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WO2016115674A1 - Cosmetic composition for the oxidation dyeing of keratin fibres comprising a cationic polymer and a particular combination of surfactants - Google Patents

Cosmetic composition for the oxidation dyeing of keratin fibres comprising a cationic polymer and a particular combination of surfactants Download PDF

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Publication number
WO2016115674A1
WO2016115674A1 PCT/CN2015/071080 CN2015071080W WO2016115674A1 WO 2016115674 A1 WO2016115674 A1 WO 2016115674A1 CN 2015071080 W CN2015071080 W CN 2015071080W WO 2016115674 A1 WO2016115674 A1 WO 2016115674A1
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WIPO (PCT)
Prior art keywords
composition
weight
chosen
group
composition according
Prior art date
Application number
PCT/CN2015/071080
Other languages
French (fr)
Inventor
Xuekun LV
Gautier Deconinck
Original Assignee
L'oreal
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Filing date
Publication date
Application filed by L'oreal filed Critical L'oreal
Priority to MX2017009500A priority Critical patent/MX2017009500A/en
Priority to PCT/CN2015/071080 priority patent/WO2016115674A1/en
Priority to CN201580078087.7A priority patent/CN107427426A/en
Priority to BR112017015526-5A priority patent/BR112017015526B1/en
Publication of WO2016115674A1 publication Critical patent/WO2016115674A1/en

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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/10—Preparations for permanently dyeing the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/42—Amides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/731—Cellulose; Quaternized cellulose derivatives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/54—Polymers characterized by specific structures/properties
    • A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
    • A61K2800/5426—Polymers characterized by specific structures/properties characterized by the charge cationic
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
    • A61K2800/88—Two- or multipart kits
    • A61K2800/882—Mixing prior to application
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
    • A61K2800/88—Two- or multipart kits
    • A61K2800/884—Sequential application

Definitions

  • the present invention relates to a cosmetic composition for the oxidation dyeing of keratin fibres, in particular human keratin fibres such as the hair.
  • a subject of the present invention is a dyeing cosmetic composition
  • a dyeing cosmetic composition comprising one or more oxidation dyes, one or more cationic polymers and a particular combination of surfactants.
  • the present invention also relates to a process for dyeing keratin fibres, in particular human keratin fibres such as the hair, using the composition according to the invention.
  • the present invention relates to a kit for the oxidation dyeing of keratin fibres, which is suitable for performing the process of the invention.
  • oxidation dyeing methods also known as oxidation dyeing, which use dye compositions containing oxidation dye precursors, generally referred to as oxidation bases, such as ortho-or para-phenylenediamines, ortho-or para-aminophenols and heterocyclic compounds, have been developed for dyeing human keratin fibres in a long-lasting manner.
  • oxidation bases are colourless or weakly coloured compounds, which, when combined with oxidizing products, may give rise to coloured compounds via a process of oxidative condensation.
  • couplers or coloration modifiers the latter being chosen especially from aromatic meta-diaminobenzenes, meta-aminophenols, meta-diphenols and certain heterocyclic compounds such as indole compounds.
  • compositions known in the prior art mention may be made of WO 2011/138838 which discloses a ready-to-use composition for the oxidation dyeing of keratin fibers comprising, in an aqueous medium at least one oxidation dye, at least one oxidizing agent, and at least 1.5% by weight of at least one amphoteric surfactant.
  • the prior art compositions are not entirely satisfactory, and their performance qualities can be further improved, in particular as regards the working qualities (whether or not the composition is mixed with an oxidizing composition before application) , especially in terms of texture, ease of application and ease of spreading of the composition on the keratin fibres.
  • the compositions of the prior art are not always sufficiently stable, and their coloring performances can also be further improved, especially in terms of intensity, homogeneity and selectivity of the dyeing obtained.
  • One subject of the present invention is thus a cosmetic composition for the oxidation dyeing of keratin fibres comprising:
  • non ionic surfactant chosen from alkanolamides of C 6 -C 30 fatty acids
  • composition according to the invention has very good working qualities, and especially a particularly pleasant texture and a good viscosity (neither too thick, nor too fluid which facilitates its use) .
  • This property is very stable over the time, and does not diminish even after several months of storage at ambient temperature (25°C) as well as from low temperatures (such as 4°C) until high temperatures (such as 45°C) .
  • the composition further exhibits excellent foaming properties similar to those of a shampoo, whenever or not is mixed with a developer composition (or oxidizer) , and it is very easy to apply and to spread on the locks of hair, in particular from the roots to the ends. More particularly, the composition of the present invention allows an easy an rapid formation of foam, such as immediately after massaging the hair. The foam is firm and creamy and allows a good dyeing performance. Moreover, the foam stays on the hair without flying away.
  • composition of the invention does not require premixing with a developer composition or oxidizing composition or oxidizer. It allows to be used simultaneously with a developer or oxidizer directly on the hair, without a step of premixing.
  • composition of the invention has very good cosmetic properties, and provides the keratin fibres with an excellent conditioning.
  • the hair is shiny, smooth, supple and easy to disentangle.
  • composition according to the invention has superior dyeing quality, especially in terms of intensity, homogeneity and selectivity of the dyeing obtained.
  • composition of the invention is intended to be used in a process for dyeing keratin fibres either as a ready-to-use composition when it contains an oxidizing agent, or in combination with an oxidizing composition.
  • a subj ect of the invention is thus also a process for dyeing keratin fibres, which consists in applying to the keratin fibres the composition of the invention. Said composition may be applied sequentially to or simultaneously with an oxidizing composition comprising one or more oxidizing agents.
  • oxyalkylenated covers, respectively, mono-or poly-oxyalkylenated, oxyethylenated, oxypropylenated and glycerolated compounds, unless specifically mentioned.
  • the composition of the invention is advantageously transparent.
  • the transparency of the composition may be characterized by measuring its turbidity according to the NTU method using a 2100P model turbidimeter from the company Hach, at room temperature.
  • the turbidity of the compositions of the invention is generally less than 400 NTU units and preferably less than 250 NTU units, more preferably less than 200 NTU.
  • composition according to the invention comprises one or more oxidation dyes.
  • oxidation dyes that may be used in the present invention are generally chosen from oxidation bases, optionally combined with one or more couplers.
  • the oxidation dye (s) comprise one or more oxidation bases.
  • the oxidation bases may be chosen especially from para-phenylenediamines, bis (phenyl) alkylenediamines, para-aminophenols, ortho-aminophenols, heterocyclic bases, and the addition salts thereof, and mixtures thereof.
  • para-phenylenediamines examples that may be mentioned include para-phenylenediamine, para-tolylenediamine, 2-chloro-para-phenylenediamine, 2, 3-dimethyl-para-phenylenediamine, 2,6-dimethyl-para-phenylenediamine, 2, 6-diethyl-para-phenylenediamine, 2, 5-dimethyl-para-phenylenediamine, N, N- dimethyl-para-phenylenediamine, N, N-diethyl-para-phenylenediamine, N,N-dipropyl-para-phenylenediamine, 4-amino-N, N-diethyl-3-methylaniline, N, N-bis ( ⁇ -hydroxyethyl) -para-phenylenediamine, 4-N,N-bis ( ⁇ -hydroxyethyl) amino-2-methylaniline, 4-N, N–bis ( ⁇ -hydroxyethyl) amino-2-chloroaniline
  • para-phenylenediamine para-tolylenediamine, 2-isopropyl-para-phenylenediamine, 2- ⁇ -hydroxyethyl-para-phenylenediamine, 2- ⁇ -hydroxyethyloxy-para-phenylenediamine, 2, 6-dimethyl-para-phenylenediamine, 2, 6-diethyl-para-phenylenediamine, 2, 3-dimethyl-para-phenylenediamine, N, N-bis ( ⁇ -hydroxyethyl) -para-phenylenediamine, 2-chloro-para-phenylenediamine and 2- ⁇ -acetylaminoethyloxy-para-phenylenediamine, and the addition salts thereof with an acid, are particularly preferred.
  • the bis (phenyl) alkylenediamines examples include N, N'-bis ( ⁇ -hydroxyethyl) -N, N'-bis (4'-aminophenyl) -1, 3-diaminopropanol, N, N'-bis ( ⁇ -hydroxyethyl) -N, N'-bis(4'-aminophenyl) ethylenediamine, N, N'-bis (4-aminophenyl) tetramethylenediamine, N, N'-bis ( ⁇ -hydroxyethyl) -N, N'-bis (4-aminophenyl) tetramethylenediamine, N, N'-bis (4-methylaminophenyl) tetramethylenediamine, N, N'-bis (ethyl) -N, N'- bis (4'-amino-3'-methylphenyl) ethylenediamine, 1, 8-bis (2, 5-diaminophenoxy)
  • para-aminophenols examples that may be mentioned include para-aminophenol, 4-amino-3-methylphenol, 4-amino-3-fluorophenol, 4-amino-3-chlorophenol, 4-amino-3-hydroxymethylphenol, 4-amino-2-methylphenol, 4-amino-2-hydroxymethylphenol, 4-amino-2-methoxymethylphenol, 4-amino-2-aminomethylphenol, 4-amino-2- ( ⁇ -hydroxyethyl-aminomethyl) phenol and 4-amino-2-fluorophenol, and the addition salts thereof with an acid.
  • ortho-aminophenols examples that may be mentioned include 2-aminophenol, 2-amino-5-methylphenol, 2-amino-6-methylphenol and 5-acetamido-2-aminophenol, and the addition salts thereof.
  • heterocyclic bases examples that may be mentioned include pyridine derivatives, pyrimidine derivatives and pyrazole derivatives.
  • pyridine derivatives that may be mentioned are the compounds described, for example, in patents GB 1 026 978 and GB 1 153 196, for instance 2, 5-diaminopyridine, 2- (4-methoxyphenyl) amino-3-aminopyridine and 3, 4-diaminopyridine, and the addition salts thereof.
  • pyridine oxidation bases that are useful in the present invention are the 3-aminopyrazolo [1, 5-a] pyridine oxidation bases or the addition salts thereof described, for example, in patent application FR 2 801 308.
  • Examples that may be mentioned include pyrazolo [1, 5-a]pyrid-3-ylamine, 2- (acetylamino) pyrazolo [1, 5-a] pyrid-3-ylamine, 2-(morpholin-4-yl) pyrazolo [1, 5-a] pyrid-3-ylamine, 3-aminopyrazolo [1, 5-a] pyridine-2-carboxylic acid, 2-methoxypyrazolo [1, 5-a] pyrid-3-ylamine, (3-aminopyrazolo [1, 5-a]pyrid-7-yl) methanol, 2- (3-aminopyrazolo [1, 5-a] pyrid-5-yl) ethanol, 2-(3-aminopyrazolo [
  • pyrimidine derivatives that may be mentioned are the compounds described, for example, in the patents DE 2359399; JP 88-169571; JP 05-63124; EP 0770375 or patent application WO 96/15765, such as 2, 4, 5, 6-tetraaminopyrimidine, 4-hydroxy-2, 5, 6-triaminopyrimidine, 2-hydroxy-4, 5, 6-triaminopyrimidine, 2, 4-dihydroxy-5, 6-diaminopyrimidine, 2, 5, 6-triaminopyrimidine and the addition salts thereof and the tautomeric forms thereof, when a tautomeric equilibrium exists.
  • pyrazole derivatives that may be mentioned are the compounds described in patents DE 3843892 and DE 4133957 and patent applications WO 94/08969, WO 94/08970, FR-A-2 733 749 and DE 195 43 988, for instance 4, 5-diamino-1-methylpyrazole, 4, 5-diamino-1- ( ⁇ -hydroxyethyl) pyrazole, 3, 4-diaminopyrazole, 4, 5-diamino-1- (4'-chlorobenzyl) pyrazole, 4, 5-diamino-1, 3-dimethylpyrazole, 4, 5-diamino-3-methyl-1-phenylpyrazole, 4, 5-diamino-1-methyl-3-phenylpyrazole, 4-amino-1, 3-dimethyl-5-hydrazinopyrazole, 1-benzyl-4, 5-diamino-3-methylpyrazole, 4, 5-diamino-3-tert-butyl-1-methyl
  • a 4, 5-diaminopyrazole will preferably be used, and even more preferentially 4, 5-diamino-1- ( ⁇ -hydroxyethyl) pyrazole and/or a salt thereof.
  • Pyrazole derivatives that may also be mentioned include diamino-N, N-dihydropyrazolopyrazolones and especially those described in patent application FR-A-2 886 136, such as the following compounds and the addition salts thereof: 2, 3-diamino-6, 7-dihydro-1H,5H-pyrazolo [1, 2-a] pyrazol-1-one, 2-amino-3-ethylamino-6, 7-dihydro-1H, 5H-pyrazolo [1, 2-a] pyrazol-1-one, 2-amino-3-isopropylamino-6, 7-dihydro-1H, 5H-pyrazolo [1, 2-a] pyrazol-1-one, 2-amino-3- (pyrrolidin-1-yl) -6, 7-dihydro-1H, 5H-pyrazolo [1, 2-a] pyrazol-1-one, 4, 5-diamino-1, 2-dimethyl-1, 2-di
  • Use will preferably be made of 2, 3-diamino-6, 7-dihydro-1H,5H-pyrazolo [1, 2-a] pyrazol-1-one and/or one of its salts.
  • Heterocyclic bases that will preferentially be used include 4, 5-diamino-1- ( ⁇ -hydroxyethyl) pyrazole and/or 2, 3-diamino-6, 7-dihydro-1H,5H-pyrazolo [1, 2-a] pyrazol-1-one and/or a salt thereof.
  • the oxidation dye (s) may also comprise one or more couplers, which may be chosen from those conventionally used for the dyeing of keratin fibres.
  • couplers mention may be made especially of meta-phenylenediamines, meta-aminophenols, meta-diphenols, naphthalene-based couplers heterocyclic couplers, and also the addition salts thereof, and mixtures thereof.
  • Examples that may be mentioned include 1, 3-dihydroxybenzene, 1,3-dihydroxy-2-methylbenzene, 4-chloro-1, 3-dihydroxybenzene, 2, 4-diamino-1- ( ⁇ -hydroxyethyloxy) benzene, 2-amino-4- ( ⁇ -hydroxyethylamino) -1-methoxybenzene, 1, 3-diaminobenzene, 1, 3-bis(2, 4-diaminophenoxy) propane, 3-ureidoaniline, 3-ureido-1-dimethylaminobenzene, sesamol, 1- ⁇ -hydroxyethylamino-3, 4-methylenedioxybenzene, ⁇ -naphthol, 2-methyl-1-naphthol, 6-hydroxyindole, 4-hydroxyindole, 4-hydroxy-N-methylindole, 2-amino-3-hydroxypyridine, 6-hydroxybenzomorpholine, 3, 5-diamino-2, 6-dimethoxypyridine, 1-N-
  • addition salts of the oxidation bases and couplers that may be used within the context of the invention are especially chosen from the addition salts with an acid such as the hydrochlorides, hydrobromides, sulfates, citrates, succinates, tartrates, lactates, tosylates, benzenesulfonates, phosphates and acetates.
  • an acid such as the hydrochlorides, hydrobromides, sulfates, citrates, succinates, tartrates, lactates, tosylates, benzenesulfonates, phosphates and acetates.
  • the oxidation base (s) may advantageously represent from 0.0001% to 10% by weight relative to the total weight of the composition, preferably from 0.005% to 5% by weight and better still from 0.1% to 5% by weight.
  • the coupler (s) may advantageously represent from 0.0001% to 10% by weight relative to the total weight of the composition, and preferably from 0.005% to 5% by weight.
  • composition of the invention further comprises one or more cationic polymer (s) .
  • cationic polymer is intended to mean any polymer comprising cationic groups and/or groups that can be ionized to cationic groups.
  • the cationic polymer is hydrophilic or amphiphilic.
  • the preferred cationic polymers are chosen from those that contain units comprising primary, secondary, tertiary and/or quaternary amine groups that may either form part of the main polymer chain or may be borne by a side substituent directly connected thereto.
  • cationic polymers mention may be made more particularly of:
  • -R 3 which may be identical or different, denote a hydrogen atom or a CH 3 group
  • -A which may be identical or different, represent a linear or branched divalent alkyl group of 1 to 6 carbon atoms, preferably 2 or 3 carbon atoms, or a hydroxyalkyl group of 1 to 4 carbon atoms;
  • R 4 , R 5 and R 6 which may be identical or different, represent an alkyl group containing from 1 to 18 carbon atoms or a benzyl group, and preferably an alkyl group containing from 1 to 6 carbon atoms;
  • R 1 and R 2 which may be identical or different, represent a hydrogen atom or an alkyl group containing from 1 to 6 carbon atoms, and preferably methyl or ethyl;
  • -X denotes an anion derived from an inorganic or organic acid, such as a methosulfate anion or a halide such as chloride or bromide.
  • the copolymers of family (1) may also contain one or more units derived from comonomers which may be chosen from the family of acrylamides, methacrylamides, diacetone acrylamides, acrylamides and methacrylamides substituted on the nitrogen with C 1- C 4 alkyls, acrylic or methacrylic acids or esters thereof, vinyllactams such as vinylpyrrolidone or vinylcaprolactam, and vinyl esters.
  • crosslinked polymers of methacryloyloxy (C 1 -C 4 )alkyl tri (C 1 -C 4 ) alkylammonium salts such as the polymers obtained by homopolymerization of dimethylaminoethyl methacrylate quaternized with methyl chloride, or by copolymerization of acrylamide with dimethylaminoethyl methacrylate quaternized with methyl chloride, the homo-or copolymerization being followed by crosslinking with an olefinically unsaturated compound, in particular methylenebisacrylamide.
  • a crosslinked acrylamide/methacryloyloxyethyltrimethylammonium chloride copolymer (20/80 by weight) in the form of a dispersion comprising 50% by weight of said copolymer in mineral oil may more particularly be used.
  • This dispersion is sold under the name SC 92 by the company Ciba.
  • a crosslinked methacryloyloxyethyltrimethylammonium chloride homopolymer comprising about 50% by weight of the homopolymer in mineral oil or in a liquid ester can also be used.
  • These dispersions are sold under the names SC 95 and SC 96 by the company Ciba.
  • Cationic polysaccharides in particular cationic celluloses and cationic galactomannan gums.
  • cationic polysaccharides mention may be made more particularly of cellulose ether derivatives comprising quaternary ammonium groups, cationic cellulose copolymers or cellulose derivatives grafted with a water-soluble quaternary ammonium monomer and cationic galactomannan gums.
  • cellulose ether derivatives comprising quaternary ammonium groups are in particular described in FR patent 1 492 597, and mention may be made of the polymers sold under the name Ucare Polymer JR (JR 400 LT, JR 125 and JR 30M) or LR (LR 400 or LR 30M) by the company Amerchol. These polymers are also defined in the CTFA dictionary as quaternary ammoniums of hydroxyethylcellulose that have reacted with an epoxide substituted with a trimethylammonium group.
  • Cationic cellulose copolymers or cellulose derivatives grafted with a water-soluble quaternary ammonium monomer are described in particular in US patent 4 131 576, and mention may be made of hydroxyalkyl celluloses, for instance hydroxymethyl-, hydroxyethyl-or hydroxypropylcelluloses grafted, in particular, with a methacryloylethyltrimethylammonium, methacrylamidopropyltrimethyl-ammonium, dimethyldiallylammonium or hydroxypropyltrialkylammonium salt, for example 2-hydroxypropyl trimethyl ammonium chloride.
  • hydroxyalkyl celluloses for instance hydroxymethyl-, hydroxyethyl-or hydroxypropylcelluloses grafted, in particular, with a methacryloylethyltrimethylammonium, methacrylamidopropyltrimethyl-ammonium, dimethyldiallylammonium or hydroxypropyltrialkylammoni
  • the commercial products corresponding to this definition are more particularly the products sold under the names Celquat L 200 and Celquat H 100 by the company National Starch, or hydroxyethyl cellulose-2-hydroxypropyl trimethyl ammonium chloride ether (INCI name: Polyquaternium-10) such as the product sold under the name Polyquta 400KC by the company KCI.
  • guar gums comprising cationic trialkylammonium groups.
  • Use is made, for example, of guar gums modified with a 2, 3-epoxypropyltrimethylammonium salt (for example, a chloride) .
  • a 2, 3-epoxypropyltrimethylammonium salt for example, a chloride
  • Such products are in particular sold under the names Jaguar C 13 S, Jaguar C 15, Jaguar C 17 and Jaguar C 162 by the company Rhodia.
  • Water-soluble polyaminoamides prepared in particular by polycondensation of an acidic compound with a polyamine; these polyaminoamides can be crosslinked by an epihalohydrin, a diepoxide, a dianhydride, an unsaturated dianhydride, a bisunsaturated derivative, a bishalohydrin, a bisazetidinium, a bishaloacyldiamine or an alkyl bishalide or alternatively by an oligomer resulting from the reaction of a bifunctional compound reactive with respect to a bishalohydrin, a bisazetidinium, a bishaloacyldiamine, an alkyl bishalide, an epihalohydrin, a diepoxide or a bisunsaturated derivative; the crosslinking agent being used in proportions ranging from 0.025 to 0.35 mol per amine group of the polyaminoamide; these polyaminoamides can be alkylated or, if they comprise one
  • Polyaminoamide derivatives resulting from the condensation of polyalkylene polyamines with polycarboxylic acids followed by alkylation with difunctional agents Mention may be made, for example, of adipic acid/dialkylaminohydroxyalkyldialkylenetriamine polymers in which the alkyl group comprises from 1 to 4 carbon atoms and preferably denotes methyl, ethyl or propyl.
  • adipic acid/dimethylaminohydroxypropyl/diethylenetriamine polymers sold under the name Cartaretine F, F4 or F8 by the company Sandoz.
  • Polymers of this type are sold in particular under the name Hercosett 57 by the company Hercules Inc. or alternatively under the name PD 170 or Delsette 101 by the company Hercules in the case of the adipic acid/epoxypropyl/diethylenetriamine copolymer.
  • Cyclopolymers of alkyldiallylamine or of dialkyldiallylammonium such as the homopolymers or copolymers comprising, as main constituent of the chain, units corresponding to formula (PI) or (PII) :
  • -R 12 denotes a hydrogen atom or a methyl group
  • R 10 and R 11 independently of each other, denote an alkyl group containing from 1 to 6 carbon atoms, a hydroxyalkyl group in which the alkyl group contains 1 to 5 carbon atoms, a C 1 -C 4 amidoalkyl group; or alternatively R 10 and R 11 may denote, together with the nitrogen atom to which they are attached, heterocyclic groups such as piperidyl or morpholinyl; R 10 and R 11 , independently of each other, preferably denote an alkyl group containing from 1 to 4 carbon atoms;
  • -Y - is an anion such as bromide, chloride, acetate, borate, citrate, tartrate, bisulfate, bisulfite, sulfate or phosphate.
  • R 13 , R 14 , R 15 and R 16 which may be identical or different, represent aliphatic, alicyclic or arylaliphatic groups comprising from 1 to 20 carbon atoms or C 1-4 hydroxyalkylaliphatic groups, or else R 13 , R 14 , R 15 and R 16 , together or separately, form, with the nitrogen atoms to which they are attached, heterocycles optionally comprising a second heteroatom other than nitrogen, or else R 13 , R 14 , R 15 and R 16 represent a linear or branched C 1 -C 6 alkyl group sub stituted by a nitrile, ester, acyl, amide or -CO-O-R 17 -D or -CO-NH-R 17 -D group, where R 17 is an alkylene and D a quaternary ammonium group;
  • -A 1 and B 1 represent divalent polymethylene groups comprising from 2 to 20 carbon atoms which may be linear or branched, and saturated or unsaturated, and which may contain, linked to or inserted in the main chain, one or more aromatic rings, or one or more oxygen or sulfur atoms or sulfoxide, sulfone, disulfide, amino, alkylamino, hydroxyl, quaternary ammonium, ureido, amide or ester groups, and
  • a 1 , R 13 and R 15 can form, with the two nitrogen atoms to which they are attached, a piperazine ring.
  • a 1 denotes a saturated or unsaturated and linear or branched alkylene or hydroxyalkylene group
  • B 1 can also denote a (CH 2 ) n -CO-D-OC- (CH 2 ) n -group in which D denotes:
  • a glycol residue of formula -O-Z-O- in which Z denotes a linear or branched hydrocarbon-based group, or a group corresponding to one of the following formulae: - (CH 2 -CH 2 -O) x -CH 2 -CH 2 -and - [CH 2 -CH(CH 3 ) -O] y -CH 2 -CH (CH 3 ) -, where x and y denote an integer from 1 to 4, representing a defined and unique degree of polymerization or any number from 1 to 4 representing an average degree of polymerization;
  • a bissecondary diamine residue such as a piperazine derivative
  • Y denotes a linear or branched hydrocarbon-based group, or else the divalent group -CH 2 -CH 2 -S-S-CH 2 -CH 2 -;
  • X - is an anion, such as chloride or bromide.
  • Mn number-average molar mass
  • R 1 , R 2 , R 3 and R 4 which may be identical or different, denote an alkyl or hydroxyalkyl group having from 1 to 4 carbon atoms approximately, n and p are integers varying from 2 to 20 approximately and X - is an anion derived from an inorganic or organic acid.
  • -R 18 , R 19 , R 20 and R 21 which may be identical or different, represent a hydrogen atom or a methyl, ethyl, propyl, ⁇ -hydroxyethyl, ⁇ -hydroxypropyl or -CH 2 CH 2 (OCH 2 CH 2 ) p OH group, where p is equal to 0 or to an integer of between 1 and 6, with the proviso that R 18 , R 19 , R 20 and R 21 do not simultaneously represent a hydrogen atom,
  • -r and s which may be identical or different, are integers between 1 and 6,
  • -q is equal to 0 or to an integer between 1 and 34
  • -A denotes a radical of a dihalide or preferably represents -CH 2 -CH 2 -O-CH 2 -CH 2 -.
  • Examples that may be mentioned include the products A 15, AD 1, AZ 1 and 175 sold by the company Miranol.
  • Polyamines such as H sold by Cognis, referred to under the name Polyethylene glycol (15) tallow polyamine in the CTFA dictionary.
  • these polymers may be chosen in particular from homopolymers or copolymers comprising one or more units derived from vinylamine and optionally one or more units derived from vinylformamide.
  • these cationic polymers are chosen from polymers comprising, in their structure, from 5 mol% to 100 mol% of units corresponding to formula (A) and from 0 to 95 mol% of units corresponding to formula (B) , preferentially from 10 mol% to 100 mol%of units corresponding to formula (A) and from 0 to 90 mol% of units corresponding to formula (B) .
  • These polymers may be obtained, for example, by partial hydrolysis of polyvinylformamide. This hydrolysis may be performed in an acidic or basic medium.
  • the weight-average molecular weight of said polymer measured by light scattering, may range from 1000 to 3 000 000 g/mol, preferably from 10 000 to 1 000 000 and more particularly from 100 000 to 500 000 g/mol.
  • the cationic charge density of these polymers may range from 2 to 20 meq/g, preferably from 2.5 to 15 meq/g and more particularly from 3.5 to 10 meq/g.
  • the polymers comprising units of formula (A) and optionally units of formula (B) are sold in particular under the name Lupamin by the company BASF, for instance, in a non-limiting manner, the products sold under the names Lupamin 9095, Lupamin 5095, Lupamin 1095, Lupamin 9030 (or Luviquat 9030) and Lupamin 9010.
  • cationic polymers that may be used in the context of the invention are cationic proteins or cationic protein hydrolysates, polyalkyleneimines, in particular polyethyleneimines, polymers comprising vinylpyridine or vinylpyridinium units, condensates of polyamines and of epichlorohydrin, quaternary polyureylenes and chitin derivatives.
  • the cationic polymers are chosen from those of family (2) mentioned above.
  • Particularly preferred cationic polymers for use in the compositions of the present invention are quaternized hydroxyalkylcelluloses such as quaternized hydroxyethylcelluloses.
  • Most particularly preferred polymers are those known under the INCI name of Polyquaternium-10.
  • composition of the invention preferably contains from 0.1 to 5% by weight of cationic polymer (s) , more preferably from 0.2 to 2.5%by weight, with regard to the total weight of the composition.
  • composition of the invention further comprises one or more amphoteric or zwitterionic surfactant (s) .
  • amphoteric or zwitterionic surfactant (s) which are preferably non-silicone, may especially be derivatives of aliphatic secondary or tertiary amines, optionally quaternized, in which derivatives the aliphatic group is a linear or branched chain comprising from 8 to 22 carbon atoms, the said amine derivatives containing at least one anionic group, for instance a carboxylate, sulfonate, sulfate, phosphate or phosphonate group.
  • -R a represents a C 10 -C 30 alkyl or alkenyl group derived from an acid R a COOH preferably present in hydrolysed coconut oil, or a heptyl, nonyl or undecyl group;
  • -R b represents a beta-hydroxyethyl group
  • -M + represents a cationic counterion derived from an alkali metal or alkaline-earth metal, such as sodium, an ammonium ion or an ion derived from an organic amine, and
  • -X - represents an organic or mineral anionic counterion, such as that chosen from halides, acetates, phosphates, nitrates, (C 1 -C 4 )alkyl sulfates, (C 1 -C 4 ) alkylsulfonates or (C 1 -C 4 ) alkylarylsulfonates, in particular methyl sulfate and ethyl sulfate; or alternatively M + and X - are absent;
  • -B represents the group -CH 2 CH 2 OX'
  • -X' represents the group -CH 2 COOH, -CH 2 -COOZ’ ,
  • -Z' represents a cationic counterion derived from an alkali metal or alkaline-earth metal, such as sodium, an ammonium ion or an ion derived from an organic amine;
  • -R a ’ represents a C 10 -C 30 alkyl or alkenyl group of an acid R a ’-COOH which is preferably present in coconut oil or in hydrolysed linseed oil, or an alkyl group, especially a C 17 group, and its iso form, or an unsaturated C 17 group.
  • cocoamphodiacetate sold by the company Rhodia under the trade name C2M Concentrate.
  • -Y′′ represents the group -COOH, -COOZ”
  • R -R d and R e represent, independently of each other, a C 1 -C 4 alkyl or hydroxyalkyl radical;
  • -Z′′ represents a cationic counterion derived from an alkali metal or alkaline-earth metal, such as sodium, an ammonium ion or an ion derived from an organic amine;
  • R a ′′ represents a C 10 -C 30 alkyl or alkenyl group of an acid R a ′′ -COOH which is preferably present in coconut oil or in hydrolysed linseed oil;
  • -n and n' denote, independently of each other, an integer ranging from 1 to 3.
  • amphoteric or zwitterionic surfactants use is preferably made of (C 8 -C 20 ) alkylbetaines, (C 8 -C 20 ) alkylsulfobetaines, (C 8 -C 20 ) alkylamido (C 3 -C 8 ) alkylbetaines and (C 8 -C 20 ) alkylamido (C 6 -C 8 ) alkylsulfobetaines, more preferably of (C 8 -C 20 ) alkylbetaines and even more preferably of cocoylbetaine.
  • composition of the invention preferably comprises said amphoteric or zwitterionic surfactant (s) in an amount of from 0.01 to 15% by weight, more preferably from 0.1 to 10% by weight, and even more preferably from 1 to 5% by weight, based on the total weight of the composition.
  • composition of the invention further comprises one or more non ionic surfactant (s) chosen from alkanolamides of C 6 -C 30 fatty acids.
  • Such surfactants can be chosen from mono-alkanolamides and di-alcanolamides of C 8 -C 30 fatty acids, and preferably from mono-alkanolamides and di-alcanolamides of C 8 -C 18 fatty acids.
  • the alkanol groups may have from 1 to 10 carbon atoms, and preferably from 2 to 5 carbon atoms.
  • cocamide monoethanolamine cocamide diethanolamine
  • cocamide mono-isopropanolamine cocamide mono-isopropanolamine
  • said non ionic surfactant is cocamide mono-isopropanolamine.
  • composition of the invention preferably comprises said non ionic surfactant (s) chosen from alkanolamides of C 6 -C 30 fatty acids in an amount ranging from 0.05 to 5 % by weight, more preferably from 0.1 to 1 % by weight, with regard to the total weight of the composition.
  • non ionic surfactant chosen from alkanolamides of C 6 -C 30 fatty acids in an amount ranging from 0.05 to 5 % by weight, more preferably from 0.1 to 1 % by weight, with regard to the total weight of the composition.
  • composition according to the invention further comprises one or more anionic surfactant (s) .
  • anionic surfactant means a surfactant comprising, as ionic or ionizable groups, only anionic groups. These anionic groups are preferably chosen from the following groups:
  • anionic surfactants that may be used in the composition according to the invention, mention may be made of alkyl sulfates, alkyl ether sulfates, alkylamido ether sulfates, alkylaryl polyether sulfates, monoglyceride sulfates, alkylsulfonates, alkylamidesulfonates, alkylarylsulfonates, ⁇ -olefin sulfonates, paraffin sulfonates, alkyl sulfosuccinates, alkyl ether sulfosuccinates, alkylamide sulfosuccinates, alkyl sulfoacetates, acylsarcosinates, acylglutamates, alkyl sulfosuccinamates, acylisethionates and N-acyltaurates, polyglycoside polycarboxylic acid and alkyl monoester
  • These compounds can be oxyethylenated and then preferably comprise from 1 to 50 ethylene oxide units.
  • the salts of C 6 -C 24 alkyl monoesters of polyglycoside-polycarboxylic acids may be chosen from C 6 -C 24 alkyl polyglycoside-citrates, C 6 -C 24 alkyl polyglycoside-tartrates and C 6 -C 24 alkyl polyglycoside-sulfosuccinates.
  • anionic surfactant (s) When the anionic surfactant (s) are in salt form, they may be chosen from alkali metal salts such as the sodium or potassium salt and preferably the sodium salt, ammonium salts, amine salts and in particular amino alcohol salts, or alkaline-earth metal salts such as the magnesium salts.
  • alkali metal salts such as the sodium or potassium salt and preferably the sodium salt, ammonium salts, amine salts and in particular amino alcohol salts, or alkaline-earth metal salts such as the magnesium salts.
  • amino alcohol salts examples include monoethanolamine, diethanolamine and triethanolamine salts, monoisopropanolamine, diisopropanolamine or triisopropanolamine salts, 2-amino-2-methyl-1-propanol salts, 2-amino-2-methyl-1, 3-propanediol salts and tris (hydroxymethyl) aminomethane salts.
  • Alkali metal or alkaline-earth metal salts and in particular sodium or magnesium salts, are preferably used.
  • Preferred anionic surfactants are chosen from (C 6 -C 30 ) alkyl sulfates, (C 6 -C 30 ) alkyl ether sulfates, (C 6 -C 30 ) alkylamido ether sulfates, alkylaryl polyether sulfates and monoglyceride sulphates, all these compounds optionally comprising from 1 to 20 ethylene oxide units; and more preferably from (C 12 -C 20 ) alkyl sulphates and (C 12 -C 20 ) alkyl ether sulfates comprising from 2 to 20 ethylene oxide units, and even more preferably from 1 to 4 ethylene oxide units, especially in the form of alkali metal, ammonium, amino alcohol and alkaline-earth metal salts, or a mixture of these compounds.
  • a polyoxyethylenated sodium lauryl ether sulphate such as sodium lauryl ether sulphate containing 2 or
  • the amount of said anionic surfactant (s) in the composition of the invention is of at least 1.5% by weight, more preferably at least 3% by weight, with regard to the total weight of the composition. This amount preferably ranges from 5 to 30% by weight, more preferably from 5 to 15% by weight, with regard to the total weight of the composition.
  • composition of the invention may further contain one or more additional non ionic surfactant (s) different from the above-described alkanolamides of C 6 -C 30 fatty acids.
  • nonionic surfactant (s) that may be used in the compositions are described, for example, in the Handbook of Surfactants by M. R. Porter, published by Blackie &Son (Glasgow and London) , 1991, pp. 116-178.
  • nonionic surfactants examples include the following nonionic surfactants:
  • the oxyalkylene units are more particularly oxyethylene or oxypropylene units, or a combination thereof, preferably oxyethylene units.
  • the number of moles of ethylene oxide and/or propylene oxide preferably ranges from 1 to 250, more particularly from 2 to 100 and better still from 2 to 50; the number of moles of glycerol ranges especially from 1 to 50 and better still from 1 to 10.
  • nonionic surfactants according to the invention do not comprise any oxypropylene units.
  • glycerolated nonionic surfactants use is preferably made of monoglycerolated or polyglycerolated C 8 -C 40 alcohols, comprising from 1 to 50 mol of glycerol and preferably from 1 to 10 mol of glycerol.
  • lauryl alcohol containing 4 mol of glycerol (INCI name: Polyglyceryl-4 Lauryl Ether) , lauryl alcohol containing 1.5 mol of glycerol, oleyl alcohol containing 4 mol of glycerol (INCI name: Polyglyceryl-4 Oleyl Ether) , oleyl alcohol containing 2 mol of glycerol (INCI name: Polyglyceryl-2 Oleyl Ether) , cetearyl alcohol containing 2 mol of glycerol, cetearyl alcohol containing 6 mol of glycerol, oleyl/cetyl alcohol containing 6 mol of glycerol, and octadecanol containing 6 mol of glycerol.
  • glycerolated alcohols it is more particularly preferred to use the C 8 /C 10 alcohol containing 1 mol of glycerol, the C 10 /C 12 alcohol containing 1 mol of glycerol and the C 12 alcohol containing 1.5 mol of glycerol.
  • the additional nonionic surfactant (s) when they are present in the composition of the invention, are preferably present in a total amount ranging from 0.01 to 1% by weight, with regard to the total weight of the composition.
  • composition of the invention may further comprise one or more cationic surfactants.
  • cationic surfactant means a surfactant that is positively charged when it is contained in the composition according to the invention. This surfactant may bear one or more positive permanent charges or may contain one or more cationizable functions in the compositions.
  • the cationic surfactant (s) are preferably chosen from optionally polyoxyalkylenated, primary, secondary or tertiary fatty amines, or salts thereof, and quaternary ammonium salts, and mixtures thereof.
  • the fatty amines generally comprise at least one C 8 -C 30 hydrocarbon-based chain.
  • quaternary ammonium cationic surfactants those that are preferred are:
  • -tetraalkylammonium salts for instance dialkyldimethylammonium or alkyltrimethylammonium salts in which the alkyl group contains approximately from 12 to 22 carbon atoms, in particular behenyltrimethylammonium, distearyldimethylammonium, cetyltrimethylammonium or benzyldimethylstearylammonium salts, or, on the other hand, the palmitylamidopropyltrimethylammonium salt, the stearamidopropyltrimethylammonium salt, the stearamidopropyldimethylcetearylammonium salt, or the stearamidopropyldimethyl (myristyl acetate) ammonium salt sold under the name 70 by the company Van Dyk. It is particularly preferred to use the chloride salts of these compounds.
  • -di-or triquaternary ammonium salts for example, Finquat CT-P, available from the company Finetex (Quaternium 89) , and Finquat CT, available from the company Finetex (Quaternium 75) .
  • acyl groups preferably contain 14 to 18 carbon atoms and are obtained more particularly from a vegetable oil, such as palm oil or sunflower oil. When the compound contains several acyl groups, these groups may be identical or different.
  • Such compounds are, for example, sold under the names by the company Henkel, by the company Stepan, by the company Ceca or WE 18 by the company Rewo-Witco.
  • composition according to the invention may contain, for example, a mixture of quaternary ammonium monoester, diester and triester salts with a weight maj ority of diester salts.
  • ammonium salts containing at least one ester function that are described in patents US-A-4 874 554 and US-A-4 137 180.
  • Use may be made of behenoylhydroxypropyltrimethylammonium chloride, provided by Kao under the name Quatarmin BTC 131.
  • the ammonium salts containing at least one ester function contain two ester functions.
  • quaternary ammonium salts containing at least one ester function which can be used, it is preferred to use dipalmitoylethylhydroxyethylmethylammonium salts.
  • composition of the present invention may further contain one or more fatty substances.
  • fatty sub stance means an organic compound that is insoluble in water at ordinary temperature (25°C) and at atmospheric pressure (760 mmHg) (solubility of less than 5% by weight, preferably less than 1% and even more preferentially less than 0.1%) . They have in their structure at least one hydrocarbon-based chain comprising at least 6 carbon atoms or a sequence of at least two siloxane groups.
  • the fatty substances are generally soluble in organic solvents under the same temperature and pressure conditions, for instance chloroform, dichloromethane, carbon tetrachloride, ethanol, benzene,toluene, tetrahydrofuran (THF) , liquid petroleum j elly or decamethylcyclopentasiloxane.
  • organic solvents for instance chloroform, dichloromethane, carbon tetrachloride, ethanol, benzene,toluene, tetrahydrofuran (THF) , liquid petroleum j elly or decamethylcyclopentasiloxane.
  • the fatty substances are chosen from C 6 -C 16 hydrocarbons, hydrocarbons containing more than 16 carbon atoms, non-silicone oils of animal origin, plant or synthetic oils of triglyceride type, fluoro oils, fatty alcohols, fatty acid and/or fatty alcohol esters other than triglycerides and plant waxes, non-silicone waxes other than fatty alcohols, and silicones, and mixtures thereof.
  • the composition of the invention contains one or more oils, that is to say one or more fatty substance (s) that are liquid at room temperature (25°C) and at atmospheric pressure (760 mmHg; i.e. 1.013 ⁇ 10 5 Pa) .
  • the oil (s) are chosen from linear or branched liquid hydrocarbons, of mineral or synthetic origin, containing more than 16 carbon atoms, and especially liquid petroleum jelly, hydrogenated polyisobutene, C 6 -C 16 alkanes; triglyceride oils of plant origin; liquid fatty acid and/or fatty alcohol esters; liquid fatty alcohols; and mixtures thereof.
  • Particularly preferred oils are chosen from liquid fatty alcohols comprising from 8 to 20 carbon atoms.
  • a most particularly preferred oil is octyldodecanol.
  • the fatty substances may be present in an amount ranging from 0.05% to 10% by weight, preferably from 0.1% to 10% by weight, better still from 0.2% to 5% by weight, even better still from 0.2% to 2% by weight, relative to the total weight of the composition.
  • composition according to the invention advantageously comprises water, in a content of greater than or equal to 40% by weight relative to the total weight of composition.
  • the water content in the composition of the invention preferably ranges from 40% to 95% by weight, more preferentially from 40% to 80% by weight, relative to the total weight of the composition.
  • composition according to the invention may also comprise one or more water-soluble organic solvents (solubility of greater than or equal to 5% in water at 25°C and at atmospheric pressure) .
  • water-soluble organic solvents examples include linear or branched and preferably saturated monoalcohols or diols, comprising 2 to 10 carbon atoms, such as ethyl alcohol, isopropyl alcohol, hexylene glycol (2-methyl-2, 4-pentanediol) , neopentyl glycol and 3-methyl-1, 5-pentanediol, butylene glycol, dipropylene glycol and propylene glycol; aromatic alcohols such as phenylethyl alcohol; polyols containing more than two hydroxyl functions, such as glycerol; polyol ethers, for instance ethylene glycol monomethyl, monoethyl and monobutyl ether, propylene glycol or ethers thereof, for instance propylene glycol monomethyl ether; and also diethylene glycol alkyl ethers, especially C 1 -C 4 alkyl ethers, for instance diethylene glycol monoethyl ether or
  • the water-soluble organic solvents when they are present, generally represent between 1% and 20% by weight relative to the total weight of the composition according to the invention, and preferably between 5% and 10% by weight.
  • composition according to the invention preferably further comprises one or more alkaline agents.
  • the alkaline agent (s) can especially be chosen from aqueous ammonia, alkali metal carbonates or bicarbonates, organic amines with a pKb at 25°C of less than 12, in particular less than 10 and even more advantageously less than 6; from the salts of the amines mentioned previously with acids such as carbonic acid or hydrochloric acid: it should be noted that it is the pKb corresponding to the function of highest basicity.
  • the amines are chosen from alkanolamines, in particular comprising a primary, secondary or tertiary amine function, and one or more linear or branched C 1 -C 8 alkyl groups bearing one or more hydroxyl radicals; from oxyethylenated and/or oxypropylenated ethylenediamines, and from amino acids and compounds having the following formula:
  • W is a C 1 -C 6 alkylene residue optionally substituted with a hydroxyl group or a C 1 -C 6 alkyl radical
  • Rx, Ry, Rz and Rt which may be identical or different, represent a hydrogen atom or a C 1 -C 6 alkyl, C 1 -C 6 hydroxyalkyl or C 1 -C 6 aminoalkyl radical.
  • the composition according to the invention comprises aqueous ammonia and/or at least one alkanolamine and/or at least one basic amino acid, more advantageously aqueous ammonia and/or at least one alkanolamine, such as monoethanolamine, or mixtures thereof.
  • the content of alkaline agent (s) ranges from 0.01% to 30% by weight, preferably from 0.1% to 20% by weight and better still from 1% to 10% by weight relative to the total weight of the composition. It should be noted that this content is expressed as NH 3 when the alkaline agent is aqueous ammonia.
  • the pH of composition of the invention is preferably greater than or equal to 8, preferably ranges from 8 to 12, and more preferably from 9 to 11.
  • acidifying agents such as hydrochloric acid, (ortho) phosphoric acid, sulfuric acid, boric acid, and also carboxylic acids, for instance acetic acid, lactic acid or citric acid, or sulfonic acids.
  • Alkaline agents such as those previously mentioned may also be used.
  • composition according to the may also comprise one or more direct dyes.
  • Examples of particularly suitable direct dyes include nitrobenzene dyes; azo direct dyes; azomethine direct dyes; methine direct dyes; azacarbocyanin direct dyes, for instance tetraazacarbocyanines (tetraazapentamethines) ; quinone and in particular anthraquinone, naphthoquinone or benzoquinone direct dyes; azine direct dyes; xanthene direct dyes; triarylmethane direct dyes; indoamine direct dyes; indigoid direct dyes; phthalocyanine direct dyes, porphyrin direct dyes and natural direct dyes, alone or as mixtures.
  • direct dyes from among: azo; methine; carbonyl; azine; nitro (hetero) aryl; tri(hetero) arylmethane; porphyrin; phthalocyanine and natural direct dyes, alone or as mixtures.
  • the direct dye (s) may represent from 0.0001% to 10% by weight and preferably from 0.005% to 5% by weight relative to the total weight of the composition.
  • composition according to the invention may also comprise one or more cosmetic adjuvants.
  • the composition may comprise one or more additives that are well known in the art, such as anionic, nonionic or amphoteric polymers or mixtures thereof, agents for preventing hair loss, vitamins and provitamins including panthenol, sunscreens, mineral or organic pigments, sequestrants, plasticizers, solubilizers, acidifying agents, mineral or organic thickeners, especially polymeric thickeners, opacifiers, antioxidants, hydroxy acids, nacreous agents, fragrances and preserving agents.
  • additives that are well known in the art, such as anionic, nonionic or amphoteric polymers or mixtures thereof, agents for preventing hair loss, vitamins and provitamins including panthenol, sunscreens, mineral or organic pigments, sequestrants, plasticizers, solubilizers, acidifying agents, mineral or organic thickeners, especially polymeric thickeners, opacifiers, antioxidants, hydroxy acids, nacreous agents, fragrances and preserving agents.
  • the above adjuvants may generally be present in an amount, for each of them, of between 0 and 20% by weight relative to the total weight of the composition.
  • the composition further comprises one or more oxidizing agents.
  • the composition is then said to be "ready to use”in the sense that it does not require the use of a separate oxidizing composition.
  • the oxidizing agent (s) used in the context of the invention are chemical oxidizing agents other than atmospheric oxygen.
  • the said oxidizing agent (s) are preferably chosen from the group formed by hydrogen peroxide, urea peroxide, alkali metal bromates or ferricyanides, peroxygenated salts, for instance persulfates, perborates, peracids and precursors thereof and alkali metal or alkaline-earth metal percarbonates, and most particularly hydrogen peroxide.
  • the oxidizing agent (s) may represent from 0.01% to 20%, preferably from 0.1% to 10% and better still from 2% to 8% by weight, relative to the total weight of the composition.
  • compositions according to the invention may be in the form of fluid or thickened liquids, gels or creams.
  • a viscosity measured at ambient temperature and atmospheric pressure, ranging from 10 to 100 UD, preferably from 20 to 80 UD, and even more preferably from 50 to 70 UD, when using rotor 3 under 200 rpm for 30 seconds.
  • the viscosity of the composition of the present invention is measured using a ProRheo R180 machine from the company Prorheo, Roter 3 is used adapted to the viscosity of the composition to be tested (rotor is chosen for having a measure between 10 and 100 for UD Unit Deviation) , the measure being made after 30 seconds rotating the rotor inside the composition, with a shear rate from 200s -1 .
  • the invention also relates to the use of the composition as described above for dyeing keratin fibres, in particular the hair.
  • Another subject of the invention is a process for dyeing human keratin fibres, in particular the hair, using the composition as described above.
  • the composition is "ready to use", i.e. it already contains at least one oxidizing agent.
  • the dyeing process of the invention consists in applying the "ready-to-use"composition to the keratin fibres.
  • the dyeing process of the invention consists in applying the composition as described above to the keratin fibres, the said composition being applied with a separate oxidizing composition.
  • the oxidizing composition that is used in this embodiment of the process of the invention comprises one or more oxidizing agents.
  • the oxidizing agent (s) of the oxidizing composition are as defined above, ie, they are preferably chosen from the group formed by hydrogen peroxide, urea peroxide, alkali metal bromates or ferricyanides, peroxygenated salts, for instance persulfates, perborates, peracids and precursors thereof and alkali metal or alkaline-earth metal percarbonates, and most particularly hydrogen peroxide.
  • the oxidizing agent (s) may represent from 0.01% to 20%, preferably from 0.1% to 10% and better still from 2% to 8%by weight, relative to the total weight of the oxidizing composition.
  • the composition according to the invention is mixed at the time of use with the oxidizing composition as described above.
  • composition of the present invention is intended to mean the action of putting the composition of the present invention into a container or palm, together with the oxidizing composition as described above, with or without stirring them.
  • the composition of the present invention is put into a container or palm together with the oxidizing composition as described above, without stirring them.
  • composition of the invention due to the very good foaming properties of the composition of the invention, it is particularly advantageous and convenient to apply onto the keratin fibers the composition of the invention and an oxidizing composition without the need of stirring them in a container or palm, but apply them directly on the hair, and allow the mixture thus formed onto the hair to foam for example by massaging with the fingers.
  • compositions described previously, optionally mixed beforehand, are applied to wet or dry keratin fibres.
  • composition (s) are usually left in place on the fibres for a time generally ranging from 1 minute to 1 hour and preferably from 5 minutes to 30 minutes.
  • the temperature during the process is conventionally between 20 and 80°C and preferably between 20 and 60°C.
  • the human keratin fibres are advantageously rinsed with water. They may optionally be further washed with a shampoo, followed by rinsing with water, before being dried or left to dry.
  • the process may be repeated several times in order to obtain the desired coloration.
  • Another subj ect of the invention concerns a multi-compartment device, or a kit for dyeing keratin fibres, comprising at least two compartments:
  • the kit also comprises an additional compartment containing an additional composition comprising one or more treating agents.
  • compositions of the kit are packaged in separate compartments, which may be optionally accompanied by suitable identical or different application means, such as fine brushes, coarse brushes or sponges.
  • kit may also be equipped with means allowing the delivery to the hair of the desired mixture, such as, for example, the device described in patent FR 2 586 913.
  • the dyeing compositions hereunder were prepared, from the ingredients indicated in the table below (in which the contents are indicated in grams of active material with regard to the total weight of the composition) :
  • composition C4 corresponds to the invention, whereascompositions C 1 to C3 correspond to comparative compositions.
  • compositions above were tested with regard to thefollowing properties:
  • Stability on storage of the composition was performed by leaving the compositions C 1 to C4 at 4°C, roomtemperature (25°C) , and 45°C for 2 months. Then C 1 to C4 were leftunder 37°C for 6 months to evaluate the long term stabilities.
  • Viscosity of the composition The viscosities of the compositions C1 to C4 were measured at 25°C, using a ProRheo R180 machine from the company Prorheo, Roter 3 was used adapted to the viscosity of the product to be tested (rotor is chosen for having a measure between 10 and 100 for UD Unit Deviation) , the measure being made after 30 seconds rotating the rotor inside the composition, with a shear rate from 200s -1 .
  • Ease of application onto the keratin fibers The ease of application onto hair of the compositions C1 to C4 was measured by 3 hair dressers using the compositions C1 to C4 for dyeing the hair. 30g of the compositions C1 to C4 were poured in the palm of the hair dressers, respectively, together with same amount of an oxidizer containing 6% of hydrogen peroxide. Without mixing, the hair dressers applied the products (compositions C1 to C4 mixing with oxidizers) immediately onto the middle-length hair, i.e., hair length is at the shoulder. The hair were massaged and foam was formed. After 15 minutes, the hair with the products mentioned above were rinsed with water.
  • a dyeing composition in accordance with the invention was prepared, from the ingredients indicated in the table below (in which the contents are indicated in grams of active material with regard to the total weight of the composition) :
  • Composition A 4-diaminophenoxyethanol, HCl 0.60 Resorcinol 1.70 m-aminophenol 0.2 p-phenylenediamine 2 Sodium laureth sulfate (2 OE) 10.0 Cocoylbetaine 3.0 Cocamide mono-isopropanolamine 0.3 Polyquaternium-10 0.8 PEG-120 methyl glucose dioleate 0.1 Polysorbate 21 0.2 Octyldodecanol 0.40 Ethanolamine 2.40 Glycerin 5 Ascorbic acid 0.25 Sodium metabisulfite 0.7 EDTA 0.1 Fragrance qs Water qs 100 g
  • composition prepared above was poured in a palm together with 30g of an oxidizer containing 6% of hydrogen peroxide. Without mixing, the compositions were applied immediately onto the middle-length hair, i.e., hair length is at the shoulder. The hair was massaged and foam was formed. After 15 minutes, the hair was rinsed with water.
  • the viscosity of the composition mentioned above is 63.8 UD, using the measurement method disclosed in example 1 above. It allows the composition staying in the palm without floating away. And furthermore, when mixing with the oxidizer on the hair, it allows the mixture and the foam staying on the hair without dropping or flying.
  • the turbidity of the composition mentioned above is 6 NTU, using the measurement method disclosed in the above description.
  • composition mentioned above is stable over 2 months under 4°C, room temperature, and 45°C.

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Abstract

A cosmetic composition for the oxidation dyeing of keratin fibres comprises one or more oxidation dye(s), one or more cationic polymer(s), one or more amphoteric or zwitterionic surfactant(s), one or more non ionic surfactants chosen from alkanolamides of C6-C30 fatty acides, and one or more anionic surfactant(s) in an amount of at least 1.5% by weight, with regard to the total weight of the composition. A process for dyeing keratin fibres using the composition and a kit suitable for implementing such a process are also provided.

Description

Cosmetic composition for the oxidation dyeing of keratin fibres comprising a cationic polymer and a particular combination of surfactants
The present invention relates to a cosmetic composition for the oxidation dyeing of keratin fibres, in particular human keratin fibres such as the hair.
More precisely, a subject of the present invention is a dyeing cosmetic composition comprising one or more oxidation dyes, one or more cationic polymers and a particular combination of surfactants.
The present invention also relates to a process for dyeing keratin fibres, in particular human keratin fibres such as the hair, using the composition according to the invention.
At last, the present invention relates to a kit for the oxidation dyeing of keratin fibres, which is suitable for performing the process of the invention.
Many people have for a long time sought to modify the colour of their hair, and especially to dye it in order, for example, to mask their grey hair.
"Permanent" dyeing methods also known as oxidation dyeing, which use dye compositions containing oxidation dye precursors, generally referred to as oxidation bases, such as ortho-or para-phenylenediamines, ortho-or para-aminophenols and heterocyclic compounds, have been developed for dyeing human keratin fibres in a long-lasting manner. These oxidation bases are colourless or weakly coloured compounds, which, when combined with oxidizing products, may give rise to coloured compounds via a process of oxidative condensation.
It is also known that the shades obtained with these oxidation bases can be varied by combining them with couplers or coloration modifiers, the latter being chosen especially from aromatic meta-diaminobenzenes, meta-aminophenols, meta-diphenols and certain heterocyclic compounds such as indole compounds.
As an example of compositions known in the prior art, mention may be made of WO 2011/138838 which discloses a ready-to-use composition for the oxidation dyeing of keratin fibers comprising, in an aqueous medium at least one oxidation dye, at least one oxidizing agent, and at least 1.5％ by weight of at least one amphoteric surfactant.
However, the prior art compositions are not entirely satisfactory, and their performance qualities can be further improved, in particular as regards the working qualities (whether or not the composition is mixed with an oxidizing composition before application) , especially in terms of texture, ease of application and ease of spreading of the composition on the keratin fibres. Furthermore, the compositions of the prior art are not always sufficiently stable, and their coloring performances can also be further improved, especially in terms of intensity, homogeneity and selectivity of the dyeing obtained.
The Applicant has now discovered that the use of a cationic polymer together with a particular combination of surfactants makes it possible to obtain a cosmetic composition for the oxidation dyeing of keratin fibres, which can overcome the above drawbacks and which has further improved properties.
One subject of the present invention is thus a cosmetic composition for the oxidation dyeing of keratin fibres comprising:
a) one or more oxidation dye (s) ,
b) one or more cationic polymer (s) ,
c) one or more amphoteric or zwitterionic surfactant (s) ,
d) one or more non ionic surfactant (s) chosen from alkanolamides of C6-C30 fatty acids, and
e) one or more anionic surfactant (s) , in an amount of at least 1.5％ by weight, with regard to the total weight of the composition.
The composition according to the invention has very good working qualities, and especially a particularly pleasant texture and a good viscosity (neither too thick, nor too fluid which facilitates its use) . This property is very stable over the time, and does not diminish  even after several months of storage at ambient temperature (25℃) as well as from low temperatures (such as 4℃) until high temperatures (such as 45℃) .
The composition further exhibits excellent foaming properties similar to those of a shampoo, whenever or not is mixed with a developer composition (or oxidizer) , and it is very easy to apply and to spread on the locks of hair, in particular from the roots to the ends. More particularly, the composition of the present invention allows an easy an rapid formation of foam, such as immediately after massaging the hair. The foam is firm and creamy and allows a good dyeing performance. Moreover, the foam stays on the hair without flying away.
In addition, the composition of the invention does not require premixing with a developer composition or oxidizing composition or oxidizer. It allows to be used simultaneously with a developer or oxidizer directly on the hair, without a step of premixing.
In addition, it does not run and remains well located at the points of application in particular on the roots, while being very easy to rinse off from the hair after application
Furthermore, the composition of the invention has very good cosmetic properties, and provides the keratin fibres with an excellent conditioning. In particular, after dyeing with such a composition the hair is shiny, smooth, supple and easy to disentangle.
At last, the composition according to the invention has superior dyeing quality, especially in terms of intensity, homogeneity and selectivity of the dyeing obtained.
The composition of the invention is intended to be used in a process for dyeing keratin fibres either as a ready-to-use composition when it contains an oxidizing agent, or in combination with an oxidizing composition.
A subj ect of the invention is thus also a process for dyeing keratin fibres, which consists in applying to the keratin fibres the composition of the invention. Said composition may be applied sequentially to or simultaneously with an oxidizing composition comprising one or more oxidizing agents.
Other characteristics and advantages of the invention will emerge more clearly on reading the description and the examples that follow.
In the text hereinbelow, and unless otherwise indicated, the limits of a range of values are included in that range. The term "at least one" associated with an ingredient of the composition signifies "one or more".
The terms "oxyalkylenated" , "oxyethylenated" , "oxypropylenated" and "glycerolated" cover, respectively, mono-or poly-oxyalkylenated, oxyethylenated, oxypropylenated and glycerolated compounds, unless specifically mentioned.
The composition of the invention is advantageously transparent. The transparency of the composition may be characterized by measuring its turbidity according to the NTU method using a 2100P model turbidimeter from the company Hach, at room temperature. The turbidity of the compositions of the invention is generally less than 400 NTU units and preferably less than 250 NTU units, more preferably less than 200 NTU.
As indicated previously, the composition according to the invention comprises one or more oxidation dyes.
The oxidation dyes that may be used in the present invention are generally chosen from oxidation bases, optionally combined with one or more couplers.
Preferentially, the oxidation dye (s) comprise one or more oxidation bases.
The oxidation bases may be chosen especially from para-phenylenediamines, bis (phenyl) alkylenediamines, para-aminophenols, ortho-aminophenols, heterocyclic bases, and the addition salts thereof, and mixtures thereof.
Among the para-phenylenediamines, examples that may be mentioned include para-phenylenediamine, para-tolylenediamine, 2-chloro-para-phenylenediamine, 2, 3-dimethyl-para-phenylenediamine, 2,6-dimethyl-para-phenylenediamine, 2, 6-diethyl-para-phenylenediamine, 2, 5-dimethyl-para-phenylenediamine, N, N- dimethyl-para-phenylenediamine, N, N-diethyl-para-phenylenediamine, N,N-dipropyl-para-phenylenediamine, 4-amino-N, N-diethyl-3-methylaniline, N, N-bis (β-hydroxyethyl) -para-phenylenediamine, 4-N,N-bis (β-hydroxyethyl) amino-2-methylaniline, 4-N, N–bis (β-hydroxyethyl) amino-2-chloroaniline, 2-β-hydroxyethyl-para-phenylenediamine, 2-fluoro-para-phenylenediamine, 2-isopropyl-para-phenylenediamine, N- (β-hydroxypropyl) -para-phenylenediamine, 2-hydroxymethyl-para-phenylenediamine, N, N-dimethyl-3-methyl-para-phenylenediamine, N, N- (ethyl-β-hydroxyethyl) -para-phenylenediamine, N- (β, γ-dihydroxypropyl) -para-phenylenediamine, N-(4'-aminophenyl) -para-phenylenediamine, N-phenyl-para-phenylenediamine, 2-β-hydroxyethyloxy-para-phenylenediamine, 2-β-acetylaminoethyloxy-para-phenylenediamine, N- (β-methoxyethyl) -para-phenylenediamine, 4-aminophenylpyrrolidine, 2-thienyl-para-phenylenediamine, 2-β-hydroxyethylamino-5-aminotoluene and 3-hydroxy-1- (4'-aminophenyl) pyrrolidine, and the addition salts thereof with an acid.
Among the para-phenylenediamines mentioned above, para-phenylenediamine, para-tolylenediamine, 2-isopropyl-para-phenylenediamine, 2-β-hydroxyethyl-para-phenylenediamine, 2-β-hydroxyethyloxy-para-phenylenediamine, 2, 6-dimethyl-para-phenylenediamine, 2, 6-diethyl-para-phenylenediamine, 2, 3-dimethyl-para-phenylenediamine, N, N-bis (β-hydroxyethyl) -para-phenylenediamine, 2-chloro-para-phenylenediamine and 2-β-acetylaminoethyloxy-para-phenylenediamine, and the addition salts thereof with an acid, are particularly preferred.
Among the bis (phenyl) alkylenediamines, examples that may be mentioned include N, N'-bis (β-hydroxyethyl) -N, N'-bis (4'-aminophenyl) -1, 3-diaminopropanol, N, N'-bis (β-hydroxyethyl) -N, N'-bis(4'-aminophenyl) ethylenediamine, N, N'-bis (4-aminophenyl) tetramethylenediamine, N, N'-bis (β-hydroxyethyl) -N, N'-bis (4-aminophenyl) tetramethylenediamine, N, N'-bis (4-methylaminophenyl) tetramethylenediamine, N, N'-bis (ethyl) -N, N'- bis (4'-amino-3'-methylphenyl) ethylenediamine, 1, 8-bis (2, 5-diaminophenoxy) -3, 6-dioxaoctane and the addition salts thereof.
Among the para-aminophenols, examples that may be mentioned include para-aminophenol, 4-amino-3-methylphenol, 4-amino-3-fluorophenol, 4-amino-3-chlorophenol, 4-amino-3-hydroxymethylphenol, 4-amino-2-methylphenol, 4-amino-2-hydroxymethylphenol, 4-amino-2-methoxymethylphenol, 4-amino-2-aminomethylphenol, 4-amino-2- (β-hydroxyethyl-aminomethyl) phenol and 4-amino-2-fluorophenol, and the addition salts thereof with an acid.
Among the ortho-aminophenols, examples that may be mentioned include 2-aminophenol, 2-amino-5-methylphenol, 2-amino-6-methylphenol and 5-acetamido-2-aminophenol, and the addition salts thereof.
Among the heterocyclic bases, examples that may be mentioned include pyridine derivatives, pyrimidine derivatives and pyrazole derivatives.
Among the pyridine derivatives that may be mentioned are the compounds described, for example, in patents GB 1 026 978 and GB 1 153 196, for instance 2, 5-diaminopyridine, 2- (4-methoxyphenyl) amino-3-aminopyridine and 3, 4-diaminopyridine, and the addition salts thereof.
Other pyridine oxidation bases that are useful in the present invention are the 3-aminopyrazolo [1, 5-a] pyridine oxidation bases or the addition salts thereof described, for example, in patent application FR 2 801 308. Examples that may be mentioned include pyrazolo [1, 5-a]pyrid-3-ylamine, 2- (acetylamino) pyrazolo [1, 5-a] pyrid-3-ylamine, 2-(morpholin-4-yl) pyrazolo [1, 5-a] pyrid-3-ylamine, 3-aminopyrazolo [1, 5-a] pyridine-2-carboxylic acid, 2-methoxypyrazolo [1, 5-a] pyrid-3-ylamine, (3-aminopyrazolo [1, 5-a]pyrid-7-yl) methanol, 2- (3-aminopyrazolo [1, 5-a] pyrid-5-yl) ethanol, 2-(3-aminopyrazolo [1, 5-a] pyrid-7-yl) ethanol, (3-aminopyrazolo [1, 5-a]pyrid-2-yl) methanol, 3, 6-diaminopyrazolo [1, 5-a] pyridine, 3, 4-diaminopyrazolo [1, 5-a] pyridine, pyrazolo [1, 5-a] pyridine-3, 7-diamine,  7-(morpholin-4-yl) pyrazolo [1, 5-a] pyrid-3-ylamine, pyrazolo [1, 5-a]pyridine-3, 5-diamine, 5- (morpholin-4-yl) pyrazolo [1, 5-a] pyrid-3-ylamine, 2- [ (3-aminopyrazolo [1, 5-a] pyrid-5-yl) (2-hydroxyethyl) amino] ethanol, 2- [ (3-aminopyrazolo [1, 5-a] pyrid-7-yl) (2-hydroxyethyl) amino] ethanol, 3-aminopyrazolo [1, 5-a] pyridin-5-ol, 3-aminopyrazolo [1, 5-a] pyridin-4-ol, 3-aminopyrazolo [1, 5-a] pyridin-6-ol, 3-aminopyrazolo [1, 5-a] pyridin-7-ol and the addition salts thereof.
Among the pyrimidine derivatives that may be mentioned are the compounds described, for example, in the patents DE 2359399； JP 88-169571； JP 05-63124； EP 0770375 or patent application WO 96/15765, such as 2, 4, 5, 6-tetraaminopyrimidine, 4-hydroxy-2, 5, 6-triaminopyrimidine, 2-hydroxy-4, 5, 6-triaminopyrimidine, 2, 4-dihydroxy-5, 6-diaminopyrimidine, 2, 5, 6-triaminopyrimidine and the addition salts thereof and the tautomeric forms thereof, when a tautomeric equilibrium exists.
Among the pyrazole derivatives that may be mentioned are the compounds described in patents DE 3843892 and DE 4133957 and patent applications WO 94/08969, WO 94/08970, FR-A-2 733 749 and DE 195 43 988, for instance 4, 5-diamino-1-methylpyrazole, 4, 5-diamino-1- (β-hydroxyethyl) pyrazole, 3, 4-diaminopyrazole, 4, 5-diamino-1- (4'-chlorobenzyl) pyrazole, 4, 5-diamino-1, 3-dimethylpyrazole, 4, 5-diamino-3-methyl-1-phenylpyrazole, 4, 5-diamino-1-methyl-3-phenylpyrazole, 4-amino-1, 3-dimethyl-5-hydrazinopyrazole, 1-benzyl-4, 5-diamino-3-methylpyrazole, 4, 5-diamino-3-tert-butyl-1-methylpyrazole, 4, 5-diamino-1-tert-butyl-3-methylpyrazole, 4, 5-diamino-1- (β-hydroxyethyl) -3-methylpyrazole, 4,5-diamino-1-ethyl-3-methylpyrazole, 4, 5-diamino-1-ethyl-3- (4'-methoxyphenyl) pyrazole, 4, 5-diamino-1-ethyl-3-hydroxymethylpyrazole, 4, 5-diamino-3-hydroxymethyl-1-methylpyrazole, 4, 5-diamino-3-hydroxymethyl-1-isopropylpyrazole, 4,5-diamino-3-methyl-1-isopropylpyrazole, 4-amino-5- (2'-aminoethyl) amino-1, 3-dimethylpyrazole, 3, 4, 5-triaminopyrazole, 1-methyl-3, 4, 5-triaminopyrazole, 3, 5-diamino-1-methyl-4-methylaminopyrazole and 3, 5-diamino-4- (β-hydroxyethyl) amino-1- methylpyrazole, and the addition salts thereof. 4, 5-Diamino-1- (β-methoxyethyl) pyrazole may also be used.
A 4, 5-diaminopyrazole will preferably be used, and even more preferentially 4, 5-diamino-1- (β-hydroxyethyl) pyrazole and/or a salt thereof.
Pyrazole derivatives that may also be mentioned include diamino-N, N-dihydropyrazolopyrazolones and especially those described in patent application FR-A-2 886 136, such as the following compounds and the addition salts thereof: 2, 3-diamino-6, 7-dihydro-1H,5H-pyrazolo [1, 2-a] pyrazol-1-one, 2-amino-3-ethylamino-6, 7-dihydro-1H, 5H-pyrazolo [1, 2-a] pyrazol-1-one, 2-amino-3-isopropylamino-6, 7-dihydro-1H, 5H-pyrazolo [1, 2-a] pyrazol-1-one, 2-amino-3- (pyrrolidin-1-yl) -6, 7-dihydro-1H, 5H-pyrazolo [1, 2-a] pyrazol-1-one, 4, 5-diamino-1, 2-dimethyl-1, 2-dihydropyrazol-3-one, 4, 5-diamino-1, 2-diethyl-1, 2-dihydropyrazol-3-one, 4, 5-diamino-1, 2-bis (2-hydroxyethyl) -1, 2-dihydropyrazol-3-one, 2-amino-3- (2-hydroxyethyl) amino-6, 7-dihydro-1 H, 5H-pyrazolo [1, 2-a] pyrazol-1-one, 2-amino-3-dimethylamino-6, 7-dihydro-1H, 5H-pyrazolo [1, 2-a] pyrazol-1-one, 2, 3-diamino-5, 6, 7, 8-tetrahydro-1H, 6H-pyridazino [1, 2-a]pyrazol-1-one, 4-amino-1, 2-diethyl-5- (pyrrolidin-1-yl) -1, 2-dihydropyrazol-3-one, 4-amino-5- (3-dimethylaminopyrrolidin-1-yl) -1,2-diethyl-1, 2-dihydropyrazol-3-one or 2, 3-diamino-6-hydroxy-6, 7-dihydro-1H, 5H-pyrazolo [1, 2-a] pyrazol-1-one.
Use will preferably be made of 2, 3-diamino-6, 7-dihydro-1H,5H-pyrazolo [1, 2-a] pyrazol-1-one and/or one of its salts.
Heterocyclic bases that will preferentially be used include 4, 5-diamino-1- (β-hydroxyethyl) pyrazole and/or 2, 3-diamino-6, 7-dihydro-1H,5H-pyrazolo [1, 2-a] pyrazol-1-one and/or a salt thereof.
The oxidation dye (s) may also comprise one or more couplers, which may be chosen from those conventionally used for the dyeing of keratin fibres.
Among these couplers, mention may be made especially of meta-phenylenediamines, meta-aminophenols, meta-diphenols,  naphthalene-based couplers heterocyclic couplers, and also the addition salts thereof, and mixtures thereof.
Examples that may be mentioned include 1, 3-dihydroxybenzene, 1,3-dihydroxy-2-methylbenzene, 4-chloro-1, 3-dihydroxybenzene, 2, 4-diamino-1- (β-hydroxyethyloxy) benzene, 2-amino-4- (β-hydroxyethylamino) -1-methoxybenzene, 1, 3-diaminobenzene, 1, 3-bis(2, 4-diaminophenoxy) propane, 3-ureidoaniline, 3-ureido-1-dimethylaminobenzene, sesamol, 1-β-hydroxyethylamino-3, 4-methylenedioxybenzene, α-naphthol, 2-methyl-1-naphthol, 6-hydroxyindole, 4-hydroxyindole, 4-hydroxy-N-methylindole, 2-amino-3-hydroxypyridine, 6-hydroxybenzomorpholine, 3, 5-diamino-2, 6-dimethoxypyridine, 1-N- (β-hydroxyethyl) amino-3, 4-methylenedioxybenzene, 2, 6-bis (β-hydroxyethylamino) toluene, 6-hydroxyindoline, 2, 6-dihydroxy-4-methylpyridine, 1-H-3-methylpyrazol-5-one, 1-phenyl-3-methylpyrazol-5-one, 2, 6-dimethylpyrazolo [1, 5-b] -1, 2, 4-triazole, 2, 6-dimethyl [3, 2-c] -1, 2, 4-triazole and 6-methylpyrazolo [1, 5-a] benzimidazole, the addition salts thereof with an acid, and mixtures thereof.
In general, the addition salts of the oxidation bases and couplers that may be used within the context of the invention are especially chosen from the addition salts with an acid such as the hydrochlorides, hydrobromides, sulfates, citrates, succinates, tartrates, lactates, tosylates, benzenesulfonates, phosphates and acetates.
The oxidation base (s) may advantageously represent from 0.0001％ to 10％ by weight relative to the total weight of the composition, preferably from 0.005％ to 5％ by weight and better still from 0.1％ to 5％ by weight.
The coupler (s) , if they are present, may advantageously represent from 0.0001％ to 10％ by weight relative to the total weight of the composition, and preferably from 0.005％ to 5％ by weight.
The composition of the invention further comprises one or more cationic polymer (s) .
The term "cationic polymer" is intended to mean any polymer comprising cationic groups and/or groups that can be ionized to  cationic groups. Preferably, the cationic polymer is hydrophilic or amphiphilic. The preferred cationic polymers are chosen from those that contain units comprising primary, secondary, tertiary and/or quaternary amine groups that may either form part of the main polymer chain or may be borne by a side substituent directly connected thereto.
Among the cationic polymers, mention may be made more particularly of:
(1) homopolymers or copolymers derived from acrylic or methacrylic esters or amides and comprising at least one of the units of the following formulae:
Figure PCTCN2015071080-appb-000001
in which:
-R3, which may be identical or different, denote a hydrogen atom or a CH3 group；
-A, which may be identical or different, represent a linear or branched divalent alkyl group of 1 to 6 carbon atoms, preferably 2 or 3 carbon  atoms, or a hydroxyalkyl group of 1 to 4 carbon atoms；
-R4, R5 and R6, which may be identical or different, represent an alkyl group containing from 1 to 18 carbon atoms or a benzyl group, and preferably an alkyl group containing from 1 to 6 carbon atoms；
-R1 and R2, which may be identical or different, represent a hydrogen atom or an alkyl group containing from 1 to 6 carbon atoms, and preferably methyl or ethyl；
-X denotes an anion derived from an inorganic or organic acid, such as a methosulfate anion or a halide such as chloride or bromide.
The copolymers of family (1) may also contain one or more units derived from comonomers which may be chosen from the family of acrylamides, methacrylamides, diacetone acrylamides, acrylamides and methacrylamides substituted on the nitrogen with C 1-C4 alkyls, acrylic or methacrylic acids or esters thereof, vinyllactams such as vinylpyrrolidone or vinylcaprolactam, and vinyl esters.
Among these copolymers of family (1) , mention may be made of:
-copolymers of acrylamide and of dimethylaminoethyl methacrylate quaternized with dimethyl sulfate or with a dimethyl halide, such as that sold under the name Hercofloc by the company Hercules,
-copolymers of acrylamide and of methacryloyloxyethyl-trimethylammonium chloride, such as those sold under the name Bina Quat P 100 by the company Ciba Geigy,
-the copolymer of acrylamide and of methacryloyloxyethyltrimethylammonium methosulfate, such as the product sold under the name Reten by the company Hercules,
-quaternized or non-quaternized vinylpyrrolidone/dialkylaminoalkyl acrylate or methacrylate copolymers, such as the products sold under the name Gafquat by the company ISP, for instance Gafquat 734 or Gafquat 755, or alternatively the products known as Copolymer 845, 958 and 937. These polymers are described in detail in French patents 2 077 143 and 2 393 573,
-dimethylaminoethyl methacrylate/vinylcaprolactam/vinyl-pyrrolidone terpolymers, such as the product sold under the name Gaffix VC 713 by the company ISP,
-vinylpyrrolidone/methacrylamidopropyldimethylamine copolymers, such as those sold under the name Styleze CC 10 by ISP,
-quaternized vinylpyrrolidone/dimethylaminopropyl-methacrylamide copolymers such as the product sold under the name Gafquat HS 100 by the company ISP,
-preferably crosslinked polymers of methacryloyloxy (C1-C4)alkyl tri (C1-C4) alkylammonium salts, such as the polymers obtained by homopolymerization of dimethylaminoethyl methacrylate quaternized with methyl chloride, or by copolymerization of acrylamide with dimethylaminoethyl methacrylate quaternized with methyl chloride, the homo-or copolymerization being followed by crosslinking with an olefinically unsaturated compound, in particular methylenebisacrylamide. A crosslinked acrylamide/methacryloyloxyethyltrimethylammonium chloride copolymer (20/80 by weight) in the form of a dispersion comprising 50％ by weight of said copolymer in mineral oil may more particularly be used. This dispersion is sold under the name 
Figure PCTCN2015071080-appb-000002
SC 92 by the company Ciba. A crosslinked methacryloyloxyethyltrimethylammonium chloride homopolymer comprising about 50％ by weight of the homopolymer in mineral oil or in a liquid ester can also be used. These dispersions are sold under the names
Figure PCTCN2015071080-appb-000003
SC 95 and
Figure PCTCN2015071080-appb-000004
SC 96 by the company Ciba.
(2) Cationic polysaccharides, in particular cationic celluloses and cationic galactomannan gums. Among the cationic polysaccharides, mention may be made more particularly of cellulose ether derivatives comprising quaternary ammonium groups, cationic cellulose copolymers or cellulose derivatives grafted with a water-soluble quaternary ammonium monomer and cationic galactomannan gums.
The cellulose ether derivatives comprising quaternary ammonium groups are in particular described in FR patent 1 492 597, and mention may be made of the polymers sold under the name Ucare Polymer JR (JR 400 LT, JR 125 and JR 30M) or LR (LR 400 or LR 30M) by the company Amerchol. These polymers are also defined in the CTFA dictionary as quaternary ammoniums of hydroxyethylcellulose that have reacted with an epoxide substituted with a trimethylammonium group.
Cationic cellulose copolymers or cellulose derivatives grafted with a water-soluble quaternary ammonium monomer are described in particular in US patent 4 131 576, and mention may be made of hydroxyalkyl celluloses, for instance hydroxymethyl-, hydroxyethyl-or hydroxypropylcelluloses grafted, in particular, with a methacryloylethyltrimethylammonium, methacrylamidopropyltrimethyl-ammonium, dimethyldiallylammonium or hydroxypropyltrialkylammonium salt, for example 2-hydroxypropyl trimethyl ammonium chloride. The commercial products corresponding to this definition are more particularly the products sold under the names Celquat L 200 and Celquat H 100 by the company National Starch, or hydroxyethyl cellulose-2-hydroxypropyl trimethyl ammonium chloride ether (INCI name: Polyquaternium-10) such as the product sold under the name Polyquta 400KC by the company KCI.
The cationic galactomannan gums are described more particularly in US patents 3 589 578 and 4 031 307, and mention may be made of guar gums comprising cationic trialkylammonium groups. Use is made, for example, of guar gums modified with a 2, 3-epoxypropyltrimethylammonium salt (for example, a chloride) . Such products are in particular sold under the names Jaguar C 13 S, Jaguar C 15, Jaguar C 17 and Jaguar C 162 by the company Rhodia.
(3) Polymers composed of piperazinyl units and of divalent alkylene or hydroxyalkylene groups containing linear or branched chains, optionally interrupted by oxygen, sulfur or nitrogen atoms or by aromatic or heterocyclic rings, and also the oxidation and/or quaternization products of these polymers.
(4) Water-soluble polyaminoamides prepared in particular by polycondensation of an acidic compound with a polyamine； these polyaminoamides can be crosslinked by an epihalohydrin, a diepoxide, a dianhydride, an unsaturated dianhydride, a bisunsaturated derivative, a bishalohydrin, a bisazetidinium, a bishaloacyldiamine or an alkyl bishalide or alternatively by an oligomer resulting from the reaction of a bifunctional compound reactive with respect to a bishalohydrin, a bisazetidinium, a bishaloacyldiamine, an alkyl bishalide, an  epihalohydrin, a diepoxide or a bisunsaturated derivative； the crosslinking agent being used in proportions ranging from 0.025 to 0.35 mol per amine group of the polyaminoamide； these polyaminoamides can be alkylated or, if they comprise one or more tertiary amine functions, quaternized.
(5) Polyaminoamide derivatives resulting from the condensation of polyalkylene polyamines with polycarboxylic acids followed by alkylation with difunctional agents. Mention may be made, for example, of adipic acid/dialkylaminohydroxyalkyldialkylenetriamine polymers in which the alkyl group comprises from 1 to 4 carbon atoms and preferably denotes methyl, ethyl or propyl. Among these derivatives, mention may be made more particularly of the adipic acid/dimethylaminohydroxypropyl/diethylenetriamine polymers sold under the name Cartaretine F, F4 or F8 by the company Sandoz.
(6) Polymers obtained by reaction of a polyalkylenepolyamine comprising two primary amine groups and at least one secondary amine group with a dicarboxylic acid chosen from diglycolic acid and saturated aliphatic dicarboxylic acids having from 3 to 8 carbon atoms； the molar ratio of polyalkylenepolyamine to dicarboxylic acid preferably being of between 0.8: 1 and 1.4: 1； the polyaminoamide resulting therefrom being reacted with epichlorohydrin in a molar ratio of epichlorohydrin in relation to the secondary amine group of the polyaminoamide preferably of between 0.5: 1 and 1.8: 1. Polymers of this type are sold in particular under the name Hercosett 57 by the company Hercules Inc. or alternatively under the name PD 170 or Delsette 101 by the company Hercules in the case of the adipic acid/epoxypropyl/diethylenetriamine copolymer.
(7) Cyclopolymers of alkyldiallylamine or of dialkyldiallylammonium, such as the homopolymers or copolymers comprising, as main constituent of the chain, units corresponding to formula (PI) or (PII) :
Figure PCTCN2015071080-appb-000005
in which:
-k and t are equal to 0 or 1, the sum k + t being equal to 1；
-R12 denotes a hydrogen atom or a methyl group；
-R10 and R11, independently of each other, denote an alkyl group containing from 1 to 6 carbon atoms, a hydroxyalkyl group in which the alkyl group contains 1 to 5 carbon atoms, a C1-C4 amidoalkyl group； or alternatively R10 and R11 may denote, together with the nitrogen atom to which they are attached, heterocyclic groups such as piperidyl or morpholinyl； R10 and R11, independently of each other, preferably denote an alkyl group containing from 1 to 4 carbon atoms；
-Y-is an anion such as bromide, chloride, acetate, borate, citrate, tartrate, bisulfate, bisulfite, sulfate or phosphate.
Mention may be made more particularly of the dimethyldiallylammonium salt (for example chloride) homopolymer for example sold under the name Merquat 100 by the company Nalco (and homologues thereof of low weight-average molar masses) and the copolymers of diallyldimethylammonium salts (for example chloride) and of acrylamide, sold in particular under the name Merquat 550 or Merquat 7SPR.
(8) quaternary diammonium polymers comprising repeating units of formula:
Figure PCTCN2015071080-appb-000006
in which:
-R13, R14, R15 and R16, which may be identical or different, represent  aliphatic, alicyclic or arylaliphatic groups comprising from 1 to 20 carbon atoms or C1-4 hydroxyalkylaliphatic groups, or else R13, R14, R15 and R16, together or separately, form, with the nitrogen atoms to which they are attached, heterocycles optionally comprising a second heteroatom other than nitrogen, or else R13, R14, R15 and R16 represent a linear or branched C 1-C6 alkyl group sub stituted by a nitrile, ester, acyl, amide or -CO-O-R17-D or -CO-NH-R17-D group, where R17 is an alkylene and D a quaternary ammonium group；
-A1 and B 1 represent divalent polymethylene groups comprising from 2 to 20 carbon atoms which may be linear or branched, and saturated or unsaturated, and which may contain, linked to or inserted in the main chain, one or more aromatic rings, or one or more oxygen or sulfur atoms or sulfoxide, sulfone, disulfide, amino, alkylamino, hydroxyl, quaternary ammonium, ureido, amide or ester groups, and
-X-denotes an anion derived from an inorganic or organic acid；
it being understood that A1, R13 and R15 can form, with the two nitrogen atoms to which they are attached, a piperazine ring.
In addition, if A1 denotes a saturated or unsaturated and linear or branched alkylene or hydroxyalkylene group, B 1 can also denote a (CH2) n-CO-D-OC- (CH2) n-group in which D denotes:
a) a glycol residue of formula -O-Z-O-, in which Z denotes a linear or branched hydrocarbon-based group, or a group corresponding to one of the following formulae: - (CH2-CH2-O) x-CH2-CH2-and - [CH2-CH(CH3) -O] y-CH2-CH (CH3) -, where x and y denote an integer from 1 to 4, representing a defined and unique degree of polymerization or any number from 1 to 4 representing an average degree of polymerization；
b) a bissecondary diamine residue, such as a piperazine derivative；
c) a bisprimary diamine residue of formula: -NH-Y-NH-, in which Y denotes a linear or branched hydrocarbon-based group, or else the divalent group -CH2-CH2-S-S-CH2-CH2-；
d) a ureylene group of formula: -NH-CO-NH-.
Preferably, X-is an anion, such as chloride or bromide. These polymers have a number-average molar mass (Mn) generally of between 1000 and 100 000. 
Mention may be made more particularly of polymers that are composed of repeating units corresponding to the formula:
Figure PCTCN2015071080-appb-000007
in which R1, R2, R3 and R4, which may be identical or different, denote an alkyl or hydroxyalkyl group having from 1 to 4 carbon atoms approximately, n and p are integers varying from 2 to 20 approximately and X-is an anion derived from an inorganic or organic acid.
A compound of formula (PIV) that is particularly preferred is the one for which R1, R2, R3 and R4 represent a methyl group and n ＝ 3, p ＝6 and X ＝ Cl, which is known as Hexadimethrine chloride according to the INCI (CTFA) nomenclature.
(9) Polyquaternary ammonium polymers comprising units of formula (PV) :
Figure PCTCN2015071080-appb-000008
in which:
-R18, R19, R20 and R21, which may be identical or different, represent a hydrogen atom or a methyl, ethyl, propyl, β-hydroxyethyl, β-hydroxypropyl or -CH2CH2 (OCH2CH2) pOH group, where p is equal to 0 or to an integer of between 1 and 6, with the proviso that R18, R19, R20 and R21 do not simultaneously represent a hydrogen atom,
-r and s, which may be identical or different, are integers between 1 and 6,
-q is equal to 0 or to an integer between 1 and 34,
-X-denotes an anion such as a halide,
-A denotes a radical of a dihalide or preferably represents -CH2-CH2-O-CH2-CH2-.
Examples that may be mentioned include the products
Figure PCTCN2015071080-appb-000009
A 15, 
Figure PCTCN2015071080-appb-000010
AD 1, 
Figure PCTCN2015071080-appb-000011
AZ 1 and
Figure PCTCN2015071080-appb-000012
175 sold by the company Miranol.
(10) Quaternary polymers of vinylpyrrolidone and of vinylimidazole, for instance the products sold under the names
Figure PCTCN2015071080-appb-000013
FC 905, FC 550 and FC 370 by the company BASF.
(11) Polyamines such as
Figure PCTCN2015071080-appb-000014
H sold by Cognis, referred to under the name Polyethylene glycol (15) tallow polyamine in the CTFA dictionary.
(12) Polymers comprising in their structure:
(a) one or more units corresponding to formula (A) below:
Figure PCTCN2015071080-appb-000015
(b) optionally one or more units corresponding to formula (B) below:
Figure PCTCN2015071080-appb-000016
In other words, these polymers may be chosen in particular from homopolymers or copolymers comprising one or more units derived from vinylamine and optionally one or more units derived from vinylformamide.
Preferably, these cationic polymers are chosen from polymers comprising, in their structure, from 5 mol％ to 100 mol％ of units corresponding to formula (A) and from 0 to 95 mol％ of units corresponding to formula (B) , preferentially from 10 mol％ to 100 mol％of units corresponding to formula (A) and from 0 to 90 mol％ of units corresponding to formula (B) .
These polymers may be obtained, for example, by partial hydrolysis of polyvinylformamide. This hydrolysis may be performed in an acidic or basic medium.
The weight-average molecular weight of said polymer, measured  by light scattering, may range from 1000 to 3 000 000 g/mol, preferably from 10 000 to 1 000 000 and more particularly from 100 000 to 500 000 g/mol.
The cationic charge density of these polymers may range from 2 to 20 meq/g, preferably from 2.5 to 15 meq/g and more particularly from 3.5 to 10 meq/g.
The polymers comprising units of formula (A) and optionally units of formula (B) are sold in particular under the name Lupamin by the company BASF, for instance, in a non-limiting manner, the products sold under the names Lupamin 9095, Lupamin 5095, Lupamin 1095, Lupamin 9030 (or Luviquat 9030) and Lupamin 9010.
Other cationic polymers that may be used in the context of the invention are cationic proteins or cationic protein hydrolysates, polyalkyleneimines, in particular polyethyleneimines, polymers comprising vinylpyridine or vinylpyridinium units, condensates of polyamines and of epichlorohydrin, quaternary polyureylenes and chitin derivatives.
Preferably, the cationic polymers are chosen from those of family (2) mentioned above. Particularly preferred cationic polymers for use in the compositions of the present invention are quaternized hydroxyalkylcelluloses such as quaternized hydroxyethylcelluloses. Most particularly preferred polymers are those known under the INCI name of Polyquaternium-10.
The composition of the invention preferably contains from 0.1 to 5％ by weight of cationic polymer (s) , more preferably from 0.2 to 2.5％by weight, with regard to the total weight of the composition.
The composition of the invention further comprises one or more amphoteric or zwitterionic surfactant (s) .
The amphoteric or zwitterionic surfactant (s) , which are preferably non-silicone, may especially be derivatives of aliphatic secondary or tertiary amines, optionally quaternized, in which derivatives the aliphatic group is a linear or branched chain comprising from 8 to 22 carbon atoms, the said amine derivatives  containing at least one anionic group, for instance a carboxylate, sulfonate, sulfate, phosphate or phosphonate group.
Mention may be made in particular of (C8-C20) alkylbetaines, (C8-C20) alkylsulfobetaines, (C8-C20) alkylamido (C3-C8) alkylbetaines and (C8-C20) alkylamido (C6-C8) alkylsulfobetaines.
Among the secondary or tertiary aliphatic amine derivatives optionally quaternized that may be used, as defined above, mention may also be made of the compounds having the respective structures (V) and (VI) below:
Ra-CONHCH2CH2-N+ (Rb) (Rc) -CH2COO-, M+ , X-   (V)
in which formula:
-Ra represents a C10-C30 alkyl or alkenyl group derived from an acid RaCOOH preferably present in hydrolysed coconut oil, or a heptyl, nonyl or undecyl group；
-Rb represents a beta-hydroxyethyl group； and
-Rc represents a carboxymethyl group；
-M+ represents a cationic counterion derived from an alkali metal or alkaline-earth metal, such as sodium, an ammonium ion or an ion derived from an organic amine, and
-X-represents an organic or mineral anionic counterion, such as that chosen from halides, acetates, phosphates, nitrates, (C1-C4)alkyl sulfates, (C1-C4) alkylsulfonates or (C1-C4) alkylarylsulfonates, in particular methyl sulfate and ethyl sulfate； or alternatively M+ and X-are absent；
Ra’ -CONHCH2CH2-N (B) (B')   (VI)
in which formula:
-B represents the group -CH2CH2OX'；
-B'represents the group - (CH2) zY', with z ＝ 1 or 2；
-X'represents the group -CH2COOH, -CH2-COOZ’ ,
-CH2CH2COOH, -CH2CH2-COOZ’ , or a hydrogen atom；
-Y'represents the group -COOH, -COOZ’ ,
-CH2CH (OH) SO3H or the group -CH2CH (OH) SO3Z’ ；
-Z'represents a cationic counterion derived from an alkali metal or alkaline-earth metal, such as sodium, an ammonium ion or an ion derived from an organic amine；
-Ra’ represents a C10-C30 alkyl or alkenyl group of an acid Ra’-COOH which is preferably present in coconut oil or in hydrolysed linseed oil, or an alkyl group, especially a C17 group, and its iso form, or an unsaturated C 17 group.
These compounds are classified in the CTFA dictionary, 5th edition, 1993, under the names disodium cocoamphodiacetate, disodium lauroamphodiacetate, disodium caprylamphodiacetate, disodium capryloamphodiacetate, disodium cocoamphodipropionate, disodium lauroamphodipropionate, disodium caprylamphodipropionate, disodium capryloamphodipropionate, lauroamphodipropionic acid and cocoamphodipropionic acid.
By way of example, mention may be made of the cocoamphodiacetate sold by the company Rhodia under the trade name 
Figure PCTCN2015071080-appb-000017
C2M Concentrate.
Use may also be made of the compounds of formula (VII) :
Ra” -NHCH (Y” ) - (CH2) nCONH (CH2) n’ -N (Rd) (Re)  (VII)
in which formula:
-Y″ represents the group -COOH, -COOZ” ,
-CH2CH (OH) SO3H or the group -CH2CH (OH) SO3Z” ；
-Rd and Re represent, independently of each other, a C1-C4 alkyl or hydroxyalkyl radical；
-Z″ represents a cationic counterion derived from an alkali metal or alkaline-earth metal, such as sodium, an ammonium ion or an ion derived from an organic amine；
-Ra″ represents a C 10-C30 alkyl or alkenyl group of an acid Ra″ -COOH which is preferably present in coconut oil or in hydrolysed linseed oil；
-n and n' denote, independently of each other, an integer ranging from 1 to 3.
Among the compounds of formula (VII) , mention may be made of the compound classified in the CTFA dictionary under the name sodium diethylaminopropyl cocoaspartamide and sold by the company Chimex under the name Chimexane HB.
These compounds may be used alone or as mixtures.
Among the amphoteric or zwitterionic surfactants mentioned above, use is preferably made of (C8-C20) alkylbetaines, (C8-C20) alkylsulfobetaines, (C8-C20) alkylamido (C3-C8) alkylbetaines and (C8-C20) alkylamido (C6-C8) alkylsulfobetaines, more preferably of (C8-C20) alkylbetaines and even more preferably of cocoylbetaine.
The composition of the invention preferably comprises said amphoteric or zwitterionic surfactant (s) in an amount of from 0.01 to 15％ by weight, more preferably from 0.1 to 10％ by weight, and even more preferably from 1 to 5％ by weight, based on the total weight of the composition.
The composition of the invention further comprises one or more non ionic surfactant (s) chosen from alkanolamides of C6-C30 fatty acids.
Such surfactants can be chosen from mono-alkanolamides and di-alcanolamides of C8-C30 fatty acids, and preferably from mono-alkanolamides and di-alcanolamides of C8-C18 fatty acids.
The alkanol groups may have from 1 to 10 carbon atoms, and preferably from 2 to 5 carbon atoms.
Mention may be made for example of cocamide monoethanolamine, cocamide diethanolamine, cocamide mono-isopropanolamine.
According to a particularly preferred embodiment, said non ionic surfactant is cocamide mono-isopropanolamine.
The composition of the invention preferably comprises said non ionic surfactant (s) chosen from alkanolamides of C6-C30 fatty acids in an amount ranging from 0.05 to 5 ％ by weight, more  preferably from 0.1 to 1 ％ by weight, with regard to the total weight of the composition.
The composition according to the invention further comprises one or more anionic surfactant (s) .
The term "anionic surfactant" means a surfactant comprising, as ionic or ionizable groups, only anionic groups. These anionic groups are preferably chosen from the following groups:
-COOH, -COO-, -SO3H, -SO3 -, -OSO3H, -OSO3 -, -PO2H2, -PO2H-, -PO2 2-, -P (OH) 2, ＝P (O) OH, -P (OH) O-, ＝P (O) O-, ＝POH, ＝PO-, the anionic parts comprising a cationic counterion such as an alkali metal, an alkaline-earth metal or an ammonium.
As examples of anionic surfactants that may be used in the composition according to the invention, mention may be made of alkyl sulfates, alkyl ether sulfates, alkylamido ether sulfates, alkylaryl polyether sulfates, monoglyceride sulfates, alkylsulfonates, alkylamidesulfonates, alkylarylsulfonates, α-olefin sulfonates, paraffin sulfonates, alkyl sulfosuccinates, alkyl ether sulfosuccinates, alkylamide sulfosuccinates, alkyl sulfoacetates, acylsarcosinates, acylglutamates, alkyl sulfosuccinamates, acylisethionates and N-acyltaurates, polyglycoside polycarboxylic acid and alkyl monoester salts, acyl lactylates, salts of D-galactoside uronic acids, salts of alkyl ether carboxylic acids, salts of alkylaryl ether carboxylic acids, salts of alkylamido ether carboxylic acids, and the corresponding non-salified forms of all these compounds； the alkyl and acyl groups of all these compounds comprising from 6 to 40 carbon atoms and the aryl group denoting a phenyl group.
These compounds can be oxyethylenated and then preferably comprise from 1 to 50 ethylene oxide units.
The salts of C6-C24 alkyl monoesters of polyglycoside-polycarboxylic acids may be chosen from C6-C24 alkyl polyglycoside-citrates, C6-C24 alkyl polyglycoside-tartrates and C6-C24 alkyl polyglycoside-sulfosuccinates.
When the anionic surfactant (s) are in salt form, they may be chosen from alkali metal salts such as the sodium or potassium salt  and preferably the sodium salt, ammonium salts, amine salts and in particular amino alcohol salts, or alkaline-earth metal salts such as the magnesium salts.
Examples of amino alcohol salts that may especially be mentioned include monoethanolamine, diethanolamine and triethanolamine salts, monoisopropanolamine, diisopropanolamine or triisopropanolamine salts, 2-amino-2-methyl-1-propanol salts, 2-amino-2-methyl-1, 3-propanediol salts and tris (hydroxymethyl) aminomethane salts.
Alkali metal or alkaline-earth metal salts, and in particular sodium or magnesium salts, are preferably used.
Preferred anionic surfactants are chosen from (C6-C30) alkyl sulfates, (C6-C30) alkyl ether sulfates, (C6-C30) alkylamido ether sulfates, alkylaryl polyether sulfates and monoglyceride sulphates, all these compounds optionally comprising from 1 to 20 ethylene oxide units； and more preferably from (C12-C20) alkyl sulphates and (C12-C20) alkyl ether sulfates comprising from 2 to 20 ethylene oxide units, and even more preferably from 1 to 4 ethylene oxide units, especially in the form of alkali metal, ammonium, amino alcohol and alkaline-earth metal salts, or a mixture of these compounds. Better still, it is preferred to use a polyoxyethylenated sodium lauryl ether sulphate, such as sodium lauryl ether sulphate containing 2 or 2.2 mol of ethylene oxide.
The amount of said anionic surfactant (s) in the composition of the invention is of at least 1.5％ by weight, more preferably at least 3％ by weight, with regard to the total weight of the composition. This amount preferably ranges from 5 to 30％ by weight, more preferably from 5 to 15％ by weight, with regard to the total weight of the composition.
The composition of the invention may further contain one or more additional non ionic surfactant (s) different from the above-described alkanolamides of C6-C30 fatty acids.
The nonionic surfactant (s) that may be used in the compositions are described, for example, in the Handbook of  Surfactants by M. R. Porter, published by Blackie &Son (Glasgow and London) , 1991, pp. 116-178.
Examples of nonionic surfactants that may be mentioned include the following nonionic surfactants:
-oxyalkylenated (C8-C24) alkylphenols；
-saturated or unsaturated, linear or branched, oxyalkylenated or glycerolated C8-C40 alcohols, comprising one or two fatty chains；
-saturated or unsaturated, linear or branched, oxyalkylenated C8-C30 fatty acid amides；
-esters of saturated or unsaturated, linear or branched, C8-C30 acids and of polyethylene glycols；
-esters of saturated or unsaturated, linear or branched, C8-C30 acids and of sorbitol, preferably oxyethylenated；
-fatty acid esters of sucrose；
-(C8-C30) alkyl (poly) glucosides, (C8-C30) alkenyl (poly) glucosides, which are optionally oxyalkylenated (0 to 10 oxyalkylene units) and comprising from 1 to 15 glucose units, (C8-C30) alkyl (poly) glucoside esters；
-saturated or unsaturated, oxyethylenated plant oils；
-condensates of ethylene oxide and/or of propylene oxide, inter alia, alone or as mixtures；
-N- (C8-C30) alkylglucamine and N- (C8-C30) acylmethylglucamine derivatives；
-aldobionamides；
-amine oxides；
-oxyethylenated and/or oxypropylenated silicones；
-and mixtures thereof.
The oxyalkylene units are more particularly oxyethylene or oxypropylene units, or a combination thereof, preferably oxyethylene units.
The number of moles of ethylene oxide and/or propylene oxide preferably ranges from 1 to 250, more particularly from 2 to 100 and better still from 2 to 50； the number of moles of glycerol ranges especially from 1 to 50 and better still from 1 to 10.
Advantageously, the nonionic surfactants according to the invention do not comprise any oxypropylene units.
As examples of glycerolated nonionic surfactants, use is preferably made of monoglycerolated or polyglycerolated C8-C40 alcohols, comprising from 1 to 50 mol of glycerol and preferably from 1 to 10 mol of glycerol.
As examples of compounds of this type, mention may be made of lauryl alcohol containing 4 mol of glycerol (INCI name: Polyglyceryl-4 Lauryl Ether) , lauryl alcohol containing 1.5 mol of glycerol, oleyl alcohol containing 4 mol of glycerol (INCI name: Polyglyceryl-4 Oleyl Ether) , oleyl alcohol containing 2 mol of glycerol (INCI name: Polyglyceryl-2 Oleyl Ether) , cetearyl alcohol containing 2 mol of glycerol, cetearyl alcohol containing 6 mol of glycerol, oleyl/cetyl alcohol containing 6 mol of glycerol, and octadecanol containing 6 mol of glycerol.
Among the glycerolated alcohols, it is more particularly preferred to use the C8/C10 alcohol containing 1 mol of glycerol, the C 10/C12 alcohol containing 1 mol of glycerol and the C12 alcohol containing 1.5 mol of glycerol.
The additional nonionic surfactant (s) , when they are present in the composition of the invention, are preferably present in a total amount ranging from 0.01 to 1％ by weight, with regard to the total weight of the composition.
The composition of the invention may further comprise one or more cationic surfactants.
The term "cationic surfactant" means a surfactant that is positively charged when it is contained in the composition according to the invention. This surfactant may bear one or more positive permanent charges or may contain one or more cationizable functions in the compositions.
The cationic surfactant (s) are preferably chosen from optionally polyoxyalkylenated, primary, secondary or tertiary fatty amines, or salts thereof, and quaternary ammonium salts, and mixtures thereof.
The fatty amines generally comprise at least one C8-C30 hydrocarbon-based chain.
Among the quaternary ammonium cationic surfactants, those that are preferred are:
-tetraalkylammonium salts, for instance dialkyldimethylammonium or alkyltrimethylammonium salts in which the alkyl group contains approximately from 12 to 22 carbon atoms, in particular behenyltrimethylammonium, distearyldimethylammonium, cetyltrimethylammonium or benzyldimethylstearylammonium salts, or, on the other hand, the palmitylamidopropyltrimethylammonium salt, the stearamidopropyltrimethylammonium salt, the stearamidopropyldimethylcetearylammonium salt, or the stearamidopropyldimethyl (myristyl acetate) ammonium salt sold under the name
Figure PCTCN2015071080-appb-000018
70 by the company Van Dyk. It is particularly preferred to use the chloride salts of these compounds.
-quaternary ammonium salts of imidazoline for example, sold under the name
Figure PCTCN2015071080-appb-000019
W 75 by the company Rewo；
-di-or triquaternary ammonium salts, for example, Finquat CT-P, available from the company Finetex (Quaternium 89) , and Finquat CT, available from the company Finetex (Quaternium 75) .
-quaternary ammonium salts containing at least one ester function, such as diacyloxyethyldimethylammonium, diacyloxyethyl (hydroxyethyl) methylammonium, monoacyloxyethyldi (hydroxyethyl) methylammonium, triacyloxyethylmethylammonium or monoacyloxyethyl (hydroxyethyl) dimethylammonium salts (in particular chloride or methyl sulfate) , and mixtures thereof. The acyl groups preferably contain 14 to 18 carbon atoms and are obtained more particularly from a vegetable oil, such as palm oil or sunflower oil. When the compound contains several acyl groups, these groups may be identical or different.
Such compounds are, for example, sold under the names 
Figure PCTCN2015071080-appb-000020
by the company Henkel, 
Figure PCTCN2015071080-appb-000021
by the company  Stepan, 
Figure PCTCN2015071080-appb-000022
by the company Ceca or
Figure PCTCN2015071080-appb-000023
WE 18 by the company Rewo-Witco.
The composition according to the invention may contain, for example, a mixture of quaternary ammonium monoester, diester and triester salts with a weight maj ority of diester salts.
Use may also be made of the ammonium salts containing at least one ester function that are described in patents US-A-4 874 554 and US-A-4 137 180.
Use may be made of behenoylhydroxypropyltrimethylammonium chloride, provided by Kao under the name Quatarmin BTC 131.
Preferably, the ammonium salts containing at least one ester function contain two ester functions.
Among the quaternary ammonium salts containing at least one ester function, which can be used, it is preferred to use dipalmitoylethylhydroxyethylmethylammonium salts.
The composition of the present invention may further contain one or more fatty substances.
The term “fatty sub stance” means an organic compound that is insoluble in water at ordinary temperature (25℃) and at atmospheric pressure (760 mmHg) (solubility of less than 5％ by weight, preferably less than 1％ and even more preferentially less than 0.1％) . They have in their structure at least one hydrocarbon-based chain comprising at least 6 carbon atoms or a sequence of at least two siloxane groups. In addition, the fatty substances are generally soluble in organic solvents under the same temperature and pressure conditions, for instance chloroform, dichloromethane, carbon tetrachloride, ethanol, benzene,toluene, tetrahydrofuran (THF) , liquid petroleum j elly or decamethylcyclopentasiloxane.
More particularly, the fatty substances are chosen from C6-C16 hydrocarbons, hydrocarbons containing more than 16 carbon atoms, non-silicone oils of animal origin, plant or synthetic oils of triglyceride type, fluoro oils, fatty alcohols, fatty acid and/or fatty alcohol esters other  than triglycerides and plant waxes, non-silicone waxes other than fatty alcohols, and silicones, and mixtures thereof.
According to a preferred embodiment, the composition of the invention contains one or more oils, that is to say one or more fatty substance (s) that are liquid at room temperature (25℃) and at atmospheric pressure (760 mmHg； i.e. 1.013×105 Pa) .
Preferably, the oil (s) are chosen from linear or branched liquid hydrocarbons, of mineral or synthetic origin, containing more than 16 carbon atoms, and especially liquid petroleum jelly, hydrogenated polyisobutene, C6-C16 alkanes； triglyceride oils of plant origin； liquid fatty acid and/or fatty alcohol esters； liquid fatty alcohols； and mixtures thereof.
Particularly preferred oils are chosen from liquid fatty alcohols comprising from 8 to 20 carbon atoms. A most particularly preferred oil is octyldodecanol.
The fatty substances may be present in an amount ranging from 0.05％ to 10％ by weight, preferably from 0.1％ to 10％ by weight, better still from 0.2％ to 5％ by weight, even better still from 0.2％ to 2％ by weight, relative to the total weight of the composition.
The composition according to the invention advantageously comprises water, in a content of greater than or equal to 40％ by weight relative to the total weight of composition.
The water content in the composition of the invention preferably ranges from 40％ to 95％ by weight, more preferentially from 40％ to 80％ by weight, relative to the total weight of the composition.
The composition according to the invention may also comprise one or more water-soluble organic solvents (solubility of greater than or equal to 5％ in water at 25℃ and at atmospheric pressure) .
Examples of water-soluble organic solvents that may be mentioned include linear or branched and preferably saturated monoalcohols or diols, comprising 2 to 10 carbon atoms, such as ethyl alcohol, isopropyl alcohol, hexylene glycol (2-methyl-2, 4-pentanediol) , neopentyl glycol and 3-methyl-1, 5-pentanediol, butylene glycol,  dipropylene glycol and propylene glycol； aromatic alcohols such as phenylethyl alcohol； polyols containing more than two hydroxyl functions, such as glycerol； polyol ethers, for instance ethylene glycol monomethyl, monoethyl and monobutyl ether, propylene glycol or ethers thereof, for instance propylene glycol monomethyl ether； and also diethylene glycol alkyl ethers, especially C 1-C4 alkyl ethers, for instance diethylene glycol monoethyl ether or monobutyl ether, alone or as a mixture.
The water-soluble organic solvents, when they are present, generally represent between 1％ and 20％ by weight relative to the total weight of the composition according to the invention, and preferably between 5％ and 10％ by weight.
The composition according to the invention preferably further comprises one or more alkaline agents.
The alkaline agent (s) can especially be chosen from aqueous ammonia, alkali metal carbonates or bicarbonates, organic amines with a pKb at 25℃ of less than 12, in particular less than 10 and even more advantageously less than 6； from the salts of the amines mentioned previously with acids such as carbonic acid or hydrochloric acid: it should be noted that it is the pKb corresponding to the function of highest basicity.
Preferably, the amines are chosen from alkanolamines, in particular comprising a primary, secondary or tertiary amine function, and one or more linear or branched C 1-C8 alkyl groups bearing one or more hydroxyl radicals； from oxyethylenated and/or oxypropylenated ethylenediamines, and from amino acids and compounds having the following formula:
Figure PCTCN2015071080-appb-000024
in which W is a C 1-C6 alkylene residue optionally substituted with a hydroxyl group or a C1-C6 alkyl radical； Rx, Ry, Rz and Rt, which may be identical or different, represent a hydrogen atom or a C 1-C6 alkyl, C1-C6 hydroxyalkyl or C1-C6 aminoalkyl radical. 
According to one embodiment of the invention, the composition according to the invention comprises aqueous ammonia and/or at least one alkanolamine and/or at least one basic amino acid, more advantageously aqueous ammonia and/or at least one alkanolamine, such as monoethanolamine, or mixtures thereof.
Advantageously, the content of alkaline agent (s) ranges from 0.01％ to 30％ by weight, preferably from 0.1％ to 20％ by weight and better still from 1％ to 10％ by weight relative to the total weight of the composition. It should be noted that this content is expressed as NH3 when the alkaline agent is aqueous ammonia.
The pH of composition of the invention is preferably greater than or equal to 8, preferably ranges from 8 to 12, and more preferably from 9 to 11.
It can be adjusted by adding acidifying agents, such as hydrochloric acid, (ortho) phosphoric acid, sulfuric acid, boric acid, and also carboxylic acids, for instance acetic acid, lactic acid or citric acid, or sulfonic acids. Alkaline agents such as those previously mentioned may also be used.
The composition according to the may also comprise one or more direct dyes.
Examples of particularly suitable direct dyes that may be mentioned include nitrobenzene dyes； azo direct dyes； azomethine direct dyes； methine direct dyes； azacarbocyanin direct dyes, for instance tetraazacarbocyanines (tetraazapentamethines) ； quinone and in particular anthraquinone, naphthoquinone or benzoquinone direct dyes； azine direct dyes； xanthene direct dyes； triarylmethane direct dyes； indoamine direct dyes； indigoid direct dyes； phthalocyanine direct dyes, porphyrin direct dyes and natural direct dyes, alone or as mixtures. In particular, mention may be made of direct dyes from among: azo； methine； carbonyl； azine； nitro (hetero) aryl； tri(hetero) arylmethane； porphyrin； phthalocyanine and natural direct dyes, alone or as mixtures.
The direct dye (s) may represent from 0.0001％ to 10％ by weight and preferably from 0.005％ to 5％ by weight relative to the total weight of the composition.
The composition according to the invention may also comprise one or more cosmetic adjuvants.
For example, the composition may comprise one or more additives that are well known in the art, such as anionic, nonionic or amphoteric polymers or mixtures thereof, agents for preventing hair loss, vitamins and provitamins including panthenol, sunscreens, mineral or organic pigments, sequestrants, plasticizers, solubilizers, acidifying agents, mineral or organic thickeners, especially polymeric thickeners, opacifiers, antioxidants, hydroxy acids, nacreous agents, fragrances and preserving agents.
Needless to say, a person skilled in the art will take care to select this or these optional additional compound (s) such that the advantageous properties intrinsically associated with the invention are not, or are not substantially, adversely affected by the envisaged addition (s) .
The above adjuvants may generally be present in an amount, for each of them, of between 0 and 20％ by weight relative to the total weight of the composition.
According to one embodiment of the invention, the composition further comprises one or more oxidizing agents. The composition is then said to be "ready to use"in the sense that it does not require the use of a separate oxidizing composition.
Advantageously, the oxidizing agent (s) used in the context of the invention are chemical oxidizing agents other than atmospheric oxygen.
The said oxidizing agent (s) are preferably chosen from the group formed by hydrogen peroxide, urea peroxide, alkali metal bromates or ferricyanides, peroxygenated salts, for instance persulfates, perborates, peracids and precursors thereof and alkali metal or alkaline-earth metal percarbonates, and most particularly hydrogen peroxide.
The oxidizing agent (s) may represent from 0.01％ to 20％, preferably from 0.1％ to 10％ and better still from 2％ to 8％ by weight, relative to the total weight of the composition.
The compositions according to the invention may be in the form of fluid or thickened liquids, gels or creams.
They advantageously have a viscosity, measured at ambient temperature and atmospheric pressure, ranging from 10 to 100 UD, preferably from 20 to 80 UD, and even more preferably from 50 to 70 UD, when using rotor 3 under 200 rpm for 30 seconds. The viscosity of the composition of the present invention is measured using a ProRheo R180 machine from the company Prorheo, Roter 3 is used adapted to the viscosity of the composition to be tested (rotor is chosen for having a measure between 10 and 100 for UD Unit Deviation) , the measure being made after 30 seconds rotating the rotor inside the composition, with a shear rate from 200s-1. The UD values may then be converted in Poises (1 Poise＝ 0.1Pa. s) with a correspondence table.
The invention also relates to the use of the composition as described above for dyeing keratin fibres, in particular the hair.
Another subject of the invention is a process for dyeing human keratin fibres, in particular the hair, using the composition as described above.
According to a first preferred embodiment of the invention, the composition is "ready to use", i.e. it already contains at least one oxidizing agent.
In this case, the dyeing process of the invention consists in applying the "ready-to-use"composition to the keratin fibres.
According to a second preferred embodiment, the dyeing process of the invention consists in applying the composition as described above to the keratin fibres, the said composition being applied with a separate oxidizing composition.
The oxidizing composition that is used in this embodiment of the process of the invention comprises one or more oxidizing agents.
The oxidizing agent (s) of the oxidizing composition are as defined above, ie, they are preferably chosen from the group formed by hydrogen peroxide, urea peroxide, alkali metal bromates or ferricyanides, peroxygenated salts, for instance persulfates, perborates, peracids and precursors thereof and alkali metal or alkaline-earth metal percarbonates, and most particularly hydrogen peroxide.
The oxidizing agent (s) may represent from 0.01％ to 20％, preferably from 0.1％ to 10％ and better still from 2％ to 8％by weight, relative to the total weight of the oxidizing composition.
In one variant of the second embodiment above, the composition according to the invention is mixed at the time of use with the oxidizing composition as described above.
More particularly, by “mixed” it is intended to mean the action of putting the composition of the present invention into a container or palm, together with the oxidizing composition as described above, with or without stirring them.
According to a preferred variant of the second embodiment, the composition of the present invention is put into a container or palm together with the oxidizing composition as described above, without stirring them.
Indeed, due to the very good foaming properties of the composition of the invention, it is particularly advantageous and convenient to apply onto the keratin fibers the composition of the invention and an oxidizing composition without the need of stirring them in a container or palm, but apply them directly on the hair, and allow the mixture thus formed onto the hair to foam for example by massaging with the fingers.
Irrespective of the process used and the number of compositions used, the composition (s) described previously, optionally mixed beforehand, are applied to wet or dry keratin fibres.
The composition (s) are usually left in place on the fibres for a time generally ranging from 1 minute to 1 hour and preferably from 5 minutes to 30 minutes.
The temperature during the process is conventionally between 20 and 80℃ and preferably between 20 and 60℃. After the treatment, the human keratin fibres are advantageously rinsed with water. They may optionally be further washed with a shampoo, followed by rinsing with water, before being dried or left to dry.
The process may be repeated several times in order to obtain the desired coloration.
Another subj ect of the invention concerns a multi-compartment device, or a kit for dyeing keratin fibres, comprising at least two compartments:
-a first compartment containing a dyeing composition as described above； and
-a second compartment containing an oxidizing composition as described above.
According to one variant of the invention, the kit also comprises an additional compartment containing an additional composition comprising one or more treating agents.
The compositions of the kit are packaged in separate compartments, which may be optionally accompanied by suitable identical or different application means, such as fine brushes, coarse brushes or sponges.
The abovementioned kit may also be equipped with means allowing the delivery to the hair of the desired mixture, such as, for example, the device described in patent FR 2 586 913.
The examples that follow are given purely as illustrations of the present invention.
EXAMPLES:
Example 1
The dyeing compositions hereunder were prepared, from the ingredients indicated in the table below (in which the contents are  indicated in grams of active material with regard to the total weight of the composition) :
Figure PCTCN2015071080-appb-000025
Composition C4 corresponds to the invention, whereascompositions C 1 to C3 correspond to comparative compositions.
The compositions above were tested with regard to thefollowing properties:
Stability on storage of the composition: Stability on storagewas performed by leaving the compositions C 1 to C4 at 4℃, roomtemperature (25℃) , and 45℃ for 2 months. Then C 1 to C4 were leftunder 37℃ for 6 months to evaluate the long term stabilities.
Viscosity of the composition: The viscosities of the compositions C1 to C4 were measured at 25℃, using a ProRheo R180 machine from the company Prorheo, Roter 3 was used adapted to the viscosity of the product to be tested (rotor is chosen for having a measure between 10 and 100 for UD Unit Deviation) , the measure being made after 30 seconds rotating the rotor inside the composition, with a shear rate from 200s-1. The UD values may then be converted in Poises (1 Poise＝ 0.1Pa. s) with a correspondence table.
Ease of application onto the keratin fibers: The ease of application onto hair of the compositions C1 to C4 was measured by 3 hair dressers using the compositions C1 to C4 for dyeing the hair. 30g of the compositions C1 to C4 were poured in the palm of the hair dressers, respectively, together with same amount of an oxidizer containing 6％ of hydrogen peroxide. Without mixing, the hair dressers applied the products (compositions C1 to C4 mixing with oxidizers) immediately onto the middle-length hair, i.e., hair length is at the shoulder. The hair were massaged and foam was formed. After 15 minutes, the hair with the products mentioned above were rinsed with water.
For each property, a score was attributed to each composition on a scale ranging from 1 to 5 as follows
1:very bad
2:not good
3:acceptable
4:good
5 perfect
The results are given in the table hereunder:
Properties C1 C2 C3 C4
Viscosity 3 1 1 4
Stability 1 1 1 4
Application 4 1 1 5
The results hereabove clearly show that the particular combination of surfactants of the composition of the invention allows achieving superior performances in terms of working qualities and stability.
Example 2
A dyeing composition in accordance with the invention was prepared, from the ingredients indicated in the table below (in which the contents are indicated in grams of active material with regard to the total weight of the composition) :
Composition A
2, 4-diaminophenoxyethanol, HCl 0.60
Resorcinol 1.70
m-aminophenol 0.2
p-phenylenediamine 2
Sodium laureth sulfate (2 OE)  10.0
Cocoylbetaine 3.0
Cocamide mono-isopropanolamine 0.3
Polyquaternium-10 0.8
PEG-120 methyl glucose dioleate 0.1
Polysorbate 21 0.2
Octyldodecanol 0.40
Ethanolamine 2.40
Glycerin 5
Ascorbic acid 0.25
Sodium metabisulfite 0.7
EDTA 0.1
Fragrance qs
Water qs 100 g
30g of the composition prepared above was poured in a palm together with 30g of an oxidizer containing 6％ of hydrogen peroxide. Without mixing, the compositions were applied immediately onto the middle-length hair, i.e., hair length is at the shoulder. The hair was massaged and foam was formed. After 15 minutes, the hair was rinsed with water.
The viscosity of the composition mentioned above is 63.8 UD, using the measurement method disclosed in example 1 above. It allows the composition staying in the palm without floating away. And furthermore, when mixing with the oxidizer on the hair, it allows the mixture and the foam staying on the hair without dropping or flying.
The turbidity of the composition mentioned above is 6 NTU, using the measurement method disclosed in the above description.
It is a clear and transparent composition, which is very pleasant to the consumers.
The composition mentioned above is stable over 2 months under 4℃, room temperature, and 45℃.
Inventors observed that without waiting for a long period of time, the hair was dyed as expected. Within 15 minutes staying on the hair, the gray hair was covered perfectly.

Claims (21)

  1. Cosmetic composition for the oxidation dyeing of keratin fibres comprising:
    a) one or more oxidation dye (s) ,
    b) one or more cationic polymer (s) ,
    c) one or more amphoteric or zwitterionic surfactant (s) ,
    d) one or more non ionic surfactant (s) chosen from alkanolamides of C6-C30 fatty acids, and
    e) one or more anionic surfactant (s) , in an amount of at least 1.5％by weight, with regard to the total weight of the composition.
  2. Composition according to Claim 1, characterized in that the oxidation dye (s) comprise one or more oxidation bases, preferably chosen from para-phenylenediamines, bis (phenyl) alkylenediamines, para-aminophenols, ortho-aminophenols, heterocyclic bases, and the addition salts thereof, and mixtures thereof.
  3. Composition according to the preceding claim, characterized in that the oxidation base (s) represent from 0.0001％to 10％by weight, preferably from 0.005％to 5％by weight and better still from 0.1％to 5％by weight relative to the total weight of the composition.
  4. Composition according to any one of the preceding claims, characterized in that the oxidation dye (s) comprise one or more couplers, preferably chosen from meta-phenylenediamines, meta-aminophenols, meta-diphenols, naphthalene-based couplers, heterocyclic couplers, and the addition salts thereof, and mixtures thereof.
  5. Composition according to the preceding claim, characterized in that the said coupler (s) represent from 0.0001％to 10％by weight, preferably from 0.005％to 5％by weight, relative to the total weight of the composition.
  6. Composition according to any one of the preceding claims, characterized in that the cationic polymers are chosen from:
    (1) homopolymers or copolymers derived from acrylic or methacrylic  esters or amides and comprising at least one of the units of the following formulae:
    Figure PCTCN2015071080-appb-100001
    in which:
    -R3, which may be identical or different, denote a hydrogen atom or a CH3 group；
    -A, which may be identical or different, represent a linear or branched divalent alkyl group of 1 to 6 carbon atoms, preferably 2 or 3 carbon atoms, or a hydroxyalkyl group of 1 to 4 carbon atoms；
    -R4, R5 and R6, which may be identical or different, represent an alkyl group containing from 1 to 18 carbon atoms or a benzyl group, and preferably an alkyl group containing from 1 to 6 carbon atoms；
    -R1 and R2, which may be identical or different, represent a hydrogen atom or an alkyl group containing from 1 to 6 carbon atoms, and preferably methyl or ethyl；
    -X denotes an anion derived from an inorganic or organic acid, such as a methosulfate anion or a halide such as chloride or bromide；
    (2) Cationic polysaccharides, in particular cationic celluloses and cationic galactomannan gums；
    (3) Polymers composed of piperazinyl units and of divalent alkylene or hydroxyalkylene groups containing linear or branched chains, optionally interrupted by oxygen, sulfur or nitrogen atoms or by aromatic or heterocyclic rings, and also the oxidation and/or quaternization products of these polymers；
    (4) Water-soluble polyaminoamides prepared in particular by polycondensation of an acidic compound with a polyamine； these polyaminoamides being optionally crosslinked by an epihalohydrin, a diepoxide, a dianhydride, an unsaturated dianhydride, a bisunsaturated derivative, a bishalohydrin, a bisazetidinium, a bishaloacyldiamine or an alkyl bishalide or alternatively by an oligomer resulting from the reaction of a bifunctional compound reactive with respect to a bishalohydrin, a bisazetidinium, a bishaloacyldiamine, an alkyl bishalide, an epihalohydrin, a diepoxide or a bisunsaturated derivative； these polyaminoamides being optionally alkylated or, if they comprise one or more tertiary amine functions, quaternized；
    (5) Polyaminoamide derivatives resulting from the condensation of polyalkylene polyamines with polycarboxylic acids followed by alkylation with difunctional agents；
    (6) Polymers obtained by reaction of a polyalkylenepolyamine comprising two primary amine groups and at least one secondary amine group with a dicarboxylic acid chosen from diglycolic acid and saturated aliphatic dicarboxylic acids having from 3 to 8 carbon atoms； the molar ratio of polyalkylenepolyamine to dicarboxylic acid preferably being of between 0.8: 1 and 1.4: 1； the polyaminoamide resulting therefrom being reacted with epichlorohydrin in a molar ratio of epichlorohydrin in relation to the secondary amine group of the polyaminoamide preferably of between 0.5: 1 and 1.8: 1；
    (7) Cyclopolymers of alkyldiallylamine or of dialkyldiallylammonium, such as the homopolymers or copolymers comprising, as main constituent of the chain, units corresponding to formula (PI) or (PII) :
    Figure PCTCN2015071080-appb-100002
    in which:
    -k and t are equal to 0 or 1, the sum k + t being equal to 1；
    -R12 denotes a hydrogen atom or a methyl group；
    -R10 and R11, independently of each other, denote an alkyl group containing from 1 to 6 carbon atoms, a hydroxyalkyl group in which the alkyl group contains 1 to 5 carbon atoms, a C1-C4 amidoalkyl group； or alternatively R10 and R11 may denote, together with the nitrogen atom to which they are attached, heterocyclic groups such as piperidyl or morpholinyl； R10 and R11, independently of each other, preferably denote an alkyl group containing from 1 to 4 carbon atoms；
    -Y- is an anion such as bromide, chloride, acetate, borate, citrate, tartrate, bisulfate, bisulfite, sulfate or phosphate；
    (8) quaternary diammonium polymers comprising repeating units of formula:
    Figure PCTCN2015071080-appb-100003
    in which:
    -R13, R14, R15 and R16, which may be identical or different, represent aliphatic, alicyclic or arylaliphatic groups comprising from 1 to 20 carbon atoms or C1-4 hydroxyalkylaliphatic groups, or else R13, R14, R15 and R16, together or separately, form, with the nitrogen atoms to which they are attached, heterocycles optionally comprising a second heteroatom other than nitrogen, or else R13, R14, R15 and R16 represent a linear or branched C1-C6 alkyl group sub stituted by a nitrile, ester, acyl,  amide or -CO-O-R17-D or -CO-NH-R17-D group, where R17 is an alkylene and D a quaternary ammonium group；
    -A1 and B1 represent divalent polymethylene groups comprising from 2 to 20 carbon atoms which may be linear or branched, and saturated or unsaturated, and which may contain, linked to or inserted in the main chain, one or more aromatic rings, or one or more oxygen or sulfur atoms or sulfoxide, sulfone, disulfide, amino, alkylamino, hydroxyl, quaternary ammonium, ureido, amide or ester groups, and
    -X- denotes an anion derived from an inorganic or organic acid；
    it being understood that A1, R13 and R15 can form, with the two nitrogen atoms to which they are attached, a piperazine ring；
    (9) Polyquaternary ammonium polymers comprising units of formula (PV) :
    Figure PCTCN2015071080-appb-100004
    in which:
    -R18, R19, R20 and R21, which may be identical or different, represent a hydrogen atom or a methyl, ethyl, propyl, β-hydroxyethyl, β-hydroxypropyl or -CH2CH2 (OCH2CH2) pOH group, where p is equal to 0 or to an integer of between 1 and 6, with the proviso that R18, R19, R20 and R21 do not simultaneously represent a hydrogen atom,
    -r and s, which may be identical or different, are integers between 1 and 6,
    -q is equal to 0 or to an integer between 1 and 34,
    -X- denotes an anion such as a halide,
    -A denotes a radical of a dihalide or preferably represents -CH2-CH2-O-CH2-CH2-；
    (10) Quaternary polymers of vinylpyrrolidone and of vinylimidazole；
    (11) Polyamines；
    (12) Polymers comprising in their structure:
    (a) one or more units corresponding to formula (A) below:
    Figure PCTCN2015071080-appb-100005
    (b) optionally one or more units corresponding to formula (B) below:
    Figure PCTCN2015071080-appb-100006
    and preferably the cationic polymer (s) are chosen from those of family (2) mentioned above.
  7. Composition according to the preceding claim, characterized in that the cationic polymer (s) are chosen from quaternized hydroxyalkylcelluloses, more preferably from quaternized hydroxyethylcelluloses and even more preferably from hydroxyethyl cellulose-2-hydroxypropyl trimethyl ammonium chloride ether.
  8. Composition according to any one of the preceding claims, characterized in that it contains from 0.1 to 5％by weight of cationic polymer (s) , more preferably from 0.2 to 2.5％by weight, with regard to the total weight of the composition.
  9. Composition according to any one of the preceding claims, characterized in that the amphoteric or zwitterionic surfactant (s) are chosen from (C8-C20) alkylbetaines, (C8-C20) alkylsulfobetaines, (C8-C20) alkylamido (C3-C8) alkylbetaines and (C8-C20) alkylamido (C6-C8)alkylsulfobetaines, more preferably from (C8-C20) alkylbetaines and even more preferably the composition comprises cocoylbetaine.
  10. Composition according to any one of the preceding claims, characterized in that said amphoteric or zwitterionic surfactant (s) are present in an amount of from 0.01 to 15％by weight, preferably from 0.1 to 10％by weight, and more preferably from 1 to 5％by weight, based on the total weight of the composition.
  11. Composition according to any one of the preceding claims, characterized in that said non ionic surfactant (s) are chosen from mono-alkanolamides and di-alcanolamides of C8-C30 fatty acids, preferably from mono-alkanolamides and di-alcanolamides of C8-C18 fatty acids and  even more preferably the composition comprises cocamide mono-isopropanolamine.
  12. Composition according to any one of the preceding claims, characterized in that it comprises said non ionic surfactant (s) chosen from alkanolamides of C6-C30 fatty acids in an amount ranging from 0.05 to 5 ％by weight, preferably from 0.1 to 1 ％by weight, with regard to the total weight of the composition.
  13.  Composition according to any one of the preceding claims, characterized in that said anionic surfactants are chosen from (C6-C30) alkyl sulfates, (C6-C30) alkyl ether sulfates, (C6-C30) alkylamido ether sulfates, alkylaryl polyether sulfates and monoglyceride sulphates, all these compounds optionally comprising from 1 to 20 ethylene oxide units； and more preferably from (C12-C20) alkyl sulphates and (C12-C20) alkyl ether sulfates comprising from 2 to 20 ethylene oxide units, and even more preferably from 1 to 4 ethylene oxide units, especially in the form of alkali metal, ammonium, amino alcohol and alkaline-earth metal salts, or a mixture of these compounds.
  14. Composition according to any one of the preceding claims, characterized in that it comprises said anionic surfactant (s) in an amount of at least 3％by weight, and preferably in an amount ranging from 5 to 30％by weight, more preferably from 5 to 15％by weight, with regard to the total weight of the composition.
  15. Composition according to any one of the preceding claims, characterized in that it further comprises one or more fatty substances preferably chosen from oils, and more preferably chosen from liquid fatty alcohols comprising from 8 to 20 carbon atoms, and even more preferably the composition comprises octyldodecanol.
  16. Composition according to the preceding claim, characterized in that it contains said fatty substance (s) in an amount ranging from 0.05％to 10％by weight, preferably from 0.1％to 10％by weight, better still from 0.2％to 5％by weight, even better still from 0.2％to 2％by weight, relative to the total weight of the composition.
  17. Composition according to any one of the preceding claims, characterized in that it further comprises one or more oxidizing agents,  preferably chosen from the group formed by hydrogen peroxide, urea peroxide, alkali metal bromates or ferricyanides, peroxygenated salts, for instance persulfates, perborates, peracids and precursors thereof and alkali metal or alkaline-earth metal percarbonates, and more preferably hydrogen peroxide.
  18. Process for dyeing human keratin fibres, in particular the hair, wherein the composition as defined in claim 17 is applied onto said keratin fibres.
  19. Process for dyeing human keratin fibres, in particular the hair, wherein a composition as defined in anyone of claims 1 to 16 is applied onto said keratin fibres sequentially to or simultaneously with a separate oxidizing composition comprising one or more oxidizing agents preferably chosen from the group formed by hydrogen peroxide, urea peroxide, alkali metal bromates or ferricyanides, peroxygenated salts, for instance persulfates, perborates, peracids and precursors thereof and alkali metal or alkaline-earth metal percarbonates, and most particularly hydrogen peroxide.
  20. The process of the preceding claim, wherein the composition as defined in anyone of claims 1 to 16 is applied to the keratin fibres with an oxidizing composition, preferably without stirring them.
  21. Kit for the oxidation dyeing keratin fibres, comprising at least two compartments:
    -a first compartment containing a dyeing composition as defined in anyone of claims 1 to 16； and
    -a second compartment containing an oxidizing composition as defined in claim 19.
PCT/CN2015/071080 2015-01-20 2015-01-20 Cosmetic composition for the oxidation dyeing of keratin fibres comprising a cationic polymer and a particular combination of surfactants WO2016115674A1 (en)

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MX2017009500A MX2017009500A (en) 2015-01-20 2015-01-20 Cosmetic composition for the oxidation dyeing of keratin fibres comprising a cationic polymer and a particular combination of surfactants.
PCT/CN2015/071080 WO2016115674A1 (en) 2015-01-20 2015-01-20 Cosmetic composition for the oxidation dyeing of keratin fibres comprising a cationic polymer and a particular combination of surfactants
CN201580078087.7A CN107427426A (en) 2015-01-20 2015-01-20 The cosmetic composition of the oxidising dyeing for keratin fiber of particular combination comprising cationic polymer and surfactant
BR112017015526-5A BR112017015526B1 (en) 2015-01-20 2015-01-20 cosmetic composition for the oxidation dyeing of keratin fibers, process for the dyeing of human keratin fibers and kit for the oxidation dyeing of keratin fibers

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WO2018056235A1 (en) * 2016-09-20 2018-03-29 L'oreal Composition for keratin fibers
WO2021124348A1 (en) * 2019-12-20 2021-06-24 L'ORéAL S.A. Multiple-compartment device comprising at least one internal frangible seal containing a keratin fibers dyeing composition
FR3146068A1 (en) * 2023-02-27 2024-08-30 L'oreal DYE COMPOSITION FOR DYEING KERATIN FIBERS AND DYEING KIT CONTAINING THE SAME
US12144878B2 (en) 2019-12-20 2024-11-19 L'oreal Multiple-compartment device comprising at least one internal frangible seal containing a keratin fibers dyeing composition

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FR3082739B1 (en) * 2018-06-20 2020-05-29 L'oreal HAIR COLORING PROCESS USING A COLORING COMPOSITION AND AN OXIDIZING COMPOSITION, SAID COMPOSITIONS COMPRISING A SCLEROGLUCAN GUM.
CN113646479B (en) * 2019-01-17 2023-06-13 埃斯普投资有限公司 Method for strengthening non-keratin fibers and use thereof

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EP1905421A1 (en) * 2006-09-29 2008-04-02 Kao Corporation Hair dye composition

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TWI422394B (en) * 2007-10-24 2014-01-11 Kao Corp Two-part hair dye
BR112015002202B1 (en) * 2012-08-02 2019-10-22 Oreal keratin fiber dyeing composition, keratin fiber dyeing process and device

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US20020157191A1 (en) * 2001-02-23 2002-10-31 Stephen Casperson Two-part aqueous composition for oxidative coloration of hair
EP1905421A1 (en) * 2006-09-29 2008-04-02 Kao Corporation Hair dye composition

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018056235A1 (en) * 2016-09-20 2018-03-29 L'oreal Composition for keratin fibers
WO2021124348A1 (en) * 2019-12-20 2021-06-24 L'ORéAL S.A. Multiple-compartment device comprising at least one internal frangible seal containing a keratin fibers dyeing composition
US12144878B2 (en) 2019-12-20 2024-11-19 L'oreal Multiple-compartment device comprising at least one internal frangible seal containing a keratin fibers dyeing composition
FR3146068A1 (en) * 2023-02-27 2024-08-30 L'oreal DYE COMPOSITION FOR DYEING KERATIN FIBERS AND DYEING KIT CONTAINING THE SAME

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