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WO2012046711A1 - Electrochemical cell module and holder - Google Patents

Electrochemical cell module and holder Download PDF

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Publication number
WO2012046711A1
WO2012046711A1 PCT/JP2011/072827 JP2011072827W WO2012046711A1 WO 2012046711 A1 WO2012046711 A1 WO 2012046711A1 JP 2011072827 W JP2011072827 W JP 2011072827W WO 2012046711 A1 WO2012046711 A1 WO 2012046711A1
Authority
WO
WIPO (PCT)
Prior art keywords
end fitting
recess
holder
fitting recesses
electrochemical cells
Prior art date
Application number
PCT/JP2011/072827
Other languages
French (fr)
Japanese (ja)
Inventor
櫻井 淳
秀秋 上原
幸雄 飯田
若松 喜美
貴弘 松浦
Original Assignee
新神戸電機株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 新神戸電機株式会社 filed Critical 新神戸電機株式会社
Priority to CN201190000772.5U priority Critical patent/CN203433999U/en
Priority to JP2012537711A priority patent/JP5849957B2/en
Publication of WO2012046711A1 publication Critical patent/WO2012046711A1/en

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G2/00Details of capacitors not covered by a single one of groups H01G4/00-H01G11/00
    • H01G2/02Mountings
    • H01G2/04Mountings specially adapted for mounting on a chassis
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50Current conducting connections for cells or batteries
    • H01M50/502Interconnectors for connecting terminals of adjacent batteries; Interconnectors for connecting cells outside a battery casing
    • H01M50/509Interconnectors for connecting terminals of adjacent batteries; Interconnectors for connecting cells outside a battery casing characterised by the type of connection, e.g. mixed connections
    • H01M50/512Connection only in parallel
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G11/00Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/10Multiple hybrid or EDL capacitors, e.g. arrays or modules
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G11/00Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/74Terminals, e.g. extensions of current collectors
    • H01G11/76Terminals, e.g. extensions of current collectors specially adapted for integration in multiple or stacked hybrid or EDL capacitors
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G11/00Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/78Cases; Housings; Encapsulations; Mountings
    • H01G11/82Fixing or assembling a capacitive element in a housing, e.g. mounting electrodes, current collectors or terminals in containers or encapsulations
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M16/00Structural combinations of different types of electrochemical generators
    • H01M16/003Structural combinations of different types of electrochemical generators of fuel cells with other electrochemical devices, e.g. capacitors, electrolysers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/20Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
    • H01M50/204Racks, modules or packs for multiple batteries or multiple cells
    • H01M50/207Racks, modules or packs for multiple batteries or multiple cells characterised by their shape
    • H01M50/213Racks, modules or packs for multiple batteries or multiple cells characterised by their shape adapted for cells having curved cross-section, e.g. round or elliptic
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50Current conducting connections for cells or batteries
    • H01M50/502Interconnectors for connecting terminals of adjacent batteries; Interconnectors for connecting cells outside a battery casing
    • H01M50/507Interconnectors for connecting terminals of adjacent batteries; Interconnectors for connecting cells outside a battery casing comprising an arrangement of two or more busbars within a container structure, e.g. busbar modules
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/13Energy storage using capacitors
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Definitions

  • the present invention relates to an electrochemical cell module in which a plurality of electrochemical cells are assembled, and a holder used for the electrochemical cell module.
  • Patent Document 1 includes a plurality of columnar batteries (a type of electrochemical cell) having a convex electrode at one end and a planar electrode at the other end arranged in parallel.
  • a battery module electrochemical cell module having a structure in which holders are disposed at both ends of an assembled battery (cell group) and a support column is provided between two holders to define a space between the two holders is disclosed.
  • the plurality of batteries are electrically connected to a metal bus bar that is insert-molded in the holder.
  • the holder is provided with a terminal fitting for taking out the output from the battery module.
  • Patent Document 2 Japanese Patent Application Laid-Open No. 2003-45504
  • Patent Document 3 also disclose battery modules configured using similar holders.
  • the conventional electrochemical cell module uses a holder with a bus bar insert-molded, so the versatility of the holder is low. Therefore, the inventor of the present application considered making a cell assembly in which a bus bar was connected in advance to a cell group, and fitting a holder to both ends of the cell assembly. The inventor initially considered the holder for the end fitting concave portion of the cell having a shape corresponding to the convex electrode and the planar electrode of the columnar electrochemical cell in consideration of the arrangement direction of the plurality of columnar electrochemical cells. A prepared holder was produced. However, it has been found that such a holder is not versatile because it cannot be used when the cell orientation changes.
  • An object of the present invention is to provide an electrochemical cell module provided with a highly versatile holder and a holder suitable for use in the electrochemical cell module.
  • the present invention is directed to an electrochemical cell module in which battery chemical cells such as batteries and capacitors are modularized.
  • the electrochemical cell module of the present invention includes a cell assembly and first and second holders.
  • the cell assembly includes a cell group in which a plurality of columnar electrochemical cells each having a convex electrode at one end and a planar electrode at the other end are arranged in parallel, and a plurality of columnar electrochemical cells in the cell group.
  • a plurality of bus bars are arranged on both sides in the extending direction.
  • the plurality of bus bars are formed by connecting a plurality of electrochemical cells with a predetermined wiring pattern so that a convex electrode and a planar electrode, a convex electrode and a convex electrode, or a planar shape of two adjacent columnar electrochemical cells. Connect the electrode and the planar electrode.
  • the convex electrode may of course be provided with a planar electrode portion around the convex electrode.
  • the planar electrode does not need to have a completely flat surface and may have some unevenness on the surface.
  • “two adjacent columnar electrochemical cells” simply mean two adjacent columnar electrochemical cells among a plurality of columnar electrochemical cells, and can be connected by one bus bar. It does not mean that the number of cells is limited to two. For example, the present invention includes a case where four cells are connected by one bus bar.
  • the first holder is fitted to one end located in the direction in which the plurality of columnar electrochemical cells of the cell assembly extend.
  • the second holder is fitted to the other end located in the direction in which the plurality of columnar electrochemical cells of the cell assembly extend.
  • the 1st and 2nd holder is provided with the some edge part fitting recessed part by which the edge part of several columnar electrochemical cell is fitted.
  • the buffer spacer is arrange
  • the assembly can be held between the first and second holders without backlash.
  • a spacer receiving recess for receiving the buffer spacer in a compressible state is formed at the bottom of the end fitting recess. Since the position of the buffer spacer is fixed by providing such a spacer receiving recess, the buffer spacer can be reliably positioned between a part of the bus bar and the bottom of the end fitting recess.
  • a matching through hole is formed in the bottom of each of the buffer spacer and the spacer receiving recess. If such a through hole is provided, after assembling the electrochemical cell module, not only can the direction of the cell be confirmed through the through hole, but also the electrical performance can be confirmed by bringing the measurement terminal into contact with the electrode through the through hole. Therefore, inspection after assembly is facilitated.
  • One bus bar may include one or more terminal portions for external connection. Even when not all bus bars are provided with a terminal portion for external connection, the module is included in the present invention.
  • the first and second holders include a bottom wall portion and a peripheral wall portion.
  • the bottom wall portion faces one end or the other end of the cell assembly.
  • the peripheral wall portion rises from the peripheral edge portion of the bottom wall portion and extends toward the cell assembly side.
  • the peripheral wall portion includes two or more openings that communicate with at least one of the at least two end fitting recesses communicating to receive the bus bar and allow the terminal portion of the bus bar to go outside. It is preferable. If there is an opening in the holder, the terminal part of the electrochemical cell module can be obtained simply by taking out the terminal part provided on the bus bar from the opening.
  • one opening is formed in the peripheral wall portion surrounding the two end fitting recesses communicating with each other so as to receive the bus bar, corresponding to an intermediate position between the two end fitting recesses,
  • the same holder is used when connecting multiple columnar electrochemical cells with various wiring patterns such as parallel, series, and series-parallel, by forming another opening that opens in the direction in which the two end fitting recesses are aligned. It becomes possible to increase the versatility of the holder.
  • the holder may have all of the plurality of end fitting recesses connected in series, or the plurality of end fitting portions may be communicated in a closed loop. Embodiments are arbitrary.
  • four through holes for drawing out the voltage detection lead wires may be formed in the bottom wall portion of the holder with an angular interval of 90 ° around the center of the bottom wall portion.
  • the holder of the present invention includes a cell group in which a plurality of columnar electrochemical cells each having a convex electrode at one end and a planar electrode at the other end are arranged in parallel, and the columnar electrochemical cell in the cell group extends in the extending direction.
  • the cell assembly composed of a plurality of bus bars connecting the planar electrodes and the planar electrodes is fitted to one end located in the extending direction of the plurality of columnar electrochemical cells.
  • the holder is fitted with a bottom wall portion facing one end of the cell assembly, a peripheral wall portion rising from the peripheral edge of the bottom wall portion and extending to the cell assembly side, and end portions of a plurality of columnar electrochemical cells.
  • a plurality of end fitting recesses and a cushioning spacer provided in the center of the bottoms of the plurality of end fitting recesses and arranged in a compressed state between the bottoms of the plurality of end fitting recesses and the bus bar And a plurality of recesses for receiving spacers.
  • the peripheral wall portion is provided with two or more openings that communicate with at least one of the two or more end fitting recesses communicating to receive the bus bar and allow the terminal portion of the bus bar to go outside. Yes.
  • a more specific holder is fitted to a cell assembly having a cell group in which four columnar electrochemical cells are arranged in parallel so that two columnar electrochemical cells are arranged side by side. Therefore, the holder is formed with four end fitting recesses into which the end portions of the four columnar electrochemical cells are fitted, and four spacer receiving recesses.
  • the holder corresponding to the four columnar electrochemical cells has two recess rows made of two end fitting recesses communicating with each other, and two portions of the peripheral wall corresponding to the center position of the two recess rows Each has one opening, and one opening may be formed in each of two portions of the peripheral wall corresponding to one end of the two recess rows.
  • two recess rows composed of two end fitting recesses communicating with each other are arranged, and one of the fitting recesses included in one of the two recess rows and one end fitting recess included in the other.
  • One opening is formed in each of the two portions of the peripheral wall portion corresponding to the center position of the two recess rows, and two locations of the peripheral wall portion corresponding to one end of the two recess rows are communicated.
  • One opening may be formed in each part.
  • two recess rows made of two end fitting recesses communicating with each other are arranged, one end fitting recess included in one of the two recess rows, and one end fitting recess included in the other, Are communicated with each other, and the remaining one end fitting recess included in one of the two recess rows communicates with the remaining one end fitting recess included in the other.
  • One opening may be formed in each of two portions of the peripheral wall corresponding to the central position.
  • a first recess row composed of two communicating end fitting recesses and a second recess row composed of two end fitting recessed portions not communicating are arranged side by side, and the two constituting the second recess row
  • One opening may be formed in each of the peripheral wall portions surrounding the end fitting recess.
  • the peripheral wall portion of the holder is constituted by four side wall portions having the same length dimension and orthogonal to each other, it is preferable that the attachment holes are respectively formed at the same diagonal positions of the four side wall portions. . If such attachment holes are formed, when a plurality of holders are connected, the holders can be connected using the attachment holes regardless of the position of the opening provided in the holder.
  • FIG. 1 It is a perspective view used in order to demonstrate the structure of the electrochemical cell module of this Embodiment. It is sectional drawing of the electrochemical cell module of embodiment of FIG. (A) is a perspective view of the holder used in the embodiment of FIG. 1, (B) is a plan view of the holder used in the embodiment of FIG. 1, and (C) is a bottom view of the holder used in the embodiment of FIG. , (D) is a right side view of the holder used in the embodiment of FIG. 1, (E) is a sectional view taken along line IIIE-IIIE in FIG. 3 (B), and (F) is a holder of the holder used in the embodiment of FIG. It is a left side view. It is a perspective view of other embodiment of the holder of this invention. It is a perspective view of other embodiment of the holder of this invention. It is a perspective view of other embodiment of the holder of this invention. It is a perspective view of other embodiment of the holder of this invention.
  • FIG. 1 shows a perspective view used for explaining the configuration of the electrochemical cell module 1 of the present embodiment
  • FIG. 2 shows the II-II line of the electrochemical cell module 1 of the embodiment of FIG. It is sectional drawing. In FIG. 2, the cell is not cross-sectional.
  • the electrochemical cell module 1 is composed of a cell assembly 3 and first and second holders 5 and 7.
  • the cell assembly 3 includes four columnar lithium ion capacitors 13A to 13D, which are a kind of columnar electrochemical cell having a convex electrode 9 at one end and a planar electrode 11 at the other end.
  • the cell group 15 arranged in parallel and the four lithium ion capacitors 13A to 13D included in the cell group 15 are arranged on both sides in the extending direction and welded to the electrodes of the four lithium ion capacitors 13A to 13D. Bus bars 17-20.
  • the lithium ion capacitors 13A to 13D have a structure in which the outer surface of the can is covered with an insulating resin tube.
  • bus bars 17 to 20 form a wiring pattern in which two sets of cell units in which two lithium ion capacitors 13A and 13B and two lithium ion capacitors 13C and 13D are connected in series are connected in parallel. In this manner, the convex electrode 9 and the convex electrode 9 of the two adjacent lithium ion capacitors 13A to 13D, the planar electrode 11 and the planar electrode 11 are connected.
  • the four bus bars 17 to 20 are formed by press-molding a conductive material or copper material having a low resistance value such as nickel, iron, copper, or aluminum, which is plated with tin or nickel.
  • the bus bars 17 and 18 used in the present embodiment include through holes 17A and 18A and terminal portions 17B and 18B that expose the tips of the convex electrodes 9 when connected to the convex electrodes 9.
  • the bus bars 19 and 20 include through-holes 19A and 20A and terminal portions 19B and 20B that partially expose the planar electrode 11 when connected to the planar electrode 11.
  • the bus assembly 17 is configured in advance by connecting the bus bars 17 to 20 to the electrodes (9, 11) of the electrochemical cell 13 by soldering or resistance welding.
  • the first holder 5 is fitted to one end of the cell assembly 3 positioned in the direction in which the lithium ion capacitors 13A to 13D extend.
  • the second holder is fitted to the other end of the cell assembly 3 positioned in the direction in which the lithium ion capacitors 13A to 13D extend.
  • the holders having the same shape shown in FIGS. 3A to 3F are used as the first and second holders 5 and 7.
  • the second holder 7 is fitted to the cell assembly 3 in a posture rotated by 90 ° with respect to the first holder 5.
  • the holder 5 used in the present embodiment is integrally formed of an insulating resin material and includes a bottom wall portion 21 and a peripheral wall portion 22.
  • the bottom wall portion 21 has a substantially rectangular outline and faces one end or the other end of the cell assembly 3.
  • a center hole 23 into which a screw with a head (not shown) for fixing the support 16 shown in FIG. 1 is inserted is formed in the bottom wall portion 21.
  • the two opposite sides 21A and 21C among the four sides 21A to 21D of the bottom wall portion 21 are formed so as to protrude toward the center hole 23 and are bottom.
  • Semicircular arc-shaped recesses 21 ⁇ / b> E and 21 ⁇ / b> F penetrating in the thickness direction of the wall portion 21 and opening away from the center hole 23 are formed.
  • the recesses 21E and 21F are used for exposing the terminal portion of the bus bar.
  • the bottom wall portion 21 has voltage detection leads at positions where a virtual line L1 orthogonal to the sides 21A and 21C and passing through the central hole 23 and a virtual line L2 orthogonal to the sides 21B and 21D and passing through the central hole 23 pass.
  • Four through holes 24 having a diameter through which a wire can pass are formed.
  • the four through-holes 24 are formed at an angular interval of 90 ° around the center hole 23, respectively.
  • the voltage detection lead wire is drawn too long regardless of the positional relationship between the holder 5 and the cell assembly 3. Without turning, it can be pulled out from any one of the four through holes 24.
  • four through holes 25 are formed in the bottom wall portion 21 so as to be positioned on two diagonal lines assumed for the four corner portions of the bottom wall portion 21. The function of the through hole 25 will be described later.
  • two through holes 26 are formed in the bottom wall portion 21 at a position where the above-described virtual line L2 passes. This through hole is an attachment hole.
  • the peripheral wall portion 22 that rises from the peripheral edge portion of the bottom wall portion 21 and extends toward the cell assembly 3 side is composed of four side wall portions 22A to 22D that have the same length and are orthogonal to each other.
  • a pair of opening portions 22E and 22F communicating with a pair of recesses 21E and 21F formed in the bottom wall portion 21 are formed in the pair of opposing side wall portions 22A and 22C.
  • two openings 22G and 22H are formed in the side wall 22B.
  • the holder 5 is surrounded by the bottom wall portion 21 and the peripheral wall portion 22 and is formed with four end fitting recesses 28A to 28D into which the ends of the four lithium ion capacitors 13A to 13D are fitted. There is.
  • the four end fitting recesses 28A to 28D are provided with spacer receiving recesses 30A to 30D for receiving buffer spacers 29 arranged in a compressed state between the bus bars 17 to 20 and the bottom wall 21 at the bottoms thereof.
  • the buffer spacer 29 is made of a ring-shaped rubber. If such a buffer spacer 29 is provided, the two holders 5 and 7 are connected to one of the bus bars 17 to 20 by the buffer spacer 29 that is compressed and deformed regardless of the arrangement direction of the four lithium ion capacitors.
  • the cell assembly 3 can be held between the first and second holders 5 and 7 by filling a space between the first portion and the bottom of the end fitting concave portions 28A to 28D.
  • the two end fitting recesses 28A and 28D communicate with each other so as to receive the bus bar 18 disposed across the two lithium ion capacitors 13A and 13D.
  • the two end fitting recesses 28B and 28C communicate with each other so as to receive the bus bar 17 disposed across the two lithium ion capacitors 13B and 13D.
  • one partition wall portion 31 is formed in the holder 5.
  • the side wall portion 22A of the peripheral wall portion 22 surrounding the two end portion fitting recesses 28A and 28D communicating with each other so as to receive the bus bar 18 has an intermediate position between the two end portion fitting recesses 28A and 28D.
  • One opening 22F is formed corresponding to an intermediate position between the fitting recesses 28B and 28C, and an opening 22G and two end fittings that open in the direction in which the two end fitting recesses 28A and 28D are arranged.
  • An opening 22H that opens in the direction in which the combination recesses 28B and 28C are arranged is formed in the side wall 22B.
  • the openings 22G and 22H open in the same direction, but one of the two openings 22G and 22H is formed on the side wall 22D, and the two openings 22G and 22H are opposite to each other. Of course, it may be made to open.
  • four openings 22E to 22G are provided in the holders 5 and 7, when connecting a plurality of columnar lithium ion capacitors in various wiring patterns such as parallel, series, and series / parallel, one holder 5 is provided.
  • by rotating the other holder 7 to determine the positional relationship between the two holders almost all wiring patterns can be realized, and the versatility of the holder is enhanced.
  • the bus bar 17 is disposed in the two end fitting recesses 28 ⁇ / b> B and 28 ⁇ / b> C that communicate with the holder 5, and the bus bar 28 is disposed in the two end fitting recesses 28 ⁇ / b> A and 28 ⁇ / b> D that communicate with the holder 5.
  • the terminal part 17B of the bus bar 17 is extended outside from the opening part 22H
  • the terminal part 18B of the bus bar 18 is extended outside from the opening part 22G.
  • the bus bar 19 is disposed in the two end fitting recesses 28 ⁇ / b> B and 28 ⁇ / b> C that communicate with the holder 7, and the bus bar 20 is disposed in the two end fitting recesses 28 ⁇ / b> A and 28 ⁇ / b> D that communicate with the holder 7.
  • the terminal part 19B of the bus bar 19 is extended outside from the opening part 22H, and the terminal part 20B of the bus bar 20 is extended outside from the opening part 2G.
  • FIG. 4 is a perspective view of another embodiment of the holder of the present invention.
  • This holder 5 ' has the same structure as that of the holder of FIG. 3 except that the partition wall portion 31 partitioning between the end fitting recesses 28C and 28D of the holder 5 shown in FIG. 3 is removed. is doing.
  • the four end fitting recesses 28A to 28D communicate in series in the order of 28A ⁇ 28D ⁇ 28C ⁇ 28B. From another point of view, one recess row made of communicating end fitting recesses 28A and 28D and one recess row 28C made of communicating end fitting recesses 28D and 28C are arranged side by side.
  • One fitting recess 28D included in one of the rows communicates with one end fitting recess 28C included in the other, and the side wall portions 22A and 22C of the peripheral wall portion corresponding to the center position of the two recess rows.
  • One opening 22E and 22F is formed in the central part of each.
  • Openings 22G and 22H are formed in two portions of the peripheral wall portion 22B corresponding to one end of the two recess rows.
  • FIG. 5 is a perspective view of still another embodiment of the holder of the present invention.
  • This holder 5 ′′ includes the part of the partition wall 31 that partitions the end fitting recesses 28C and 28D of the holder 5 shown in FIG. 3 and the end fitting recess 28A of the holder 5 shown in FIG.
  • the part of the partition wall 31 that partitioned the space 28B is removed, except that the openings 22G and 22H formed in the side wall 22B of the holder 5 in FIG. 3 are closed.
  • 3 has the same structure as the holder 5.
  • four end fitting recesses 28A to 28D communicate in a closed loop.
  • one recess row composed of communicating end fitting recesses 28A and 28D and one recess row 28C composed of communicating end fitting recesses 28D and 28C are arranged side by side.
  • One fitting recess 28D included in one of the two recess rows communicates with one end fitting recess 28C included in the other, and the remaining one included in one of the two recess rows
  • the end fitting recess 28A communicates with the other end fitting recess 28B included in the other, and the central portions of the side wall portions 22A and 22C of the peripheral wall portions corresponding to the center positions of the two recess rows.
  • One opening 22E and 22F is formed in each part.
  • FIG. 6 is a perspective view of still another embodiment of the holder of the present invention.
  • the partition wall portion 31 ', the first recess row composed of two end fitting recesses 28C and 28D communicating with each other, and the second end fitting recess 28A and 28B not communicating with each other are provided.
  • One opening 22E and 22F is formed in each of the peripheral wall portions (side walls 22A and 22C) surrounding the two end fitting recesses 28A and 28B constituting the second recess row.
  • Such a structure is not particularly problematic.
  • a lithium ion capacitor is used as the electrochemical cell.
  • an electrochemical cell it is needless to say that an electric double layer capacitor, a lithium ion battery, or another secondary battery may be used.
  • the first and second holders 5 and 7 are attracted by the support column 16, but so as to surround the first and second holders 5 and 7 and the cell assembly 3. You may make it attract the 1st and 2nd holders 5 and 7 by arrange
  • the buffer spacer 29 made of a rubber material is used.
  • the buffer spacer 29 is formed of a material other than the rubber material as long as it is deformed and elastic when compressed. May be.
  • the electrochemical cell module 1 of the above embodiment includes a cell assembly 3 composed of four electrochemical cells (13A to 13D).
  • the number of electrochemical cells included in the cell assembly 3 is as follows. It is not particularly limited.
  • the bus bars 17 to 20 are of a type in which all two adjacent electrochemical cells are connected.
  • the bus bar connected only to the electrode of one electrochemical cell may be electrically connected.
  • it may be included in the chemical cell module 1.
  • FIG. 1 In the embodiment of FIG. 1, two holders of the same type are used. Of course, a plurality of types of holders shown in FIGS. 3 to 6 may be used in combination depending on the wiring pattern. is there.
  • the compression buffer spacer between the part of the bus bar and the bottom of the end fitting recess is compressed regardless of the arrangement direction of the electrochemical cell.
  • the cell assembly can be held between the first and second holders without rattling.
  • Electrochemical cell module 3 Cell aggregate
  • assembly 5 1st holder 7 2nd holder 9
  • Convex electrode 11 Planar electrode 13A-13D
  • Lithium ion capacitor (electrochemical cell) 15 cell group 16 support 17-20 bus bar 21 bottom wall 22 peripheral wall 22A-22D side wall 22E-22H opening 23 center hole 24 through hole 25 through hole 26 through hole 28A-28D end fitting recess 29 buffer spacer 30A to 30D Spacer receiving recess 31 Partition wall

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  • Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Battery Mounting, Suspending (AREA)
  • Connection Of Batteries Or Terminals (AREA)

Abstract

Provided are an electrochemical cell module provided with a holder having a high level of general utility and a holder suitable for use with that electrochemical module. In a holder (5) are formed four end part mating depressions (28A - 28D) formed so as to be surrounded by a bottom wall part (21) and a peripheral wall part (22) for mating with the end parts of four lithium ion capacitors (13A - 13D). The four end part mating depressions (28A - 28D) are provided with spacer accommodating depressions (30A - 30D) that accommodate buffering spacers (29) which are disposed in a compressed state between bus bars (17 - 20) and the bottom wall part (21) in the bottom part of the depressions.

Description

電気化学セルモジュール及びホルダElectrochemical cell module and holder
 本発明は、複数本の電気化学セルを集合させた電気化学セルモジュール及び該電気化学セルモジュールに用いるホルダに関するものである。 The present invention relates to an electrochemical cell module in which a plurality of electrochemical cells are assembled, and a holder used for the electrochemical cell module.
 特開2006-99997号公報(特許文献1)には、一端に凸状電極を有し且つ他端に面状電極を有する複数本の柱状電池(電気化学セルの一種)が並列配置されてなる組電池(セル群)の両端にそれぞれホルダを配置して、二つのホルダの間に両者間の間隔を画定する支柱を配置した構造の電池モジュール(電気化学セルモジュール)が開示されている。複数の電池は、ホルダ内にインサート成形された金属製のバスバに電気的に接続されている。そしてホルダには、電池モジュールからの出力を取り出す端子金具が設けられている。特開2003-45504号公報(特許文献2)及び特開2001-325931号公報(特許文献3)にも、同様のホルダを用いて構成された電池モジュールが開示されている。 Japanese Patent Laid-Open No. 2006-99997 (Patent Document 1) includes a plurality of columnar batteries (a type of electrochemical cell) having a convex electrode at one end and a planar electrode at the other end arranged in parallel. A battery module (electrochemical cell module) having a structure in which holders are disposed at both ends of an assembled battery (cell group) and a support column is provided between two holders to define a space between the two holders is disclosed. The plurality of batteries are electrically connected to a metal bus bar that is insert-molded in the holder. The holder is provided with a terminal fitting for taking out the output from the battery module. Japanese Patent Application Laid-Open No. 2003-45504 (Patent Document 2) and Japanese Patent Application Laid-Open No. 2001-325931 (Patent Document 3) also disclose battery modules configured using similar holders.
特開2006-99997号公報JP 2006-99997 A 特開2003-45504号公報JP 2003-45504 A 特開2001-325931号公報JP 2001-325931 A
 従来の電気化学セルモジュールでは、バスバをインサート成形したホルダを用いるため、ホルダの汎用性が低かった。そこで本願発明者は、バスバをセル群に予め接続したセル集合体を作り、このセル集合体の両端部にホルダを嵌合させることを考えた。発明者が当初考えたホルダは、複数本の柱状電気化学セルの配置向きを考慮して、柱状電気化学セルの凸状電極と平面状電極にそれぞれ対応した形状のセルの端部嵌合用凹部を備えたホルダを製作した。しかしながらこのようなホルダは、セルの配置向きが変わると使用できなくなるため、汎用性が低いことが判った。 The conventional electrochemical cell module uses a holder with a bus bar insert-molded, so the versatility of the holder is low. Therefore, the inventor of the present application considered making a cell assembly in which a bus bar was connected in advance to a cell group, and fitting a holder to both ends of the cell assembly. The inventor initially considered the holder for the end fitting concave portion of the cell having a shape corresponding to the convex electrode and the planar electrode of the columnar electrochemical cell in consideration of the arrangement direction of the plurality of columnar electrochemical cells. A prepared holder was produced. However, it has been found that such a holder is not versatile because it cannot be used when the cell orientation changes.
 本発明の目的は、汎用性の高いホルダを備えた電気化学セルモジュール及び該電気化学セルモジュールに使用するのに適したホルダを提供することにある。 An object of the present invention is to provide an electrochemical cell module provided with a highly versatile holder and a holder suitable for use in the electrochemical cell module.
 本発明は、電池、キャパシタ等の電池化学セルをモジュール化した電気化学セルモジュールを対象とする。本発明の電気化学セルモジュールは、セル集合体と、第1及び第2のホルダとから構成される。セル集合体は、一端に凸状電極を有し且つ他端に面状電極を有する複数本の柱状電気化学セルが並列配置されてなるセル群と、セル群の複数本の柱状電気化学セルが延びる方向の両側にそれぞれ配置され複数のバスバとから構成される。複数のバスバは、複数本の電気化学セルを所定の配線パターンで接続するように、隣り合う2本の柱状電気化学セルの凸状電極と面状電極、凸状電極と凸状電極または面状電極と面状電極を接続する。本願明細書において、凸状電極は、凸状電極の周囲に面状の電極部を備えていてもよいのは勿論である。また、面状電極とは、完全に平坦な表面を有している必要はなく、表面に多少の凹凸があってもよいものである。さらに本願明細書において「隣り合う2本の柱状電気化学セル」とは、複数本の柱状電気化学セルの中の隣り合う2本の柱状電気化学セルを意味するだけで、1つのバスバで接続できるセルの本数が2本に限定されることを意味するものではない。例えば4本のセルが1つのバスバで接続される場合も本発明に含まれる。 The present invention is directed to an electrochemical cell module in which battery chemical cells such as batteries and capacitors are modularized. The electrochemical cell module of the present invention includes a cell assembly and first and second holders. The cell assembly includes a cell group in which a plurality of columnar electrochemical cells each having a convex electrode at one end and a planar electrode at the other end are arranged in parallel, and a plurality of columnar electrochemical cells in the cell group. A plurality of bus bars are arranged on both sides in the extending direction. The plurality of bus bars are formed by connecting a plurality of electrochemical cells with a predetermined wiring pattern so that a convex electrode and a planar electrode, a convex electrode and a convex electrode, or a planar shape of two adjacent columnar electrochemical cells. Connect the electrode and the planar electrode. In the present specification, the convex electrode may of course be provided with a planar electrode portion around the convex electrode. The planar electrode does not need to have a completely flat surface and may have some unevenness on the surface. Further, in the present specification, “two adjacent columnar electrochemical cells” simply mean two adjacent columnar electrochemical cells among a plurality of columnar electrochemical cells, and can be connected by one bus bar. It does not mean that the number of cells is limited to two. For example, the present invention includes a case where four cells are connected by one bus bar.
 第1のホルダは、セル集合体の複数本の柱状電気化学セルが延びる方向に位置する一端に嵌合される。また第2のホルダは、セル集合体の複数本の柱状電気化学セルが延びる方向に位置する他端に嵌合される。第1及び第2のホルダは、複数本の柱状電気化学セルの端部が嵌合される複数の端部嵌合凹部を備えている。そして複数の端部嵌合用凹部の底部とバスバとの間に圧縮状態で緩衝用スペーサが配置されている。このような緩衝用スペーサを用いると、セルの配置方向の如何にかかわらず、圧縮変形した緩衝用スペーサにより、バスバの一部と端部嵌合用凹部の底部との間のスペースを埋めて、セル集合体を第1及び第2のホルダ間にガタツキ無く保持することができる。 The first holder is fitted to one end located in the direction in which the plurality of columnar electrochemical cells of the cell assembly extend. The second holder is fitted to the other end located in the direction in which the plurality of columnar electrochemical cells of the cell assembly extend. The 1st and 2nd holder is provided with the some edge part fitting recessed part by which the edge part of several columnar electrochemical cell is fitted. And the buffer spacer is arrange | positioned in the compression state between the bottom part of the recessed part for several edge part fitting, and a bus bar. When such a buffer spacer is used, the space between a part of the bus bar and the bottom of the end fitting recess is filled with the buffer spacer compressed and deformed regardless of the cell arrangement direction. The assembly can be held between the first and second holders without backlash.
 端部嵌合用凹部の底部には、緩衝用スペーサが圧縮可能な状態で収容されるスペーサ収容凹部が形成されているのが好ましい。このようなスペーサ収容凹部を設けると、緩衝用スペーサの位置が固定されるため、確実に緩衝用スペーサをバスバの一部と端部嵌合用凹部の底部との間に位置させることができる。 It is preferable that a spacer receiving recess for receiving the buffer spacer in a compressible state is formed at the bottom of the end fitting recess. Since the position of the buffer spacer is fixed by providing such a spacer receiving recess, the buffer spacer can be reliably positioned between a part of the bus bar and the bottom of the end fitting recess.
 また緩衝用スペーサ及びスペーサ収容用凹部の底部には、それぞれ整合する(重なる)貫通孔が形成されているのが好ましい。このような貫通孔を設けると、電気化学セルモジュールの組立後に、この貫通孔を通してセルの向きを確認することができるだけでなく、貫通孔を通して測定端子を電極と接触させることにより電気性能を確認することができるので、組立後の検査が容易になる。 Further, it is preferable that a matching through hole is formed in the bottom of each of the buffer spacer and the spacer receiving recess. If such a through hole is provided, after assembling the electrochemical cell module, not only can the direction of the cell be confirmed through the through hole, but also the electrical performance can be confirmed by bringing the measurement terminal into contact with the electrode through the through hole. Therefore, inspection after assembly is facilitated.
 1つのバスバは、外部接続用の1以上の端子部を備えていてもよい。なおすべてのバスバが外部接続用の端子部を備えていない場合でも、そのモジュールは本発明に含まれる。第1及び第2のホルダは、底壁部と周壁部とを備えている。底壁部は、セル集合体の一端または他端と対向する。そして周壁部は、底壁部の周縁部から立ち上がってセル集合体側に延びる。そして周壁部には、バスバを受け入れるように連通している少なくとも2つの端部嵌合用凹部の少なくとも1つと連通してバスバの端子部が外部に出ることを許容する2以上の開口部を備えているのが好ましい。ホルダに開口部があれば、バスバに設けた端子部を開口部から出すだけで、電気化学セルモジュールの端子部とすることができる。 One bus bar may include one or more terminal portions for external connection. Even when not all bus bars are provided with a terminal portion for external connection, the module is included in the present invention. The first and second holders include a bottom wall portion and a peripheral wall portion. The bottom wall portion faces one end or the other end of the cell assembly. The peripheral wall portion rises from the peripheral edge portion of the bottom wall portion and extends toward the cell assembly side. The peripheral wall portion includes two or more openings that communicate with at least one of the at least two end fitting recesses communicating to receive the bus bar and allow the terminal portion of the bus bar to go outside. It is preferable. If there is an opening in the holder, the terminal part of the electrochemical cell module can be obtained simply by taking out the terminal part provided on the bus bar from the opening.
 特に、バスバを受け入れるように連通している2つの端部嵌合用凹部を囲む周壁部に、2つの端部嵌合用凹部の中間位置に対応して1つの前記開口部が形成されており、前記2つの端部嵌合用凹部が並ぶ方向に開口する別の開口部を形成すると、並列、直列、直並列等の各種の配線パターンで複数の柱状電気化学セルを接続する場合に、同じホルダを使用できるようになり、ホルダの汎用性が高くなる。 In particular, one opening is formed in the peripheral wall portion surrounding the two end fitting recesses communicating with each other so as to receive the bus bar, corresponding to an intermediate position between the two end fitting recesses, The same holder is used when connecting multiple columnar electrochemical cells with various wiring patterns such as parallel, series, and series-parallel, by forming another opening that opens in the direction in which the two end fitting recesses are aligned. It becomes possible to increase the versatility of the holder.
 なおホルダは、複数の端部嵌合用凹部がすべて直列に連通していてもよく、また複数の端部嵌合部が閉ループ状に連通していてもよく、複数の端部嵌合用凹部の連通態様は任意である。 The holder may have all of the plurality of end fitting recesses connected in series, or the plurality of end fitting portions may be communicated in a closed loop. Embodiments are arbitrary.
 またホルダの底壁部に、電圧検出用リード線を引き出す4つの貫通孔が、底壁部の中心の回りに90°ずつ角度間隔を開けて形成されていてもよい。このように電圧検出用リード線を引き出す貫通孔を設ければ、ホルダをセル集合体に対してどのような位置関係で嵌合させたとしても、電圧検出用リード線をあまり長く引き廻すことなく、4つの貫通孔のいずれか1つから外部に引き出すことができる。 Further, four through holes for drawing out the voltage detection lead wires may be formed in the bottom wall portion of the holder with an angular interval of 90 ° around the center of the bottom wall portion. By providing a through-hole for drawing out the voltage detection lead wire in this way, the voltage detection lead wire is not routed so long no matter what positional relationship the holder is fitted to the cell assembly. It can be pulled out from any one of the four through holes.
 本発明のホルダは、一端に凸状電極を有し且つ他端に面状電極を有する複数の柱状電気化学セルが並列配置されてなるセル群と、セル群の柱状電気化学セルが延びる方向の両側に配置されて、複数本の電気化学セルを所定の配線パターンで接続するように、隣り合う2本の柱状電気化学セルの凸状電極と面状電極、凸状電極と凸状電極または面状電極と面状電極を接続する複数のバスバとからなるセル集合体の、複数本の柱状電気化学セルが延びる方向に位置する一端に嵌合される。そしてホルダは、セル集合体の一端と対向する底壁部と、該底壁部の周縁部から立ち上がってセル集合体側に延びる周壁部と、複数本の柱状電気化学セルの端部が嵌合される複数の端部嵌合用凹部と、複数の端部嵌合用凹部の底部の中央に設けられて、複数の端部嵌合用凹部の底部とバスバとの間に圧縮状態で配置される緩衝用スペーサを収容する複数のスペーサ収容用凹部とを有している。そして周壁部に、バスバを受け入れるように連通している2以上の端部嵌合用凹部の少なくとも1つと連通してバスバの端子部が外部に出ることを許容する2以上の開口部が設けられている。 The holder of the present invention includes a cell group in which a plurality of columnar electrochemical cells each having a convex electrode at one end and a planar electrode at the other end are arranged in parallel, and the columnar electrochemical cell in the cell group extends in the extending direction. Convex electrode and planar electrode, convex electrode and convex electrode or surface of two adjacent columnar electrochemical cells arranged on both sides to connect a plurality of electrochemical cells with a predetermined wiring pattern The cell assembly composed of a plurality of bus bars connecting the planar electrodes and the planar electrodes is fitted to one end located in the extending direction of the plurality of columnar electrochemical cells. The holder is fitted with a bottom wall portion facing one end of the cell assembly, a peripheral wall portion rising from the peripheral edge of the bottom wall portion and extending to the cell assembly side, and end portions of a plurality of columnar electrochemical cells. A plurality of end fitting recesses and a cushioning spacer provided in the center of the bottoms of the plurality of end fitting recesses and arranged in a compressed state between the bottoms of the plurality of end fitting recesses and the bus bar And a plurality of recesses for receiving spacers. The peripheral wall portion is provided with two or more openings that communicate with at least one of the two or more end fitting recesses communicating to receive the bus bar and allow the terminal portion of the bus bar to go outside. Yes.
 より具体的なホルダは、4本の柱状電気化学セルが2本ずつ横に並ぶように並列配置されてなるセル群を有するセル集合体に対して嵌合される。したがってホルダには、4本の柱状電気化学セルの端部が嵌合される4つの端部嵌合用凹部と、4つのスペーサ収容用凹部が形成されている。4本の柱状電気化学セルに対応するホルダは、連通する2つの端部嵌合用凹部からなる2つの凹部列が並んでおり、2つの凹部列の中央位置に対応する周壁部の二箇所の部分には、それぞれ1つの開口部が形成されており、2つの凹部列の一端に対応する周壁部の二箇所の部分に、それぞれ1つの開口部が形成されていてもよい。また連通する2つの端部嵌合用凹部からなる2つの凹部列が並んでおり且つ2つの凹部列の一方に含まれる1つの前記嵌合用凹部と他方に含まれる1つの端部嵌合用凹部とが連通しており、2つの凹部列の中央位置に対応する周壁部の二箇所の部分に、それぞれ1つの開口部が形成されており、2つの凹部列の一端に対応する周壁部の二箇所の部分に、それぞれ1つの開口部が形成されていてもよい。さらに連通する2つの端部嵌合用凹部からなる2つの凹部列が並んでおり、2つの凹部列の一方に含まれる1つの端部嵌合用凹部と他方に含まれる1つの端部嵌合用凹部とが連通しており、2つの凹部列の一方に含まれる残りの1つの端部嵌合用凹部と他方に含まれる残りの1つの端部嵌合用凹部とが連通しており、2つの凹部列の中央位置に対応する周壁部の二箇所の部分に、それぞれ1つの開口部が形成されていてもよい。さらに連通する2つの端部嵌合用凹部からなる第1の凹部列と連通しない2つの端部嵌合用凹部からなる第2の凹部列とが並んでおり、第2の凹部列を構成する2つの端部嵌合用凹部を囲む周壁部の部分には、それぞれ1つの開口部が形成されていてもよい。 A more specific holder is fitted to a cell assembly having a cell group in which four columnar electrochemical cells are arranged in parallel so that two columnar electrochemical cells are arranged side by side. Therefore, the holder is formed with four end fitting recesses into which the end portions of the four columnar electrochemical cells are fitted, and four spacer receiving recesses. The holder corresponding to the four columnar electrochemical cells has two recess rows made of two end fitting recesses communicating with each other, and two portions of the peripheral wall corresponding to the center position of the two recess rows Each has one opening, and one opening may be formed in each of two portions of the peripheral wall corresponding to one end of the two recess rows. Further, two recess rows composed of two end fitting recesses communicating with each other are arranged, and one of the fitting recesses included in one of the two recess rows and one end fitting recess included in the other. One opening is formed in each of the two portions of the peripheral wall portion corresponding to the center position of the two recess rows, and two locations of the peripheral wall portion corresponding to one end of the two recess rows are communicated. One opening may be formed in each part. Further, two recess rows made of two end fitting recesses communicating with each other are arranged, one end fitting recess included in one of the two recess rows, and one end fitting recess included in the other, Are communicated with each other, and the remaining one end fitting recess included in one of the two recess rows communicates with the remaining one end fitting recess included in the other. One opening may be formed in each of two portions of the peripheral wall corresponding to the central position. Further, a first recess row composed of two communicating end fitting recesses and a second recess row composed of two end fitting recessed portions not communicating are arranged side by side, and the two constituting the second recess row One opening may be formed in each of the peripheral wall portions surrounding the end fitting recess.
 ホルダの周壁部が、同じ長さ寸法を有し且つそれぞれ直交する4つの側壁部によって構成されている場合には、4つの側壁部の同じ対角位置にそれぞれそ取り付け孔を形成するのが好ましい。このような取り付け孔を形成すれば、複数のホルダを連結する場合に、ホルダに設けた開口部の位置の如何にかかわらず、取り付け孔を利用して各ホルダを連結することができる。 When the peripheral wall portion of the holder is constituted by four side wall portions having the same length dimension and orthogonal to each other, it is preferable that the attachment holes are respectively formed at the same diagonal positions of the four side wall portions. . If such attachment holes are formed, when a plurality of holders are connected, the holders can be connected using the attachment holes regardless of the position of the opening provided in the holder.
本実施の形態の電気化学セルモジュールの構成を説明するために用いる斜視図である。It is a perspective view used in order to demonstrate the structure of the electrochemical cell module of this Embodiment. 図1の実施の形態の電気化学セルモジュールの断面図である。It is sectional drawing of the electrochemical cell module of embodiment of FIG. (A)は図1の実施の形態で用いるホルダの斜視図、(B)は図1の実施の形態で用いるホルダの平面図、(C)は図1の実施の形態で用いるホルダの底面図、(D)は図1の実施の形態で用いるホルダの右側面図、(E)は図3(B)のIIIE-IIIE線断面図、(F)は図1の実施の形態で用いるホルダの左側面図である。(A) is a perspective view of the holder used in the embodiment of FIG. 1, (B) is a plan view of the holder used in the embodiment of FIG. 1, and (C) is a bottom view of the holder used in the embodiment of FIG. , (D) is a right side view of the holder used in the embodiment of FIG. 1, (E) is a sectional view taken along line IIIE-IIIE in FIG. 3 (B), and (F) is a holder of the holder used in the embodiment of FIG. It is a left side view. 本発明のホルダの他の実施の形態の斜視図である。It is a perspective view of other embodiment of the holder of this invention. 本発明のホルダの更に他の実施の形態の斜視図である。It is a perspective view of other embodiment of the holder of this invention. 本発明のホルダの更に他の実施の形態の斜視図である。It is a perspective view of other embodiment of the holder of this invention.
 以下、図面を参照して、本発明の電気化学セルモジュール及びホルダの実施の形態について説明する。図1は、本実施の形態の電気化学セルモジュール1の構成を説明するために用いる斜視図を示しており、図2は、図1の実施の形態の電気化学セルモジュール1のII-II線断面図である。図2において、セルは断面にしていない。 Hereinafter, embodiments of the electrochemical cell module and the holder of the present invention will be described with reference to the drawings. FIG. 1 shows a perspective view used for explaining the configuration of the electrochemical cell module 1 of the present embodiment, and FIG. 2 shows the II-II line of the electrochemical cell module 1 of the embodiment of FIG. It is sectional drawing. In FIG. 2, the cell is not cross-sectional.
 この電気化学セルモジュール1は、セル集合体3と、第1及び第2のホルダ5及び7とから構成される。セル集合体3は、図1に示すように一端に凸状電極9を有し且つ他端に面状電極11を有する柱状電気化学セルの一種である柱状のリチウムイオンキャパシタ13A~13Dが4本並列配置されてなるセル群15と、セル群15に含まれる4本のリチウムイオンキャパシタ13A~13Dが延びる方向の両側にそれぞれ配置されて、4本のリチウムイオンキャパシタ13A~13Dの電極に溶接されるバスバ17~20とから構成される。リチウムイオンキャパシタ13A~13Dは、缶の外面が絶縁樹脂チューブにより被覆された構造を有している。この例では、4本のバスバ17~20により、2本のリチウムイオンキャパシタ13A及び13Bと2本のリチウムイオンキャパシタ13C及び13Dが直列接続された2組のセルユニットが並列接続された配線パターンになるように、隣り合う2本のリチウムイオンキャパシタ13A~13Dの凸状電極9と凸状電極9と、面状電極11と面状電極11とを接続している。4本のバスバ17~20は、ニッケル、鉄、銅、アルミニウム等の抵抗値が低い導電性材料や銅材にスズメッキやニッケルメッキを施しものをプレス成形して形成したものである。なお4本のリチウムイオンキャパシタ13A~13Dにより構成する配線パターンに応じて、使用するバスバの形状及び個数が異なるのは当然である。本実施の形態で用いるバスバ17及び18は、凸状電極9と接続される際に凸状電極9の先端を露出させる貫通孔17A及び18Aと端子部17B及び18Bを備えている。バスバ19及び20は、面状電極11と接続される際に面状電極11を部分的に露出させる貫通孔19A及び20Aと端子部19B及び20Bを備えている。本実施の形態では、バスバ17~20をハンダや抵抗溶接により電気化学セル13の電極(9,11)に接続して、セル集合体3が事前に構成される。 The electrochemical cell module 1 is composed of a cell assembly 3 and first and second holders 5 and 7. As shown in FIG. 1, the cell assembly 3 includes four columnar lithium ion capacitors 13A to 13D, which are a kind of columnar electrochemical cell having a convex electrode 9 at one end and a planar electrode 11 at the other end. The cell group 15 arranged in parallel and the four lithium ion capacitors 13A to 13D included in the cell group 15 are arranged on both sides in the extending direction and welded to the electrodes of the four lithium ion capacitors 13A to 13D. Bus bars 17-20. The lithium ion capacitors 13A to 13D have a structure in which the outer surface of the can is covered with an insulating resin tube. In this example, four bus bars 17 to 20 form a wiring pattern in which two sets of cell units in which two lithium ion capacitors 13A and 13B and two lithium ion capacitors 13C and 13D are connected in series are connected in parallel. In this manner, the convex electrode 9 and the convex electrode 9 of the two adjacent lithium ion capacitors 13A to 13D, the planar electrode 11 and the planar electrode 11 are connected. The four bus bars 17 to 20 are formed by press-molding a conductive material or copper material having a low resistance value such as nickel, iron, copper, or aluminum, which is plated with tin or nickel. Of course, the shape and the number of bus bars to be used differ depending on the wiring pattern constituted by the four lithium ion capacitors 13A to 13D. The bus bars 17 and 18 used in the present embodiment include through holes 17A and 18A and terminal portions 17B and 18B that expose the tips of the convex electrodes 9 when connected to the convex electrodes 9. The bus bars 19 and 20 include through-holes 19A and 20A and terminal portions 19B and 20B that partially expose the planar electrode 11 when connected to the planar electrode 11. In the present embodiment, the bus assembly 17 is configured in advance by connecting the bus bars 17 to 20 to the electrodes (9, 11) of the electrochemical cell 13 by soldering or resistance welding.
 第1のホルダ5は、セル集合体3のリチウムイオンキャパシタ13A~13Dが延びる方向に位置する一端に嵌合されている。また第2のホルダは、セル集合体3のリチウムイオンキャパシタ13A~13Dが延びる方向に位置する他端に嵌合されている。本実施の形態では、図3(A)乃至(F)に示す同じ形状のホルダを第1及び第2のホルダ5及び7として使用している。第2のホルダ7は第1のホルダ5に対して90°回転させた姿勢でセル集合体3に嵌合されている。 The first holder 5 is fitted to one end of the cell assembly 3 positioned in the direction in which the lithium ion capacitors 13A to 13D extend. The second holder is fitted to the other end of the cell assembly 3 positioned in the direction in which the lithium ion capacitors 13A to 13D extend. In the present embodiment, the holders having the same shape shown in FIGS. 3A to 3F are used as the first and second holders 5 and 7. The second holder 7 is fitted to the cell assembly 3 in a posture rotated by 90 ° with respect to the first holder 5.
 以下図3を参照して、ホルダ5の構造を説明する。本実施の形態で使用するホルダ5は、絶縁樹脂材料により一体に成形されており、底壁部21と周壁部22とを備えている。底壁部21は、ほぼ矩形状の輪郭を有してセル集合体3の一端または他端と対向する。底壁部21には、その中心部に図1に示した支柱16を固定するための図示しない頭部付きのネジを挿入する中心孔23が形成されている。また図3(C)に示すように、底壁部21の4つの辺21A乃至21Dのうち対向する2つの辺21A及び21Cには、中心孔23に向かって凸となるように形成されて底壁部21の厚み方向に貫通し且つ中心孔23から離れる方向に開口する半円弧状の凹部21E及び21Fが形成されている。この凹部21E及び21Fは、バスバの端子部を露出させるために利用される。また底壁部21には、辺21A及び21Cと直交し中心孔23を通る仮想線L1と、辺21B及び21Dと直交し中心孔23を通る仮想線L2が通る位置に、それぞれ電圧検出用リード線を通すことが可能な直径を有する貫通孔24が4個形成されている。4個の貫通孔24は、それぞれ中心孔23の回りに90°ずつ角度間隔を開けて形成されている。このように電圧検出用リード線を引き出す貫通孔24を設ければ、ホルダ5をセル集合体3に対してどのような位置関係で嵌合させたとしても、電圧検出用リード線をあまり長く引き廻すことなく、4つの貫通孔24のいずれ1つから外部に引き出すことができる。更に底壁部21には、底壁部21の4つの角部に対して想定される2本の対角線上にそれぞれ位置するように4つの貫通孔25が形成されている。この貫通孔25の機能については後に説明する。また底壁部21には、前述の仮想線L2が通る位置に、2つの貫通孔26が形成されている。この貫通孔は、取り付け孔である。 Hereinafter, the structure of the holder 5 will be described with reference to FIG. The holder 5 used in the present embodiment is integrally formed of an insulating resin material and includes a bottom wall portion 21 and a peripheral wall portion 22. The bottom wall portion 21 has a substantially rectangular outline and faces one end or the other end of the cell assembly 3. A center hole 23 into which a screw with a head (not shown) for fixing the support 16 shown in FIG. 1 is inserted is formed in the bottom wall portion 21. Further, as shown in FIG. 3C, the two opposite sides 21A and 21C among the four sides 21A to 21D of the bottom wall portion 21 are formed so as to protrude toward the center hole 23 and are bottom. Semicircular arc-shaped recesses 21 </ b> E and 21 </ b> F penetrating in the thickness direction of the wall portion 21 and opening away from the center hole 23 are formed. The recesses 21E and 21F are used for exposing the terminal portion of the bus bar. The bottom wall portion 21 has voltage detection leads at positions where a virtual line L1 orthogonal to the sides 21A and 21C and passing through the central hole 23 and a virtual line L2 orthogonal to the sides 21B and 21D and passing through the central hole 23 pass. Four through holes 24 having a diameter through which a wire can pass are formed. The four through-holes 24 are formed at an angular interval of 90 ° around the center hole 23, respectively. If the through hole 24 for drawing out the voltage detection lead wire is provided in this way, the voltage detection lead wire is drawn too long regardless of the positional relationship between the holder 5 and the cell assembly 3. Without turning, it can be pulled out from any one of the four through holes 24. Furthermore, four through holes 25 are formed in the bottom wall portion 21 so as to be positioned on two diagonal lines assumed for the four corner portions of the bottom wall portion 21. The function of the through hole 25 will be described later. Further, two through holes 26 are formed in the bottom wall portion 21 at a position where the above-described virtual line L2 passes. This through hole is an attachment hole.
 底壁部21の周縁部から立ち上がってセル集合体3側に延びる周壁部22は、同じ長さ寸法を有し且つそれぞれ直交する4つの側壁部22A~22Dによって構成されている。対向する一対の側壁部22A及び22Cには、底壁部21に形成した一対の凹部21E及び21Fと連通する一対の開口部22E及び22Fが形成されている。また側壁部22Bには、2つの開口部22G及び22Hが形成されている。 The peripheral wall portion 22 that rises from the peripheral edge portion of the bottom wall portion 21 and extends toward the cell assembly 3 side is composed of four side wall portions 22A to 22D that have the same length and are orthogonal to each other. A pair of opening portions 22E and 22F communicating with a pair of recesses 21E and 21F formed in the bottom wall portion 21 are formed in the pair of opposing side wall portions 22A and 22C. In addition, two openings 22G and 22H are formed in the side wall 22B.
 ホルダ5内には、底壁部21と周壁部22とによって囲まれて形成されて、4本のリチウムイオンキャパシタ13A~13Dの端部が嵌合される4つの端部嵌合用凹部28A~28Dがある。4つの端部嵌合用凹部28A~28Dは、その底部に、バスバ17~20と底壁部21との間に圧縮状態で配置される緩衝用スペーサ29を収容するスペーサ収容用凹部30A~30Dを備えている。緩衝用スペーサ29は、リング状のゴムによって構成されている。このような緩衝用スペーサ29を設ければ、2つのホルダ5及び7を、4本のリチウムイオンキャパシタの配置方向の如何にかかわらず、圧縮変形した緩衝用スペーサ29により、バスバ17~20の一部と端部嵌合用凹部28A~28Dの底部との間のスペースを埋めて、セル集合体3を第1及び第2のホルダ5及び7間に保持することができる。 The holder 5 is surrounded by the bottom wall portion 21 and the peripheral wall portion 22 and is formed with four end fitting recesses 28A to 28D into which the ends of the four lithium ion capacitors 13A to 13D are fitted. There is. The four end fitting recesses 28A to 28D are provided with spacer receiving recesses 30A to 30D for receiving buffer spacers 29 arranged in a compressed state between the bus bars 17 to 20 and the bottom wall 21 at the bottoms thereof. I have. The buffer spacer 29 is made of a ring-shaped rubber. If such a buffer spacer 29 is provided, the two holders 5 and 7 are connected to one of the bus bars 17 to 20 by the buffer spacer 29 that is compressed and deformed regardless of the arrangement direction of the four lithium ion capacitors. The cell assembly 3 can be held between the first and second holders 5 and 7 by filling a space between the first portion and the bottom of the end fitting concave portions 28A to 28D.
 4つの端部嵌合用凹部28A~28Dのうち、2つの端部嵌合用凹部28A及び28Dは、2本のリチウムイオンキャパシタ13A及び13Dに跨って配置されるバスバ18を受け入れるように連通している。また2つの端部嵌合用凹部28B及び28Cは、2本のリチウムイオンキャパシタ13B及び13Dに跨って配置されるバスバ17を受け入れるように連通している。このような構成を採用した結果、ホルダ5内には、1本の仕切壁部31が形成されている。 Of the four end fitting recesses 28A to 28D, the two end fitting recesses 28A and 28D communicate with each other so as to receive the bus bar 18 disposed across the two lithium ion capacitors 13A and 13D. . Further, the two end fitting recesses 28B and 28C communicate with each other so as to receive the bus bar 17 disposed across the two lithium ion capacitors 13B and 13D. As a result of adopting such a configuration, one partition wall portion 31 is formed in the holder 5.
 本実施の形態では、バスバ18を受け入れるように連通している2つの端部嵌合用凹部28A及び28Dを囲む周壁部22の側壁部22Aに、2つの端部嵌合用凹部28A及び28Dの中間位置に対応して1つの開口部22Eが形成されており、バスバ17を受け入れるように連通している2つの端部嵌合用凹部28B及び28Cを囲む周壁部22の側壁部22Cに、2つの端部嵌合用凹部28B及び28Cの中間位置に対応して1つの開口部22Fが形成されており、さらに2つの端部嵌合用凹部28A及び28Dが並ぶ方向に開口する開口部22Gと2つの端部嵌合用凹部28B及び28Cが並ぶ方向に開口する開口部22Hが側壁部22Bに形成されている。この例では開口部22G及び22Hが、同じ方向に向かって開口しているが、2つの開口部22G及び22Hの一方を側壁部22Dに形成して、2つの開口部22G及び22Hが互いに逆向きに開口するようにしてもよいのは勿論である。このような4つの開口部22E~22Gをホルダ5及び7に設けると、並列、直列、直並列等の各種の配線パターンで複数の柱状のリチウムイオンキャパシタを接続する場合に、一方のホルダ5に対して他方のホルダ7を回転させて両ホルダの位置関係を定めることにより、殆どの配線パターンを実現できるようになり、ホルダの汎用性が高くなる。 In the present embodiment, the side wall portion 22A of the peripheral wall portion 22 surrounding the two end portion fitting recesses 28A and 28D communicating with each other so as to receive the bus bar 18 has an intermediate position between the two end portion fitting recesses 28A and 28D. Are formed in the side wall portion 22C of the peripheral wall portion 22 surrounding the two end fitting recesses 28B and 28C communicating with each other so as to receive the bus bar 17. One opening 22F is formed corresponding to an intermediate position between the fitting recesses 28B and 28C, and an opening 22G and two end fittings that open in the direction in which the two end fitting recesses 28A and 28D are arranged. An opening 22H that opens in the direction in which the combination recesses 28B and 28C are arranged is formed in the side wall 22B. In this example, the openings 22G and 22H open in the same direction, but one of the two openings 22G and 22H is formed on the side wall 22D, and the two openings 22G and 22H are opposite to each other. Of course, it may be made to open. When such four openings 22E to 22G are provided in the holders 5 and 7, when connecting a plurality of columnar lithium ion capacitors in various wiring patterns such as parallel, series, and series / parallel, one holder 5 is provided. On the other hand, by rotating the other holder 7 to determine the positional relationship between the two holders, almost all wiring patterns can be realized, and the versatility of the holder is enhanced.
 なお図1に示すように、バスバ17はホルダ5の連通する2つの端部嵌合用凹部28B及び28C内に配置され、バスバ28はホルダ5の連通する2つの端部嵌合用凹部28A及び28D内に配置される。そしてバスバ17の端子部17Bは、開口部22Hから外部に延び出ており、バスバ18の端子部18Bは、開口部22Gから外部に延び出ている。バスバ19はホルダ7の連通する2つの端部嵌合用凹部28B及び28C内に配置され、バスバ20はホルダ7の連通する2つの端部嵌合用凹部28A及び28D内に配置される。そしてバスバ19の端子部19Bは、開口部22Hから外部に延び出ており、バスバ20の端子部20Bは、開口部2Gから外部に延び出ている。 As shown in FIG. 1, the bus bar 17 is disposed in the two end fitting recesses 28 </ b> B and 28 </ b> C that communicate with the holder 5, and the bus bar 28 is disposed in the two end fitting recesses 28 </ b> A and 28 </ b> D that communicate with the holder 5. Placed in. And the terminal part 17B of the bus bar 17 is extended outside from the opening part 22H, and the terminal part 18B of the bus bar 18 is extended outside from the opening part 22G. The bus bar 19 is disposed in the two end fitting recesses 28 </ b> B and 28 </ b> C that communicate with the holder 7, and the bus bar 20 is disposed in the two end fitting recesses 28 </ b> A and 28 </ b> D that communicate with the holder 7. And the terminal part 19B of the bus bar 19 is extended outside from the opening part 22H, and the terminal part 20B of the bus bar 20 is extended outside from the opening part 2G.
 図4は、本発明のホルダの他の実施の形態の斜視図である。このホルダ5′は、図3に示したホルダ5の端部嵌合用凹部28C及び28Dの間を仕切っていた仕切壁部31の部分を取り除いた点を除いて図3のホルダと同じ構造を有している。本実施の形態のホルダ5′では、4つの端部嵌合用凹部28A~28Dが、28A→28D→28C→28Bの順番で直列に連通している。別の見方をすると、連通する端部嵌合用凹部28A及び28Dからなる1つの凹部列と、連通する端部嵌合用凹部28D及び28Cからなる1つの凹部列28Cとが並んでおり、2つの凹部列の一方に含まれる1つの嵌合用凹部28Dと他方に含まれる1つの端部嵌合用凹部28Cとが連通しており、2つの凹部列の中央位置に対応する周壁部の側壁部22A及び22Cの中央部部分に、それぞれ1つの開口部22E及び22Fが形成されている。そして2つの凹部列の一端に対応する周壁部22Bの二箇所の部分に、それぞれ開口部22G及び22Hが形成されている。このホルダ5′では、図3のホルダと比べて端部嵌合用凹部28C及び28Dが連通しているため、図3のホルダ5と比べて更に汎用性が高くなる。 FIG. 4 is a perspective view of another embodiment of the holder of the present invention. This holder 5 'has the same structure as that of the holder of FIG. 3 except that the partition wall portion 31 partitioning between the end fitting recesses 28C and 28D of the holder 5 shown in FIG. 3 is removed. is doing. In the holder 5 ′ of the present embodiment, the four end fitting recesses 28A to 28D communicate in series in the order of 28A → 28D 28C → 28B. From another point of view, one recess row made of communicating end fitting recesses 28A and 28D and one recess row 28C made of communicating end fitting recesses 28D and 28C are arranged side by side. One fitting recess 28D included in one of the rows communicates with one end fitting recess 28C included in the other, and the side wall portions 22A and 22C of the peripheral wall portion corresponding to the center position of the two recess rows. One opening 22E and 22F is formed in the central part of each. Openings 22G and 22H are formed in two portions of the peripheral wall portion 22B corresponding to one end of the two recess rows. In this holder 5 ', since the end fitting recesses 28C and 28D communicate with each other as compared with the holder of FIG.
 図5は、本発明のホルダの更に他の実施の形態の斜視図である。このホルダ5″は、図3に示したホルダ5の端部嵌合用凹部28C及び28Dの間を仕切っていた仕切壁部31の部分と図3に示したホルダ5の端部嵌合用凹部28A及び28Bの間を仕切っていた仕切壁部31の部分の両方が除かれ、図3のホルダ5の側壁部22Bに形成されていた開口部22G及び22Hが塞がれている点を除いて、図3のホルダ5と同じ構造を有している。本実施の形態のホルダ5″では、4つの端部嵌合用凹部28A~28Dが、閉ループ状に連通している。見方を変えると、このホルダ5″では、連通する端部嵌合用凹部28A及び28Dからなる1つの凹部列と、連通する端部嵌合用凹部28D及び28Cからなる1つの凹部列28Cとが並んでおり、2つの凹部列の一方に含まれる1つの嵌合用凹部28Dと他方に含まれる1つの端部嵌合用凹部28Cとが連通しており、2つの凹部列の一方に含まれる残りの1つの端部嵌合用凹部28Aと他方に含まれる残りの1つの端部嵌合用凹部28Bとが連通している。そして2つの凹部列の中央位置に対応する周壁部の側壁部22A及び22Cの中央部部分に、それぞれ1つの開口部22E及び22Fが形成されている。このホルダ5″では、図3のホルダと比べて開口部の数は半減しているが、端部嵌合用凹部28A~28Dが閉ループ状に連通しているため、図3のホルダ5と同程度に汎用性が高くなる。 FIG. 5 is a perspective view of still another embodiment of the holder of the present invention. This holder 5 ″ includes the part of the partition wall 31 that partitions the end fitting recesses 28C and 28D of the holder 5 shown in FIG. 3 and the end fitting recess 28A of the holder 5 shown in FIG. The part of the partition wall 31 that partitioned the space 28B is removed, except that the openings 22G and 22H formed in the side wall 22B of the holder 5 in FIG. 3 are closed. 3 has the same structure as the holder 5. In the holder 5 ″ of the present embodiment, four end fitting recesses 28A to 28D communicate in a closed loop. In other words, in this holder 5 ″, one recess row composed of communicating end fitting recesses 28A and 28D and one recess row 28C composed of communicating end fitting recesses 28D and 28C are arranged side by side. One fitting recess 28D included in one of the two recess rows communicates with one end fitting recess 28C included in the other, and the remaining one included in one of the two recess rows The end fitting recess 28A communicates with the other end fitting recess 28B included in the other, and the central portions of the side wall portions 22A and 22C of the peripheral wall portions corresponding to the center positions of the two recess rows. One opening 22E and 22F is formed in each part. In this holder 5 ″, the number of openings is halved compared to the holder of FIG. 3, but the end fitting recesses 28A to 28D are provided. Communicating in a closed loop And for that versatility is increased to the same extent as the holder 5 in FIG.
 図6は、本発明のホルダの更に他の実施の形態の斜視図である。このホルダ5*では、仕切壁部31´と、連通する2つの端部嵌合用凹部28C及び28Dからなる第1の凹部列と、連通しない2つの端部嵌合用凹部28A及び28Bからなる第2の凹部列とが並んでいる。そして第2の凹部列を構成する2つの端部嵌合用凹部28A及び28Bを囲む周壁部の部分(側壁部22A及び22C)には、それぞれ1つの開口部22E及び22Fが形成されている。このホルダ5*では、連通する2つの端部嵌合用凹部28C及び28Dからなる第1の凹部列に対しては、バスバを外部に引き出す開口部が設けられていないが、配線パターンによっては、このような構造でも特に問題となることはない。 FIG. 6 is a perspective view of still another embodiment of the holder of the present invention. In this holder 5 *, the partition wall portion 31 ', the first recess row composed of two end fitting recesses 28C and 28D communicating with each other, and the second end fitting recess 28A and 28B not communicating with each other are provided. Are arranged in parallel with the recess rows. One opening 22E and 22F is formed in each of the peripheral wall portions ( side walls 22A and 22C) surrounding the two end fitting recesses 28A and 28B constituting the second recess row. In this holder 5 *, there is no opening for pulling out the bus bar to the outside of the first recess row composed of the two end fitting recesses 28C and 28D that communicate with each other. Such a structure is not particularly problematic.
 上記実施の形態の電気化学セルモジュール1を、複数集合させて相互に電気的に接続することにより大容量の電気化学セルモジュールを構成することが可能である。 It is possible to construct a large capacity electrochemical cell module by collecting a plurality of electrochemical cell modules 1 of the above embodiment and electrically connecting them.
 また上記実施の形態では、電気化学セルとしてリチウムイオンキャパシタを用いたが、電気化学セルとしては、電気二重層コンデンサ、リチウムイオン電池、その他の二次電池を用いてもよいのは勿論である。 In the above embodiment, a lithium ion capacitor is used as the electrochemical cell. However, as an electrochemical cell, it is needless to say that an electric double layer capacitor, a lithium ion battery, or another secondary battery may be used.
 また上記実施の形態の電気化学セルモジュール1では支柱16によって第1及び第2のホルダ5,7を引き付けているが、第1及び第2のホルダ5及び7とセル集合体3を囲むようにベルト状部材を配置して、モジュールを外側から締め付けることにより、第1及び第2のホルダ5,7を引き付けるようにしてもよい。 Further, in the electrochemical cell module 1 of the above embodiment, the first and second holders 5 and 7 are attracted by the support column 16, but so as to surround the first and second holders 5 and 7 and the cell assembly 3. You may make it attract the 1st and 2nd holders 5 and 7 by arrange | positioning a belt-shaped member and fastening a module from the outside.
 上記実施の形態では緩衝用スペーサ29としてゴム材料で形成されたものを用いたが、圧縮されると変形し且つ弾性を有する材料であれば、ゴム材料以外の材料で緩衝用スペーサ29を形成してもよい。 In the above embodiment, the buffer spacer 29 made of a rubber material is used. However, the buffer spacer 29 is formed of a material other than the rubber material as long as it is deformed and elastic when compressed. May be.
 緩衝用スペーサ29の効果を確認するために振動試験を実施した結果、緩衝用スペーサ29の存在により耐振性が向上することを確認した。図1の実施の形態において、緩衝用スペーサ29を設けたものと、設けないものに、下記の試験条件でランダム振動試験を実施した。 As a result of conducting a vibration test to confirm the effect of the buffer spacer 29, it was confirmed that the vibration resistance was improved by the presence of the buffer spacer 29. In the embodiment shown in FIG. 1, a random vibration test was carried out under the following test conditions for the case where the buffer spacer 29 was provided and the case where the buffer spacer 29 was not provided.
 試験条件 ランダム振動試験
        上下 4.3G×5h
        左右 3.8G×5h
        前後 2.0G×5h
 その結果、4本のセルとホルダとの接触による、セルの外面を覆う絶縁チューブが振動により粉末状に飛散し缶がむき出しとなった。これに対して緩衝用スペーサ29を入れた本実施の形態では、セルの外観に異常は見られなかった。また本実施の形態において、加速度10Gの条件で振動試験を行ったが、セルの外観に異常は見られず、緩衝用スペーサを入れることで、耐震性が向上していることが確認された。
Test conditions Random vibration test Up / down 4.3G × 5h
Left and right 3.8G × 5h
Front and rear 2.0G × 5h
As a result, due to the contact between the four cells and the holder, the insulating tube covering the outer surface of the cell was scattered in powder form by vibration, and the can was exposed. In contrast, in the present embodiment in which the buffer spacer 29 was inserted, no abnormality was observed in the appearance of the cell. Further, in this embodiment, a vibration test was performed under the condition of an acceleration of 10 G. However, no abnormality was observed in the appearance of the cell, and it was confirmed that the earthquake resistance was improved by inserting a buffer spacer.
 また上記実施の形態の電気化学セルモジュール1は、4本の電気化学セル(13A~13D)からなるセル集合体3を備えているが、セル集合体3に含まれる電解化学セルの本数は、特に限定されるものではない。 The electrochemical cell module 1 of the above embodiment includes a cell assembly 3 composed of four electrochemical cells (13A to 13D). The number of electrochemical cells included in the cell assembly 3 is as follows. It is not particularly limited.
 更に上記実施の形態ではバスバ17~20が、すべて隣り合う2つの電気化学セルを接続するタイプのものであるが、配線パターンによっては、1つの電気化学セルの電極にのみ接続されるバスバが電気化学セルモジュール1内に含まれていてもよいのは勿論である。 Furthermore, in the above embodiment, the bus bars 17 to 20 are of a type in which all two adjacent electrochemical cells are connected. However, depending on the wiring pattern, the bus bar connected only to the electrode of one electrochemical cell may be electrically connected. Of course, it may be included in the chemical cell module 1.
 図1の実施の形態では、同種類のホルダを2つ用いているが、配線パターンに応じて、図3乃至図6に示される複数種類のホルダを組み合わせて使用してもよいのは勿論である。 In the embodiment of FIG. 1, two holders of the same type are used. Of course, a plurality of types of holders shown in FIGS. 3 to 6 may be used in combination depending on the wiring pattern. is there.
 本発明によれば、緩衝用スペーサを配置したことにより、電気化学セルの配置方向の如何にかかわらず、圧縮変形した緩衝用スペーサによって、バスバの一部と端部嵌合用凹部の底部との間のスペースを埋めて、セル集合体を第1及び第2のホルダ間にガタツキ無く保持することができる。 According to the present invention, since the buffer spacer is arranged, the compression buffer spacer between the part of the bus bar and the bottom of the end fitting recess is compressed regardless of the arrangement direction of the electrochemical cell. The cell assembly can be held between the first and second holders without rattling.
 1 電気化学セルモジュール
 3 セル集合体
 5 第1のホルダ
 7 第2のホルダ
 9 凸状電極
 11 面状電極
 13A~13D リチウムイオンキャパシタ(電気化学セル)
 15 セル群
 16 支柱
 17~20 バスバ
 21 底壁部
 22 周壁部
 22A~22D 側壁部
 22E~22H 開口部
 23 中心孔
 24 貫通孔
 25 貫通孔
 26 貫通孔
 28A~28D 端部嵌合用凹部
 29 緩衝用スペーサ
 30A~30D スペーサ収容用凹部
 31 仕切壁部
DESCRIPTION OF SYMBOLS 1 Electrochemical cell module 3 Cell aggregate | assembly 5 1st holder 7 2nd holder 9 Convex electrode 11 Planar electrode 13A-13D Lithium ion capacitor (electrochemical cell)
15 cell group 16 support 17-20 bus bar 21 bottom wall 22 peripheral wall 22A-22D side wall 22E-22H opening 23 center hole 24 through hole 25 through hole 26 through hole 28A-28D end fitting recess 29 buffer spacer 30A to 30D Spacer receiving recess 31 Partition wall

Claims (15)

  1.  一端に凸状電極を有し且つ他端に面状電極を有する複数本の柱状電気化学セルが並列配置されてなるセル群と、前記セル群の前記複数本の柱状電気化学セルが延びる方向の両側に配置されて、前記複数本の電気化学セルを所定の配線パターンで接続するように、隣り合う2本以上の前記柱状電気化学セルの前記凸状電極と前記面状電極、前記凸状電極と前記凸状電極または前記面状電極と前記面状電極を接続する複数のバスバとからなるセル集合体と、
     前記セル集合体の前記複数本の柱状電気化学セルが延びる方向に位置する一端に嵌合される第1のホルダと、
     前記セル集合体の前記複数本の柱状電気化学セルが延びる方向に位置する他端に嵌合される第2のホルダとを備え、
     前記第1及び第2のホルダは、前記複数本の柱状電気化学セルの端部が嵌合される複数の端部嵌合用凹部を備えており、
     前記複数の端部嵌合用凹部の底部と前記バスバとの間に圧縮状態で緩衝用スペーサが配置されていることを特徴とする電気化学セルモジュール。
    A cell group in which a plurality of columnar electrochemical cells having a convex electrode at one end and a planar electrode at the other end are arranged in parallel; and a direction in which the plurality of columnar electrochemical cells of the cell group extend The convex electrode, the planar electrode, and the convex electrode of two or more columnar electrochemical cells adjacent to each other so as to connect the plurality of electrochemical cells with a predetermined wiring pattern disposed on both sides And a plurality of bus bars connecting the convex electrode or the planar electrode and the planar electrode,
    A first holder fitted to one end located in a direction in which the plurality of columnar electrochemical cells of the cell assembly extend;
    A second holder fitted to the other end of the cell assembly located in the extending direction of the plurality of columnar electrochemical cells;
    The first and second holders include a plurality of end fitting recesses into which end portions of the plurality of columnar electrochemical cells are fitted,
    A buffer cell spacer is disposed in a compressed state between bottoms of the plurality of end fitting recesses and the bus bar.
  2.  前記端部嵌合用凹部の前記底部には、前記緩衝用スペーサが圧縮可能な状態で収容されるスペーサ嵌合用凹部が形成されている請求項1に記載の電気化学セルモジュール。 2. The electrochemical cell module according to claim 1, wherein a spacer fitting recess for accommodating the buffer spacer in a compressible state is formed at the bottom of the end fitting recess.
  3.  前記緩衝用スペーサ及び前記スペーサ収容用凹部の底部には、それぞれ整合する貫通孔が形成されている請求項1に記載の電気化学セルモジュール。 2. The electrochemical cell module according to claim 1, wherein matching buffering holes are formed in bottom portions of the buffer spacer and the spacer receiving recess.
  4.  1つの前記バスバは、外部接続用の1以上の端子部を備えており、
     前記ホルダは、前記セル集合体の前記一端または他端と対向する底壁部と、該底壁部の周縁部から立ち上がって前記セル集合体側に延びる周壁部とを備え、前記周壁部には、前記バスバを受け入れるように連通している2以上の前記端部嵌合用凹部の少なくとも1つと連通して前記バスバの前記端子部が外部に出ることを許容する2以上の開口部を備えている請求項1乃至3のいずれか1項に記載の電気化学セルモジュール。
    One said bus bar is provided with one or more terminal parts for external connection,
    The holder includes a bottom wall portion that faces the one end or the other end of the cell assembly, and a peripheral wall portion that rises from a peripheral portion of the bottom wall portion and extends toward the cell assembly side. Two or more openings that communicate with at least one of the two or more end fitting recesses that communicate with each other so as to receive the bus bar and allow the terminal portion of the bus bar to go outside. Item 4. The electrochemical cell module according to any one of Items 1 to 3.
  5.  前記バスバを受け入れるように連通している2つの前記端部嵌合用凹部を囲む前記周壁部には、2つの前記端部嵌合用凹部の中間位置に対応して1つの前記開口部が形成されてり、2つの前記端部嵌合用凹部が並ぶ方向に開口する別の前記開口部が形成されている請求項4に記載の電気化学セルモジュール。 One opening is formed in the peripheral wall portion surrounding the two end fitting recesses communicating with each other so as to receive the bus bar, corresponding to an intermediate position between the two end fitting recesses. 5. The electrochemical cell module according to claim 4, wherein another opening that opens in a direction in which the two end fitting recesses are arranged is formed.
  6.  前記複数の端部嵌合用凹部がすべて直列に連通している請求項4に記載の電気化学セルモジュール。 The electrochemical cell module according to claim 4, wherein all of the plurality of end fitting recesses communicate in series.
  7.  前記複数の端部嵌合用凹部が、閉ループ状に連通している請求項4に記載の電気化学セルモジュール。 The electrochemical cell module according to claim 4, wherein the plurality of end fitting recesses communicate in a closed loop.
  8.  前記底壁部には、電圧検出用リード線を引き出す4つの貫通孔が、前記底壁部の中心の回りに90°ずつ角度間隔を開けて形成されている請求項4に記載の電気化学セルモジュール。 5. The electrochemical cell according to claim 4, wherein the bottom wall portion is formed with four through-holes through which a voltage detection lead wire is pulled out at an angular interval of 90 ° around the center of the bottom wall portion. module.
  9.  一端に凸状電極を有し且つ他端に面状電極を有する複数の柱状電気化学セルが並列配置されてなるセル群と、前記セル群の前記柱状電気化学セルが延びる方向の両側に配置されて、前記複数本の電気化学セルを所定の配線パターンで接続するように、隣り合う2本の前記柱状電気化学セルの前記凸状電極と前記面状電極、前記凸状電極と前記凸状電極または前記面状電極と前記面状電極を接続する複数のバスバとからなるセル集合体の、前記複数本の柱状電気化学セルが延びる方向に位置する一端に嵌合されるホルダであって、
     前記セル集合体の前記一端と対向する底壁部と、
     該底壁部の周縁部から立ち上がって前記セル集合体側に延びる周壁部と、
     前記複数本の柱状電気化学セルの端部が嵌合される複数の端部嵌合用凹部と、
     前記複数の端部嵌合用凹部の底部の中央に設けられて、前記複数の端部嵌合用凹部の底部と前記バスバとの間に圧縮状態で配置される緩衝用スペーサを収容する複数のスペーサ収容用凹部と、
     前記周壁部に設けられて、前記バスバを受け入れるように連通している2以上の前記端部嵌合用凹部の少なくとも1つと連通して前記バスバの端子部が外部に出ることを許容する2以上の開口部とを備えているホルダ。
    A cell group in which a plurality of columnar electrochemical cells having a convex electrode at one end and a planar electrode at the other end are arranged in parallel, and arranged on both sides of the cell group in the direction in which the columnar electrochemical cell extends. The convex electrodes and the planar electrodes, and the convex electrodes and the convex electrodes of the two adjacent columnar electrochemical cells so that the plurality of electrochemical cells are connected with a predetermined wiring pattern. Or a holder fitted to one end of the cell assembly composed of the planar electrode and a plurality of bus bars connecting the planar electrode, the end being located in the extending direction of the plurality of columnar electrochemical cells,
    A bottom wall facing the one end of the cell assembly;
    A peripheral wall that rises from the peripheral edge of the bottom wall and extends toward the cell assembly;
    A plurality of end fitting recesses into which end portions of the plurality of columnar electrochemical cells are fitted;
    A plurality of spacer housings that are provided in the center of the bottoms of the plurality of end fitting recesses and receive buffer spacers disposed in a compressed state between the bottoms of the plurality of end fitting recesses and the bus bar A recess for
    Two or more terminals that are provided on the peripheral wall portion and communicate with at least one of the two or more end fitting recesses that communicate with each other so as to receive the bus bar, and allow the terminal portion of the bus bar to go outside. A holder having an opening.
  10.  一端に凸状電極を有し且つ他端に面状電極を有する4本の柱状電気化学セルが2本ずつ横に並ぶように並列配置されてなるセル群と、前記セル群の前記4本の柱状電気化学セルが延びる方向の両側に配置されて、前記4本の電気化学セルを所定の配線パターンで接続するように、隣り合う2本の前記柱状電気化学セルの前記凸状電極と前記面状電極、前記凸状電極と前記凸状電極または前記面状電極と前記面状電極を接続する複数のバスバとからなるセル集合体の前記複数本の柱状電気化学セルが延びる方向に位置する一端に嵌合されるホルダであって、
     前記セル集合体の前記一端と対向する底壁部と、
     該底壁部の周縁部から立ち上がって前記セル集合体側に延びる周壁部と、
     前記4本の柱状電気化学セルの端部が嵌合される4つの端部嵌合用凹部と、
     前記4つの端部嵌合用凹部の底部の中央に設けられて、前記複数の端部嵌合用凹部の底部と前記バスバとの間に圧縮状態で配置される緩衝用スペーサを収容する4つのスペーサ収容用凹部と、
     前記周壁部に設けられて、前記バスバを受け入れるように連通している2以上の前記端部嵌合用凹部の少なくとも1つと連通して前記バスバの前記端子部が外部に出ることを許容する2以上の開口部を備えているホルダ。
    A cell group in which four columnar electrochemical cells each having a convex electrode at one end and a planar electrode at the other end are arranged side by side so as to be lined side by side; and the four groups of the cell group The convex electrodes and the surfaces of the two adjacent columnar electrochemical cells are arranged on both sides in the direction in which the columnar electrochemical cells extend and connect the four electrochemical cells with a predetermined wiring pattern. One end located in the direction in which the plurality of columnar electrochemical cells extend in a cell assembly composed of a cylindrical electrode, the convex electrode and the convex electrode, or a plurality of bus bars connecting the planar electrode and the planar electrode A holder fitted to
    A bottom wall facing the one end of the cell assembly;
    A peripheral wall that rises from the peripheral edge of the bottom wall and extends toward the cell assembly;
    Four end fitting recesses into which the ends of the four columnar electrochemical cells are fitted;
    Four spacer housings that are provided in the center of the bottoms of the four end fitting recesses and that accommodate cushioning spacers arranged in a compressed state between the bottoms of the plurality of end fitting recesses and the bus bar A recess for
    2 or more which is provided in the peripheral wall portion and communicates with at least one of the two or more end fitting recesses communicating to receive the bus bar and allows the terminal portion of the bus bar to go outside. A holder having an opening.
  11.  前記周壁部は、同じ長さ寸法を有し且つそれぞれ直交する4つの側壁部によって構成されており、前記4つの側壁部の同じ対角位置にそれぞれ取り付け孔が形成されている請求項10に記載のホルダ。 The said surrounding wall part is comprised by the four side wall part which has the same length dimension, and is orthogonal, respectively, and the attachment hole is each formed in the same diagonal position of the said four side wall part. Holder.
  12.  連通する2つの前記端部嵌合用凹部からなる2つの凹部列が並んでおり、
     前記2つの凹部列の中央位置に対応する前記周壁部の二箇所の部分には、それぞれ1つの前記開口部が形成されており、
     前記2つの凹部列の一端に対応する前記周壁部の二箇所の部分には、それぞれ1つの前記開口部が形成されている請求項10に記載のホルダ。
    Two rows of recesses are formed of two end fitting recesses communicating with each other,
    One opening is formed in each of the two portions of the peripheral wall corresponding to the center position of the two recess rows,
    The holder according to claim 10, wherein one opening is formed in each of two portions of the peripheral wall portion corresponding to one end of the two recess rows.
  13.  連通する2つの前記端部嵌合用凹部からなる2つの凹部列が並んでおり且つ前記2つの凹部列の一方に含まれる1つの前記端部嵌合用凹部と他方に含まれる1つの前記端部嵌合用凹部とが連通しており、
     前記2つの凹部列の中央位置に対応する前記周壁部の二箇所の部分には、それぞれ1つの前記開口部が形成されており、
     前記2つの凹部列の一端に対応する前記周壁部の二箇所の部分には、それぞれ1つの前記開口部が形成されている請求項10に記載のホルダ。
    Two recess rows made of two end fitting recesses communicating with each other are arranged side by side and one end fitting recess included in one of the two recess rows and one end fitting included in the other The joint recess communicates with
    One opening is formed in each of the two portions of the peripheral wall corresponding to the center position of the two recess rows,
    The holder according to claim 10, wherein one opening is formed in each of two portions of the peripheral wall portion corresponding to one end of the two recess rows.
  14.  連通する2つの前記端部嵌合用凹部からなる2つの凹部列が並んでおり、前記2つの凹部列の一方に含まれる1つの前記端部嵌合用凹部と他方に含まれる1つの前記端部嵌合用凹部とが連通しており、前記2つの凹部列の一方に含まれる残りの1つの前記端部嵌合用凹部と他方に含まれる残りの1つの前記端部嵌合用凹部とが連通しており、
     前記2つの凹部列の中央位置に対応する前記周壁部の二箇所の部分には、それぞれ1つの前記開口部が形成されている請求項10に記載のホルダ。
    Two recess rows made of two end fitting recesses communicating with each other are arranged, one end fitting recess included in one of the two recess rows and one end fitting included in the other. The joint recess is in communication, and the remaining one end fitting recess included in one of the two recess rows communicates with the remaining one end fitting recess included in the other. ,
    The holder according to claim 10, wherein one opening is formed in each of two portions of the peripheral wall portion corresponding to a central position of the two recess rows.
  15.  連通する2つの前記端部嵌合用凹部からなる第1の凹部列と連通しない2つの前記端部嵌合用凹部からなる第2の凹部列とが並んでおり、
     前記第2の凹部列を構成する2つの前記端部嵌合用凹部を囲む前記周壁部の部分には、それぞれ1つの前記開口部が形成されている請求項10に記載のホルダ。
    The first recess row consisting of the two end fitting recesses communicating and the second recess row consisting of the two end fitting recesses not communicating are arranged,
    The holder according to claim 10, wherein one opening is formed in each of the peripheral wall portions surrounding the two end fitting recesses constituting the second recess row.
PCT/JP2011/072827 2010-10-04 2011-10-04 Electrochemical cell module and holder WO2012046711A1 (en)

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JPWO2012173233A1 (en) * 2011-06-17 2015-02-23 新神戸電機株式会社 Electrochemical cell module, electrochemical cell module unit and holder
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JP2014229564A (en) * 2013-05-24 2014-12-08 株式会社豊田自動織機 Power storage device module
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