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WO2015045185A1 - Disposable body warmer - Google Patents

Disposable body warmer Download PDF

Info

Publication number
WO2015045185A1
WO2015045185A1 PCT/JP2013/076627 JP2013076627W WO2015045185A1 WO 2015045185 A1 WO2015045185 A1 WO 2015045185A1 JP 2013076627 W JP2013076627 W JP 2013076627W WO 2015045185 A1 WO2015045185 A1 WO 2015045185A1
Authority
WO
WIPO (PCT)
Prior art keywords
storage
inner bag
portions
disposable body
body warmer
Prior art date
Application number
PCT/JP2013/076627
Other languages
French (fr)
Japanese (ja)
Inventor
剛 伊賀上
Original Assignee
小林製薬株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 小林製薬株式会社 filed Critical 小林製薬株式会社
Priority to PCT/JP2013/076627 priority Critical patent/WO2015045185A1/en
Priority to CN201380081175.3A priority patent/CN105764456B/en
Priority to JP2015538827A priority patent/JPWO2015045189A1/en
Priority to PCT/JP2013/079368 priority patent/WO2015045189A1/en
Publication of WO2015045185A1 publication Critical patent/WO2015045185A1/en

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Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F7/00Heating or cooling appliances for medical or therapeutic treatment of the human body
    • A61F7/02Compresses or poultices for effecting heating or cooling
    • A61F7/03Compresses or poultices for effecting heating or cooling thermophore, i.e. self-heating, e.g. using a chemical reaction
    • A61F7/032Compresses or poultices for effecting heating or cooling thermophore, i.e. self-heating, e.g. using a chemical reaction using oxygen from the air, e.g. pocket-stoves
    • A61F7/034Flameless

Definitions

  • the present invention relates to a disposable body warmer.
  • a disposable warmer in which a heat-generating composition that generates heat by contact with air is enclosed in a breathable flat bag (inner bag) has been known as a body warmer, and is portable and safe. It is frequently used because of its simplicity and low cost.
  • the inner bag is packaged in a flat bag (outer bag) having airtightness so that the exothermic composition does not come into contact with air.
  • the outer bag 101 includes one storage portion 102, and the storage portion 102 stores one inner bag 103.
  • the outer bag 101 includes two outer bags 101. 2. Description of the Related Art
  • a disposable body warmer 100 that is provided with partitioned storage units 102 and stores one compact sized inner bag 103 in each storage unit 102 is generally known.
  • Such disposable body warmers control the exothermic conditions (maximum temperature, average temperature, duration, etc.) by adjusting the components of the exothermic composition (for example, the amount of iron powder filling and the moisture blending ratio). Yes.
  • water which is an essential component of the exothermic composition
  • the duration of the disposable body warmer is shortened, and when too large, the disposable body warmer does not generate heat.
  • the inner bag in which the heat generating composition is sealed is sealed in an airtight outer bag before use, if the unused state continues for a long period of time, such as the state of being placed in a storefront, FIG. 13 and FIG.
  • the duration (40 ° C. from when the disposable body warmer starts to generate heat and exceeds 40 ° C. It has been found by the present inventors that the time until the value falls below is greatly reduced. This decrease in duration is considered to be due to the evaporation of moisture contained in the exothermic composition from the outer bag. Therefore, in the past, the amount of exothermic composition was increased more than necessary by reducing the duration of heat generation, thereby ensuring that the desired heat generation duration was satisfied even after long-term storage. There is a problem that it takes. Therefore, it is necessary to wrap the inner bag in the outer bag so that moisture is not scattered from the outer bag as much as possible.
  • the present invention has been made paying attention to the above-described problem, and suppresses the moisture contained in the exothermic composition from scattering from the outer bag, so that the exothermic heat of the exothermic composition can be maintained even if the unused state continues for a long period of time.
  • An object of the present invention is to provide a disposable body warmer capable of maintaining a good duration.
  • the object of the present invention is that a heat-generating composition containing moisture and generating heat upon contact with air is enclosed in an air-permeable inner bag, and the inner bag is accommodated in an air-tight outer bag.
  • the outer bag is capable of storing the inner bag and includes at least three storage portions partitioned from each other, and the inner bag can enclose the exothermic composition. And at least two enclosure parts partitioned from each other, and a disposable body warmer accommodated in the accommodation part in a state where at least one of the enclosure parts is folded at least once so as to overlap with the other enclosure parts Achieved.
  • all the other enclosure parts are stacked in one enclosure part.
  • the inner bag is formed by laminating a non-breathable sheet material on at least one surface, and the enclosing portion is overlapped so that the non-breathable sheet material becomes upper and lower outermost surfaces. It is characterized by being.
  • the outer bag is formed so that at least three other storage parts are continuously provided in at least one storage part, or at least two of all the storage parts are provided. It is preferable that the outer bag is formed so that the other storage units are continuously provided.
  • the number of the enclosing portions is 2 to 4.
  • the moisture contained in the exothermic composition can be prevented from scattering from the outer bag, so that the exothermic duration of the exothermic composition can be favorably maintained even if the unused state continues for a long period of time. .
  • FIG. 4 is a cross-sectional view of FIG. 3. It is a top view which shows the modification of an inner bag. It is a top view which shows the modification of an outer bag. It is a top view which shows the modification of an outer bag. It is a top view which shows the modification of an outer bag. It is a top view which shows the modification of an outer bag. It is a top view which shows the modification of an outer bag. It is a top view which shows the modification of an outer bag. It is a top view which shows the modification of an outer bag. It is a top view which shows the modification of an outer bag. It is a top view which shows the modification of an outer bag. It is a top view which shows the modification of an outer bag.
  • the disposable body warmer 1 includes a heat generating composition 2 that generates heat when in contact with air enclosed in a flat inner bag 3 having air permeability. Is housed in a flat outer bag 4 having airtightness, the inner bag 3 is taken out from the outer bag 4, and the heat generating composition 2 of the inner bag 3 is removed from the limbs, lower back, back, abdomen, and feet. Heat is applied to various parts of the body such as the back, shoulders, and buttocks.
  • the exothermic composition 2 only needs to generate heat upon contact with air.
  • an oxidizable metal, activated carbon, water retention agent (wood powder, vermiculite, diatomaceous earth, perlite, silica gel, alumina, water-absorbing resin, etc. ), Metal salts (such as sodium chloride), and water, each of which contains an appropriate content, and a known composition conventionally used for disposable warmers can be used.
  • the oxidizable metal is a metal that generates heat of oxidation reaction, and examples thereof include one or more powders and fibers selected from iron, aluminum, zinc, manganese, magnesium, and calcium. Among these, iron powder is preferable from the viewpoints of handleability, safety, manufacturing cost, storage stability, and stability.
  • the iron powder examples include one or more selected from reduced iron powder and atomized iron powder.
  • the disposable body warmer 1 is controlled so as to have desired heat generation conditions (maximum temperature, average temperature, heat generation duration, etc.) during use by adjusting the components of the heat generating composition 2 described above.
  • the blending amount of the oxidizable metal in the exothermic composition 2 is preferably 30% to 80%, more preferably 40% to 70%, and further preferably 40% to 65%.
  • water, which is an essential component of the exothermic composition 2 has a reduced exothermic duration when the blending ratio is small, the blending ratio of water in the exothermic composition 2 is devised.
  • the blending ratio of moisture contained in the exothermic composition 2 is an important factor for realizing a desired exothermic duration during use. Therefore, even when the disposable body warmer 1 is placed in the store for a long time, such as when it is not used for a long period of time, the heat generating composition 2 prevents the moisture contained in the heat generating composition 2 from scattering from the outer bag 4 as much as possible.
  • the shape of the inner bag 3 and the outer bag 4 and the method for storing the inner bag 3 in the outer bag 4 in order to prevent the duration of heat generation from decreasing due to a decrease in the moisture mixing ratio Devised about.
  • the enclosing portions 32 can be overlapped with each other by folding the inner bag 3 between the adjacent enclosing portions 32.
  • the number of the sealing portions 32 provided in the inner bag 3 is not limited to two, and may be three or more, but is preferably two to four.
  • the arrangement method of the plurality of encapsulating portions 32 is not particularly limited, and as shown in FIG. 3, the plurality of encapsulating portions 32 may be arranged in a line, For example, when the number of the enclosing portions 32 is four, the two upper and lower rows may be arranged so that two rows are aligned in each of the upper and lower rows. Also in this case, each enclosure part 32 can be mutually piled up by folding the inner bag 3 between the enclosure parts 32 adjacent on the upper and lower sides and / or right and left.
  • the first sheet material 30 has air permeability and comes into contact with the body when used.
  • the first sheet material 30 may be a porous resin film, a resin film perforated with a needle, or a non-woven fabric or a woven fabric.
  • seat material 30 may be a single layer structure, and the multilayer structure which laminated
  • the resin film those conventionally used as the inner bag 3 of the disposable body warmer 1 can be used.
  • non-woven fabrics are also artificial fibers such as polypropylene, nylon, vinylon, polyester, polyethylene terephthalate, rayon, acetate, acrylic, polyethylene, polyvinyl chloride, etc. Examples include those containing natural fibers such as cotton, hemp and silk. Moreover, paper etc. can be illustrated other than a nonwoven fabric.
  • the second sheet material 31 may have either air permeability or non-air permeability, and may be a resin film, a non-woven fabric, or a woven fabric, like the first sheet material 30. A single layer configuration or a multilayer configuration may be used.
  • the adhesion layer 33 can be provided in the surface. Specifically, it is possible to apply an adhesive made of acrylic resin, rubber resin, or the like having an adhesive action to the skin and clothes to the surface of the second sheet material 31, so that a so-called sticking type warmer and can do.
  • the adhesive layer 33 is covered with the release paper 34 until the inner bag 3 is stored in the outer bag 4 and used.
  • the inner bag 3 is stored in the outer bag 4 until it is used. It is preferable that at least one surface of the first sheet material 31 and the second sheet material 32 is covered with a non-breathable sheet material.
  • the inner bag 3 has two sealed portions 32 separated from each other by sealing the two sheet materials 30 and 31 at the outer peripheral edge (side edges of the four directions) and the center position.
  • two compact sized inner bags each having one enclosing portion 32 are individually manufactured, and then the binding margins of the peripheral edges of the two inner bags are integrated by bonding. May be formed.
  • the ratio of the enclosing volume of the exothermic composition 2 to the volume of the enclosing portion 32 is preferably about 30% to 80%, and particularly preferably about 50% to 70%. If this ratio exceeds 80%, the exothermic composition 2 becomes excessive, and when the inner bag 3 having a plurality of enclosing portions 32 is formed by sealing the two sheet materials 30 and 31, heat is generated in the seal portion. This is because the composition 2 may bite and the inner bag 3 may not be formed. On the other hand, if this ratio is less than 30%, the desired heat generation condition may not be satisfied during use. Moreover, it is preferable that the area of the enclosure part 32 is 0.05 m ⁇ 2 > or less.
  • the area of the enclosing portion 32 exceeds 0.05 m 2
  • the area of the storage portion 42 of the outer bag 4 that stores the inner bag 3 to be described later increases, so that the overall size of the outer bag 4 increases and is carried. This is because there is a possibility that problems such as being bulky and increasing the amount of use of the outer bag 4 (wrapping films 40 and 41) may lead to an increase in cost.
  • the outer bag 4 is composed of two front and back packaging films 40 and 41, and the two packaging films 40 and 41 are overlapped, and the outer peripheral edge is, for example, thermally bonded (heat sealed).
  • at least three rectangular storage portions 42 capable of storing the inner bag 3 therein, and a first seal portion 43 sealing the outer bag 4 at the outer peripheral edge.
  • first seal portion 43 sealing the outer bag 4 at the outer peripheral edge.
  • the two sealing films 40 and 41 are linearly sealed (joined) to form a second seal portion 44, and the adjacent storage portions 42 are the second seal portions 44.
  • the at least three storage portions 42 of the outer bag 4 will be described later, it is not particularly limited.
  • those conventionally used as the outer bag 4 of the disposable body warmer 1 can be used, and examples thereof include non-porous films such as polyethylene, polypropylene, silica-deposited film, and vinylidene chloride coated film. Can do. Among these, vinylidene chloride coated films (KOP, K nylon, KPET, etc.) and aluminum vapor-deposited coated films (VMPET, VMCPP, etc.) are preferable from the viewpoint of impermeability of oxygen and water vapor and appropriate permeability of hydrogen.
  • KOP vinylidene chloride coated films
  • VMPET aluminum vapor-deposited coated films
  • the disposable body warmer 1 is configured so that the inner bag 3 is folded at least once so that at least one enclosing portion 32 of the inner bag 3 is overlapped with the other enclosing portion 32, and each storage portion of the outer bag 4 is stored. It is characterized in that it is housed in each of 42. That is, when the number of enclosure parts 32 provided in the inner bag 3 is two, for example, as shown in FIG. 2, the inner bag 3 is folded at the center position so that the one enclosure part 32 is replaced with the other enclosure part 32. In this state, one inner bag 3 is stored in each storage portion 42 of the outer bag 4.
  • the area of the inner bag 3 (total surface area of the plurality of enclosure parts 32) can be reduced by half, so that the exothermic composition 2 enclosed in each enclosure part 32 is The area touching the outside is reduced. Therefore, it is possible to make it difficult for the moisture in the exothermic composition 2 enclosed in each enclosure part 32 to scatter.
  • the area of the storage portion 42 of the outer bag 4 that stores the inner bag 3 can be made smaller than when the inner bag 3 is stored without being folded. 2 can also be prevented from passing through the front and back surfaces (wrapping films 40, 41) of the storage portion 42 and splashing to the outside of the storage portion 42.
  • the amount of use of the outer bag 4 (wrapping films 40 and 41) can be reduced as compared with the case where the inner bag 3 is not folded and stored, which leads to cost reduction.
  • the inner bag 3 has the second sheet material 31 when the second sheet material 31 is air-impermeable and the first sheet material 31 and the second sheet material when the second sheet material 31 is air-permeable. It is preferable that a non-breathable sheet material (not shown) covering at least one surface of the sheet material 32 is folded so as to be upper and lower outermost surfaces. Thereby, since the uppermost surface of the stacked enclosure part 32 becomes air-impermeable, the moisture in the heat-generating composition 2 enclosed in each enclosure part 32 can be more effectively prevented from scattering.
  • the inner bag 3 When the number of enclosures 32 provided in the inner bag 3 is three, the inner bag 3 is folded once between the enclosure 32 at one end and the enclosure 32 at the center, and the two enclosures 32 are provided.
  • the inner bag 3 may be stored one by one in each storage portion 42 of the outer bag 4 in a state where only the two are stacked, but the other sealing portions 32 are stacked on the two stacked sealing portions 32.
  • the area of the inner bag 3 (total surface area of the enclosing part 32) can be minimized (1/3), the moisture in the exothermic composition 2 is scattered from the storage part 42 to the outside as described above. This can be suppressed.
  • the inner sheet 3 is the second sheet material 31 and when the second sheet material 31 is air-permeable, the first sheet material 31 is used.
  • the non-breathable sheet material (not shown) covering at least one surface of the second sheet material 32 is folded so as to be the upper and lower outermost surfaces, whereby the exothermic composition 2 enclosed in each enclosure portion 32. It is possible to make it difficult to effectively disperse moisture therein.
  • the inner bag 3 may be folded by various methods and stored in the storage portions 42 of the outer bag 4, respectively.
  • each of the accommodating portions 42 of the outer bag 4 is accommodated in the area of the inner bag 3 (total surface area of the enclosed portion 32). ) Can be minimized (1/4), which is preferable. Thereby, as above-mentioned, it can suppress that the water
  • the inner sheet 3 is the second sheet material 31 and when the second sheet material 31 is air-permeable, the first sheet material 31 is used.
  • the non-breathable sheet material (not shown) covering at least one surface of the second sheet material 32 is folded so as to be the upper and lower outermost surfaces, whereby the exothermic composition 2 enclosed in each enclosure portion 32. It is possible to make it difficult to effectively disperse moisture therein. Even when the number of the enclosure parts 32 provided in the inner bag 3 is five or more, similarly, the inner bag 3 is arranged so that all the other enclosure parts 32 are stacked in one enclosure part 32. It is preferable that a plurality of folded portions are folded between adjacent enclosing portions 32 and the inner bag 3 is stored in the two storing portions 42 of the outer bag 4 one by one in this folded state.
  • the disposable body warmer 1 of the present embodiment at least 3 of the storage portion 42 of the inner bag 3 is provided in the outer bag 4.
  • One is provided.
  • the moisture in the heat generating composition 2 enclosed in the inner bag 3 may be scattered outside from the outer peripheral edge of the storage unit 42 in addition to the front and back surfaces (packaging films 40 and 41) of the storage unit 42.
  • the outer bag 4 is provided with three or more storage portions 42, all the storage portions 42 are connected to at least one other storage portion 42 via the second seal portion 44, and at least One storage portion 42 is connected to at least two other storage portions 42 via the second seal portion 44.
  • the shape of the storage portion 42 is rectangular, even if moisture in the exothermic composition 2 scatters from one side edge of the storage portion 42, it passes through the second seal portion 44 and others. As a result, the moisture from the exothermic composition 2 is eventually exchanged in the mutual storage portions 42. Therefore, the moisture from the exothermic composition 2 can be retained in the storage portion 42, and scattering from the storage portion 42 to the outside can be suppressed.
  • the at least three storage portions 42 of the outer bag 4 can be arranged so as to be aligned in one row, for example, as shown in FIG.
  • the other storage portions 42 are connected only to the side edges of one direction, but the storage portions 42 between them are connected to the side edges of the two directions. Since the other storage portions 42 are connected to each other, a total of two other storage portions 42 are connected, and moisture from the exothermic composition 2 can be satisfactorily retained in the storage portion 42, and from the storage portion 42 to the outside. It is possible to effectively suppress the scattering.
  • at least three storage portions 42 can be arranged in an L shape as shown in FIG. 6, for example.
  • the other storage portions 42 are connected to only one side edge, but the storage portion 42 between them has two directions. Since the other storage portions 42 are connected to the side edges of the storage portion 42, a total of two other storage portions 42 are connected, and moisture from the exothermic composition 2 can be satisfactorily retained in the storage portion 42. Can be effectively prevented from being scattered outside.
  • 1 and 6 exemplify the case where the number of the storage units 42 is three, the same applies to four or more storage units 42.
  • At least three storage units 42 can be arranged so as to be aligned in a plurality of upper and lower rows.
  • the number of storage parts 42 is four, as shown in FIG. 7, it can arrange
  • the other storage portions 42 are connected to the side edges in the two directions with respect to all the storage portions 42, a total of two other storage portions 42 are connected to each other in the storage portion 42.
  • moisture from the heat generating composition 2 can be kept well, and scattering from the storage portion 42 to the outside can be effectively suppressed.
  • the number of the storage units 42 is 6, as shown in FIG.
  • the other storage portions 42 are connected to the side edges of the two directions, but the storage portions 42 between them are connected to the side edges of the three directions. Since the other storage portions 42 are connected, a total of three other storage portions 42 are connected, and moisture from the exothermic composition 2 can be better retained in the storage portion 42, and from the storage portion 42 to the outside. It is possible to more effectively suppress scattering. The same applies to the case of eight or more. Further, for example, when the number of storage units 42 is nine, as shown in FIG.
  • the other storage portions 42 are connected to the side edges of the two directions, and the storage portions 42 between them are connected to the side edges of the three directions.
  • the storage part 42 is connected, since the other storage part 42 is connected to the side edges of all four sides of the central storage part 42, a total of four other storage parts 42 are connected and stored.
  • the moisture from the exothermic composition 2 can be further satisfactorily retained in the portion 42, and the scattering from the storage portion 42 to the outside can be more effectively suppressed.
  • the at least three storage portions 42 may be T-shaped (illustrated when the number of storage portions 42 is four) shown in FIG. 10 or a cross shape (when the number of storage portions 42 is five) shown in FIG. In other words, the moisture from the exothermic composition 2 is kept in the storage portion 42 as much as possible, and scattered from the storage portion 42 to the outside. To suppress.
  • the outer bag 4 has at least three storage portions 42, at least one storage portion 42 is provided with other storage portions 42 continuously on at least two side edges. In addition, a total of two other storage parts 42 are connected, and it is possible to more effectively suppress the moisture from the heat generating composition 2 in the storage part 42 from being scattered from the storage part 42 to the outside. Furthermore, if the outer bag 4 is formed so that at least two other storage units 42 are continuously provided for all the storage units 42, the moisture from the exothermic composition 2 is stored in the storage units 42 for each storage unit 42. It is possible to more effectively suppress scattering from the outside to the outside.
  • the area of the plan view of the housing portion 42 is preferably 0.0025m 2 ⁇ 0.25m 2, 0.01m 2 ⁇ 0.05m 2 is more preferable.
  • the strength of the first seal portion 43 formed on the outer peripheral edge of the outer bag 4 is strong.
  • the strength of the first seal portion 43 is preferably in the range of 10 N / 15 mm to 100 N / 15 mm, depending on the seal width and seal conditions.
  • the strength of the second seal portion 44 between the two storage portions 42 may be equal to or less than the strength of the first seal portion 43, and is preferably in the range of 5 N / 15 mm to 80 N / 15 mm.
  • sticker part 44 can be measured with the test method based on JIS Z02381998.
  • the seal width of the first seal portion 43 is preferably 1 mm to 50 mm, and more preferably 1 mm to 15 mm.
  • the seal width of the second seal portion 44 is preferably 1 mm to 50 mm, and more preferably 1 mm to 15 mm.
  • the moisture in the exothermic composition 2 passes through the second seal portion 44 and is adjacent to the storage portion 42 adjacent to the first seal portion 43. It becomes easy to scatter. Further, the higher the ratio of the length of the second seal portion 44 to the first seal portion 43 is, the more moisture in the heat generating composition 2 is scattered to the second seal portion 44 than the first seal portion 43, As described above, since the water scattered between the adjacent storage portions 42 is exchanged, it is possible to suppress the water in the heat generating composition 2 from being scattered from the storage portion 42. Similarly, if the seal width of the second seal portion 44 is smaller than the seal width of the first seal portion 43, moisture in the heat generating composition 2 is scattered from the second seal portion 44 rather than the first seal portion 43. Since it becomes easy, it is preferable.
  • Table 1 shows the disposable body warmer 1 of the present embodiment in which the outer bag 4 has at least three storage portions 42 and the inner bag 3 having a plurality of enclosure portions 32 is stored in each storage portion 42 in a folded state.
  • Embodiments 1, 2-1, and 2-2 have three storage portions 42 of the outer bag 4 shown in FIG. 1 and nine storage portions 42 of the outer bag 4 shown in FIG. Show.
  • the disposable warmers of Comparative Examples 1, 2-1, and 2-2 in the same manner as in Examples 1, 2-1, and 2-2, the outer bag having three or nine storage portions is used, and the enclosed portion is 1 The one containing a single inner bag is shown.
  • FIG. 12 shows the results of calculating the reduction rate based on the heat generation duration immediately after manufacturing (initial) for the measured heat generation duration of each example.
  • Example 1 the heat generation duration of the inner bag 3 (heat generating composition 2) taken out from the central storage part 42 (FIG. 1) among the three continuous storage parts 42 was measured, and Example 2 -1 and Example 2-2, two inner bags 3 (heat generation) taken out from one of the corners and the central storage part 42 (FIG. 9) out of the nine storage parts 42 arranged in a rectangular shape The exothermic duration for composition 2) was measured. Also, in Comparative Examples 1, 2-1, 2-2, the heat generation duration of the inner bag (heat generation composition) taken out from the storage portion at the same position as each of Examples 1, 2-1, 2-2 was also set. It was measured.
  • fever duration about the inner bag (heat-generating composition) taken out from either one of the two storage parts was measured. Also, storing the disposable body warmer for 3 months and 6 months under severe test conditions of a temperature of 40 ° C. and a humidity of 75% means storing the disposable body warmer at room temperature for 18 months and 36 months. Equivalent to.
  • the heat generation duration of the inner bag (heat generating composition) housed inside can be maintained to a certain extent, but at least two side edges as in Examples 1, 2-1, and 2-2.
  • the storage part in which the other storage parts are continuously provided can hold the heat generation duration of the inner bag (heat generating composition) stored therein more effectively, so that it can be further prolonged. I understand.
  • Comparative Examples 1, 2-1, 2-2 when the unused state continues for a long period of time, the duration of heat generation is reduced compared with immediately after production, and if 36 months have passed at room temperature, The duration of heat generation is greatly reduced to 10% or more.
  • the disposable body warmer 1 of this embodiment in which the outer bag 4 has at least three storage portions 42 and the inner bag 3 having a plurality of enclosing portions 32 is stored in the respective storage portions 42 in a folded state. From the result of FIG. 12, even if the unused state continues for a long time, it is possible to extend the heat generation duration of the inner bag 3 (heat generating composition) stored in each storage portion 42.
  • the blending ratio of moisture contained in the exothermic composition is increased, it is theoretically possible to maintain the duration of the disposable body warmer longer.
  • the viscosity of the exothermic composition is considerably increased by simply increasing the water content.
  • the exothermic composition is sticky, it becomes difficult to enclose it in the inner bag 3, and it becomes impossible to produce a warmer, and the temperature of the exothermic composition does not rise and cannot be used as a warmer. Therefore, it is extremely difficult to produce a disposable body warmer that can sustain the heat generation duration of the heat generating composition for a long time simply by increasing the blending ratio of water contained in the heat generating composition.
  • any storage part 42 of the outer bag 4 is opened and the inner bag 3 is taken out.
  • easy-opening means such as notches may be provided in correspondence with the respective storage portions 42 of the outer bag 4.
  • the release paper covering the adhesive layer or the non-breathable sheet material covering at least one surface of the first sheet material 31 and the second sheet material 32 is peeled off from the inner bag 3 to generate heat at a desired part of the body. It arrange
  • the outer bag 4 has at least three storage portions 42, and the inner bag 3 having a plurality of enclosure portions 32 is stored in a folded state in each storage portion 42.
  • the shapes of the inner bag 3 and the outer bag 4 are devised so that the moisture contained in the exothermic composition 2 enclosed in the inner bag 3 is not scattered from the storage portion 42 as much as possible. Is packaged in the outer bag 4, so that even if the disposable body warmer 1 is placed in the store for a long period of time, such as when it is not used for a long period of time, the exothermic duration time is reduced due to a decrease in the moisture content of the exothermic composition 2.
  • Decrease can be suppressed, and the heat generation duration at the beginning of production can be maintained over a long period of time. Therefore, even if the disposable body warmer 1 is used after it has been unused for a long time, it is possible to achieve the desired heat generation duration that was planned at the beginning of manufacture. Since the duration of the exothermic composition 2 scheduled at the beginning of production is generally displayed on the surface of the outer bag 4 and advertised to the user, it is actually used using the disposable body warmer 1 It is not necessary to dispose of the unused disposable body warmer 1 for the reason that the heat generation duration planned at the beginning of manufacture cannot be realized.
  • the amount of the outer bag 4 is reduced compared to storing the inner bag 3 in the outer bag 4 without folding. Therefore, cost can be reduced in terms of material.
  • the moisture in the heat generating composition 2 enclosed in the enclosing part 32 can be hardly scattered by folding the inner bag 3 so that the non-breathable sheet material becomes the upper and lower surfaces. As a result, it is possible to better maintain the initial duration for a long period of time.
  • the shape of the enclosure part 32 of the inner bag 3 is a rectangular shape, it is not restricted to a rectangular shape, but other various shapes, such as polygonal shapes, such as a triangular shape and a pentagon shape, circular shape, elliptical shape, are included. It can employ
  • the shape of the storage portion 42 of the outer bag 4 is not limited to a rectangular shape, and other various shapes such as a polygonal shape such as a triangular shape and a pentagonal shape, a circular shape, and an elliptical shape can be adopted.
  • the shape of the outer bag 4 can also be various shapes. Even when the shape of the storage portion 42 of the outer bag 4 is other than a rectangular shape, the outer bag 4 is formed so that at least three other storage portions 42 are continuously provided in at least one storage portion 42, Alternatively, it is preferable that the outer bag 4 is formed so that at least two other storage portions 42 are continuously provided in all the storage portions 42.

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  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Biomedical Technology (AREA)
  • Heart & Thoracic Surgery (AREA)
  • Vascular Medicine (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
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  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Thermotherapy And Cooling Therapy Devices (AREA)

Abstract

Provided is a disposable body warmer with which the dispersion, from an outer package, of moisture included in a heat-generating composition is inhibited, and with which an excellent heat-generation duration can be maintained, even if kept in an unused state for an extended period of time. In this disposable body warmer (1), a heat-generating composition (2), which generates heat as a result of coming into contact with air, is enclosed in air-permeable inner packages (3), and the inner packages (3) are accommodated in an airtight outer package (4). The outer package (4) is provided with at least 3 accommodation portions (42) which are capable of accommodating the inner packages (3), and which are separated from each other. The inner packages (3) are each provided with at least 2 enclosure portions (32) which are capable of enclosing the heat-generating composition (2), and which are separated from each other. The inner packages (3), each of which being in a state of having been folded at least once such that at least one of the enclosure portions thereof is on top of another of the enclosure portions thereof, are accommodated in the accommodation portions (42).

Description

使い捨てカイロDisposable body warmer
 本発明は、使い捨てカイロに関するものである。 The present invention relates to a disposable body warmer.
 従来より、身体の保温具として、通気性を有する扁平状の袋(内袋)に、空気と接触することで発熱する発熱組成物を封入した使い捨てカイロが知られており、携帯性、安全性、簡便性などに優れかつ安価であるために頻用されている。この使い捨てカイロは、未使用時は、発熱組成物が空気と接触しないように、内袋が気密性を有する扁平状の袋(外袋)で包装されている。例えば、図13に示すように、外袋101が1つの収納部102を備え、この収納部102に1つの内袋103を収納したものや、図14に示すように、外袋101が2つの区画された収納部102を備え、各収納部102にコンパクトサイズの内袋103を1つずつ収納した使い捨てカイロ100が一般的に知られている。 Conventionally, a disposable warmer in which a heat-generating composition that generates heat by contact with air is enclosed in a breathable flat bag (inner bag) has been known as a body warmer, and is portable and safe. It is frequently used because of its simplicity and low cost. When the disposable body warmer is not used, the inner bag is packaged in a flat bag (outer bag) having airtightness so that the exothermic composition does not come into contact with air. For example, as shown in FIG. 13, the outer bag 101 includes one storage portion 102, and the storage portion 102 stores one inner bag 103. As shown in FIG. 14, the outer bag 101 includes two outer bags 101. 2. Description of the Related Art A disposable body warmer 100 that is provided with partitioned storage units 102 and stores one compact sized inner bag 103 in each storage unit 102 is generally known.
特開平5-208031号公報JP-A-5-208031
 かかる使い捨てカイロは、発熱組成物の成分(例えば発熱体となる鉄粉の充填量や水分配合比)などを調整することにより、発熱条件(最高温度、平均温度、持続時間など)をコントロールしている。発熱組成物の必須成分である水は、配合割合が少ないと使い捨てカイロの持続時間が短くなり、多すぎると使い捨てカイロが発熱しないため、発熱組成物における水分の配合割合は工夫されている。しかしながら、発熱組成物を封入した内袋を使用前において気密性の外袋に密封しているとしても、店頭に置かれる状態が長くなるなど未使用状態が長期間続くと、図13や図14のような方法で内袋を外袋に包装した場合には、使用時に十分な発熱性能が得られない、特に、持続期間(使い捨てカイロが発熱を開始して40℃を越えたときから40℃を下回るまでの時間)が大きく減少していることが本発明者らの研究により判明している。この持続時間の減少は、発熱組成物に含まれる水分が蒸発して外袋から飛散しているためであると考えられる。そのため、従来では、発熱持続期間が減少する分、必要以上に発熱組成物の封入量を増やすことで、長期保存後においても所望の発熱持続期間を満たすよう担保していたが、この方法ではコストがかかるという問題がある。よって、水分ができる限り外袋から飛散しないよう、内袋を外袋に包装する必要がある。 Such disposable body warmers control the exothermic conditions (maximum temperature, average temperature, duration, etc.) by adjusting the components of the exothermic composition (for example, the amount of iron powder filling and the moisture blending ratio). Yes. When water, which is an essential component of the exothermic composition, has a small blending ratio, the duration of the disposable body warmer is shortened, and when too large, the disposable body warmer does not generate heat. However, even if the inner bag in which the heat generating composition is sealed is sealed in an airtight outer bag before use, if the unused state continues for a long period of time, such as the state of being placed in a storefront, FIG. 13 and FIG. When the inner bag is wrapped in the outer bag by such a method, sufficient heat generation performance cannot be obtained at the time of use. In particular, the duration (40 ° C. from when the disposable body warmer starts to generate heat and exceeds 40 ° C. It has been found by the present inventors that the time until the value falls below is greatly reduced. This decrease in duration is considered to be due to the evaporation of moisture contained in the exothermic composition from the outer bag. Therefore, in the past, the amount of exothermic composition was increased more than necessary by reducing the duration of heat generation, thereby ensuring that the desired heat generation duration was satisfied even after long-term storage. There is a problem that it takes. Therefore, it is necessary to wrap the inner bag in the outer bag so that moisture is not scattered from the outer bag as much as possible.
 本発明は、上記した課題に着目してなされたもので、発熱組成物に含まれる水分が外袋から飛散するのを抑制して、未使用状態が長期間続いても、発熱組成物の発熱持続時間が良好に保持可能な使い捨てカイロを提供することを目的とする。 The present invention has been made paying attention to the above-described problem, and suppresses the moisture contained in the exothermic composition from scattering from the outer bag, so that the exothermic heat of the exothermic composition can be maintained even if the unused state continues for a long period of time. An object of the present invention is to provide a disposable body warmer capable of maintaining a good duration.
 本発明の上記目的は、水分を含有し空気と接触することで発熱する発熱組成物が通気性を有する内袋内に封入されており、前記内袋が気密性を有する外袋内に収納されている使い捨てカイロであって、前記外袋は、前記内袋を収納可能でありかつ互いに区画された収納部を少なくとも3つ備えており、前記内袋は、前記発熱組成物を封入可能でありかつ互いに区画された封入部を少なくとも2つ備えており、少なくとも1つの前記封入部が他の前記封入部と重ねられるよう少なくとも1回折り畳まれた状態で前記収納部に収納されている使い捨てカイロにより達成される。 The object of the present invention is that a heat-generating composition containing moisture and generating heat upon contact with air is enclosed in an air-permeable inner bag, and the inner bag is accommodated in an air-tight outer bag. The outer bag is capable of storing the inner bag and includes at least three storage portions partitioned from each other, and the inner bag can enclose the exothermic composition. And at least two enclosure parts partitioned from each other, and a disposable body warmer accommodated in the accommodation part in a state where at least one of the enclosure parts is folded at least once so as to overlap with the other enclosure parts Achieved.
 上記構成の発熱具の好ましい実施態様においては、1つの前記封入部に他の全ての前記封入部が積み重ねられていることを特徴としている。 In a preferred embodiment of the heating tool having the above-described configuration, all the other enclosure parts are stacked in one enclosure part.
 さらに好ましい実施態様においては、前記内袋は、少なくとも一方の表面に非通気性のシート材が積層されており、前記非通気性のシート材が上下の最表面となるように前記封入部が重ねられていることを特徴としている。 In a more preferred embodiment, the inner bag is formed by laminating a non-breathable sheet material on at least one surface, and the enclosing portion is overlapped so that the non-breathable sheet material becomes upper and lower outermost surfaces. It is characterized by being.
 さらに好ましい実施態様においては、少なくとも1つの前記収納部に少なくとも3つの他の前記収納部が連続して設けられるよう、前記外袋が形成されている、あるいは、全ての前記収納部に少なくとも2つの他の前記収納部が連続して設けられるよう、前記外袋が形成されていることが好ましい。 In a further preferred embodiment, the outer bag is formed so that at least three other storage parts are continuously provided in at least one storage part, or at least two of all the storage parts are provided. It is preferable that the outer bag is formed so that the other storage units are continuously provided.
 さらに好ましい実施態様においては、前記封入部の数が2~4であることを特徴としている。 In a further preferred embodiment, the number of the enclosing portions is 2 to 4.
 本発明の使い捨てカイロによれば、発熱組成物に含まれる水分が外袋から飛散するのを抑制できるので、未使用状態が長期間続いても、発熱組成物の発熱持続時間を良好に保持できる。 According to the disposable body warmer of the present invention, the moisture contained in the exothermic composition can be prevented from scattering from the outer bag, so that the exothermic duration of the exothermic composition can be favorably maintained even if the unused state continues for a long period of time. .
本発明の一実施形態に係る使い捨てカイロの平面図である。It is a top view of the disposable body warmer concerning one embodiment of the present invention. 図1の断面図である。It is sectional drawing of FIG. 内袋の平面図である。It is a top view of an inner bag. 図3の断面図である。FIG. 4 is a cross-sectional view of FIG. 3. 内袋の変形例を示す平面図である。It is a top view which shows the modification of an inner bag. 外袋の変形例を示す平面図である。It is a top view which shows the modification of an outer bag. 外袋の変形例を示す平面図である。It is a top view which shows the modification of an outer bag. 外袋の変形例を示す平面図である。It is a top view which shows the modification of an outer bag. 外袋の変形例を示す平面図である。It is a top view which shows the modification of an outer bag. 外袋の変形例を示す平面図である。It is a top view which shows the modification of an outer bag. 外袋の変形例を示す平面図である。It is a top view which shows the modification of an outer bag. 本実施形態の使い捨てカイロと比較例の使い捨てカイロとの持続時間の減少率を比較するグラフである。It is a graph which compares the decreasing rate of the duration of the disposable body warmer of this embodiment, and the disposable body warmer of a comparative example. 従来例の使い捨てカイロの平面図である。It is a top view of the disposable warmer of a prior art example. 従来例の使い捨てカイロの平面図である。It is a top view of the disposable warmer of a prior art example.
 以下、本発明に係る使い捨てカイロの実施形態について図面を参照しつつ説明する。本実施形態の使い捨てカイロ1は、図1及び図2に示すように、空気と接触することで発熱する発熱組成物2が通気性を有する扁平状の内袋3内に封入され、内袋3が気密性を有する扁平状の外袋4内に収納されてなるものであり、内袋3を外袋4から取り出し、内袋3の発熱組成物2を、手足や腰部、背中、腹、足の裏、肩、臀部など身体の種々の部位に当てることで、温熱を与えるものである。 Hereinafter, embodiments of the disposable body warmer according to the present invention will be described with reference to the drawings. As shown in FIGS. 1 and 2, the disposable body warmer 1 according to the present embodiment includes a heat generating composition 2 that generates heat when in contact with air enclosed in a flat inner bag 3 having air permeability. Is housed in a flat outer bag 4 having airtightness, the inner bag 3 is taken out from the outer bag 4, and the heat generating composition 2 of the inner bag 3 is removed from the limbs, lower back, back, abdomen, and feet. Heat is applied to various parts of the body such as the back, shoulders, and buttocks.
 発熱組成物2は、空気との接触により発熱するものであればよく、例えば、被酸化性金属、活性炭、保水剤(木粉、バーミキュライト、けい藻土、パーライト、シリカゲル、アルミナ、吸水性樹脂など)、金属塩(食塩など)及び水をそれぞれ適宜の含有量含んでいる、従来から使い捨てカイロに用いられている公知の組成物を使用することができる。被酸化性金属は、酸化反応熱を発する金属であり、例えば、鉄、アルミニウム、亜鉛、マンガン、マグネシウム、及びカルシウムから選ばれる1種又は2種以上の粉末や繊維が挙げられる。なかでも、取り扱い性、安全性、製造コスト、保存性及び安定性の点から鉄粉が好ましい。鉄粉としては、例えば、還元鉄粉、及びアトマイズ鉄粉から選ばれる1種又は2種以上が挙げられる。使い捨てカイロ1は、上記した発熱組成物2の成分が調整されていることにより、使用時に所望の発熱条件(最高温度、平均温度、発熱持続時間など)となるようにコントロールされている。例えば、発熱組成物2中の被酸化性金属の配合量は、30%~80%が好ましく、40%~70%がより好ましく、40%~65%がさらに好ましい。また、発熱組成物2の必須成分である水は、配合割合が少ないと発熱持続時間が短くなるため、発熱組成物2における水分の配合割合は工夫されている。このように、発熱組成物2に含まれる水分の配合割合は、使用時に所望の発熱持続時間を実現するための重要なファクターである。よって、使い捨てカイロ1が店頭に置かれる状態が長くなるなど未使用状態が長期間続いても、発熱組成物2に含まれる水分ができる限り外袋4から飛散しないようにして、発熱組成物2の水分の配合割合の低下により発熱持続時間が減少しないようにするために、本実施形態の使い捨てカイロ1では、内袋3及び外袋4の形状や内袋3の外袋4への収納方法について工夫している。 The exothermic composition 2 only needs to generate heat upon contact with air. For example, an oxidizable metal, activated carbon, water retention agent (wood powder, vermiculite, diatomaceous earth, perlite, silica gel, alumina, water-absorbing resin, etc. ), Metal salts (such as sodium chloride), and water, each of which contains an appropriate content, and a known composition conventionally used for disposable warmers can be used. The oxidizable metal is a metal that generates heat of oxidation reaction, and examples thereof include one or more powders and fibers selected from iron, aluminum, zinc, manganese, magnesium, and calcium. Among these, iron powder is preferable from the viewpoints of handleability, safety, manufacturing cost, storage stability, and stability. Examples of the iron powder include one or more selected from reduced iron powder and atomized iron powder. The disposable body warmer 1 is controlled so as to have desired heat generation conditions (maximum temperature, average temperature, heat generation duration, etc.) during use by adjusting the components of the heat generating composition 2 described above. For example, the blending amount of the oxidizable metal in the exothermic composition 2 is preferably 30% to 80%, more preferably 40% to 70%, and further preferably 40% to 65%. In addition, since water, which is an essential component of the exothermic composition 2, has a reduced exothermic duration when the blending ratio is small, the blending ratio of water in the exothermic composition 2 is devised. Thus, the blending ratio of moisture contained in the exothermic composition 2 is an important factor for realizing a desired exothermic duration during use. Therefore, even when the disposable body warmer 1 is placed in the store for a long time, such as when it is not used for a long period of time, the heat generating composition 2 prevents the moisture contained in the heat generating composition 2 from scattering from the outer bag 4 as much as possible. In the disposable body warmer 1 of the present embodiment, the shape of the inner bag 3 and the outer bag 4 and the method for storing the inner bag 3 in the outer bag 4 in order to prevent the duration of heat generation from decreasing due to a decrease in the moisture mixing ratio Devised about.
 内袋3は、図3及び図4に示すように、表裏2枚の矩形状の第1シート材30及び第2シート材31からなり、両シート材30,31を重ね合わせ、外周縁(四つの方面の側縁)を公知の接着剤を用いてシール(接合)する、あるいは熱接合(ヒートシール)することによって、内部に発熱組成物2を封入可能な複数(本実施形態では2つ)の矩形状の封入部32を有する袋状に形成されている。複数の封入部32は、隣接する封入部32の間を両シート材30,31のシールにより仕切ることで、互いに区画されている。各封入部32は、図2に示すように、隣接する封入部32の間で内袋3を折り畳むことで、互いに重ねることが可能である。なお、内袋3に設けられる封入部32の数は、2つに限られず3つ以上でもよいが、2つ~4つであることが好ましい。また、複数の封入部32の配置の仕方は特に限定されるものではなく、図3に示すように、複数の封入部32が1列で整列するようにして配置されていてもよく、また、上下複数列で整列するようにして、例えば封入部32の数が4つの場合には、図5に示すように、上下2列でそれぞれ2つずつ整列するようにして配置されていてもよい。この場合も、各封入部32は、内袋3を上下及び/又は左右で隣接する封入部32の間で折り畳むことで、互いに重ねることが可能である。 As shown in FIGS. 3 and 4, the inner bag 3 is composed of two sheets of a first sheet material 30 and a second sheet material 31 that are rectangular on the front and back sides. A plurality of (two in the present embodiment) in which the exothermic composition 2 can be encapsulated by sealing (bonding) the side edges of one surface) using a known adhesive or by heat bonding (heat sealing). It is formed in a bag shape having a rectangular enclosing portion 32. The plurality of enclosing portions 32 are partitioned from each other by partitioning the adjacent enclosing portions 32 with the seals of both sheet materials 30 and 31. As shown in FIG. 2, the enclosing portions 32 can be overlapped with each other by folding the inner bag 3 between the adjacent enclosing portions 32. Note that the number of the sealing portions 32 provided in the inner bag 3 is not limited to two, and may be three or more, but is preferably two to four. Further, the arrangement method of the plurality of encapsulating portions 32 is not particularly limited, and as shown in FIG. 3, the plurality of encapsulating portions 32 may be arranged in a line, For example, when the number of the enclosing portions 32 is four, the two upper and lower rows may be arranged so that two rows are aligned in each of the upper and lower rows. Also in this case, each enclosure part 32 can be mutually piled up by folding the inner bag 3 between the enclosure parts 32 adjacent on the upper and lower sides and / or right and left.
 第1シート材30は、通気性を有しており、使用時に身体に接触される。第1シート材30としては、通気性を有していれば、多孔質の樹脂フィルムであっても針で穿孔した樹脂フィルムであってもよく、不織布又は織布であってもよい。また、第1シート材30は、単層構成であってもよいし、樹脂フィルムと不織布とを積層した多層構成であってもよい。樹脂フィルムとしては、従来から使い捨てカイロ1の内袋3として用いられているものを使用でき、例えば、ポリエチレン、ポリプロピレン、ポリエステル、ポリアミド、ポリビニルアルコール、ポリ塩化ビニル、ポリ塩化ビニリデン、ポリウレタン、ポリスチレン、エチレン-酢酸ビニル共重合体、ポリカーボネート、塩酸ゴムなどを例示することができ、また、不織布も、ポリプロピレン、ナイロン、ビニロン、ポリエステル、ポリエチレンテレフタレート、レーヨン、アセテート、アクリル、ポリエチレン、ポリ塩化ビニルなどの人工繊維、綿、麻、絹などの天然繊維を含むものなどを例示することができる。また、不織布以外にも例えば紙などを例示することができる。 The first sheet material 30 has air permeability and comes into contact with the body when used. As long as it has air permeability, the first sheet material 30 may be a porous resin film, a resin film perforated with a needle, or a non-woven fabric or a woven fabric. Moreover, the 1st sheet | seat material 30 may be a single layer structure, and the multilayer structure which laminated | stacked the resin film and the nonwoven fabric may be sufficient as it. As the resin film, those conventionally used as the inner bag 3 of the disposable body warmer 1 can be used. For example, polyethylene, polypropylene, polyester, polyamide, polyvinyl alcohol, polyvinyl chloride, polyvinylidene chloride, polyurethane, polystyrene, ethylene -Vinyl acetate copolymer, polycarbonate, hydrochloric acid rubber and the like can be exemplified, and non-woven fabrics are also artificial fibers such as polypropylene, nylon, vinylon, polyester, polyethylene terephthalate, rayon, acetate, acrylic, polyethylene, polyvinyl chloride, etc. Examples include those containing natural fibers such as cotton, hemp and silk. Moreover, paper etc. can be illustrated other than a nonwoven fabric.
 第2シート材31としては、通気性又は非通気性のいずれを有していてもよく、第1シート材30と同様に、樹脂フィルムであっても不織布又は織布であってもよく、また、単層構成であってもよいし多層構成であってもよい。第2シート材31を非通気性とする場合には、図4に示すように、表面に粘着層33を設けることができる。具体的には、皮膚及び衣服への粘着作用のあるアクリル樹脂系、ゴム系樹脂などからなる粘着剤を第2シート材31の表面に塗布することができ、これにより、いわゆる貼るタイプのカイロとすることができる。粘着層33は、内袋3を外袋4に収納して使用されるまでの間は、剥離紙34で被覆されている。一方で、第2シート材31を通気性とし、手に持って使用するようないわゆる貼らないタイプのカイロとする場合には、内袋3を外袋4に収納して使用されるまでの間は、第1シート材31及び第2シート材32の少なくとも一方の表面が非通気性のシート材で覆われていることが好ましい。 The second sheet material 31 may have either air permeability or non-air permeability, and may be a resin film, a non-woven fabric, or a woven fabric, like the first sheet material 30. A single layer configuration or a multilayer configuration may be used. When making the 2nd sheet material 31 air-impermeable, as shown in FIG. 4, the adhesion layer 33 can be provided in the surface. Specifically, it is possible to apply an adhesive made of acrylic resin, rubber resin, or the like having an adhesive action to the skin and clothes to the surface of the second sheet material 31, so that a so-called sticking type warmer and can do. The adhesive layer 33 is covered with the release paper 34 until the inner bag 3 is stored in the outer bag 4 and used. On the other hand, when the second sheet material 31 is made to be breathable and is a so-called non-stick type warmer that is used by holding it in the hand, the inner bag 3 is stored in the outer bag 4 until it is used. It is preferable that at least one surface of the first sheet material 31 and the second sheet material 32 is covered with a non-breathable sheet material.
 なお、内袋3は、本実施形態では、2枚のシート材30,31を外周縁(四つの方面の側縁)及び中央位置でシールすることで、互いに区画された2つの封入部32が一体に設けられるように形成されているが、例えば、封入部32を1つ有する2つのコンパクトサイズの内袋を個々に作製した後、この2つの内袋の周縁の綴じ代同士を接着により一体にして形成してもよい。 In this embodiment, the inner bag 3 has two sealed portions 32 separated from each other by sealing the two sheet materials 30 and 31 at the outer peripheral edge (side edges of the four directions) and the center position. Although formed so as to be provided integrally, for example, two compact sized inner bags each having one enclosing portion 32 are individually manufactured, and then the binding margins of the peripheral edges of the two inner bags are integrated by bonding. May be formed.
 封入部32は、封入部32の容積に対する発熱組成物2の封入容積の割合が、30%~80%程度であることが好ましく、50%~70%程度であることが特に好ましい。この割合が80%を超えると、発熱組成物2が過剰となり、2枚のシート材30,31をシールすることで複数の封入部32を有する内袋3を形成する際に、シール部分に発熱組成物2が噛み込み、内袋3を形成できないおそれがあるからである。一方で、この割合が30%より少ないと、使用時に所望の発熱条件を満たさないおそれがあるからである。また、封入部32の面積は、0.05m以下であることが好ましい。封入部32の面積が0.05mを超えると、後述する内袋3を収納する外袋4の収納部42の面積が大きくなり、よって、外袋4全体のサイズが大きくなって携帯するには嵩張る、外袋4(包装フィルム40,41)の使用量が増えてコストアップにつながる、などの問題が生じるおそれがあるからである。 In the enclosing portion 32, the ratio of the enclosing volume of the exothermic composition 2 to the volume of the enclosing portion 32 is preferably about 30% to 80%, and particularly preferably about 50% to 70%. If this ratio exceeds 80%, the exothermic composition 2 becomes excessive, and when the inner bag 3 having a plurality of enclosing portions 32 is formed by sealing the two sheet materials 30 and 31, heat is generated in the seal portion. This is because the composition 2 may bite and the inner bag 3 may not be formed. On the other hand, if this ratio is less than 30%, the desired heat generation condition may not be satisfied during use. Moreover, it is preferable that the area of the enclosure part 32 is 0.05 m < 2 > or less. When the area of the enclosing portion 32 exceeds 0.05 m 2 , the area of the storage portion 42 of the outer bag 4 that stores the inner bag 3 to be described later increases, so that the overall size of the outer bag 4 increases and is carried. This is because there is a possibility that problems such as being bulky and increasing the amount of use of the outer bag 4 (wrapping films 40 and 41) may lead to an increase in cost.
 外袋4は、図1及び図2に示すように、表裏2枚の包装フィルム40,41からなり、両包装フィルム40,41を重ね合わせ、外周縁を、例えば熱接合(ヒートシール)する、あるいは公知の接着剤を用いてシール(接合)することにより、内部に内袋3を収納可能な少なくとも3つの矩形状の収納部42を、外周縁に外袋4を密封する第1シール部43を、それぞれ有する袋状に形成されている。隣接する収納部42の間には、両包装フィルム40,41が直線状にシール(接合)されることで第2シール部44が形成されており、隣接する収納部42は第2シール部44により互いに区画されている。なお、外袋4の少なくとも3つの収納部42の配置の仕方については後述するが、特に限定されるものではない。 As shown in FIGS. 1 and 2, the outer bag 4 is composed of two front and back packaging films 40 and 41, and the two packaging films 40 and 41 are overlapped, and the outer peripheral edge is, for example, thermally bonded (heat sealed). Alternatively, by sealing (joining) using a known adhesive, at least three rectangular storage portions 42 capable of storing the inner bag 3 therein, and a first seal portion 43 sealing the outer bag 4 at the outer peripheral edge. Are each formed into a bag shape. Between the adjacent storage portions 42, the two sealing films 40 and 41 are linearly sealed (joined) to form a second seal portion 44, and the adjacent storage portions 42 are the second seal portions 44. Are separated from each other. In addition, although how to arrange the at least three storage portions 42 of the outer bag 4 will be described later, it is not particularly limited.
 包装フィルム40,41としては、従来から使い捨てカイロ1の外袋4として用いられているものを使用でき、例えば、ポリエチレン、ポリプロピレン、シリカ蒸着フィルム、塩化ビニリデンコートフィルムなどの無孔フィルムを例示することができる。中でも、酸素や水蒸気の非透過性、及び、水素の適切な透過性の点で、塩化ビニリデンコートフィルム(KOP、Kナイロン、KPETなど)、アルミ蒸着コートフィルム(VMPET、VMCPPなど)が好ましい。 As the packaging films 40 and 41, those conventionally used as the outer bag 4 of the disposable body warmer 1 can be used, and examples thereof include non-porous films such as polyethylene, polypropylene, silica-deposited film, and vinylidene chloride coated film. Can do. Among these, vinylidene chloride coated films (KOP, K nylon, KPET, etc.) and aluminum vapor-deposited coated films (VMPET, VMCPP, etc.) are preferable from the viewpoint of impermeability of oxygen and water vapor and appropriate permeability of hydrogen.
 本実施形態の使い捨てカイロ1は、内袋3の少なくとも1つの封入部32が他の封入部32と重ねられるよう、内袋3が少なくとも1回折り畳まれた状態で、外袋4の各収納部42にそれぞれ収納されていることに特徴を有している。つまり、内袋3に設けられた封入部32の数が例えば2つの場合には、図2に示すように、内袋3を中央位置で折り畳むことで一方の封入部32に他方の封入部32を積み重ね、この状態で内袋3が外袋4の各収納部42に1つずつ収納されている。このように、封入部32が積み重ねられると、内袋3の面積(複数の封入部32の総表面積)を半分に減少させることができるので、各封入部32に封入された発熱組成物2が外部と触れる面積が減少する。よって、各封入部32に封入された発熱組成物2中の水分を飛散しにくくすることができる。また、内袋3を折り畳んで収納すれば、折り畳まないで収納する場合よりも、内袋3を収納する外袋4の収納部42の面積を小さくすることができるので、その分、発熱組成物2中の水分が収納部42の表裏面(包装フィルム40,41)を通り抜けて収納部42の外部に飛散することも抑制することができる。その上、内袋3を折り畳んで収納すれば、折り畳まないで収納する場合よりも、外袋4(包装フィルム40,41)の使用量を抑えることができるので、コストダウンにもつながる。 The disposable body warmer 1 according to the present embodiment is configured so that the inner bag 3 is folded at least once so that at least one enclosing portion 32 of the inner bag 3 is overlapped with the other enclosing portion 32, and each storage portion of the outer bag 4 is stored. It is characterized in that it is housed in each of 42. That is, when the number of enclosure parts 32 provided in the inner bag 3 is two, for example, as shown in FIG. 2, the inner bag 3 is folded at the center position so that the one enclosure part 32 is replaced with the other enclosure part 32. In this state, one inner bag 3 is stored in each storage portion 42 of the outer bag 4. Thus, when the enclosure part 32 is stacked, the area of the inner bag 3 (total surface area of the plurality of enclosure parts 32) can be reduced by half, so that the exothermic composition 2 enclosed in each enclosure part 32 is The area touching the outside is reduced. Therefore, it is possible to make it difficult for the moisture in the exothermic composition 2 enclosed in each enclosure part 32 to scatter. Further, if the inner bag 3 is folded and stored, the area of the storage portion 42 of the outer bag 4 that stores the inner bag 3 can be made smaller than when the inner bag 3 is stored without being folded. 2 can also be prevented from passing through the front and back surfaces (wrapping films 40, 41) of the storage portion 42 and splashing to the outside of the storage portion 42. In addition, if the inner bag 3 is folded and stored, the amount of use of the outer bag 4 (wrapping films 40 and 41) can be reduced as compared with the case where the inner bag 3 is not folded and stored, which leads to cost reduction.
 なお、このとき、内袋3は、第2シート材31が非通気性の場合には第2シート材31が、第2シート材31が通気性の場合には第1シート材31及び第2シート材32の少なくとも一方の表面を覆う非通気性のシート材(図示せず)が、上下の最表面となるように折り畳まれることが好ましい。これにより、積み重ねられた封入部32の上下の最表面が非通気性となるため、各封入部32に封入された発熱組成物2中の水分をさらに効果的に飛散しにくくすることができる。 At this time, the inner bag 3 has the second sheet material 31 when the second sheet material 31 is air-impermeable and the first sheet material 31 and the second sheet material when the second sheet material 31 is air-permeable. It is preferable that a non-breathable sheet material (not shown) covering at least one surface of the sheet material 32 is folded so as to be upper and lower outermost surfaces. Thereby, since the uppermost surface of the stacked enclosure part 32 becomes air-impermeable, the moisture in the heat-generating composition 2 enclosed in each enclosure part 32 can be more effectively prevented from scattering.
 また、内袋3に設けられた封入部32の数が3つの場合には、一端の封入部32と中央の封入部32との間で内袋3を1回折り畳み、この2つの封入部32だけが重ねられた状態で、内袋3を外袋4の各収納部42に1つずつ収納してもよいが、さらに、他端の封入部32を積み重ねられた2つの封入部32に重ねる、つまりは、全ての封入部32が積み重ねられるように、内袋3を2回折り畳んだ状態で、外袋4の各収納部42に1つずつ収納するのが好ましい。これにより、内袋3の面積(封入部32の総表面積)を最小(1/3)とすることができるので、上記した通り、発熱組成物2中の水分が収納部42から外部に飛散することを抑制できる。また、このとき、内袋3を、同様に、第2シート材31が非通気性の場合には第2シート材31が、第2シート材31が通気性の場合には第1シート材31及び第2シート材32の少なくとも一方の表面を覆う非通気性のシート材(図示せず)が、上下の最表面となるように折り畳むことで、各封入部32に封入された発熱組成物2中の水分をさらに効果的に飛散しにくくすることができる。 When the number of enclosures 32 provided in the inner bag 3 is three, the inner bag 3 is folded once between the enclosure 32 at one end and the enclosure 32 at the center, and the two enclosures 32 are provided. The inner bag 3 may be stored one by one in each storage portion 42 of the outer bag 4 in a state where only the two are stacked, but the other sealing portions 32 are stacked on the two stacked sealing portions 32. In other words, it is preferable to store the inner bag 3 one by one in each storage portion 42 of the outer bag 4 in a state where the inner bag 3 is folded twice so that all the enclosing portions 32 are stacked. Thereby, since the area of the inner bag 3 (total surface area of the enclosing part 32) can be minimized (1/3), the moisture in the exothermic composition 2 is scattered from the storage part 42 to the outside as described above. This can be suppressed. At this time, similarly, when the second sheet material 31 is air-impermeable, the inner sheet 3 is the second sheet material 31 and when the second sheet material 31 is air-permeable, the first sheet material 31 is used. And the non-breathable sheet material (not shown) covering at least one surface of the second sheet material 32 is folded so as to be the upper and lower outermost surfaces, whereby the exothermic composition 2 enclosed in each enclosure portion 32. It is possible to make it difficult to effectively disperse moisture therein.
 また、内袋3に設けられた封入部32の数が4つの場合には、内袋3を種々の方法で折り畳んで、外袋4の各収納部42にそれぞれ収納してもよいが、全ての封入部32が積み重ねられるように内袋3を2回ないしは3回折り畳んだ状態で、外袋4の各収納部42にそれぞれ収納するのが、内袋3の面積(封入部32の総表面積)を最小(1/4)とできるので好ましい。これにより、上記した通り、発熱組成物2中の水分が収納部42から外部に飛散することを抑制できる。また、このとき、内袋3を、同様に、第2シート材31が非通気性の場合には第2シート材31が、第2シート材31が通気性の場合には第1シート材31及び第2シート材32の少なくとも一方の表面を覆う非通気性のシート材(図示せず)が、上下の最表面となるように折り畳むことで、各封入部32に封入された発熱組成物2中の水分をさらに効果的に飛散しにくくすることができる。なお、内袋3に設けられた封入部32の数が5つ以上の場合であっても、同様に、1つの封入部32に他の全ての封入部32が積み重ねられるように内袋3を隣接する封入部32の間で複数回折り畳み、この折り畳んだ状態で内袋3を外袋4の2つの収納部42に1つずつ収納するのが好ましい。 Further, when the number of the enclosing portions 32 provided in the inner bag 3 is four, the inner bag 3 may be folded by various methods and stored in the storage portions 42 of the outer bag 4, respectively. In the state where the inner bag 3 is folded twice or three times so that the enclosed portions 32 of the inner bag 3 are stacked, each of the accommodating portions 42 of the outer bag 4 is accommodated in the area of the inner bag 3 (total surface area of the enclosed portion 32). ) Can be minimized (1/4), which is preferable. Thereby, as above-mentioned, it can suppress that the water | moisture content in the heat-generating composition 2 splashes outside from the accommodating part 42. FIG. At this time, similarly, when the second sheet material 31 is air-impermeable, the inner sheet 3 is the second sheet material 31 and when the second sheet material 31 is air-permeable, the first sheet material 31 is used. And the non-breathable sheet material (not shown) covering at least one surface of the second sheet material 32 is folded so as to be the upper and lower outermost surfaces, whereby the exothermic composition 2 enclosed in each enclosure portion 32. It is possible to make it difficult to effectively disperse moisture therein. Even when the number of the enclosure parts 32 provided in the inner bag 3 is five or more, similarly, the inner bag 3 is arranged so that all the other enclosure parts 32 are stacked in one enclosure part 32. It is preferable that a plurality of folded portions are folded between adjacent enclosing portions 32 and the inner bag 3 is stored in the two storing portions 42 of the outer bag 4 one by one in this folded state.
 さらに、上記した発熱組成物2中の水分が収納部42から外部に飛散することを抑制するために、本実施形態の使い捨てカイロ1では、外袋4に内袋3の収納部42を少なくとも3つ設けるようにしている。内袋3に封入された発熱組成物2中の水分は、収納部42の表裏面(包装フィルム40,41)の他、収納部42の外周縁からも外部に飛散する可能性があるが、外袋4に収納部42が3つ以上設けられていると、全ての収納部42が、第2シール部44を介して少なくとも1つ他の収納部42と連結されるようになるうえ、少なくとも1つの収納部42が、第2シール部44を介して少なくとも2つの他の収納部42と連結されるようになる。よって、収納部42の形状が矩形状である場合には、ある収納部42の一つの方面の側縁から発熱組成物2中の水分が飛散しても、第2シール部44を通り抜けて他の収納部42に飛散するため、結局、互いの収納部42で発熱組成物2からの水分を交換することになる。したがって、収納部42内に発熱組成物2からの水分を留めることができ、収納部42から外部に飛散することを抑制できる。 Furthermore, in order to suppress the moisture in the exothermic composition 2 from scattering from the storage portion 42 to the outside, in the disposable body warmer 1 of the present embodiment, at least 3 of the storage portion 42 of the inner bag 3 is provided in the outer bag 4. One is provided. The moisture in the heat generating composition 2 enclosed in the inner bag 3 may be scattered outside from the outer peripheral edge of the storage unit 42 in addition to the front and back surfaces (packaging films 40 and 41) of the storage unit 42. When the outer bag 4 is provided with three or more storage portions 42, all the storage portions 42 are connected to at least one other storage portion 42 via the second seal portion 44, and at least One storage portion 42 is connected to at least two other storage portions 42 via the second seal portion 44. Therefore, when the shape of the storage portion 42 is rectangular, even if moisture in the exothermic composition 2 scatters from one side edge of the storage portion 42, it passes through the second seal portion 44 and others. As a result, the moisture from the exothermic composition 2 is eventually exchanged in the mutual storage portions 42. Therefore, the moisture from the exothermic composition 2 can be retained in the storage portion 42, and scattering from the storage portion 42 to the outside can be suppressed.
 外袋4の少なくとも3つの収納部42は、例えば図1に示すように、1列で整列するようにして配置することができる。この配置の仕方の場合には、両端の収納部42については、一つの方面の側縁だけに他の収納部42が連結されるが、間の収納部42については、二つの方面の側縁に他の収納部42が連結されるので、合計2つの他の収納部42が連結され、収納部42内に発熱組成物2からの水分を良好に留めることができ、収納部42から外部に飛散することを効果的に抑制できる。また、少なくとも3つの収納部42は、例えば図6に示すように、L字状となるようにして配置することができる。この配置の仕方の場合においても、L字の両端の収納部42については、一つの方面の側縁だけに他の収納部42が連結されるが、間の収納部42については、二つの方面の側縁に他の収納部42が連結されるので、合計2つの他の収納部42が連結され、収納部42内に発熱組成物2からの水分を良好に留めることができ、収納部42から外部に飛散することを効果的に抑制できる。なお、図1及び図6は、収納部42の数が3つの場合を例示しているが、4つ以上でも同様である。 The at least three storage portions 42 of the outer bag 4 can be arranged so as to be aligned in one row, for example, as shown in FIG. In the case of this arrangement, with respect to the storage portions 42 at both ends, the other storage portions 42 are connected only to the side edges of one direction, but the storage portions 42 between them are connected to the side edges of the two directions. Since the other storage portions 42 are connected to each other, a total of two other storage portions 42 are connected, and moisture from the exothermic composition 2 can be satisfactorily retained in the storage portion 42, and from the storage portion 42 to the outside. It is possible to effectively suppress the scattering. Further, at least three storage portions 42 can be arranged in an L shape as shown in FIG. 6, for example. Even in the case of this arrangement, with respect to the storage portions 42 at both ends of the L-shape, the other storage portions 42 are connected to only one side edge, but the storage portion 42 between them has two directions. Since the other storage portions 42 are connected to the side edges of the storage portion 42, a total of two other storage portions 42 are connected, and moisture from the exothermic composition 2 can be satisfactorily retained in the storage portion 42. Can be effectively prevented from being scattered outside. 1 and 6 exemplify the case where the number of the storage units 42 is three, the same applies to four or more storage units 42.
 また、少なくとも3つの収納部42は、上下複数列で整列するようにして配置することができる。例えば収納部42の数が4つの場合には、図7に示すように、上下2列でそれぞれ2つずつ整列するようにして配置することができる。この配置の仕方の場合には、全ての収納部42について、二つの方面の側縁に他の収納部42が連結されるので、合計2つの他の収納部42が連結され、収納部42内に発熱組成物2からの水分を良好に留めることができ、収納部42から外部に飛散することを効果的に抑制できる。また、例えば収納部42の数が6つの場合には、図8に示すように、上下2列でそれぞれ3つずつ整列するようにして配置することができる。この配置の仕方の場合には、四隅の収納部42については、二つの方面の側縁に他の収納部42が連結されるが、間の収納部42については、三つの方面の側縁に他の収納部42が連結されるので、合計3つの他の収納部42が連結され、収納部42内に発熱組成物2からの水分をより良好に留めることができ、収納部42から外部に飛散することをより効果的に抑制できる。なお、8つ以上の場合でも同様である。また、例えば収納部42の数が9つの場合には、図9に示すように、上下3列でそれぞれ3つずつ整列するようにして配置することができる。この配置の仕方の場合には、四隅の収納部42については、二つの方面の側縁に他の収納部42が連結され、その間の収納部42については、三つの方面の側縁に他の収納部42が連結されるが、中央の収納部42については、四つ全ての方面の側縁に他の収納部42が連結されるので、合計4つの他の収納部42が連結され、収納部42内に発熱組成物2からの水分をさらに良好に留めることができ、収納部42から外部に飛散することをさらに効果的に抑制できる。 In addition, at least three storage units 42 can be arranged so as to be aligned in a plurality of upper and lower rows. For example, when the number of storage parts 42 is four, as shown in FIG. 7, it can arrange | position so that it may each arrange 2 each in two upper and lower rows. In the case of this arrangement, since the other storage portions 42 are connected to the side edges in the two directions with respect to all the storage portions 42, a total of two other storage portions 42 are connected to each other in the storage portion 42. In addition, moisture from the heat generating composition 2 can be kept well, and scattering from the storage portion 42 to the outside can be effectively suppressed. For example, when the number of the storage units 42 is 6, as shown in FIG. In the case of this arrangement, with respect to the storage portions 42 at the four corners, the other storage portions 42 are connected to the side edges of the two directions, but the storage portions 42 between them are connected to the side edges of the three directions. Since the other storage portions 42 are connected, a total of three other storage portions 42 are connected, and moisture from the exothermic composition 2 can be better retained in the storage portion 42, and from the storage portion 42 to the outside. It is possible to more effectively suppress scattering. The same applies to the case of eight or more. Further, for example, when the number of storage units 42 is nine, as shown in FIG. In the case of this arrangement, with respect to the storage portions 42 at the four corners, the other storage portions 42 are connected to the side edges of the two directions, and the storage portions 42 between them are connected to the side edges of the three directions. Although the storage part 42 is connected, since the other storage part 42 is connected to the side edges of all four sides of the central storage part 42, a total of four other storage parts 42 are connected and stored. The moisture from the exothermic composition 2 can be further satisfactorily retained in the portion 42, and the scattering from the storage portion 42 to the outside can be more effectively suppressed.
 また、少なくとも3つの収納部42は、図10に示すT字状(収納部42の数が4つの場合を例示している)や図11に示す十字状(収納部42の数が5つの場合を例示している)など、種々の形状となるようにして配置することもでき、これにより、収納部42内に発熱組成物2からの水分をできる限り留めて、収納部42から外部に飛散することを抑制している。 Further, the at least three storage portions 42 may be T-shaped (illustrated when the number of storage portions 42 is four) shown in FIG. 10 or a cross shape (when the number of storage portions 42 is five) shown in FIG. In other words, the moisture from the exothermic composition 2 is kept in the storage portion 42 as much as possible, and scattered from the storage portion 42 to the outside. To suppress.
 このように、外袋4が収納部42を少なくとも3つ備えていれば、少なくとも1つの収納部42は、少なくとも二方の側縁に他の収納部42が連続して設けられるようになるので、合計2つの他の収納部42が連結され、収納部42内の発熱組成物2からの水分が収納部42から外部に飛散することをより効果的に抑制できるようになる。さらに、全ての収納部42について、少なくとも2つの他の収納部42が連続して設けられるように外袋4を形成すれば、各収納部42について、発熱組成物2からの水分が収納部42から外部に飛散することをより効果的に抑制できるようになる。なお、収納部42の平面視の面積は、0.0025m~0.25mが好ましく、0.01m~0.05mがより好ましい。 Thus, if the outer bag 4 has at least three storage portions 42, at least one storage portion 42 is provided with other storage portions 42 continuously on at least two side edges. In addition, a total of two other storage parts 42 are connected, and it is possible to more effectively suppress the moisture from the heat generating composition 2 in the storage part 42 from being scattered from the storage part 42 to the outside. Furthermore, if the outer bag 4 is formed so that at least two other storage units 42 are continuously provided for all the storage units 42, the moisture from the exothermic composition 2 is stored in the storage units 42 for each storage unit 42. It is possible to more effectively suppress scattering from the outside to the outside. The area of the plan view of the housing portion 42 is preferably 0.0025m 2 ~ 0.25m 2, 0.01m 2 ~ 0.05m 2 is more preferable.
 さらに、上記した発熱組成物2中の水分が収納部42から飛散することを抑制するためには、外袋4の外周縁に形成された第1シール部43の強度が強いことが好ましい。外袋4の第1シール部43の強度が強いと、発熱組成物2中の水分が、収納部42の他の収納部42とは連結されていない側縁から外部に飛散する際に、第1シール部43によって外部に飛散するのが遮断されるので、収納部42内に発熱組成物2からの留めることができるからである。第1シール部43の強度は、シール幅やシール条件にもよるが、10N/15mm~100N/15mmの範囲であることが好ましい。一方で、2つの収納部42の間の第2シール部44の強度は、第1シール部43の強度以下であってよく、5N/15mm~80N/15mmの範囲であることが好ましい。なお、第1シール部43及び第2シール部44の強度は、JIS Z 0238 1998に準拠した試験方法により測定できる。また、第1シール部43のシール幅は、1mm~50mmが好ましく、1mm~15mmがより好ましい。また、第2シール部44のシール幅は、1mm~50mmが好ましく、1mm~15mmがより好ましい。第2シール部44の強度が第1シール部43の強度との比較で小さければ、発熱組成物2中の水分が第1シール部43よりも第2シール部44を通り抜けて隣接する収納部42に飛散しやすくなる。また、第1シール部43に対する第2シール部44の長さの割合が、高ければ高いほど、発熱組成物2中の水分が第1シール部43よりも第2シール部44に飛散して、上記した通り、隣接する収納部42同士で飛散した水分の交換をするので、発熱組成物2中の水分が収納部42から飛散することを抑制できる。同様に、第1シール部43のシール幅よりも第2シール部44のシール幅の方が小さければ、発熱組成物2中の水分が第1シール部43よりも第2シール部44から飛散しやすくなるので、好ましい。 Furthermore, in order to prevent the moisture in the exothermic composition 2 from scattering from the storage portion 42, it is preferable that the strength of the first seal portion 43 formed on the outer peripheral edge of the outer bag 4 is strong. When the strength of the first seal portion 43 of the outer bag 4 is strong, when the moisture in the heat generating composition 2 is scattered outside from the side edge not connected to the other storage portion 42 of the storage portion 42, This is because scattering from the outside is blocked by the one seal portion 43, so that the heat generating composition 2 can be retained in the storage portion 42. The strength of the first seal portion 43 is preferably in the range of 10 N / 15 mm to 100 N / 15 mm, depending on the seal width and seal conditions. On the other hand, the strength of the second seal portion 44 between the two storage portions 42 may be equal to or less than the strength of the first seal portion 43, and is preferably in the range of 5 N / 15 mm to 80 N / 15 mm. In addition, the intensity | strength of the 1st seal | sticker part 43 and the 2nd seal | sticker part 44 can be measured with the test method based on JIS Z02381998. The seal width of the first seal portion 43 is preferably 1 mm to 50 mm, and more preferably 1 mm to 15 mm. Further, the seal width of the second seal portion 44 is preferably 1 mm to 50 mm, and more preferably 1 mm to 15 mm. If the strength of the second seal portion 44 is smaller than the strength of the first seal portion 43, the moisture in the exothermic composition 2 passes through the second seal portion 44 and is adjacent to the storage portion 42 adjacent to the first seal portion 43. It becomes easy to scatter. Further, the higher the ratio of the length of the second seal portion 44 to the first seal portion 43 is, the more moisture in the heat generating composition 2 is scattered to the second seal portion 44 than the first seal portion 43, As described above, since the water scattered between the adjacent storage portions 42 is exchanged, it is possible to suppress the water in the heat generating composition 2 from being scattered from the storage portion 42. Similarly, if the seal width of the second seal portion 44 is smaller than the seal width of the first seal portion 43, moisture in the heat generating composition 2 is scattered from the second seal portion 44 rather than the first seal portion 43. Since it becomes easy, it is preferable.
 表1は、外袋4が少なくとも3つの収納部42を有し、各収納部42に複数の封入部32を有する内袋3を折り畳んだ状態で収納した本実施形態の使い捨てカイロ1について、図1に示した外袋4の収納部42の数が3つのもの及び図9に示した外袋4の収納部42の数が9つものを、実施例1,2-1,2-2として示している。また、比較例1,2-1,2-2の使い捨てカイロとして、実施例1,2-1,2-2と同様に収納部をそれぞれ3つあるいは9つ有する外袋に、封入部を1つ有する内袋を収納したものを示している。さらに、比較例3の使い捨てカイロとして、収納部を2つ有する外袋に封入部を2つ有する内袋を折り畳んだ状態で収納したものを示している。この表1の実施例1,2-1,2-2と、比較例1~3とについて、製造後、温度40℃、湿度75%の過酷試験状況下で3ヶ月及び6ヶ月の間、使い捨てカイロを未使用の状態で保管し、その後、内袋を外袋の収納部から取り出して使用した際の発熱組成物2の発熱持続時間を測定した。測定された各例の発熱持続時間について、製造直後(初期)の発熱持続時間を基準とした減少率を算出した結果を図12に示す。なお、実施例1では、連続する3つの収納部42のうち、中央の収納部42(図1)から取り出した内袋3(発熱組成物2)についての発熱持続時間を測定し、実施例2-1及び実施例2-2については、矩形状に配置された9つの収納部42のうち、いずれか1つの角及び中央の収納部42(図9)から取り出した2つの内袋3(発熱組成物2)についての発熱持続時間を測定した。また、比較例1,2-1,2-2についても、実施例1,2-1,2-2とそれぞれ同じ位置の収納部から取り出した内袋(発熱組成物)についての発熱持続時間を測定した。また、比較例3については、2つの収納部のいずれか一方の収納部から取り出した内袋(発熱組成物)についての発熱持続時間を測定した。また、温度40℃、湿度75%の過酷試験状況下で使い捨てカイロを3ヶ月及び6ヶ月の間、保管することは、常温の状態で使い捨てカイロを18ヶ月及び36ヶ月の間、保管することに相当する。 Table 1 shows the disposable body warmer 1 of the present embodiment in which the outer bag 4 has at least three storage portions 42 and the inner bag 3 having a plurality of enclosure portions 32 is stored in each storage portion 42 in a folded state. Embodiments 1, 2-1, and 2-2 have three storage portions 42 of the outer bag 4 shown in FIG. 1 and nine storage portions 42 of the outer bag 4 shown in FIG. Show. Further, as the disposable warmers of Comparative Examples 1, 2-1, and 2-2, in the same manner as in Examples 1, 2-1, and 2-2, the outer bag having three or nine storage portions is used, and the enclosed portion is 1 The one containing a single inner bag is shown. Furthermore, as the disposable hand warmer of Comparative Example 3, an outer bag having two storage portions and an inner bag having two sealed portions stored in a folded state are shown. For Examples 1, 2-1 and 2-2 in Table 1 and Comparative Examples 1 to 3, after production, they were disposable for 3 and 6 months under severe test conditions at a temperature of 40 ° C. and a humidity of 75%. The body was stored in an unused state, and then the heat generation duration of the heat generating composition 2 when the inner bag was taken out from the outer bag storage and used was measured. FIG. 12 shows the results of calculating the reduction rate based on the heat generation duration immediately after manufacturing (initial) for the measured heat generation duration of each example. In Example 1, the heat generation duration of the inner bag 3 (heat generating composition 2) taken out from the central storage part 42 (FIG. 1) among the three continuous storage parts 42 was measured, and Example 2 -1 and Example 2-2, two inner bags 3 (heat generation) taken out from one of the corners and the central storage part 42 (FIG. 9) out of the nine storage parts 42 arranged in a rectangular shape The exothermic duration for composition 2) was measured. Also, in Comparative Examples 1, 2-1, 2-2, the heat generation duration of the inner bag (heat generation composition) taken out from the storage portion at the same position as each of Examples 1, 2-1, 2-2 was also set. It was measured. Moreover, about the comparative example 3, the heat_generation | fever duration about the inner bag (heat-generating composition) taken out from either one of the two storage parts was measured. Also, storing the disposable body warmer for 3 months and 6 months under severe test conditions of a temperature of 40 ° C. and a humidity of 75% means storing the disposable body warmer at room temperature for 18 months and 36 months. Equivalent to.
Figure JPOXMLDOC01-appb-T000001
 
Figure JPOXMLDOC01-appb-T000001
 
 図12に示されているように、まず、実施例1,2-1,2-2は、未使用状態が長期間続いても、製造直後(初期)との比較で持続時間がさほど減少しておらず、発熱持続時間が良好に保持されている。これに対して、比較例3は、未使用状態が長期間続いた場合、18ヶ月までは発熱持続時間が良好に保持されているが、36ヶ月経過すると、大幅に減少しているわけではないが、実施例1,2-1,2-2によりも発熱持続時間が若干減少している。この比較例3は、本実施形態における図3の両端の収納部42など、一つの側縁に他の収納部が連続して設けられた収納部に相当するものであり、未使用状態が長期間続いても、内部に収納した内袋(発熱組成物)の発熱持続時間をある程度良好に保持可能であるが、実施例1,2-1,2-2のように少なくとも二つの側縁に他の収納部が連続して設けられた収納部の方が、内部に収納した内袋(発熱組成物)の発熱持続時間をより効果的に保持できることから、さらなる長持続化が可能であることが分かる。一方で、比較例1,2-1,2-2は、未使用状態が長期間続くと、製造直後との比較で発熱持続時間が減少しており、常温の状態で36ヶ月経過すれば、発熱持続時間が10%以上と大幅に減少している。よって、外袋4が少なくとも3つの収納部42を有し、各収納部42に複数の封入部32を有する内袋3を折り畳んだ状態で収納するようにした本実施形態の使い捨てカイロ1は、図12の結果より、未使用状態が長期間続いても、各収納部42に収納された内袋3(発熱組成物)の発熱持続時間の長持続化を可能にしている。 As shown in FIG. 12, first, in Examples 1, 2-1, and 2-2, even if the unused state continues for a long period of time, the duration time is significantly reduced compared with immediately after manufacturing (initial stage). The heat generation duration is well maintained. On the other hand, in Comparative Example 3, when the unused state continues for a long period of time, the heat generation duration is well maintained until 18 months, but it does not decrease significantly after 36 months. However, the duration of heat generation is slightly decreased as compared with Examples 1, 2-1, and 2-2. This comparative example 3 corresponds to a storage portion in which other storage portions are continuously provided on one side edge, such as the storage portions 42 at both ends of FIG. 3 in this embodiment, and the unused state is long. Even if it continues for a period of time, the heat generation duration of the inner bag (heat generating composition) housed inside can be maintained to a certain extent, but at least two side edges as in Examples 1, 2-1, and 2-2. The storage part in which the other storage parts are continuously provided can hold the heat generation duration of the inner bag (heat generating composition) stored therein more effectively, so that it can be further prolonged. I understand. On the other hand, in Comparative Examples 1, 2-1, 2-2, when the unused state continues for a long period of time, the duration of heat generation is reduced compared with immediately after production, and if 36 months have passed at room temperature, The duration of heat generation is greatly reduced to 10% or more. Therefore, the disposable body warmer 1 of this embodiment in which the outer bag 4 has at least three storage portions 42 and the inner bag 3 having a plurality of enclosing portions 32 is stored in the respective storage portions 42 in a folded state. From the result of FIG. 12, even if the unused state continues for a long time, it is possible to extend the heat generation duration of the inner bag 3 (heat generating composition) stored in each storage portion 42.
 なお、発熱組成物に含まれる水分の配合割合を高くすれば、使い捨てカイロの持続時間を長く持続させることが理論上可能となる。しかし、単に水分の配合割合だけを増加させただけでは、発熱組成物の粘度がかなり増加する。その結果、発熱組成物がべとべとするため、内袋3への封入が困難となり、カイロを製造できないうえ、発熱組成物の温度が上がらずカイロとして使用できないという問題が生じる。よって、単に発熱組成物に含まれる水分の配合割合を高くしただけでは、発熱組成物の発熱持続時間を長く持続させることが可能な使い捨てカイロを製造するのが極めて困難である。また、発熱組成物の総封入量を増加させることで、発熱組成物に含まれる水分量を増加させることも考えられるが、発熱組成物の総封入量を増加させると、内袋の封入部に封入される発熱組成物の量が過剰になる。その結果、内袋の2枚のシート材をシールする際に、シール部分に発熱組成物が噛み込むために、良好に両シート材をシールできず、内袋を形成できないという問題が生じる。よって、単に発熱組成物の総封入量を増加させただけでも、発熱組成物の発熱持続時間を長く持続させることが可能な使い捨てカイロを製造するのが極めて困難である。 In addition, if the blending ratio of moisture contained in the exothermic composition is increased, it is theoretically possible to maintain the duration of the disposable body warmer longer. However, the viscosity of the exothermic composition is considerably increased by simply increasing the water content. As a result, since the exothermic composition is sticky, it becomes difficult to enclose it in the inner bag 3, and it becomes impossible to produce a warmer, and the temperature of the exothermic composition does not rise and cannot be used as a warmer. Therefore, it is extremely difficult to produce a disposable body warmer that can sustain the heat generation duration of the heat generating composition for a long time simply by increasing the blending ratio of water contained in the heat generating composition. It is also conceivable to increase the amount of moisture contained in the exothermic composition by increasing the total amount of the exothermic composition, but if the total amount of exothermic composition is increased, The amount of exothermic composition enclosed becomes excessive. As a result, when the two sheet materials of the inner bag are sealed, the heat generating composition bites into the seal portion, so that there is a problem that both the sheet materials cannot be sealed well and the inner bag cannot be formed. Therefore, it is extremely difficult to produce a disposable body warmer that can maintain the heat generation duration of the heat generating composition for a long time simply by increasing the total amount of the heat generating composition.
 次に、上記構成の使い捨てカイロ1の使用方法について説明する。まず、外袋4のいずれかの収納部42を開封して内袋3を取り出す。その際、切り込みなどの易開封手段を外袋4のそれぞれの収納部42に対応させて設けるようにしてもよい。そして、粘着層を覆う剥離紙、あるいは、第1シート材31及び第2シート材32の少なくとも一方の表面を覆う非通気性のシート材を内袋3から剥がして、身体の所望の部位に発熱組成物2が当たるように配置する。これにより、発熱組成物2から発せられる熱により装着部位に温熱が与えられる。 Next, a method of using the disposable body warmer 1 having the above configuration will be described. First, any storage part 42 of the outer bag 4 is opened and the inner bag 3 is taken out. At that time, easy-opening means such as notches may be provided in correspondence with the respective storage portions 42 of the outer bag 4. Then, the release paper covering the adhesive layer or the non-breathable sheet material covering at least one surface of the first sheet material 31 and the second sheet material 32 is peeled off from the inner bag 3 to generate heat at a desired part of the body. It arrange | positions so that the composition 2 may hit. Thereby, warm heat is given to a wearing part by the heat emitted from exothermic composition 2.
 上記構成の使い捨てカイロ1では、外袋4が少なくとも3つの収納部42を有し、各収納部42に複数の封入部32を有する内袋3を折り畳んだ状態で収納している。これにより、上記したように、内袋3に封入された発熱組成物2の含有水分ができる限り収納部42から飛散しないように、内袋3及び外袋4の形状が工夫されて内袋3が外袋4に包装されているので、使い捨てカイロ1が店頭に置かれる状態が長くなるなど未使用状態が長期間続いても、発熱組成物2の水分の配合割合の低下により発熱持続時間が減少することを抑制でき、製造当初の発熱持続時間を長期間にわたって保持することができる。よって、長期間未使用状態が続いた後に使い捨てカイロ1を使用しても、製造当初に予定していた所望の発熱持続時間を実現できる。この製造当初に予定している発熱組成物2の持続時間は、外袋4の表面などに表示されて使用者に宣伝されるのが一般的であるため、実際に使い捨てカイロ1を使用した使用者を騙すことがなく、また、製造当初に予定していた発熱持続時間を実現できなくなるなどの理由で、未使用の使い捨てカイロ1を廃棄する必要もなくなる。また、従来行われているような、発熱持続期間を長く持続させるために発熱組成物の封入量を必要以上に増やす必要がないので、余分なコストをかける必要がなくなるうえ、軽量化により使い捨てカイロ1の携帯や使用がより好適となる。 In the disposable body warmer 1 configured as described above, the outer bag 4 has at least three storage portions 42, and the inner bag 3 having a plurality of enclosure portions 32 is stored in a folded state in each storage portion 42. Thereby, as described above, the shapes of the inner bag 3 and the outer bag 4 are devised so that the moisture contained in the exothermic composition 2 enclosed in the inner bag 3 is not scattered from the storage portion 42 as much as possible. Is packaged in the outer bag 4, so that even if the disposable body warmer 1 is placed in the store for a long period of time, such as when it is not used for a long period of time, the exothermic duration time is reduced due to a decrease in the moisture content of the exothermic composition 2. Decrease can be suppressed, and the heat generation duration at the beginning of production can be maintained over a long period of time. Therefore, even if the disposable body warmer 1 is used after it has been unused for a long time, it is possible to achieve the desired heat generation duration that was planned at the beginning of manufacture. Since the duration of the exothermic composition 2 scheduled at the beginning of production is generally displayed on the surface of the outer bag 4 and advertised to the user, it is actually used using the disposable body warmer 1 It is not necessary to dispose of the unused disposable body warmer 1 for the reason that the heat generation duration planned at the beginning of manufacture cannot be realized. Moreover, since it is not necessary to increase the amount of the exothermic composition more than necessary in order to keep the exothermic duration for a long time as is conventionally done, there is no need to add extra cost and the weight reduction makes it possible to use disposable warmers. 1 is more suitable for carrying and using.
 また、内袋3を折り畳んでコンパクトにして外袋4に収納すれば、内袋3を折り畳まないで外袋4に収納するよりも、外袋4(包装フィルム40,41)の使用量を抑えることができるので、材料面でコストを抑えることができる。 Moreover, if the inner bag 3 is folded and compacted and stored in the outer bag 4, the amount of the outer bag 4 (wrapping films 40 and 41) is reduced compared to storing the inner bag 3 in the outer bag 4 without folding. Therefore, cost can be reduced in terms of material.
 また、内袋3を折り畳む際に、非通気性のシート材が上下の最表面となるように折り畳むことで、封入部32に封入された発熱組成物2中の水分を飛散しにくくすることができるので、さらに良好に製造当初の持続時間を長期間にわたって保持することができる。 Further, when the inner bag 3 is folded, the moisture in the heat generating composition 2 enclosed in the enclosing part 32 can be hardly scattered by folding the inner bag 3 so that the non-breathable sheet material becomes the upper and lower surfaces. As a result, it is possible to better maintain the initial duration for a long period of time.
 以上、本発明の実施形態について説明したが、本発明は上記実施形態に限定されるものではなく、本発明の趣旨を逸脱しない限りにおいて種々の変更が可能である。例えば、上記実施形態では、内袋3の封入部32の形状が矩形状であるが、矩形状に限らず三角形状や五角形状などの多角形状、円形状、楕円形状など他の種々の形状を採用することができ、これに応じて内袋3の形状も種々の形状とすることができる。また、外袋4の収納部42の形状も、矩形状に限らず三角形状や五角形状などの多角形状、円形状、楕円形状など他の種々の形状を採用することができ、これに応じて外袋4の形状も種々の形状とすることができる。外袋4の収納部42の形状が矩形状以外の場合においても、少なくとも1つの収納部42に少なくとも3つの他の収納部42が連続して設けられるよう、外袋4が形成されていたり、あるいは、全ての収納部42に少なくとも2つの他の収納部42が連続して設けられるよう外袋4が形成されていることが好ましい。 As mentioned above, although embodiment of this invention was described, this invention is not limited to the said embodiment, A various change is possible unless it deviates from the meaning of this invention. For example, in the said embodiment, although the shape of the enclosure part 32 of the inner bag 3 is a rectangular shape, it is not restricted to a rectangular shape, but other various shapes, such as polygonal shapes, such as a triangular shape and a pentagon shape, circular shape, elliptical shape, are included. It can employ | adopt and according to this, the shape of the inner bag 3 can also be made into various shapes. Further, the shape of the storage portion 42 of the outer bag 4 is not limited to a rectangular shape, and other various shapes such as a polygonal shape such as a triangular shape and a pentagonal shape, a circular shape, and an elliptical shape can be adopted. The shape of the outer bag 4 can also be various shapes. Even when the shape of the storage portion 42 of the outer bag 4 is other than a rectangular shape, the outer bag 4 is formed so that at least three other storage portions 42 are continuously provided in at least one storage portion 42, Alternatively, it is preferable that the outer bag 4 is formed so that at least two other storage portions 42 are continuously provided in all the storage portions 42.
 1  使い捨てカイロ
 2  発熱組成物
 3  内袋
 4  外袋
 32 封入部
 40,41 包装フィルム
 42 収納部
 43 外周シール部
 44 第2シール部
DESCRIPTION OF SYMBOLS 1 Disposable body warmer 2 Exothermic composition 3 Inner bag 4 Outer bag 32 Enclosing part 40,41 Packaging film 42 Storage part 43 Peripheral seal part 44 2nd seal part

Claims (6)

  1.  水分を含有し空気と接触することで発熱する発熱組成物が通気性を有する内袋内に封入されており、前記内袋が気密性を有する外袋内に収納されている使い捨てカイロであって、
     前記外袋は、前記内袋を収納可能でありかつ互いに区画された収納部を少なくとも3つ備えており、
     前記内袋は、前記発熱組成物を封入可能でありかつ互いに区画された封入部を少なくとも2つ備えており、少なくとも1つの前記封入部が他の前記封入部と重ねられるよう少なくとも1回折り畳まれた状態で前記収納部に収納されている使い捨てカイロ。
    A disposable body warmer that contains moisture and generates heat when in contact with air is enclosed in an air-permeable inner bag, and the inner bag is housed in an air-tight outer bag. ,
    The outer bag includes at least three storage portions that can store the inner bag and are partitioned from each other.
    The inner bag includes at least two enclosing portions that can enclose the exothermic composition and are partitioned from each other, and is folded at least once so that at least one of the enclosing portions overlaps with the other enclosing portion. Disposable body warmer that is stored in the storage part in a state where
  2.  1つの前記封入部に他の全ての前記封入部が積み重ねられている請求項1に記載の使い捨てカイロ。 The disposable body warmer according to claim 1, wherein all the other enclosure parts are stacked on one enclosure part.
  3.  前記内袋は、少なくとも一方の表面に非通気性のシート材が積層されており、
     前記非通気性のシート材が上下の最表面となるように前記封入部が重ねられている請求項1又は2に記載の使い捨てカイロ。
    The inner bag has a non-breathable sheet material laminated on at least one surface,
    The disposable body warmer according to claim 1 or 2, wherein the enclosing portion is overlapped so that the non-breathable sheet material becomes upper and lower outermost surfaces.
  4.  少なくとも1つの前記収納部に少なくとも3つの他の前記収納部が連続して設けられるよう、前記外袋が形成されている請求項1~3のいずれかに記載の使い捨てカイロ。 The disposable body warmer according to any one of claims 1 to 3, wherein the outer bag is formed so that at least three other storage portions are continuously provided in at least one storage portion.
  5.  全ての前記収納部に少なくとも2つの他の前記収納部が連続して設けられるよう、前記外袋が形成されている請求項1~3のいずれかに記載の使い捨てカイロ。 The disposable body warmer according to any one of claims 1 to 3, wherein the outer bag is formed so that at least two other storage units are continuously provided in all the storage units.
  6.  前記封入部の数が2~4である請求項1~5のいずれかに記載の使い捨てカイロ。 The disposable body warmer according to any one of claims 1 to 5, wherein the number of the enclosed portions is 2 to 4.
PCT/JP2013/076627 2013-09-30 2013-09-30 Disposable body warmer WO2015045185A1 (en)

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