WO2014059682A1 - 金属零件清洗液及制备方法 - Google Patents
金属零件清洗液及制备方法 Download PDFInfo
- Publication number
- WO2014059682A1 WO2014059682A1 PCT/CN2012/083261 CN2012083261W WO2014059682A1 WO 2014059682 A1 WO2014059682 A1 WO 2014059682A1 CN 2012083261 W CN2012083261 W CN 2012083261W WO 2014059682 A1 WO2014059682 A1 WO 2014059682A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- sodium pyrophosphate
- trisodium phosphate
- deionized water
- metal part
- cleaning fluid
- Prior art date
Links
- 238000004140 cleaning Methods 0.000 title claims abstract description 18
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 15
- 239000002184 metal Substances 0.000 title claims abstract description 15
- 238000002360 preparation method Methods 0.000 title abstract description 9
- 239000012530 fluid Substances 0.000 title abstract 4
- 239000001488 sodium phosphate Substances 0.000 claims abstract description 16
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims abstract description 16
- 229910000406 trisodium phosphate Inorganic materials 0.000 claims abstract description 16
- 235000019801 trisodium phosphate Nutrition 0.000 claims abstract description 16
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims abstract description 15
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 claims abstract description 13
- 229940048086 sodium pyrophosphate Drugs 0.000 claims abstract description 13
- 235000019818 tetrasodium diphosphate Nutrition 0.000 claims abstract description 13
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims abstract description 13
- 239000008367 deionised water Substances 0.000 claims abstract description 12
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 8
- 235000011118 potassium hydroxide Nutrition 0.000 claims abstract description 4
- 239000007788 liquid Substances 0.000 claims description 10
- NJPHDFNSISEFEM-UHFFFAOYSA-L [OH-].[Na+].[O-]P(O)(=O)OP(=O)(O)O.[K+] Chemical compound [OH-].[Na+].[O-]P(O)(=O)OP(=O)(O)O.[K+] NJPHDFNSISEFEM-UHFFFAOYSA-L 0.000 claims description 3
- 239000004615 ingredient Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 4
- 238000010438 heat treatment Methods 0.000 abstract description 3
- 239000000203 mixture Substances 0.000 abstract 1
- 238000003756 stirring Methods 0.000 abstract 1
- 230000001066 destructive effect Effects 0.000 description 3
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- 241000282412 Homo Species 0.000 description 1
- 208000000453 Skin Neoplasms Diseases 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000005431 greenhouse gas Substances 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 201000000849 skin cancer Diseases 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
- C11D3/062—Special methods concerning phosphates
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/14—Cleaning or pickling metallic material with solutions or molten salts with alkaline solutions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/16—Metals
Definitions
- the invention relates to a cleaning liquid and a preparation method thereof, in particular to a metal parts cleaning liquid and a preparation method thereof.
- Metal parts especially high-precision parts, need to be cleaned before assembly. At present, most of these parts are cleaned with trichloroethane.
- the large amount of trichloroethane will consume a large amount of ozone-depleting substances, which seriously endangers human living environment.
- the ozone layer forms a "protective umbrella” over the earth, filtering 99% of the ultraviolet light in the sun, which is very important for the survival of life on Earth.
- UV light can reduce the immunity of humans and animals. The most obvious manifestation is the increased incidence of skin cancer and even blinding animals and human eyes.
- Plankton Plants and microorganisms can die because they cannot withstand the intense exposure of ultraviolet light. Plankton is directly infested in the ocean, and plankton in the ocean can absorb large amounts of greenhouse gases. In this way, a vicious circle will form. The death of plankton in turn creates a chain reaction that causes other organisms in the ocean to die one after another and will ultimately affect the human activity.
- the object of the present invention is to provide a metal parts cleaning liquid which is environmentally friendly and has no destructive effect on the atmospheric ozone layer and a preparation method thereof, and overcome the deficiencies of the prior art.
- the preparation method of the metal parts cleaning liquid of the invention is as follows: firstly mixing trisodium phosphate, sodium pyrophosphate and deionized water according to the above mass ratio and heating to 90oC, so that all the trisodium phosphate and sodium pyrophosphate are dissolved, and then Add other ingredients and mix well.
- the metal parts cleaning liquid of the invention has no destructive effect on the atmospheric ozone layer, is green and environmentally friendly, has simple preparation method and good cleaning effect.
- the preparation method of the metal parts cleaning liquid of the invention is as follows: firstly mixing trisodium phosphate, sodium pyrophosphate and deionized water according to the above mass ratio and heating to 90oC, so that all the trisodium phosphate and sodium pyrophosphate are dissolved, and then Add other ingredients and mix well.
- the metal parts cleaning liquid of the invention has no destructive effect on the atmospheric ozone layer, is green and environmentally friendly, has simple preparation method and good cleaning effect.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Cleaning By Liquid Or Steam (AREA)
- Detergent Compositions (AREA)
Abstract
本发明的金属零件清洗液包括如下组分:磷酸三钠、焦磷酸钠、氢氧化钾、非离子表面活性剂、去离子水,所述的各组分的质量配比为:磷酸三钠∶焦磷酸钠∶氢氧化钾∶非离子表面活性剂∶去离子水=0.5∶0.5∶0.1∶20∶50。本发明的金属零件清洗液的制备方法如下:按上述质量配比先将磷酸三钠、焦磷酸钠、去离子水混合并加温至90ºC,使磷酸三钠、焦磷酸钠全部溶解,然后再加入其它成分并搅拌均匀。本发明的金属零件清洗液对大气臭氧层无破坏作用、绿色环保,制备方法简单,清洗效果好。
Description
本发明涉及一种清洗液 及制备方法 ,特别是一种 金属零件清洗液及制备方法。
金属零件特别是高精零件在组装前都需要清洗,目前清洗这些零件大多利用三氯乙烷,三氯乙烷的大量使用会大量的消耗臭氧层物质,严重危害人类生存环境。
臭氧层离地面约20到30公里处,它在地球上空形成一把"保护伞",它将太阳光中99%的紫外线过滤掉,这对于地球上生命的生存十分重要。
过量的紫外线会使人和动物免疫力下降,最明显的表现是皮肤癌的发病率增高,甚至于使动物和人眼睛失明。
植物的和微生物会因为承受不了紫外线的强烈照射而死亡。在海洋中直接受到侵害的是浮游生物,海洋中的浮游生物可以大量吸收温室气体。如此,会形成恶性循环。浮游生物的死亡又会产生连锁反应,使海洋中的其它生物相继死亡,并最终将影响的人类的活动。
本发明的目的是提供一种环保、对大气臭氧层无破坏作用的金属零件清洗液及制备方法, 克服现有技术的不足。
本发明的金属零件清洗液包括如下组分:磷酸三钠、焦磷酸钠、氢氧化钾、非离子表面活性剂、去离子水,所述的各组分的质量配比为:磷酸三钠 ∶焦磷酸钠
∶氢氧化钾∶非离子表面活性剂∶去离子水=0.5∶0.5∶0.1∶20∶50。
本发明的金属零件清洗液的制备方法如下:按上述质量配比先将磷酸三钠、焦磷酸钠、去离子水混合并加温至90ºC,使磷酸三钠、焦磷酸钠全部溶解,然后再加入其它成分并搅拌均匀。
本发明的金属零件清洗液对大气臭氧层无破坏作用、绿色环保,制备方法简单,清洗效果好。
本发明的
金属零件清洗液组分如下:磷酸三钠、焦磷酸钠、氢氧化钾、非离子表面活性剂、去离子水,所述的各组分的质量配比为:磷酸三钠 ∶焦磷酸钠
∶氢氧化钾∶非离子表面活性剂∶去离子水=0.5∶0.5∶0.1∶20∶50。
本发明的金属零件清洗液的制备方法如下:按上述质量配比先将磷酸三钠、焦磷酸钠、去离子水混合并加温至90ºC,使磷酸三钠、焦磷酸钠全部溶解,然后再加入其它成分并搅拌均匀。本发明的金属零件清洗液对大气臭氧层无破坏作用、绿色环保,制备方法简单,清洗效果好。
Claims (2)
- 一种金属零件清洗液,其特征在于:包括如下组分:磷酸三钠、焦磷酸钠、氢氧化钾、非离子表面活性剂、去离子水,所述的各组分的质量配比为:磷酸三钠∶焦磷酸钠 ∶氢氧化钾∶非离子表面活性剂∶去离子水=0.5∶0.5∶0.1∶20∶50。
- 根据权利要求1所述的金属零件清洗液的制备方法,其特征在于:先将磷酸三钠、焦磷酸钠、去离子水混合并加温至90ºC,使磷酸三钠、焦磷酸钠全部溶解,然后再加入其它成分并搅拌均匀。
Priority Applications (1)
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PCT/CN2012/083261 WO2014059682A1 (zh) | 2012-10-21 | 2012-10-21 | 金属零件清洗液及制备方法 |
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PCT/CN2012/083261 WO2014059682A1 (zh) | 2012-10-21 | 2012-10-21 | 金属零件清洗液及制备方法 |
Publications (1)
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WO2014059682A1 true WO2014059682A1 (zh) | 2014-04-24 |
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PCT/CN2012/083261 WO2014059682A1 (zh) | 2012-10-21 | 2012-10-21 | 金属零件清洗液及制备方法 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105297047A (zh) * | 2015-11-13 | 2016-02-03 | 佛山市高明俊品金属制品有限公司 | 一种不锈钢清洗剂 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4382825A (en) * | 1981-07-08 | 1983-05-10 | Amchem Products, Inc. | Alkaline cleaner for ferrous-based metal surfaces |
US4895675A (en) * | 1988-12-21 | 1990-01-23 | Pro-Max Performance, Inc. | Neutral pH wheel cleaner |
CN1872974A (zh) * | 2006-06-30 | 2006-12-06 | 天津晶岭电子材料科技有限公司 | 金属零件清洗剂及其制备方法 |
CN102041518A (zh) * | 2009-10-13 | 2011-05-04 | 北京中科三环高技术股份有限公司 | 用于永磁材料的除油剂 |
CN102094209A (zh) * | 2009-12-14 | 2011-06-15 | 徐冰 | 一种表面处理清洗液 |
-
2012
- 2012-10-21 WO PCT/CN2012/083261 patent/WO2014059682A1/zh active Application Filing
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4382825A (en) * | 1981-07-08 | 1983-05-10 | Amchem Products, Inc. | Alkaline cleaner for ferrous-based metal surfaces |
US4895675A (en) * | 1988-12-21 | 1990-01-23 | Pro-Max Performance, Inc. | Neutral pH wheel cleaner |
CN1872974A (zh) * | 2006-06-30 | 2006-12-06 | 天津晶岭电子材料科技有限公司 | 金属零件清洗剂及其制备方法 |
CN102041518A (zh) * | 2009-10-13 | 2011-05-04 | 北京中科三环高技术股份有限公司 | 用于永磁材料的除油剂 |
CN102094209A (zh) * | 2009-12-14 | 2011-06-15 | 徐冰 | 一种表面处理清洗液 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105297047A (zh) * | 2015-11-13 | 2016-02-03 | 佛山市高明俊品金属制品有限公司 | 一种不锈钢清洗剂 |
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