WO2015055505A1 - Active substance for controlling stink bugs - Google Patents

Abstract

The known compound of formula (I) is ideally suited to the control of animal pests of the family of stink bugs (Pentatomidae).

Description

 Active substance for the control of stink bugs

The present application relates to the use of a known active substance for combating animal pests of the family of spotted bugs (Pentatomidae)

The compound of the formula (I)

and its preparation are known from EP 0 268 915 A2. See also WO 2012/029672 Al, WO 2013/031671 A1, EP 2 628 389 A1 and EP 2 631 235 A2.

Structurally similar compounds have already been described in EP 432 600 A2 as herbicidally active compounds. Furthermore, in EP 2 628 389 A1, the effect of the active compound of the formula (I) against the Brown-Winged Green Bug (bug) from the family of the Pentatomidae on apples was tested.

Since the control of stink bugs in surface crops is becoming increasingly important and the number of suitable active ingredients is falling, above all due to regulatory requirements with regard to the ecotoxicological properties, the demand for suitable active substances is particularly high. Surprisingly, it has now been found that the compound of the formula (I) is particularly suitable for controlling insects of the family of the bugs (Pentatomidae), in particular for the protection of surface crops such as soybean, cotton, corn, rice and cereals and not only for the protection of Fruits is suitable. In addition, the compound of the formula (I) also has favorable ecotoxicological properties. The compound of the formula (I) is particularly suitable for combating the following species of the family of spotted bugs (Pentatomidae), wherein each of the following combinations of pest and culture represents in itself a particular and preferred embodiment of the invention:

Antestiopsis orbitalus in soy,

Acrosternum hilare in cotton,

Dichelops furcatus in corn, soya and cereals, Dichelops melacanthus in corn, soya and cereals,

Chlorochroa sayi in cotton,

Eurygaster intergriceps in cereals,

Eurygaster maura in cereals, euschistus heros in soy, corn, cotton and rice,

Euschistus servus in cotton, soy and corn,

Euschistus conspersus in cotton,

Euschistus impictiventris in cotton,

Nezara viridula in soya, corn, cotton, cereals and rice, Nezara hilare in soy, corn, cotton, cereals and rice,

Oebalus mexicana in rice and cereals,

Oebalus poecilus in rice and cereals,

Oebalus purgnase in rice and cereals,

Oebalus pugnax in rice, Piezodorus guildinii in soy, corn, cotton and rice,

Scotinophara lurida in rice,

Scotinophara coaretata in rice.

The compound of the formula (I) is particularly suitable for controlling the following species of the family of the stink bug (Pentatomidae): Antestiopsis orbitalus in soy,

Dichelops furcatus in corn, soya and cereals,

Dichelops melacanthus in corn, soya and cereals,

Euschistus heros in soya, corn and cotton,

Euschistus servus in soya, corn and cotton, Nezara viridula in soya, corn and cotton, Nezara hilare in soy, corn and cotton, Piezodorus guildinü in soy, corn and cotton. Formulations The present invention furthermore relates to formulations and use forms prepared therefrom as pesticides, such as, for example, pesticides. B. drench, drip and spray, comprising the compound of formula (I). Optionally, the uses include other pesticides and / or effect-enhancing adjuvants such as penetration enhancers, e.g. As vegetative oils such as rapeseed oil, sunflower oil, mineral oils such as paraffin oils, alkyl esters of vegetable fatty acids such as rapeseed oil or soybean oil or alkanol alkoxylates and / or spreading agents such as alkyl siloxanes and / or salts such as organic or inorganic ammonium or phosphonium salts such as ammonium sulfate or diammonium hydrogen phosphate and / or retention-demanding agents such as. As dioctylsulfosuccinate or hydroxypropyl guar polymers and / or humectants such as glycerol and / or fertilizers such as ammonium, potassium or phosphorus-containing fertilizer.

Typical formulations are, for example, water-soluble liquids (SL), emulsion concentrates (EC), emulsions in water (EW), suspension concentrates (SC, SE, FS, OD), water-dispersible granules (WG), granules (GR) and capsule concentrates (CS). ; These and other possible formulation types are described, for example, by Crop Life International and in Pesticide Specifications, Manual on Development and Use of FAO and WHO Specifications for Pesticides, FAO Plant Production and Protection Papers - 173, prepared by the FAO / WHO Joint Meeting on Pesticide Specifications, 2004, ISBN: 9251048576. If appropriate, the formulations contain, in addition to one or more compounds of the formula (I), further agrochemical active substances.

They are preferably formulations or use forms which contain auxiliaries, such as extenders, solvents, spontaneity promoters, carriers, emulsifiers, dispersants, antifreeze agents, biocides, thickeners and / or further auxiliaries, for example adjuvants. An adjuvant in this context is a component that enhances the biological effect of the formulation without the component itself having a biological effect. Examples of adjuvants are agents that promote retention, spreading behavior, adherence to the leaf surface, or penetration.

These formulations are prepared in a known manner, for example by mixing the compound of formula (I) with excipients such as extenders, solvents and / or solid carriers and / or other excipients such as surfactants. The Preparation of the formulations is carried out either in suitable equipment or before or during use.

Excipients which can be used are those which are suitable for formulating the compound of the formula (I) or the use forms prepared from these formulations (such as, for example, pesticides suitable for use, such as spraying broths or seed dressing), such as certain physical, technical and / or biological properties To give properties.

As extender, e.g. Water, polar and non-polar organic chemical liquids e.g. from the classes of aromatic and non-aromatic hydrocarbons (such as paraffins, alkylbenzenes, alkylnaphthalenes, chlorobenzenes), alcohols and polyols (which may also be substituted, etherified and / or esterified), ketones (such as acetone, cyclohexanone), Esters (including fats and oils) and (poly) ethers, simple and substituted amines, amides, lactams (such as N-alkylpyrrolidones) and lactones, sulfones and sulfoxides (such as dimethylsulfoxide).

In the case of using water as an extender, e.g. also organic solvents can be used as auxiliary solvents. Suitable liquid solvents are essentially: aromatics such as xylene, toluene or alkylnaphthalenes, chlorinated aromatics or chlorinated aliphatic hydrocarbons such as chlorobenzenes, chloroethylenes or methylene chloride, aliphatic hydrocarbons such as cyclohexane or paraffins, e.g. Petroleum fractions, mineral and vegetable oils, alcohols such as butanol or glycol and their ethers and esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents such as dimethylformamide and dimethyl sulfoxide, and water.

In principle, all suitable solvents can be used. Suitable solvents are, for example, aromatic hydrocarbons, e.g. Xylene, toluene or alkylnaphthalenes, chlorinated aromatic or aliphatic hydrocarbons, e.g. Chlorobenzene, chloroethylene, or methylene chloride, aliphatic hydrocarbons, e.g. Cyclohexane, paraffins, petroleum fractions, mineral and vegetable oils, alcohols such as e.g. Methanol, ethanol, iso-propanol, butanol or glycol and their ethers and esters, ketones such as e.g. Acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strong polar solvents such as dimethyl sulfoxide and water.

In principle, all suitable carriers can be used. Suitable carriers are in particular: for example, ammonium salts and ground natural minerals such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth and synthetic rock flour, such as finely divided silica, alumina and natural or synthetic silicates, resins, waxes and / or solid fertilizers , Mixtures of such carriers can also be used. Suitable carriers for granules are: for example, broken and fractionated natural rocks such as calcite, marble, pumice, sepiolite, dolomite and synthetic granules of inorganic and organic flours and granules of organic material such as sawdust, paper, coconut shells, corn cobs and tobacco stems.

Also, liquefied gaseous diluents or solvents can be used. Particularly suitable are those diluents or carriers which are gaseous at normal temperature and under normal pressure, e.g. Aerosol propellants such as halogenated hydrocarbons as well as butane, propane, nitrogen and carbon dioxide.

Examples of emulsifying and / or foaming agents, dispersants or wetting agents having ionic or non-ionic properties or mixtures of these surfactants are salts of polyacrylic acid, salts of lignosulphonic acid, salts of phenolsulphonic acid or naphthalenesulphonic acid, polycondensates of ethylene oxide with fatty alcohols or with fatty acids or with fatty amines, with substituted phenols (preferably alkylphenols or arylphenols), salts of sulphosuccinic acid esters, taurine derivatives (preferably alkyl taurates), phosphoric acid esters of polyethoxy hydrogens or phenols, fatty acid esters of polyols and derivatives of the compounds containing sulphates, sulphonates and phosphates, eg Alkylaryl polyglycol ethers, alkylsulfonates, alkyl sulfates, arylsulfonates, protein hydrolysates, lignin-sulphite liquors and methylcellulose. The presence of a surfactant is advantageous when the compound of formula (I) and / or one of the inert carriers is not soluble in water and when applied in water.

As further adjuvants, in the formulations and the applications derived therefrom, dyes such as inorganic pigments, e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes and nutrient and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc.

Stabilizers such as cold stabilizers, preservatives, antioxidants, light stabilizers or other chemical and / or physical stability-improving agents may also be present. It may also contain foam-forming agents or defoamers.

Furthermore, the formulations and derived therefrom application forms as additional auxiliaries and adhesives such as carboxymethyl cellulose, natural and synthetic powdery, granular or latex-containing polymers such as gum arabic, polyvinyl alcohol, polyvinyl acetate and natural phospholipids such as cephalins and lecithins and synthetic phospholipids. Other auxiliaries may be mineral and vegetable oils.

Optionally, further auxiliaries may be present in the formulations and in the use forms derived therefrom. Such additives are, for example, fragrances, protective colloids, binders, adhesives, thickeners, thixotropic substances, penetration promoters, retention promoters, stabilizers, sequestrants, complexing agents, humectants, spreading agents. in the In general, the compounds of formula (I) may be combined with any solid or liquid additive commonly used for formulation purposes.

As retention promoters are all those substances which reduce the dynamic surface tension such as dioctylsulfosuccinate or increase the visco-elasticity such as hydroxypropyl guar polymers.

Suitable penetration promoters in the present context are all those substances which are usually used to improve the penetration of agrochemical active substances into plants. Penetration promoters are in this context defined by the fact that they can penetrate from the (usually aqueous) application broth and / or from the spray coating into the cuticle of the plant and thereby increase the material mobility (mobility) of the active ingredients in the cuticle. The method described in the literature (Baur et al., 1997, Pesticide Science 51, 131-152) can be used to determine this property. Examples include alcohol alkoxylates such as coconut oil ethoxylate (10) or isotridecyl ethoxylate (12), fatty acid esters such as rapeseed oil or soybean oil, fatty amine alkoxylates such as tallowamine ethoxylate (15) or ammonium and / or phosphonium salts such as ammonium sulfate or diammonium hydrogen phosphate ,

The formulations preferably contain between 0.00000001 and 98 wt .-% of the compound of formula (I), more preferably between 0.01 and 95 wt .-% of the compound of formula (I), most preferably between 0.5 and 90% by weight of the compound of formula (I), based on the weight of the formulation.

The content of the compound of the formula (I) in the forms of application prepared from the formulations (in particular pesticides) can vary within wide ranges. The concentration of the compound of the formula (I) in the use forms may usually be between 0.00000001 and 95% by weight of the compound of the formula (I), preferably between 0.00001 and 1% by weight, based on the weight of the application form , lie. The application is done in a custom forms adapted to the application.

mixtures

The compound of formula (I) may be used as such or in their formulations also in admixture with one or more suitable fungicides (see the list below), bactericides, acaricides, molluscicides, nematicides, insecticides (see list below), microbiologicals, Useful, herbicides, fertilizers, bird repellents, phytotonics, sterilants, synergists, safeners, semiochemicals and / or plant growth regulators are used, for example, to broaden the spectrum of action, extend the duration of action, increase the rate of action, prevent re-exposure or prevent development of resistance. Furthermore you can such drug combinations plant growth and / or tolerance to abiotic factors such. As high or low temperatures, against drought or increased Wasserbzw. Improve soil salt content. Also, flowering and fruiting behavior can be improved, germination and rooting can be improved, harvesting and crop yields increased, maturity can be enhanced, crop quality and / or nutritional value increased, shelf life extended and / or crop productivity improved.

Furthermore, the compound of the formula (I) as such or in its (commercial) formulations and in the formulations prepared from these formulations in admixture with other active ingredients or semiochemicals, such as attractants and / or bird repellents and / or plant activators and / or growth regulators and / or fertilizers and / or synergists. Likewise, the compound of formula (I) and its compositions can be used in mixtures with agents for improving plant properties such as growth, yield and quality of the crop.

In a particular embodiment of the invention, the compound of the formula (I) or its compositions is present in commercial formulations or in the formulations prepared from these formulations in admixture with synergists and are used as insecticides. By synergists is meant those compounds which enhance the activity of the compound of formula (I) without the synergist having an insecticidal / acaricidal / nematicidal action.

Suitable mixing partners are the following insecticides / acaricides / nematicides

The active substances mentioned here with their "common name" are known and described, for example, in the Pesticide Handbook ("The Pesticide Manual" 16th ed., British Crop Protection Council 2012) or searchable on the Internet (eg http://www.alanwood.net/pesticides ).

(1) acetylcholinesterase (AChE) inhibitors such as carbamates, eg alanycarb, aldicarb, bendocarb, benfuracarb, butocarboxime, butoxycarboxim, carbaryl, carbofuran, carbosulfan, ethiofencarb, fenobucarb, formetanate, furathiocarb, isoprocarb, methiocarb, methomyl, metolcarb, oxamyl, Pirimicarb, propoxur, thiodicarb, thiofanox, triazamate, trimethacarb, XMC and xylylcarb or organophosphates, eg acephates, azamethiphos, azinphos-ethyl, azinphos-methyl, cadusafos, chloroethoxyfos, chlorfenvinphos, chlormephos, chlorpyrifos, chlorpyrifos-methyl, coumaphos, cyanophos, demeton -S-methyl, diazinon, dichlorvos / DDVP, dicrotophos, dimethoates, dimethylvinphos, disulfone, EPN, ethione, ethoprophos, famphur, fenamiphos, fenitrothion, fenthione, fosthiazate, heptenophos, imicyafos, isofenphos, isopropyl 0- (methoxyaminothiophosphoryl) salicylate , Isoxathione, Malathion, Mecarbam, Methamidophos, Methidathione, Mevinphos, Monocrotophos, Naled, Omethoate, Oxydemeton-methyl, Parathion, Parathion-m ethyl, Phenthoate, Phorates, Phosalones, Phosmet, Phosphamidone, Phoxim, Pirimiphos-methyl, Profenofos, Propetamphos, Prothiofos, Pyraclofos, Pyridaphenthion, Quinalphos, Sulfotep, Tebupirimfos, Temephos, Terbufos, Tetrachlorvinphos, Thiometon, Triazophos, Triclorfon and Vamidothion.

(2) GABA-controlled chloride channel antagonists, such as cyclodiene organochlorines, e.g. Chlordanes and endosulfan or phenylpyrazoles (fiproles), e.g. Ethiprole and fipronil.

(3) sodium channel modulators / voltage dependent sodium channel blockers such as pyrethroids, e.g. Acrinathrin, allethrin, d-cis-trans allethrin, d-trans allethrin, bifenthrin, bioallethrin, bioallethrin S-cyclopentenyl isomer, bioresmethrin, cycloprothrin, cyfluthrin, beta-cyfluthrin, cyhalothrin, lambda-cyhalothrin, gamma-cyhalothrin, cypermethrin, alpha- Cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, cyphenothrin [(lR) trans isomers], deltamethrin, empenthrin [(EZ) (lR) isomers], esfenvalerates, etofenprox, fenpropathrin, fenvalerates, flucythrinates, Flumethrin, tau-fluvalinate, halfenprox, imiprothrin, kadethrin, permethrin, phenothrin [(lR) -trans-isomer), prallethrin, pyrethrin (pyrethrum), resmethrin, silafluofen, tefluthrin, tetramethrin, tetramethrin [(1R) - isomer)], Tralomethrin and transfluthrin or DDT or methoxychlor.

(4) nicotinergic acetylcholine receptor (nAChR) agonists such as neonicotinoids, e.g. Acetamiprid, clothianidin, dinotefuran, imidacloprid, nitenpyram, thiacloprid and thiamethoxam or nicotine or sulfoxaflor.

(5) nicotinergic acetylcholine receptor (nAChR) allosteric activators such as spinosines, e.g. Spinetoram and spinosad.

(6) chloride channel activators, such as avermectins / milbemycins, e.g. Abamectin, Emamectin benzoate, Lepimectin and Milbemectin.

(7) Juvenile hormone mimics, such as juvenile hormone analogs, e.g. Hydroprene, Kinoprene and Methoprene or Fenoxycarb or Pyriproxyfen. (8) agents with unknown or non-specific mechanisms of action, such as

Alkyl halides, e.g. Methyl bromide and other alkyl halides; or chloropicrin or sulfuryl fluoride or borax or tartar emetic.

(9) Selective feeding inhibitors, e.g. Pymetrozine or flonicamide.

(10) mite growth inhibitors, eg clofentezine, hexythiazox and diflovidazine or etoxazole. (11) Microbial disruptors of insect intestinal membrane, eg, Bacillus thuringiensis subspecies israelensis, Bacillus sphaericus, Bacillus thuringiensis subspecies aizawai, Bacillus thuringiensis Subspecies kurstaki, Bacillus thuringiensis subspecies tenebrionis and BT plant proteins: CrylAb, CrylAc, CrylFa, Cry2Ab, mCry3A, Cry3Ab, Cry3Bb, Cry34 / 35Abl.

(12) oxidative phosphorylation inhibitors, ATP disruptors such as diafenthiuron or organotin compounds, e.g. Azocyclotin, Cyhexatin and Fenbutatin-oxide or Propargite or Tetradifon.

(13) Decoupling of oxidative phosphorylation by interruption of the H proton gradient, such as chlorfenapyr, DNOC, and sulfluramide.

(14) Nicotinergic acetylcholine receptor antagonists such as Bensultap, Cartap hydrochloride, Thiocyclam and Thiosultap sodium. (15) Type 0 inhibitors of chitin biosynthesis, such as bistrifluron, chlorofluorazuron, diflubenzuron, flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novaluron, noviflumuron, teflubenzuron and triflumuron.

(16) inhibitors of chitin biosynthesis, type 1, such as Bupro fezin.

(17) Moulting agents, dipteran, such as cyromazine. (18) ecdysone receptor agonists, such as chromafenozides, halofenozides, methoxyfenozides, and tebufenozides.

(19) Octopaminergic agonists, such as amitraz.

(20) complex III electron transport inhibitors such as, for example, hydramethylnone or acequinocyl or fluacrypyrim. (21) complex I electron transport inhibitors, for example, METI acaricides, e.g. Fenazaquin, Fenpyroximate, Pyrimidifen, Pyridaben, Tebufenpyrad and Tolfenpyrad or Rotenone (Derris).

(22) voltage dependent sodium channel blockers, e.g. Indoxacarb or metaflumizone.

(23) inhibitors of acetyl-CoA carboxylase, such as tetronic and tetramic acid derivatives, e.g. Spirodiclofen, spiromesifen and spirotetramat. (24) complex IV electron transport inhibitors such as phosphines, e.g. Aluminum phosphide, calcium phosphide, phosphine and zinc phosphide or cyanide.

(25) Complex II electron transport inhibitors such as cyenopyrafen and cyflumetofen.

(28) ryanodine receptor effectors, such as, for example, diamides, for example chlorantraniliproles, cyantraniliproles and flubendiamides, Other agents such as afidopyropene, azadirachtin, benclothiaz, benzoximate, bifenazate, bromopropylate, quinomethionate, cryolite,

Dicofol, Diflovidazine, Fluensulfone, Flometoquine, Flufenerim, Flufenoxystrobin, Flufiprole, Fluopyram, Flupyradifurone, Fufenocide, Heptafluthrin, Imidaclothiz, Iprodione, Meperfluthrin, Paichongding, Pyflubumide, Pyrifluquinazone, Pyriminostrobin, Tetramethylfluthrin and Iodomethane; furthermore preparations based on Bacillus firmus (1-1582, BioNeem, Votivo), and the following compounds: 3-bromo-N- {2-bromo-4-chloro-6 - [(1-cyclopropyl-ethyl) -carbamoyl] -phenyl} -l - (3-chloropyridin-2-yl) -1H-pyrazole-5-carboxamide (known from WO2005 / 077934) and 1- {2-fluoro-4-methyl-5- [(2,2,2-trifluoroethyl) sulfinyl ] phenyl} -3- (trifluoromethyl) -1H-1,2,4-triazol-5-amine (known from WO2006 / 043635), {1 '- [(2E) -3- (4-chlorophenyl) propane] 2-en-1-yl] -5-fluorospiro [indole-3,4'-piperidin] -1 (2H) -yl} (2-chloropyridin-4-yl) -methanone (known from WO2003 / 106457), 2- Chloro-N- [2- {1 - [(2E) -3- (4-chloro-1-yl-yl) prop-2-en-1-yl] -piperidin-4-yl} -4- (trifluoromethyl) -phenyl] isonicotinamide ( known from WO2006 / 003494), 3- (2,5-dimethylphenyl) -4-hydroxy-8-methoxy-1,8-diazaspiro [4.5] dec-3-en-2-one (known from WO2009 / 049851), 3- (2,5-dimethylphenyl) -8-methoxy-2-oxo-1,8-diazaspiro [4.5] dec-3-en-4-yl-ethyl carbonate (known from WO2009 / 049851), 4- (but- 2-yn-1-yloxy) -6- (3,5-dimethylpiperidin-1-yl) -5-fluoropyrimidine (known from WO2004 / 0 99160), 4- (but-2-yn-1-yloxy) -6- (3-chlorophenyl) pyrimidine (known from WO2003 / 076415), PF1364 (CAS Reg. 1204776-60-2)

(trifluoromethyl) -4,5-dihydro-l, 2-oxazol-3-yl] -2-methyl-N- {2-oxo-2 - [(2,2,2-trifluoroethyl) amino] ethyl} benzamide (known from WO2005 / 085216), 4- {5- [3-chloro-5- (trifluoromethyl) phenyl] -5- (trifluoromethyl) -4,5-dihydro-1,2-oxazo ^

naphthamide (known from WO2009 / 002809), methyl 2- [2 - ({[3-bromo-1- (3-chloropyridin-2-yl) -1H-pyrazol-5-yl] carbonyl} amino) -5- chloro-3-methylbenzoyl] -2-methylhydrazinecarboxylate (known from WO2005 / 085216), methyl 2- [2- ({[3-bromo-1- (3-chloropyridin-2-yl) -1H-pyrazole-5 -yl] carbonyl} amino) -5-cyano-3-methylbenzoyl] -2-ethylhydrazinecarboxylate (known from WO2005 / 085216), methyl 2- [2 - ({[3-bromo-1 - (3-chloropyridine-2 -yl) -1 H -pyrazol-5-yl] carbonyl} amino) -5-cyano-3-methylbenzoyl] -2-methylhydrazinecarboxylate (known from WO2005 / 085216), methyl 2- [3,5-dibromo-2 - ({[3-bromo-1- (3-chloropyridin-2-yl) -1-H-pyrazol-5-yl] carbonyl} amino) benzoyl] -2-ethylhydrazinecarboxylate (known from WO2005 / 085216), 3-chloropyridin-2-yl) - N - [4-cyano-2-methyl-6- (methylcarbamoyl) phenyl] -3- {[5- (trifluoromethyl) -2H-tetrazol-2-yl] methyl} -H pyrazole-5-carboxamide (known from WO2010 / 069502), N- [2- (5-amino-1, 3,4-thiadiazol-2-yl) -4-chloro-6-methylphenyl] -3-bromo 1- (3-chloro-2-yl) -1H-pyrazole-5-carboxamide (known from CN102057 925), 3-chloro-N- (2-cyanopropan-2-yl) -N- [4- (1, 1, 1, 2,3,3,3-heptafluoropropan-2-yl) -2-methylphenyl] phthalamide (known from WO2012 / 034472), 8-chloro-N - [(2-chloro-5-methoxyphenyl) sulfonyl] -6- (trifluoromethyl) imidazo [1,2-a] pyridine-2-carboxamide (known from WO2010 No. 129500), 4- [5- (3,5-dichlorophenyl) -5- (trifluoromethyl) -4,5-dihydro-1,2-oxazol-3-yl] -2-methyl-N- (1 -oxidothietane 3-yl) benzamide (known from WO2009 / 080250), 4- [5- (3,5-dichlorophenyl) -5- (trifluoromethyl) -4,5-dihydro-1,2-oxazol-3-yl] - 2-methyl-N- (1 -oxidothietan-3-yl) benzamide (known from WO2012 / 029672), 1 - [(2-chloro-1,3-thiazol-5-yl) methyl] -4-oxo -3-phenyl-4H- pyrido [1,2-a] pyrimidine-l-ium-2-olate (known from WO2009 / 099929), l - [(6-chloropyridin-3-yl) methyl] -4-oxo-3-phenyl-4H- pyrido [1,2-a] pyrimidin-1-ium-2-olate (known from WO2009 / 099929), (5S, 8R) -1 - [(6-chloro-3-yl) -methyl] -9- nitro-2,3,5,6,7,8-hexahydro-1H-5,8-epoxyimidazo [1,2-a] azepine (known from WO2010 / 069266), (2E) -l - [(6-chloropyridine 3-yl) methyl] -N'-nitro-2-pentylidenehydrazinecarboximidamide (known from WO2010 / 060231), 4- (3- {2,6-dichloro-4 - [(3,3-dichloro-prop-2- en-1-yl) oxy] plnoxy} propoxy) -2-methoxy-6- (trifluoromethyl) pyrimidine (known from CN101337940), N- [2- (tert-butylcarbamoyl) -4-chloro-6-methylphenyl] - 1 - (3-chloropyridin-2-yl) -3 - (fluoromethoxy) -1 H -pyrazole-5-carboxamide (known from WO2008 / 134969).

Further suitable mixing partners are the following fungicides

The active ingredients specified here with their "common name" are known, for example, described in the "Pesticide Manual" or on the Internet (for example: http://www.alanwood.net/pesticides).

If a compound can exist in various tautomeric forms, these forms are also the subject of this application, although they have not been explicitly mentioned in each case. (1) inhibitors of ergosterol biosynthesis, such as (1.1) aldimorph, (1.2) azaconazole, (1.3) bitertanol, (1.4) bromuconazole, (1.5) cyproconazole, (1.6) diclobutrazole, (1.7) difenoconazole, (1.8) diniconazole , (1.9) Diniconazole-M, (1.10) dodemorph, (1.11) dodemorph acetate, (1.12) epoxiconazole, (1.13) etaconazole, (1.14) fenarimol, (1.15) fenbuconazole, (1.16) fenhexamide, (1.17) fenpropidine, ( 1.18) fenpropimorph, (1.19) fluquinconazole, (1.20) flurprimidol, (1.21) flusilazole, (1.22) flutriafol, (1-23) furconazole, (1.24) furconazole cis, (1.25) hexaconazole, (1.26) imazalil, (1.27 ) Imazalil sulfate, (1.28) imibenconazole, (1.29) ipconazole, (1.30) metconazole, (1.31) myclobutanil, (1.32) naftifine, (1.33) nuarimol, (1.34) oxpoconazole, (1.35) paclobutrazole, (1.36) peiurazoate, ( 1.37) penconazole, (1.38) piperalin, (1.39) prochlorazole, (1.40) propiconazole, (1.41) prothioconazole, (1.42) pyributicarb, (1.43) pyrifenox, (1.44) quinconazole, (1.45) simeconazole, (1.46) spiroxamine, ( 1.47) Tebuconazole, ( 1.48) Terbinafine, (1.49) Tetraconazole, (1.50) Triadimefon, (1.51) Triadimenol, (1.52) Tridemorph, (1.53) Triflumizole, (1.54) Triforin, (1.55) Triticonazole, (1.56) Uniconazole, (1.57) Uniconazole-p , (1.58) viniconazole, (1.59) voriconazole, (1.60) 1- (4-chlorophenyl) -2- (1H-l, 2,4-triazol-1-yl) cycloheptanol, (1.61) methyl 1- (2 , 2-dimethyl-2,3-dihydro-1H-inden-1-yl) -1H-imidazole-5-carboxylate, (1.62) N '- {5- (difluoromethyl) -2-methyl-4- [3- (trimethylsilyl) propoxy] phenyl} -N-ethyl-N-methylimidoformamide, (1.63) N -ethyl-N-methyl-N '- {2-methyl-5- (trifluoromethyl) -4- [3- (trimethylsilyl) propoxy ] phenyl} imidoformamide and (1.64) 0- [1- (4-methoxyphenoxy) -3,3-dimethylbutan-2-yl] -1H-imidazole-1-carbothioate, (1.65) pyrisoxazoles.

(2) inhibitors of respiration (respiratory chain inhibitors), such as (2.1) bixafen, (2.2) boscalid, (2.3) carboxin, (2.4) difluorotorim, (2.5) fenfuram, (2.6) fluopyram, (2.7) flutolanil, ( 8/2) Fluxapyroxad, (2.9) Furametpyr, (2.10) Furmecyclox, (2.11) Isopyrazam Mixture of the syn-epimeric racemate 1RS, 4SR, 9RS and the anti-empimidal racemate 1RS, 4SR, 9SR, (2.12) isopyrazam (anti- epimeric racemate), (2.13) isopyrazam (anti-epimeric enantiomer 1R, 4S, 9S), (2.14) isopyrazam (anti-epimeric enantiomer 1S, 4R, 9R), (2.15) isopyrazam (syn-epimeric racemate 1RS, 4SR, 9RS), ( 2.16) isopyrazam (syn-epimeric enantiomer 1R, 4S, 9R), (2.17) isopyrazam (syn-epimeric enantiomer 1S, 4R, 9S), (2.18) mepronil, (2.19) oxycarboxine, (2.20) pen- penene, (2.21) penthiopyrad , (2.22) Sedaxanes, (2.23) Thifluzamide, (2.24) l-Methyl-N- [2- (l, l, 2,2-tetrafluoroethoxy) phenyl] -3- (trifluoromethyl) -1H-pyrazole-4-carboxamide , (2.25) 3- (Difluoromethyl) -1-methyl-N- [2- (1,2,2-tetrafluoroethoxy) phenyl] -1H-pyrazole-4-carboxamide, (2.26) 3- (difluoromethyl) - N- [4-fluoro-2- (1,2,2,3,3,3-hexafluoropropoxy) pllenyl] -1-metllyl-1H-pyrazole-4-carboxamide, (2.27) - [1- (2,4 Dichloro) -1-methoxypropan-2-yl] -3- (difluoromethyl) -1-methyl-1H-pyra zol-4-carboxamide, (2.28) 5,8-Difluoro-N- [2- (2-fluoro-4- {[4- (trifluoromethyl) pyridin-2-yl] oxy} phenyl) ethyl] quinazolin-4 amine, (2.29) benzovindiflupyr, (2.30) N- [(1S, 4R) -9- (dichloromethylene) -1,2,3,4-tetrahydro-1,4-methanonaphthalen-5-yl] -3 - (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide and (2.31) N - [(IR, 4S) -9- (dichloromethylene) -1,2,3,4-tetrahydro-1,4-methanonaphthalene -5-yl] -3- (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide, (2.32) 3- (difluoromethyl) -1-methyl-N- (1, 1, 3-trimethyl-2 , 3-dihydro-1H-inden-4-yl) -1H-pyrazole-4-carboxamide, (2.33) 1,3,5-trimethyl-N- (1,1,3-trimethyl-2,3-dihydro o 1-H-inden-4-yl) -1-H-pyrazole-4-carboxamide, (2.34) 1-methyl-3- (trifluoromethyl) -N- (1, 1, 3-trimethyl-2,3-dihydro- 1H-inden-4-yl) -1H-pyrazole-4-carboxamide, (2.35) 1-methyl-3 - (trifluoromethyl) -N - [(3R) -1,1,3-trimethyl-2,3-dihydro - 1 H -inden-4-yl] -1H-pyrazole-4-carboxamide, (2.36) 1-methyl-3- (trifluoromethyl) -N - [(3S) -l, l, 3-trimethyl-2,3 - dihydro-1H-inden-4-yl] -1H-pyrazole-4-carboxamide , (2.37) 3- (difluoromethyl) -1-methyl-N - [(3S) -1,3,1-trimethyl-2,3-dihydro-1H-inden-4-yl] -1 H-pyrazole 4-carboxamide, (2.38) 3- (difluoromethyl) -1-methyl-N- [(3R) -1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl] -1H pyrazole-4-carboxamide, (2.39) 1, 3,5-trimethyl-N- [(3R) -1,3,3-trimethyl-2,3-dihydro-1H-inden-4-yl] -1 H-pyrazole-4-carboxamide, (2.40) 1, 3,5-trimethyl-N- [(3S) -l, l, 3-trimethyl-2,3-dihydro-1H-inden-4-yl] -H pyrazole-4-carboxamide, (2.41) benodanil, (2.42) 2-chloro-N- (1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl) -pyridine-3-carboxamide , (2.43) isofetamide

(3) inhibitors of respiration (respiratory chain inhibitors) at the complex III of the respiratory chain, such as (3.1) ametoctradine, (3.2) amisulbrom, (3.3) azoxystrobin, (3.4) cyazofamide, (3.5) coumethoxystrobin, (3.6) coumoxystrobin, ( 3.5) dimoxystrobin, (3.8) enestroburine, (3.9) famoxadone, (3.10) fenamidone, (3.11) flufenoxystrobin, (3.12) fluoxastrobin, (3.13) kresoxime-methyl, (3.14) metominostrobin, (3.15) orysastrobin, (3.16) picoxystrobin , (3.17) Pyraclostrobin, (3.18) Pyrametostrobin, (3.19) Pyraoxystrobin, (3.20) Pyribencarb, (3.21) Triclopyricarb, (3.22) Trifloxystrobin, (3.23) (2E) -2- (2- {[6- (3- Chloro-2-methylphenoxy) -5-fluoro-pyrimidin-4-yl] oxy} phenyl) -2- (methoxyimino) -N-methylethanamide, (3.24) (2E) -2- (methoxyimino) -N-methyl-2- (2- {[({(1Ε) -1- [3- (trifluoromethyl) phenyl] ethylidene} amino) oxy] methyl} phenyl) ethanamide, (3.25) (2E) -2- (methoxyimino) -N-methyl- 2- {2 - [(E) - ({1- [3- (trifluoromethyl) phenyl] ethoxy} imino) methyl] phenyl} ethanamide, (3.26) (2E) -2- {2- [({[(1 E) - 1 - (3 - {[(E ) - 1-fluoro-2-phenylethenyl] oxy} phenyl) ethylidene] amino} oxy) me- ethyl] phenyl} -2- (methoxyimino) -N-methylethanamide, (3.27) (2E) -2- {2 - [({[(2E, 3E) -4- (2,6-dichloro-phenyl) -butyl] 3-en-2-ylidene] amino} oxy) methyl] phenyl} -2- (methoxyimino) -N-methylet ^ (3.28) 2-

Chloro-N- (1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl) pyridine-3-carboxamide, (3.29) 5-methoxy-2-methyl-4- (2- {[ ({(1E) -1 - [3- (trifluoromethyl) phenyl] ethylidene} amino) oxy] methyl} phenyl) -2,4-dihydro-3H-l, 2,4-triazol-3-one, (3.30 ) Methyl (2E) -2- {2 - [({cyclopropyl [(4-methoxyphenyl) imino] methyl} sulfanyl) methyl] phenyl} -3-methoxyprop-2-enoate, (3.31) N- (3 Ethyl-3,5,5-trimethylcyclohexyl) -3- (formylamino) -2-hydroxybenzamide, (3.32) 2- {2 - [(2,5-dimethylphenoxy) methyl] phenyl} -2-methoxy-N-methylacetamide (4) inhibitors of mitosis and cell division, such as (4.1) benomyl, (4.2) carbendazim, (4.3) chlorfenazole, (4.4) diethofencarb, (4.5) ethaboxam, (4.6) fluopicolide, (4.7) fuberidazole, (4.8) Pencycuron, (4.9) thiabendazole, (4.10) thiophanate-methyl, (4.11) thiophanate, (4.12) zoxamide, (4.13) 5-chloro-7- (4-methylpiperidin-l-yl) -6- (2,4, 6-trifluorophenyl) [l, 2,4] triazolo [l, 5-a] pyrimidine and (4.14) 3-chloro-5- (6-chloropyridin-3-yl) -6-methyl-4- (2,4 , 6-trifluorohexyl) pyridazine.

(5) Compounds with multisite activity, such as (5.1) Bordeaux mixture, (5.2) captafol, (5.3) captan, (5.4) chlorothalonil, (5.5) copper compounds such as copper hydroxide, (5.6) copper naphthenate, (5.7) copper oxide, (5.8 ) Copper oxychloride, (5.9) copper sulfate, (5.10) dichlorofluanide, (5.11) dithianone, (5.12) dodine, (5.13) dodine free base, (5.14) ferbam, (5.15) fluoro folpet, (5.16) folpet, (5.17) guazatine, (5.18) guazatinoacetate, (5.19) iminoctadine, (5.20) iminoctadinalesilate, (5.21) iminoctadine triacetate, (5.22) mancopper, (5.23) mancozeb, (5.24) maneb, (5.25) metiram, (5.26) zinc metiram, (5.27) copper Oxine, (5.28) propamidine, (5.29) propynol, (5.30) sulfur and sulfur compounds such as calcium polysulfide, (5.31) thiram, (5.32) tolylfluanide, (5.33) zineb, (5.34) ziram, and (5.35) anilazine.

(6) resistance inducers such as (6.1) acibenzolar-S-methyl, (6.2) isotianil, (6.3) probenazole, (6.4) tiadinil, and (6.5) laminarin.

(7) inhibitors of amino acid and protein biosynthesis, such as (7.1), (7.2) blasticidin-S, (7.3) cyprodinil, (7.4) kasugamycin, (7.5) kasugamycin hydrochloride hydrate, (7.6) mepanipyrim,

(7.7) pyrimethanil, (7.8) 3- (5-fluoro-3,3,4,4-tetramethyl-3,4-dihydroisoquinolin-1-yl) quinoline and (7.9) oxytetracycline and (7.10) streptomycin.

(8) inhibitors of ATP production, such as (8.1) fentin acetate, (8.2) fentin chloride, (8.3) fentin hydroxide and (8.4) silthiofam. (9) inhibitors of cell wall synthesis, such as (9.1) benthia-valicarb, (9.2) dimethomorph, (9.3) flumorph, (9.4) iprovalicarb, (9.5) mandipropamide, (9.6) polyoxins, (9.7) polyoxorim, (9.8) validamycin A, (9.9) Valifenalate and (9.10) Polyoxin B.

(10) inhibitors of lipid and membrane synthesis, such as (10.1) biphenyl, (10.2) chloroben, (10.3) diclorane, (10.4) edifenphos, (10.5) etridiazole, (10.6) iodocarb, (10.7) Iprobenfos, (10.8) isoprothiolane, (10.9) propamocarb, (10.10) propamocarb hydrochloride, (10.11) prothiocarb ,, (10.12) pyrazophos, (10.13) quintoene, (10.14) tecnazenes, and (10.15) tolclofos-methyl.

(11) inhibitors of melanin biosynthesis, such as (11.1) carpropamide, (11.2) diclocymet, (11.3) fenoxanil, (11.4) fthalide, (11.5) pyroquilone, (11.6) tricyclazole, and (11.7) 2,2,2 Trifluoroethyl {3-methyl-1 - [(4-methylbenzoyl) amino] butan-2-yl} carbamate.

(12) inhibitors of nucleic acid synthesis, such as (12.1) benalaxyl, (12.2) benalaxyl-M (kiralaxyl), (12.3) bupirimate, (12.4) clozylacon, (12.5) dimethirimol, (12.6) ethirimol, (12.7) furalaxyl, ( 12.8) hymexazole, (12.9) metalaxyl, (12.10) metalaxyl-M (mefenoxam), (12.11) ofurace,

(12.12) oxadixyl, (12.13) oxolinic acid and (12.14) octhilinone. (13) Signal transduction inhibitors such as (13.1) chlozolinate, (13.2) fenpiclonil, (13.3) fludioxonil, (13.4) iprodione, (13.5) procymidone, (13.6) quinoxyfen, (13.7) vinclozoline, and (13.8) proquinazide.

(14) decouplers such as (14.1) binapacryl, (14.2) dinocap, (14.3) ferimzone, (14.4) fluazinam, and (14.5) meptyldinocap. (15) Other compounds such as (15.1) benthiazole, (15.2) bethoxazine, (15.3) capsimycin, (15.4) carvone, (15.5) quinomethionate, (15.6) pyriofenone (Chlazafenone), (15.7) Cufraneb, (15.8) cyflufenamid , (15.9) Cymoxanil, (15.10) Cyprosulfamide, (15.11) Dazomet, (15.12) Debacarb,

(15.13) dichlorophene, (15.14) diclomethine, (15.15) difenzoquat, (15.16) difenzoquat methylsulphate, (15.17) diphenylamine, (15.18) ecomat, (15.19) fenpyrazamine, (15.20) flumetover, (15.21) fluorimide, (15.22) flusulfamide , (15.23) flutianil, (15.24) fosetyl-aluminum, (15.25) fosetyl-calcium, (15.26) fosetyl-sodium, (15.27) hexachlorobenzene, (15.28) irumamycin, (15.29) methasulfocarb, (15.30) methylisothiocyanate, (15.31) Metrafenone, (15.32) Mildiomycin, (15.33) Natamycin, (15.34) Nickel Dimethyldithiocarbamate, (15.35) Nitrothal-isopropyl, (15.36) Octhilinone, (15.37) Oxamocarb, (15.38) Oxyfenthiine, (15.39) Pentachlorophenol and its salts, (15.40 ) Phenothrin, (15.41) phosphoric acid and its salts, (15.42) propamocarb-fosetylate, (15.43) propanosine sodium, (15.44) pyrimorph, (15.45) (2E) -3- (4-tert-butylphenyl) -3- ( 2-chloro-pyridin-4-yl) -1- (4-yl) prop-2-en-1-one, (15.46) (2Z) -3- (4-tert-butylphenyl) -3- (2- chloropyridin-4-yl) -1- (morpholin-4-yl) prop-2-en-1-one, (15.47) pyrroline nitrate, (15.48) Tebufloquine, (15.49) tecloftalam, (15.50) tolnifanide, (15.51) triazoxide, (15.52) trichlamide, (15.53) zarilamide, (15.54) (3S, 6S, 7R, 8R) -8-benzyl-3 - [({3 - [(isobutyryloxy) methoxy] -4-methoxypyridin-2-yl} carbonyl) amino] -6-methyl-4,9-dioxo-l, 5-dioxonan-7-yl 2-methylpropanoate, (15.55) l- ( 4- {4 - [(5R) -5- (2,6-difluorophenyl) -4,5-dihydro-l, 2-oxazol-3-yl] -l, 3-thiazol-2-yl} piperidin-l - yl) -2- [5-methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] ethanone, (15.56) 1- (4- {4 - [(5S) -5- (2,6-) Difluorophenyl) -4,5-dihydro-l, 2-oxazol-3-yl] -1,3-thiazol-2-yl} piperidin-1-yl) -2- [5-methyl-3- (trifluoromethyl ) - 1H-pyrazol-1-yl] ethanone, (15.57) 1- (4- {4- [5- (2,6-difluorophenyl) -4,5-dihydro-1,2-oxazol-3-yl] -l, 3-thiazol-2-yl} piperidin-1-yl) -2- [5-methyl-3 - (trifluoromethyl) -1-H-pyrazol-1-yl] ethanone, (15.58) 1 - (4- Methoxyphenoxy) -3,3-dimethylbutan-2-yl 1H-imidazole-1-carboxylate, (15.59) 2,3,5,6-tetrachloro-4- (methylsulfonyl) pyridine, (15.60) 2,3-dibutyl-6 chlorothieno [2,3-d] pyrimidin-4 (3H) -one, (15.61) 2,6-dimethyl-1H, 5H- [1,4] dithiino [2,3-c: 5,6-c '] ] dipyrrole-l, 3,5,7 (2H, 6H) -tetrone, (15.62) 2- [5-methyl-3- (trifluoro-ethyl) -m-pyrazol-1-yl] -l- (4- {4 - [(5R) -5-phenyl-4,5-dihydroxy-2-oxazol-3-yl] -1,3-thiazol-2-yl} piperidin-1-yl) ethanone, (15.63) 2- [5-Methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] -1- (4- {4 - [(5S) -5-phenyl-4,5-dihydro-1,2-oxazole 3-yl] -1,3-thiazol-2-yl} piperidin-1-yl) ethanone, (15.64) 2- [5-methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] -1 - {4- [4- (5-phenyl-4,5-dihydro-l, 2-oxazol-3-yl) -l, 3-tliiazol-2-yl] piperidin-1-yl} ethanone, (15.65) 2-butoxy-6-iodo-3-propyl-4H-chromen-4-one, (15.66) 2-chloro-5- [2-chloro-1- (2,6-difluoro-4-methoxyphenyl) -4- methyl-1H-imidazol-5-yl] pyridine, (15.67) 2-phenylphenol and salts, (15.68) 3- (4,4,5-trifluoro-3,3-dimethyl-3,4-dihydroisoquinolin-1-yl ) quinoline, (15.69) 3,4,5-trichloropy ruthenium-2,6-dicarbonitrile, (15.70) 3-Chloro-5- (4-chlorophenyl) -4- (2,6-difluorophenyl) -6-methylpyridazine, (15.71) 4- (4-chlorophenyl) -5- (2,6-difluorophenyl) -3,6-dimethylpyridazine, (15.72) 5-amino-l, 3,4-thiadiazole-2-thiol, (15.73) 5-chloro-N'-phenyl-N '- (prop -2-yn-1-yl) thiophene-2-sulfonohydrazide, (15.74) 5-fluoro-2 - [(4-fluorobenzyl) oxy] pyrimidin-4-amine, (15.75) 5-fluoro-2 - [(4 - methylbenzyl) oxy] pyrimidin-4-amine, (15.76) 5-methyl-6-octyl [l, 2,4] triazolo [l, 5-a] pyrimidin-7-amine, (15.77) ethyl (2Z) - 3-amino-2-cyano-3-phenyl acrylate, (15.78) N '- (4- {[3- (4-chlorobenzyl) -l, 2,4-thiadiazol-5-yl] oxy} -2,5- dimethylphenyl) -N-ethyl-N-methylimidoformamide, (15.79) N- (4-

Chlorobenzyl) -3- [3-methoxy-4- (prop-2-yn-1-yloxy) phenyl] propanamide, (15.80) N - [(4-chlorophenyl) (cyano) methyl] -3- [3 -methoxy-4- (prop-2-yn-1-yloxy) phenyl] propanamide, (15.81) N - [(5-bromo-3-chloropyridin-2-yl) methyl] -2,4-dichloronotinamide, (15.82 ) N- [1- (5-Bromo-3-chloropyridin-2-yl) ethyl] -2,4-dichloronotinamide, (15.83) N- [1- (5-bromo-3-chloropyridin-2-yl) -ethyl ] -2-fluoro-4-iodonicotinamide, (15.84) N- {(E) - [(cyclopropylmethoxy) imino] [6- (difluoromethyl) ^

acetamide, (15.85) N- {(Z) - [(cyclopropylmethoxy) imino] [6- (difluoromethane

 2-phenylacetamide, (15.86) N '- {4 - [(3-tert-butyl-4-cyano-1,2-thiazol-5-yl) oxy] -2-chloro-5-methyl-1-benzyl} -N-ethyl N-methylimidoformamide, (15.87) N-methyl-2- (1- {[5-methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] -acetyl} -piperidin-4-yl) -N- (1 , 2,3,4-tetrahydronaphthalen-1-yl) -1,3-thiazole-4-carboxamide, (15.88) N-methyl-2- (1 - {[5-methyl-3- (trifluoromethyl) -lH- pyrazol-l-yl] acetyl} piperidin-4-yl) ^

tetrahydronaphthalene-1-yl] -1,3-thiazole-4-carboxamide, (15.89) N-methyl-2- (1 - {[5-methyl-3 - (trifluoromethyl) -1H-pyrazol-1-yl] acetyl} piperidin-4-yl) -N - [(1S) -1,2,3,4-tetrahydronaphthalene-1-yl] -l, 3-thiazole-4-carboxamide, (15.90) pentyl {6- [ ({[(1-methyl-1H-tetrazol-5-yl) (phenyl) methylene] amino} oxy) methyl] pyridin-2-yl} carbamate, (15.91) phenazine-1-carboxylic acid, (15.92) quinoline - 8-ol, (15.93) quinoline-8-ol sulfate (2: 1), (15.94) tert -butyl {6 - [({[(1-methyl-1H-tetrazol-5-yl) (phenyl) methylene ] amino} oxy) methyl] pyridin-2-yl} carbamate, (15.95) 1-methyl-3 - (trifluoromethyl) - N - [2 '- (trifluoromethyl) biphenyl-2-yl] -1H-pyrazole-4 carboxamide, (15.96) N- (4'-chlorobiphenyl-2-yl) -3- (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide, (15.97) N- (2 ', 4'-dichlorobiphenyl- 2-yl) -3- (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide, (15.98) 3 - (difluoromethyl) -1-methyl-N- [4'- (trifluoromethyl) biphenyl-2- yl] - 1H-pyrazole-4-carboxamide, (15.99) N- (2 ', 5'-difluorobiphenyl-2-yl) -1-met hyl-3- (trifluoromethyl) -1H-pyrazole-4-carboxamide, (15.100) 3- (difluoromethyl) -1-methyl-N- [4 '- (propyl) 1-yn-1-yl) biphenyl-2-yl] -1H-pyrazole-4-carboxamide, (15.101) 5-fluoro-1,3-dimethyl-N- [4 '- (prop-1-yn-1 - yl) biphenyl-2-yl] -1-H-pyrazole-4-carboxamide, (15.102) 2-chloro-N- [4 '- (prop-1 -yn-1-yl) biphenyl-2-yl] nicotinamide , (15.103) 3- (Difluoromethyl) -N- [4 '- (3,3-dimethylbut-1 -yn-1-yl) biphenyl-2-yl] -1-methyl-1H-pyrazole-4-carboxamide , (15.104) N- [4 '- (3,3-dimethylbut-1 -yn-1-yl) biphenyl-2-yl] -5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide, (15.105) 3- (Difluoromethyl) -N- (4'-ethynyl-biphenyl-2-yl) -l-methyl-1H-pyrazole-4-carboxamide, (15.106) N- (4'-ethynyl-biphenyl-2-yl) -5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide, (15.107) 2-chloro-N- (4'-ethynyl-biphenyl-2-yl) nicotinamide, (15.108) 2-chloro-N- [4 '- (3,3-dimethylbut-1 -yn-1-yl) biphenyl-2-yl] nicotinamide, (15.109) 4- (Difluoromethyl) -2-methyl-N- [4'- (trifluoromethyl) biphenyl -2-yl] -l, 3-thiazole-5-carboxamide, (15.110) 5-fluoro-N- [4 '- (3-hydroxy-3-methylbut-1-yn-1-yl) biphenyl-2- yl] - 1,3-dimethyl-1H-pyrazole-4-carboxamide, (15.111) 2 -Chloro-N- [4 '- (3-hydroxy-3-methylbut-1-yn-1-yl) biphenyl-2-yl] nicotinamide, (15.112) 3- (difluoromethyl) -N- [4' - ( 3-methoxy-3-methylbut-1-yn-1-yl) biphenyl-2-yl] -1-methyl-1H-pyrazole-4-carboxamide, (15.113) 5-fluoro-N- [4 '- ( 3-methoxy-3-methylbut-1 -yn-1-yl) biphenyl-2-yl] - 1, 3-dimethyl-1H-pyrazole-4-carboxamide, (15.114) 2-Chloro-N- [4 ' - (3-methoxy-3-methylbut-1-yn-1-yl) biphenyl-2-yl] nicotinamide, (15.115) (5-bromo-2-methoxy-4-methylpyridin-3-yl) (2,3 , 4-trimethoxy-6-methylphenyl) methanone, (15.116) N- [2- (4- {[3- (4-chlorophenyl) prop-2-yn-1-yl] oxy} -3-methoxyphenyl) ethyl] -N2- (methylsulfonyl) valinamide, (15.117) 4-oxo-4 - [(2-phenylethyl) amino] butanoic acid, (15,118) but-3-yn-1-yl {6 - [({[(Z) - (1-methyl-1H-tetrazol-5-yl) (phenyl) methylene] amino} oxy) methyl] pyridin-2-yl} carbamate, (15.119) 4-amino-5-fluoropyrimidin-2-ol (Tautomeric form: 4-amino-5-fluoropyrimidine-2 (1H) -one), (15,120) propyl 3,4,5-trihydroxybenzoate, (15,121) 1,3-dimethyl-N- (1,1,3-trimethyl-2, 3-dihydro-1H-inden-4-yl) -1H-pyrazole-4-c arboxamide, (15,122) 1,3-dimethyl-N - [(3R) -l, l, 3-trimethyl-2,3-dihydro-1H-inden-4-yl] -1H-pyrazole-4-carboxamide, ( 15,123) 1,3-Dimethyl-N - [(3S) -l, l, 3-trimethyl-2,3-dihydro-1H-inden-4-yl] -1H-pyrazole-4-carboxamide, (15.124) 3- (4-Chloro-2-fluorophenyl) -5- (2,4-difluorophenyl) -1,2-oxazol-4-yl] (pyridin-3-yl) -methanol, (15.125) (S) - [3 - (4-chloro-2-fluorophenyl) -5- (2,4-difluorophenyl) -1,2-oxazol-4-yl] (pyridin-3-yl) -methanol, (15.126) (R) - [3- (4-Chloro-2-fluorophenyl) -5- (2,4-difluorophenyl) -1,2-oxazol-4-yl] (pyridin-3-yl) -methanol, (15.127) 2 - {[3- (2 -Chlorophenyl) -2- (2,4-difluorohexyl) oxiran-2-yl] methyl} -2,4-dihydro-3H-1,2,4-triazole-3-thione, (15.128) 1 - {[ 3 - (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -1 H -1, 2,4-triazol-5-yl thiocyanate, (15.129) 5- (allylsulfanyl) -l - {[3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -1 H -1, 2,4-triazole, (15.130) 2- [1- (2 , 4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro-3H-l, 2,4-triazole-3-thione, (15.131) 2- {[ rel (2R, 3S) -3- (2-CHLC ^ h enyl) -

2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -2,4-dihydro-3H-1,2,4-triazole-3-thione, (15.132) 2- {[rel (2R, 3R ) -3- (2-chlorophenyl) -2- (2,4-difluoφhenyl) oxiran-2-yl] methyl} -2,4-dihydro-3H-l, 2,4-triazol-

3-thion, (15.133) 1 - {[rel (2R, 3S) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -LH-1, 2, 4-triazol-5-yl thiocyanate, (15.134) 1 - {[rel (2R, 3R) -3- (2-chloro-phenyl) -2- (2,4-difluoro-phenyl) -oxiran-2-yl] -methyl} -H -l, 2,4-triazol-5-yl thiocyanate, (15.135) 5- (allylsulfanyl) -l- {[rel (2R, 3S) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl ) oxiran-2-yl] methyl} -1H-l, 2,4-triazole, (15.136) 5- (allylsulfanyl) -1- [¢ [η (2,3) -3- (2-chloro-phenyl) -2-] (2,4-difluorophenyl) oxiran-2-yl] methyl} -1H-l, 2,4-triazole, (15,137) 2- [(2S, 4S, 5S) -1- (2,4-dichloro-phenyl) - 5-hydroxy-2,6,6-trimethylheptane-4-yl] -2,4-dihydro-3H-l, 2,4-triazol- 3-thione, (15,138) 2 - [(2R, 4S, 5S) -1- (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro 3H-l, 2,4-triazole-3-thione, (15,139) 2 - [(2R, 4R, 5R) -1- (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptane 4-yl] -2,4-dihydro-3H-l, 2,4-triazole-3-thione, (15.140) 2 - [(2S, 4R, 5R) -l- (2,4-)

Dichlo ^ henyl) -5-hydroxy-2,6,6-trimethylheptane-4-yl] -2,4-dihydro-3H-l, 2,4-triazole-3-thione _^ (15,141) of 2- [(2 S , 4S, 5R) -l- (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro-3H-l, 2,4

3-thione, (15,142) 2 - [(2R, 4S, 5R) -1- (2,4-Dichloro-phenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro -3H-l, 2,4-triazole-3-thione, (15,143) 2 - [(2R, 4R, 5S) -1- (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptane 4-yl] -2,4-dihydro-3H-l, 2,4-triazole-3-thione, (15,144) 2 - [(2S, 4R, 5S) -l- (2,4-)

Dichloro) -5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro-3H-1,2,4-triazole-3-thio (15.145) 2-fluoro-6- (trifluoromethyl) -N- (1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl) -benzamide, (15.146) 2- (6-benzylpyridin-2-yl) quinazoline, (15.147) 2- [6- (3-Fluoro-4-methoxyphenyl) -5-methylpyridin-2-yl] quinazoline, (15.148) 3- (4,4-Difluoro-3,3-dimethyl-3,4-dihydroisoquinoline-1 -yl) quinoline, (15.149) abscisic acid, (15.150) 3- (difluoromethyl) -N-niethoxy-1-methyl-N- [1- (2,4,6-trichlorophenyl) propan-2-yl] -1 H pyrazole-4-carboxamide, (15.151) N'- [5-bromo-6- (2,3-dihydro-1H-inden-2-yloxy) -2-methylpyridin-3-yl] -N-ethyl- N-methylimidoformamide, (15.152) N '- {5-bromo-6- [1- (3,5-difluhenyl) ethoxy] -2-methylpyridin-3-yl} -N-ethyl-N-methylimidoformamide, 15,153) N '- {5-bromo-6 - [(1R) -1- (3,5-difluorophenyl) ethoxy] -2-methylpyridin-3-yl} -N-ethyl-N-diethyliniidoformamide, (15.154) N '- {5-bromo-6 - [(1S) -1- (3,5-difluorohexyl) ethoxy] -2-methylpyridin-3-yl} -N-ethyl-N-methylimidoformamide, (15.155) N' - {5-bromo-6 - [(cis-4-ISOPRO pylcyclohexyl) oxy] -2-methylpyridin-3-yl} -N-ethyl-N-methylimidoformamide, (15.156) N '- {5-bromo-6 - [(trans-4-isopropylcyclohexyl) oxy] -2- methylpyridin-3-yl} -N-ethyl-N-methylimidoformamide, (15.157) N-cyclopropyl-3- (difluoromethyl) -5-fluoro-N- (2-isopropylbenzyl) -1-methyl-1H-pyrazole-4 -carboxamide, (15.158) N-Cyclopropyl-N- (2-cyclopropylbenzyl) -3- (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (15.159) N- (2-tert-butyl) butylbenzyl) -N-cyclopropyl-3- (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (15.160) N- (5-chloro-2-ethylbenzyl) -N-cyclopropyl-3 - (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (15.161) N- (5-chloro-2-isopropylbenzyl) -N-cyclopropyl-3- (difluoromethyl) -5-fluoro 1-methyl-1H-pyrazole-4-carboxamide, (15.162) N-cyclopropyl-3- (difluoromethyl) -N- (2-ethyl-5-fluorobenzyl) -5-fluoro-1-methyl-1H-pyrazole-4 - carboxamide, (15.163) N-cyclopropyl-3- (difluoromethyl) -5-fluoro-N- (5-fluoro-2-isopropylbenzyl) -1-methyl-1H-pyrazole-4-carboxamide, (15.164) N-cyclopropyl -N- (2- cyclopropyl-5-fluorobenzyl) -3- (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (15.165) N- (2-cyclopentyl-5-fluorobenzyl) -N-cyclopropyl-3- (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (15.166) N-cyclopropyl-3- (difluoromethyl) -5-fluoro-N- (2-fluoro-6-isopropylbenzyl) -1 -methyl-1H-pyrazole-4-carboxamide, (15.167) N-cyclopropyl-3- (difluoromethyl) -N- (2-ethyl-5-methylbenzyl) -5-fluoro-1-methyl-1H-pyrazole-4 - carboxamide, (15.168) N-cyclopropyl-3- (difluoromethyl) -5-fluoro-N- (2-isopropyl-5-methylbenzyl) -1-methyl-1H-pyrazole-4-carboxamide, (15.169) N-cyclopropyl N- (2-cyclopropyl-5-methylbenzyl) -3- (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (15.170) N- (2-tert-butyl-5- methylbenzyl) - N -cyclopropyl-3- (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (15.171) N- [5-chloro-2- (trifluoromethyl) benzyl] -N-cyclopropyl -3- (difluoromethyl) -5-fluoro-l-methyl-lH-pyrazole-4-carboxamide, (15.172) N-Cyclopropyl-3- (difluoromethyl) -5-fluoro-1-methyl-N- [5-methyl-2- (trifluoropyrazole-4-carboxamide, (15,173) N- [2-chloro-6- (trifluoromethyl) benzyl] -N-cyclopropyl-3- (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (15.174) N- [3-chloro-2-fluoro-6- ( trifluoromethyl) benzyl] -N-cyclopropyl-3- (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (15.175) N-cyclopropyl-3- (di-uormethyl) -N- (2- ethyl-4,5-dimethylbenzyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (15.176) N-cyclopropyl-3- (difluoromethyl) -5-fluoro-N- (2-isopropylbenzyl) -l-methyl-1H-pyrazole-4-carbothioamide, (15.177) 3 - (difluoromethyl) -N- (7-fluoro-1,1,3-trimethyl-2,3-dihydro-1H-indene-4 yl) -1-methyl-1H-pyrazole-4-carboxamide, (15.178) 3- (difluoromethyl) -N - [(3R) -7-fluoro-1,1,3-trimethyl-2,3-dihydro- 1 H -inden-4-yl] -1-methyl-1H-pyrazole-4-carboxamide, (15.179) 3- (difluoromethyl) -N - [(3S) -7-fluoro-1,1,3-trimethyl- 2,3-dihydro-1H-inden-4-yl] -1-methyl-1H-pyrazole-4-carboxamide, (15,180) N '- (2,5-dimethyl) 4-phenoxyphenyl) -N-ethyl-N-methylimidoformamide, (15.181) N '- {4 - [(4,5-dichloro-1,3-thiazol-2-yl) oxy] -2,5-dimethylphenyl} - N-ethyl-N-methylimidoformamide, (15.182) N- (4-chloro-2,6-difluorophenyl) -4- (2-chloro-4-fluorophenyl) -1,3-dimethyl-1H-pyrazole-5- amine. All mentioned

Mixture partners of classes (1) to (15), if they are capable of doing so on the basis of their functional groups, may optionally form salts with suitable bases or acids.

The combinations of the compound of formula (I) with said fungicides have very good fungicidal properties and can be used in the treatment of seeds, in particular for controlling phytopathogenic fungi, such as Ascomycetes and Basidiomycetes. The active compounds according to the invention are particularly suitable in the treatment of seed for controlling Pyrenophora, Rhizoctonia, Tilletia and Ustilago species.

By way of example, but not by way of limitation, some pathogens of fungal diseases, which fall under the abovementioned generic terms, are named:

Pyrenophora species such as P. allosuri, P. alternarina, P. avenae, P. bartramiae, P. bondarzewii, P. bromi, P. bryophila, P. buddleiae, P. bupleuri, P. calvertii, P. calvescens var. moravica, P. carthami, P. centranthi, P. cerastii, P. chengii, P. chrysanthemi, P. convolvuli, P. coppeyana, P. cytisi, P. dactylidis, P. dictyoides, P. echinopis , P. ephemera, P. eryngicola, P. erythrospila, P. euphorbiae, P. freticola, P. graminea, P. heraclei, P. hordei, P. horrida, P. hyperici, P. japonica, P. kugitangi, P Lithophila, P. lolii, P. macrospora, P. metasequoiae, P. minuartiae-hirsutae, P. moravica, P. moroczkovskii, P. muscorum, P. osmanthi, P. phlei, P. pimpinellae, P. pittospori , P. polytricha, P. pontresinerisis, P. pulsatillae, P. raetica, P. rayssiae, P. rugosa, P. saviczii, P. schroeteri, P. scirpi, P. scirpicola, P. secalis, P. semeniperda, P semiusta, P. seseli f. poterii, P. seseli, P. sobolevskii, P. subalpina, P. subantarctica, P. sudetica, P. syntrichiae, P. szaferiana, P. teres f. maculata, P. teres subsp. graminea, P. teres, P. tetrarrhenae, P. tranzschelii, P. trifolii, P. tritici-repentis, P. typhicola, P. ushuwaiensis, P. villosa, Rhizoctonia species, such as, for example, Rh. aerea, Rh. alba, Rh. Alpina, Rh. Anaticula, Rh. Anomala, Rh. Apocynacearum, Rh. Arachnion, Rh. Asclerotica, Rh. Bataticola, Rh. Borealis, Rh. Callae, Rh. Candida, Rh. Carotae, Rh. Cerealis, Rh. choussii, Rh. coniothecioides, Rh. dichotoma, Rh. dimorpha, Rh. endophytica g., var. filicata, Rh. endophytica, Rh. ferraginea, Rh. floccosa, Rh. fragariae, Rh. fraxini, Rh. fuliginea, Rh. fumigata, Rh. globularis, Rh. goodyerae-repentis, Rh. gossypii var. anatolica, Rh gossypii, Rh. gracilis,

Rh. Grisea, Rh. Hiemalis, Rh. Juniperi, Rh. Lamellifera, Rh. Leguminicola, Rh. Lilacina, Rh. Lupini, Rh. Macrosclerotia, Rh. Melongenae, Rh. Microsclerotia, Rh. Monilioides, Rh. Monteithiana, Rh. muneratii, Rh. nandorii, Rh. oryzae, Rh. oryzae-sativae, Rh. pallida, Rh. pini-insignis, Rh. praticola, Rh. quercus,

Ramicola, Rh. Robusta, Rh. Rubi, Rh. Rubiginosa, Rh. Sclerotica, Rh. Solani, Rh. Solani f. paroketea,

Solani forma specialis, Rh. Solani var. Cedri-deodarae, Rh. Solani var. Fuchsiae, Rh. Solani var. Hortensis, Rh. Stahlii, Rh. Subtilis var. Nigra, Rh. Subtilis, Rh. Tomato, Rh. tuliparum, Rh. versicolor, Rh. zeae, Tilletia species such as T. aegilopis, T. aegopogonis, T. ahmadiana, T. airina, T. ajrekari, T. alopecuri, T. anthoxanthi, T. apludae, T. arundinellae, T. asperifolia, T. asperitolioides, T. atacamensis, T. baldrati, T. bambusae, T. banarasae, T. bangalorensis, T. barclayana, T. biharica, T. bolayi, T. boliviensis, T. boutelouae, T. brachypodii, T. brachypodii ramosi, T. brevifaciens, T. bromi.,

T. bromina, T. bromo-tectorum, T. brunkii, T. buchloeana, T. caries, T. cathcartae, T. cerebrina, T. chloridicola, T. controversa, T. controversa var. Elymi, T. controversa var. prostrata, T. Corona, T. cynosuri, T. dacamarae, T. deyeuxiae, T. digitariicola, T. durangensis, T. earlei, T. echinochloae f. foliicola, T. echinochloae, T. echinosperma, T. ehrhartae, T. elegusines, T. elymandrae, T. elymi, T. elymicola, T. elytrophori, T. eragrostidis, T. euphorbiae, T. fahrendorfii, T. festuca- octoflorana, T.foetida, T. fusca, T.fusca var. bromo-tectorum, T.fusca var. guyotiana, T.fusca var. patagonica, T. georfischeri, T. gigaspora, T.goloskokovii, T. haynaldiae, T. heterospora, T. holci, T. hordei var. spontanei, T. horrida, T. hyalospora var. cuzcoensis, T. hyparrheniae, T. indica, T. intermedia, T. iowensis, T. ixophori, T. koeleriae, T kuznetzoviana, T. laevis, T. laguri, T. leptochloae, T. lepturi, T. lycuroides, T. maclaganii, T. macrotuberculata, T. madeirensis, T. makutensis, T. milii vernalis, T. milli,

T. montana, T. montemartinii, T. nanifica, T. narasimhanii, T. narayanaraoana, T. narduri, T. nigrifaciens, T. obscura-reticulata, T. oklahomae, T. okudairae, T. oplismeni-cristati, T. pachyderma, T. pallida, T. panici, T. panici-humilis, T. paradoxa, T. paspali, T. pennisetina, T. perotidis, T. phalaridis,

T. poae, T. polypogonis, T. poonensis, T. prostrata, T. pulcherrima var. Brachiariae, T. redfieldiae, T. rhei, T. rugispora, T. sabaudiae, T. salzmannii, T. savilei, T. scrobiculata T. setariae, T. setariae palmiflorae, T. setariicola, T. sphaerococca, T. sphenopi, T. sphenopodis, T. sterilis, T. taiana, T. texana,

T. themedae-anatherae, T. themedicola, T. togwateei, T. trachypogonis, T. transiliensis, T. transvaalensis, T. tritici [var.] Nanifica, T. tritici f. monococci, T. tritici var. controversa, T. tritici var. laevis, T. tritici-repentis, T. triticoides, T. tuberculata, T. vetiveriae, T. viennotii, T. vittata var. burmannii, T. vittata, T. Walkeri, T. youngii, T. zundelii. Ustilago species, such as U. abstrusa,

U. aegilopsidis, U. aeluropodis, U. affinis var. Hilariae, U. agrestis, U. agropyrina, U. agrostis palustris,

U. ahmadiana, U. airae-caespitosae, U. alismatis, U. alopecurivora, U. asineae, U. altilis, U. amadelpha var. Glabriuscula, U. amphilophidis, U. amplexa, U. andropogonis-tectorum, U. aneilemae U. anhweiana, U. anomala [var.] Microspora, U. anomala var. Avicularis, U. anomala var. Carnea, U. anomala var. Cordai, U. anomala var. Muricata, U. anomala var. Tovarae, U anthoxanthi, U. apscheronica, U. arabidia alpinae, U. arctagrostis, U. arctica, U. arenariae bryophyllae, U. argentina, U. aristidarius, U. arundinellae-hirtae, U. asparagi-pygmaei, U. asprellae, U. avenae f.sp. perennans, U. avenae subsp. barbellis, U. bahuichivoensis, U. barberi, U. beckeropsis, U. belgiana, U. bethelii, U. bicolor, U. bistortarum var. marginalis, U. bistortarum var. pustulata, U. bistortarum var. ustilaginea U. borealis, U. bothriochloae, U. bothriochloae intermediae, U. bouriqueti, U. braziliensis, U. brizae, U. bromo-arvensis, U. bromi-erecti, U. bromi-mollis, U. bromina, U bromivora f. brachypodii, U. bromivora var. microspora, U. bullata f. brachypodii distachyi, U. bullata var. bonariensis, U. bullata var. macrospora, U. bungeana, U. calamagrostidis var. scrobiculata, U. calamagrostidis var. typica, U. calamagrostidis, U. cardamines, U. cariciphila, U. caricis-wallichianae,

U. carnea, U. catherinae, U. caulicola, U. centrodomis, U. ceparum, U. cephalariae, U. chacoensis, U. chloridii, U. chloridionis, U. chrysopogonis, U. chubutensis, U. cichorii, U. cilinodis, U. clelandii, U. clintoniana, U. coloradensis, U. commelinae, U. compacta, U. concelata, U. condigna, U. consimilis, U. constantineanui, U. controversa, U. convertere-sexualis, U. cordai, U. coronariae, U. coronata, U. cortaderiae var. araucana, U. courtoisii, U. crus-galli var. minor, U. cryptica, U. curta, U. custanaica, U. cynodontis f. ovariicola, U. cynodontis, U. cyperi-lucidi, U. davisii, U. deccanii, U. decipiens, U. deformis, U. dehiscens, U. delicata, U. deyeuxiae, U. dianthorum, U. distichlidis, U. dubiosa, U. dumosa, U. earlei, U. echinochloae, U. ehrhartana, U. eleocharidis, U. elegusines, U. elymicola, U. elytrigiae, U. enneapogonis, U. epicampida, U. eragrostidis-japonicana, U. eriocauli, U. eriochloae, U. euphorbiae, U. fagopyri, U. festucae, U. festucarum, U. filamenticola, U. fmgerhuthiae, U. flectens, U. flowersii, U. foliorum, U. formosana, U. fueguina, Gageae, U. garcesi, U. gardneri, U. gaussenii, U. gigantispora, U. glyceriae, U. goyazana, U. gregaria, U. grossheimii, U. gunnerae, U. haesendocki var. Chloraphorae, U. halophiloides var. vargasii, U. halophiloides, U. haynaldiae, U. heleochloae, U. helictotrichi, U. herteri var. bicolor, U. hierochloae odoratae, U. hieronymi var. insularis, U. hieronymi var. minor, U. hilariicola , U. himalensis, U. hitchcockiana, U. holci-avenacei, U. holubii, U. h ordei, U. hordei f.sp. avenae, U. hsuii, U. hyalino bipolaris, U. hydropiperis, U. hyparrheniae, U. hypodytes f. congoensis, U. hypodytes f. sporoboli, U. hypodytes var. agrestis, U. idonea, U. imperatae, U. induta, U. inouyei, U. intercedens, U. iranica, U. isachnes, U. ischaemi-akoensis, U. ischaemi-anthephoroidis, U ixiolirii, U. ixophori, U. jacksonii var. ventanensis, U. jacksonii, U. jaczevskyana var. sibirica, U. jaczevskyana var. typica, U. jaczevskyana, U. jagdishwari, U. jalalainenii, U. judeudana, U. johnstonii,

U. kairamoi, U. kazachstanica, U. kenjiana, U. kweichowensis, U. kyllingae, U. lachrymae-jobi, U. lepyrodiclidis, U. lidii, U. liebbergii, U. linderi, U. linearis, U. liroae, U. loliicola, U. longiflora, U. longiseti, U. longissima var. Dubiosa, U. longissima var. Paludificans, U. longissima var. Typica, U. lupini, U. lychnidis dioicae, U. lycoperdiformis, U. lyginiae , U. machili, U. magellanica, U. mariscana,

U. maydis, U. megalospora, U. melicae, U. merxmuellerana, U. mesatlantica, U. michnoana, U. microspora var. Paspalicola, U. microspora, U. microstegii, U. microthelis, U. mihi, U. modesta U. moehringiae, U. moenchiae manticae, U. monermae, U. montagnei var. Minor, U. morinae, U. morobiana, U. muehlenbergiae var. Tucumanensis, U. muricata, U. muscari-botryoidis, U. nagornyi U. nannfeldtii, U. nelsoniana, U. nepalensis, U. neyraudiae, U. nigra, U. nivalis, U. nuda, U. nuda var. Hordei, U. nuda var. Tritici, U. nyassae, U. okudairae , U. olida, U. olivacea var. Macrospora, U. onopordi, U. onumae, U. opiziicola, U. oplismeni, U. orientalis, U. otophora, U. overeemii, U. pamirica, U. panici- geminati, U. panjabensis, U. pappophori var. Magdalensis, U. pappophori, U parasparathii, U. parodii, U. parvula, U. paspalidiicola, U. patagonica, U. penniseti var. verruculosa, U. perrara, U. persicariae, U. petrakii, U. phalaridis, U. phlei, U. phlei. pratensis, U. phragmites, U. picacea, U. pimprina, U. piperi [var.] rosulata, U. poae, U. poae-bulbosae, U. poae-nemoralis, U. polygoni-alati, U. polygoni-alpini U. polygoni-punctati, U. polygoni-serrulati, U. polytocae, U. polytocae-barbatae, U. pospelovii, U. prostrata, U. pseudohieronymi, U. pueblaensis, U. puellaris, U. pulverulenta, U. raciborskiana , U. radians, U. ravida, U. rechingeri, U. reticulata, U. reticulispora, U. rhei, U. rhynchelytri, U. rwandensis,

U. sabouriana, U. salviae, U. sanctae-catharinae, U. scaura, U. Scillae, U. scitaminea var. Saccharibarberi, U. scitaminea var. Sacchari-officinarum, U. scitaminea, U. scleranthi, U. scrobiculata, U. scutulata, U. secalis var. elymi, U. semenoviana, U. Serena, U. serpens, U. sesleriae, U. setariae mombassanae, U. shastensis, U. shimadae, U. silenes-inflatae, U silenes-nutantis, U. sinkiangensis, U. sitanii, U. sleumeri, U. sonoriana, U. sorghi-stipoidei, U. spadicea, U. sparti, U. speculariae, U. spegazzinii var. agrestis, U. spegazzinii, Spermophora var. Orientalis, U. spermophoroides, U. spinulosa, U. sporoboli indici, U. sporoboli tremuli, U. stellariae, U. sterilis, U. stewartli, U. stipae, U. striaeformis f. agrostidis, U. striaeformis f. phlei, U. striaeformis f. poaeannuae, U. striaeformis f. poa pratensis, U. striiformis f. stochiformis var. dactylidis, U. striiformis var. holci, U. striiformis var. phlei, U. striiformis var. poae, U. stygia, U. sumnevicziana, U. superba U. sydowiana, U. symbiotica, U. taenia, U. taiana, U. tanakae, U. tenuispora, U. thaxteri, U. tinantiae, U. togata, U. tourneuxii, U. tovarae, U. trachyniae, U trachypogonis, U. tragana, U. tragi, U. tragica, U. tragi racemosi, U. trichoneurana, U. trichophora var. crus-galli, U. trichophora var. panici frumentacei, U. triseti, U. tritici forma specialis, U. trochophora var. pacifica, U. tuberculata, U. tucumanensis, U. tumeformis, U. turcomanica var. prostrata, U. turcomanica var. typica, U. turcomanica, U. ugamica, U. ugandensis var. macrospora U. underwoodii, U. urginede, U. urochloana, U. ustilaginea, U. utriculosa var. Cordai, U. utriculosa var. Reticulata, U. valentula, U. vavilovi, U. verecunda, U. verruculosa, U. versatilis , U. vetiveriae, U. violacea var. Stellariae, U. v iolaceo irregularis, U. violaceoverrucosa, U. williamsii, U. wynaadensis, U. zambettakisii, U. zernae.

Plants and Plant Parts According to the invention, all plants and plant parts can be treated. Plants are understood to mean all plants and plant populations, such as desirable and unwanted wild plants or crops (including naturally occurring crops), for example cereals (wheat, rice, triticale, barley, rye, oats), corn, soybeans, potatoes, sugar beets, sugarcane, tomatoes , Peas and other vegetables, cotton, tobacco, oilseed rape, as well as fruit plants (with the fruits apples, pears, citrus fruits and grapes). Crop plants can be plants obtained by conventional breeding and optimization methods or by biotechnological and genetic engineering methods or combinations of these methods including transgenic plants and including those plant varieties which can or can not be protected by plant breeder's rights. Plant parts are understood to mean all aboveground and subterranean parts and organs of plants such as shoot, leaf, flower and root, examples of which include leaves, needles, stems, stems, flowers, fruiting bodies, fruits and seeds, and roots, tubers and rhizomes. The plant parts also include crops and vegetative and generative propagation material, such as cuttings, tubers, rhizomes, offshoots and seeds.

The treatment according to the invention of the plants and plant parts with the compound of the formula (I) is carried out directly or by acting on their environment, habitat or storage room according to the usual treatment methods, e.g. by dipping, spraying, evaporating, atomizing, spreading, brushing, injecting and in propagating material, in particular in seeds, further by single or multilayer coating.

As already mentioned above, all plants and their parts can be treated according to the invention. In a preferred embodiment, wild-type or plant species and plant varieties obtained by conventional biological breeding methods such as crossing or protoplast fusion and parts thereof are treated. In a further preferred embodiment, transgenic plants and plant cultivars obtained by genetic engineering, if appropriate in combination with conventional methods (Genetically Modified Organisms), and parts thereof are treated. The term "parts" or "parts of plants" or "parts of plants" has been explained above.Propes of the respective commercially available or in use plant varieties are particularly preferably treated according to the invention.PV plants are understood as meaning plants with new properties ("traits") have been bred either by conventional breeding, by mutagenesis or by recombinant DNA techniques. These may be varieties, breeds, biotypes and genotypes. Transgenic plant, seed treatment and integration events

The preferred plants or plant varieties to be treated according to the invention to be treated include all plants which, as a result of the genetic engineering modification, obtained genetic material which gives these plants particularly advantageous valuable properties ("traits"). Examples of such properties are better plant growth, increased tolerance to high or low temperatures, increased tolerance to dryness or to bottoms salt, increased flowering, easier harvesting, acceleration of ripeness, higher crop yields, higher quality and / or higher nutritional value of the harvested products , higher shelf life and / or workability of the harvested products. Further and particularly emphasized examples of such properties are an increased resistance of the plants against animal and microbial pests, such as insects, arachnids, nematodes, mites, snails, caused for example by toxins formed in the plants, in particular those caused by the genetic material from Bacillus Thuringiensis (eg by the genes CrylA (a), CrylA (b), CrylA (c), CryllA, CrylllA, CryIIIB2, Cry9c Cry2Ab, Cry3Bb and CrylF and their combinations) are produced in the plants, furthermore an increased resistance of the plants against Phytopathogenic fungi, bacteria and / or viruses, eg by systemically acquired resistance (SAR), systemin, phytoalexins, elicitors and resistance genes and correspondingly expressed proteins and toxins, and increased tolerance of the plants against certain herbicidal active ingredients, such as imidazolinones, sulfonylureas, glyphosate or phosphinotricin (eg, "PAT" gene). The genes which confer the desired properties ("traits") can also occur in combinations with one another in the transgenic plants. Examples of transgenic plants are the important crops such as cereals (wheat, rice, triticale, barley, rye, oats), corn, soy, potato, sugar beets, sugarcane, tomatoes, peas and other vegetables, cotton, tobacco, oilseed rape, and fruit plants (with the fruits apples, pears, citrus fruits and grapes), with special emphasis on corn, soy, wheat, rice, potato, cotton, sugar cane, tobacco and oilseed rape. Traits that are particularly emphasized are the increased immunity of the plants to insects, arachnids, nematodes and snails.

The good effect of the compound of the formula (I) against stink bugs in surface crops is evident from the following examples:

Biological examples

example 1

Nezara viridula test (EZAVI)

Solvent: 7 parts by weight of dimethylformamide Emulsifier: 1 part by weight of alkylaryl polyglycol ether

To produce a suitable active compound preparation, 1 part by weight of active compound is mixed with the stated amounts of solvent and emulsifier, and the concentrate is diluted with water to the desired concentration. If required addition of ammonium salts or ammonium salts and penetration requisite these are pipetted in a concentration of lOOOppm after dilution of each of the finished preparation solution.

Cotton plants (Gossypium hirsutum) or barley plants (Hordeum vulgare) are treated by spraying with the preparation of active compound in the desired concentration and then populated with larvae of the green rice bug (Nezara viridula).

After the desired time the kill is determined in%. 100% means that all rice bugs have been killed; 0% means that no rice bugs have been killed.

In this test, the result shown in the table was obtained:

 dat = days after treatment

It is therefore achieved a good effect in a dicotylen- (eg cotton plant (Gossypium hirsutum)) and in a monocotyledonous (eg barley plants (Hordeum vulgare)) crop. Example 2

Euschistus heros test (EUSCHE)

Solvent: 7 parts by weight of dimethylformamide

Emulsifier: 1 part by weight of alkylaryl polyglycol ether

To prepare a suitable preparation of active compound, 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with water to the desired concentration. When necessary addition of ammonium salts or ammonium salts and Penetrationsför those these are pipetted in a concentration of l OOOppm after dilution of each of the finished preparations solution.

Cotton plants (Gossypium hirsutum, GOSHI), soybean plants (Glycine max, GLXMA)) or maize plants (Zea mays, ZEAMX) are treated by spraying with the preparation of active compound in the desired concentration and then populated with 10 larvae of the brown stink bug (Euschistus heros, EUSCHE) ,

After 6 days, the phytoprotective effect is determined in%. 100% means that no damage can be seen; 0% means that the damage to the treated leaves is the same as the untreated control.

In this test, the compound of formula (I) exhibited the activity shown in the following table:

Compound of the formula (I) Object Plant Concentration% Action

EUS GOSHI 100 ppm 100

GLXMA 100 ppm 90

ZEAMX 100 ppm 90

Example 3

Euschistus heros test (EUSCHE)

Solvent: 7 parts by weight of dimethylformamide

Emulsifier: 1 part by weight of alkylaryl polyglycol ether To prepare a suitable preparation of active compound, 1 part by weight of active compound is dissolved with the stated parts by weight of solvent and filled with water containing an emulsifier concentration of 1000 ppm until reaching the desired concentration. To prepare further test concentrations, dilute with emulsifier-containing water. Ammonium salts and Penetrationsförderer (rapeseed oil methyl ester) are added to the preparation solution in a concentration of 1000 ppm.

Cotton plants (Gossypium hirsutum - GOSHI) and bush bean plants (Phaseolus vulgaris - PHSVX) are treated by spraying with the preparation of active compound in the desired concentration and then populated with 10 larvae of the brown stink bug {Euschistus heros).

After the desired time, the phytosanitary effect is determined in%. 100% means that no damage can be seen; 0% means that the damage to the treated leaves is the same as the untreated control. In addition, the kill is determined in%. A mortality of 100% means that all bugs have been killed; 0% means that no bugs have been killed.

In this test, the compound of the formula (I) showed the activity given in the table following Example 4.

Example 4

Nezara viridula test (NEZAVI)

Solvent: 7 parts by weight of dimethylformamide

Emulsifier: 1 part by weight of alkylaryl polyglycol ether To prepare a suitable preparation of active compound, 1 part by weight of active compound is dissolved with the stated parts by weight of solvent and filled with water containing an emulsifier concentration of 1000 ppm until reaching the desired concentration. To prepare further test concentrations, dilute with emulsifier-containing water. Ammonium salts and Penetrationsförderer (rapeseed oil methyl ester) are added to the preparation solution in a concentration of 1000 ppm.

Cotton plants (Gossypium hirsutum - GOSHI), maize plants (Zea mays - ZEAMX), soybean plants (Glycine max - GLXMA) and bush bean plants (Phaseolus vulgaris - PHSVX) are treated by spraying with the preparation of active compound in the desired concentration and are subsequently treated with larvae of the green rice bug ( Nezara viridula). After the desired time, mortality is determined in%. 100% means that all bugs have been killed; 0% means that no bugs have been killed.

In the tests according to Examples 3 and 4, the compound of formula (I) showed the activity / feeding protection given in the table below.

 TnB = days after treatment

Claims

claims

1. Use of the compound of the formula (I)

for combating animal pests of the family of spotted bugs (Pentatomidae), except for the control of Brown-Winged Green Bugs on apples treated with the compound of formula (I).