WO2013162956A2 - Methods and devices for casing and cementing a wellbore - Google Patents
Methods and devices for casing and cementing a wellbore Download PDFInfo
- Publication number
- WO2013162956A2 WO2013162956A2 PCT/US2013/036861 US2013036861W WO2013162956A2 WO 2013162956 A2 WO2013162956 A2 WO 2013162956A2 US 2013036861 W US2013036861 W US 2013036861W WO 2013162956 A2 WO2013162956 A2 WO 2013162956A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- casing string
- fluid
- tool
- vortex
- vibrating
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 43
- 239000004568 cement Substances 0.000 claims abstract description 18
- 239000012530 fluid Substances 0.000 claims description 86
- 238000005086 pumping Methods 0.000 claims description 11
- 238000005553 drilling Methods 0.000 claims description 8
- 229910000831 Steel Inorganic materials 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- 239000010959 steel Substances 0.000 claims description 3
- 229910001369 Brass Inorganic materials 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 230000000712 assembly Effects 0.000 claims description 2
- 238000000429 assembly Methods 0.000 claims description 2
- 239000010951 brass Substances 0.000 claims description 2
- 239000002131 composite material Substances 0.000 claims description 2
- 230000008602 contraction Effects 0.000 claims description 2
- 125000004122 cyclic group Chemical group 0.000 claims description 2
- 239000004033 plastic Substances 0.000 claims description 2
- 230000003190 augmentative effect Effects 0.000 abstract 1
- 239000003129 oil well Substances 0.000 description 2
- 239000011398 Portland cement Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000002457 bidirectional effect Effects 0.000 description 1
- 239000012267 brine Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000011499 joint compound Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 230000010349 pulsation Effects 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B28/00—Vibration generating arrangements for boreholes or wells, e.g. for stimulating production
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B33/00—Sealing or packing boreholes or wells
- E21B33/10—Sealing or packing boreholes or wells in the borehole
- E21B33/13—Methods or devices for cementing, for plugging holes, crevices or the like
- E21B33/14—Methods or devices for cementing, for plugging holes, crevices or the like for cementing casings into boreholes
Definitions
- the present invention relates generally to casing and cementing well bores.
- Figure 1 is a diagrammatic illustration of a casing string deployment system comprising a plurality of variable flow resistance devices in accordance with the present invention.
- Figure 2 is a longitudinal sectional view of a preferred casing collar comprising a variable flow resistance device in accordance with a preferred embodiment of the present invention.
- Figure 3 is a longitudinal sectional view of a preferred casing shoe comprising a variable flow resistance device in accordance with a preferred embodiment of the present invention.
- Figure 4 is an illustration of the flow path of a preferred variable flow resistance device for use in the methods and devices of the present invention.
- Figure 5 is a longitudinal sectional view of a casing plug comprising a variable flow resistance device in accordance with a preferred embodiment of the present invention.
- Figure 6 is a perspective view taken from the uphole or trailing end of the casing plug shown in Figure 4.
- Figure 7 is a perspective view taken from the downhole or leading end of the casing plug shown in Figure 4.
- the present invention is directed to methods and devices for finishing a wellbore, that is, for positioning the casing in the wellbore or for cementing the emplaced casing or both.
- These methods and devices employ a vibrating tool in the casing string to facilitate advancement of the string.
- vibrating tool refers to a tool comprising a variable flow resistance device, that is, a force generating tool that repetitively interrupts fluid flow to generate cyclic hydraulic loading on the casing string, thereby causing repeated extension and contraction of the casing string.
- This vibratory motion breaks the static friction reducing the drag force on the casing string.
- the pulsating motion of the casing string caused by the vibrating tool helps advance the casing string along the borehole.
- the pulsing and vibration of the casing string enhances the distribution of the cement as it is pumped into the annulus around the casing.
- the tools can be drilled out once the cementing operation is completed.
- casing deployment system means any system or structure for supporting and advancing the casing string for lining the wellbore 14.
- the exemplary casing deployment system 12 includes a derrick 16 and the casing string assembly 18.
- the casing string assembly 18 includes tools, such as float shoes and float collars, that are connected in the casing string 20.
- the number, type, and location of such tools in the casing string assembly 18 may vary.
- the casing string 20 is equipped with a float shoe 24, a float collar 26, and two vibrating collars both designated at 28.
- the casing string assembly 18 includes a vibrating plug 30.
- the vibrating tool of the present invention may take the form of a collar, plug, or shoe, but usually will be combined with one or more conventional float shoes or collars. It will be understood that although the casing string 18 includes all these types of devices, in practice not all these tools would be used together as shown. For example, the operator may run the plug after drilling out one or more of the collars.
- the wellbore 14 comprises a vertical section 34 and a generally horizontal section 36.
- the vertical section is lined with casing 38.
- the casing 38 is secured by cement 40 in the annulus 42 between the walls of the wellbore 14 and the casing.
- the casing string assembly 18 is shown positioned in the still uncased horizontal section 36.
- FIG. 2 shows a casing collar embodiment of the preferred vibrating tool of the present invention and is designated generally at 100.
- the vibrating tool 100 comprises a housing 102 with a body section 104 having uphole and downhole ends 106 and 108, each adapted for connection to the casing string 20 or to another tool in the casing string assembly 18. In most instances, the ends 106 and 108 will be threaded at 110 and 112.
- the housing 102 preferably is made from tubular steel.
- An insert 118 is secured inside the body section 104 of the housing 102.
- the insert 118 defines a flow path 120 for generating pulsations, as described in more detail hereafter.
- the housing 102 may be made of tubular steel, it is advantageous to make the insert 118 out of rubber, brass, aluminum, composite, or plastic.
- the insert 118 is molded of rubber.
- the insert 118 preferably is molded in two halves forming opposing inner faces, only one of which is shown herein.
- the flow path 120 may be formed as a patterned recess in each of the faces, which together form a complete flow path.
- the insert 118 may be permanently secured inside the body section 104 using a high strength cement 122, such as Portland cement, some other drillable adhesive.
- the insert 118 includes an insert inlet 124 continuous with the uphole end 106 of the tool 100.
- the insert inlet 124 directs fluid to enter flow path inlet 126.
- the insert 118 includes an insert outlet 128 that receives fluid leaving the flow path 120 through the flow path outlet 130. In this way, fluid flowing through the casing string assembly is forced through the flow path 118.
- Figure 3 shows a casing shoe embodiment of the preferred vibrating tool of the present invention and is designated generally at 200.
- the vibrating tool 200 comprises a housing 202 with a body section 204 having uphole and downhole ends 206 and 208.
- the uphole end 206 is adapted for connection to the casing string 20 or to another tool in the casing string assembly 18.
- the uphole end 206 will be threaded at 210.
- the downhole end 208 is open and the edge 212 surrounding the open end beveled or radiused or otherwise blunted in a known manner to facilitate advancement of the leading end of the casing string assembly 18.
- the tool 200 includes an insert 218 secured inside the body section 204 of the housing 202 using cement 222.
- the insert 218 defines a flow path 220 similar to the flow path 120 of the tool 100 in Figure 2, and includes an insert inlet 224 and insert outlet 228 continuous with a flow path inlet 226 and flow path outlet 230, as in the previously described collar embodiment.
- FIG. 4 shows the preferred flow path for use in the vibrating tools of the present invention. Since the flow paths 120 and 220 are similar, only the flow path 120 will be described in detail. Fluid enters the flow path 120 through the flow path inlet 126 and exits through the flow path outlet 130, as indicated previously. Fluid is directed from the inlet 126 to a vortex chamber 140 that is continuous with the outlet 130. In a known manner, fluid directed into the vortex chamber 140 tangentially will gradually form a vortex, either clockwise or counter-clockwise. As the vortex decays, the fluid exits the outlet 130.
- a switch of some sort is used to reverse the direction of the vortex flow, and the vortex builds and decays again. As this process of building and decaying vortices repeats, and assuming a constant flow rate, the resistance to flow through flow path varies and a fluctuating backpressure is created above the device.
- the switch designated generally at 150, takes the form of a Y-shaped bi-stable fluidic switch.
- the flow path 120 includes a nozzle 152 that directs fluid from the inlet 126 into a jet chamber 154.
- the jet chamber 154 expands and then divides into two diverging input channels, the first input channel 156 and the second input channel 158, which are the legs of the Y.
- the fluid stream exiting the nozzle 152 will tend to adhere to or follow one or the other of the outer walls of the chamber so the majority of the fluid passes into one or other of the input channels 156 and 158. The flow will continue in this path until acted upon in some manner to shift to the other side of the jet chamber 154.
- the ends of the input channels 156 and 158 connect to first and second inlet openings 170 and 172 in the periphery of the vortex chamber 140.
- the first and second inlet openings 170 and 172 are positioned to direct fluid in opposite, tangential paths into the vortex chamber. In this way, fluid entering the first inlet opening 170 produces a clockwise vortex indicated by the dashed line at "CW” in Figure 4. Similarly, once shifted, fluid entering the second inlet opening 172 produces a counterclockwise vortex indicated by the dotted line at "CCW.”
- each of the first and second input channels 170 and 170 are identical to each of the first and second input channels 170 and
- the flow path 120 preferably includes a feedback control circuit, designated herein generally by the reference numeral 176.
- the feedback control circuit 176 includes first and second feedback channels 178 and 180 that conduct fluid to control ports in the jet chamber 154, as described in more detail below.
- the first feedback channel 178 extends from a first feedback outlet 182 at the periphery of the vortex chamber 140.
- the second feedback channel 180 extends from a second feedback outlet 184 also at the periphery of the vortex chamber 140.
- the first and second feedback outlets 182 and 184 are positioned to direct fluid in opposite, tangential paths out of the vortex chamber 140.
- first and second feedback outlets 182 and 184 are positioned to direct fluid in opposite, tangential paths out of the vortex chamber 140.
- the first feedback channel 178 connects the first feedback outlet 182 to a first control port 186 in the jet chamber 154, and the second feedback channel 180 connects the second feedback outlet 184 to a second control port 188.
- each feedback channel could be isolated or separate from the other, in this preferred embodiment of the flow path, the feedback channels 178 and 180 share a common curved section 190 through which fluid flows bidrectionally.
- the first feedback channel 178 has a separate straight section 178a that connects the first feedback outlet 182 to the curved section 190 and a short connecting section 178b that connects the common curved section 190 to the control port 186, forming a generally J-shaped path.
- the second feedback channel 180 has a separate straight section 118a that connects the second feedback outlet 184 to the common curved section 190 and a short connection section that connects the curved section to the second control port 188.
- the curved section 190 of the feedback circuit 176 together with the connecting sections 178b and 180b form an oval return loop extending between the first and second control ports 186 and 188.
- two separate curved sections could be used, but the common bidirectional segment 190 promotes compactness of the overall design.
- the diameter of the return loop approximates that of the vortex chamber 140. This allows the feedback channels 178 and 180 to be straight, which facilitates flow therethrough. However, these dimensions may be varied.
- first and second inlet openings 170 and 172 may be within about 60-90 degrees of each other. Additionally, the first inlet opening 170 is adjacent the first feedback outlet 182, and the second inlet opening 172 is adjacent the second feedback outlet 184. Even more preferably, the first and second inlet openings 170 and 172 and the first and second feedback outlets 182 and 184 all are within about a 180 segment of the peripheral wall of the vortex chamber 140.
- the vibrating tool 300 shown in these Figures and designated generally by the reference number 300 is a casing plug. As such, it can be pumped down the casing string assembly and "landed" at a target location to become a component of the casing string assembly.
- the casing plug 300 comprises a housing 302 with a body section 304 having uphole and downhole ends 306 and 308.
- the housing preferably is formed with circumferential wipers 310 and is made of rubber.
- the uphole and downhole ends 306 and 308 are provided with teeth 312 and 314. These teeth engage the landing surface to prevent rotation of the plug with a drill bit when the plug is later drilled out of the casing string.
- an insert 318 defining a flow path 320 is secured inside the housing body 304 using cement 322.
- the housing 302 may be molded directly on the preformed insert 318.
- the insert 318 includes an insert inlet 324 continuous with the uphole end 306 of the plug 300.
- the insert inlet 324 directs fluid to enter the flow path inlet 326.
- the insert 318 includes an insert outlet 328 that receives fluid leaving the flow path 320 through the flow path outlet 330.
- the configuration of the flow path may be varied.
- the flow path may have multiple vortex chambers.
- the tool may have multiple flow paths, arranged end to end or circumferentially.
- a wellbore is finished.
- finished refers to the process of casing a well bore, cementing a casing string, or both.
- the wellbore may be finished in a single operation in monobore applications, or in multiple operations in tapered casing applications.
- a first casing string assembly is deployed in the well.
- the first casing string assembly comprises at least one vibrating tool.
- the vibrating tool may be any of several commercially available vibrating tools that comprise a variable flow resistance device.
- One such tool is the Achiever brand tool available from Thru Tubing Solutions, Inc. (Oklahoma City, OK)
- Another is the Agitator Brand tool made by National Oilwell Varco (Houston, TX).
- the vibrating tools used the casing string assembly will be those made in accordance with one or more of the above-described embodiments.
- the casing string assembly likely will also include float equipment, such as a float shoe or a float collar or both.
- This first casing string assembly next is advanced to the target location.
- the type of fluid may vary, so long as the fluid can be pumped at a rate to activate the vibrating tool or tools in the casing string assembly.
- the fluid may be a circulating fluid (not cement), such as drilling mud, brine, or water.
- the fluid pumping may be continuous or intermittent. This process is continued until the first casing string reaches the target location.
- the vibrating tool may indicate wear. Wear or damage to the vibrating tool of this invention may be indicated by a change in overall circulating pressure, which indicates a change in pressure drop at the tool. This, in turn, suggests that the tool is worn or damaged. Additionally, in some cases, a noticeable decrease in vibration of the casing string at the surface suggests decreasing function of the vibrating tool downhole. Still further, increasing difficulty in advancing the casing may reveal a worn or damaged vibrating tool.
- additional vibrating tools may be added to the casing string assembly by deploying one or more casing plugs, also described above. After one or more vibrating casing plugs of the present invention have been deployed and landed in the casing string, advancement of the casing string assembly is resumed while maintaining fluid flow. This may be repeated as necessary until the target location is reached.
- the annulus may be cemented. This may be carried out in the conventional manner using top and bottom cementing plugs to create an isolated column of cement. The cement/fluid column created is pumped to force the cement into the annulus. Again, this pumping action continuous to activate the one or more vibrating tools in the first casing string assembly, and this vibrating facilitates the distribution the cement through the annular void. Once the cement is properly distributed, operations are paused and maintained under pressure until the cement sets. At this point, the vibrating tools in the first casing string, as well as any float equipment, can be drilled out of the cemented casing. In the case of tapered casing applications, after the first casing string is drilled out, the wellbore may be extended and second and subsequent casing string assemblies may be installed using the same procedures.
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- Geology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mining & Mineral Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Fluid Mechanics (AREA)
- Physics & Mathematics (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Structures Of Non-Positive Displacement Pumps (AREA)
- Investigation Of Foundation Soil And Reinforcement Of Foundation Soil By Compacting Or Drainage (AREA)
- Earth Drilling (AREA)
- Ropes Or Cables (AREA)
Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU2013252728A AU2013252728B2 (en) | 2012-04-25 | 2013-04-17 | Methods and devices for casing and cementing a wellbore |
MX2014012982A MX349087B (en) | 2012-04-25 | 2013-04-17 | Methods and devices for casing and cementing a wellbore. |
CA2869335A CA2869335C (en) | 2012-04-25 | 2013-04-17 | Methods and devices for casing and cementing a wellbore |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US13/455,554 | 2012-04-25 | ||
US13/455,554 US8424605B1 (en) | 2011-05-18 | 2012-04-25 | Methods and devices for casing and cementing well bores |
Publications (3)
Publication Number | Publication Date |
---|---|
WO2013162956A2 true WO2013162956A2 (en) | 2013-10-31 |
WO2013162956A3 WO2013162956A3 (en) | 2014-08-07 |
WO2013162956A9 WO2013162956A9 (en) | 2014-10-02 |
Family
ID=48184540
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2013/036861 WO2013162956A2 (en) | 2012-04-25 | 2013-04-17 | Methods and devices for casing and cementing a wellbore |
Country Status (5)
Country | Link |
---|---|
AR (1) | AR090826A1 (en) |
AU (1) | AU2013252728B2 (en) |
CA (1) | CA2869335C (en) |
MX (1) | MX349087B (en) |
WO (1) | WO2013162956A2 (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106320984A (en) * | 2016-09-26 | 2017-01-11 | 西南石油大学 | Drilling tool achieving axial impacting through vortex-induced vibration |
CN111594096A (en) * | 2020-05-22 | 2020-08-28 | 中国农业大学 | Underground ultrasonic vibration well cementation system and vibration well cementation method thereof |
US10781654B1 (en) | 2018-08-07 | 2020-09-22 | Thru Tubing Solutions, Inc. | Methods and devices for casing and cementing wellbores |
US10865605B1 (en) | 2015-08-11 | 2020-12-15 | Thru Tubing Solutions, Inc. | Vortex controlled variable flow resistance device and related tools and methods |
CN113123749A (en) * | 2020-01-16 | 2021-07-16 | 中国石油天然气股份有限公司 | Thickened oil falls thick device based on pulse ripples |
CN114183077A (en) * | 2021-12-01 | 2022-03-15 | 中国海洋石油集团有限公司 | Downhole hydraulic vibration-assisted casing running and well cementation integrated combined tool and use method thereof |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8066059B2 (en) | 2005-03-12 | 2011-11-29 | Thru Tubing Solutions, Inc. | Methods and devices for one trip plugging and perforating of oil and gas wells |
US10677024B2 (en) | 2017-03-01 | 2020-06-09 | Thru Tubing Solutions, Inc. | Abrasive perforator with fluid bypass |
US10301883B2 (en) | 2017-05-03 | 2019-05-28 | Coil Solutions, Inc. | Bit jet enhancement tool |
WO2018204655A1 (en) | 2017-05-03 | 2018-11-08 | Coil Solutions, Inc. | Extended reach tool |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20120292015A1 (en) | 2011-05-18 | 2012-11-22 | Thru Tubing Solutions, Inc. | Vortex Controlled Variable Flow Resistance Device and Related Tools and Methods |
US20120291539A1 (en) | 2011-05-18 | 2012-11-22 | Thru Tubing Solutions, Inc. | Vortex Controlled Variable Flow Resistance Device and Related Tools and Methods |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB9224300D0 (en) * | 1992-11-19 | 1993-01-06 | British Petroleum Co Plc | Method for freeing or preventing stuck pipe |
US7404416B2 (en) * | 2004-03-25 | 2008-07-29 | Halliburton Energy Services, Inc. | Apparatus and method for creating pulsating fluid flow, and method of manufacture for the apparatus |
US20100212901A1 (en) * | 2009-02-26 | 2010-08-26 | Frank's International, Inc. | Downhole vibration apparatus and methods |
US8726993B2 (en) * | 2010-05-27 | 2014-05-20 | Claude E Cooke, Jr. | Method and apparatus for maintaining pressure in well cementing during curing |
-
2013
- 2013-04-17 WO PCT/US2013/036861 patent/WO2013162956A2/en active Application Filing
- 2013-04-17 MX MX2014012982A patent/MX349087B/en active IP Right Grant
- 2013-04-17 AU AU2013252728A patent/AU2013252728B2/en not_active Ceased
- 2013-04-17 CA CA2869335A patent/CA2869335C/en active Active
- 2013-04-24 AR ARP130101371A patent/AR090826A1/en active IP Right Grant
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20120292015A1 (en) | 2011-05-18 | 2012-11-22 | Thru Tubing Solutions, Inc. | Vortex Controlled Variable Flow Resistance Device and Related Tools and Methods |
US20120291539A1 (en) | 2011-05-18 | 2012-11-22 | Thru Tubing Solutions, Inc. | Vortex Controlled Variable Flow Resistance Device and Related Tools and Methods |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10865605B1 (en) | 2015-08-11 | 2020-12-15 | Thru Tubing Solutions, Inc. | Vortex controlled variable flow resistance device and related tools and methods |
CN106320984A (en) * | 2016-09-26 | 2017-01-11 | 西南石油大学 | Drilling tool achieving axial impacting through vortex-induced vibration |
US10781654B1 (en) | 2018-08-07 | 2020-09-22 | Thru Tubing Solutions, Inc. | Methods and devices for casing and cementing wellbores |
CN113123749A (en) * | 2020-01-16 | 2021-07-16 | 中国石油天然气股份有限公司 | Thickened oil falls thick device based on pulse ripples |
CN111594096A (en) * | 2020-05-22 | 2020-08-28 | 中国农业大学 | Underground ultrasonic vibration well cementation system and vibration well cementation method thereof |
CN114183077A (en) * | 2021-12-01 | 2022-03-15 | 中国海洋石油集团有限公司 | Downhole hydraulic vibration-assisted casing running and well cementation integrated combined tool and use method thereof |
CN114183077B (en) * | 2021-12-01 | 2023-12-05 | 中国海洋石油集团有限公司 | Underground hydraulic vibration assisted casing running and well cementation integrated combined tool and use method thereof |
Also Published As
Publication number | Publication date |
---|---|
AU2013252728B2 (en) | 2016-12-22 |
MX349087B (en) | 2017-07-10 |
WO2013162956A9 (en) | 2014-10-02 |
MX2014012982A (en) | 2015-02-05 |
WO2013162956A3 (en) | 2014-08-07 |
CA2869335C (en) | 2020-05-05 |
AR090826A1 (en) | 2014-12-10 |
AU2013252728A1 (en) | 2014-11-13 |
CA2869335A1 (en) | 2013-10-31 |
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