm)
　ポリエチレンビーズ：商品名「Ｍｉｃｒｏｓｃｒｕｂ　１４３５ＰＣ」（マイクロパウダーズ社製、粒子径：５００～１４１０μｍ）
　シリカビーズ：商品名「ＳＣＲＵＢ　ＳＩＬＩＣＡ　８５０Ｇ」（日揮触媒化成社製、平均粒子径：約７２０μｍ） Polyethylene beads: trade name “Microscrub 1435PC” (manufactured by Micro Powders, particle size: 500-1410 μm)
Silica beads: Trade name “SCRUB SILICA 850G” (manufactured by JGC Catalysts & Chemicals, average particle size: about 720 μm)
（各試料の調製１）
　表１に記した組成に従い、実施例１～６および比較例１～２の皮膚洗浄剤用組成物を調製後、３０ｇ容量のチューブ容器に夫々充填し、下記評価試験に供した。結果を表１に併記する。 (Preparation 1 of each sample)
According to the composition shown in Table 1, after preparing the compositions for skin cleansing agents of Examples 1 to 6 and Comparative Examples 1 and 2, each was filled in a tube container of 30 g capacity and subjected to the following evaluation test. The results are also shown in Table 1.
（試験例１：使用感の評価）
　男性官能評価パネル１０名により、実施例および比較例で得られた各試料を用いて洗顔剤の態様で下記使用試験を行い、使用感の評価を行った。 (Test Example 1: Evaluation of feeling of use)
Using the male sensory evaluation panels, the following usage test was conducted in the form of a facial cleanser using each sample obtained in the examples and comparative examples, and the feeling of use was evaluated.
　顔全体を４０℃の温水で十分に濡らした後、手の平に試料１ｇを取り、少量の温水で泡立てた後、顔全体に塗布し手の平で擦るように３０秒間洗顔を行い、その後４０℃の温水で十分に洗い流してもらった。評価は、洗顔時の「皮膚刺激感・異物感」および「スクラブ効果」について評価を行い、下記評価基準に従って官能評価した。なお、評価は、最も人数の多く得られた評価結果を各試料の成績とした。 After fully wetting the entire face with warm water of 40 ° C, take 1 g of sample on the palm, lather with a small amount of warm water, apply to the entire face and wash the face for 30 seconds by rubbing with the palm, then warm water of 40 ° C I was thoroughly washed away. In the evaluation, the “skin irritation / foreign body sensation” and the “scrub effect” at the time of face washing were evaluated, and sensory evaluation was performed according to the following evaluation criteria. In addition, evaluation made the result of each sample the evaluation result obtained most people.
＜皮膚刺激感・異物感の評価基準＞
○（良好）：ほとんど感じない
△（不十分）：少し感じる
×（不良）：感じる（痛みを感じる） <Evaluation criteria for skin irritation and foreign body feeling>
○ (good): hardly felt △ (insufficient): feel a little × (poor): feel (feel pain)
＜スクラブ効果の評価基準＞
◎（非常に良好）：十分にある
○（良好）：ある
△（不十分）：あまりない
×（不良）：ない <Evaluation criteria for scrub effect>
◎ (very good): enough ○ (good): some △ (insufficient): not much × (poor): none
Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000001
　表１の結果から、洗顔剤である各実施例の皮膚洗浄剤用組成物は、各比較例のものと対比して、不快な皮膚刺激感や異物感を与えることがなく使用感に優れるとともに、最適なスクラブ効果を発揮していることが分かる。 From the results of Table 1, the skin cleansing composition of each example, which is a facial cleanser, is superior to the feeling of use without giving an unpleasant skin irritation or foreign body feeling, as compared with those of each comparative example. It can be seen that the optimum scrubbing effect is exhibited.
（各試料の調製２）
　表２に記した組成に従い、実施例７～１２および比較例３～４の皮膚洗浄剤用組成物を調製後、６０ｇ容量のボトル容器に夫々充填し、下記評価試験に供した。結果を表２に併記する。 (Preparation 2 of each sample)
According to the composition described in Table 2, after preparing the skin cleansing compositions of Examples 7 to 12 and Comparative Examples 3 to 4, they were each filled into a 60 g capacity bottle container and subjected to the following evaluation test. The results are also shown in Table 2.
（試験例２：使用感の評価）
　男性官能評価パネル１０名により、実施例および比較例で得られた各試料を用いてボディシャンプーの態様で下記使用試験を行い、使用感の評価を行った。 (Test Example 2: Evaluation of usability)
Using the male sensory evaluation panels, the following usage tests were conducted in the form of body shampoo using the samples obtained in the examples and comparative examples, and the feeling of use was evaluated.
　身体全体を４０℃の温水で十分に濡らした後、手の平に試料３ｇを取り、少量の温水で泡立てた後、身体全体を洗い、その後４０℃の温水で十分に洗い流してもらった。評価は、洗い時の「皮膚刺激感・異物感」および「スクラブ効果」について評価を行い、下記評価基準に従って官能評価した。なお、評価は、最も人数の多く得られた評価結果を各試料の成績とした。 After fully wetting the whole body with warm water of 40 ° C., 3 g of a sample was taken on the palm, foamed with a small amount of warm water, washed the whole body, and then thoroughly washed with warm water of 40 ° C. In the evaluation, “skin irritation / foreign material sensation” and “scrub effect” at the time of washing were evaluated, and sensory evaluation was performed according to the following evaluation criteria. In addition, evaluation made the result of each sample the evaluation result obtained most people.
＜皮膚刺激感・異物感の評価基準＞
○（良好）：ほとんど感じない
△（不十分）：少し感じる
×（不良）：感じる（痛みを感じる） <Evaluation criteria for skin irritation and foreign body feeling>
○ (good): hardly felt △ (insufficient): feel a little × (poor): feel (feel pain)
＜スクラブ効果の評価基準＞
◎（非常に良好）：十分にある
○（良好）：ある
△（不十分）：あまりない
×（不良）：ない <Evaluation criteria for scrub effect>
◎ (very good): enough ○ (good): some △ (insufficient): not much × (poor): none
Figure JPOXMLDOC01-appb-T000002
Figure JPOXMLDOC01-appb-T000002
　表２の結果から、ボディシャンプーである各実施例の皮膚洗浄剤用組成物は、各比較例のものと対比して、不快な皮膚刺激感や異物感を与えることがなく使用感に優れるとともに、最適なスクラブ効果を発揮していることが分かる。 From the results of Table 2, the composition for skin cleanser of each example, which is a body shampoo, is superior to the feeling of use without giving an unpleasant skin irritation or foreign body sensation as compared with those of each comparative example. It can be seen that the optimum scrubbing effect is exhibited.

Claims (6)

  1. 　炭化水素ワックス粒子であることを特徴とするスクラブ剤。 Scrub agent characterized by being hydrocarbon wax particles.
  2. 　前記炭化水素ワックス粒子の平均粒子径が、１００～１，０００μｍであることを特徴とする請求項１に記載のスクラブ剤。 The scrub agent according to claim 1, wherein the hydrocarbon wax particles have an average particle size of 100 to 1,000 µm.
  3. 　前記炭化水素ワックス粒子が、石油由来炭化水素ワックス粒子および合成炭化水素ワックス粒子の群から選ばれることを特徴とする請求項１又は２に記載のスクラブ剤。 The scrub agent according to claim 1 or 2, wherein the hydrocarbon wax particles are selected from the group of petroleum-derived hydrocarbon wax particles and synthetic hydrocarbon wax particles.
  4. 　請求項１～３の何れか一項に記載のスクラブ剤を含有することを特徴とする皮膚洗浄剤用組成物。 A skin cleansing composition comprising the scrub agent according to any one of claims 1 to 3.
  5. 　スクラブ剤の含有量が、０．１～３０質量％である請求項４に記載の皮膚洗浄剤用組成物。 The composition for a skin cleanser according to claim 4, wherein the content of the scrub agent is 0.1 to 30% by mass.
  6. 　さらに、高級脂肪酸塩を含有することを特徴とする請求項４又は５に記載の皮膚洗浄剤用組成物。 The composition for skin cleanser according to claim 4 or 5, further comprising a higher fatty acid salt.
PCT/JP2017/018632 2016-05-19 2017-05-18 Scrubbing agent and skin cleansing composition comprising same WO2017200036A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2018518348A JPWO2017200036A1 (en) 2016-05-19 2017-05-18 Scrub agent and composition for skin cleanser containing the scrub agent

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2016100880 2016-05-19
JP2016-100880 2016-05-19

Publications (1)

Publication Number Publication Date
WO2017200036A1 true WO2017200036A1 (en) 2017-11-23

Family

ID=60326491

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2017/018632 WO2017200036A1 (en) 2016-05-19 2017-05-18 Scrubbing agent and skin cleansing composition comprising same

Country Status (2)

Country Link
JP (1) JPWO2017200036A1 (en)
WO (1) WO2017200036A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7571352B1 (en) 2024-03-21 2024-10-23 資生堂ホネケーキ工業株式会社 Powder granulation

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004269494A (en) * 2002-09-23 2004-09-30 Johnson & Johnson Consumer Co Inc Composition for exfoliating skin and treating blackhead
JP2005537275A (en) * 2002-07-18 2005-12-08 ユニリーバー・ナームローゼ・ベンノートシヤープ Cosmetic stick having both release and moisture retention properties
JP2006512309A (en) * 2002-11-08 2006-04-13 ユニリーバー・ナームローゼ・ベンノートシヤープ Liquid cleansing composition having both exfoliating and wetting properties
JP2015172187A (en) * 2014-02-19 2015-10-01 株式会社コーセー detergent composition
US20150320674A1 (en) * 2014-05-08 2015-11-12 Micro Powders, Inc. Compositions Comprising Synthetic Waxes
JP2017039660A (en) * 2015-08-19 2017-02-23 株式会社マンダム Skin cleansing composition and method for producing skin cleansing composition

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005537275A (en) * 2002-07-18 2005-12-08 ユニリーバー・ナームローゼ・ベンノートシヤープ Cosmetic stick having both release and moisture retention properties
JP2004269494A (en) * 2002-09-23 2004-09-30 Johnson & Johnson Consumer Co Inc Composition for exfoliating skin and treating blackhead
JP2006512309A (en) * 2002-11-08 2006-04-13 ユニリーバー・ナームローゼ・ベンノートシヤープ Liquid cleansing composition having both exfoliating and wetting properties
JP2015172187A (en) * 2014-02-19 2015-10-01 株式会社コーセー detergent composition
US20150320674A1 (en) * 2014-05-08 2015-11-12 Micro Powders, Inc. Compositions Comprising Synthetic Waxes
JP2017039660A (en) * 2015-08-19 2017-02-23 株式会社マンダム Skin cleansing composition and method for producing skin cleansing composition

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7571352B1 (en) 2024-03-21 2024-10-23 資生堂ホネケーキ工業株式会社 Powder granulation

Also Published As

Publication number Publication date
JPWO2017200036A1 (en) 2018-11-15

Similar Documents

Publication Publication Date Title
JP5522828B2 (en) Skin cleanser
JP6482722B2 (en) Warm feeling cosmetics
JP2010270066A (en) Hairdressing cosmetic
JP5495810B2 (en) Non-aqueous warm skin cleansing composition
JP2015093859A (en) Cosmetic
TW526265B (en) Cleansing agents
JP2012240988A (en) Gel cosmetic for cleansing
TWI641392B (en) Detergent composition and manufacturing method thereof
JP6812099B2 (en) Skin cleanser
JPH10167953A (en) Cosmetic composition
WO2017200036A1 (en) Scrubbing agent and skin cleansing composition comprising same
JP5680496B2 (en) Warmth cleaning agent
BR112015032654B1 (en) fluid and foamy personal care composition and method for forming a fluid and foamable personal care composition
JP2001072573A (en) Cosmetic for face washing
JP2010229070A (en) Hair dressing agent
JP6986329B2 (en) Wrinkle-relieving skin cleanser
JP6242179B2 (en) Transparent detergent composition
JP6990496B2 (en) Detergent composition
JP2001072574A (en) Cosmetic for face cleansing
JP6366437B2 (en) Skin cleanser composition
JP2001072574A5 (en)
JP2007161906A (en) Composition for foam detergent, and foam detergent
JP2016216412A (en) Cleansing cosmetic
JP2015205862A (en) Cosmetic and aging odor inhibitor
JP6375860B2 (en) Gel-like cleaning material

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 2018518348

Country of ref document: JP

NENP Non-entry into the national phase

Ref country code: DE

121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 17799460

Country of ref document: EP

Kind code of ref document: A1

122 Ep: pct application non-entry in european phase

Ref document number: 17799460

Country of ref document: EP

Kind code of ref document: A1