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WO2011147272A1 - Anti-bending muti-mode optical fiber - Google Patents

Anti-bending muti-mode optical fiber Download PDF

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Publication number
WO2011147272A1
WO2011147272A1 PCT/CN2011/074242 CN2011074242W WO2011147272A1 WO 2011147272 A1 WO2011147272 A1 WO 2011147272A1 CN 2011074242 W CN2011074242 W CN 2011074242W WO 2011147272 A1 WO2011147272 A1 WO 2011147272A1
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WO
WIPO (PCT)
Prior art keywords
layer
refractive index
optical fiber
cladding
quartz glass
Prior art date
Application number
PCT/CN2011/074242
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French (fr)
Chinese (zh)
Inventor
曹蓓蓓
张方海
Original Assignee
长飞光纤光缆有限公司
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Publication of WO2011147272A1 publication Critical patent/WO2011147272A1/en

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Classifications

    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/02Optical fibres with cladding with or without a coating
    • G02B6/036Optical fibres with cladding with or without a coating core or cladding comprising multiple layers
    • G02B6/03616Optical fibres characterised both by the number of different refractive index layers around the central core segment, i.e. around the innermost high index core layer, and their relative refractive index difference
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/02Optical fibres with cladding with or without a coating
    • G02B6/02395Glass optical fibre with a protective coating, e.g. two layer polymer coating deposited directly on a silica cladding surface during fibre manufacture
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/02Optical fibres with cladding with or without a coating
    • G02B6/028Optical fibres with cladding with or without a coating with core or cladding having graded refractive index
    • G02B6/0288Multimode fibre, e.g. graded index core for compensating modal dispersion
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/02Optical fibres with cladding with or without a coating
    • G02B6/036Optical fibres with cladding with or without a coating core or cladding comprising multiple layers
    • G02B6/03694Multiple layers differing in properties other than the refractive index, e.g. attenuation, diffusion, stress properties
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/02Optical fibres with cladding with or without a coating
    • G02B6/036Optical fibres with cladding with or without a coating core or cladding comprising multiple layers
    • G02B6/03616Optical fibres characterised both by the number of different refractive index layers around the central core segment, i.e. around the innermost high index core layer, and their relative refractive index difference
    • G02B6/03638Optical fibres characterised both by the number of different refractive index layers around the central core segment, i.e. around the innermost high index core layer, and their relative refractive index difference having 3 layers only
    • G02B6/0365Optical fibres characterised both by the number of different refractive index layers around the central core segment, i.e. around the innermost high index core layer, and their relative refractive index difference having 3 layers only arranged - - +
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/02Optical fibres with cladding with or without a coating
    • G02B6/036Optical fibres with cladding with or without a coating core or cladding comprising multiple layers
    • G02B6/03616Optical fibres characterised both by the number of different refractive index layers around the central core segment, i.e. around the innermost high index core layer, and their relative refractive index difference
    • G02B6/03661Optical fibres characterised both by the number of different refractive index layers around the central core segment, i.e. around the innermost high index core layer, and their relative refractive index difference having 4 layers only
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/02Optical fibres with cladding with or without a coating
    • G02B6/036Optical fibres with cladding with or without a coating core or cladding comprising multiple layers
    • G02B6/03616Optical fibres characterised both by the number of different refractive index layers around the central core segment, i.e. around the innermost high index core layer, and their relative refractive index difference
    • G02B6/03688Optical fibres characterised both by the number of different refractive index layers around the central core segment, i.e. around the innermost high index core layer, and their relative refractive index difference having 5 or more layers

Definitions

  • the present invention relates to a bending-resistant multimode optical fiber for use in an access network or miniaturized optical device, and more particularly to an optical fiber having a lower bending additional attenuation, which belongs to the field of optical communication technology.
  • Bending-resistant multimode fiber has been greatly improved in bending performance, minimizing signal loss and enabling faster and more efficient fiber path, cabling and installation. Cabling in a narrow environment requires that the bend-resistant multimode fiber can withstand small angle bends with a radius equal to or less than 10 mm and its signal loss is much less than that of conventional multimode fibers.
  • the new bend-resistant multimode fiber is easier to operate and install than copper, allowing fiber to be deployed in more locations.
  • an effective way to reduce the additional attenuation of fiber bending is to use a depressed cladding design in which a layer having a lower refractive index is added to the cladding to achieve the effect of confining optical power.
  • the refractive index profiles are mainly "groove type” (shown in Figures 1 and 3) and "double-clad type” (shown in Figure 2).
  • U.S. Patents US20080166094A1, US20090169163A1 and US20090154888A1 are such designs.
  • the design principle is: When the fiber is subjected to small bending, the light leaking from the core is easily confined to the inner cladding and returned to the core, thereby reducing the additional attenuation of the fiber macrobend.
  • the addition of a layer having a low refractive index to the cladding has the disadvantage that the range of the layered refractive index is limited, that is, it is difficult to achieve a layered refractive index of less than -1.5%, and the process complexity is high and the product uniformity is poor. How to ensure the optical performance consistency of such fibers and the long-term operation in the small radius bending state remains to be further studied.
  • Existing multimode fibers are difficult to meet the demanding optical performance and reliability requirements at small bend radii.
  • Mandrel a quartz glass piece containing a core or core layer and a partial cladding
  • Preform A quartz glass component that has a reasonable geometric and optical parameter that can be melt drawn into an optical fiber;
  • Refractive index When light is refracted from a vacuum injection medium, the ratio of the sine of the incident angle to the sine of the refraction angle is called the "absolute refractive index" of the medium.
  • Relative refractive index difference X 100% *" ⁇ °- X 100 %, and 3 ⁇ 4 are each
  • Refractive index profile The relationship between the refractive index of the glass and its radius, as indicated by a graph of the fiber or fiber preform (including the mandrel);
  • Low refractive index The refractive index of the material is smaller than that of pure quartz glass, which is called low refractive index. Pure quartz glass has a refractive index of 1.458 at 589 nm and a refractive index of 1.457 at 630 nm. The refractive index is lower than that of pure quartz glass at the same wavelength.
  • the coating is called a low refractive index coating;
  • Radius the distance between the outer boundary of the layer and the center point
  • Power exponential refractive index profile a refractive index profile that satisfies the power exponential function below, where is the refractive index of the fiber axis; r is the distance from the fiber axis; a is the fiber core radius; a is the distribution index; ⁇ is the core /package relative refractive index difference;
  • n 2 (r) n ⁇ [l - 2A(-) a ] r ⁇ a
  • the technical problem to be solved by the present invention is to provide a bending-resistant multimode optical fiber having a lower bending additional attenuation in view of the deficiencies of the prior art described above.
  • the technical solution of the multimode optical fiber proposed by the invention comprises: an optical fiber and a coating coated on the outer surface of the optical fiber, the optical fiber being composed of a quartz glass core layer having a parabolic or step-shaped refractive index profile structure and surrounding the core layer Quartz glass cladding composition, the difference is: the core layer diameter 2R1 is 20 ⁇ 200 ⁇ , composed of ytterbium-doped (Ge) and fluorine (F) quartz glass materials, the cladding is covered with double The layer-cured polymer coating, the inner coating coated on the outer surface of the cladding is a low refractive index flexible polymer coating, and the outer coating is a high Young's modulus polymer coating.
  • the cladding layer is a pure quartz glass cladding layer surrounding the core layer, or a sum of pure quartz and a doped quartz glass cladding layer, and the outermost quartz glass cladding layer has a diameter of 80 ⁇ m to 230 ⁇ m.
  • the inner coating layer has a Young's modulus of less than or equal to 10 MPa in the range of -65 ° C to 85 ° C, a typical Young's modulus range is 0.5 MPa to 2 MPa, and a refractive index (589 nm wavelength sodium yellow)
  • the range of light is 1.37 to 1.455; the outer coating is in the range of -65 ° C to 55 ° C.
  • the Young's modulus ranges from 500 MPa to 1500 MPa, the typical range is from 700 MPa to 1000 MPa, and the refractive index ranges from 1.47 to 1.78.
  • the layer refractive index has no significant effect on the fiber properties.
  • the inner coating layer is a UV-curable or heat-curable flexible silicone rubber coating, and the inner coating layer has a thickness of 10 ⁇ m to 40 ⁇ m ; the outer coating layer is ultraviolet light curing or heat curing. Polyacrylate coating, the outer coating has a diameter of 160 ⁇ 260 ⁇ .
  • the multimode fiber has a typical additional bending attenuation of less than or equal to 0.15 dB, or even less than or equal to 0.05 dB, at a wavelength of 850 nm with a radius of 10 mm around one turn.
  • the refractive index profile of the core layer is parabolic, (1.9 to 2.2, the relative refractive index difference ⁇ 1 is 0.9% to 1.2%, the inner coating refractive index range is 1.40 to 1.43, and the core diameter is 47 ⁇ 53 ⁇ .
  • the dynamic fatigue parameter Nd is equal to or greater than 26; at a wavelength of 850nm and a wavelength of 1300nm with a bandwidth of 500MHz-km or more, by adjusting the power exponential refractive index profile, the optimized 850nm wavelength window can reach 2000MHz-km or even 5000MHz. Bandwidth above -km.
  • the refractive index profile of the core layer is parabolic, (1.9 to 2.2, the relative refractive index difference ⁇ 1 is 1.8% to 2.3%, and the core layer diameter is 60 ⁇ to 65 ⁇ .
  • the refractive index profile of the core layer is stepped, and the relative refractive index difference ⁇ 1 is 0.3% to 2.2%.
  • the double-coated composite structure used in the present invention combines the advantages of the two coatings, can improve the mechanical properties of the optical fiber and minimize the microbending loss: the flexible inner coating can alleviate the pressure on the outer surface of the glass cladding and reduce the microbending loss.
  • the optical power loss, high Young's modulus of the outer coating can withstand large mechanical forces, the fiber is protected from mechanical damage during processing, transportation and use.
  • the method for manufacturing the multimode optical fiber of the present invention comprises: fixing a pure quartz glass liner on a plasma enhanced chemical vapor deposition (PCVD) lathe for doping deposition, and introducing a gas containing F into the reaction gases SiCl 4 and 02 ; Introducing F doping, introducing GeCl 4 to introduce Ge doping, ionizing the reaction gas in the liner into a plasma by microwave, and finally depositing it on the inner wall of the liner in the form of glass; according to the doping of the fiber waveguide structure Miscellaneous requirements, the waveguide structure curve is subdivided into thousands to 10,000 layers of thin layer step-by-step deposition, and the core layer with precise refractive index distribution is realized by programmatically controlling the flow rate and ratio of the doping gas in each mixed gas; Upon completion, the deposition tube is melted into a solid mandrel using an electric heating furnace.
  • PCVD plasma enhanced chemical vapor deposition
  • the solid mandrel is placed in a pure quartz glass hollow tube with suitable size parameters to form a preform for preparing the optical fiber, or a pure quartz glass layer is deposited on the surface of the mandrel by an OVD process as a cladding and then fired into a preform.
  • the preform is placed in a drawing tower to form a fiber, and the inner and outer layers of the polymer coating are coated on the surface of the fiber to form an optical fiber.
  • the additional bending attenuation of the fiber consists of both macrobend additional attenuation and microbend additional attenuation.
  • Increasing the fiber's resistance to bending can be achieved by optimizing the structure to reduce both attenuations.
  • the inner coating material uses a low refractive index polymer
  • the low refractive index of the elastomer which limits the light leaking from the core, is confined to the quartz glass cladding and returned to the core, thereby reducing the additional attenuation of the fiber macrobend.
  • it has a Young's modulus of less than 10 MPa in the range of -65 ° C to 85 ° C, and a typical Young's modulus range of 0.5 MPa to 2 MPa. This property minimizes the glass cladding and the inner layer.
  • the stress at the coating and the optical power loss caused by the irregular deformation reduce the additional attenuation of the microbend, thereby improving the bending resistance of the fiber.
  • the beneficial effects of the present invention are as follows: 1.
  • the design of the low refractive index inner coating avoids the introduction of additional stress in the quartz glass cladding and the core layer, and the low refractive index characteristic can limit the light leaked from the core to the quartz.
  • the glass cladding is returned to the core, thereby reducing the additional attenuation of the fiber macrobend, avoiding the attenuation and bandwidth loss caused by the additional stress;
  • the design of the low refractive index inner coating avoids the internal stress of the fiber and greatly improves the fiber.
  • the mechanical properties ensure the performance and service life of the fiber working under small radius bending conditions, and have excellent bending resistance. 3.
  • the design of the low refractive index inner coating is equivalent to the introduction of the "sag layer” outside the quartz glass cladding. ", this can change the parameters of the "sag layer” by flexibly adjusting the properties of the coating, such as the diameter and depth of the trap layer, etc., and the parameters can be adjusted in the drawing process without adding unstable factors in the complicated preform design. Thereby, the reliability of the wire drawing manufacturing process is improved; 4.
  • the manufacturing method of the invention is simple and effective, and is suitable for mass production.
  • FIG. 1 is a schematic view showing the structure of a refractive index profile in a first embodiment of the present invention
  • Fig. 2 is a schematic view showing the structure of a refractive index profile in a second embodiment of the present invention.
  • Fig. 3 is a schematic view showing the structure of a refractive index profile in the third embodiment of the present invention.
  • Fig. 4 is a view showing the structure of a refractive index profile of a fourth embodiment of the present invention.
  • Fig. 5 is a view showing the structure of a refractive index profile in a fifth embodiment of the present invention.
  • Fig. 6 is a view showing the structure of a refractive index profile of a sixth embodiment of the present invention.
  • Fig. 7 is a view showing the structure of a refractive index profile of a step type energy transmission fiber according to Embodiments 7 and 8 of the present invention.
  • the refractive index parameter of the coating is expressed by the absolute refractive index.
  • the relative refractive index difference ⁇ of the coating is indicated in order to compare the refractive index of the coating with the core layer and the cladding.
  • the drawing uses ⁇ to indicate the relative refractive index difference of the quartz glass fiber core layer or cladding layer.
  • FIG. 1 is a schematic view showing the refractive index profile of a double-coated bending insensitive multimode fiber according to Embodiment 1 of the present invention.
  • the solid line in the figure indicates the refractive index structure of the quartz glass core and the cladding, and the broken line indicates the refractive index structure of the inner and outer coatings in the optical fiber.
  • ⁇ 1 represents the relative refractive index difference of the doped quartz glass core center, quartz in the structure
  • the relative refractive index difference of the glass cladding is 0;
  • ⁇ ⁇ and ⁇ 2 represent the relative refractive indices of the inner and outer coatings, respectively.
  • R1 and R2 represent the radii of the core layer and the cladding, respectively, and rl and r2 represent the radii of the inner and outer coatings, respectively.
  • Fig. 2 is a schematic view showing the structure of a refractive index profile of the second embodiment.
  • the quartz glass cladding is divided into three layers, wherein the first and third layers are pure quartz layers, and the second layer is a depressed cladding layer.
  • ⁇ 1 and ⁇ 3 represent the relative refractive index difference between the core and the depressed cladding, respectively;
  • ⁇ ⁇ and ⁇ 2 represent the relative refractive indices of the inner and outer coatings, respectively.
  • Rl, R2, R3, and R4 represent the core, the first cladding layered pure quartz layer, the second cladding layer, that is, the depressed cladding layer, and the radius of the third cladding layer, and the second layer radius R3 is 28 ⁇ m. ⁇ 58 ⁇ ;
  • the relative refractive index difference ⁇ 3 is -0.50% to -0.90%.
  • Rl and r2 represent the radius of the inner and outer coatings, respectively.
  • Fig. 3 is a schematic view showing the structure of a refractive index profile of the third embodiment.
  • the quartz glass cladding is divided into two layers, wherein the first layer is a pure quartz layer, and the second layer is a low refractive index depressed cladding.
  • ⁇ 1 and ⁇ 3 represent the relative refractive indices of the core and the depressed cladding, respectively;
  • ⁇ ⁇ and ⁇ 2 represent the relative refractive indices of the inner and outer coatings, respectively.
  • Rl, R2, and R3 respectively represent the core, the first cladding layered pure silica layer, and the second cladding layer, that is, the radius of the depressed cladding layer, and the second layering radius R3 is 28 ⁇ to 63 ⁇ ; the relative refractive index difference ⁇ 3 is -0.40% to -1.00%.
  • Rl and r2 represent the radius of the inner and outer coatings, respectively.
  • Fig. 4 is a view showing the structure of a refractive index profile of the fourth embodiment.
  • the quartz glass cladding is divided into two layers, wherein the first layer is a low refractive index depressed cladding layer, and the second layer is a pure quartz layer.
  • ⁇ 1 and ⁇ 2 represent the relative refractive indices of the core and the depressed cladding, respectively;
  • ⁇ ⁇ and ⁇ 2 represent the relative refractive indices of the inner and outer coatings, respectively.
  • Rl, R2, and R3 respectively represent the core, the first cladding layer, that is, the depressed cladding layer, and the radius of the second cladding layer.
  • the first layering radius R2 is 21 ⁇ 58 ⁇ ; the relative refractive index difference ⁇ 2 is -0.40%. To -0.80%.
  • Rl and r2 represent the radius of the inner and outer coatings, respectively.
  • Fig. 5 is a view showing the structure of a refractive index profile of the fifth embodiment.
  • the quartz glass cladding is divided into four layers, wherein the first layer is a pure quartz layer, the second layer is a low refractive index depressed cladding layer, and the third layer is a doped high refractive index quartz layer, the fourth layer.
  • the layer is a layer of pure quartz. ⁇ 1, ⁇ 3, and ⁇ 4 represent the relative refractive indices of the core, the depressed cladding, and the high refractive index doped quartz layer, respectively, the second layering radius R3 is 28 ⁇ to 55 ⁇ , and the relative refractive index difference ⁇ 3 is -0.40% to -1.10%.
  • the third layering radius R4 is 31 ⁇ m to 58 ⁇ m, and the relative refractive index difference ⁇ 4 is 0.1% to 0.8%.
  • ⁇ ⁇ and ⁇ 2 represent the relative refractive indices of the inner and outer coatings, respectively.
  • R1, R2, R3, R4, and R5 respectively represent a core, a first cladding layer, a second cladding layer, that is, a depressed cladding layer, a third cladding layer, that is, a high refractive index doped quartz layer, and a fourth package.
  • Layer stratification is the radius of the pure quartz layer.
  • Rl and r2 represent the radius of the inner and outer coatings, respectively.
  • Fig. 6 is a schematic view showing the refractive index profile of a double-coated bending insensitive multimode fiber according to Embodiment 6 of the present invention.
  • the solid line in the figure indicates the refractive index structure of the quartz glass core and the cladding, and the dotted line indicates the inner and outer coatings.
  • ⁇ 1 represents the relative refractive index difference of the center of the doped quartz glass core, and the relative refractive index difference of the quartz glass cladding in the structure is 0;
  • ⁇ ⁇ and ⁇ 2 represent the relative refractive indices of the inner and outer coatings, respectively.
  • R1 and R2 represent the radii of the core layer and the cladding, respectively, and rl and r2 represent the radii of the inner and outer coatings, respectively.
  • Fig. 7 is a view showing the structure of a refractive index profile of a step type energy transmission fiber according to Embodiments 7 and 8 of the present invention.
  • the solid line in the figure indicates the refractive index structure of the quartz glass core and the cladding, and the broken line indicates the refractive index structure of the inner and outer coatings in the fiber.
  • the relative refractive index difference ⁇ 1 of the doped quartz glass core is 0.3% to 1.2%.
  • the cladding is a doped quartz glass cladding with a low refractive index
  • the relative refractive index difference ⁇ 2 of the cladding is -0.1% to -1.1. %.
  • ⁇ ⁇ and ⁇ 2 represent the relative refractive indices of the inner and outer coatings, respectively.
  • Rl and R2 represent the radii of the core and cladding, respectively, and rl and r2 represent the radii of the inner and outer coatings, respectively.

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Glass Compositions (AREA)
  • Surface Treatment Of Glass Fibres Or Filaments (AREA)

Abstract

An anti-bending multi-mode optical fiber for an access network and a miniaturized optical device comprises an optical fiber and a coating layer covering the optical fiber. The optical fiber is composed of a quartz glass core layer with a parabola-shape index or a step-index profile structure and a quartz glass cladding layer surrounding the core layer. The core layer is made of quartz glass material doped with germanium and fluorine. The cladding layer is covered with two cured polymer coating layers, wherein the inner coating layer is low-refraction index flexible polymer coating layer, and the outer coating layer is high Young's modulus polymer coating layer. The inner coating layer of the multi-mode optical fiber with low-refraction index avoids the internal stress in the optical fiber, so as to improve the mechanical performance of the optical fiber and guarantee better usage performance and longer service life of the optical fiber working in a small-radius bending state.

Description

一种抗弯曲多模光纤 技术领域  Anti-bending multimode optical fiber technical field
本发明涉及一种用于接入网或小型化光器件中的抗弯曲多模光纤, 特别涉及一种具 有较低弯曲附加衰减的光纤, 属于光通信技术领域。  The present invention relates to a bending-resistant multimode optical fiber for use in an access network or miniaturized optical device, and more particularly to an optical fiber having a lower bending additional attenuation, which belongs to the field of optical communication technology.
背景技术 Background technique
近年来通信技术的发展和集成小型化光器件的兴起, 使得应用中的多模光纤常常 布设在越来越小的弯折通道并缠绕在空间越来越小的小型存储盒中,例如电讯配线箱、 数据中心机柜等, 这种情况下光纤就会经常遇到小角度弯曲。 传统的光纤进行小角度 弯曲时, 靠近多模光纤芯子边界传输的高阶模很容易在光纤弯曲时从芯子泄露出去, 从而造成信号损失, 导致成本较高的传输中断。  In recent years, the development of communication technology and the rise of integrated miniaturized optical devices have made multimode optical fibers in applications often placed in smaller and smaller bending channels and wound in small storage boxes with smaller and smaller spaces, such as telecommunications. Wire boxes, data center cabinets, etc. In this case, the fiber often encounters small angle bends. When the conventional fiber is bent at a small angle, the high-order mode transmitted near the boundary of the multimode fiber core is easily leaked from the core when the fiber is bent, resulting in signal loss, resulting in a costly transmission interruption.
抗弯曲多模光纤在弯曲性能上得到了大幅改善, 可以使信号损失最小化, 实现更 快更高效的光缆路径、 布线与安装。 狭窄环境下的布线要求抗弯曲多模光纤能经受半 径等于甚至小于 10mm的小角度弯曲而其信号损失却远远小于传统的多模光纤。 新型 的抗弯曲多模光纤比铜缆更易操作与安装, 从而得以在更多的地方部署光纤。  Bending-resistant multimode fiber has been greatly improved in bending performance, minimizing signal loss and enabling faster and more efficient fiber path, cabling and installation. Cabling in a narrow environment requires that the bend-resistant multimode fiber can withstand small angle bends with a radius equal to or less than 10 mm and its signal loss is much less than that of conventional multimode fibers. The new bend-resistant multimode fiber is easier to operate and install than copper, allowing fiber to be deployed in more locations.
现有技术中, 降低光纤弯曲附加衰减的一个有效方法是采用下陷包层的设计, 即 在包层中添加具有较低折射率的分层来实现约束光功率的效果。 其折射率剖面主要有 "壕沟型"(图 1和图 3所示)和"双包层型"(图 2所示)等。美国专利 US20080166094A1 , US20090169163A1和 US20090154888A1就是采用的此类设计。 其设计原理为: 当光 纤受到小的弯曲时, 从芯子泄露出去的光易被限制在内包层并返回到芯子中, 从而降 低了光纤宏弯附加衰减。 但是, 在包层中添加具有低折射率的分层, 缺点是分层折射 率范围受限制即难以实现低于 -1.5%的分层折射率, 且工艺复杂成本高昂产品均匀性 差。如何保证此类光纤的光学性能一致性及长期工作在小半径弯曲状态下的使用寿命, 仍然有待进一步的研究。 现有的多模光纤难以满足小弯曲半径下的苛刻的光学性能和 可靠性能的要求。  In the prior art, an effective way to reduce the additional attenuation of fiber bending is to use a depressed cladding design in which a layer having a lower refractive index is added to the cladding to achieve the effect of confining optical power. The refractive index profiles are mainly "groove type" (shown in Figures 1 and 3) and "double-clad type" (shown in Figure 2). U.S. Patents US20080166094A1, US20090169163A1 and US20090154888A1 are such designs. The design principle is: When the fiber is subjected to small bending, the light leaking from the core is easily confined to the inner cladding and returned to the core, thereby reducing the additional attenuation of the fiber macrobend. However, the addition of a layer having a low refractive index to the cladding has the disadvantage that the range of the layered refractive index is limited, that is, it is difficult to achieve a layered refractive index of less than -1.5%, and the process complexity is high and the product uniformity is poor. How to ensure the optical performance consistency of such fibers and the long-term operation in the small radius bending state remains to be further studied. Existing multimode fibers are difficult to meet the demanding optical performance and reliability requirements at small bend radii.
发明内容 Summary of the invention
为方便介绍本发明内容, 定义部分术语:  To facilitate the introduction of the present invention, define some terms:
芯棒: 含有芯层或芯层及部分包层的石英玻璃件;  Mandrel: a quartz glass piece containing a core or core layer and a partial cladding;
预制棒: 具有合理几何及光学参数的可以熔融拉丝成为光纤的石英玻璃组件; 折射率: 光从真空射入介质发生折射时, 入射角的正弦值与折射角的正弦值的比 值叫做介质的 "绝对折射率" 相对折射率差: X 100% *」 ~~ °- X 100%, 和 ¾分别为各
Figure imgf000004_0001
Preform: A quartz glass component that has a reasonable geometric and optical parameter that can be melt drawn into an optical fiber; Refractive index: When light is refracted from a vacuum injection medium, the ratio of the sine of the incident angle to the sine of the refraction angle is called the "absolute refractive index" of the medium. Relative refractive index difference: X 100% *" ~~ °- X 100 %, and 3⁄4 are each
Figure imgf000004_0001
对应部分和纯石英玻璃折射率, 除非另做说明, 为各对应部分的最大折射率; Corresponding part and the refractive index of pure quartz glass, unless otherwise specified, the maximum refractive index of each corresponding part;
折射率剖面: 用曲线图表示的光纤或光纤预制棒 (包括芯棒) 玻璃折射率与其半 径之间的关系;  Refractive index profile: The relationship between the refractive index of the glass and its radius, as indicated by a graph of the fiber or fiber preform (including the mandrel);
低折射率: 物质折射率小于纯石英玻璃折射率的特性, 称为低折射率; 纯石英玻 璃在 589nm折射率为 1.458,在 630nm折射率为 1.457, 同一波长下折射率比纯石英玻 璃低的涂料称为低折射率涂料;  Low refractive index: The refractive index of the material is smaller than that of pure quartz glass, which is called low refractive index. Pure quartz glass has a refractive index of 1.458 at 589 nm and a refractive index of 1.457 at 630 nm. The refractive index is lower than that of pure quartz glass at the same wavelength. The coating is called a low refractive index coating;
半径: 该层外边界与中心点之间的距离;  Radius: the distance between the outer boundary of the layer and the center point;
幂指数律折射率剖面: 满足下面幂指数函数的折射率剖面, 其中, 为光纤轴心 的折射率; r为离开光纤轴心的距离; a为光纤芯半径; a为分布指数; Δ为芯 /包相对 折射率差;  Power exponential refractive index profile: a refractive index profile that satisfies the power exponential function below, where is the refractive index of the fiber axis; r is the distance from the fiber axis; a is the fiber core radius; a is the distribution index; Δ is the core /package relative refractive index difference;
n2 (r) = n^[l - 2A(—)a ] r<a n 2 (r) = n^[l - 2A(-) a ] r<a
a  a
本发明所要解决的技术问题在于针对上述现有技术存在的不足而提供一种具有更 低弯曲附加衰减的抗弯曲多模光纤。  The technical problem to be solved by the present invention is to provide a bending-resistant multimode optical fiber having a lower bending additional attenuation in view of the deficiencies of the prior art described above.
本发明提出的多模光纤的技术方案为: 包括光纤和包覆在光纤外表面的涂层, 所 述的光纤由具有抛物线形或阶跃形折射率剖面结构的石英玻璃芯层和围绕芯层的石英 玻璃包层组成, 其不同之处在于: 所述的芯层直径 2R1为 20〜200μηι, 由掺锗 (Ge) 和氟(F)石英玻璃材料组成, 所述的包层外覆有双层固化的聚合物涂层, 包覆在包层 外表面的内涂层为低折射率柔性聚合物涂层, 外涂层为高杨氏模量的聚合物涂层。  The technical solution of the multimode optical fiber proposed by the invention comprises: an optical fiber and a coating coated on the outer surface of the optical fiber, the optical fiber being composed of a quartz glass core layer having a parabolic or step-shaped refractive index profile structure and surrounding the core layer Quartz glass cladding composition, the difference is: the core layer diameter 2R1 is 20~200μηι, composed of ytterbium-doped (Ge) and fluorine (F) quartz glass materials, the cladding is covered with double The layer-cured polymer coating, the inner coating coated on the outer surface of the cladding is a low refractive index flexible polymer coating, and the outer coating is a high Young's modulus polymer coating.
按上述方案, 所述的包层为围绕在芯层外的纯石英玻璃包层, 或纯石英与掺杂石 英玻璃包层的总和, 最外层的石英玻璃包层直径为 80μηι〜230μηι。  According to the above scheme, the cladding layer is a pure quartz glass cladding layer surrounding the core layer, or a sum of pure quartz and a doped quartz glass cladding layer, and the outermost quartz glass cladding layer has a diameter of 80 μm to 230 μm.
按上述方案, 所述的内涂层在 -65 °C〜85 °C范围内杨氏模量小于或等于 10MPa, 典 型的杨氏模量范围是 0.5MPa〜2MPa,折射率(589nm波长钠黄光)范围是 1.37至 1.455 ; 外涂层在 -65 °C〜55 °C范围内杨氏模量范围是 500MPa〜1500MPa, 典型的范围是 700MPa〜1000MPa,折射率范围为 1.47至 1.78,外涂层折射率对光纤性能无明显影响。 按上述方案, 所述的内涂层为紫外光固化或热固化的柔性硅橡胶涂层, 内涂层的 单边厚度为 10μηι〜40μηι; 所述的外涂层为紫外光固化或热固化的聚丙烯酸脂涂层, 外涂层的直径为 160μηι〜260μηι。 According to the above scheme, the inner coating layer has a Young's modulus of less than or equal to 10 MPa in the range of -65 ° C to 85 ° C, a typical Young's modulus range is 0.5 MPa to 2 MPa, and a refractive index (589 nm wavelength sodium yellow) The range of light is 1.37 to 1.455; the outer coating is in the range of -65 ° C to 55 ° C. The Young's modulus ranges from 500 MPa to 1500 MPa, the typical range is from 700 MPa to 1000 MPa, and the refractive index ranges from 1.47 to 1.78. The layer refractive index has no significant effect on the fiber properties. According to the above scheme, the inner coating layer is a UV-curable or heat-curable flexible silicone rubber coating, and the inner coating layer has a thickness of 10 μm to 40 μm ; the outer coating layer is ultraviolet light curing or heat curing. Polyacrylate coating, the outer coating has a diameter of 160μηι~260μηι.
按上述方案, 所述的多模光纤在 850nm波长处, 以 10mm弯曲半径绕 1圈导致的 弯曲附加衰减典型值小于或等于 0.15dB, 甚至小于或等于 0.05dB。  According to the above scheme, the multimode fiber has a typical additional bending attenuation of less than or equal to 0.15 dB, or even less than or equal to 0.05 dB, at a wavelength of 850 nm with a radius of 10 mm around one turn.
按上述方案, 所述的芯层折射率剖面结构为抛物线形, ( 为 1.9〜2.2, 相对折射率 差 Δ1为 0.9%至 1.2%, 内涂层折射率范围是 1.40至 1.43, 芯层直径为 47μηι〜53μηι。 动态疲劳参数 Nd等于或大于 26; 在 850nm波长和 1300nm波长具有 500MHz-km以 上的带宽, 通过调整幂指数律折射率剖面分布, 可以使优化的 850nm波长窗口达到 2000MHz-km甚至 5000MHz-km以上的带宽。  According to the above scheme, the refractive index profile of the core layer is parabolic, (1.9 to 2.2, the relative refractive index difference Δ1 is 0.9% to 1.2%, the inner coating refractive index range is 1.40 to 1.43, and the core diameter is 47μηι~53μηι. The dynamic fatigue parameter Nd is equal to or greater than 26; at a wavelength of 850nm and a wavelength of 1300nm with a bandwidth of 500MHz-km or more, by adjusting the power exponential refractive index profile, the optimized 850nm wavelength window can reach 2000MHz-km or even 5000MHz. Bandwidth above -km.
按上述方案, 所述的芯层折射率剖面结构为抛物线形, ( 为 1.9〜2.2, 相对折射率 差 Δ1为 1.8%至 2.3%, 芯层直径为 60μηι〜65μηι。  According to the above scheme, the refractive index profile of the core layer is parabolic, (1.9 to 2.2, the relative refractive index difference Δ1 is 1.8% to 2.3%, and the core layer diameter is 60 μηι to 65 μηι.
按上述方案, 所述的芯层折射率剖面结构为阶跃形, 相对折射率差 Δ1为 0.3%至 2.2%。  According to the above scheme, the refractive index profile of the core layer is stepped, and the relative refractive index difference Δ1 is 0.3% to 2.2%.
本发明采用的双涂层复合结构结合了两种涂料的优点, 可以提高光纤的机械性能 并且最大程度地降低微弯损耗: 柔性内涂层可以缓解外界对玻璃包层的压力降低微观 弯曲损耗引起的光功率损失, 高杨氏模量的外涂层可以承受较大的机械力, 使光纤免 受加工、 运输、 使用过程中的机械损伤。  The double-coated composite structure used in the present invention combines the advantages of the two coatings, can improve the mechanical properties of the optical fiber and minimize the microbending loss: the flexible inner coating can alleviate the pressure on the outer surface of the glass cladding and reduce the microbending loss. The optical power loss, high Young's modulus of the outer coating can withstand large mechanical forces, the fiber is protected from mechanical damage during processing, transportation and use.
本发明多模光纤制造方法为: 将纯石英玻璃衬管固定在等离子体增强化学气相沉 积 (PCVD) 车床上进行掺杂沉积, 在反应气体 SiCl4和 02中, 通入含 F的气体, 引 进 F掺杂,通入 GeCl4以引入 Ge掺杂,通过微波使衬管内的反应气体离子化变成等离 子体, 并最终以玻璃的形式沉积在衬管内壁; 根据所述光纤波导结构的掺杂要求, 将 波导结构曲线细分成数千至一万多层薄层分步沉积, 通过程序控制每步混合气体中掺 杂气体的流量和比例来实现具有精确折射率分布的芯层; 沉积完成后, 用电加热炉将 沉积管熔縮成实心芯棒。 The method for manufacturing the multimode optical fiber of the present invention comprises: fixing a pure quartz glass liner on a plasma enhanced chemical vapor deposition (PCVD) lathe for doping deposition, and introducing a gas containing F into the reaction gases SiCl 4 and 02 ; Introducing F doping, introducing GeCl 4 to introduce Ge doping, ionizing the reaction gas in the liner into a plasma by microwave, and finally depositing it on the inner wall of the liner in the form of glass; according to the doping of the fiber waveguide structure Miscellaneous requirements, the waveguide structure curve is subdivided into thousands to 10,000 layers of thin layer step-by-step deposition, and the core layer with precise refractive index distribution is realized by programmatically controlling the flow rate and ratio of the doping gas in each mixed gas; Upon completion, the deposition tube is melted into a solid mandrel using an electric heating furnace.
将实心芯棒套入具有适宜尺寸参数的纯石英玻璃空管内即可组成制备光纤用的预 制棒, 或者在芯棒表面用 OVD 工艺沉积纯石英玻璃层作为包层再烧实成预制棒。 将 预制棒置于拉丝塔拉成纤维, 在纤维表面涂覆内外两层聚合物涂层即成光纤。  The solid mandrel is placed in a pure quartz glass hollow tube with suitable size parameters to form a preform for preparing the optical fiber, or a pure quartz glass layer is deposited on the surface of the mandrel by an OVD process as a cladding and then fired into a preform. The preform is placed in a drawing tower to form a fiber, and the inner and outer layers of the polymer coating are coated on the surface of the fiber to form an optical fiber.
光纤的弯曲附加衰减由宏弯附加衰减和微弯附加衰减两者组成, 增加光纤的抗弯 曲能力可通过优化结构以减少这两种衰减来实现。 内涂层材料采用低折射率的聚合物 弹性体, 其低折射率的特性可以将从芯子泄露出去的光限制在石英玻璃包层并返回到 芯子中, 从而降低光纤宏弯附加衰减。 另一方面, 其在 -65 °C〜85 °C范围内杨氏模量小 于 10MPa, 典型的杨氏模量范围是 0.5MPa〜2MPa, 这种特性最大限度地减小了玻璃 包层与内涂层处的应力与不规则形变导致的光功率损失, 降低了微弯附加衰减, 从而 提高了光纤的抗弯曲能力。 The additional bending attenuation of the fiber consists of both macrobend additional attenuation and microbend additional attenuation. Increasing the fiber's resistance to bending can be achieved by optimizing the structure to reduce both attenuations. The inner coating material uses a low refractive index polymer The low refractive index of the elastomer, which limits the light leaking from the core, is confined to the quartz glass cladding and returned to the core, thereby reducing the additional attenuation of the fiber macrobend. On the other hand, it has a Young's modulus of less than 10 MPa in the range of -65 ° C to 85 ° C, and a typical Young's modulus range of 0.5 MPa to 2 MPa. This property minimizes the glass cladding and the inner layer. The stress at the coating and the optical power loss caused by the irregular deformation reduce the additional attenuation of the microbend, thereby improving the bending resistance of the fiber.
本发明的有益效果在于: 1、低折射率内涂层的设计避免了在石英玻璃包层和芯层 中引入附加应力, 其低折射率的特性可以将从芯子泄露出去的光限制在石英玻璃包层 并返回到芯子中, 从而降低了光纤宏弯附加衰减, 避免了附加应力造成的衰减和带宽 损失; 2、 低折射率内涂层的设计避免了光纤内部应力, 大大提高了光纤的机械性能, 保证了光纤工作在小半径弯曲状态下的使用性能和使用寿命,具有优异的抗弯曲性能; 3、低折射率内涂层的设计相当于在石英玻璃包层外部引入 "下陷层", 这样可以通过灵 活调整涂层性质来改变"下陷层 "的参数, 如下陷层的直径和深度等, 在拉丝工序中可 以实现参数的调整而不必在复杂的预制棒设计中增加不稳定因素, 从而提高了拉丝制 造工艺的可靠性; 4、 本发明制造方法简便有效, 适用于大规模生产。  The beneficial effects of the present invention are as follows: 1. The design of the low refractive index inner coating avoids the introduction of additional stress in the quartz glass cladding and the core layer, and the low refractive index characteristic can limit the light leaked from the core to the quartz. The glass cladding is returned to the core, thereby reducing the additional attenuation of the fiber macrobend, avoiding the attenuation and bandwidth loss caused by the additional stress; 2. The design of the low refractive index inner coating avoids the internal stress of the fiber and greatly improves the fiber. The mechanical properties ensure the performance and service life of the fiber working under small radius bending conditions, and have excellent bending resistance. 3. The design of the low refractive index inner coating is equivalent to the introduction of the "sag layer" outside the quartz glass cladding. ", this can change the parameters of the "sag layer" by flexibly adjusting the properties of the coating, such as the diameter and depth of the trap layer, etc., and the parameters can be adjusted in the drawing process without adding unstable factors in the complicated preform design. Thereby, the reliability of the wire drawing manufacturing process is improved; 4. The manufacturing method of the invention is simple and effective, and is suitable for mass production.
附图说明 DRAWINGS
图 1是本发明实施例 1的折射率剖面结构示意图。  BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a schematic view showing the structure of a refractive index profile in a first embodiment of the present invention
图 2是本发明实施例 2的折射率剖面结构示意图。  Fig. 2 is a schematic view showing the structure of a refractive index profile in a second embodiment of the present invention.
图 3是本发明实施例 3的折射率剖面结构示意图。  Fig. 3 is a schematic view showing the structure of a refractive index profile in the third embodiment of the present invention.
图 4是本发明实施例 4的折射率剖面结构示意图。  Fig. 4 is a view showing the structure of a refractive index profile of a fourth embodiment of the present invention.
图 5是本发明实施例 5的折射率剖面结构示意图。  Fig. 5 is a view showing the structure of a refractive index profile in a fifth embodiment of the present invention.
图 6是本发明实施例 6的折射率剖面结构示意图。  Fig. 6 is a view showing the structure of a refractive index profile of a sixth embodiment of the present invention.
图 7是本发明实施例 7和 8的阶跃型能量传输光纤折射率剖面结构示意图。  Fig. 7 is a view showing the structure of a refractive index profile of a step type energy transmission fiber according to Embodiments 7 and 8 of the present invention.
通常涂层的折射率参数用绝对折射率来表示, 附图中为了对比涂层折射率与芯层 及包层的关系, 标示出了涂层相对折射率差 δ。 附图用 Δ表示石英玻璃光纤芯层或包 层分层的相对折射率差。  Generally, the refractive index parameter of the coating is expressed by the absolute refractive index. In the drawing, the relative refractive index difference δ of the coating is indicated in order to compare the refractive index of the coating with the core layer and the cladding. The drawing uses Δ to indicate the relative refractive index difference of the quartz glass fiber core layer or cladding layer.
具体实施方式 detailed description
以下结合附图进一步说明本发明的实施例。  Embodiments of the present invention are further described below in conjunction with the accompanying drawings.
图 1是本发明实施例 1的双涂层弯曲不敏感多模光纤折射率剖面结构示意图。 图 中的实线部分表示石英玻璃纤芯和包层的折射率结构, 虚线部分表示内、 外两层涂层 在光纤中的折射率结构。 Δ1表示掺杂石英玻璃纤芯中心相对折射率差, 该结构中石英 玻璃包层的相对折射率差为 0; δΐ和 δ2分别表示内外两层涂层的相对折射率。 R1和 R2分别表示光纤芯层和包层的半径, rl和 r2分别表示内外两层涂层的半径。 1 is a schematic view showing the refractive index profile of a double-coated bending insensitive multimode fiber according to Embodiment 1 of the present invention. The solid line in the figure indicates the refractive index structure of the quartz glass core and the cladding, and the broken line indicates the refractive index structure of the inner and outer coatings in the optical fiber. Δ1 represents the relative refractive index difference of the doped quartz glass core center, quartz in the structure The relative refractive index difference of the glass cladding is 0; δ ΐ and δ 2 represent the relative refractive indices of the inner and outer coatings, respectively. R1 and R2 represent the radii of the core layer and the cladding, respectively, and rl and r2 represent the radii of the inner and outer coatings, respectively.
图 2是实施例 2的折射率剖面结构示意图。 该结构中石英玻璃包层分为 3层, 其 中第 1和第 3分层为纯石英层, 第 2分层为下陷包层。 Δ1和 Δ3分别表示纤芯和下陷 包层的相对折射率差; δΐ和 δ2分别表示内外两层涂层的相对折射率。 Rl、 R2、 R3、 R4分别表示纤芯、 第 1包层分层纯石英层、 第 2包层分层即下陷包层、 第 3包层分层 的半径, 第 2分层半径 R3为 28μηι〜58μηι; 相对折射率差 Δ3为 -0.50%至 -0.90%。 rl 和 r2分别表示内外两层涂层的半径。  Fig. 2 is a schematic view showing the structure of a refractive index profile of the second embodiment. In this structure, the quartz glass cladding is divided into three layers, wherein the first and third layers are pure quartz layers, and the second layer is a depressed cladding layer. Δ1 and Δ3 represent the relative refractive index difference between the core and the depressed cladding, respectively; δ ΐ and δ 2 represent the relative refractive indices of the inner and outer coatings, respectively. Rl, R2, R3, and R4 represent the core, the first cladding layered pure quartz layer, the second cladding layer, that is, the depressed cladding layer, and the radius of the third cladding layer, and the second layer radius R3 is 28 μm. 〜58μηι; The relative refractive index difference Δ3 is -0.50% to -0.90%. Rl and r2 represent the radius of the inner and outer coatings, respectively.
图 3是实施例 3的折射率剖面结构示意图。 该结构中石英玻璃包层分为 2层, 其 中第 1分层为纯石英层, 第 2分层为低折射率下陷包层。 Δ1和 Δ3分别表示纤芯和下 陷包层的相对折射率; δΐ和 δ2分别表示内外两层涂层的相对折射率。 Rl、 R2、 R3分 别表示纤芯、 第 1包层分层纯石英层、 第 2包层分层即下陷包层的半径, 第 2分层半 径 R3为 28μηι〜63μηι; 相对折射率差 Δ3为 -0.40%至 -1.00%。 rl和 r2分别表示内外两 层涂层的半径。  Fig. 3 is a schematic view showing the structure of a refractive index profile of the third embodiment. In this structure, the quartz glass cladding is divided into two layers, wherein the first layer is a pure quartz layer, and the second layer is a low refractive index depressed cladding. Δ1 and Δ3 represent the relative refractive indices of the core and the depressed cladding, respectively; δ ΐ and δ 2 represent the relative refractive indices of the inner and outer coatings, respectively. Rl, R2, and R3 respectively represent the core, the first cladding layered pure silica layer, and the second cladding layer, that is, the radius of the depressed cladding layer, and the second layering radius R3 is 28 μηι to 63 μηι; the relative refractive index difference Δ3 is -0.40% to -1.00%. Rl and r2 represent the radius of the inner and outer coatings, respectively.
图 4是实施例 4的折射率剖面结构示意图。 该结构中石英玻璃包层分为 2层, 其 中第 1分层为低折射率下陷包层, 第 2分层为纯石英层。 Δ1和 Δ2分别表示纤芯和下 陷包层的相对折射率; δΐ和 δ2分别表示内外两层涂层的相对折射率。 Rl、 R2、 R3分 别表示纤芯、 第 1包层分层即下陷包层、 第 2包层分层的半径, 第 1分层半径 R2为 21μηι〜58μηι; 相对折射率差 Δ2为 -0.40%至 -0.80%。 rl和 r2分别表示内外两层涂层的 半径。  Fig. 4 is a view showing the structure of a refractive index profile of the fourth embodiment. In this structure, the quartz glass cladding is divided into two layers, wherein the first layer is a low refractive index depressed cladding layer, and the second layer is a pure quartz layer. Δ1 and Δ2 represent the relative refractive indices of the core and the depressed cladding, respectively; δ ΐ and δ 2 represent the relative refractive indices of the inner and outer coatings, respectively. Rl, R2, and R3 respectively represent the core, the first cladding layer, that is, the depressed cladding layer, and the radius of the second cladding layer. The first layering radius R2 is 21μηι~58μηι; the relative refractive index difference Δ2 is -0.40%. To -0.80%. Rl and r2 represent the radius of the inner and outer coatings, respectively.
图 5是实施例 5的折射率剖面结构示意图。 该结构中石英玻璃包层分为 4层, 其 中第 1分层为纯石英层, 第 2分层为低折射率下陷包层, 第 3分层为掺杂高折射率石 英层, 第 4分层为纯石英层。 Δ1、 Δ3和 Δ4分别表示纤芯、 下陷包层和高折射率掺杂 石英层的相对折射率, 第 2分层半径 R3为 28μηι〜55μηι, 相对折射率差 Δ3为- 0.40% 至 -1.10%, 第 3分层半径 R4为 31μηι〜58μηι, 相对折射率差 Δ4为 0.1%至 0.8%。 δΐ 和 δ2分别表示内外两层涂层的相对折射率。 Rl、 R2、 R3、 R4、 R5分别表示纤芯、 第 1包层分层、 第 2包层分层即下陷包层、 第 3包层分层即高折射率掺杂石英层、 第 4 包层分层即纯石英层的半径。 rl和 r2分别表示内外两层涂层的半径。  Fig. 5 is a view showing the structure of a refractive index profile of the fifth embodiment. In this structure, the quartz glass cladding is divided into four layers, wherein the first layer is a pure quartz layer, the second layer is a low refractive index depressed cladding layer, and the third layer is a doped high refractive index quartz layer, the fourth layer. The layer is a layer of pure quartz. Δ1, Δ3, and Δ4 represent the relative refractive indices of the core, the depressed cladding, and the high refractive index doped quartz layer, respectively, the second layering radius R3 is 28 μηι to 55 μηι, and the relative refractive index difference Δ3 is -0.40% to -1.10%. The third layering radius R4 is 31 μm to 58 μm, and the relative refractive index difference Δ4 is 0.1% to 0.8%. δ ΐ and δ 2 represent the relative refractive indices of the inner and outer coatings, respectively. R1, R2, R3, R4, and R5 respectively represent a core, a first cladding layer, a second cladding layer, that is, a depressed cladding layer, a third cladding layer, that is, a high refractive index doped quartz layer, and a fourth package. Layer stratification is the radius of the pure quartz layer. Rl and r2 represent the radius of the inner and outer coatings, respectively.
图 6是本发明实施例 6的双涂层弯曲不敏感多模光纤折射率剖面结构示意图。 图 中的实线部分表示石英玻璃纤芯和包层的折射率结构, 虚线部分表示内、 外两层涂层 在光纤中的折射率结构。 Δ1表示掺杂石英玻璃纤芯中心相对折射率差, 该结构中石英 玻璃包层的相对折射率差为 0; δΐ和 δ2分别表示内外两层涂层的相对折射率。 R1和 R2分别表示光纤芯层和包层的半径, rl和 r2分别表示内外两层涂层的半径。 Fig. 6 is a schematic view showing the refractive index profile of a double-coated bending insensitive multimode fiber according to Embodiment 6 of the present invention. The solid line in the figure indicates the refractive index structure of the quartz glass core and the cladding, and the dotted line indicates the inner and outer coatings. The refractive index structure in the fiber. Δ1 represents the relative refractive index difference of the center of the doped quartz glass core, and the relative refractive index difference of the quartz glass cladding in the structure is 0; δ ΐ and δ 2 represent the relative refractive indices of the inner and outer coatings, respectively. R1 and R2 represent the radii of the core layer and the cladding, respectively, and rl and r2 represent the radii of the inner and outer coatings, respectively.
图 7是本发明实施例 7和 8的阶跃型能量传输光纤折射率剖面结构示意图。 图中 的实线部分表示石英玻璃纤芯和包层的折射率结构, 虚线部分表示内、 外两层涂层在 光纤中的折射率结构。 掺杂石英玻璃纤芯相对折射率差 Δ1为 0.3%至 1.2%, 该结构中 包层为具有低折射率的掺杂石英玻璃包层, 包层相对折射率差 Δ2为- 0.1%至 -1.1%。 δΐ 和 δ2分别表示内外两层涂层的相对折射率。 Rl和 R2分别表示光纤芯层和包层的半径, rl和 r2分别表示内外两层涂层的半径。  Fig. 7 is a view showing the structure of a refractive index profile of a step type energy transmission fiber according to Embodiments 7 and 8 of the present invention. The solid line in the figure indicates the refractive index structure of the quartz glass core and the cladding, and the broken line indicates the refractive index structure of the inner and outer coatings in the fiber. The relative refractive index difference Δ1 of the doped quartz glass core is 0.3% to 1.2%. In this structure, the cladding is a doped quartz glass cladding with a low refractive index, and the relative refractive index difference Δ2 of the cladding is -0.1% to -1.1. %. δ ΐ and δ 2 represent the relative refractive indices of the inner and outer coatings, respectively. Rl and R2 represent the radii of the core and cladding, respectively, and rl and r2 represent the radii of the inner and outer coatings, respectively.
下表为上述实施例的具体参数:  The following table shows the specific parameters of the above embodiment:
表 1  Table 1
实施例编号 1 2 3 4 5 6 7 8 芯层直径 ( μηι) 50 50 50 50 50 62.5 105 200 芯层 α 1.90 2.03 2.02 2.03 2.19 1.92 - - 芯层折射率 Δ1 ( % ) 1.04 1.10 0.90 0.96 1.02 1.97 0.58 0.46 包层分层数 1 3 2 2 4 1 1 包层直径 (μηι) 80.5 125.4 127.0 125.0 123.0 125.9 124.8 230.5 下陷包层相对折射率 (%) 0 -0.59 -0.52 -0.44 -0.45 0 -0.57 -0.69 内涂层直径 (μηι) 123 185 190 195 192 210 185 325 外涂层直径 (μη ) 165 240 250 249 251 250 250 500 内涂层折射率 1.45 1.42 1.44 1.45 1.45 1.40 1.37 1.41 满注入带宽 Example No. 1 2 3 4 5 6 7 8 Core diameter (μηι) 50 50 50 50 50 62.5 105 200 Core layer α 1.90 2.03 2.02 2.03 2.19 1.92 - - Core refractive index Δ1 ( % ) 1.04 1.10 0.90 0.96 1.02 1.97 0.58 0.46 cladding layer number 1 3 2 2 4 1 1 cladding diameter (μηι) 80.5 125.4 127.0 125.0 123.0 125.9 124.8 230.5 depressed cladding relative refractive index (%) 0 -0.59 -0.52 -0.44 -0.45 0 -0.57 - 0.69 inner coating diameter (μηι) 123 185 190 195 192 210 185 325 outer coating diameter (μη) 165 240 250 249 251 250 250 500 inner coating refractive index 1.45 1.42 1.44 1.45 1.45 1.40 1.37 1.41 full injection bandwidth
4328 6218 2850 2296 5336 350 - - @850nm (MHz-km)  4328 6218 2850 2296 5336 350 - - @850nm (MHz-km)
满注入带宽 Full injection bandwidth
640 637 521 489 631 553 - - @1300nm(MHz-km)  640 637 521 489 631 553 - - @1300nm(MHz-km)
1圈 10mm弯曲半径宏弯  1 turn 10mm bend radius macro bend
0.02 0.03 0.01 0.02 0.01 0.02 0.02 0.01 附加衰减@85(^^1((©)  0.02 0.03 0.01 0.02 0.01 0.02 0.02 0.01 Additional attenuation @85(^^1(()
1圈 5mm弯曲半径宏弯  1 turn 5mm bend radius macro bend
0.10 0.07 0.03 0.07 0.09 0.04 0.05 0.03 附加衰减@85(^^1((©)  0.10 0.07 0.03 0.07 0.09 0.04 0.05 0.03 Additional attenuation @85(^^1(()

Claims

权 利 要 求 书 Claim
1. 一种抗弯曲多模光纤, 包括光纤和包覆在光纤外表面的涂层, 所述的光纤由具 有抛物线形或阶跃形折射率剖面结构的石英玻璃芯层和围绕芯层的石英玻璃包层组 成,其特征在于: 所述的芯层直径 2R1为 20〜200μπι, 由掺锗和氟石英玻璃材料组成, 所述的包层外覆有双层固化的聚合物涂层, 包覆在包层外表面的内涂层为低折射率柔 性聚合物涂层, 外涂层为高杨氏模量的聚合物涂层。 A bend-resistant multimode optical fiber comprising an optical fiber and a coating coated on an outer surface of the optical fiber, the optical fiber being composed of a quartz glass core layer having a parabolic or stepped refractive index profile structure and quartz surrounding the core layer The glass cladding composition is characterized in that: the core layer has a diameter of 2R1 of 20 to 200 μm, and is composed of an erbium-doped and fluoroquartz glass material, and the cladding layer is coated with a double-layer cured polymer coating and coated. The inner coating on the outer surface of the cladding is a low refractive index flexible polymer coating and the outer coating is a high Young's modulus polymer coating.
2. 按权利要求 1所述的抗弯曲多模光纤, 其特征在于: 所述的包层为围绕在芯层 外的纯石英玻璃包层, 或纯石英与掺杂石英玻璃包层的总和, 最外层的石英玻璃包层 直径为 80μπι〜230μπι。 2. The anti-bending multimode optical fiber according to claim 1, wherein: said cladding is a pure quartz glass cladding surrounding the core layer, or a sum of pure quartz and a doped quartz glass cladding. The outermost quartz glass cladding has a diameter of 80 μm to 230 μm.
3. 按权利要求 1 或 2 所述的抗弯曲多模光纤, 其特征在于: 所述的内涂层在 -65°C〜85°C范围内杨氏模量小于或等于 10MPa, 折射率范围是 1.37至 1.455; 外涂层 在 -65°C〜55°C范围内杨氏模量范围是 500MPa〜1500MPa,折射率范围为 1.47至 1.78。 The anti-bending multimode optical fiber according to claim 1 or 2, wherein: the inner coating layer has a Young's modulus of less than or equal to 10 MPa in a range of -65 ° C to 85 ° C, and a refractive index range It is 1.37 to 1.455; the outer coating has a Young's modulus in the range of -65 ° C to 55 ° C of 500 MPa to 1500 MPa, and a refractive index ranging from 1.47 to 1.78.
4. 按权利要求 1或 2所述的抗弯曲多模光纤, 其特征在于: 所述的内涂层为紫外 光固化或热固化的柔性硅橡胶涂层, 内涂层的单边厚度为 ΙΟμπ!〜 40μπι; 所述的外涂 层为紫外光固化或热固化的聚丙烯酸脂涂层, 外涂层的直径为 160μπ!〜 260μπι。 The anti-bending multimode optical fiber according to claim 1 or 2, wherein: the inner coating layer is a UV-curable or heat-curable flexible silicone rubber coating, and the thickness of the inner layer of the inner coating layer is ΙΟμπ ! ~ 40μπι ; The outer coating is UV-cured or heat-cured polyacrylate coating, the outer coating diameter is 160μπ! ~ 260μπι.
5. 按权利要求 3所述的抗弯曲多模光纤, 其特征在于: 所述的芯层折射率剖面结 构为抛物线形, α 为 1.9〜2.2, 相对折射率差 A 1为 0.9%至 1.2%, 内涂层折射率范 围是 1.40至 1.43, 芯层直径为 47μπ!〜 53μπι; 动态疲劳参数 Nd等于或大于 26; 在 850nm波长和 1300nm波长具有 500MHz_km以上的带宽。 The anti-bending multimode optical fiber according to claim 3, wherein: said core layer has a refractive index profile of a parabolic shape, α is 1.9 to 2.2, and relative refractive index difference A 1 is 0.9% to 1.2%. , the inner coating refractive index range is 1.40 to 1.43, and the core layer diameter is 47μπ! ~ 53μπι ; dynamic fatigue parameter Nd is equal to or greater than 26; has a bandwidth of 500 MHz_km or more at a wavelength of 850 nm and a wavelength of 1300 nm.
6. 按权利要求 3所述的抗弯曲多模光纤, 其特征在于: 所述的芯层折射率剖面结 构为抛物线形, α 为 1.9〜2.2,相对折射率差 A 1为 1.8%至 2.3%,芯层直径为 60 μ m〜 65 μ m。 The anti-bending multimode optical fiber according to claim 3, wherein: said core layer has a refractive index profile of a parabolic shape, α is 1.9 to 2.2, and relative refractive index difference A 1 is 1.8% to 2.3%. The core layer has a diameter of 60 μm to 65 μm.
7. 按权利要求 5所述的抗弯曲多模光纤, 其特征在于: 包层分为 3层, 其中第 1 和第 3分层为纯石英玻璃层,第 2分层为下陷包层,第 2分层半径 R3为 28 μ m 58 μ m 相对折射率差 Δ 3为 -0. 50%至 -0. 90% The anti-bending multimode optical fiber according to claim 5, wherein the cladding layer is divided into three layers, wherein the first layer and the third layer are pure quartz glass layers, and the second layer is a depressed cladding layer. 2 层的半径R2 is 28 μ m 58 μ m Relative refractive index difference Δ 3 is -0. 50% to -0.90%
8. 按权利要求 5所述的抗弯曲多模光纤, 其特征在于: 包层分为 2层, 其中第 1 分层为纯石英玻璃层, 第 2分层为低折射率下陷包层, 第 2分层半径 R3为 28 μ πι 63 μ m, 相对折射率差 Δ 3为 -0. 40%至- 1· 00% 8. The anti-bending multimode optical fiber according to claim 5, wherein: the cladding layer is divided into two layers, wherein the first layer is a pure quartz glass layer, and the second layer is a low refractive index depressed cladding layer, 2 The layering radius R3 is 28 μ πι 63 μ m, and the relative refractive index difference Δ 3 is -0.40% to -1· 00%
9. 按权利要求 5所述的抗弯曲多模光纤, 其特征在于: 包层分为 2层, 其中第 1 分层为低折射率下陷包层, 第 2分层为纯石英玻璃层, 第 1分层半径 R2为 21 μ πι 58 μ m, 相对折射率差 Δ 2为 -0. 40%至 -0. 80% 9. The anti-bending multimode optical fiber according to claim 5, wherein: the cladding layer is divided into two layers, wherein the first layer is a low refractive index depressed cladding layer, and the second layer is a pure quartz glass layer, The layered radius R2 is 21 μ πι 58 μ m, and the relative refractive index difference Δ 2 is -0.40% to -0.80%
10. 按权利要求 5所述的抗弯曲多模光纤, 其特征在于: 包层分为 4层, 其中第 1、第 4分层为纯石英玻璃层, 第 2分层为低折射率下陷包层, 第 3分层为掺杂高折射 率石英层, 第 2分层半径 R3为 28 μ n 55 μ m, 相对折射率差 Δ 3为 -0. 40%至 -1. 10% 第 3分层半径 R4为 31 μ m 58 μ m, 相对折射率差 A 4为 0. 1%至 0. 8%  10. The anti-bending multimode optical fiber according to claim 5, wherein: the cladding layer is divided into four layers, wherein the first layer and the fourth layer are pure quartz glass layers, and the second layer is a low refractive index sinking package. Layer, the third layer is a doped high refractive index quartz layer, the second layer radius R3 is 28 μ n 55 μ m, and the relative refractive index difference Δ 3 is -0.40% to -1. 10% 1%至0. 8%。 8% 。 8% 8% 8% 8% 8%
11. 按权利要求 3所述的抗弯曲多模光纤, 其特征在于: 芯层结构为阶跃形, 包 层为一层石英玻璃包层, 芯层相对折射率差 Δ 1为 0. 3%至 1. 2%, 包层为具有低折射率 的掺杂石英玻璃包层, 包层相对折射率差 Δ 2为- 0. 1%至 -1. 1% 3%。 The core layer is a layer of quartz glass cladding, the relative refractive index difference Δ 1 of the core layer is 0. 3% 1%至-1. 1%, the cladding relative refractive index difference Δ 2 is -0. 1% to -1. 1%
12. 按权利要求 3所述的抗弯曲多模光纤,其特征在于:所述的多模光纤在 850nm 波长处, 以 10 弯曲半径绕 1圈导致的弯曲附加衰减小于或等于 0. 15dB The bending-resistant multimode optical fiber according to claim 3, wherein the multimode fiber has a bending attenuation of less than or equal to 0.15 dB at a wavelength of 850 nm and a radius of 10 turns of one turn.
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