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WO2012060241A1 - Composition cosmétique pour les cheveux - Google Patents

Composition cosmétique pour les cheveux Download PDF

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Publication number
WO2012060241A1
WO2012060241A1 PCT/JP2011/074462 JP2011074462W WO2012060241A1 WO 2012060241 A1 WO2012060241 A1 WO 2012060241A1 JP 2011074462 W JP2011074462 W JP 2011074462W WO 2012060241 A1 WO2012060241 A1 WO 2012060241A1
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WO
WIPO (PCT)
Prior art keywords
hair
agent
cosmetic composition
acid
hair cosmetic
Prior art date
Application number
PCT/JP2011/074462
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English (en)
Japanese (ja)
Inventor
祐貴 笹尾
奈美子 藤城
育三 石河
Original Assignee
ホーユー株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ホーユー株式会社 filed Critical ホーユー株式会社
Publication of WO2012060241A1 publication Critical patent/WO2012060241A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/342—Alcohols having more than seven atoms in an unbroken chain
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/10—Preparations for permanently dyeing the hair

Definitions

  • the present invention relates to a hair cosmetic composition. More specifically, the present invention relates to a hair cosmetic composition in which the first agent contains potassium carbonate, a higher alcohol, and a cationic surfactant.
  • carbonates are known as alkali agents for imparting lightness to hair while reducing irritating odors in hair dyes.
  • the formulation stability such as liquid / liquid separation, white turbidity, or separation of the emulsion during storage of the hair dye.
  • the inventor of the present application firstly shows that even if the same carbonate is used, potassium carbonate and sodium carbonate have different effects on formulation stability, and secondly, potassium carbonate, It was found that the stability of the preparation was improved only by containing a higher alcohol and a cationic surfactant. It was also found that the hair cosmetic composition containing potassium carbonate, a higher alcohol and a cationic surfactant is a hair cosmetic composition that imparts good lightness to the hair.
  • an object of the present invention is to provide a hair cosmetic composition that is excellent in formulation stability and imparts good lightness to hair even when carbonate is added.
  • the composition of the first invention of the present application for solving the above problems is a hair cosmetic composition that is configured as a hair dye or a hair bleaching agent and is applied to hair by mixing the first agent and the second agent at the time of use.
  • the hair cosmetic composition contains the following components (A) to (C) in the first agent.
  • the first invention provides a hair cosmetic composition that is excellent in formulation stability and imparts good lightness to hair.
  • the hair cosmetic composition according to the first invention can impart good lightness to the hair as in the case of using sodium carbonate. And it is a hair cosmetic composition excellent in formulation stability.
  • potassium carbonate exhibits a markedly advantageous formulation stability compared to sodium carbonate.
  • Patent Documents 1 to 4 do not disclose the problem itself of improving formulation stability, and therefore, in the examples of the document, a composition containing all three components of potassium carbonate, higher alcohol and cationic surfactant. There was no disclosure of things.
  • Potassium carbonate is highly soluble in the base and can be used in a wide range of dosage forms such as liquid and cream. Furthermore, even when a large amount of a surfactant is contained, liquid / liquid separation, white turbidity, or separation of emulsions hardly occurs.
  • a hair cosmetic composition that is a hair dye, which makes the hair after dyeing hair that is easy to feel a bright color.
  • D When a component is mix
  • a hair cosmetic composition having a viscosity of less than 1000 mPa ⁇ s after mixing the first and second agents of the hair cosmetic composition.
  • it becomes a hair cosmetic composition suitable for making it into a foamy dosage form using a non-aerosol foamer container, maintaining the effect of the above-mentioned this invention.
  • the non-aerosol type uses a pump former, a squeeze foamer, or other non-aerosol foamer container to form air bubbles by using a pump former, a squeeze foamer, or the like, and makes the dosage form foamy. Therefore, the viscosity is preferably less than 1000 mPa ⁇ s, preferably 300 mPa ⁇ s or less, more preferably 100 mPa ⁇ s or less.
  • a hair cosmetic composition in which the dosage form when applied to hair is foamy can be mentioned. It is more preferable to use a hair cosmetic composition that satisfies the above viscosity conditions. According to the embodiment, it is easy to uniformly apply the hair cosmetic composition to the hair uniformly, and advantages such as eliminating the need for hair blocking during the use of gel-like or cream-like hair cosmetics, etc. Can be obtained.
  • a preferred embodiment of the present invention includes a hair cosmetic composition in which a foamy dosage form is formed by a non-aerosol foamer container. It is more preferable to use a hair cosmetic composition that satisfies the above viscosity conditions. According to the embodiment, a hair cosmetic composition capable of obtaining the advantages of a foamy dosage form without using a propellant is provided.
  • a hair cosmetic product comprising the hair cosmetic composition of the present invention and a non-aerosol foamer container for discharging the hair cosmetic composition in the form of foam may be mentioned.
  • the hair cosmetic composition of the present invention is more preferably a hair cosmetic composition that satisfies the above viscosity conditions.
  • a hair cosmetic product having the effect of the hair cosmetic composition of the present invention is provided. Since the hair cosmetic composition of the present invention is excellent in formulation stability, it is a hair cosmetic product that is easy to handle and suitable for distribution.
  • a method of using a hair cosmetic composition in which the hair cosmetic composition of the present invention is applied to hair by being ejected in a foam form from a non-aerosol foamer container is more preferably a hair cosmetic composition that satisfies the above viscosity conditions. According to the embodiment, a more preferable method of using the hair cosmetic composition of the present invention is provided.
  • the hair cosmetic composition according to the present invention applies a mixture of a first agent and a second agent to hair at the time of use.
  • the first agent contains (A) potassium carbonate, (B) a higher alcohol, and (C) a cationic surfactant.
  • the hair cosmetic composition is of a two-part type, but includes a composition in which the first agent and / or the second agent are further divided into a plurality of agents.
  • the mixing amount of the first agent and the second agent at the time of use is not particularly limited, and can be appropriately determined according to the properties of the hair cosmetic composition.
  • the hair dye is a concept including, for example, an oxidative hair dye.
  • the hair bleaching agent is a concept including, for example, a hair bleaching agent and a hair bleaching agent.
  • the dosage form of the first agent and the second agent in the two-part hair cosmetic composition is not particularly limited.
  • solid, aqueous solution, dispersed liquid, emulsion, gel, foam, and cream can be mentioned.
  • solid dosage forms include powder and tablets. In the case of a solid dosage form, it is preferably in a powder form from the viewpoint of excellent dispersibility when mixing the first agent and the second agent.
  • the dosage form of the first agent and the second agent is preferably an emulsion type, a solubilization type or a dispersion type.
  • it is preferably liquid, creamy or emulsion.
  • cream or foam is preferable, and foam is more preferable. Furthermore, it is preferable to make it foam using a non-aerosol foamer container.
  • foamer container can be achieved by appropriately using conventional methods.
  • foaming the dosage form at the time of application to hair use an aerosol foam container or non-aerosol foam container, or stir and / or shake in a suitable container, or manually or automatically It can also be made foamy by using a vertical vessel.
  • the dosage form at the time of application to hair is foamed, it is preferable that at least one of the first agent and the second agent contains water as a base for foaming.
  • the water content in that case is preferably 40% by mass or more, and more preferably 50% by mass or more.
  • the dosage form at the time of application to hair is foamed, it is preferable that at least one of the first agent and the second agent contains a nonionic surfactant.
  • Non-ionic surfactants have the property of producing bubbles that are difficult to defoam. Moreover, there is little irritation although it is a surfactant. In the present invention, even when a large amount of a nonionic surfactant is contained, liquid / liquid separation, white turbidity, or separation of an emulsion is hardly caused. In this case, the amount of the nonionic surfactant is preferably 10% by mass or more, and particularly preferably 11% by mass to 25% by mass.
  • the viscosity after mixing the first agent and the second agent is less than 1000 mPa ⁇ s, preferably 300 mPa ⁇ s or less, More preferably, it is 100 mPa ⁇ s or less.
  • the non-aerosol type uses a pump former, a squeeze foamer, or other non-aerosol foamer containers to form air bubbles by using a pump former, a squeeze foamer, or the like, and makes the dosage form foamy.
  • the viscosity is high, the hair cosmetic composition becomes difficult to move in the container, and as a result, it is difficult to foam.
  • the component (A) of the present invention is potassium carbonate (K 2 CO 3 ).
  • the content of the component (A) in the first agent of the present invention is preferably 0.01% by mass to 20% by mass, more preferably 0.05% by mass to 10% by mass, and further preferably 0.1% to 5% by mass.
  • the content of the component (A) is less than 0.01% by mass, the effect of imparting sufficient lightness to the hair may be insufficient, and even if it exceeds 20% by mass, the effect of the present invention is further increased. May not improve, that is, it may be disadvantageous in cost.
  • the component (B) of the present invention is a higher alcohol.
  • the higher alcohol of component (B) is not particularly limited as long as it has 10 to 30 carbon atoms, and the carbon skeleton portion may be linear, branched, cyclic, or a combination thereof, saturated. -Unsaturation is not limited.
  • cetyl alcohol cetanol
  • 2-hexyldecanol 2-octyldodecanol
  • stearyl alcohol isostearyl alcohol, cetostearyl alcohol, oleyl alcohol, aralkyl alcohol
  • behenyl alcohol lauryl alcohol
  • myristyl alcohol decyltetradecanol
  • lanolin alcohol And one or more selected from hydrogenated lanolin alcohol and the like.
  • it is at least one selected from myristyl alcohol, cetyl alcohol, stearyl alcohol, 2-hexyldecanol, and 2-octyldodecanol, which are saturated or unsaturated linear or branched higher alcohols.
  • the higher alcohol of the component is a component related to increase or decrease in the viscosity of the hair cosmetic composition. Therefore, the type and content of the higher alcohol can be appropriately determined according to the use of the hair cosmetic composition and the function required for the hair cosmetic composition.
  • the content of the higher alcohol in the first agent of the present invention is preferably 0.01% by mass to 15% by mass, and more preferably 0.1% by mass to 10% by mass.
  • Component (C) of the present invention is a cationic surfactant.
  • the cationic surfactant of a component is not specifically limited.
  • a surfactant that is an organic amine or a salt thereof, a surfactant that is a quaternary ammonium or a salt thereof, and the like are preferable.
  • lauryltrimethylammonium chloride cetyltrimethylammonium chloride (cetrimonium chloride), stearyltrimethylammonium chloride (steartrimonium chloride), alkyltrimethylammonium chloride, behenyltrimethylammonium chloride (behentrimonium chloride), distearyldimethylammonium chloride ( Distearyldimonium chloride), dicocoyl dimethyl ammonium chloride, cetyl trimethyl ammonium bromide, stearyl trimethyl ammonium bromide, ethyl lanolin sulfate fatty acid aminopropylethyl dimethyl ammonium, stearyl trimethyl ammonium saccharin, cetyl trimethyl ammonium saccharin, methyl behenyl trimethyl ammonium sulfate , And quaternium
  • One or more kinds selected from 1 and the like are preferable. More preferably, it is at least one selected from lauryltrimethylammonium
  • the content of the cationic surfactant as the component (C) of the first agent of the present invention is preferably 0.01% by mass to 10% by mass, and more preferably 0.1% by mass to 5% by mass.
  • the content of the component (C) is less than 0.01% by mass, the effect of imparting a good feel to the hair may be insufficient, and even when the content exceeds 10% by mass, the effect of the present invention is further increased. May not improve, that is, it may be disadvantageous in cost.
  • stimulation may become strong at the time of use of hair cosmetics composition.
  • the component (D) of the present invention is at least one selected from p-aminophenol and salts thereof.
  • the salt include hydrochloride, sulfate, acetate, and the like.
  • the hair cosmetic composition of this invention is not limited, For example, it is comprised as an oxidative hair dye, a hair bleaching agent, or a hair decoloring agent. Particularly preferably, it is configured as an oxidative hair dye or a hair bleaching agent.
  • the oxidative hair dye comprises a first agent containing an alkali agent and an oxidative dye and a second agent containing an oxidant, decomposes melanin in the hair, and results in oxidative polymerization of the oxidative dye by the oxidant. I do. Oxidative dyes are classified as dye intermediates and couplers. Instead of the oxidation dye, a direct dye such as a basic dye, a nitro dye, a natural dye, or a disperse dye may be blended.
  • the dye intermediate is not particularly limited as long as the effect of the present invention is not impaired.
  • phenylenediamines, aminophenols excluding component (D) toluylenediamine, diphenylamines, diaminophenylamines, N-phenyl
  • examples include phenylenediamines, diaminopyridines, and salts thereof.
  • the salts include hydrochloride, sulfate, acetate, and the like.
  • the dye intermediate it is preferable to use p-aminophenol or its salt as component (D) in combination with another dye intermediate.
  • a coupler is a compound that develops color by binding to a dye intermediate, and is contained in the first agent as necessary.
  • the coupler is not particularly limited as long as it does not inhibit the effect of the present invention.
  • resorcin pyrogallol, catechol, metaaminophenol, metaphenylenediamine, 2,4-diaminophenol, 1,2,4-benzenetriol, toluene- 3,4-diamine, toluene-2,4-diamine, hydroquinone, ⁇ -naphthol, 2,6-diaminopyridine, 1,5-dihydroxynaphthalene, 5-aminoorthocresol, paramethylaminophenol, 2,4-diamino
  • Examples include phenoxyethanol, gallic acid, tannic acid, ethyl gallate, methyl gallate, propyl gallate, pentaploid, 5- (2-hydroxyethylamino) -2-methylphenol and salts thereof.
  • the content of the dye intermediate in the oxidative hair dye is preferably 0.01 to 10% by mass, more preferably 0.1 to 5% by mass. If the content of the dye intermediate is less than 0.01% by mass, sufficient dyeability may not be obtained. Even if the content of the dye intermediate exceeds 10% by mass, the dyeability does not improve any more, and the economics of hair dyeing may be reduced.
  • the first agent is, for example, at least selected from the dyes other than the above-mentioned oxidation dyes selected from, for example, the oxidation dyes listed in Japanese “Quasi-drug raw material standards” (issued in June 2006, Yakuji Nippo), and direct dyes. You may contain 1 type suitably.
  • the alkali agent promotes the action of the oxidizing agent contained in the second agent and improves the dyeability by swelling the hair and improving the permeability of the dye into the hair.
  • potassium carbonate as the component (A) is essential for the hair cosmetic composition of the present invention.
  • the alkali agent that can be used in combination with the component (A) potassium carbonate is not particularly limited as long as it does not inhibit the effects of the present invention, and examples thereof include ammonia, alkanolamines, organic amines, inorganic alkalis, basic amino acids, and sulfates. It is done.
  • organic amines include 2-amino-2-methyl-1,3-propanediol and guanidine.
  • Examples of the inorganic alkali include sodium hydroxide, potassium hydroxide, ammonium carbonate, and ammonium hydrogen carbonate.
  • Examples of basic amino acids include arginine and lysine, and basic amino acid salts.
  • Examples of basic amino acid salts include ammonium salts.
  • Examples of the sulfate include ammonium sulfate.
  • Examples of the alkanolamine include monoethanolamine.
  • the content of the alkali agent is preferably such an amount that the pH is in the range of 7 to 12 in the oxidative hair dye in which the first agent and the second agent are mixed.
  • the pH is less than 7, when hydrogen peroxide as an oxidizing agent is contained in the second agent, the action of hydrogen peroxide may not be sufficiently promoted. If the pH during use exceeds 12, when the oxidative hair dye is applied to the hair, problems such as damage to the hair may easily occur.
  • the second agent contains at least an oxidizing agent.
  • the oxidizing agent develops a color by oxidative polymerization of an oxidation dye.
  • the oxidizing agent is not particularly limited as long as it does not inhibit the effect of the present invention.
  • Examples include hydrogen adducts.
  • the content of the oxidizing agent in the second agent is preferably 0.1 to 10.0% by mass, more preferably 0.5 to 8.0% by mass.
  • the content of the oxidizing agent is less than 0.1% by mass, it may be difficult to sufficiently oxidatively polymerize the oxidation dye.
  • the content of the oxidizing agent exceeds 10.0% by mass, the hair may be easily damaged.
  • the hair bleaching agent comprises a first agent containing an alkaline agent and a second agent containing an oxidizing agent, and decolorizes the hair by decomposing the melanin of the hair.
  • the hair bleaching agent is basically configured in the same manner as the oxidation hair dye except that it does not contain an oxidation dye.
  • the hair decoloring agent is usually a multi-component type of two or more agents, and is mainly intended for hair decoloring (decomposition of dyes dyed on the hair). The difference is that an alkali agent is blended with one agent, and further, a persulfate that is a kind of alkali agent is blended as a decoloring aid.
  • the first agent is in the form of powder, granule, tablet or the like, and the second agent is liquid.
  • the persulfate is not particularly limited as long as the effects of the present invention are not impaired, but an alkali metal salt of persulfate is preferably exemplified, and potassium persulfate or sodium persulfate is particularly preferably exemplified.
  • the content of the persulfate in the first agent is not limited, but is preferably in the range of 2.0 to 25% by mass, more preferably in the range of 3.5 to 18% by mass.
  • the first agent and the second agent in the hair cosmetic composition of the present invention include, for example, oily components, silicones, water-soluble polymers in addition to the components described above as necessary, as long as the effects of the present invention are not impaired.
  • a compound, a chelating agent, an inorganic salt, a dispersant, a nonionic surfactant, an amphoteric surfactant, an anionic surfactant, and the like may be appropriately selected and contained.
  • oil components include fats and oils, waxes, hydrocarbons, higher fatty acids, alkyl glyceryl ethers, esters, and polyhydric alcohols.
  • fats and oils examples include lanolin, olive oil, camellia oil, shea fat, almond oil, safflower oil, sunflower oil, soybean oil, cottonseed oil, sesame oil, corn oil, rapeseed oil, rice bran oil, rice germ oil, grape seed oil, avocado Oil, macadamia nut oil, castor oil, coconut oil, and evening primrose oil.
  • silicones examples include dimethylpolysiloxane (dimethicone), methylphenylpolysiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, terminal hydroxyl group-modified dimethylpolysiloxane, amino-modified silicone, polyether-modified silicone, and betaine-modified silicone. , Alkyl-modified silicone, alkoxy-modified silicone, carboxy-modified silicone, and fluorine-modified silicone.
  • waxes examples include beeswax, candelilla wax, carnauba wax, jojoba oil, and lanolin.
  • hydrocarbon examples include paraffin, olefin oligomer, polyisobutene, hydrogenated polyisobutene, mineral oil, squalane, polybutene, polyethylene, microcrystalline wax, and petrolatum.
  • higher fatty acids examples include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, isostearic acid, 12-hydroxystearic acid, oleic acid, and lanolin fatty acid.
  • alkyl glyceryl ether examples include batyl alcohol, chimyl alcohol, seraalkyl alcohol, and isostearyl glyceryl ether.
  • esters include diisopropyl adipate, isopropyl myristate, cetyl octanoate, isononyl isononanoate, octyldodecyl myristate, isopropyl stearate, stearyl stearate, myristyl myristate, isotridecyl myristate, 2-ethylhexyl palmitate, Octyldodecyl ricinoleate, fatty acid cholesteryl / lanosteryl having 10 to 30 carbon atoms, cetyl lactate, lanolin acetate, ethylene glycol di-2-ethylhexanoate, pentaerythritol fatty acid ester, dipentaerythritol fatty acid ester, cetyl caprate, tricapryl Examples include glyceryl acid, diisostearyl malate, dioctyl succinate, and
  • Examples of the polyhydric alcohol include glycol and glycerin.
  • Examples of the glycol include ethylene glycol, diethylene glycol, triethylene glycol, polyethylene glycol, propylene glycol, dipropylene glycol, isoprene glycol, and 1,3-butylene glycol.
  • Examples of glycerin include glycerin, diglycerin, and polyglycerin.
  • water-soluble polymer compounds include natural polymers, semi-synthetic polymers, and synthetic polymers.
  • natural polymers include gum arabic, carrageenan, galactan, guar gum, quince seed gum, locust bean gum, tragacanth gum, pectin, mannan, starch, xanthan gum, dextran, curdlan, succinoglucan, gelatin, collagen, Casein, albumin, tamarind gum and the like can be mentioned.
  • the semi-synthetic polymer examples include cellulose polymers such as methyl cellulose, ethyl cellulose, hydroxyethyl cellulose, carboxymethyl cellulose, hydroxypropyl methyl cellulose, hydroxyethyl cellulose dimethyl diallyl ammonium chloride, hydroxyethyl cellulose hydroxypropyl trimethyl ammonium chloride; carboxymethyl starch, Examples thereof include starch polymers such as methyl starch and soluble starch; alginic acid polymers such as alginates and propylene glycol alginate; and guar gum polymers such as cationized guar gum.
  • the synthetic polymer examples include carboxyvinyl polymer, polyacrylic acid amide, acrylic acid / alkyl methacrylate copolymer, polyvinyl alcohol, polyvinyl pyrrolidone, quaternized polyvinyl pyrrolidone, polyvinyl methyl ether, sodium polyacrylate, etc.
  • Examples include acid-based water-dispersed polymers.
  • anionic polymer compounds examples include carboxymethyl cellulose.
  • examples of the cationic polymer compound include polydimethyldimethylmethylene piperidinium liquid and hydroxyethyl cellulose dimethyl diallylammonium chloride.
  • chelating agents include ethylenediaminetetraacetic acid (EDTA, edetic acid), hydroxyethylethylenediaminetriacetic acid (HEDTA) and salts thereof, diethylenetriaminepentaacetic acid and salts thereof, and hydroxyethanediphosphonic acid (HEDP, etidronic acid) and salts thereof. Is mentioned.
  • inorganic salts include sodium chloride and sodium sulfate.
  • dispersant examples include magnesium stearate.
  • nonionic surfactants examples include the following.
  • POE Polyoxyethylene
  • POE alkyl phenyl ethers such as POE nonyl phenyl ether and POE octyl phenyl ether.
  • POE sorbitan fatty acid esters such as monooleic acid POE sorbitan, monostearic acid POE sorbitan, monopalmitic acid POE sorbitan, monolauric acid POE sorbitan, trioleic acid POE sorbitan.
  • POE glyceryl mono fatty acid esters such as monostearic acid POE glycerin and monomyristic acid POE glycerin.
  • POE sorbitol fatty acid esters such as tetraoleic acid POE sorbit, hexastearic acid POE sorbit, monolauric acid POE sorbit, and POE sorbit beeswax.
  • Higher fatty acid glycerin esters such as lipophilic glyceryl monooleate, lipophilic glyceryl monostearate, and self-emulsifying glyceryl monostearate.
  • Sorbitan fatty acid esters such as sorbitan monooleate, sorbitan sesquioleate, sorbitan trioleate, sorbitan monostearate, sorbitan monopalmitate, sorbitan monolaurate, and the like.
  • Lanolin derivatives such as POE lanolin, POE lanolin alcohol, and POE sorbitol lanolin.
  • Alkylolamides such as lauric acid diethanolamide and coconut oil fatty acid diethanolamide
  • POE fatty acid amides such as POE stearamide.
  • Alkyl amine oxides such as dimethyl lauryl amine oxide
  • Alkyl glucosides such as lauryl glucoside and alkyl (8-16) glucoside.
  • Lecithin derivative hydrogenated soybean lecithin, hydrogenated egg yolk lecithin, etc.
  • POE / POP alkyl ethers such as POE / polyoxypropylene (hereinafter abbreviated as POP) cetyl ether.
  • amphoteric surfactants examples include the following.
  • Fatty acid amidopropyl dimethylamino such as palm oil fatty acid amidopropyldimethylaminoacetic acid betaine, palm oil fatty acid amidopropyldimethylaminoacetic acid betaine, lauric acid amidopropyldimethylaminoacetic acid betaine (lauramidopropyl betaine), ricinoleic acid amidopropyldimethylaminoacetic acid betaine Betaine acetate and their sodium, potassium or triethanolamine salts.
  • Decyldimethylaminoacetic acid betaine lauryldimethylaminoacetic acid betaine, myristyldimethylaminoacetic acid betaine, cetyldimethylaminoacetic acid betaine, stearyldimethylaminoacetic acid betaine, oleyldimethylaminoacetic acid betaine, behenyldimethylaminoacetic acid betaine, coconut oil alkyldimethylaminoacetic acid betaine, etc. Alkyldimethylaminoacetic acid betaines and their sodium, potassium or triethanolamine salts.
  • Cocoamphoacetic acid Na N-coconut oil fatty acid acyl-N′-carboxymethyl-N′-hydroxyethylethylenediamine
  • Cocoamphopropionic acid Na N-coconut oil fatty acid acyl-N′-carboxyethyl-N′-hydroxyethylethylenediamine
  • Lauroamphoacetate Na N-lauroyl-N′-carboxymethyl-N′-hydroxyethylethylenediamine
  • Olive Amphoacetate Na Cacao Fat Amphoacetate Na
  • Sesame Amphoacetate Na Sweet Almond Amphoacetate Na
  • Palm Ampho N-acylaminoethyl-N-2-hydroxyethylaminocarboxylates such as sodium acetate, sodium peanut amphoacetate, sodium sunflower seed amphoacetate, and cottonseed amphoacetate Na.
  • N-acylaminoethyl-N-carboxymethoxyethylaminocarboxylates such as Na cocoamphodiacetate, Na cocoamphodipropionate and Nauroamphodiacetate.
  • anionic surfactant examples include the following. POE alkyl ether sulfate such as sodium lauryl ether sulfate, sodium lauryl sulfate, sodium cetostearyl sulfate, alkyl sulfate such as sodium cetyl sulfate, alkenyl ether sulfate, alkenyl sulfate, olefin sulfonate, alkane sulfonate, saturated Or N-acyl amino acid type surfactants such as unsaturated fatty acid salts, alkyl or alkenyl ether carboxylates, ⁇ -sulfone fatty acid salts, cocoyl glutamic acid triethanolamine (cocoyl glutamic acid TEA), phosphoric acid mono- or diester type surfactants And sulfosuccinic acid esters.
  • the counter ion of the anionic group of these surfactants include sodium ion, potassium ion, and tri
  • propellants for example, propellants, sugars, preservatives, stabilizers, pH adjusters, plant extracts, herbal extracts, vitamins, fragrances, and UV absorbers, and Japan's "Quasi-drug raw material standards" (June 2006 issue, Pharmaceutical Affairs Daily) may contain at least one selected from those listed.
  • a creamy hair cosmetic composition may be applied to the hair using an applicator, brush, comb, hand, etc., or the hair cosmetic composition may be foamed from a non-aerosol foamer container. You may make it discharge and apply to hair using a hand, an applicator, etc.
  • the non-aerosol foamer container is not limited as long as it has a function capable of foaming and discharging non-aerosol type to the hair cosmetic composition.
  • foaming can be performed using a non-aerosol foamer container described later.
  • a cosmetic method using the above-described hair cosmetic composition particularly a cosmetic method using a foamed hair cosmetic composition is provided.
  • the hair cosmetic product according to the present invention is a non-aerosol foam type dosage form to be applied to hair when used, and the hair cosmetic composition to be ejected in the form of foam.
  • Non-aerosol foamer container is a non-aerosol foam type dosage form to be applied to hair when used, and the hair cosmetic composition to be ejected in the form of foam.
  • a typical example of a non-aerosol foamer container is a pump former or a squeeze foamer.
  • the pump former is a device that presses the pump head to discharge the stored liquid (for example, the first / second mixed liquid of hair cosmetics) in the form of foam.
  • the stored liquid is mixed with air.
  • a foam discharger that discharges in the form of foam is mounted on the mouth of the container body.
  • a pump former is disclosed in Japanese Patent Application Laid-Open No. 2007-275777 and the like, and is well known.
  • the squeeze foamer squeezes the container body made of a soft synthetic resin with fingers (repeating the compression and decompression operations on the container) to mix the liquid and air in the former with the foam discharge head.
  • the squeeze former is published in Japanese Patent Application Laid-Open No. 2008-291024 and in the June 2009 issue of the magazine “Fragrance Journal” (New Development of Hair Color Technology (-Development of Foam Hair Color Technology)) And the like, which are publicly known.
  • the foam dispenser of a non-aerosol foamer container has one or more porous membranes for forming foam.
  • the material for the porous membrane include nylon, polyester, polyethylene, and polypropylene.
  • the mesh of the porous membrane for example, 50 to 300 mesh is preferable.
  • Example 1 to Example 6 and Comparative Example 1 to Example 2 were prepared by preparing a solubilized second hair dye of the conventional method and combining the first agent and the second agent according to each of the above examples selectively.
  • a solubilized or dispersed two-component hair dye according to Comparative Example 3 was constructed. Since the second agent in these examples and comparative examples is common, the column of “first agent” in Table 3 shows the first agent corresponding to each of the solubilized or dispersed examples and comparative examples. Example numbers are displayed.
  • the first agent and the second agent were prepared in a conventional manner with the combinations shown in Formula A and Formula B.
  • the second agent is common in these formulations.
  • each prescription corresponding to Example 7 and Comparative Example 4 was displayed.
  • the numerical value indicating the content of the component of the first agent or the second agent is a content notation in units of mass in the first agent or the second agent, the first agent and the second agent It is not the content notation when mixing the agent. Strong ammonia water, monoethanolamine solution, and hydrogen peroxide water are also expressed in percent by mass.
  • Tables 1 and 2 show the components corresponding to any one of the components (A) to (D) of the present invention and the comparative component (A) for the component (A). A message to that effect is displayed outside the box.
  • “POE (5) alkyl (C12-14) ether” in Table 1 is a mixed raw material of POE alkyl ether having 12 to 14 carbon atoms in the alkyl chain.
  • ⁇ Evaluation criteria of solubilization system or dispersion system> After preparation, no separation and cloudiness even after 1 week ⁇ : After preparation, it is separated or clouded in 30 minutes to 1 day ⁇ : After preparation, it is separated or clouded in less than 30 minutes ⁇ Evaluation criteria for emulsion system> ⁇ : After preparation, no separation after 1 week ⁇ : After preparation, it is separated in 1 to 3 days ⁇ : After preparation, it is separated in less than 1 day (Evaluation of lightness imparting effect of two-component hair dye) ⁇ Solubilized or dispersed two-component hair dye>
  • a pump former trade name W-5721 manufactured by Yoshino Kogyo Co., Ltd., WP former pump L nozzle type (gas / liquid mixing ratio: 13/1, discharge amount: 0.9 g (1 push), porous Membrane: Two 90 mesh polyethylene mesh rings) were used.
  • the first agent and the second agent according to Examples 1 to 6 and Comparative Examples 1 to 3 are contained in the above-described non-aerosol foamer container (pump former) at a mass ratio of 1: 1 and mixed liquid Then, by pressing the pump head part, the mixed liquid was discharged in a foam and applied to 15 cm black human hair. After application, it was allowed to stand at room temperature for 30 minutes, and was treated twice with plain rinse and shampoo by a conventional method to dry the hair. Thereafter, 10 panelists were compared and visually evaluated for the lightness imparted to the hair by the two-component hair dye according to Examples 1 to 4, using Comparative Example 1 as a control.
  • ⁇ Emulsified two-component hair dye> The 1st agent and 2nd agent which concern on said Example 7 and the comparative example 4 were mixed in the ratio of mass ratio 1: 1, and it apply
  • a hair cosmetic composition that is excellent in formulation stability even when a carbonate is blended and imparts good lightness to hair.

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Abstract

L'invention concerne une composition cosmétique pour les cheveux ayant une excellente stabilité de la formulation même quand elle est mélangée avec un carbonate, et conférant une brillance favorable aux cheveux. L'invention concerne une composition cosmétique pour les cheveux configurée en tant que teinture pour les cheveux ou agent de décoloration des cheveux, qui au moment de l'emploi, entraîne le mélange d'un premier agent et d'un second agent et l'application ultérieure aux cheveux, la composition cosmétique pour les cheveux étant caractérisée en ce qu'elle contient les composants suivants (A-C) dans le premier agent : du carbonate de potassium (A), un alcool supérieur (B), et un tensioactif cationique (C).
PCT/JP2011/074462 2010-11-01 2011-10-24 Composition cosmétique pour les cheveux WO2012060241A1 (fr)

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JP2010-245610 2010-11-01

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JP5956811B2 (ja) * 2012-04-09 2016-07-27 花王株式会社 二剤式泡状染毛剤
WO2017115827A1 (fr) * 2015-12-28 2017-07-06 花王株式会社 Produit cosmétique aérosol
JP2024102825A (ja) * 2023-01-19 2024-07-31 花王株式会社 毛髪脱色用又は染毛用化粧品

Citations (3)

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Publication number Priority date Publication date Assignee Title
JP2001328926A (ja) * 2000-05-19 2001-11-27 Hoyu Co Ltd 染毛剤組成物
JP2003040747A (ja) * 2001-07-26 2003-02-13 Hoyu Co Ltd 酸化染毛剤組成物
JP2005023024A (ja) * 2003-07-03 2005-01-27 Kao Corp 酸化染毛剤又は脱色剤組成物

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001328926A (ja) * 2000-05-19 2001-11-27 Hoyu Co Ltd 染毛剤組成物
JP2003040747A (ja) * 2001-07-26 2003-02-13 Hoyu Co Ltd 酸化染毛剤組成物
JP2005023024A (ja) * 2003-07-03 2005-01-27 Kao Corp 酸化染毛剤又は脱色剤組成物

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