WO2012156695A1 - Support structure - Google Patents
Support structure Download PDFInfo
- Publication number
- WO2012156695A1 WO2012156695A1 PCT/GB2012/051039 GB2012051039W WO2012156695A1 WO 2012156695 A1 WO2012156695 A1 WO 2012156695A1 GB 2012051039 W GB2012051039 W GB 2012051039W WO 2012156695 A1 WO2012156695 A1 WO 2012156695A1
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- WO
- WIPO (PCT)
- Prior art keywords
- support structure
- additive
- release component
- additive release
- filter
- Prior art date
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- BAQAVOSOZGMPRM-QBMZZYIRSA-N sucralose Chemical compound O[C@@H]1[C@@H](O)[C@@H](Cl)[C@@H](CO)O[C@@H]1O[C@@]1(CCl)[C@@H](O)[C@H](O)[C@@H](CCl)O1 BAQAVOSOZGMPRM-QBMZZYIRSA-N 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
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Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/04—Tobacco smoke filters characterised by their shape or structure
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/04—Tobacco smoke filters characterised by their shape or structure
- A24D3/048—Tobacco smoke filters characterised by their shape or structure containing additives
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/061—Use of materials for tobacco smoke filters containing additives entrapped within capsules, sponge-like material or the like, for further release upon smoking
Definitions
- the present invention relates to additive release component support structures for use in smoking articles.
- smoking article includes smokeable products such as cigarettes, cigars and cigarillos whether based on tobacco, tobacco derivatives, expanded tobacco, reconstituted tobacco or tobacco substitutes and also heat-not-burn products (i.e. products in which flavour is generated from a smoking material by the application of heat without causing combustion of the material).
- smoking articles are provided with filters for removing constituents from the smoke.
- additive release components containing additives such as flavour ants inside smoking articles. By applying force to the outside of the smoking article, the smoker may induce the release of the flavourant from additive release component.
- a smoker wishing to add flavour to the smoke may do so by simply squeezing the smoking article.
- additive release components are located within the smoking article, it may be difficult for the user to release the additive.
- additive release components may be used from which additive is more easily released; however such additive release components may have an increased likelihood of accidental additive release.
- additive release components are generally placed within smoking articles, it may be difficult for the user to determine whether or not the additive has been released from the additive release component.
- a support structure for use in smoking article the support structure being arranged to cause release of an additive from an additive release component when a compressive force is applied, wherein the support structure changes the compressive force required to cause release of the additive from the additive release component compared to the force required to release the additive from the same additive release component in the absence of the support structure.
- an additive release system comprising a support structure in accordance with the first aspect, and an additive release component.
- a filter for a smoking article comprises a support structure in accordance with the first aspect, or an additive release system in accordance with the second aspect.
- a smoking article comprising a support structure in accordance with the first aspect, a support system in accordance with the second aspect, and/or a filter in accordance with the third aspect.
- Figures lA and iB show an additive release component support structure with additive release component in situ, according to a first embodiment
- Figure 2 shows an additive release component support structure according to the first embodiment in a second, deformed state, in which the support structure is deformed, and the additive release component is ruptured;
- Figure 3 shows an exploded view of a smoking article comprising an additive release component support structure according to the first embodiment
- Figures 4A and 4B show an additive release component support structure with and without an additive release component, according to a second embodiment
- Figure 5 shows an exploded side elevation view of a smoking article comprising an additive release component support structure according to the second embodiment
- Figures 6A and 6B show an additive release component support structure with additive release component in situ, according to a third embodiment
- Figure 7 shows an additive release component support structure according to the third embodiment in a second state, in which the support structure is deformed, and the additive release component is ruptured;
- Figure 8 shows an exploded side elevation view of a smoking article comprising an additive release component support structure according to the third embodiment
- Figure 9 shows an exploded side elevation view of a smoking article comprising two additive release component support structures, according to a fourth embodiment
- Figure 10 shows a smoking article filter comprising an additive release component support structure container according to a fifth embodiment
- Figures 11A and nB show an additive release component support structure with additive release component in situ, according to a sixth embodiment.
- Figures 12A to 12C show an additive release component support structure with additive release component in situ, according to further embodiments.
- An additive release component support structure is a structure which may support an additive release component and which may be positioned within a smoking article.
- the additive release component support structure allows, facilitates and/or enhances the controlled release of the additive from the additive release component. Release may be controlled, for example, in terms of the direction, the quantity, the velocity, the timing, and/or the duration of release.
- the additive release component support structure may also provide feedback to the user that the additive has been released from the additive release component.
- additive may easily be released from an additive release component by a user as and when desired, and furthermore the nature of the release can be precisely controlled.
- the user may be able to feel when the additive release component support structure has been actuated, and therefore can be confident that the additive has been released.
- Actuation of the additive release component support structure may also involve a noise such as a click, which may provide further feedback to the user that additive has been released from the additive release component.
- the support structure may support the additive release component, for example the support structure may be arranged to receive the additive release component. In some embodiments, the support structure retains the additive release component. The support structure may hold the additive release component. For example, the support structure may be shaped to receive or grip the additive release component, and/or the additive release component may be adhered or bound to the support structure.
- a smoking article may be produced by a method in which an additive release component is inserted into a support structure, and then a smoking article is produced which comprises the support structure.
- the support structure may have a substantially cylindrical configuration, and in this case, the centre of the cylinder may be arranged to receive the additive release component.
- the support structure is actuatable to cause release of an additive from an additive release component. Actuation may be induced by the application of external force, such as by a compressive force.
- the actuation of the support structure may be induced by external force applied to the support structure, which may be any type of force, such as a compressive or tensional force.
- the external force may be applied to the support structure in an inward lateral direction.
- force may be applied to the external surface of the support structure, for example by squeezing the smoking article.
- the support structure may have a cylindrical conformation, and the force may be applied to the curved, circumferential surface of the support structure.
- External force applied to the support structure may be any sort of force, including a compressive force, or a tensional force.
- the external force may be applied directly to the support structure, or may be applied via other components of the smoking article, such as via one or more wrapping layers, and/or one or more sections of filter material, for example.
- Force exerted on the filter may be transmitted to a support structure positioned therein due to compression of the surrounding filter material.
- a portion of the support structure may protrude from, or be at or near the surface of the smoking article, and thus force may be exerted substantially directly on the support structure.
- the direction of compression is in a plane perpendicular to longitudinal axis of the smoking article in which the support structure is incorporated.
- the support structure may be actuated.
- the support structure is a solid shaped article.
- the support structure may, in some embodiments, provide a rigid reaction surface i.e. the support structure is stiff, hard and/or difficult to bend.
- the support structure may be formed from a single part or may be made from multiple parts that are held together to provide sufficient rigidity to substantially resist compression upon actuation of the support structure, so that the compressive force is transmitted to the additive release component.
- the force applied to the support structure is only transmitted to and/or is focused on particular parts of the additive release component.
- the support structure has an inner surface with restricted areas over which it will contact the additive release component, for example due to the shape of the inner surface of the support structure. In some embodiments, this may be achieved by the provision of one or more protrusions on the inner surface of the support structure which may, for example, puncture the additive release component.
- the support structure may have a folded or undulating inner surface.
- the support structure may comprise a deformable section.
- the rest of the support structure is substantially resistant to being deformed by the compressive force applied.
- the deformable section may be resiliently or plastically deformable.
- the deformable section may comprise a tapered projection.
- the deformable section may have the form of a hinged arm.
- the deformable section may be a section of the circumferential surface of the capsule holder, which may be formed between two weakened sections in the circumferential surface.
- the region of deformation of the support structure is not predefined.
- the support structure may provide a reaction surface against which the additive release component may be compressed.
- the support structure may comprise a protrusion, such as a tapered projection, wherein actuation involves the additive release component and the protrusion, for example, the tapered projection, being compressed or pressed together.
- the additive release component support structure may induce the release of the additive from the additive release component via any possible mechanism.
- the support structure may be configured to transmit actuating force to the additive release component to induce the release of the additive via any suitable mechanism.
- the release may be, for example, a pumped release, a directional release, a multi-stage release or a single release of additive.
- the type of release may be
- the additive release component support structure may induce the release of the additive from the additive release component in a single dose, in multiple doses, or by means of a variable release, for example in which the release is proportional to the strength or duration of force applied to the support structure. This may be achieved by appropriate selection of the material from which the support structure is manufactured. For example, if the support structure is moulded from a flexible plastic, then upon the application of force, following the actuation, the support structure may return to its original conformation. In this case, depending on the nature of the additive release component, further additive may be released from the additive release component by subsequent applications of force to the support structure.
- the support structure is made from an inflexible material, such as an inflexible plastic, then as the support structure is actuated, it may break. Such an arrangement may limit the support structure to a single actuation, and thus the additive release component may deliver a single release of additive.
- Actuation of the support structure may be accompanied by an audible sound or a perceivable structural change in the support structure. Therefore, the user may easily be able to determine whether or not the additive has been released from the additive release component.
- the support structure may comprise a moulded plastics material, for example, polylactic acid, cellulose acetate, or polyvinyl alcohol.
- the size and shape of the additive release component support structure is preferably determined in combination with the size and shape of the additive release component to be used. In this way, the additive release component may be supported by the support structure, and the support structure may offer physical protection to the additive release component until such time that the release of the additive is required.
- the support structure is preferably substantially hollow and/or may include gaps and/or channels when an additive release component is positioned within the support structure, to permit airflow through the structure so that the support structure and additive release component do not obstruct the pathway of the smoke and any ventilating air flowing through the filter within which they are located.
- the additive release component support structure may be smaller than the diameter of the smoking article in which it is to be used.
- the support structure may have a generally cylindrical shape, the outer circumference being smaller than the diameter of the accompanying smoking article.
- a support structure for use within the filter of a king-size smoking article may have a diameter of approximately 5mm to 10mm.
- a support structure for use within the filter of a superslim smoking article may have a diameter of approximately 3mm to 7mm.
- the additive release component support structure is typically of a length between 3mm and 12mm, preferably between 4mm and 10mm, such about 5mm, 6mm, 7mm, 8mm, or 9mm in length.
- the additive release component support structure has a cross- sectional shape that is substantially similar to that of the smoking article in which the support structure is to be used.
- support structures for use in conventional cigarettes may be circular in cross-section. The reason for this is that the support structure may also function to provide shape, format, or strength to the smoking article.
- the additive release component support structure has a size which is substantially smaller than the diameter of the smoking article.
- one or more support structures may be distributed throughout the smoking article.
- the support structure has a size which is substantially the same as the cross-sectional size of the smoking article into which it is to be incorporated.
- the support structure will not be surrounded by a layer of material, such as filter material, or by a void or gap. Rather, the support structure may, for example, be surrounded merely by the tipping paper, paper wrapper and/or plugwrap, or other wrapper surrounding the relevant part of the smoking article.
- the additive release component support structure may comprise on its outer surface one or more pimples, grooves, raised elements, or any other deviation from a smooth surface.
- the support structure may be hexagonal or other polygonal, elliptical, or irregular shape in cross-section, rather than circular. Such elements may be detectable to the user of the smoking article, and may thus provide an indication of the position of the additive release component support structure in the smoking article filter, and the region of the support structure to which actuating force must be applied in order to induce the release of additive from the additive release component.
- the additive release component support structure may be a moulded plastic structure.
- the support structure is manufactured from a biodegradable plastic such as PLA (polylactic acid), CA (cellulose acetate) or PVOH (polyvinyl alcohol).
- PLA polylactic acid
- CA cellulose acetate
- PVOH polyvinyl alcohol
- the support structure may be produced using any mouldable plastic, ceramic, starch, card, paper, fluted wrap, or other suitable material known to the skilled person.
- the material from which the support structure is manufactured may, in some embodiments, be transparent or translucent.
- the additive release component support structure may be at least partially visible to the user, for example, via a transparent window portion in the filter tipping paper.
- the support structure may be made from a clear, colourless material.
- the support structure may be coloured.
- the support structure may comprise a colouring agent.
- the colouring agent may also be used to render more easily the location of the support structure within the filter during the manufacturing process.
- the additive release component support structure may also function to provide the consumer with a sensation upon actuation. This may be achieved, for example, by the support structure producing an audible sound when actuated, and/or by the support structure undergoing perceptible change in shape upon actuation.
- the additive component support structure may be manufactured by a process in which a rod or tube having a suitable internal and/or external shape is initially manufactured.
- the rod or tube may be extruded, or may be shaped or stamped, for example from a sheet of suitable material.
- the rod or tube is sliced or otherwise separated into individual units, each of which is a single support structure.
- the support structure comprises a shaped tube having a cross sectional shape which will hold and support an additive release component.
- the support structure will be shaped to transmit compressive force to an additive release component located within the inner void.
- the compressive force will be transmitted to the surface of the additive release component.
- the force may be focused at this location. In some embodiments, this localised transmission of force enables the additive release components to be ruptured upon application of less force than would be required to rupture the additive release component in situ in a conventional filter without the support structure.
- the cross-sectional shape of the support structure provides channels through which air may flow.
- the channels may be located between the support structure and the additive release component and/or external to the support structure, as indentations or grooves in the outer surface which may form channels between the outer surface of the support structure and the part of the smoking article into which it is incorporated.
- the support structure is a fluted tube. The fluting may, for example, be smooth and undulating, irregular, angular or castellated.
- the material of such support structures may comprise or consist of sheet materials including, for example: cellulose acetate, which may be extruded or provided as a sheet and then thermoformed, for example to provide a fluted cross- sectional shape; cellulose diacetate, such as Clarifoil®, optionally shaped by thermoforming techniques; or a hotmelt material including EVA, PU, metallocene catalyzed polymers, APAO, polyamide and block copolymers, such as Henkel
- the additive release component is combined with the support structure prior to insertion of the combination (also referred to as the additive release system) into the desired part of the smoking article. Insertion into the smoking article may occur at the same time as assembly of the smoking article.
- the support structure is shaped so that once inserted into the support structure, the additive release component is held in place, for example by vanes or the shape of the support structure.
- the support structure includes a deformable section and this section may be deformed to insert the additive release component and it then returns to its original configuration so that the additive release component is held in position within the support structure. Where the support structure holds the additive release component this can help to ensure that the two components are correctly inserted into a smoking article.
- the additive release component may be held in the support structure by a friction fit, the inner diameter of the support structure being no greater than the outer diameter of the additive release component as they are aligned when combined.
- additive release components may be inserted into a rod or tube which is to be slice or otherwise divided into sections to form individual support structures. Upon slicing or otherwise dividing the tube or rod, support structures are formed which are already associates with an additive release component.
- the additive release component may be anything which is capable of carrying an additive, and releasing the additive as and when required. Release may be induced in response to external force imparted on the smoking article, for example by the user's fingers, via the additive release component support structure.
- Additive release components may comprise an outer shell and a central core, wherein the additive is held in the central core.
- the outer shell may be frangible, plastically deformable, or resiliently deformable.
- the core may simply be a cavity in which the additive is held.
- the core may comprise a sponge-like material, an adsorbent material, or a gel material, in which the additive is held.
- the additive release component may comprise an outer shell and an inner core.
- the outer shell may be frangible, resiliently deformable, or plastically deformable.
- the smoking article comprises a capsule which is a capsule comprising an additive in a central core.
- the additive release component may comprise a sponge-like material (as shown in the accompanying Figure 10), an adsorbent material, a gel material, or any other suitable material.
- the additive may be released from the additive release component by any suitable means.
- force exerted on the additive release component by the user via the additive release component support structure may induce release of the additive.
- the force may be an external force, such as a compressive force exerted by the user squeezing the smoking article or support structure.
- Release of the additive may, for example, involve rupture of the additive release component, or alternatively, squeezing the additive from an additive release component comprising a porous or sponge-like material.
- the outer wall of the additive release component which may be made of gelatine, comprises an inner core filled with the additive.
- a spongelike material which may be compressible, may be used to carry the additive.
- the additive may be distributed within the sponge-like material, and optionally, absorbed by the sponge-like material, which may release the additive when compressed.
- a sponge-like material may be a body of absorbent material impregnated with the additive, which is progressively compressible and configured to release at least a part of the additive contents when partly compressed.
- the sponge-like material may comprise a matrix with a closed cell structure, in particular, a closed cell foam structure.
- the closed cell foam defines a matrix having a plurality of small cavities which may contain additive. The cavities are closed by the foam material, retaining the additive until selective release. On application of a compressive force, the closed cell foam may be configured to release additive.
- the closed cell foam substrate does not require an outer shell to retain the additive, and so may form the additive release component without an outer shell.
- the additive release component may alternatively comprise a coating on the surface of the sponge-like material, which may form an outer shell encompassing the sponge-like material. This outer material may function to retain the additive within the sponge-like material until release of the contents is desired, at which time, external force exerted by the user via the support structure may rupture the outer shell and squeeze the additive from the sponge-like material.
- the additive release component may be a porous material which is capable of carrying an additive.
- This material may be, for example, an adsorbent material, or a gel material.
- the additive release component support structure may comprise a plurality of additive release components, which may be similar or different additive release components.
- the support structure may induce the actuation of all of the additive release components by a single actuating mechanism, or alternatively, the support structure may be designed to carry additive release components which are independently actuatable by means of separate actuation mechanisms of the support structure.
- multiple additive release components may contain similar or a combination of different additives.
- the plurality of additives may chemically react, for example, to produce an exothermic or endothermic reaction.
- the additives could be an organic acid and an alcohol which react to form an ester.
- the additive release component may be an entirely separate entity to the additive release component support structure, or may comprise an integral part of the support structure.
- part of the support structure may be manufactured to comprise a sealed chamber which serves as an additive release component and contains the additive.
- the size and shape of the additive release component may be determined on the basis of the dimensions of the support structure with which the additive release component is to be used.
- the size of the additive release component may also be dependent on the volume of additive required. Consideration may be given, however, to the fact that the presence of the additive release component in the filter should maintain acceptable filtration or draw characteristics of the filter.
- the additive release component may be within the range 0.1mm to 12mm in length, and more preferably between 2mm and 5mm in length.
- the additive release components may be of the same or of different sizes.
- the additive release component may be formed in a variety of physical formations.
- the additive release component may be a capsule which may be a singular part or multipart capsule, a large capsule, a small capsule, a microcapsule, etc.
- a number of different additive release component configurations may be suitable, for example, the additive release component may be generally spherical (as described in respect of the preferred embodiments), ovoid, ellipsoidal, cylindrical, or may have any other shape.
- the support structure reduces the compressive force required to cause release of the additive from the additive release component compared to the force required to release the additive from the same additive release component in the absence of the support structure.
- the support structure may be used with an additive release component which cannot be manually compressed to release the additive in the absence of the support structure, but can be manually compressed to release the additive in the presence of the support structure.
- an additive release component may, for example, comprise an outer shell comprising a hard material which cannot be ruptured by the application of compressive force in the absence of the support structure, but can be ruptured by the application of compressive force in the presence of the support structure.
- a compressive force of greater magnitude would need to be applied by the user of the smoking article to initiate rupture and/or deformation of the outer shell of the additive release component compared to the compressive force that would be required in the presence of the support structure.
- the additive release component is actuated by the additive release component support structure, it may, in some embodiments, be more robust than additive release components that have been used previously in smoking articles. This is because force exerted by the user's fingers is focused by the additive release component support structure on a small area of the additive release component, which increases the intensity of the force on the additive release component.
- Conventional capsules which are incorporated into a smoking article filter without a support structure generally have a crush strength no greater than 2.3kp in order to ensure that the capsule is sufficiently frangible to enable the consumer to break the capsule without requiring the application of excessive pressure when squeezing the filter.
- Conventional capsules with crush strengths no greater than 2.1 kp, or no greater than 1.9 kp may be preferred for the same reason.
- 1 kp is a unit of force equal to 1 kilogramme-force, which is approximately 9.8 Newtons (N).
- the additive release component support structure facilitates the release of the additive from the additive release component, preferably reducing the compressive force than must be applied. Therefore, in some embodiments of the present invention, the additive release component support structure may be used with additive release components having a crush strength of greater than 2.5 kp, greater than 2.6 kp, greater than 2.7 kp, greater than 2.8 kp, greater than 2.9 kp or greater than 3 kp-
- the crush strength referred to herein refers to the initial crush strength Ci of the additive release component as measured before smoking (in a dry state), by
- the additive release component support structure may comprise a protrusion, projection, point, a tapered edge, or other tapered projection or region having a small surface area, which upon actuation of the support structure, contacts the additive release component.
- external pressure applied to the support structure may be focused on a small region of the surface of the additive release component.
- the support structure may directed the force radially though the centre of the capsule, thus localising the force over a small area for piercing rupture, maximising ease of rupture.
- the support structure increases the compressive force required to cause release of the additive from the additive release component compared to the force required to release the additive from the same additive release component in the absence of the support structure.
- the additive release component support structure also facilitates the use of additive release components that are less robust than those that it has previously been possible to use in smoking articles. This is because the additive release component is protected from accidental actuation and/or damage due to its being supported within the support structure.
- the minimum crush strength of the capsule should generally be at least o.skp so that the capsule is sufficiently robust to resist being prematurely or accidentally crushed during the manufacture of the cigarette.
- the additive release component support structure may be used with additive release components having a crush strength of less than 0.5 kp, less than 0.25 kp or less than o.2kp may be used.
- additive release component support structure permits the use of a much broader range of potential additive release component actuation tolerances than was previously possible.
- Additive release components may be used having a crush strength of between 0.1 kp and 3kp.
- Additive release components may be used which have a point of weakness in the area at which the additive release component support structure makes contact with the additive release component. This regional additive release component resilience may be achieved in a number of ways.
- the additive release component may be a capsule which is elliptical or ovoid and consequently demonstrate an increased resistance to rupture when force is exerted in one direction versus another.
- an additive release component which has been specifically strengthened in certain areas.
- Such an additive release component may be, for example, an additive release component having an increased shell thickness in selected areas.
- a similar effect may be achieved by weakening the additive release component wall in certain areas.
- the additive release component may be a double-layered component.
- the additive release component may be a capsule that is further encapsulated in a second encapsulating layer, or a sheath, or the like. This may allow greater protection from accidental or premature actuation or breakage, or incidental leakage.
- single wall or multi-wall additive release components may be used to tailor stability, strength, rupture resistance, processing ease in filter making, etc.
- the additive release component support structure has particular structural features, such as arms 12, flanges 25, or a strut 32, which are designed to receive the additive release component.
- the additive release component support structure does not have any particular design features to receive the additive release component.
- the additive release component may simply be adhered to a portion of the inside surface of the support structure.
- the additive release component is not adhered, but is retained within the additive release component support structure by some other means, for example, due to being trapped within the support structure between two filter sections of a composite filter.
- the additive release component is a capsule which is
- the additive release component is composed of a low solubility, high molecular weight polyvinyl alcohol.
- suitable alternative materials are known, and by way of example, additive release components typically utilized in the pharmaceutical industry may be used.
- additive release components may be gelatin based, for example, or may be formed from a polymeric material, such as modified cellulose.
- modified cellulose One type of modified cellulose which may be used is hydroxypropylmethyl cellulose.
- biodegradable materials which may be suitable for use in the production of additive release components and these include high molecular weight polyethylene glycols, polylactic acid, plastarch material, polycaprolactone, polyglycolide, a polyhydroxyalkanoate such as poly-3- hydroxybutyrate, and zein-derived bioplastics.
- the additive release component may comprise a hollow foodstuff material, such as, for example, pasta, or extruded hollow tubing of reconstituted tobacco material.
- the inner walls of the additive release component material may advantageously be coated with a varnish or waterproof material, such as silicone, to preserve the rigidity of the additive release component material by preventing absorption of, or degradation by, the liquid contents over a prolonged period.
- the additive release component may alternatively be comprised of a wax, resin, natural or synthetic gum, latex or plastic material which retains its shape and strength at room temperature and at smoking temperature but which is rupturable upon action of the additive release component support structure.
- suitable waxes include beeswax, candelilla, carnauba, shellac wax, caranday, sugarcane wax, myrtle wax and petroleum wax.
- Suitable resins include epoxy resins, terpene resins, petroleum resins, ester gum, phenolic resins and rosin based resins.
- Preferred gums include gum arabic, locust bean, guar, alginates, carrageenan and pectin.
- any suitable sponge-like material may be used.
- the sponge-like material may be a foamed material, which may be a foamed plastic polymer such as polyvinyl alcohol (PVOH).
- the additive release component may be coloured.
- the additive release component may comprise a colouring agent.
- the colouring agent may be used to render more easily the location of the additive release component and additive release component support structure within the filter during the manufacturing process.
- the colouring agent may provide an interesting and attractive appearance to the smoking article, particularly if the additive release component support structure or structures are intended to be only partially enclosed within the filter material, or if the tipping paper is intended to have a transparent window portion. If a coloured additive release component is to be used, it may be used in combination with a colourless transparent support structure. Alternatively or in addition, the additive held in the additive release component may be coloured. This may give the user an additional, visual indication that the additive has been successfully released, as the additive may be seen to migrate out of the additive release component. This may be particularly useful if the additive release component comprises a combination of additives, wherein one of the additives is coloured, and thereby serves to indicate release of the other, colourless, additive(s).
- the additive When the additive is coloured, it may be desirable for the support structure to assist the directional release of additive into a region of the smoking article or smoking article filter in which the colour will be observed.
- the additive may be
- the coloured additive may be directionally released into a section of the smoking article that is visible via a transparent window portion.
- the additive release component may be manufactured using any suitable method, the method of manufacture of the additive release component being dependent on the precise composition and make-up required. Suitable methods of additive release component manufacture may include techniques such as co-extrusion, spin coating, coacervation, interfacial polymerization, solvent evaporation, and annular jet forming.
- the capsule may be produced using a co-extrusion process.
- the co-extrusion process is a synchronous extrusion of the two liquids that will subsequently form the shell and the capsule contents (or "core"), which in this case is the additive.
- the first (co-extrusion) step involves forming a droplet having the liquid additive inside the liquid shell material.
- the "capsule" is solidified by cooling or by immersion in a curing agent, for example.
- the capsules may then be subjected to various treatments, such as washing, removal of surplus liquid, colouring, application of additional coatings, etc.
- annular jet forming technique may be used. This method utilises two concentric jets to eject an inner jet of liquid core material and an outer jet of liquid shell material.
- the fluid stream breaks into droplets and the liquid shell material solidifies by phase transition induced by the presence of cross-linking ions, pH differences, temperature changes, etc.
- the capsule may be formed, for example, by a method comprising freezing a solution of the liquid core material until small crystals are formed. According to this method, the crystals are then dropped into molten wax and removed by spatula after a wax coat has formed around the cold crystals. The frozen core material gradually becomes liquid as the coated capsule reaches room temperature.
- Foamed sponge-like materials may be made using a foamed extrusion process.
- the additive held within the additive release component may be a flavourant, deodoriser, adsorbent, diluent or any other substance that is capable of modifying the smoke.
- the additive may be menthol or water.
- the terms "flavour” and “flavourant” refer to materials which, where local regulations permit, may be used to create a desired taste or aroma in a product for adult consumers. They may include extracts (e.g., licorice, hydrangea, Japanese white bark magnolia leaf, chamomile, fenugreek, clove, menthol, Japanese mint, aniseed, cinnamon, herb, wintergreen, cherry, berry, peach, apple, Drambuie, bourbon, scotch, whiskey, spearmint, peppermint, lavender, cardamon, celery, cascarilla, nutmeg, sandalwood, bergamot, geranium, honey essence, rose oil, vanilla, lemon oil, orange oil, cassia, caraway, cognac, jasmine, ylang-ylang, sage, fennel, piment, ginger, anise, coriander, coffee, or a mint oil from any species of the genus Mentha),
- extracts
- the flavour may be a tobacco flavour. Where the flavour is delivered in liquid form, the tobacco flavour could be derived from tobacco extract. Where the additive is in solid form, the additive may be tobacco leaf or reconstituted tobacco material in shredded, particulate or granular form.
- the additive may be a solid, such as a powder, a liquid, such as a liquid flavourant, deodoriser, water, etc, or a gas, such as an aromatic composition.
- the additive may be an adsorbent which may be in granular, powdered, particulate, or any other suitable form. In this case, the adsorbent material preferably has particle sizes of less than 5 ⁇ and preferably less than ⁇ . More preferably the adsorbent material has a mean particle size of less than 5 ⁇ . The particle size is considered to be the diameter of the particle. In some embodiments, the adsorbent material has a particle size or mean particle size of 2 ⁇ -7 ⁇ .
- the adsorbent material is selected from a group of relatively high surface area materials.
- the material may have a high or a low specificity for particular smoke constituents.
- Suitable adsorbents include carbon, activated carbon, activated charcoal, activated coconut carbon, activated coal-based carbon or charcoal, zeolite, silica gel, sepiolite, clay, aluminium oxide (activated or not), carbonaceous resin or combinations thereof.
- the adsorbent material is carbon and more preferably is activated carbon or charcoal.
- activated coconut carbon is used.
- An example of a suitable coal-based charcoal is one made from semi-anthracite coal with a density about 50% greater than coconut-based charcoal (available from Calgon Carbon, Pittsburgh, PA, WA).
- a suitable carbonaceous resin is one derived from the pyrolysis of sulphonated styrene-divinyl benzene, such as Ambersorb 572 or Ambersorb 563
- adsorbent material may be used as a single substance or a mixture, and/ or may be in admixture with other material.
- the filter may comprise a composite filter, and in this case, one of the filter sections, such as a mouth end, central, or tobacco rod end filter section may comprise a support system.
- the filter may comprise a plurality of support structures, for example the filter may comprise 2, 3, 4, 5, or 6 support structures.
- the filter may comprise an indicator to indicate the area or areas of the filter on which force should be applied in order to actuate the support structure.
- the support structure is aligned perpendicularly to the longitudinal axis of the smoking article into which it is inserted, and the support structure substantially fills the cross-section of the filter.
- the combination of the support structure and additive release component includes pathways through which airflow is possible, thus providing a pathway for smoke and an ventilating air to pass through, preferably without adversely affecting pressure drop.
- the support structure may induce the release of additive into the filter in any specific direction.
- the direction may be predetermined by the shape and structure of the additive release component and/or support structure.
- the additive may be directionally released towards a particular region of the filter.
- the region may be, for example, a cavity, or a particular region of filter material, such as a peripheral region of the smoking article filter.
- the region into which the additive is released may comprise an active component, such as a second additive, which may or may not be held by an additive release component.
- the filter may comprise a composite filter.
- the filter may comprise a means of indicating the area of the filter on which force should be applied in order to actuate the support structure.
- the support structure may have a surface that is detectable through any layers of wrapping of the smoking article, and/or the smoking article surface may comprise a printed graphic or other visual indication.
- the support structure may be visible within the smoking article via a window in the filter plugwrap and tipping papers.
- the additive release component support structure is situated within a composite filter, for example between two sections of filter material.
- the filter sections comprise a mouth end section and a section at the smokeable material end of the filter.
- the additive release component support structure may be situated in the centre of the filter, that is, the two sections of filter material may be of equal size.
- the support structure may be situated away from the centre, towards one or other end of the filter.
- the filter may simply be a dual filter comprising a support structure and a section of filter material at the mouthpiece end.
- the filter is attached to the rod of smokeable material by means of a tipping paper in a known manner. If a non-transparent tipping paper is used, then the filter may comprise a means of indicating the position of the additive release component support structure and the area in which force should be applied in order to actuate the support structure.
- the orientation in which the additive release component is inserted into the smoking article or smoking article filter should be controlled.
- the smoking article may comprise one or more additive release components that are arranged to directionally release additive towards a particular region of the smoking article or smoking article filter, which may be any region of the smoking article or smoking article filter.
- This region may comprise a material which is activated by the additive released from the additive release component.
- this material may comprise a solid that is active when in solution, and is thus activated by the action of additive in the form of water or a specific solvent.
- the target region of directional additive release may be a cavity within the centre of the filter, which may or may not comprise other active materials.
- the cavity may comprise crystalline flavourant, which may be activated when additive in the form of a solvent is directionally released into the cavity to contact the crystals.
- the cavity may comprise a material which is sensitive to additive in the form of water, for example, a material which in contact with water changes colour, dissolves, makes a sound, emits a flavour or an odour, etc.
- the particular region to which additive is directed may be a region of filter material comprising a solid material in the form of small granules evenly distributed within the material.
- Such an arrangement may be useful, for example, when a granular crystalline flavourant is to be used in combination with an additive release component comprising a solvent additive.
- a plurality of additive release components may be used, from which additive may be sequentially released to provide flavourant over the duration of use of the smoking article.
- additive may be directed into the same or different regions of the granule-containing filter material.
- the region to which additive is directed may be a peripheral region of the smoking article or smoking article filter, such as a region at or near the circumferential surface of the smoking article, or at the mouth end of the filter.
- Such an arrangement may be suitable, for example, when the additive is coloured, to provide an interesting appearance to the smoking article, and/or to provide a visual indication that the additive has been released, for example, where the additive release component comprises a combination of coloured and colourless additives.
- This arrangement may also be suitable when the additive is an odorant, to facilitate diffusion of the odour out of the smoking article.
- a smoking article or smoking article filter may comprise two or more additives, each carried within a separate additive release component, which may be carried in similar or separate support structures. This arrangement may be suitable, for example, when the two or more additives chemically react, or where the additives are subject to oxidation, diffusion, or other means of loss of intensity over time.
- the two or more additive release components may be arranged to directionally release additive towards each other. Such an arrangement may be useful, for example, where the additives chemically react, such as to produce an exothermic or endothermic reaction, or a reaction in which an odour or a gas is evolved, or a colour or other visual effect is produced.
- the two or more additive release components may be arranged to directionally release additive towards a common region of the filter. This may be suitable where a significant quantity of additive is required to be supplied to a particular region of the filter, for example, where the additive is water, and the target region of the filter comprises a water sensitive material, such as a water swellable, water soluble, or water degradable material.
- the filter comprises a transparent window which allows visualisation of the additive release component support structure and/or additive release component within the filter. In this way the user is able to visualise the additive release component within the filter, and may be able to visually determine whether the additive has been released.
- a transparent window may be provided in a filter plug wrap and/or tipping paper.
- the window may extend around the entire circumference of the smoking article. It may be restricted to the area where the support structure and additive release components are located, so that just these are visible. Alternatively, the window may be larger, so that adjacent parts of the smoking article, such as adjacent plugs of filter material are at least partially visible.
- the support structure may be transparent or translucent, or comprise a transparent or translucent section to enable the user to see the additive release component.
- the relevant part of the smoking article may comprise a means of indicating the area of the smoking article on which force should be applied in order to actuate the support structure.
- the support structure may have a surface that is detectable through any layers of wrapping of the smoking article, and/or the smoking article surface may comprise a printed graphic or other visual indication.
- the tipping paper may comprise a single piece of transparent material, which can be, but is not limited to, one of polypropylene, polyvinyl chloride (PVC), cellulose acetate film, polyethylene terephthalate (PET), polyethylene oxide (PEOX), polyethylene, cellophane, NatureflexTM, polylactic acid, plastarch material, polycaprolactone, polyglycolide, a polyhydroxyalkanoate such as poly-3-hydroxybutyrate, and zein-derived bioplastics.
- the tipping paper may have an opaque coating on certain portions to leave a transparent uncoated section which defines the window.
- the filter sections may be formed as separate sections of filtration material wrapped in a porous sheet material.
- the filter sections and the additive release component support structure are preferably not directly connected to each other, but rather are connected only by the means of a wrapping paper, or indeed by the tipping paper.
- Figures lA and iB show an additive release component support structure 10 according to a first embodiment.
- An additive release component 11 is positioned within the additive release component support structure 10.
- the additive release component is a frangible spherical capsule containing an additive.
- the additive release component support structure 10 is generally in the form of a hollow cylinder.
- the circumference of the cylinder matches or is slightly smaller than that of the smoking article filter in which the support structure is to be used.
- Projecting into the central cavity of the cylinder are three arms 12. As shown in Figure iB, the ends of the arms facing the centre of the support structure are shaped to receive the capsule 11.
- the additive release component support structure 10 comprises in the circumferential surface, two weakened sections 13.
- the weakened sections of the additive release component support structure are formed by means of the support structure having a reduced thickness in these regions.
- rupture of the capsule 11 is aided by means of a pointed projection 15 situated on the inner surface of the deformable section 14.
- a pointed projection 15 situated on the inner surface of the deformable section 14.
- FIG 3 shows an exploded view of a smoking article comprising an additive release component support structure according to a first embodiment.
- the smoking article comprises a rod of smokeable material 16, and a filter 17.
- the filter 17 is a triple filter arrangement, in which the support structure 10 is situated between two sections of cellulose acetate filter material 18 and 19.
- the support structure 10 comprises an additive release component 11, which in this case is a frangible capsule.
- the filter sections are combined to form the filter 17 by means of a plugwrap (not shown), and attached to the rod of smokeable material 16 by means of a tipping paper (not shown) in a known manner.
- Figures 4A and 4B show an additive release component support structure 20 according to a second embodiment.
- An additive release component 21 is positioned within the additive release component support structure 20.
- the additive release component is a frangible spherical capsule containing an additive.
- the outer circumference of the additive release component support structure 20 matches or is slightly smaller than that of the smoking article filter in which the support structure is to be used.
- the support structure 20 has the form of a ring or hollow cylinder having a number of axial corrugations 22. In the embodiment shown, the support structure has 8 corrugations. In other embodiments, the support structure may have between 2 and 16 corrugations. For example, the support structure may have 3, 4, 5, 6, 7, 9, 10, 11, 12, 13, 14, or 15 corrugations.
- the corrugations are in the form of axial grooves 23.
- the corrugations On the inner surface of the support structure, the corrugations have tapered ends 24, which project into the central core of the support structure 20.
- an additive release component 21 may be positioned within the centre of the additive release component support structure 20.
- the ends of the projections 24 are shaped to receive the additive release component 21.
- the distance between the tapered ends of opposing projections 24 is greater than the diameter of the capsule 21.
- the capsule is retained within the additive release component support structure by means of flanges 25 on the projections 24.
- the axial corrugations 22 reduce the rigidity of the additive release component support structure 20, particularly in response to laterally applied force, applied to the additive release component support structure in any lateral direction.
- the additive release component support structure 20 deforms from an approximately circular into a more elliptical cross- sectional shape.
- embodiment is not predefined, but is determined by the location at which force is applied to the support structure.
- FIG. 5 shows an exploded view of a smoking article comprising an additive release component support structure according to the second embodiment.
- the smoking article comprises a rod of smokeable material 26, and a filter 27.
- the filter 27 is a triple filter arrangement, in which the additive release component support structure 20 is situated between two sections of cellulose acetate filter material, 28 and 29.
- the additive release component support structure 20 comprises an additive release component 21.
- the filter sections are combined to form the filter 27 by means of a plugwrap (not shown), and attached to the rod of smokeable material 26 by means of a tipping paper (not shown) in a known manner.
- force exerted on the filter 27 in the region of the additive release component support structure 20 in any lateral direction, by the user causes deformation of the support structure, as described above, and rupture of the capsule 21.
- the additive carried by the capsule is released, and may be entrained in the smoke that is drawn through the filter by the user.
- Figures 6A and 6B show an additive release component support structure 30 according to a third embodiment.
- An additive release component 31 is positioned within the additive release component support structure 30.
- the additive release component is a frangible spherical capsule containing an additive.
- the outer circumference of the additive release component support structure 30 is not in the form of a complete circle, but rather has the form of a circular arc or 'C-shape'.
- the support structure 30 is generally in the form of a hollow cylinder that is missing a section of the circumferential surface.
- the additive release component support structure 30 of the third embodiment is similar to the support structure 10 of the first embodiment.
- the circumference of the cylinder matches or is slightly smaller than that of the smoking article filter in which the support structure is to be used.
- the capsule fits within the central cavity of the cylinder and is held in position by means of a strut 32 and a thickened wall section 33. As shown in Figure 6B, one end of the strut 32 and the thickened wall section 33 are joined to form a base which is shaped to receive the capsule 31.
- the additive release component support structure 30 comprises in the circumferential surface, a weakened section 34.
- the weakened section 34 separates the section of the support structure which retains the capsule (comprising the strut 32 and thickened wall section 33) from a deformable section of the additive release component support structure which has the form of a hinged arm 35.
- the weakened section 34 functions as a hinge or pivot about which the hinged arm 35 is able to move relative to the section of the additive release component support structure which retains the capsule.
- Rupture of the capsule 31 is aided by means of a pointed projection 36 situated on the inner surface of the hinged arm 35.
- a pointed projection 36 situated on the inner surface of the hinged arm 35.
- FIG 8 shows an exploded view of a smoking article comprising an additive release component support structure according to the third embodiment.
- the smoking article comprises a rod of smokeable material 37, and a filter 38.
- the filter 38 is a triple filter arrangement, in which the additive release component support structure 30 is situated between two sections of cellulose acetate filter material 39 and 40.
- the additive release component support structure 30 comprises an additive release component 31, which in this case is a frangible capsule.
- the filter sections are combined to form the filter 38 by means of a plugwrap (not shown), and attached to the rod of smokeable material 37 by means of a tipping paper (not shown) in a conventional manner.
- Smoking article filters may comprise 2 or more additive release component support structures, such as 3, 4, 5, or 6 support structures.
- the additive release component carried by each support structure may comprise the same or different additives, and may be of the same or different sizes.
- the support structures may require the same or different forces to be exerted by the user in order to be actuated. This provides the user with the ability to control the degree of additive released as required.
- the support structures may be of the same design, or of different designs. For example, different designs may be used if different forces are to be required for additive release component actuation.
- Figure 9 shows an exploded view of a smoking article according to a fourth
- the smoking article comprises a rod of smokeable material 41, and a filter 42.
- the filter 42 comprises two additive release component support structures 43 of the type described above in respect of the second embodiment.
- Each support structure comprises an additive release component 44, which in this case is a frangible capsule.
- the support structures 43 are situated between two sections of cellulose acetate filter material 45 and 46. The filter sections are combined to form the filter 42 by means of a plugwrap (not shown), and attached to the rod of smokeable material 41 by means of a tipping paper (not shown) in a conventional manner.
- FIG. 10 shows a smoking article 50 comprising a cylindrical rod of smokeable material, in this case tobacco 51, and a filter 52.
- the filter 52 is wrapped in a plugwrap (not shown).
- the rod of smokeable material 51 is aligned with the filter 52 such that the end of the tobacco rod 51 abuts the end of the filter 52.
- the rod is wrapped in a paper wrapper (not shown), and is joined to the filter 52 by tipping paper (not shown) in a
- the filter 52 is a triple filter comprising two substantially cylindrical plugs of filter material 53, separated by an additive release component support structure 54 according to a fifth embodiment.
- An additive release component 55 is positioned within the support structure 54.
- the additive release component 55 is a sponge-like material containing an additive.
- the sponge-like material is coated in a frangible outer shell.
- the additive release component support structure 54 is generally in the form of a hollow cylinder.
- the circumference of the cylinder matches or is slightly smaller than that of the smoking article filter 52.
- Projecting into the central cavity of the cylinder, and dividing the cavity into three equal sectors are three support struts 56. As shown in Figure 10, each of the sectors is arranged to receive an additive release component 55.
- the additive release component support structure 54 comprises in the inner circumferential surface, at the centre of each of the three sectors, a spike 57.
- Figures 11A shows a cross section of a smoking article comprising an additive release component support structure 60 according to a sixth embodiment.
- An additive release component 61 is positioned within the additive release component support structure 60.
- the additive release component is a frangible spherical capsule containing an additive.
- the additive release component support structure 60 is substantially the same as that shown in respect of the first embodiment. The only difference is that the present additive release component support structure 60 has no deformable section and does not deform under the application of external force.
- the additive release component support structure 60 is generally in the form of a hollow cylinder.
- the circumference of the cylinder matches or is slightly smaller than that of the smoking article filter 63 in which the support structure is to be used.
- the ends of the arms facing the centre of the support structure are shaped to receive the capsule 61.
- the support structure 10 of the first embodiment comprises in the
- the present support structure 60 has a gap 64, as indicated in Figure 11B.
- the additive release component 61 is not fully enclosed by the support structure 60.
- external force exerted is on the additive release component support structure 60 at the location of the gap 64, in the direction of arrows B. This force pushes the additive release component 61 against the arms 62 of the support structure 60. As a result, the capsule, which is held in place by the arms 62 of the support structure, is crushed.
- Rupture of the capsule 61 is aided by means of a pointed projection 65 situated on the end of the arm 62 opposite the gap 64. Due to the presence of the pointed projection, force exerted on the capsule is concentrated over a small area, increasing the ease with which the capsule is ruptured.
- Figures 12A to 12C show various embodiments in which the support structure is a fluted tube.
- the figures illustrate a few of the possible fluted cross-sectional shapes.
- the fluting is rounded in Figure 12A, angular in Figure 12B and square or castellated in Figure 12C.
- the support structures of Figures 4A, 4B and 12A-12C can be described as a petaloid shape having a plurality of joined petals or lobes.
- Each petal or lobe includes a radially outward segment and two generally radial segments.
- the radially outward segment has a radially outward surface that is adapted to contact the inner cylindrical surface of the smoking article, and an opposing radially inner surface.
- the radially outward surface has first and second ends, each of which are attached to a radially outward end portion of one of the generally radial segments.
- Each generally radial segment, as illustrated, includes the aforementioned radially outward end portion and a radially inward end portion.
- the radially inward end portions of each petal or lobe is attached to the radially inward end portion of an adjacent petal or lobe.
- the support thus can act to grasp and retain an additive release component by being radially expanded slightly.
- support structures including those illustrated in Figures 12A to 12C may manufactured by extrusion and are then cut to length.
- the support structures may be produced by suitable techniques including, for example, blow moulding, injection moulding, 3D printing and the use of Rotary Dies may be used. A combination of techniques may be used. These techniques are especially useful for manufacturing the intricate structures such as those illustrated in Figures 4A and 4B.
- additive release component support structures containing additive release components in the form of 3.4mm diameter macro-capsules were prepared. Filters of 27mm in length were prepared comprising an additive release component support structure situated between two cellulose acetate filter sections of 10mm and 12mm in length.
- the filters were then attached to tobacco rods in a conventional manner to produce standard king size test cigarettes.
- the additive release component support structures were depressed and the additive released from the macro-capsules. Bound pressure drop of the cigarettes was measured before and after actuation of the additive release component support structure, and the results are given in the table below.
- Embodiments of the invention are configured to comply with applicable laws and/or regulations, such as, by way of non-limiting example, regulations relating to flavours, additives, emissions, constituents, and/or the like.
- applicable laws and/or regulations such as, by way of non-limiting example, regulations relating to flavours, additives, emissions, constituents, and/or the like.
- the invention may be configured such that a smoking article implementing the invention is compliant with applicable regulations before release of an additive, after release of a first additive, and remains compliant after the release of one or more additional additives.
- the generated substance complies with applicable laws/regulations.
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Abstract
Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
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EP12721580.4A EP2706873A1 (en) | 2011-05-13 | 2012-05-11 | Support structure |
US14/116,990 US20140202479A1 (en) | 2011-05-13 | 2012-05-11 | Support structure |
BR112013029365A BR112013029365A2 (en) | 2011-05-13 | 2012-05-11 | smoking article and method for manufacturing a smoking article |
RU2013155217/12A RU2596465C2 (en) | 2011-05-13 | 2012-05-11 | Bearing element |
MX2013013251A MX346812B (en) | 2011-05-13 | 2012-05-11 | Support structure. |
JP2014509831A JP5901745B2 (en) | 2011-05-13 | 2012-05-11 | Support structure |
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GBGB1108057.9A GB201108057D0 (en) | 2011-05-13 | 2011-05-13 | Support structure |
GB1108057.9 | 2011-05-13 |
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WO2012156695A1 true WO2012156695A1 (en) | 2012-11-22 |
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PCT/GB2012/051039 WO2012156695A1 (en) | 2011-05-13 | 2012-05-11 | Support structure |
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US (1) | US20140202479A1 (en) |
EP (1) | EP2706873A1 (en) |
JP (1) | JP5901745B2 (en) |
AR (1) | AR086375A1 (en) |
BR (1) | BR112013029365A2 (en) |
CL (1) | CL2013003254A1 (en) |
GB (1) | GB201108057D0 (en) |
MX (1) | MX346812B (en) |
RU (1) | RU2596465C2 (en) |
TW (1) | TW201306761A (en) |
WO (1) | WO2012156695A1 (en) |
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2018007561A1 (en) * | 2016-07-07 | 2018-01-11 | Philip Morris Products S.A. | Smoking article mouthpiece for receiving an insert unit |
CN108024572A (en) * | 2015-09-30 | 2018-05-11 | 菲利普莫里斯生产公司 | Aerosol generation product with dispersed spices |
WO2019034872A1 (en) * | 2017-08-16 | 2019-02-21 | British American Tobacco (Investments) Limited | Flavour system |
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CN108024572A (en) * | 2015-09-30 | 2018-05-11 | 菲利普莫里斯生产公司 | Aerosol generation product with dispersed spices |
US11019843B2 (en) | 2015-09-30 | 2021-06-01 | Philip Morris Products S.A. | Aerosol-generating article having dispersed flavourant |
US12075822B2 (en) | 2016-05-20 | 2024-09-03 | Nicoventures Trading Limited | Capsule for tobacco industry product |
US11632984B2 (en) | 2016-07-07 | 2023-04-25 | Philip Morris Products S.A. | Smoking article mouthpiece for receiving an insert unit |
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RU2745861C2 (en) * | 2016-07-07 | 2021-04-02 | Филип Моррис Продактс С.А. | Mouthpiece of the smoking article for positioning the inserted element |
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US12016996B2 (en) | 2016-09-14 | 2024-06-25 | Nicoventures Trading Limited | Receptacle section |
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US11910822B2 (en) | 2017-10-25 | 2024-02-27 | British American Tobacco (Investments) Limited | Filter for a smoking article or an aerosol generating product |
US11623053B2 (en) | 2017-12-06 | 2023-04-11 | Nicoventures Trading Limited | Component for an aerosol-generating apparatus |
EP3729977A4 (en) * | 2017-12-22 | 2021-07-21 | Japan Tobacco Inc. | Smoking article, and smoking article filter |
Also Published As
Publication number | Publication date |
---|---|
US20140202479A1 (en) | 2014-07-24 |
JP2014513538A (en) | 2014-06-05 |
RU2596465C2 (en) | 2016-09-10 |
RU2013155217A (en) | 2015-06-20 |
TW201306761A (en) | 2013-02-16 |
BR112013029365A2 (en) | 2017-01-31 |
MX346812B (en) | 2017-03-31 |
CL2013003254A1 (en) | 2014-07-25 |
MX2013013251A (en) | 2014-02-27 |
JP5901745B2 (en) | 2016-04-13 |
AR086375A1 (en) | 2013-12-11 |
EP2706873A1 (en) | 2014-03-19 |
GB201108057D0 (en) | 2011-06-29 |
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