WO2015046426A1 - Coated surface regeneration agent and coated surface regeneration method - Google Patents
Coated surface regeneration agent and coated surface regeneration method Download PDFInfo
- Publication number
- WO2015046426A1 WO2015046426A1 PCT/JP2014/075626 JP2014075626W WO2015046426A1 WO 2015046426 A1 WO2015046426 A1 WO 2015046426A1 JP 2014075626 W JP2014075626 W JP 2014075626W WO 2015046426 A1 WO2015046426 A1 WO 2015046426A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- painted surface
- coated surface
- surface regeneration
- acrylic copolymer
- synthetic resin
- Prior art date
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
- C09D5/028—Pigments; Filters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/66—Additives characterised by particle size
- C09D7/67—Particle size smaller than 100 nm
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/66—Additives characterised by particle size
- C09D7/68—Particle size between 100-1000 nm
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
Definitions
- the present invention relates to a painted surface regenerating agent that can revive the color of the painted surface simply by applying after washing the deteriorated painted surface, and a painted surface regenerating method using the painted surface regenerating agent.
- Patent Document 1 Patent No. 3185572
- Patent Document 1 Patent No. 3185572
- a method of exposing a new painted surface and applying a transparent coating agent to the new painted surface is known.
- the conventional method of regenerating a deteriorated painted surface requires a step of polishing the painted surface from which dirt has been removed with a polisher to expose a new painted surface.
- a polisher is required to expose the new painted surface, which raises the initial cost, requires time and effort, and makes it difficult to polish the vertical painted surface.
- the worker was burdened.
- the present invention is necessary for reconstructing the color of the deteriorated painted surface without polishing the painted surface with a polisher. The purpose is to reduce the cost and to easily perform the work in a short time.
- the coated surface regenerating agent of the invention according to claim 1 is obtained by adding a surfactant, a film-forming aid, and water to an acrylic copolymer synthetic resin emulsion containing inorganic fine particles, and the inorganic fine particles And the amount of the inorganic fine particles is 0.05 to 1.5 parts by weight with respect to 1 part by weight of the resin in the acrylic copolymer-based synthetic resin emulsion. And
- the painted surface regenerating agent of the invention according to claim 2 is characterized in that an ultraviolet absorber is further added to the painted surface regenerating agent according to claim 1.
- the painted surface regenerating agent of the invention according to claim 3 is characterized in that a thickener is further added to the painted surface regenerating agent according to claim 1 or 2.
- a painted surface regeneration method the step of washing a deteriorated painted surface, and applying the painted surface regeneration agent according to any one of claims 1 to 3 without polishing the washed painted surface. And a step of naturally drying the coating surface regenerating agent applied to the painted surface.
- acrylic copolymer-based synthetic resin emulsion an acrylate copolymer emulsion or an acrylic-styrene copolymer emulsion is used, and an appropriate one is added depending on the purpose of use, taking weather resistance, film strength, cost, etc. into consideration. Select use.
- the particle size of the inorganic fine particles may be 5 to 300 nm in the colloidal region, but is preferably 5 to 50 nm, and more preferably 8 to 20 nm. If the particle size of the inorganic fine particles is too large, the wettability of the painted surface regenerating agent and the wettability of the painted surface are lowered, so that the ability to revive the color of the painted surface is lowered.
- the amount of the inorganic fine particles may be 0.05 to 1.5 parts by weight, preferably 0.1 to 1 part by weight, based on 1 part by weight of the resin in the acrylic copolymer synthetic resin emulsion. More preferably, it is 0.4 to 0.8 part by weight.
- the inorganic fine particle material examples include various inorganic oxides or inorganic composite oxides (Si, Al, Ti, Zr, Ce, Mg, Ca, Fe, Sn, Zn, W, Sb, K, Na, P, B, etc. Single oxide or composite oxide) and various inorganic salts (silicate, phosphate, aluminate, carbonate, etc.) can be used, and silica (SiO 2 ) is particularly preferable.
- the acrylic copolymer synthetic resin emulsion containing inorganic fine particles is produced by emulsion polymerization of an acrylic monomer in the presence of inorganic fine particles.
- an acrylic monomer n-butyl methacrylate (BMA), methyl methacrylate (MMA), butyl acrylate (BA), styrene (ST) or a combination thereof can be used, and BMA is particularly preferable.
- the painted surface regenerating agent of the invention according to claim 1, after the deteriorated painted surface is washed, the painted surface regenerating agent is faded by simply applying and drying the painted surface using a brush or a sponge. Since the color of the painted surface is revived, the labor and time-consuming work of polishing the deteriorated painted surface and exposing the new painted surface can be omitted. Therefore, it is possible to quickly regenerate the deteriorated painted surface at a small initial cost. Moreover, since the transparent and hard film
- the film formed on the paint surface suppresses the transmission of ultraviolet rays, so the deterioration rate of the subsequent paint surface is reduced. It can be further lowered.
- the viscosity of the painted surface regenerating agent can be increased. Even if it is applied to the surface of the paint surface, the paint surface regenerant is supplied from the top of the paint surface using a brush or sponge, etc. By recovering the surface regenerating agent and naturally drying it, a film having a substantially uniform thickness can be formed on the vertical painted surface.
- the step of cleaning the deteriorated painted surface, the painted surface regenerating agent according to any one of claims 1 to 3 without polishing the cleaned painted surface Since it consists of the process of apply
- the drawing substitute photograph which shows the state which wash
- An acrylic monomer was emulsion polymerized in the presence of colloidal silica having a particle size of 8 to 20 nm to obtain 88 parts of an acrylic copolymer synthetic resin emulsion containing colloidal silica.
- the resin content (acrylic copolymer) of this acrylic copolymer synthetic resin emulsion was 23.7 parts, and the colloidal silica was 14.2 parts.
- the ratio of the resin content to the colloidal silica was 1: 0.60 by weight, and the solid content of the acrylic copolymer-based synthetic resin emulsion containing the colloidal silica (total amount of the resin content and the colloidal silica) was 43% by weight. It was.
- FIG. 1 shows a photograph of a traffic sign 1 in which a cured film of a painted surface regenerating agent is formed on the right half surface 2 and no painted surface regenerating agent is applied on the left half surface 3.
- the adhesion of the formed film to the painted surface was confirmed by a cross-cut test and was sufficient for practical use. Moreover, as a result of measuring the hardness of the film formed by the pencil scratch tester method specified in JIS K5400, the hardness was 3H, which was sufficient for practical use.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Nanotechnology (AREA)
- Dispersion Chemistry (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The present invention provides a coated surface regeneration agent and a coated surface regeneration method allowing, without polishing a deteriorated coated surface with a polisher, the color of the coated surface to be restored, the costs required for application to be decreased, and the work to be performed effortlessly and in a short time. This coated surface regeneration agent contains a surfactant, a film-forming helper, and water added to an acrylic copolymer synthetic resin emulsion containing a mineral microparticle, said coated surface regeneration agent being characterized in that the diameter of the mineral microparticle is 5 to 300 nm, and the amount of the mineral microparticle is 0.05 to 1.5 parts by weight with respect to 1 part by weight of resin fraction in the acrylic copolymer synthetic resin emulsion. In addition, this coated surface regeneration method comprises each of the steps for applying the coated surface regeneration agent.
Description
この発明は、劣化した塗装面を洗浄した後に塗布するだけでその塗装面の色を蘇生することのできる塗装面再生剤及びその塗装面再生剤を用いる塗装面再生方法に関するものである。
The present invention relates to a painted surface regenerating agent that can revive the color of the painted surface simply by applying after washing the deteriorated painted surface, and a painted surface regenerating method using the painted surface regenerating agent.
従来、劣化した塗装面を再生する方法としては、特許文献１（特許第３１８５７７２号公報）に記載されるように、塗装面の汚れを除去し、汚れを除去した塗装面をポリッシャーで研磨して新しい塗装面を露出させ、新しい塗装面に透明なコーティング剤を塗布する方法が知られている。
Conventionally, as described in Patent Document 1 (Patent No. 3185572), as a method of regenerating a deteriorated painted surface, dirt on the painted surface is removed, and the painted surface from which the dirt has been removed is polished with a polisher. A method of exposing a new painted surface and applying a transparent coating agent to the new painted surface is known.
しかし、従来の劣化した塗装面を再生する方法は、汚れを除去した塗装面をポリッシャーで研磨して新しい塗装面を露出させる工程を必要とするため、施工に際して洗浄装置、洗浄液、コーティング剤及びコーティング剤塗布具だけでなく、新しい塗装面を露出させるためのポリッシャーが必要であり、初期コストがかさむという問題、作業に手間と時間がかかるという問題、垂直な塗装面への施工に際して研磨作業が難しく作業員に負担がかかるという問題があった。
本発明は、このような従来の劣化した塗装面を再生する方法における問題点に鑑み、塗装面をポリッシャーで研磨することなく、劣化した塗装面の色を蘇生できるようにすること、施工に必要なコストを下げること、及び作業を楽に短時間に行えるようにすることを目的とする。 However, the conventional method of regenerating a deteriorated painted surface requires a step of polishing the painted surface from which dirt has been removed with a polisher to expose a new painted surface. In addition to the agent applicator, a polisher is required to expose the new painted surface, which raises the initial cost, requires time and effort, and makes it difficult to polish the vertical painted surface. There was a problem that the worker was burdened.
In view of the problems in the conventional method for regenerating a deteriorated painted surface, the present invention is necessary for reconstructing the color of the deteriorated painted surface without polishing the painted surface with a polisher. The purpose is to reduce the cost and to easily perform the work in a short time.
本発明は、このような従来の劣化した塗装面を再生する方法における問題点に鑑み、塗装面をポリッシャーで研磨することなく、劣化した塗装面の色を蘇生できるようにすること、施工に必要なコストを下げること、及び作業を楽に短時間に行えるようにすることを目的とする。 However, the conventional method of regenerating a deteriorated painted surface requires a step of polishing the painted surface from which dirt has been removed with a polisher to expose a new painted surface. In addition to the agent applicator, a polisher is required to expose the new painted surface, which raises the initial cost, requires time and effort, and makes it difficult to polish the vertical painted surface. There was a problem that the worker was burdened.
In view of the problems in the conventional method for regenerating a deteriorated painted surface, the present invention is necessary for reconstructing the color of the deteriorated painted surface without polishing the painted surface with a polisher. The purpose is to reduce the cost and to easily perform the work in a short time.
請求項１に係る発明の塗装面再生剤は、無機質微粒子を含有するアクリル共重合体系合成樹脂エマルジョンに、界面活性剤と、造膜助剤と、水を添加したものであって、前記無機質微粒子の粒径が、５～３００ｎｍであり、前記無機質微粒子の量が、前記アクリル共重合体系合成樹脂エマルジョン中の樹脂分１重量部に対し、０．０５～１．５重量部であることを特徴とする。
The coated surface regenerating agent of the invention according to claim 1 is obtained by adding a surfactant, a film-forming aid, and water to an acrylic copolymer synthetic resin emulsion containing inorganic fine particles, and the inorganic fine particles And the amount of the inorganic fine particles is 0.05 to 1.5 parts by weight with respect to 1 part by weight of the resin in the acrylic copolymer-based synthetic resin emulsion. And
請求項２に係る発明の塗装面再生剤は、請求項１に記載の塗装面再生剤に、紫外線吸収剤をさらに添加したことを特徴とする。
The painted surface regenerating agent of the invention according to claim 2 is characterized in that an ultraviolet absorber is further added to the painted surface regenerating agent according to claim 1.
請求項３に係る発明の塗装面再生剤は、請求項１又は２に記載の塗装面再生剤に、増粘剤をさらに添加したことを特徴とする。
The painted surface regenerating agent of the invention according to claim 3 is characterized in that a thickener is further added to the painted surface regenerating agent according to claim 1 or 2.
請求項４に係る発明の塗装面再生方法は、劣化した塗装面を洗浄する工程、洗浄した前記塗装面を研磨せずに請求項１ないし３のいずれかに記載の塗装面再生剤を塗布する工程、及び前記塗装面に塗布した塗装面再生剤を自然乾燥させる工程からなることを特徴とする。
According to a fourth aspect of the present invention, there is provided a painted surface regeneration method, the step of washing a deteriorated painted surface, and applying the painted surface regeneration agent according to any one of claims 1 to 3 without polishing the washed painted surface. And a step of naturally drying the coating surface regenerating agent applied to the painted surface.
アクリル共重合体系合成樹脂エマルジョンとしては、アクリル酸エステル共重合体エマルジョン又はアクリル－スチレン共重合体エマルジョンが用いられ、使用目的に応じて耐候性、被膜強度、コストなどを加味して適当なものを選択使用する。
As the acrylic copolymer-based synthetic resin emulsion, an acrylate copolymer emulsion or an acrylic-styrene copolymer emulsion is used, and an appropriate one is added depending on the purpose of use, taking weather resistance, film strength, cost, etc. into consideration. Select use.
無機質微粒子の粒径は、コロイド領域の５～３００ｎｍであれば良いが、好ましくは５～５０ｎｍ、さらに好ましくは８～２０ｎｍである。無機質微粒子の粒径が大きすぎると塗装面再生剤の濡れ性及び塗装面への浸潤性が低下するため、塗装面の色を蘇生する能力が低下する。
また、無機質微粒子の量は、アクリル共重合体系合成樹脂エマルジョン中の樹脂分１重量部に対し、０．０５～１．５重量部であれば良いが、好ましくは０．１～１重量部、さらに好ましくは０．４～０．８重量部である。無機質微粒子の量が余りに少ないときは塗装面に対する密着性、硬度などの点で所期の効果が得られず、余りに多いときは密着性、透明性などの点で不利となる。
無機質微粒子の材料としては、各種無機酸化物又は無機複合酸化物（Ｓｉ、Ａｌ、Ｔｉ、Ｚｒ、Ｃｅ、Ｍｇ、Ｃａ、Ｆｅ、Ｓｎ、Ｚｎ、Ｗ、Ｓｂ、Ｋ、Ｎａ、Ｐ、Ｂ等の単独酸化物または複合酸化物）、各種無機塩（ケイ酸塩、リン酸塩、アルミン酸塩、炭酸塩等）を用いることができるが、シリカ（ＳｉＯ２）が特に好適である。
無機質微粒子を含有するアクリル共重合体系合成樹脂エマルジョンは、無機質微粒子の共存下にアクリルモノマーをエマルジョン重合して製造する。アクリルモノマーとしては、ｎ－ブチルメタクリレート（ＢＭＡ）、メチルメタクリレート（ＭＭＡ）、ブチルアクリレート（ＢＡ）、スチレン（ＳＴ）やこれらの組み合わせを用いることができるが、ＢＭＡが特に好適である。 The particle size of the inorganic fine particles may be 5 to 300 nm in the colloidal region, but is preferably 5 to 50 nm, and more preferably 8 to 20 nm. If the particle size of the inorganic fine particles is too large, the wettability of the painted surface regenerating agent and the wettability of the painted surface are lowered, so that the ability to revive the color of the painted surface is lowered.
The amount of the inorganic fine particles may be 0.05 to 1.5 parts by weight, preferably 0.1 to 1 part by weight, based on 1 part by weight of the resin in the acrylic copolymer synthetic resin emulsion. More preferably, it is 0.4 to 0.8 part by weight. When the amount of the inorganic fine particles is too small, the desired effect cannot be obtained in terms of adhesion to the coated surface and hardness, and when it is too large, it is disadvantageous in terms of adhesion and transparency.
Examples of the inorganic fine particle material include various inorganic oxides or inorganic composite oxides (Si, Al, Ti, Zr, Ce, Mg, Ca, Fe, Sn, Zn, W, Sb, K, Na, P, B, etc. Single oxide or composite oxide) and various inorganic salts (silicate, phosphate, aluminate, carbonate, etc.) can be used, and silica (SiO 2 ) is particularly preferable.
The acrylic copolymer synthetic resin emulsion containing inorganic fine particles is produced by emulsion polymerization of an acrylic monomer in the presence of inorganic fine particles. As the acrylic monomer, n-butyl methacrylate (BMA), methyl methacrylate (MMA), butyl acrylate (BA), styrene (ST) or a combination thereof can be used, and BMA is particularly preferable.
また、無機質微粒子の量は、アクリル共重合体系合成樹脂エマルジョン中の樹脂分１重量部に対し、０．０５～１．５重量部であれば良いが、好ましくは０．１～１重量部、さらに好ましくは０．４～０．８重量部である。無機質微粒子の量が余りに少ないときは塗装面に対する密着性、硬度などの点で所期の効果が得られず、余りに多いときは密着性、透明性などの点で不利となる。
無機質微粒子の材料としては、各種無機酸化物又は無機複合酸化物（Ｓｉ、Ａｌ、Ｔｉ、Ｚｒ、Ｃｅ、Ｍｇ、Ｃａ、Ｆｅ、Ｓｎ、Ｚｎ、Ｗ、Ｓｂ、Ｋ、Ｎａ、Ｐ、Ｂ等の単独酸化物または複合酸化物）、各種無機塩（ケイ酸塩、リン酸塩、アルミン酸塩、炭酸塩等）を用いることができるが、シリカ（ＳｉＯ２）が特に好適である。
無機質微粒子を含有するアクリル共重合体系合成樹脂エマルジョンは、無機質微粒子の共存下にアクリルモノマーをエマルジョン重合して製造する。アクリルモノマーとしては、ｎ－ブチルメタクリレート（ＢＭＡ）、メチルメタクリレート（ＭＭＡ）、ブチルアクリレート（ＢＡ）、スチレン（ＳＴ）やこれらの組み合わせを用いることができるが、ＢＭＡが特に好適である。 The particle size of the inorganic fine particles may be 5 to 300 nm in the colloidal region, but is preferably 5 to 50 nm, and more preferably 8 to 20 nm. If the particle size of the inorganic fine particles is too large, the wettability of the painted surface regenerating agent and the wettability of the painted surface are lowered, so that the ability to revive the color of the painted surface is lowered.
The amount of the inorganic fine particles may be 0.05 to 1.5 parts by weight, preferably 0.1 to 1 part by weight, based on 1 part by weight of the resin in the acrylic copolymer synthetic resin emulsion. More preferably, it is 0.4 to 0.8 part by weight. When the amount of the inorganic fine particles is too small, the desired effect cannot be obtained in terms of adhesion to the coated surface and hardness, and when it is too large, it is disadvantageous in terms of adhesion and transparency.
Examples of the inorganic fine particle material include various inorganic oxides or inorganic composite oxides (Si, Al, Ti, Zr, Ce, Mg, Ca, Fe, Sn, Zn, W, Sb, K, Na, P, B, etc. Single oxide or composite oxide) and various inorganic salts (silicate, phosphate, aluminate, carbonate, etc.) can be used, and silica (SiO 2 ) is particularly preferable.
The acrylic copolymer synthetic resin emulsion containing inorganic fine particles is produced by emulsion polymerization of an acrylic monomer in the presence of inorganic fine particles. As the acrylic monomer, n-butyl methacrylate (BMA), methyl methacrylate (MMA), butyl acrylate (BA), styrene (ST) or a combination thereof can be used, and BMA is particularly preferable.
請求項１に係る発明の塗装面再生剤によれば、劣化した塗装面を洗浄した後、その塗装面再生剤を洗浄した塗装面に刷毛やスポンジ等を用いて塗布し乾燥させるだけで色あせた塗装面の色が蘇生するので、劣化した塗装面を研磨して新しい塗装面を露出させるという手間と時間のかかる作業を省略できる。
そのため、小さい初期コストで、素早く劣化した塗装面を再生することができる。
また、塗装面再生剤の乾燥後は、塗装面に密着した透明で硬い膜が形成されるので、その後の塗装面の劣化速度を下げることができる。 According to the painted surface regenerating agent of the invention according to claim 1, after the deteriorated painted surface is washed, the painted surface regenerating agent is faded by simply applying and drying the painted surface using a brush or a sponge. Since the color of the painted surface is revived, the labor and time-consuming work of polishing the deteriorated painted surface and exposing the new painted surface can be omitted.
Therefore, it is possible to quickly regenerate the deteriorated painted surface at a small initial cost.
Moreover, since the transparent and hard film | membrane closely_contact | adhered to the coating surface is formed after drying of the coating surface regeneration agent, the deterioration rate of the subsequent coating surface can be lowered | hung.
そのため、小さい初期コストで、素早く劣化した塗装面を再生することができる。
また、塗装面再生剤の乾燥後は、塗装面に密着した透明で硬い膜が形成されるので、その後の塗装面の劣化速度を下げることができる。 According to the painted surface regenerating agent of the invention according to claim 1, after the deteriorated painted surface is washed, the painted surface regenerating agent is faded by simply applying and drying the painted surface using a brush or a sponge. Since the color of the painted surface is revived, the labor and time-consuming work of polishing the deteriorated painted surface and exposing the new painted surface can be omitted.
Therefore, it is possible to quickly regenerate the deteriorated painted surface at a small initial cost.
Moreover, since the transparent and hard film | membrane closely_contact | adhered to the coating surface is formed after drying of the coating surface regeneration agent, the deterioration rate of the subsequent coating surface can be lowered | hung.
請求項２に係る発明の塗装面再生剤によれば、請求項１に係る発明による効果に加え、塗装面に形成された膜が紫外線の透過を抑制するので、その後の塗装面の劣化速度をさらに下げることができる。
According to the paint surface regenerating agent of the invention according to claim 2, in addition to the effect of the invention according to claim 1, the film formed on the paint surface suppresses the transmission of ultraviolet rays, so the deterioration rate of the subsequent paint surface is reduced. It can be further lowered.
請求項３に係る発明の塗装面再生剤によれば、請求項１又は２に係る発明による効果に加え、塗装面再生剤の粘度を上げることができるので、塗装面再生剤を垂直な塗装面に塗布する場合でも、塗装面の上部から塗装面再生剤を刷毛やスポンジ等を用いて供給し、塗装面の表面に沿って流下させながら全面に延ばすとともに、塗装面の下部で垂れてきた塗装面再生剤を回収し、自然乾燥させることにより、垂直な塗装面にほぼ均一な厚さの膜を形成することができる。
According to the painted surface regenerating agent of the invention according to claim 3, in addition to the effect of the invention according to claim 1 or 2, the viscosity of the painted surface regenerating agent can be increased. Even if it is applied to the surface of the paint surface, the paint surface regenerant is supplied from the top of the paint surface using a brush or sponge, etc. By recovering the surface regenerating agent and naturally drying it, a film having a substantially uniform thickness can be formed on the vertical painted surface.
請求項４に係る発明の塗装面再生方法によれば、劣化した塗装面を洗浄する工程、洗浄した前記塗装面を研磨せずに請求項１ないし３のいずれかに記載の塗装面再生剤を塗布する工程、及び前記塗装面に塗布した塗装面再生剤を自然乾燥させる工程からなっているので、小さい初期コストで、素早く劣化した塗装面を再生することができる。
According to the painted surface regeneration method of the invention according to claim 4, the step of cleaning the deteriorated painted surface, the painted surface regenerating agent according to any one of claims 1 to 3 without polishing the cleaned painted surface. Since it consists of the process of apply | coating and the process of naturally drying the coating surface regeneration agent apply | coated to the said coating surface, the coating surface which deteriorated quickly can be reproduced | regenerated at small initial cost.
以下、実施例によって本発明の実施形態を説明する。
Hereinafter, embodiments of the present invention will be described by way of examples.
粒径８～２０ｎｍのコロイダルシリカを共存させつつアクリルモノマーをエマルジョン重合して、コロイダルシリカを含有するアクリル共重合体系合成樹脂エマルジョン８８部を得た。このアクリル共重合体系合成樹脂エマルジョンの樹脂分（アクリル共重合体）は２３．７部、コロイダルシリカは１４．２部であった。樹脂分とコロイダルシリカとの比率は重量比で１：０．６０、コロイダルシリカを含有するアクリル共重合体系合成樹脂エマルジョンの固形分（樹脂分とコロイダルシリカとの合計量）は４３重量％であった。
An acrylic monomer was emulsion polymerized in the presence of colloidal silica having a particle size of 8 to 20 nm to obtain 88 parts of an acrylic copolymer synthetic resin emulsion containing colloidal silica. The resin content (acrylic copolymer) of this acrylic copolymer synthetic resin emulsion was 23.7 parts, and the colloidal silica was 14.2 parts. The ratio of the resin content to the colloidal silica was 1: 0.60 by weight, and the solid content of the acrylic copolymer-based synthetic resin emulsion containing the colloidal silica (total amount of the resin content and the colloidal silica) was 43% by weight. It was.
次にこのコロイダルシリカを含有するアクリル共重合体系合成樹脂エマルジョン中に、添加剤（界面活性剤、造膜助剤、増粘剤及び水を含む混合物）８部にベンゾトリアゾール系紫外線吸収剤３部を添加したものを加えて混合した。紫外線吸収剤の添加量は、アクリル共重合体系合成樹脂エマルジョン中の樹脂分１部に対し０．１３部であった。
Next, in this acrylic copolymer synthetic resin emulsion containing colloidal silica, 8 parts of an additive (a mixture containing a surfactant, a film-forming aid, a thickener and water) and 3 parts of a benzotriazole ultraviolet absorber Was added and mixed. The addition amount of the ultraviolet absorber was 0.13 part with respect to 1 part of the resin content in the acrylic copolymer synthetic resin emulsion.
このようにして製造された塗装面再生剤を、設置されている劣化した交通標識１（逆三角形の止まれの標識）の右半分だけを水で洗浄した後、洗浄した塗装面の上部から刷毛やスポンジ等を用いて塗装面再生剤を供給し、塗装面の表面に沿って流下させながら右半面に延ばすとともに、塗装面の下部で垂れてきた塗装面再生剤を回収した。
その後、数分間自然乾燥させたところ、厚み約２０μｍの均一な透明被膜が交通標識の右半面に形成された。
右半面２に塗装面再生剤の硬化膜が形成され、左半面３には塗装面再生剤を施工していない交通標識１の写真を図１に示す。 After the painted surface regenerating agent thus produced is washed with water only on the right half of the installed degraded traffic sign 1 (inverted triangle stop sign), the brush or The paint surface regenerant was supplied using a sponge or the like and extended along the surface of the paint surface to the right half while collecting the paint surface regenerant drooping at the bottom of the paint surface.
Then, when it was naturally dried for several minutes, a uniform transparent film having a thickness of about 20 μm was formed on the right half of the traffic sign.
FIG. 1 shows a photograph of a traffic sign 1 in which a cured film of a painted surface regenerating agent is formed on theright half surface 2 and no painted surface regenerating agent is applied on the left half surface 3.
その後、数分間自然乾燥させたところ、厚み約２０μｍの均一な透明被膜が交通標識の右半面に形成された。
右半面２に塗装面再生剤の硬化膜が形成され、左半面３には塗装面再生剤を施工していない交通標識１の写真を図１に示す。 After the painted surface regenerating agent thus produced is washed with water only on the right half of the installed degraded traffic sign 1 (inverted triangle stop sign), the brush or The paint surface regenerant was supplied using a sponge or the like and extended along the surface of the paint surface to the right half while collecting the paint surface regenerant drooping at the bottom of the paint surface.
Then, when it was naturally dried for several minutes, a uniform transparent film having a thickness of about 20 μm was formed on the right half of the traffic sign.
FIG. 1 shows a photograph of a traffic sign 1 in which a cured film of a painted surface regenerating agent is formed on the
形成した被膜の塗装面に対する密着性は、クロスカット試験で確認したところ、実用に耐える十分なものであった。
また、ＪＩＳ Ｋ５４００に規定する鉛筆引っかき試験機法で形成した被膜の硬度を測定した結果、硬度は３Ｈであり実用に耐える十分なものであった。 The adhesion of the formed film to the painted surface was confirmed by a cross-cut test and was sufficient for practical use.
Moreover, as a result of measuring the hardness of the film formed by the pencil scratch tester method specified in JIS K5400, the hardness was 3H, which was sufficient for practical use.
また、ＪＩＳ Ｋ５４００に規定する鉛筆引っかき試験機法で形成した被膜の硬度を測定した結果、硬度は３Ｈであり実用に耐える十分なものであった。 The adhesion of the formed film to the painted surface was confirmed by a cross-cut test and was sufficient for practical use.
Moreover, as a result of measuring the hardness of the film formed by the pencil scratch tester method specified in JIS K5400, the hardness was 3H, which was sufficient for practical use.
１ 劣化した塗装面を持つ交通標識
２ 塗装面再生剤を形成した交通標識の右半面
３ 塗装面再生剤を形成していない交通標識の左半面
1 Traffic sign with deteriorated paintedsurface 2 Right half of traffic sign with painted surface regeneration agent 3 Left half of traffic sign without painted surface regeneration agent
２ 塗装面再生剤を形成した交通標識の右半面
３ 塗装面再生剤を形成していない交通標識の左半面
1 Traffic sign with deteriorated painted
Claims (4)
- 無機質微粒子を含有するアクリル共重合体系合成樹脂エマルジョンに、界面活性剤と、造膜助剤と、水を添加した塗装面再生剤であって、
前記無機質微粒子の粒径は、５～３００ｎｍであり、
前記無機質微粒子の量は、前記アクリル共重合体系合成樹脂エマルジョン中の樹脂分１重量部に対し、０．０５～１．５重量部であることを特徴とする
塗装面再生剤。 A coating surface regeneration agent obtained by adding a surfactant, a film-forming aid, and water to an acrylic copolymer synthetic resin emulsion containing inorganic fine particles,
The inorganic fine particles have a particle size of 5 to 300 nm,
An amount of the inorganic fine particles is 0.05 to 1.5 parts by weight with respect to 1 part by weight of the resin content in the acrylic copolymer synthetic resin emulsion. - 前記アクリル共重合体系合成樹脂エマルジョンに、紫外線吸収剤をさらに添加したことを特徴とする
請求項１に記載の塗装面再生剤。 The painted surface regenerating agent according to claim 1, further comprising an ultraviolet absorber added to the acrylic copolymer synthetic resin emulsion. - 前記アクリル共重合体系合成樹脂エマルジョンに、増粘剤をさらに添加したことを特徴とする
請求項１又は２に記載の塗装面再生剤。 The painted surface regeneration agent according to claim 1, wherein a thickener is further added to the acrylic copolymer synthetic resin emulsion. - 劣化した塗装面を洗浄する工程、洗浄した前記塗装面を研磨せずに請求項１ないし３のいずれかに記載の塗装面再生剤を塗布する工程、及び前記塗装面に塗布した塗装面再生剤を自然乾燥させる工程からなる
塗装面再生方法。
A step of cleaning a deteriorated painted surface, a step of applying the painted surface regenerating agent according to any one of claims 1 to 3 without polishing the cleaned painted surface, and a painted surface regenerating agent applied to the painted surface A method for reclaiming the painted surface, which consists of the process of naturally drying.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201480053878.XA CN105814153A (en) | 2013-09-30 | 2014-09-26 | Coating surface regeneration agent and coating surface regeneration method |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2013-204194 | 2013-09-30 | ||
| JP2013204194A JP2015067753A (en) | 2013-09-30 | 2013-09-30 | Agent for regenerating painted surface, and method for regenerating painted surface |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2015046426A1 true WO2015046426A1 (en) | 2015-04-02 |
Family
ID=52743552
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/JP2014/075626 WO2015046426A1 (en) | 2013-09-30 | 2014-09-26 | Coated surface regeneration agent and coated surface regeneration method |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JP2015067753A (en) |
| CN (1) | CN105814153A (en) |
| WO (1) | WO2015046426A1 (en) |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06157978A (en) * | 1992-05-01 | 1994-06-07 | Kanebo Nsc Ltd | Coating composition for recoating |
| JPH08134407A (en) * | 1994-11-07 | 1996-05-28 | Sofuto Kyukyu Corp:Kk | Material for restoring deteriorated coating film and small mar and lustering for automobile |
| JP2002355609A (en) * | 2001-05-31 | 2002-12-10 | Toagosei Co Ltd | Repairing method for structure |
| JP2005054096A (en) * | 2003-08-06 | 2005-03-03 | Dainippon Ink & Chem Inc | Aqueous coating composition |
| JP2006335831A (en) * | 2005-05-31 | 2006-12-14 | Nippon Paint Co Ltd | Emulsion coating composition and method for forming multilayer coating film using the same |
| JP2007224261A (en) * | 2006-01-30 | 2007-09-06 | Dainippon Ink & Chem Inc | Water-based paint for floor and floor coating method |
| JP2008274084A (en) * | 2007-04-27 | 2008-11-13 | Dic Corp | Resin aqueous dispersion |
| JP2009149798A (en) * | 2007-12-21 | 2009-07-09 | Dic Corp | Resin aqueous dispersion |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3289700B2 (en) * | 1999-04-09 | 2002-06-10 | ダイキン工業株式会社 | Resin composition for water-based paint |
| JP2001335721A (en) * | 2000-05-25 | 2001-12-04 | Mizutani Paint Co Ltd | Colloidal fine particle, method for manufacturing the same and coating composition |
| CN1333024C (en) * | 2004-11-18 | 2007-08-22 | 复旦大学 | Method for preparing multifunctional building engineering paint |
| CN100584867C (en) * | 2006-08-11 | 2010-01-27 | 中山耐乐生物科技有限公司 | Process for preparing room temperature self-crosslinking acrylic ester emulsion modified by inorganic nano particle |
| JP2008208272A (en) * | 2007-02-27 | 2008-09-11 | Johnson Diversey Co Ltd | Floor polish composition for flooring floor |
| CN102459482B (en) * | 2009-06-08 | 2014-11-05 | 三菱丽阳株式会社 | Water-based coating material and coated articles |
| JP2011111516A (en) * | 2009-11-26 | 2011-06-09 | Jts Kk | Emulsion coating and coating film having ultraviolet cut function |
| JP2012241181A (en) * | 2011-05-24 | 2012-12-10 | Nippon Paint Co Ltd | Aqueous antifouling coating composition, and method of forming antifouling coating layer |
| JP5946356B2 (en) * | 2011-08-05 | 2016-07-06 | 関西ペイント株式会社 | Coating composition and coating film forming method |
-
2013
- 2013-09-30 JP JP2013204194A patent/JP2015067753A/en active Pending
-
2014
- 2014-09-26 WO PCT/JP2014/075626 patent/WO2015046426A1/en active Application Filing
- 2014-09-26 CN CN201480053878.XA patent/CN105814153A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06157978A (en) * | 1992-05-01 | 1994-06-07 | Kanebo Nsc Ltd | Coating composition for recoating |
| JPH08134407A (en) * | 1994-11-07 | 1996-05-28 | Sofuto Kyukyu Corp:Kk | Material for restoring deteriorated coating film and small mar and lustering for automobile |
| JP2002355609A (en) * | 2001-05-31 | 2002-12-10 | Toagosei Co Ltd | Repairing method for structure |
| JP2005054096A (en) * | 2003-08-06 | 2005-03-03 | Dainippon Ink & Chem Inc | Aqueous coating composition |
| JP2006335831A (en) * | 2005-05-31 | 2006-12-14 | Nippon Paint Co Ltd | Emulsion coating composition and method for forming multilayer coating film using the same |
| JP2007224261A (en) * | 2006-01-30 | 2007-09-06 | Dainippon Ink & Chem Inc | Water-based paint for floor and floor coating method |
| JP2008274084A (en) * | 2007-04-27 | 2008-11-13 | Dic Corp | Resin aqueous dispersion |
| JP2009149798A (en) * | 2007-12-21 | 2009-07-09 | Dic Corp | Resin aqueous dispersion |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2015067753A (en) | 2015-04-13 |
| CN105814153A (en) | 2016-07-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US6846512B2 (en) | System and method for cleaning and/or treating vehicles and the surfaces of other objects | |
| US6562142B2 (en) | System and method for cleaning and/or treating vehicles and the surfaces of other objects | |
| RU2377115C2 (en) | Method and device to process hard surfaces and floor surface-processing machine | |
| US20120082791A1 (en) | Coating Composition Amenable to Elastomeric Substrates | |
| WO2001048109A1 (en) | Hard surface treating agent, stain-proofing agent and method for surface treatment | |
| US2330365A (en) | Abrasion resistant coating | |
| JP2013028778A (en) | Matte clear coating composition for vehicle | |
| JP4782214B2 (en) | Plastic flexible composition for polishing and coating of surface protective material | |
| WO2015046426A1 (en) | Coated surface regeneration agent and coated surface regeneration method | |
| US9427778B2 (en) | Headlight restoration kit | |
| KR101344532B1 (en) | Method for restoring headlights of car and coating agent for restoring headlights of car | |
| US9718095B2 (en) | Headlight restoration kit | |
| JP7054946B2 (en) | Method for forming paint composition and coating film | |
| TW201940654A (en) | Structured abrasives containing polishing materials for use in the home | |
| KR100523692B1 (en) | The method of partial painting for automobile | |
| US5743789A (en) | Process for finishing a painting | |
| US3600348A (en) | Coating composition for wooden concrete forms and method of preparing wooden forms having improved concrete anti-sticking characteristics | |
| CN103313853A (en) | Laminate body | |
| CN206492685U (en) | A kind of hairbrush for powdery paints | |
| JP2010234350A (en) | Method of repairing and finishing damaged or degraded surface of molding of enamel and fiber reinforced plastic | |
| JP2009095805A (en) | Coating method for flooring | |
| JPH09187725A (en) | Method for restoring gloss of coating film surface of automobile and protective coat forming method | |
| JP2006167904A (en) | Specular polishing method for clear coating surface of automobile body | |
| JP4185737B2 (en) | Coating surface finishing method and coating surface finishing agent | |
| JPH0284484A (en) | Treating agent for coating surface of automobile or the like |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 14847106 Country of ref document: EP Kind code of ref document: A1 |
|
| NENP | Non-entry into the national phase |
Ref country code: DE |
|
| 122 | Ep: pct application non-entry in european phase |
Ref document number: 14847106 Country of ref document: EP Kind code of ref document: A1 |