WO2017126810A1 - 방향성 전기강판의 자구미세화 방법과 그 장치 - Google Patents
방향성 전기강판의 자구미세화 방법과 그 장치 Download PDFInfo
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- WO2017126810A1 WO2017126810A1 PCT/KR2016/015160 KR2016015160W WO2017126810A1 WO 2017126810 A1 WO2017126810 A1 WO 2017126810A1 KR 2016015160 W KR2016015160 W KR 2016015160W WO 2017126810 A1 WO2017126810 A1 WO 2017126810A1
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- steel sheet
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- irradiation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/08—Devices involving relative movement between laser beam and workpiece
- B23K26/082—Scanning systems, i.e. devices involving movement of the laser beam relative to the laser head
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/08—Devices involving relative movement between laser beam and workpiece
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/16—Removal of by-products, e.g. particles or vapours produced during treatment of a workpiece
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/352—Working by laser beam, e.g. welding, cutting or boring for surface treatment
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/352—Working by laser beam, e.g. welding, cutting or boring for surface treatment
- B23K26/354—Working by laser beam, e.g. welding, cutting or boring for surface treatment by melting
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/36—Removing material
- B23K26/362—Laser etching
- B23K26/364—Laser etching for making a groove or trench, e.g. for scribing a break initiation groove
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/70—Auxiliary operations or equipment
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/70—Auxiliary operations or equipment
- B23K26/702—Auxiliary equipment
- B23K26/704—Beam dispersers, e.g. beam wells
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K37/00—Auxiliary devices or processes, not specially adapted to a procedure covered by only one of the preceding main groups
- B23K37/04—Auxiliary devices or processes, not specially adapted to a procedure covered by only one of the preceding main groups for holding or positioning work
- B23K37/047—Auxiliary devices or processes, not specially adapted to a procedure covered by only one of the preceding main groups for holding or positioning work moving work to adjust its position between soldering, welding or cutting steps
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/74—Methods of treatment in inert gas, controlled atmosphere, vacuum or pulverulent material
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D10/00—Modifying the physical properties by methods other than heat treatment or deformation
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
- C21D8/1216—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties the working step(s) being of interest
- C21D8/1238—Flattening; Dressing; Flexing
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/0006—Details, accessories not peculiar to any of the following furnaces
- C21D9/0012—Rolls; Roll arrangements
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/52—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
- C21D9/54—Furnaces for treating strips or wire
- C21D9/56—Continuous furnaces for strip or wire
- C21D9/561—Continuous furnaces for strip or wire with a controlled atmosphere or vacuum
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/52—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
- C21D9/54—Furnaces for treating strips or wire
- C21D9/56—Continuous furnaces for strip or wire
- C21D9/562—Details
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/52—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
- C21D9/54—Furnaces for treating strips or wire
- C21D9/56—Continuous furnaces for strip or wire
- C21D9/562—Details
- C21D9/563—Rolls; Drums; Roll arrangements
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/52—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
- C21D9/54—Furnaces for treating strips or wire
- C21D9/56—Continuous furnaces for strip or wire
- C21D9/562—Details
- C21D9/564—Tension control
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D10/00—Modifying the physical properties by methods other than heat treatment or deformation
- C21D10/005—Modifying the physical properties by methods other than heat treatment or deformation by laser shock processing
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
- C21D8/1277—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties involving a particular surface treatment
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
- C21D8/1294—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties involving a localized treatment
Definitions
- the present invention relates to a method for minimizing magnetic domain of a grain-oriented electrical steel sheet and a device for irradiating a laser to the grain-oriented electrical steel sheet to permanently refine the magnetic domain of the steel sheet.
- oriented electrical steel sheets having magnetic properties having low iron loss and high magnetic flux density are required.
- the domain refinement method can be broadly classified into temporary domain micronization and permanent domain micronization according to whether or not to maintain the domain domain improvement effect after stress relief annealing.
- Temporary magnetic micronization method has a disadvantage in that the magnetic micronization effect is lost after stress relief annealing.
- the temporary magnetic domain miniaturization method refines the magnetic domain by forming a local compressive stress portion on the surface of the steel sheet.
- this method requires recoating because it causes damage to the insulating coating layer on the surface of the steel sheet, and has a disadvantage in that manufacturing cost is high because the micronizing treatment is performed in an intermediate process instead of the final product.
- Permanent magnetization can maintain the iron loss improvement after heat treatment.
- a technique using an etching method, a roll method, or a laser method is mainly used.
- the etching method it is difficult to control the depth or width of the groove formation, it is difficult to guarantee the iron loss characteristics of the final product, and it is not environmentally friendly because the acid solution is used.
- a roll process there are disadvantages in that the stability, reliability and process for machining are complicated.
- the magnetic domain can be refined by forming a molten groove on the surface of the steel sheet by irradiating a laser beam on the surface of the steel sheet while supporting the steel sheet and adjusting the tension.
- a more effective process improvement and optimization is required in order to enable high-speed processing and to lower iron loss and increase magnetic flux density of electrical steel sheets.
- the present invention provides a method and apparatus for magnetizing microstructured grain-oriented electrical steel sheet which can increase the micronization efficiency and improve workability to increase processing capacity.
- the present invention provides a method and apparatus for magnetizing a grain-oriented electrical steel sheet capable of preventing a groove depth deviation caused by a change in focal length of a laser beam.
- the present invention provides a method and apparatus for magnetizing a grain-oriented electrical steel sheet capable of improving the iron loss improving efficiency and minimizing the decrease in magnetic flux density.
- the present invention provides a method and apparatus for fine-grained grain-oriented electrical steel sheet which can effectively remove contaminants such as heel-up and spatter formed by laser irradiation to improve product quality.
- a method and apparatus for magnetizing a grain-oriented electrical steel sheet capable of providing an optimal operating environment required for a process.
- the irradiation angle of the laser beam with respect to the width direction of the steel sheet can be converted into a range of ⁇ 4 °.
- the focal length maintaining step may include an inclination angle calculation step of calculating an inclination of the steel sheet support roll according to a laser beam focal length change of the steel sheet surface according to the rotation of an optical system, and an amount of the steel sheet support roll according to a value obtained in the inclination angle calculation step. It may include an inclination adjustment step of changing the inclination of the steel sheet support roll by moving the tip portion up and down, respectively.
- the inclination angle calculation step is an optical angle calculation step of calculating the rotation angle of the optical system according to the angle of the laser beam irradiation line, the tilt calculation of obtaining the inclination angle of the steel sheet support roll according to the rotation angle of the optical system obtained by the optical system angle calculation step And a roll control step of calculating a stretch driving amount of each lifting cylinders disposed at both ends of the steel plate supporting roll and applying an output signal to each of the lifting cylinders according to the gradient values obtained in the step and the tilt calculation step.
- the optical system angle calculating step may be a structure for calculating the rotation angle of the optical system rotated in accordance with the angle of the irradiation line from the irradiation interval of the laser beam and the steel plate moving speed.
- the laser irradiation step is a steel sheet at the reference point with respect to the surface of the steel sheet that is in contact with the surface of the steel sheet support roll in the form of an arc, the laser beam irradiation position when the irradiation direction of the laser beam passes through the central axis of the steel sheet support roll as a reference point
- the laser beam may be irradiated at a position spaced from the center of the support roll along the outer circumferential surface at an angle.
- the laser beam may be irradiated in a range of 3 to 7 ° along the outer circumferential surface at the center of the steel sheet support roll with respect to the reference point.
- the magnetic domain refinement method may further include a setting and maintaining step of setting and maintaining an internal operating environment of the laser room where the laser irradiation is performed.
- the magnetic domain refinement method may further include a tension control step of applying tension to the steel sheet to maintain the steel sheet in a flat unfolded state.
- the magnetic domain miniaturization method may further include a meandering control step of allowing the steel sheet to move left and right along the center of the production line without bias.
- the setting and maintaining step may include isolating the inside of the laser room from the outside to block the inflow of external contaminants, and controlling the temperature, pressure, and humidity inside the laser room.
- the magnetic domain refinement method may further include a post-treatment step for removing heel up and spatter formed on the surface of the steel sheet through a laser irradiation step.
- the post-treatment step may include a brush step of removing heel up and spatter on the surface of the steel sheet with a brush roll.
- the post-treatment step includes a cleaning step of further removing the heel up and spatter remaining on the surface of the steel sheet by electrolytically reacting the steel sheet with an alkaline solution, and filtering foreign substances contained in the alkaline solution removed from the steel sheet in the cleaning step from the alkaline solution.
- the method may further include a filtering step to bet.
- the meandering control step includes a meandering amount measuring step of measuring a meandering amount at which the width center position of the steel sheet is out of the center of the production line, and a shaft of a steering roll according to the meandering amount of the steel sheet measured in the meandering amount measuring step. It may include a meandering amount control step of controlling the meandering amount of the steel sheet by rotating and moving to adjust the direction in which the steel sheet moves.
- the meandering amount control step may control the meandering amount of the steel sheet within ⁇ 1mm.
- the tension control step may include a steel sheet tension applying step of applying tension to the steel sheet by the tension bridle roll, a steel sheet tension measuring step of measuring tension of the steel sheet subjected to the steel sheet tension applying step, and The steel sheet tension control step of controlling the steel sheet tension by adjusting the speed of the tension bridal roll according to the tension of the steel sheet measured in the steel sheet tension measurement step.
- the steel sheet support roll position adjusting step may include a steel sheet supporting step of supporting a steel sheet positioned in the laser irradiation step with a steel sheet supporting roll, a brightness measuring step of measuring brightness of a flame generated when laser irradiation is applied to the steel sheet in the laser irradiation step; Steel sheet support roll position control step of controlling the position of the steel sheet in the depth of focus by adjusting the position of the steel sheet support roll by the steel sheet support roll position control system according to the brightness of the flame measured in the brightness measurement step It may include.
- the laser irradiation step by irradiating the surface of the steel sheet by the optical system receiving the laser beam irradiated from the laser oscillator to form grooves of the upper width, lower width and depth of less than 70 ⁇ m, less than 10 ⁇ m, 3-30 ⁇ m respectively
- a laser irradiation and energy transfer step of delivering a laser beam energy density within a range of 1.0 to 5.0 J / mm 2 necessary for melting of the steel sheet to produce a resolidification portion remaining in the groove inner wall of the molten portion when the laser beam is irradiated. Can be.
- the laser oscillator is turned on by the laser oscillator controller under normal working conditions, and the laser oscillator is turned off when the steel sheet has a meandering amount of 15 mm or more. It may include a beam oscillation control step.
- the laser oscillator may oscillate a single mode continuous wave laser beam.
- the optical system may control the laser scanning speed to adjust the interval of the laser beam irradiation line to 2 to 30 mm in the rolling direction.
- the laser irradiation step may further include a dust collecting step of sucking and removing a fume generated during laser beam irradiation and molten iron.
- the dust collecting step may include a spraying step for removing the molten iron remaining in the grooves by spraying compressed dry air into the grooves of the steel sheet.
- the laser irradiation step may further include a blocking step of blocking scattered light and heat of the laser beam from entering the optical system of the laser irradiation facility.
- the magnetic domain micronizing device of this embodiment is a steel plate support roll position adjusting device for controlling the steel plate moving along the production line while controlling the vertical position of the steel plate, and by irradiating a laser beam to melt the steel plate to form grooves on the surface of the steel plate.
- a laser irradiating device to be formed wherein the laser irradiating device has a structure in which an optical system for irradiating a laser beam to a steel sheet is rotatable by a driving unit, and the optical system is rotated with respect to the steel sheet to irradiate the laser beam with respect to the width direction of the steel sheet.
- the angle conversion structure and may further include a focal length maintaining unit for changing the inclination of the steel sheet support roll for supporting the steel sheet in accordance with the change in the focal length of the laser beam along the width direction of the steel sheet.
- the focal length maintaining part is installed in each of the front end of the control unit for calculating the inclination of the steel sheet support roll and the tilt of the steel sheet support roll according to the laser beam focal length change of the steel sheet surface according to the optical system rotation, It may include a lifting cylinder which is driven in accordance with the signal of the control unit to change the inclination by raising and lowering both ends of the steel sheet support roll up and down.
- the control unit is an optical angle calculation unit for calculating the rotation angle of the optical system according to the angle of the laser beam irradiation line, the tilt calculation unit for obtaining the inclination angle of the steel sheet support roll in accordance with the rotation angle of the optical system obtained by the optical system angle calculation unit, obtained from the tilt calculation unit It may include a roll control unit for calculating the amount of stretch driving of each lifting cylinder disposed on both ends of the steel sheet support roll in accordance with the inclination value, and applies an output signal to each lifting cylinder.
- the control unit may further include an input unit configured to input a laser beam irradiation interval, a steel plate moving speed, and an angle of the irradiation line.
- the optical system angle calculator may be configured to calculate a rotation angle of the optical system rotated according to the angle of the irradiation line from the irradiation interval of the laser beam and the steel plate moving speed.
- the laser irradiation equipment is a steel sheet at the reference point with respect to the surface of the steel sheet which is in contact with the surface of the steel sheet supporting roll in an arc shape, with the laser beam irradiation position when the irradiation direction of the laser beam passes through the central axis of the steel sheet supporting roll as a reference point.
- the laser beam may be irradiated to a position spaced at an angle along the outer circumferential surface from the center of the support roll.
- the laser irradiation facility may be a structure for irradiating a laser beam in a range of 3 to 7 degrees along the outer circumferential surface from the center of the steel sheet support roll with respect to the reference point.
- It may further include a laser room that accommodates the steel sheet support roll position adjusting device and the laser irradiation equipment from the outside and provides an operating environment for laser irradiation.
- the steel sheet may further include a tension control device for imparting tension to the steel sheet to maintain the flat unfolded state.
- the steel sheet may further include a meandering control system for moving the left and right along the center of the production line without bias.
- the laser room accommodates the laser irradiation equipment and the steel sheet support roll position control equipment to form an inner space to isolate the outside, the inlet and the outlet is formed on both sides along the traveling direction of the steel sheet, inside the laser room It may include a positive pressure device to increase the pressure than the outside, an optical system lower frame for separating the upper space in which the optical system of the laser irradiation equipment and the lower space passing through the steel sheet, and a constant temperature and humidity controller for controlling the temperature and humidity inside the laser room.
- the apparatus may further include a post-treatment facility for removing a heel up and spatter formed on the surface of the steel sheet.
- the aftertreatment facility may include a brush roll disposed at the rear end of the laser room to remove heel up and spatter of the steel sheet surface.
- the post-treatment facility is disposed at the rear end of the brush roll and is electrolytically reacted with the alkaline solution to remove the heel up and spatter remaining on the surface of the steel sheet, and a cleaning unit connected to the cleaning unit and included in the alkaline solution of the cleaning unit. It may further include a filtering unit for filtering foreign matter from the alkaline solution.
- the meandering control device includes a steering roll for switching the moving direction of the steel sheet, a meander measuring sensor for measuring the degree of deviation of the width center position of the steel sheet from the center of the production line, and the meandering measurement.
- the steel sheet may include a strip center position control system for adjusting the direction in which the steel sheet moves by rotating and moving the axis of the steering roll according to the output value of the sensor.
- the tension control device is a tension bridle roll for inducing movement while applying tension to the steel sheet, a steel plate tension measuring sensor for measuring the tension of the steel sheet passed through the tension bridle roll, and the steel sheet
- the steel sheet may include a strip tension control system for adjusting the speed of the tension bridal roll according to the tension of the steel sheet measured by the tension measuring sensor.
- the steel sheet support roll position adjusting device is a steel sheet support roll for supporting a steel sheet at the laser irradiation equipment position, a brightness sensor for measuring the brightness of the flame generated when the laser irradiation to the steel sheet in the laser irradiation equipment, and the brightness measurement It may include a steel sheet support roll position control system for controlling the position of the steel sheet support roll according to the brightness of the flame measured by the sensor.
- the laser irradiation equipment is a laser oscillator for oscillating a continuous wave laser beam, the laser beam oscillated from the laser oscillator is irradiated on the surface of the steel sheet, the upper width, lower width and depth of each within 70 ⁇ m, within 10 ⁇ m, 3 to
- the laser irradiation apparatus may further include a laser oscillator controller for controlling the laser oscillator to an off state when the laser oscillator is turned on under normal working conditions and the steel sheet meandering amount is 15 mm or more.
- the laser oscillator may oscillate a single mode continuous wave laser beam.
- the optical system may control the laser scanning speed to adjust the interval of the laser irradiation line to 2 to 30mm along the rolling direction.
- the laser irradiation facility may further include a shielding unit for blocking laser scattered light and heat from entering the optical system.
- the laser irradiation equipment may further include molten iron removal equipment for removing the fumes and spatter generated by the laser beam irradiation on the steel sheet.
- the molten iron removal equipment may include an air knife for removing the molten iron remaining in the groove by injecting compressed dry air into the groove of the steel sheet, and a dust collecting hood for sucking and removing the fume and the molten iron.
- the magnetic domain miniaturization process is stably performed by laser, and the iron loss improvement rates before and after heat treatment of the electrical steel sheet are respectively 5% or more and 10%. The above can be secured.
- FIG. 1 is a view schematically showing the configuration of a magnetic domain micronizing device of a grain-oriented electrical steel sheet according to the present embodiment.
- FIG. 2 is a schematic view showing a steel sheet microstructured according to the present embodiment.
- FIG. 3 is a schematic diagram illustrating a change in focal length of a laser beam according to rotation of an optical system with respect to a steel sheet according to the present embodiment.
- Figure 4 is a schematic diagram showing the structure of the focal length holding unit for adjusting the tilt of the steel sheet support roll according to this embodiment.
- FIG 5 is a graph showing the groove depth of the irradiation line formed in the steel sheet according to the present embodiment in comparison with the prior art.
- the present embodiment will be described by way of example as a facility for permanent magnetization of the grain-oriented electrical steel sheet used in the transformer core material.
- FIG. 1 schematically shows a magnetic domain micronizing apparatus of a grain-oriented electrical steel sheet according to this embodiment
- FIG. 2 shows a magnetic domain micronized steel sheet according to this embodiment
- the rolling direction or the steel plate moving direction means the x-axis direction in FIG. 2
- the width direction means the y-axis direction in FIG. 2 in a direction perpendicular to the rolling direction
- the width of the steel sheet with respect to the y-axis direction Means length.
- reference numeral 31 denotes an irradiation line which is dug into a groove by a laser beam and is continuously formed on the surface of the steel sheet 1.
- the magnetic domain micronizing apparatus of the grain-oriented electrical steel sheet according to the present embodiment stably performs permanent magnetization micromachining even when the steel sheet 1 proceeds at a high speed of 2 m / s or more.
- the magnetic domain micronizing device of this embodiment supports a steel plate 1 moving along a production line, and controls a steel sheet support roll position adjusting device for controlling the vertical position of the steel sheet, and irradiates a laser beam to melt the steel sheet to the surface of the steel sheet.
- the magnetic domain micronized device may further include a tension control device for imparting tension to the steel sheet so that the steel sheet is kept flat and unfolded.
- the magnetic domain micronizing device may further include a meander control device for moving the steel plate without bias left and right along the center of the production line.
- the magnetic domain micronizing device may further include a post-treatment facility for removing hill up and spatter formed on the surface of the steel sheet in accordance with the laser beam irradiation.
- Hill up refers to a portion in which the molten iron is formed by stacking a predetermined height or more on both sides of the groove portion when the groove is formed by irradiating a laser beam on the surface of the steel sheet.
- Spatter refers to molten iron generated when the laser beam is irradiated and solidified on the surface of the steel sheet.
- the apparatus may further include a focal length maintaining unit configured to maintain a constant focal length of the laser beam with respect to the surface of the steel sheet by changing the inclination of the steel sheet support roll supporting the steel sheet according to the focal length change of the laser beam along the width direction of the steel sheet. can do.
- a focal length maintaining unit configured to maintain a constant focal length of the laser beam with respect to the surface of the steel sheet by changing the inclination of the steel sheet support roll supporting the steel sheet according to the focal length change of the laser beam along the width direction of the steel sheet. can do.
- the detailed structure of the focal length holding unit will be described later in more detail.
- the meandering control device is a steering roll (2A, 2B) for switching the direction of movement of the steel sheet 1, the degree to which the center width position of the steel sheet 1 is out of the center of the production line (meandering amount) Steel plate center for adjusting the moving direction of the steel sheet 1 by calculating the meandering measurement sensor 4 for measurement and the detection signal of the meandering measurement sensor 4 to rotate and move the axes of the steering rolls 2A and 2B.
- a position control system (Strip Center Position Control System) 3 may be included.
- the meander measuring sensor 4 is disposed at the rear end of the steering roll 2B to detect the actual meandering amount of the steel sheet which has passed through the steering roll in real time.
- the steel sheet is moved straight along the center of the production line without lateral shift, thereby forming grooves on the surface of the steel sheet over the entire width of the steel sheet.
- the meandering amount of the steel sheet is measured by the meander measuring sensor 4 in the step before forming the steel sheet surface grooves by laser irradiation.
- the value measured by the meander measuring sensor 4 is output to the steel sheet central position control system, and the steel sheet central position control system calculates the output value of the meander measuring sensor to rotate the axes of the steering rolls 2A and 2B according to the calculated meandering degree. Will be moved. As the steering rolls 2A and 2B are rotated and moved in this manner, the moving direction of the steel sheet wound and moved on the steering roll is adjusted.
- the meandering amount of the steel sheet can be controlled to control the meandering amount of the steel sheet 1 within ⁇ 1 mm.
- the tension control device is a tension bridle roll (TBR) (5A, 5B) for inducing movement while applying a fixed amount of tension to the steel sheet 1, the steel sheet passed through the tension bridle roll (TBR) (5A, 5B) for inducing movement while applying a fixed amount of tension to the steel sheet 1, the steel sheet passed through the tension bridle roll ( The speed of the tension bridal rolls 5A and 5B is adjusted according to the tension of the steel sheet tension measuring sensor 7 for measuring the tension of 1) and the steel sheet 1 measured by the steel sheet tension measuring sensor 7. It may include a steel plate (Strip) tension control system 6 for the purpose.
- TBR tension bridle roll
- Strip steel plate
- the steel plate tension measuring sensor 7 is disposed at the rear end of the tension bridal roll 5B to measure in real time the actual tension of the steel sheet given tension through the tension bridal roll 5B.
- the tension of the steel sheet can be set so that the steel sheet surface shape at the laser irradiation position of the laser irradiation equipment is made flat so that no breakage of the steel sheet occurs due to too much tension.
- the tension control device is a tension bridle roll (Tension Bridle Roll) by the steel sheet (Stripe) tension control system 6 in accordance with the tension of the steel sheet measured by the steel sheet tension measuring sensor 7 in order to operate in the steel sheet tension within a set range: TBR) (5A, 5B) to adjust the speed.
- TBR set range
- the tension control device controls the tension error of the steel sheet 1 to be within the set range to impart tension to the steel sheet.
- the steel sheet that has passed through the tension control equipment is introduced into the laser room 20 to be finely processed through the steel plate supporting roll position adjusting device and the laser irradiation facility, and then to the outside of the laser room 20.
- the laser room will be described later.
- the steel sheet support roll 9 is disposed directly below the laser irradiation equipment in the laser room 20, and deflector rolls 8A and 8B are disposed on both sides with the steel sheet support rolls interposed therebetween. Is placed.
- the moving direction of the steel sheet 1 is switched so as to be directed to the steel sheet supporting roll 9 by deflector rolls 8A and 8B.
- the steel sheet 1 is shifted toward the steel plate supporting roll 9 while passing through the deflector roll 8A to be in contact with the steel plate supporting roll 9, and then the direction of the steel sheet 1 is changed to the deflector roll 8B again to deflector roll 8B. Is moved past.
- the steel sheet 1 is wound in an arc shape along the steel sheet supporting roll 9 and passes while being in surface contact with the steel sheet supporting roll.
- the steel sheet In order to minimize the laser beam focal length fluctuation caused by the vibration and wave of the steel sheet during the laser beam irradiation, the steel sheet must pass through in sufficient surface contact with the steel sheet support roll, and in this state, the laser beam is applied to the steel sheet which is traveling along the steel sheet support roll. You should investigate.
- the laser beam can be accurately irradiated onto the steel sheet.
- the steel sheet supporting roll position adjusting device is a steel sheet supporting roll 9 for supporting the steel sheet 1 at the laser irradiation position of the laser irradiation equipment, and the brightness of the flame generated when laser irradiation is applied to the steel sheet 1 at the laser irradiation equipment.
- a steel plate support roll (SPR) position control system 12 for controlling the position of the steel plate support roll 9 according to the brightness of the flame measured by the brightness measurement sensor 10 and the brightness measurement sensor 10. ) May be included.
- the steel sheet supporting roll position adjusting device supports the steel sheet 1 at the laser irradiation part position by the steel sheet supporting roll 9, and the steel sheet is positioned in the depth of focus with high laser steel sheet irradiation efficiency.
- the position of the steel plate supporting roll 9 is adjusted up and down as a whole so that the brightness of the spark generated during laser irradiation is the best.
- the brightness of the flame generated when the laser is irradiated on the steel sheet is measured using the luminance measuring sensor 10.
- the steel sheet support roll position adjusting device may further include a distance measuring sensor 11 for measuring the actual distance between the surface of the steel sheet from the optical system of the laser irradiation equipment.
- the steel sheet supporting roll position control system 12 calculates the distance between the optical system and the surface of the steel sheet actually measured by the brightness of the flame detected by the luminance measuring sensor 10 and the distance measuring sensor 11 and the position of the steel sheet supporting roll 9. Control more precisely.
- the meandering control device, the tension control device, and the steel sheet support roll position adjusting device serve to create a steel sheet condition at the laser irradiation position so that the laser groove can be precisely formed on the steel sheet by the laser irradiation facility.
- the steel sheet at the laser irradiation position should be at the center position of the production line and the distance from the optical system should be maintained at the set value.
- the laser irradiation equipment may include a laser oscillator controller 13, a laser oscillator 14 for oscillating the continuous wave laser beam 16, and an optical system 15.
- the laser oscillator controller 13 turns on the laser oscillator under normal operation conditions and controls the laser oscillator off when the steel sheet meandering amount is 15 mm or more. do.
- the laser oscillator 14 may oscillate a single mode continuous wave laser beam and transmit it to the optical system 15.
- the optical system 15 irradiates the surface of the steel sheet with the transmitted laser beam 16.
- the laser oscillator 14 and the optical system 15 irradiate the surface of the steel sheet with a laser beam to form grooves having an upper width, a lower width and a depth of less than 70 ⁇ m, less than 10 ⁇ m, and 3 to 30 ⁇ m, respectively.
- the laser energy density in the range of 1.0 to 5.0 J / mm 2 necessary for melting the steel sheet may be transmitted to the steel sheet so that the resolidification portion remaining on the groove inner wall of the molten portion during irradiation is generated.
- the optical system 15 has a function of controlling the laser scanning speed so that the interval of the laser irradiation line (31 in FIG. 2) can be adjusted to 2 to 30 mm in the rolling direction.
- the iron loss of the steel sheet can be improved by minimizing the influence of the heat affected zone (HAZ, Heat Affected Zone) by the laser beam.
- the laser irradiation equipment controls the irradiation position of the laser beam to the steel sheet 1, to prevent the back reflection phenomenon that the laser beam irradiated to the steel sheet is reflected from the steel sheet to enter the optical system or the laser oscillator It is structured.
- the laser irradiation apparatus supports the steel sheet irradiating direction of the laser beam irradiated from the optical system 15 with respect to the surface of the steel sheet which is brought into contact with the surface of the steel sheet supporting roll 9 in an arc shape.
- an angle along the outer circumferential surface from the center of the steel plate supporting roll 9 from the reference point P may be a structure for irradiating a laser beam at a position spaced apart.
- the reference point P is a point where the line passing through the central axis of the steel plate supporting roll 9 and the steel plate meet in FIG. 3.
- the laser irradiation apparatus irradiates the laser beam at a position spaced apart from the reference point P by the separation angle R, such that the laser beam reflected back from the steel sheet is not incident to the optical system. Therefore, the back reflection phenomenon can be prevented and the quality of the groove shape formed by the laser beam can be maintained.
- the separation angle R may be set in the range of 3 to 7 ° along the outer circumferential surface at the center of the steel plate support roll 9 with respect to the reference point (P).
- the separation angle R which is the position at which the laser beam is irradiated, is smaller than 3 °, a part of the laser beam reflected back from the steel sheet may flow into the optical system or the laser oscillator.
- the separation angle R exceeds 7 °, grooves may not be properly formed by the laser beam, and groove formation defects may occur.
- the laser irradiation apparatus of the present embodiment prevents back reflection phenomenon and stably improves the quality of the groove shape formed by the laser beam by irradiating the laser onto the steel sheet at a predetermined angle spaced from the reference point P. It can be maintained.
- the laser irradiation equipment may be a structure for converting the irradiation line angle of the laser beam irradiated on the surface of the steel sheet with respect to the width direction of the steel sheet.
- the laser irradiation equipment can convert the angle of irradiation of the laser beam in the range of ⁇ 4 ° with respect to the width direction of the steel sheet.
- the laser irradiating device has a structure in which the optical system 15 for irradiating a laser beam to the steel sheet is rotatable by the driving unit 36 to convert the irradiation angle of the laser beam formed on the surface of the steel sheet with respect to the width direction of the steel sheet. It may be a structure. In this way, the irradiation line angle of the laser beam by the optical system is converted, so that the irradiation line 31 by the laser beam is inclined in a range of ⁇ 4 ° in a direction perpendicular to the rolling direction of the steel sheet. Therefore, it is possible to minimize the decrease in magnetic flux density due to the groove formation by the laser.
- the optical system 15 is rotated at a predetermined angle with respect to the width direction of the steel sheet in order to form the angle of irradiation of the laser beam at a predetermined angle with respect to the width direction of the steel sheet.
- the irradiation direction of the laser beam irradiated from the optical system is also changed. It is shifted in the width direction of.
- reference numeral L denotes a line segment passing through the width direction of the steel sheet
- reference numeral W denotes an irradiation line of a laser irradiated onto the steel sheet surface by the rotated optical system.
- This irradiation line L can be understood as the irradiation line 31 of the laser beam when the movement of the steel sheet is not considered.
- Reference numeral (A) means the rotation angle of the optical system with respect to the width direction of the steel sheet.
- the line segment L passing through the width direction of the steel sheet and the irradiation line W of the laser beam irradiated from the rotated optical system are The position of the steel sheet is relatively higher toward the right end around the meeting point (C), and the distance (D) between the optical system of the laser irradiation equipment and the steel sheet is gradually shortened, and the position of the steel sheet is relatively low toward the left, which is the opposite end.
- the distance E between the optical system and the steel sheet is gradually longer. As such, the distance between the optical system 15 and the steel sheet 1 is changed along the irradiation line W so that the focal length of the laser beam irradiated to the steel sheet in the optical system is changed.
- the focal length maintaining part of the present embodiment corrects the focal length change of the laser beam generated while the optical system 15 rotates in accordance with the above-described irradiation angle of angle to maintain the focal length uniformly.
- the apparatus of this embodiment is provided with a focal length holding part, and by changing the inclination of the steel plate support roll 9 for supporting the steel sheet in accordance with the change in the focal length of the laser beam with respect to the width direction of the steel sheet in accordance with the above-mentioned irradiation line angle.
- the focus distance can be kept constant.
- FIG 4 illustrates the configuration of the focal length maintaining unit according to the present embodiment.
- the focal length maintaining unit 45 controls the tilt of the steel sheet support roll 9 and controls the tilt of the steel sheet support roll according to the laser beam focal length change of the steel sheet surface according to the rotation of the optical system.
- lifting cylinders 43 and 44 respectively installed at both ends of the steel plate supporting roll 9 and driven in accordance with a signal from the controller 45 to raise and lower both ends of the steel plate supporting roll up and down to change the inclination. ) May be included.
- the control unit 45 is an inclination for calculating the inclination angle of the steel sheet support roll in accordance with the rotation angle of the optical system obtained by the optical system angle calculation unit 46, the optical system angle calculation unit to calculate the rotation angle of the optical system according to the angle of the laser beam irradiation line
- the roll control unit 48 which calculates the amount of stretch driving of the lifting cylinders 43 and 44 disposed at both ends of the steel plate supporting rolls according to the inclination value obtained by the calculating unit 47 and the tilt calculating unit and applies an output signal to each lifting cylinder. It may include.
- the controller 45 may further include an input unit 49 for inputting a laser beam irradiation interval, a steel plate moving speed, and an angle of the irradiation line.
- the optical system angle calculator 46 calculates a rotation angle of the optical system 15 that is rotated at an appropriate angle according to the irradiation line angle.
- the optical system angle calculator 46 may be configured to calculate a rotation angle of the optical system rotated according to the angle of the irradiation line in consideration of the influence of the laser beam irradiation interval and the steel plate moving speed. That is, the optical system angle calculator 46 calculates the rotation angle of the optical system from the laser beam irradiation interval, the steel plate moving speed, and the set irradiation angle.
- the optical system angle calculator 46 calculates the laser beam irradiation angle formed on the steel sheet according to the laser beam irradiation interval and the irradiation width therein, and the rotation of the optical system with respect to the angle of the given irradiation line. Save Equation (2) to find the angle. Accordingly, the optical angle calculator calculates an irradiation angle of a laser beam generated according to the influence of the steel sheet movement from Equation (1) through each numerical value applied from the input unit 49, and reflects this value in Equation (2) below. To calculate the rotation angle A of the actual optical system
- Equation (1)-laser beam irradiation angle sin -1 (laser beam irradiation interval / laser beam irradiation width)
- the laser beam irradiation angle means an angle at which the irradiation line of the laser beam is inclined with respect to the steel plate width direction as the steel sheet moves even when the optical system is not rotated.
- Equation (2)-Optical system rotation angle (A) irradiation line angle-laser beam irradiation angle
- an irradiation line angle is an angle of the irradiation line formed by irradiating a laser beam to a steel plate with respect to the width direction of a steel plate.
- the irradiation line angle is a value obtained by adding the irradiation angle of the laser beam according to the rotation of the optical system with the laser beam irradiation angle in consideration of the steel plate movement from the above formula (1). Accordingly, the rotation angle A of the optical system can be obtained by subtracting the laser beam irradiation angle obtained by the formula (1) from the set irradiation angle.
- the inclination calculator 47 calculates the inclination B of the steel plate support roll according to the optical system rotation angle calculated from the optical system angle calculator 46.
- the inclination calculation unit 47 pre-stores the formula (3) for calculating the inclination of the steel plate support roll therein.
- the tilt calculator 47 calculates the tilt B of the steel plate support roll by reflecting the irradiation line coordinate value of the laser beam according to the rotation angle of the optical system obtained through the above equation (2) to the following equation (3).
- Equation (3)-Slope of steel plate support roll (B) tan -1 (
- Z 2, Z 1, X 2, and X 1 are coordinate values of the xyz coordinate system of FIG. 3, and are coordinate values on the irradiation line W of the laser irradiated to the steel plate surface by the rotated optical system.
- the tilt calculator 47 can calculate the tilt angle of the laser beam on the steel sheet according to the optical system rotation angle, that is, the tilt to be reflected on the steel sheet support roll.
- the roll control unit 48 pre-stores the following equation (4) which calculates the amount of stretch drive of each lifting cylinders 43 and 44 disposed at both ends of the steel plate supporting roll 9 therein.
- the roll control unit 48 controls the respective lifting cylinders according to the stretching driving amounts of the lifting cylinders 43 and 44 obtained through the following equation (4) to bring the steel plate supporting roll 9 to the required inclination B.
- Equation (4)- ⁇ Z left M ⁇ tanB
- ⁇ Z right -N ⁇ tanB
- ⁇ Z left represents the amount of expansion and contraction for the lifting cylinder 43 on the left side in FIG. 4
- ⁇ Z right represents the amount of expansion and driving of the lifting cylinder 44 on the right side.
- B is the inclination value of the steel plate support roll 9.
- Negative (-) in the -N means a value in which the amount of expansion and contraction is reduced by the contraction of the lifting cylinder is not elongation, not the elongation.
- M is the inclination axis line K when the steel plate support roll 9 is inclined by the horizontal axis H when the steel plate support roll 9 is arrange
- the roll control unit 48 determines the amount of expansion and contraction of the lifting cylinders 43 and 44 in accordance with the inclination B of the steel plate supporting rolls. do.
- the lifting cylinders 43 and 44 are driven in accordance with the control signal of the roll control unit 48 to adjust the steel sheet support roll to the set inclination B.
- the slope B of the steel sheet support roll is calculated so that the left side goes up and the right side goes down.
- the cylinder 44 is retracted and the lifting cylinder 43 on the left side is driven to extend.
- the steel sheet support roll 9 is inclined at the set inclination B so that the axial direction is placed along the inclination axis line K.
- FIG. 4 Therefore, in FIG. 4, the position of the steel sheet 1 passing through the right side of the steel plate supporting roll 9 around the point G becomes low, and the position of the steel sheet passing through the left side becomes high.
- the distance between the optical system 15 and the steel sheet 1 becomes longer.
- the distance between the optical system and the steel sheet becomes shorter.
- the distance between the optical system and the steel sheet is adjusted by the inclination B of the steel sheet support roll, thereby compensating for the change in distance between the steel sheet and the optical system due to the rotation of the optical system.
- the distance between the optical system 15 and the steel sheet 1 is shortened on the right side of the steel sheet as the optical system 15 rotates, but by giving the tilt B to the steel sheet support roll 9, As shown in FIG. 4, the position of the steel sheet is lowered on the right side of the steel sheet, thereby compensating for the reduction of the distance between the steel sheet and the optical system in FIG. 3. Therefore, the focal length of the laser beam irradiated from the optical system to the steel sheet surface is kept constant along the irradiation line. Thus, despite the rotation of the optical system it is possible to form the irradiation line while minimizing the fluctuation in the width direction groove depth on the surface of the steel sheet.
- the laser irradiation equipment may further include molten iron removal equipment for removing the fumes and spatter generated by the laser beam irradiation on the steel sheet.
- the molten iron removal equipment sprays compressed dry air into the grooves of the steel sheet to remove an air knife (17) for removing molten iron remaining in the grooves, and dust collecting hoods (19A, 19B) for sucking and removing fumes and molten iron. It may include.
- the fume generated during laser irradiation through the air knife and the dust collecting hood is removed to prevent the fume from flowing into the optical system.
- the air knife 17 removes molten iron remaining in the grooves by spraying compressed dry air having a predetermined size of pressure Pa into the grooves of the steel plate 1.
- the compressed dry air preferably has a pressure Pa of 0.2 kg / cm 2 or more.
- the laser irradiation equipment may further include a shielding portion 18 for blocking the reflection of the laser beam, scattered light and radiant heat from entering the optical system.
- the shield 18 blocks the reflected light and the scattered light flowing into the optical system by the reflection and scattering of the laser beam 16 irradiated onto the steel sheet, thereby preventing the optical system from being heated and thermally deformed by the radiant heat caused by the reflected light and the scattered light. do.
- the laser room 20 is a room structure having an internal space, and accommodates the laser irradiation facility and the steel sheet support roll 9 position control device therein, and separates it from the outside, and provides an appropriate operating environment for smooth driving thereof. do.
- Inlets and outlets are formed at the entrance and exit sides of the laser room 20 along the steel plate traveling direction, respectively.
- the laser room 20 is provided with a facility for blocking the inflow of pollutants so that the internal space is not contaminated by external dust or the like.
- the laser room 20 is provided with a positive pressure device 23 for increasing the internal pressure than the outside.
- the positive pressure device 23 maintains the pressure inside the laser room 20 relatively higher than the external pressure. As a result, it is possible to prevent foreign substances from flowing into the laser room 20.
- air curtains 22A, 22B, 22C, and 22D are installed at the inlet and the outlet through which the steel sheet enters and exits.
- the air curtain forms a film by injecting air into the inlet and the outlet, which are the passages through which the steel sheet enters and exits the laser room 20, thereby preventing dust and the like from flowing through the inlet and the outlet.
- a shower booth 21 may be installed at a door that is an entrance and exit of the laser room 20. The shower booth 21 removes foreign substances from the body of the person coming into the laser room 20.
- the laser room 20 is a space where the process of refining the steel sheet domain by the laser beam is substantially performed, and it is necessary to minimize the change of the internal environment and maintain a proper environment.
- the laser room 20 is an optical system lower frame 24 that separates the upper space in which the laser oscillator 14 and the optical system 15, etc. of the laser irradiation equipment and the lower space through which the steel sheet 1 passes, and the laser Room 20 is provided with a constant temperature and humidity controller 25 for controlling the temperature and humidity inside.
- the optical system lower frame 24 allows for more thorough management of the main equipment operating environment such as the laser oscillator 14 and the optical system 15.
- the optical system lower frame 24 is installed to separate the optical system lower space through which the steel sheet passes in the laser room 20 and the optical system upper space in which the laser oscillator and the optical mirrors are located.
- the upper space of the optical system is separately separated inside the laser room 20 by the optical system lower frame 24, so that pollution prevention and temperature and humidity control for main equipment such as a laser oscillator or an optical system can be more easily performed.
- the constant temperature and humidity controller 25 controls the temperature and humidity inside the laser room 20 to provide an appropriate environment.
- the constant temperature and humidity controller 25 may maintain the internal temperature of the laser room 20 at 20 to 25 ° C., and the humidity at 50% or less.
- the internal space of the laser room 20 is continuously maintained at a temperature and humidity suitable for the working environment, so that the magnetic domain refinement process may be performed on the steel sheet in an optimal state.
- the magnetic domain refinement process may be performed on the steel sheet in an optimal state.
- the magnetic domain refiner of the present embodiment may further include a post-treatment facility for removing heel up and spatter formed on the surface of the steel sheet.
- the aftertreatment facility may include brush rolls 26A and 26B disposed at the rear end of the laser room 20 along the moving direction of the steel sheet to remove heel-up and spatter on the surface of the steel sheet.
- the brush rolls 26A and 26B are rotated at a high speed by the drive motor, and the current control system controls the current value of the drive motor generated during operation to the set target value, and the brush position is controlled by adjusting the distance between the brush roll and the steel sheet.
- the distance between the rotational speed and the steel sheet is controlled by the control system.
- the brush roll may be disposed on only one surface of the steel sheet in which the groove is formed by the laser beam, or may be disposed on both sides of the steel sheet.
- the brush rolls 26A and 26B are in close contact with the surface of the steel sheet and rotate at high speed to remove heel up, spatter, etc. attached to the surface of the steel sheet.
- a dust collection hood 19C for discharging the heel up and the spatter removed by the brush roll in close proximity to the brush rolls 26A and 26B is further provided.
- the dust collecting hood 19C sucks molten iron such as heel up and spatter separated from the steel sheet by brush rolls 26A and 26B and discharges them to the outside.
- connection unit may further include a filtering unit 30 for filtering foreign substances contained in the alkaline solution of the cleaning unit from the alkaline solution.
- the steel sheet is first removed through the brush roll (26A, 26B) and the heel up and spatter is removed, and the remaining heel up and spatter is removed secondly through the cleaning unit (29).
- the heel up and spatter attached to the surface of the steel sheet can be more completely removed to improve product quality.
- the cleaning unit 29 is filled with an alkaline solution therein, the filtering unit 30 is connected to one side.
- the heel up and spatter which are removed from the steel sheet is accumulated in the internal alkaline solution, thereby degrading the clean performance of the steel sheet.
- the filtering unit 30 removes the heel and spatter contained in the alkaline solution while circulating the alkaline solution of the clean unit.
- the filtering unit 30 controls the iron content of the alkaline solution to 500 ppm or less by removing the heel up and the spatter. In this way, it is possible to prevent the degradation of the cleaning performance of the cleaning unit and to process the steel sheet continuously.
- the steel sheet continuously transferred enters the laser room through the meandering control device and the tension control device and proceeds at a speed of 2 m / sec or more, and is finely processed.
- the steel sheet entering the laser room is drawn out of the laser room after the permanent magnetization is processed through the laser irradiation equipment.
- the steel sheet drawn out of the laser room is passed through a post-treatment facility to remove heel ups and spatters remaining on the surface.
- the laser room where the laser irradiation on the surface of the steel sheet proceeds to properly set and maintain an internal operating environment so as to provide an optimal environment for miniaturization of magnetic domains.
- the laser room isolates the inside from the outside to block the inflow of external contaminants, and controls the laser room internal temperature, pressure, and humidity according to an operating environment for forming magnetic domains.
- the laser room is set to maintain the internal pressure higher than the outside, thereby preventing foreign matters such as dust from entering the laser room.
- the laser room is set to maintain the internal pressure higher than the outside, thereby preventing foreign matters such as dust from entering the laser room.
- the constant temperature and humidity controller installed in the laser room maintains the temperature inside the laser room at 20 to 25 ° C and maintains the humidity at 50% or less, thereby providing optimum conditions for the magnetic domain refinement treatment by laser irradiation.
- the laser room provides an optimal environment for the laser beam irradiation, and the steel sheet is precisely positioned at the laser irradiation position while passing through the meandering control device, the tension control device, and the steel plate support roll position adjusting device.
- the steel sheet is moved for straightening of the steel sheet through the meandering control equipment without any bias from side to side along the center of the production line.
- the meander measuring sensor continuously detects the meandering amount of the steel sheet, and when the steel sheet meanders, it calculates the signal detected by the meander measuring sensor so that the steel sheet central position control system rotates and moves the axis of the steering roll to move the steel sheet to the correct position. do. By continuously controlling the steering roll according to the position of the steel sheet, the steel sheet can be continuously moved without leaving the center of the production line.
- the steel sheet is moved past the steering roll and the tension bridle roll for tension adjustment.
- the tension of the steel sheet past the tension bridal roll is detected by the tension measuring sensor.
- the steel plate tension control system calculates the measured value detected by the tension measuring sensor to control the speed of the tension bridal roll in addition to the set tension. Thus, it is possible to continuously maintain the tension of the steel sheet being moved in accordance with the set range.
- the steel sheet passed through the tension bridal roll is introduced into the laser room through the entrance of the laser room.
- the steel sheet is shifted by the bridle roll in the laser room and moved in close contact with the steel plate supporting roll positioned between the two bridal rolls.
- the steel sheet supporting roll moves the steel sheet up and down to position the steel sheet within the depth of focus of the laser beam.
- the luminance sensor detects the flame brightness of the surface of the steel sheet in real time, and the steel sheet supporting roll position control system moves the steel sheet supporting roll up and down according to the measured value detected by the luminance measuring sensor.
- the steel sheet is positioned within the depth of focus of the laser beam.
- the laser oscillator controller turns on / off the laser oscillator according to the degree of meandering of the steel sheet.
- the laser oscillator controller is connected to the meander measuring sensor, and when the meandering amount of the steel sheet measured from the meander measuring sensor becomes 15 mm or more, for example, the laser oscillator is turned off by determining that the steel sheet is deviated from the steel sheet supporting roll too much.
- the laser beam is irradiated to the surface of the steel sheet support roll past the meandered steel sheet to prevent the roll from being damaged.
- the laser beam generated by the laser oscillator is irradiated onto the surface of the steel sheet through the optical system.
- the laser oscillator oscillates and transmits the TEM 00 continuous wave laser beam to the optical system.
- the optical system switches the direction of the laser beam and irradiates a laser onto the surface of the steel sheet, thereby forming molten grooves continuously on the surface of the steel sheet to perform magnetic domain refinement.
- a molten groove is formed along the irradiation line.
- the laser oscillator and the optical system transmit the laser energy density within the range of 1.0 to 5.0 J / mm 2 necessary for melting the steel sheet to the steel sheet so that the remaining resolidification portion is produced.
- the laser beam reflected back from the steel sheet is not incident to the optical system. Therefore, it is possible to prevent the back reflection phenomenon and maintain the quality of the groove shape formed by the laser beam because the incident light path of the laser beam is not interrupted by the reflected light.
- the optical system has a function of controlling the laser scanning speed so that the interval of the laser irradiation line can be adjusted with respect to the rolling direction.
- the optical system has a rotation function to change the angle of the laser irradiation line.
- the distance of the laser irradiation line to 2 to 30mm in the rolling direction by the optical system, the iron loss of the steel sheet can be improved by minimizing the influence of the heat affected zone (HAZ) by the laser beam. have.
- HZ heat affected zone
- the optical system may convert the irradiation angle of the laser beam into a range of ⁇ 4 ° with respect to the width direction of the steel sheet. That is, in FIG. 2, the radiation line 31 of the laser beam may be formed by tilting in a range of ⁇ 4 ° with respect to the y-axis direction. Accordingly, the irradiation line formed on the surface of the steel sheet may be inclined in the range of 86 to 94 ° with respect to the rolling direction. Thus, by forming the irradiation line inclined with respect to the y-axis direction, it is possible to minimize the decrease in magnetic flux density due to the groove formation by the laser.
- the tilt of the steel sheet support roll supporting the steel sheet is changed.
- the focal length of the beam can be kept constant.
- the slope of the steel sheet support roll is calculated in accordance with the laser beam focal length change of the steel sheet surface according to the rotation of the optical system, and the lifting is provided at both ends of the steel sheet support roll in accordance with the obtained tilt of the steel sheet support roll.
- the cylinders are moved up and down, respectively, to change the inclination of the steel sheet support roll.
- the laser beam focal length change according to the rotation of the optical system is compensated by the inclination of the steel sheet support roll so that the distance between the optical system and the steel sheet is kept constant. Therefore, the focal length of the laser beam irradiated from the optical system to the surface of the steel sheet is kept constant along the irradiation line to form the irradiation line while minimizing the widthwise groove depth variation on the surface of the steel sheet.
- FIG. 5 is a graph showing the groove depth of the irradiation line formed in the steel sheet along the width direction of the steel sheet according to the present embodiment compared with the prior art.
- the comparative example shows the groove depth for the structure irradiated with the laser beam without changing the inclination of the steel plate support roll as in the prior art, and the embodiment converts the inclination of the steel plate support roll when the optical system is rotated according to the present invention.
- the groove depth for the structure is shown.
- the groove depth is not uniform in the groove depth in the steel sheet width direction.
- the groove depth is formed uniformly along the width direction of the steel sheet.
- the focal length of the laser beam irradiated onto the surface of the steel sheet is kept constant along the irradiation line, thereby minimizing the widthwise groove depth variation on the surface of the steel sheet.
- the magnetic domain micronization process is performed, and the magnetic domain micronized steel plate is continuously moved and discharged to the outside through the exit of the laser room.
- the steel sheet discharged from the laser room is subjected to a post-treatment process to remove the heel up and spatter attached to the surface of the steel sheet.
- the steel sheet first passes through the brush roll disposed outside the laser room, and the heel up and the spatter are firstly removed by the brush roll that is in close contact with the steel sheet and rotates at high speed.
- the steel rolls which have undergone brush rolls, are secondarily passed through a clean unit, and the remaining heel-ups and spatters are finally removed through the electrolysis reaction between the steel sheets and the alkaline solution.
- the steel plate from which the heel up and the spatter are removed while passing through the clean unit is transferred to the post process.
- Table 1 shows the iron loss improvement rate of the grain-oriented electrical steel sheet by the groove formed on the steel sheet surface of 0.27mm thickness by continuous wave laser beam irradiation according to the present embodiment. As shown in Table 1, in the case of the magnetic domain micronized steel sheet through the present embodiment it can be seen that the iron loss is improved both after the laser irradiation and after the magnetic domain micronized and heat treated with a laser.
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Abstract
Description
철손개선율(%) | |
레이저 조사후 | 열처리후 |
9.5 | 11.6 |
9.7 | 12.9 |
11.5 | 13.5 |
8.4 | 11.6 |
8.6 | 11.8 |
8.5 | 11.7 |
Claims (23)
- 생산라인을 따라 진행하는 강판을 지지하면서 상기 강판의 상하 방향 위치를 제어하는 강판지지롤 위치 조절단계, 강판 표면에 레이저빔을 조사하여 상기 강판을 용융시켜 강판의 표면에 홈을 형성하는 레이저 조사 단계를 포함하고,상기 레이저 조사단계는 강판에 레이저 빔을 조사하는 광학계가 강판에 대해 회전하여 강판의 폭방향에 대해 레이저빔의 조사선 각도를 변환하는 각도 변환 단계, 및 상기 강판의 폭 방향을 따라 레이저 빔의 초점거리 변화에 맞춰 강판을 지지하는 강판지지롤의 기울기를 변화하는 초점거리 유지 단계를 포함하는 방향성 전기강판의 자구미세화 방법.
- 제 1 항에 있어서,상기 각도 변환 단계는, 강판의 폭방향에 대해 레이저 빔의 조사선 각도를 ±4°의 범위로 변환하는 방향성 전기강판의 자구미세화 방법.
- 제 1 항에 있어서,상기 레이저 조사단계는, 강판지지롤 표면에 원호형태로 접하여 진행되는 강판의 표면에 대해, 레이저 빔의 조사방향이 강판지지롤의 중심축을 지날 때의 레이저 빔 조사 위치를 기준점으로 하여 상기 기준점에서 강판지지롤 중심에서 외주면을 따라 각도를 두고 이격된 위치에, 레이저 빔을 조사하는 방향성 전기강판의 자구미세화 방법.
- 제 3 항에 있어서,상기 레이저 조사단계에서, 레이저 빔은 상기 기준점에 대해 강판지지롤 중심에서 외주면을 따라 3 내지 7°이격된 범위에서 조사되는 방향성 전기강판의 자구미세화 방법.
- 제 1 항 내지 제 4 항 중 어느 한 항에 있어서,상기 초점 거리 유지 단계는, 광학계 회전에 따른 강판 표면의 레이저 빔 초점거리 변화에 맞춰 상기 강판지지롤의 기울기를 연산하는 기울기 각도 계산 단계, 및 기울기 각도 계산 단계에서 구해진 값에 따라 강판지지롤의 양 선단부를 각각 상하로 이동시켜 강판지지롤의 기울기를 변화시키는 기울기 조절 단계를 포함하는 방향성 전기강판의 자구미세화 방법.
- 제 5 항에 있어서,상기 기울기 각도 계산 단계는 레이저 빔 조사선의 각도 부여에 따라 광학계의 회전 각도를 연산하는 광학계 각도 연산 단계, 상기 광학계 각도 연산 단계에 의해 구해진 광학계의 회전 각도에 맞춰 강판지지롤의 기울기 각도를 구하는 기울기 연산 단계, 및 기울기 연산 단계에서 구해진 기울기 값에 따라 강판지지롤 양 선단부에 배치된 각 승강실린더의 신축 구동량을 연산하고 각 승강실린더에 출력신호를 인가하는 롤 제어 단계를 포함하는 방향성 전기강판의 자구미세화 방법.
- 제 6 항에 있어서,상기 광학계 각도 연산 단계는 레이저 빔의 조사 간격과 강판 이동 속도로부터 조사선의 각도에 맞춰 회전되는 광학계의 회전 각도를 연산하는 구조의 방향성 전기강판의 자구미세화 방법.
- 제 6 항에 있어서,레이저 조사가 진행되는 레이저룸의 내부 동작 환경을 설정하고 유지하는 설정유지단계를 더 포함하고,상기 설정유지단계는, 레이저룸 내부를 외부와 격리시켜 외부 오염물질의 유입을 차단하는 단계와, 레이저룸 내부 온도와 압력 및 습도를 제어하는 단계를 포함하는 방향성 전기강판의 자구미세화 방법.
- 제 6 항에 있어서,상기 강판을 평평하게 펼쳐진 상태로 유지되게 상기 강판에 장력을 부여하는 장력 제어단계를 더 포함하는 방향성 전기강판의 자구미세화 방법.
- 제 6 항에 있어서,상기 강판이 생산라인 중앙을 따라 좌우로 치우침이 없이 이동하게 하는 사행 제어단계를 더 포함하는 방향성 전기강판의 자구미세화 방법.
- 제 6 항에 있어서,상기 레이저 조사단계를 거쳐 상기 강판의 표면에 형성된 힐업(hill up)과 스패터(spatter)를 제거하기 위한 후처리 단계를 더 포함하는 방향성 전기강판의 자구미세화 방법.
- 생산라인을 따라 이동되는 강판을 지지하면서 강판의 상하 방향 위치를 제어하는 강판지지롤 위치 조절설비, 및 레이저 빔을 조사하여 강판을 용융시켜 상기 강판의 표면에 홈을 형성하는 레이저 조사설비를 포함하고,상기 레이저 조사설비는 강판에 레이저 빔을 조사하는 광학계가 구동부에 의해 회전 가능한 구조로 이루어져, 상기 광학계가 강판에 대해 회전하여 강판의 폭방향에 대해 레이저빔의 조사선 각도를 변환하는 구조이고,상기 강판의 폭 방향을 따라 레이저 빔의 초점거리 변화에 맞춰 강판을 지지하는 강판지지롤의 기울기를 변화하는 초점거리 유지부를 더 포함하는 방향성 전기강판의 자구미세화 장치.
- 제 12 항에 있어서,상기 레이저 조사설비는 강판지지롤 표면에 원호형태로 접하여 진행되는 강판의 표면에 대해, 레이저 빔의 조사방향이 강판지지롤의 중심축을 지날 때의 레이저 빔 조사 위치를 기준점으로 하여, 상기 기준점에서 강판지지롤 중심에서 외주면을 따라 각도를 두고 이격된 위치에 레이저 빔이 조사하는 구조의 방향성 전기강판의 자구미세화 장치.
- 제 13 항에 있어서,상기 레이저 조사설비는 레이저 빔을 상기 기준점에 대해 강판지지롤 중심에서 외주면을 따라 3 내지 7°이격된 범위에 조사하는 구조의 방향성 전기강판의 자구미세화 장치.
- 제 12 항에 있어서,상기 강판지지롤 위치 조절설비와 레이저조사설비를 외부로부터 격리 수용하며 레이저 조사를 위한 동작 환경을 제공하는 레이저룸을 더 포함하는 방향성 전기강판의 자구미세화 장치.
- 제 15 항에 있어서,상기 레이저룸은 상기 레이저 조사설비와 강판지지롤 위치 제어설비를 수용하여 외부와 격리시키도록 내부 공간을 형성하고, 강판의 진행방향을 따라 양 측면에는 입구와 출구가 형성되며, 내부에는 레이저룸 내부 압력을 외부보다 높이기 위한 양압장치, 레이저 조사설비의 광학계가 위치한 상부공간을 강판이 지나가는 하부공간과 분리시키는 광학계 하부프레임, 및 레이저룸 내부 온도와 습도를 제어하는 항온항습제어기를 포함하는 방향성 전기강판의 자구미세화 장치.
- 제 12 항 내지 제 16 항 중 어느 한 항에 있어서,상기 초점 거리 유지부는 광학계 회전에 따른 강판 표면의 레이저 빔 초점거리 변화에 맞춰 상기 강판지지롤의 기울기를 연산하고 강판지지롤의 기울기를 제어하는 제어부, 및 상기 강판지지롤의 양 선단부에 각각 설치되고 상기 제어부의 신호에 따라 구동되어 강판지지롤의 양 선단부를 상하로 승하강시켜 기울기를 변화시키는 승강실린더를 포함하는 방향성 전기강판의 자구미세화 장치.
- 제 17 항에 있어서,상기 제어부는 레이저 빔 조사선의 각도 부여에 따라 광학계의 회전 각도를 연산하는 광학계 각도 연산부, 상기 광학계 각도 연산부에 의해 구해진 광학계의 회전 각도에 맞춰 강판지지롤의 기울기 각도를 구하는 기울기 연산부, 및 기울기 연산부에서 구해진 기울기 값에 따라 강판지지롤 양 선단부에 배치된 각 승강실린더의 신축 구동량을 연산하고 각 승강실린더에 출력신호를 인가하는 롤 제어부를 포함하는 방향성 전기강판의 자구미세화 장치.
- 제 18 항에 있어서,상기 제어부는 레이저 빔 조사 간격과 강판 이동 속도 및 조사선의 각도를 입력하는 입력부를 더 포함하는 방향성 전기강판의 자구미세화 장치.
- 제 18 항에 있어서,상기 광학계 각도 연산부는 레이저 빔의 조사 간격과 강판 이동 속도로부터 조사선의 각도에 맞춰 회전되는 광학계의 회전 각도를 연산하는 구조의 방향성 전기강판의 자구미세화 장치.
- 제 17 항에 있어서,상기 강판을 평평하게 펼쳐진 상태로 유지되게 강판에 장력을 부여하는 장력 제어설비를 더 포함하는 방향성 전기강판의 자구미세화 장치.
- 제 17 항에 있어서,상기 강판이 생산라인 중앙을 따라 좌우로 치우침이 없이 이동하게 하는 사행 제어설비를 더 포함하는 방향성 전기강판의 자구미세화 장치.
- 제 17 항에 있어서,상기 강판의 표면에 형성된 힐업(hill up)과 스패터(spatter)를 제거하기 위한 후처리 설비를 더 포함하는 방향성 전기강판의 자구미세화 장치.
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CN201680079808.0A CN108495940B (zh) | 2016-01-22 | 2016-12-23 | 取向电工钢板的磁畴细化方法及其装置 |
US16/072,171 US11000920B2 (en) | 2016-01-22 | 2016-12-23 | Method and device for magnetic domain refinement of oriented electrical steel plate |
EP16886653.1A EP3406740B1 (en) | 2016-01-22 | 2016-12-23 | Method and device for magnetic domain refinement of orientated electrical steel plate |
PL16886653T PL3406740T3 (pl) | 2016-01-22 | 2016-12-23 | Sposób i urządzenie do udoskonalenia domeny magnetycznej zorientowanej elektrotechnicznej blachy stalowej |
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CN110177891B (zh) | 2016-12-23 | 2021-05-14 | Posco公司 | 取向电工钢板的磁畴细化方法及其装置 |
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EP3406740B1 (en) | 2020-06-03 |
JP2019512047A (ja) | 2019-05-09 |
PL3406740T3 (pl) | 2020-11-16 |
EP3406740A4 (en) | 2018-11-28 |
EP3406740A1 (en) | 2018-11-28 |
KR20170088246A (ko) | 2017-08-01 |
CN108495940A (zh) | 2018-09-04 |
US20190070693A1 (en) | 2019-03-07 |
JP6826604B2 (ja) | 2021-02-03 |
CN108495940B (zh) | 2019-12-03 |
KR102148383B1 (ko) | 2020-08-26 |
US11000920B2 (en) | 2021-05-11 |
WO2017126810A8 (ko) | 2017-09-21 |
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