WO2014113909A1 - 钢板和混凝土复合结构的单元罐、单元组罐及海上平台 - Google Patents
钢板和混凝土复合结构的单元罐、单元组罐及海上平台 Download PDFInfo
- Publication number
- WO2014113909A1 WO2014113909A1 PCT/CN2013/070808 CN2013070808W WO2014113909A1 WO 2014113909 A1 WO2014113909 A1 WO 2014113909A1 CN 2013070808 W CN2013070808 W CN 2013070808W WO 2014113909 A1 WO2014113909 A1 WO 2014113909A1
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- WIPO (PCT)
- Prior art keywords
- tank
- unit
- tanks
- pile
- offshore
- Prior art date
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2221/00—Handled fluid, in particular type of fluid
- F17C2221/03—Mixtures
- F17C2221/032—Hydrocarbons
- F17C2221/033—Methane, e.g. natural gas, CNG, LNG, GNL, GNC, PLNG
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2221/00—Handled fluid, in particular type of fluid
- F17C2221/03—Mixtures
- F17C2221/032—Hydrocarbons
- F17C2221/035—Propane butane, e.g. LPG, GPL
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2223/00—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
- F17C2223/01—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the phase
- F17C2223/0146—Two-phase
- F17C2223/0153—Liquefied gas, e.g. LPG, GPL
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2223/00—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
- F17C2223/01—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the phase
- F17C2223/0146—Two-phase
- F17C2223/0153—Liquefied gas, e.g. LPG, GPL
- F17C2223/0161—Liquefied gas, e.g. LPG, GPL cryogenic, e.g. LNG, GNL, PLNG
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2223/00—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
- F17C2223/03—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the pressure level
- F17C2223/033—Small pressure, e.g. for liquefied gas
Definitions
- the invention relates to a steel tank and a concrete composite tank wall storage tank (unit tank, unit group tank) for storing industrial liquid products under water, such as crude oil, refined oil, LNG, LPG, etc., and the composite tank Wall-based tank-based marine storage, drilling and production facilities.
- industrial liquid products under water such as crude oil, refined oil, LNG, LPG, etc.
- composite tank Wall-based tank-based marine storage, drilling and production facilities such as crude oil, refined oil, LNG, LPG, etc.
- the present invention discloses a storage tank for a steel plate and a concrete composite structure, and Based on the improvement of the offshore facilities such as offshore platforms involved in the above two patent applications.
- the liquid storage tank and the seawater ballast tank of the process are sealed, and the upper part of the liquid of the two tanks is pre-charged with a certain pressure of nitrogen, and the nitrogen gas is connected to the same pressure system through the pipes and the top of the two tanks; the liquid of any one of the two tanks Discharge, another tank must have another liquid of equal quality to ensure that the operating weight of the system during the loading and unloading process remains unchanged.
- the function of the closed pressurized nitrogen gas is as the covering gas above the liquid, and the second is to realize the transfer of pressure energy between the two liquids. Nitrogen does not need to be replenished or discharged externally during system loading and unloading.
- the equal mass flow rate replacement of the process is usually achieved by the linkage of the associated loading pump and the external pump, wherein the ballast water or the storage liquid is first pressured to the inlet of the external pump by the pressure of the nitrogen in the tank.
- the patent application also discloses a combined liquid storage tank matched with the above process, and an offshore floating and fixed platform based on the liquid storage tank, which is used for drilling, production and storage of crude oil in offshore oil fields, but does not involve Production and storage of liquefied natural gas (abbreviation: LNG).
- LNG liquefied natural gas
- the fixed facilities involved in the application adopt the "small underwater weight sitting" technology, that is, the operating weight of the facility is equal to or slightly larger than the buoyancy (displacement) when designing the high water level.
- the seabed is fixed at the bottom of the facility, relying on long Piles or suction piles are resistant to slippage and overturning.
- the combined liquid storage tank of this application is an internal pressure vessel under most working conditions and is designed and constructed using existing concrete technology.
- PCT/CN2009 application number: PCT/CN2009
- LPG LPG
- the seawater in the ballast tank of the tank in the process and the LNG or LPG in the LNG or LPG tank are replaced by equal mass flow rate during the loading and unloading process to ensure the operating weight of the system.
- the equal mass flow rate replacement of the process is usually achieved by the associated load pump and external pump linkage.
- the saturated gas above the liquid in the LNG or LPG storage tank comes from or returns to different positions in the upper facility flow of the multifunctional base.
- the gas above the seawater inside the seawater ballast tank comes from or returns to the upper part of the upper facility flow of the multifunctional base. Different bit positions.
- the patent application also discloses a horizontal long cylindrical combined liquid storage tank matched with the above process, and an offshore floating and fixed facility based on the liquid storage tank for drilling, production and natural gas liquefaction in an offshore gas field. And storage, but does not involve the storage of crude oil.
- the application of the horizontal long cylindrical combined liquid storage tank is designed and built using existing concrete technology.
- the above first application also has the following deficiencies: 1.
- the outer wall of the storage tank of the vertical "up and down can” type and the horizontal "left and right can” type combination tank is sea. Once the wall is broken, the reservoir will cause pollution.
- the application of the fixed combination tank and its application - the fixed platform and the fixed artificial island adopt the small underwater weight and the pile foundation to resist the slip and anti-overturn, eliminating the gravity foundation; the long pile needs piling , did not propose a viable "self-installation” program. 3.
- the combined tank structure and scale of the floating platform and floating artificial island of the application have great influence on the hydrodynamic performance of the floating body.
- the above second application also has the above-mentioned deficiencies of items 1 and 2, and also has the following disadvantages: Because the horizontal long cylindrical combination tank is composed of multiple combinations of end to end The total elongation of the axial elongation of each combination tank due to the internal pressure is not negligible. The application does not target water. The characteristics of the flat-type combination tank propose a structural connection optimization scheme. Summary of the invention
- One of the objects of the present invention is to provide a unit can of steel plate and concrete composite structure which has good tensile and compressive effects, high structural strength, low difficulty in construction and construction, small construction period, short construction period, low cost and simple maintenance.
- Another object of the present invention is to provide a unit assembly tank for storing industrial liquids at sea, which is composed of the above plurality of unit tanks.
- the present invention provides a unit tank of a steel plate and a concrete composite structure, the unit tank comprising: a concrete outer tank, including an outer cylinder, a head and a connecting structure disposed at both ends of the outer cylinder; An inner can, comprising an inner cylinder, an epitaxial structure disposed at two ends of the inner cylinder, the inner cylinder being connected to the outer cylinder through the epitaxial structure; an isolation layer, the inner inner tank A gap is formed with the outer can of the concrete, and the isolating layer is filled with an isolating medium.
- the unit tank as described above wherein one end of the epitaxial structure of the steel inner can is fixedly connected to the connecting structure of one end of the outer can of the concrete to form a fixed connection structure; the other end of the epitaxial structure is slidably connected to a joint structure of the other end of the concrete outer tank forms a sliding joint structure, so that the steel inner tank can slide along the central axis in the concrete outer tank; the concrete outer tank, the steel The inner can and the isolation layer are connected by the fixed connection structure and the sliding connection structure to form a unitary structure.
- the unit can as described above, wherein the epitaxial structure is a cylindrical epitaxial structure or a leg epitaxial structure formed by extending outwardly from both ends of the inner cylinder.
- the storage tank and the seawater ballast tank of the combined liquid storage tank are arranged in a vertical vertical or horizontal horizontal or horizontal tank or in a tank; the steel inner tank is in contact with a corrosive liquid such as sea water or crude oil.
- the surface is coated with a protective coating.
- the liquid storage tank is used for storing various industrial liquids, such as crude oil, refined oil, LPG, LNG, etc.
- the bulkhead of the liquid storage tank is a steel single bulkhead or The composite bulkhead
- the composite bulkhead storing the low-temperature liquid such as LNG is a steel plate, a thermal insulation material layer and an outer steel plate which are resistant to ultra-low temperature and low linear expansion rate from the inside to the outside.
- the system pressure of the insulation medium of the insulation layer can be set according to the external pressure of the concrete outer tank and the internal pressure of the steel inner tank as needed The purpose is to reduce the pressure load acting on the concrete casing and the steel inner can; the system pressure of the insulation medium is controllable and safe to release.
- the present invention also provides a monomer group tank for storing industrial liquids at sea, the monomer group tank being composed of one unit tank or at least two unit tanks, wherein the at least two unit tanks are sequentially connected in parallel by a connection structure. Or the first and last series fixed connection, the top of the monomer group tank is submerged under water or protrudes from the water surface; the unit tanks in the monomer group tank are erected to form a vertical monomer group tank, or the monomer The unit tanks in the group tanks are arranged in a horizontal position to form a horizontal unit group tank.
- the function is to increase buoyancy for construction and towing, to adjust the position of the center of gravity and increase the weight, to add additional mass and damping to the floating monomer tank, to improve the hydrodynamic performance, and to improve the seabed erosion for the stationary monomer tank.
- the monomer group tank is a floating monomer group tank, and the floating monomer group tank is anchored to a seabed by mooring legs; or the monomer group tank
- the fixed monocoque tank is fixed on the seabed by a suction pile foundation or a long pile foundation or a gravity foundation or a combination of a pile and a gravity foundation.
- the closed steel pipe pile is inserted into the pile sleeve of the monomer group tank before being towed by the monomer group tank and temporarily fixed, and is installed at the time of offshore installation by means of the monomer group tank Gravity pushes the pile into the seabed; the installation steps are as follows: 1) The monomer group can float, tow, position and position, open the venting raft, relieve the temporary fixation of the pile, and lower the long pile into the mud by self-weight; 2) Closed The steel pipe pile and the monomer group tank are temporarily fixed again, and the water is pressurized to the monomer group tank to make the pile under the pile.
- ballast water volume of the unit tanks of different orientations is adjusted according to the level of the monomer group tank; 3) After the bottom of the tank sinks to the seabed, the temporary fixing of the pile is lifted again, and the drainage causes the single-group tank to float. 4) Repeat the above-mentioned steps of pile-up-re-pushing, and let the pile reach the designed depth of the mud. The seabed is seated, and the pile and the tank are officially fixed; 5) The water injection and discharge are opened. After closing the exhaust full of water and water Min Min, discharging the excess monomer ballast water tank, complete offshore installation.
- the closed steel pipe pile can be pulled up by the floating of the single-group tank; the steps of pulling the pile are as follows: 1) Excluding the liquid in the monomer group and the fixed ballast, so that The monomer group tank is in light load state, open the venting valve, realize the floating of the monomer group tank and the initial pile pulling; 2) The monomer group tank floats to the water surface, and closes the water injection after filling the closed steel pipe pile with water Exhaust ⁇ , release of the pile, the water column in the closed steel pipe pile can ensure that the long pile will not sink due to its own weight; 3) Pressurize the water in the monomer tank to make the monomer tank sink again Temporarily fix the pile and the tank; 4) Repeat the above-mentioned row of floating piles - water injection in the pile to prevent sinking, release the fixed-ballasted bottom of the pile and temporarily fix the closed steel pipe pile - re-discharge the pile Until the pile is completely pulled out; when the pile is pulled out, the gas can be injected
- the steel pipe is controlled by the gravity of the monomer tank and the ballast, and the steel pipe is controlled to open and close the gas enthalpy, the gas inlet enthalpy and the water inlet raft.
- the pile is pressed into the seabed and the pile is taken.
- the invention also provides an offshore platform for offshore oil and gas field development, drilling, oil and gas production, natural gas liquefaction, natural gas chemical and liquid storage, the offshore platform comprising: 1) one or more of the above a monomer tank for storing the produced liquid of the platform, the tank is provided with or without a vertically permeable moon pool, the top of the tank is submerged under water or protrudes from the water surface; 2) upper facility , including drilling, oil and gas production and storage, utilities and facilities required for life, above the surface above the monomer tank, connected to the monomer tank through the leg structure; 3) floating the offshore platform A positioning system positioned at sea, including a mooring leg system, a dynamic positioning system, or a combination of both; or an infrastructure that secures an offshore platform to the seabed, including a long pile foundation or a suction pile foundation, a gravity foundation, or a pile foundation A combination with a gravity basis.
- the parallel monomer group can includes a main body and a skirt bottom chamber connected to a lower portion of the main body, the main body being closely arranged by the at least two unit tanks in a single layer or a plurality of concentric circles, and a concentric center through hole
- the central unit tank may or may not be disposed, and the upper and lower ends of the vertical parallel monomer group tank are connected by a connection structure of the concrete shell and extend outward to form a flat cylinder having a diameter equal to the outer unit tank Projecting the diameter of the circumscribed circle, the center of the upper and lower flat cylindrical connecting structure of the vertical unit group tank not having the central unit tank is provided with a circular hole, and the circular hole is connected to
- the offshore floating platform as described above wherein the bottom and top planes of the flat cylindrical connecting structure are respectively swelled downward and upward to form a conical surface, and intersect with the outer unit tank of the vertical parallel monomer group tank An intersecting line is formed, the purpose of which is to reduce the vertical wave force generated by the downward and upward diffraction of the wave water quality point; the cone angle of the tapered surface is not more than 45 degrees.
- the skirt bottom compartment is fixedly coupled to the flat cylindrical connecting structure of the main body by a plurality of evenly connected connecting members, the skirt bottom compartment being flush with the bottom of the flat cylindrical connecting structure and having a radial clearance of not less than 0 ⁇
- the length of the base of the rectangular skirt is not less than 0.3 times the radius of the flat cylindrical connecting structure, the length of the rectangle perpendicular to the side of the bottom edge.
- the top of the annular skirt bottom compartment is at a depth that is less affected by the waves, and the inside of the annular skirt bottom compartment is provided with a liquid storage tank and a seawater ballast tank.
- a liquid storage tank and a seawater ballast tank.
- the skirt bottom compartment; or the annular skirt bottom compartment is completely broken into a fracture at the notch, forming a plurality of intermittent and uniform annular skirt bottom compartments, the fracture being sized to ensure that the offshore platform is in motion During the process, the mooring legs do not touch or collide with the bottom skirt.
- the offshore floating platform comprises at least two horizontal series unit tanks of the unit tanks, wherein the unit tanks are laid flat, and the unit tanks are connected end to end and kept at a certain distance.
- the horizontal series monomer group can be connected as a whole through a horizontal connecting plate at both ends thereof and a plurality of horizontal connecting rods at an intermediate portion; the unit tanks in the horizontal series single unit tank are submerged under water, horizontally parallel and Maintaining a certain distance, at least two unit tanks of the horizontal unit group tank are connected in series to form a horizontal long cylinder, and the steel inner tank of the unit tank has a cylindrical epitaxial structure at both ends;
- the epitaxial structure of the cylinder body is a fixed connection structure
- the two cylindrical epitaxial structures can be welded into one body, and then fixed with the connection structure of the concrete outer tank; when the epitaxial structure of two adjacent steel cylinder bodies
- the two extension structures When all are slip-type connection structures, or one is a slip-type connection structure, and the other is a fixed connection structure, the two
- the present invention has the following features and advantages:
- the unit tank of the steel plate and concrete composite structure of the invention fully utilizes the respective advantages of the concrete and the steel plate material, and circumvents their respective shortcomings; relies on the separation layer between the concrete outer can and the steel inner can, and utilizes the static pressure of the seawater outside the storage tank and The internal reservoir pressure improves the stress on the tank structure. Due to the existence of the isolation layer, the underwater storage tank of the present invention becomes a double-layer tank, and the damage of any layer does not cause the risk of leakage of the liquid storage, which is safe and environmentally friendly.
- the invention tank can store various industrial liquid products including LNG.
- the storage tank of the invention has the advantages of low difficulty and small complexity in construction and construction, short construction period, low cost and simple maintenance.
- the marine floating and fixed platform based on the unit tank of the steel plate and concrete composite structure of the invention is in the present application
- the overall and structural design of the platform with underwater storage tanks, especially the floating platform is optimized and floated.
- the platform fully meets the requirements for drilling and installing dry wellheads, extending the scope of application, enabling the platform to be used both for the development and production of offshore oil and gas fields, as well as for the production and storage of offshore LPG and LNG; for stationary with submarine storage tanks.
- FIG. 1 is a schematic structural view of a unit tank of a steel plate and concrete composite structure according to the present invention
- Figure 2 is a cross-sectional view taken along line A-A of Figure 1;
- Figure 3 is a partial enlarged view of a portion B of Figure 1;
- Figure 4 is a partial enlarged view of a portion C of Figure 1;
- Figure 5 is a schematic view showing the extension structure of the steel inner can body leg of the present invention.
- Figure 6 is a structural view of a closed steel pipe pile of the present invention.
- Figure 7 is an elevational view of a vertical honeycomb unit of a square honeycomb arrangement of the present invention.
- Figure 8 is a cross-sectional view taken along line G-G of Figure 7;
- Figure 9 is a schematic structural view of the offshore floating platform of the present invention.
- Figure 10 is a cross-sectional view taken along line D-D of Figure 9;
- Figure 11 is a schematic view showing the first embodiment of the horizontal unit group tank adjacent unit tank structure connection;
- Figure 12 is a partial enlarged view of the portion D of Figure 11;
- Figure 13 is a schematic view showing the second embodiment of the horizontal unit stacking unit adjacent unit tank structure connection;
- Figure 14 is a partial enlarged view of the E portion of Figure 13;
- Figure 15 is a schematic view showing the third embodiment of the structural connection of the adjacent unit cans of the horizontal unit group tank of the present invention.
- Figure 16 is a partially enlarged view of the portion F of Figure 15;
- FIG. 1 to FIG. 4 are respectively a structural schematic view of a unit tank of a steel plate and a concrete composite structure according to the present invention; a cross-sectional view taken along line AA of FIG. 1; a partial enlarged view of a portion B of FIG. 1; and a portion C of FIG. Partially enlarged view.
- the unit tank 1 of the steel sheet and concrete composite structure of the present invention comprises:
- Concrete rigid outer can (hereinafter referred to as “concrete outer can 2")
- the concrete outer can 2 includes a concrete outer can body (hereinafter referred to as "outer cylinder 3"), a concrete structure or a steel structure disposed at both ends of the outer cylinder or The head and the joint structure of the hybrid structure; the head includes an arched head and a flat head (as shown in Figures 3 and 4).
- the concrete structure of the present invention includes all structures in which concrete is the main building material, such as reinforced concrete structure, prestressed concrete structure, steel reinforced concrete structure, steel reinforced concrete structure (BI-STEEL), fiber reinforced concrete structure and the like.
- Steel inner tank 5 located inside the concrete outer tank 2, including a cylindrical steel container (hereinafter referred to as "inner cylinder"
- the epitaxial structure is the inner cylinder 6 a cylindrical epitaxial structure 7 extending directly to both ends (as shown in FIGS. 3 and 4).
- the epitaxial structure is an inner cylinder
- Extension structure 8 of the leg extending to both ends (as shown in Figure 5).
- the gap between the steel inner can 5 and the concrete outer can 2 (including the gap between the inner cylinder and the outer cylinder and the gap between the head of the steel inner can 5 and the head of the concrete outer can 2)
- the isolation layer 9 is formed, and the isolation layer 9 is filled with an isolation medium as shown in FIGS. 3 and 4.
- the isolation medium is an inert gas or a liquid or an inert gas plus a flexible solid material Material or liquid plus flexible solid material, its main function is to avoid or reduce the possibility of direct transfer of strain and stress between the steel inner tank 5 and the concrete outer tank 2 due to internal and external pressure.
- the unit tank of the steel plate and the concrete composite structure used in the invention is used for storing industrial liquid products in water, such as crude oil, refined oil, LNG, LPG, etc.; the unit tank of the invention fully utilizes the concrete material to have high compressive strength and steel resistance
- the strong physical properties of the steel tank inner wall of the steel tank of the unit tank and the concrete tank wall of the concrete outer tank are respectively subjected to tensile stress and compressive stress, thereby greatly improving the structural strength of the unit tank and having construction
- the construction is characterized by low difficulty and complexity, short construction period, low cost and simple maintenance.
- one end of the epitaxial structure 7 of the steel inner can 5 is fixedly connected to the connection structure 4 at the end of the concrete outer can 2 Forming a fixed connection structure 20 (as shown in FIG. 3); the other end of the extension structure 7 is slidably connected to the connection structure 4 at the other end of the concrete outer can 2 to form a sliding connection structure 21 (as shown in FIG. 4).
- the steel inner can 5 can be slid along the central axis in the concrete outer can 2, and a sliding structure is required to be provided in the connecting structure 4 of the concrete outer can to reserve the expansion gap 22, the main purpose of which is to avoid the constrained steel.
- the axial elongation of the inner can due to internal pressure.
- the 20 and slip joint structure 21 allows the concrete outer can 2, the steel inner can 5 and the barrier layer 9 to form a rigid unitary structure.
- the steel inner can 5 comprises at least one set of structurally symmetric storage tanks 10 and a combined liquid storage tank of seawater ballast tanks 11 (hereinafter referred to as "" Combination tank").
- the combined tank can realize the adjustment of the operating weight and even the operation weight by means of the loading of ballast seawater.
- Each group of storage tanks 10 and seawater ballast tanks 11 are arranged in three configurations: vertical up and down, horizontal left and right, and tank cans.
- the inside of the inner cylinder 6 of the steel inner tank 5 is divided into two by a head, forming two tanks, one for the liquid storage tank and the other for the seawater ballast tank; or As shown, the inside of the inner cylinder 6 is divided into three by the two heads to form three compartments, one large compartment is a storage tank, usually in the middle, and the other two are seawater ballast tanks, usually in the upper and lower At the end, the two seawater ballast tanks are connected by pipes (not shown in Figure 1) to form a substantial seawater ballast tank.
- the horizontal left and right type that is, the inner cylinder 6 of the horizontal horizontal steel inner can 5 is divided into three by the left and right sides of the two heads to form three compartments, one central large compartment is a liquid storage compartment, and the left and right ends are two
- the small tanks are seawater ballast tanks that are connected together by pipes to form a substantial seawater ballast tank.
- the canister type that is, the reservoir 10 is located inside the seawater ballast tank 11, both having the same central axis.
- the steel inner can 5 does not have a seawater ballast tank, and the steel inner can 5 is a liquid storage tank.
- the surface of the steel inner can 5 in the unit tank 1 and the corrosive liquid such as seawater are coated with a protective coating.
- the steel inner tank 5 of the present invention wherein the liquid storage tank 10 is used for storing various industrial liquids such as crude oil, refined oil, LPG, LNG and the like.
- the bulkhead of the storage tank 10 is a steel single bulkhead or composite bulkhead to accommodate the characteristics of different industrial liquid storage.
- the tank wall of a storage tank storing cryogenic liquids such as LNG is usually from the outside to the inside: a, 16MnR steel tank wall, b, low temperature insulation material, such as nitrogen positive pressure pearlescent sand, c, ultra-low temperature resistant steel , such as low temperature resistant austenitic stainless steel 0Cr l8Ni9 inner tank wall.
- the support between the inner and outer cylinders is a combination of epoxy glass reinforced plastic and 0Cr l8Ni9 steel sheet with low temperature resistance and good heat insulation performance. Insulation can be added to the bulkheads of storage tanks with higher temperature stocks, such as hot crude oil.
- the primary function of the barrier layer 9 is to prevent direct contact between the surface strain and stress caused by internal stresses in the steel inner can 5 to the rigid monolithic outer can 2 .
- the system pressure of the barrier layer 9 is resizable and safe to release.
- the system pressure can be set according to the external seawater static pressure of the concrete outer tank 2 and the internal pressure of the steel inner tank 5, in order to reduce the pressure load acting on the concrete outer tank 2 and the steel inner tank 5. .
- the concrete outer tank of the unit tank is subjected to internal and external The pressure balance, which is of great significance for the structural design of the tank in deep water.
- the steel inner tank inside the unit tank is 40 meters high, and the crude oil needs to be sent to the water surface 20 meters above the surface by the pressure of compressed nitrogen inside the steel inner tank.
- the minimum pressure of compressed nitrogen is 1020 meters high. According to this, the nitrogen pressure can be set to 102 atmospheres.
- the isolation layer of the unit tank is connected with the external seawater.
- the maximum external hydrostatic pressure is at the bottom of the tank.
- the minimum external hydrostatic pressure is at the top of the tank.
- the pressure inside and outside the tank is equal and does not need to be designed according to the pressure vessel.
- the liquid storage and seawater of the deep water storage tank and the seawater ballast tank can be effluxed by the pressure of the gas without using a pump, and the deep water underwater pump can be avoided, and the investment and operation and maintenance costs are reduced, which is the advantage of the unit tank of the present invention.
- FIG. 8 are elevational views of a square honeycomb-arranged vertical monolithic can of the present invention and FIG. 7 GG section view.
- the invention also proposes a monomer group tank 12 for storing industrial liquids at sea, which is formed by at least two unit tanks 1 in sequence through a parallel connection of the connection structure 4 or a series connection of the first and last ends, forming a whole.
- the unit stack can 12 can also be constructed separately from a unit tube 1.
- the unit tanks 1 in the monomer group tank 12 are erected to form a vertical unit group tank, or the unit tanks 1 in the unit group tank 12 are laid flat to form a horizontal unit group tank.
- the top of the monomer stack can 12 is submerged or protrudes from the water.
- the monomer group tank 12 is divided into a floating monomer group tank and a fixed unit group tank according to the positioning state in seawater, and the floating unit group tank is anchored to the seabed by mooring legs, and the fixed type monomer group tank is fixed. It is fixed on the seabed by suction pile or long pile or gravity foundation, or fixed on the seabed by the combination of pile and gravity foundation.
- the vertical parallel monomer group tank includes a main body 24 and a skirt bottom chamber 25 connected to a lower portion of the main body 24.
- the main body 24 is closely connected into a rectangular honeycomb by 9 (representing two or more) unit tanks 1 Shapes, or other shapes, such as hexagons, multi-layer concentric circles, etc., are connected as a unitary structure by the heads of the outer cans of the concrete tanks at the upper and lower ends of the unit tank 1 and the joint structure 4.
- an auxiliary connection is also made between the outer cylinders 3 of the concrete tank of the unit tank.
- the heads and connecting structures of the concrete outer cans at the upper and lower ends of the nine unit tanks are connected to form a rectangular flat cylindrical connecting structure.
- the roots of the body 24 are flanked by a split skirt bilge 25.
- the single-unit tank 12 of the offshore platform shown in FIG. 9 is also a parallel vertical single-unit tank, and also includes a main body 24 composed of 6 unit tanks and a wraparound skirt bottom tank. 18; the two can be directly connected into one body, or there may be a radial gap as shown in FIG. 9 and FIG. 10, and the wraparound skirt bottom chamber is formed as a separate "ring" which is connected by the connecting member 19 and is dedicated to floating. Facilities. As shown in Fig.
- the annular skirt bottom compartment 18 is a circular skirt bottom compartment, and may also be a positive polygonal annular skirt bottom compartment.
- the omni-lateral circular skirt bilge is connected by a plurality of elongated skirts of equal length in a regular polygon, and the long strip is less difficult to construct than the arc.
- the cross section of the skirt bottom compartment is usually rectangular or polygonal, the bottom is flush with the bottom of the main body, the height is much smaller than the height of the main body, and the top is submerged in water in the in-state state (IN-PLACE). under.
- the inner space of the skirt bottom compartment may be provided with one or more of a storage tank, a seawater ballast tank, and a fixed ballast tank as needed.
- the function of the skirt bottom compartment is to increase buoyancy for construction and towing, to adjust the position of the center of gravity and to increase the weight, to add additional mass and damping to the floating monocoque tank, to improve hydrodynamic performance, to improve the seabed for stationary monomer tanks. Scour the situation.
- the main body 24 of the above vertical parallel monomer group can be placed horizontally to form a horizontal parallel monomer group can.
- the cylinders 3 of the concrete outer tanks of the plurality of unit tanks 1 of the horizontal unit tank are joined end to end to form a single horizontally long cylindrical horizontal unit group tank.
- Both ends of the steel inner can 5 inside each unit can 1 have a cylindrical epitaxial structure.
- the horizontal series cell stacks described above are placed vertically to form a vertical series cell stack.
- FIG. 6 it is a structural view of the closed steel pipe pile of the present invention.
- the long pile foundation of the fixed type monomer tank is a closed steel pipe pile 26, and the closed steel pipe pile 26 includes a round steel pipe 31 and a welded sealing head 30 at the top thereof, and a venting dam 28 is installed on the sealing head 30, and the intake air is provided. ⁇ 29 and water ⁇ 27.
- the steel pipe pile 26 is inserted into the pile sleeve of the single-group tank before being towed by the single-group tank and temporarily fixed. When the pile is pressed at the sea, the pile is pressed into the seabed by the gravity of the single-group tank and water ballast.
- the installation steps are as follows: 1) The monomer group can be floated and towed, and then placed and positioned after the oilfield site, the venting shovel 28 is opened, the temporary fixing of the pile 26 is released, and the closed steel pipe pile is placed under the self-weight; 2) The closed steel pipe pile 26 and the monomer group tank 12 are temporarily fixed again, and the water is pressurized to the monomer group tank to make the pile under the pile. According to the calculation result of the pile driving force for each pile, the two are symmetrically The root piles are grouped, and the number of piles is determined.
- the ballast water volume of the unit tanks in different orientations is adjusted in time; 3) the bottom of the tank sinks to the seabed Afterwards, the temporary fixing of the pile is lifted again, and the drainage unit is used to float the monomer group; 4) repeating the steps of pressing the pile-up-re-pushing pile, and when the pile reaches the depth of the design, let the tank bottom sit on the bottom and then pile It is officially fixed with the tank; 5) Open the water inlet 27 venting water, close the exhaust ⁇ 28 and the water inlet ⁇ 27 after the water is full, the purpose of this method is to be able to carry the lower end of the soil plug after the pile is completed, and discharge the single Excess ballast water in the body tank 12, complete the offshore pile
- the present invention adopts the pile-based fixed type monomer can of the above-mentioned closed steel pipe pile 26, wherein the closed steel pipe pile 26 can rely on the monomer group 12 to drain and float to realize the pile pulling, and then the monomer group can is wet and towed away.
- the steps of pulling the pile are as follows: 1) Excluding the liquid in the monomer group tank 12 and the fixed ballast, opening the venting damper 28, realizing the floating of the monomer group tank and initial pulling; 2) the monomer group tank 12 floats to the water surface, After filling the closed steel pipe pile 26 with water, the water injection port 27 and the deflation port 28 are closed, and the pile is fixed.
- the water column in the closed steel pipe pile 26 can ensure that the long pile does not sink due to its own weight; 3)
- the monomer group tank 12 is pressurized with water to make it sink down again, and the closed steel pipe pile 26 and the tank body 12 are temporarily fixed; 4) repeating the above-mentioned row loading and unloading pile-pile water injection to prevent sinking and lifting
- the pile is fixed-ballasted and the long pile is temporarily fixed.
- the pile is pulled up again until the pile is completely pulled out.
- the pile is pulled to the shallow surface of the seabed, it can also pass through the intake ⁇ 29 Injecting gas, pull out the pile and lift it to the desired position by the buoyancy increased by air pressure and drainage; 5) Fix the pile and the tank to complete the pile pulling operation.
- the steel is controlled by the gravity of the monomer tank and water ballast, and the opening and closing of the bleed air enthalpy, the intake enthalpy and the water inlet raft are controlled.
- the pipe pile is pressed into the seabed and the pile is taken.
- the invention also proposes an offshore platform for offshore oil and gas field development, drilling, oil and gas production, natural gas liquefaction, liquid storage, both floating and stationary.
- the two forms of offshore platforms are composed of three parts: 1) an underwater storage tank, which is one or more monomer tanks 12 as described above floating on the sea or fixed on the seabed.
- the top of monomer group 12 is submerged under water or extended to the surface;
- the offshore platform of the drilling or platform wellhead facility, the monohull tank 12 of the offshore platform is provided with a vertically permeable moon pool 14 ; 2) the upper facility 15 is located above the water surface above the monomer group tank 12, through the leg structure 16 is connected to the monomer group tank 12, and the upper facility 15 includes drilling equipment, oil and gas production and storage equipment, public systems and living facilities, etc.; 3) a positioning system for floating the offshore platform at sea, including a mooring leg system, Dynamic positioning system or a combination of both (not shown in Figure 9); or an infrastructure that secures an offshore platform to the seabed, including pile foundations, ie long pile foundations or suction pile foundations, gravity foundations or pile foundations Gravity-based compositions.
- the offshore platform can have various structural forms.
- the offshore platform is an offshore floating artificial island, which is characterized by the height of the tank top of the floating monocoque stack 12. The water surface has a certain height. If the tank top of the floating monocoque tank 12 is submerged to a certain depth under water, the leg structure 16 has sufficient waterline surface area to ensure the stability of the floating platform, thereby forming a float with an underwater storage tank. Platform.
- the offshore platform becomes a fixed artificial island; when the top of the monomer group tank 12 is submerged under water At a certain depth, the offshore platform becomes a fixed platform with submarine storage tanks.
- the liquid storage and ballast seawater of the offshore platform can be directly transported by an external pump, such as a pump chamber pump or a deep well pump or an external underwater pump; or relying on the pressure energy of a compressed gas containing no oxygen, such as nitrogen or natural gas.
- the inlet of the external pump that is discharged to the surface above the water surface is then externally transferred by the external pump.
- the advantage of the former is that the internal pressure of the liquid storage tank and the seawater ballast tank is small, the amount of steel used in the bulkhead is small, and the cost is low.
- the disadvantage is that the system in the cabin is complicated, the maintenance workload is large, and the cost and operation cost of the pump are high. The latter is the opposite.
- the pressure in the cabin is high and the bulkhead steel plate is thick.
- the external pump of the relay can adopt the conventional centrifugal pump, and the system is simple and the maintenance workload is small.
- the invention proposes a scheme of using a gas pressure energy plus an external pump. During the process of liquid storage, it can be replaced with ballast water by equal mass flow rate or non-equal mass flow rate, or not with ballast seawater. Wait The mass flow rate replacement is preferably carried out by using the "mass flow rate replacement process such as closed gas pressure connected ballast seawater and liquid storage" and "the mass flow rate replacement process of ballast seawater and liquefied natural gas or liquefied petroleum gas" as mentioned in the background section. .
- the equal mass flow rate replacement process can ensure that the operating weight of the platform during the loading and unloading process is constant, and the draft depth of the floating platform is constant, which is very important for the floating platform with the dry wellhead installed.
- the non-equal mass flow rate replacement with ballast seawater can be used in the process of liquid storage outside, or not replaced with ballast water, relying on floating platform loading-drink
- the automatic adjustment mechanism achieves a balance of loading and buoyancy, which has the advantage of greatly increasing the volume of the reservoir 10 of the steel inner can 5 to increase the liquid storage capacity of the platform.
- the underwater storage tank of the floating platform on the sea is a vertical parallel single-unit tank 12, which is arranged in a single or multi-layer concentric circle, and the center of the concentric circle may or may not be centered.
- the unit tank (shown in Figure 10 is a unit group of 6 unit tanks arranged in a circular arrangement, without a central unit tank), and the connection structure of the concrete shells at the upper and lower ends is connected and expanded into a flat cylinder 13,
- the diameter of the upper and lower unit cans is equal to the diameter of the circumscribed circle, and the center of the upper and lower flat cylindrical connection structure of the vertical unit can without the central unit can is a circular hole, and the diameter of the circular hole is equal to the vacant
- the outer diameter of the central unit can body forms a vertical monocoque tank with a top and bottom permeate pool 14; the bottom of the vertical unit stack 13 is affected by waves with a small depth.
- the vertical parallel monomer tank 12 of the offshore floating platform wherein the bottom and top planes of the upper and lower flat cylindrical connecting structures 13 are respectively swelled downward and upward to form a conical surface 17, and a vertical monocoque can
- the outer unit cans intersect to form an intersecting line, the purpose of which is to reduce the wave force generated by the downward and upward diffraction of the wave water point; the cone angle of the cone is no more than 45 degrees (see Figure 9).
- the wraparound skirt bottom hull 18 at the lower end of the main body 24 of the vertical parallel monomer can of the floating offshore platform is a circular or regular polygonal annular skirt bilge, the bottom of the annular skirt bilge 18 Forming a flush with the bottom of the lower end flat cylindrical connecting structure 13 of the vertical monomer can, the circular or regular polygonal annular skirt bottom chamber has a rectangular cross section, and the section width is not less than the flat cylindrical connection The ratio of the height of the section to the width is not less than 0.30, and the skirt bottom compartment is fixedly coupled to the flat cylindrical connecting structure 13 by a plurality of evenly connected connecting members 19. Please note that the connecting member 19 shown in Fig.
- the radial minimum clearance of the annular skirt bilge and the flat cylinder is not less than 0.3 m, and the top of the skirt bilge is at a depth that is less affected by the waves, which is usually not less than 30 m in the South China Sea.
- the space in the bottom compartment of the skirt can be provided with a storage tank, a seawater ballast tank, and a fixed ballast tank (not shown in Figure 9 for simplicity).
- the cable guide for the mooring leg is located on the floating platform above the annular skirt bilge 18, and a notch is formed in a portion where the inner diameter mooring leg of the circular skirt hull 18 passes, that is, the mooring leg passage 22 Ensure that the mooring leg does not hit the skirt bottom during the movement; or the circular skirt hopper 18 is completely broken at the notch to form a plurality of uniform skirts.
- the skirt bottom compartment has three important functions: First, the position of the center of gravity of the platform is adjusted by adding a fixed ballast. The second is to increase the additional mass and damping of the floating offshore platform and improve hydrodynamic performance. The third is to provide sufficient buoyancy and waterline area during construction and towing to ensure that the platform can be built with a smaller draft (eg
- the skirt bottom compartment 18 and the skirt bottom compartment connecting member 19 are constructed of steel or reinforced concrete structures or hybrid structures.
- the floating platform of the present invention has the characteristics of "INTRINSIC STABILITY", which is that the motion response of the floating body is very small under severe sea conditions; Due to the increase in its natural period, for example, the heave period has increased from more than 20 seconds to more than 30 seconds, the radius of gyration of the roll and pitch is increased, the motion damping is increased, and the wave load is not increased by much, so that the invention floats The hydrodynamic performance of the platform is superior to the current SPAR platform.
- the underwater storage tank of the floating offshore platform is two horizontal series single-unit tanks which are submerged, parallel, and kept at a certain distance, and pass through horizontal connecting plates and intermediate portions at both ends of the monomer group tank.
- the plurality of horizontal connecting rods are connected in one piece.
- the barrels of the concrete outer cans of the plurality of unit tanks in which the two rows of legs are connected to the horizontal unit stack are joined to form a single horizontal long cylinder to form a long cylindrical horizontal unit stack.
- the steel inner can inside the long cylindrical horizontal unit tank has a cylindrical epitaxial structure at both ends.
- one of the two epitaxial structures may be Insert into another cylinder, and at the same time realize the sliding or fixed connection with the concrete shell connection structure, so that each sliding epitaxial structure can be simultaneously in the joint structure of the concrete shell and the cylinder body of another extension structure (or outside the cylinder) ) slip (see Figures 13, 14 and Figures 15, 16).
- the foundation long pile of the above fixed offshore platform is a closed steel pipe pile, and the structure, the method and the step of the construction work of the closed steel pipe pile, the pile installation and the floating pile are fixed with the pile foundation.
- the monomer group tanks are the same and will not be repeated here. It should be noted that the level of the platform needs to be controlled during the process of pile driving and pile pulling. All unnecessary liquid and bulk materials in the upper part of the platform need to be removed when pulling the pile. The liquid in the monomer group can 12 and the fixed ballast are excluded, so that the platform is in a light load state.
- the unit tank of the steel plate and concrete composite structure of the invention is used for storing industrial liquid products in water, such as crude oil, refined oil, LNG, LPG, etc.; the purpose is to make full use of the different characteristics of the concrete material and the steel, so that the unit
- the steel tank wall of the steel inner tank of the tank and the concrete tank wall of the concrete outer tank are respectively subjected to tensile stress and compressive stress.
- a plurality of the above unit tanks are connected together to form a monomer group tank.
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Abstract
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Priority Applications (21)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201380069107.5A CN104968583B (zh) | 2013-01-22 | 2013-01-22 | 钢板和混凝土复合结构的单元罐、单元组罐及海上平台 |
CA2897267A CA2897267C (en) | 2013-01-22 | 2013-01-22 | Steel plate and concrete composite tank unit, tank group and offshore platforms |
PCT/CN2013/070808 WO2014113909A1 (zh) | 2013-01-22 | 2013-01-22 | 钢板和混凝土复合结构的单元罐、单元组罐及海上平台 |
AU2013375773A AU2013375773B2 (en) | 2013-01-22 | 2013-01-22 | Unitary barrel of steel plate and concrete composite structure, unitary group barrel, and offshore platform |
GB1512439.9A GB2524690A (en) | 2013-01-22 | 2013-01-22 | Unitary barrel of steel plate and concrete composite structure, unitary group barrel, and offshore platform |
MYPI2015001687A MY170043A (en) | 2013-01-22 | 2013-01-22 | Steel plate and concrete composite tank unit, tank group and offshore platforms |
BR112015016893A BR112015016893A2 (pt) | 2013-01-22 | 2013-01-22 | unidade de tanque composta por placa de aço e concreto, grupo de tanques e plataformas marítimas |
PCT/CN2014/071120 WO2014114235A1 (zh) | 2013-01-22 | 2014-01-22 | 吸力式桩腿、海上沉箱及坐底式海上平台 |
GB1512429.0A GB2523717A (en) | 2013-01-22 | 2014-01-22 | Ring wing floating platform |
BR112015016892A BR112015016892A2 (pt) | 2013-01-22 | 2014-01-22 | plataforma flutuante de anel-asa |
AU2014210247A AU2014210247B2 (en) | 2013-01-22 | 2014-01-22 | Ring wing floating platform |
PCT/CN2014/071121 WO2014114236A1 (zh) | 2013-01-22 | 2014-01-22 | 一种环翼式浮式平台 |
MYPI2015001685A MY174732A (en) | 2013-01-22 | 2014-01-22 | A ring-wing floating platform |
CN201480001335.3A CN104321247B (zh) | 2013-01-22 | 2014-01-22 | 一种环翼式浮式平台 |
CA2897223A CA2897223A1 (en) | 2013-01-22 | 2014-01-22 | A ring-wing floating platform |
CN201480001337.2A CN104395530B (zh) | 2013-01-22 | 2014-01-22 | 吸力式桩腿、海上沉箱及坐底式海上平台 |
US14/805,384 US9850636B2 (en) | 2013-01-22 | 2015-07-21 | Ring-wing floating platform |
US14/805,357 US10060090B2 (en) | 2013-01-22 | 2015-07-21 | Type of suction leg, an offshore caisson and a sit-on-bottom offshore platform |
US14/805,398 US10041221B2 (en) | 2013-01-22 | 2015-07-21 | Steel plate and concrete composite tank unit, tank group and offshore platforms |
NO20151014A NO20151014A1 (en) | 2013-01-22 | 2015-08-12 | A ring-wing floating platform |
NO20151013A NO20151013A1 (en) | 2013-01-22 | 2015-08-12 | Steel plate and concrete composite tank unit, tank group and offshore platforms |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/CN2013/070808 WO2014113909A1 (zh) | 2013-01-22 | 2013-01-22 | 钢板和混凝土复合结构的单元罐、单元组罐及海上平台 |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
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US14/805,398 Continuation US10041221B2 (en) | 2013-01-22 | 2015-07-21 | Steel plate and concrete composite tank unit, tank group and offshore platforms |
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WO2014113909A1 true WO2014113909A1 (zh) | 2014-07-31 |
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Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
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PCT/CN2013/070808 WO2014113909A1 (zh) | 2013-01-22 | 2013-01-22 | 钢板和混凝土复合结构的单元罐、单元组罐及海上平台 |
PCT/CN2014/071121 WO2014114236A1 (zh) | 2013-01-22 | 2014-01-22 | 一种环翼式浮式平台 |
PCT/CN2014/071120 WO2014114235A1 (zh) | 2013-01-22 | 2014-01-22 | 吸力式桩腿、海上沉箱及坐底式海上平台 |
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Application Number | Title | Priority Date | Filing Date |
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PCT/CN2014/071121 WO2014114236A1 (zh) | 2013-01-22 | 2014-01-22 | 一种环翼式浮式平台 |
PCT/CN2014/071120 WO2014114235A1 (zh) | 2013-01-22 | 2014-01-22 | 吸力式桩腿、海上沉箱及坐底式海上平台 |
Country Status (9)
Country | Link |
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US (3) | US10060090B2 (zh) |
CN (2) | CN104968583B (zh) |
AU (2) | AU2013375773B2 (zh) |
BR (2) | BR112015016893A2 (zh) |
CA (2) | CA2897267C (zh) |
GB (2) | GB2524690A (zh) |
MY (1) | MY174732A (zh) |
NO (2) | NO20151013A1 (zh) |
WO (3) | WO2014113909A1 (zh) |
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2015
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CN104968583B (zh) | 2016-12-21 |
CN104321247B (zh) | 2017-04-12 |
AU2014210247B2 (en) | 2016-02-11 |
NO20151014A1 (en) | 2015-08-12 |
CN104321247A (zh) | 2015-01-28 |
US20150321838A1 (en) | 2015-11-12 |
GB2524690A (en) | 2015-09-30 |
CN104968583A (zh) | 2015-10-07 |
AU2014210247A1 (en) | 2015-08-20 |
BR112015016892A2 (pt) | 2017-07-11 |
MY174732A (en) | 2020-05-12 |
CA2897267C (en) | 2016-09-06 |
CA2897223A1 (en) | 2014-07-31 |
NO20151013A1 (en) | 2015-08-12 |
AU2013375773A1 (en) | 2015-08-20 |
US9850636B2 (en) | 2017-12-26 |
GB2523717A (en) | 2015-09-02 |
US20150322642A1 (en) | 2015-11-12 |
AU2013375773B2 (en) | 2016-02-04 |
BR112015016893A2 (pt) | 2017-07-11 |
WO2014114235A1 (zh) | 2014-07-31 |
WO2014114236A1 (zh) | 2014-07-31 |
US20150322640A1 (en) | 2015-11-12 |
GB201512439D0 (en) | 2015-08-19 |
GB201512429D0 (en) | 2015-08-19 |
CA2897267A1 (en) | 2014-07-31 |
US10060090B2 (en) | 2018-08-28 |
US10041221B2 (en) | 2018-08-07 |
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