WO2011013654A1

WO2011013654A1 - Cosmetic

Info

Publication number: WO2011013654A1
Application number: PCT/JP2010/062598
Authority: WO
Inventors: 和浩中村; 利昭久保
Original assignee: 富士フイルム株式会社
Priority date: 2009-07-30
Filing date: 2010-07-27
Publication date: 2011-02-03
Also published as: JP2011046695A

Abstract

Provided is a cosmetic that contains a composite powder comprising: mica flakes having a mean thickness between 50 nm and 200 nm and an aspect ratio between 5 and 1000; and a coating layer that coats the surfaces of the mica flakes and that has a refractive index higher than that of the mica flakes.

Description

Cosmetics

The present invention relates to cosmetics.

Conventionally, for example, makeup cosmetics cover the dullness of the skin color that is felt with aging due to poor blood circulation and pigmentation (a state in which lightness decreases and yellow saturation increases), so concealment of titanium oxide, iron oxide, etc. Cosmetics containing a high-strength pigment and cosmetics that change the hue of the skin by adding red, such as Bengala, lake pigments, or organic pigments, are known.
Also known is a technology that improves lightness and bluishness and improves transparency by blending blue interference mica into the foundation instead of pigments with high hiding power that may give an unnatural impression. (For example, JP-A-11-139929).

On the other hand, a composite powder using metal oxide flakes and a cosmetic using the same are also known in order to have high ultraviolet shielding ability, high transparency to visible light, and obtaining a good feeling of use. .
For example, in JP-A-7-315858, metal oxide fine particles having a particle diameter of 30 nm to 120 nm are dispersed in the form of single particles, and a metal oxide fine particle-dispersed flaky glass having a thickness of 0.4 μm to 0.9 μm. And cosmetics containing the same are disclosed.
Japanese Patent Application Laid-Open No. 9-71417 discloses that a surface of a metal oxide flake powder mainly composed of amorphous silica having an aspect ratio of 0.4 to 0.8 μm and an aspect ratio of 50 to 94 has a thickness of 25 to 95 nm. A titanium oxide-coated metal oxide flaky powder coated with a titanium oxide layer having a thickness and a cosmetic containing the same are disclosed.

In contrast, JP-A-2005-314649 discloses an interference pigment in which SiO ₂ flakes or natural or synthetic mica flakes are coated with a high refractive index layer made of TiO ₂ having a thickness of 20 to 200 nm. This interference pigment is used for so-called `` color flop '' in which the color of reflected light changes greatly depending on the viewing angle rather than the natural finish, and in the case of cosmetics such as nail polish, loose powder, gel, It is described as being characterized by particularly interesting color effects and strong color shifts.

However, it is difficult to say that cosmetics using blue interference mica are sufficient in terms of both lightness and saturation. Further, the metal oxide flake powder disclosed in JP-A-9-71417 or JP-A-2005-314649 has a low reflectance as a powder, and therefore has sufficient brightness when blended in cosmetics. It is difficult to obtain, and the saturation as a cosmetic may be impaired.

An object of the present invention is to provide a cosmetic with good brightness and saturation.

The present invention is as follows.
[1] A mica flake having an average thickness in the range of 50 nm to 200 nm and an aspect ratio in the range of 5 to 1000, and a coating layer that covers the surface of the mica flake and has a higher refractive index than the mica flake. Cosmetics containing the composite powder.
[2] The cosmetic according to [1], wherein the mica flakes have an average thickness in the range of 50 nm to 150 nm and an aspect ratio in the range of 10 to 400.
[3] The cosmetic according to [1], wherein the mica flakes have an average thickness in the range of 70 nm to 120 nm and an aspect ratio in the range of 10 to 300.
[4] The cosmetic according to any one of [1] to [3], wherein an average thickness (μ) and standard deviation (σ) of the mica flakes satisfy σ / μ ≦ 0.5.
[5] The cosmetic according to any one of [1] to [3], wherein an average thickness (μ) and standard deviation (σ) of the mica flakes satisfy σ / μ ≦ 0.3.
[6] The cosmetic according to any one of [1] to [5], wherein the coating layer has an average thickness in the range of 25 nm to 90 nm.
[7] The cosmetic according to any one of [1] to [6], wherein the average thickness of the composite powder is in the range of 100 nm to 300 nm.
[8] The mica, wherein the composite powder has an average thickness of 70 nm to 120 nm and an aspect ratio of 10 to 300, and an average thickness (μ) and a standard deviation (σ) are σ / μ ≦ 0.3. The cosmetic according to [1], comprising flakes and the coating layer having an average thickness of 40 nm to 60 nm, wherein the composite powder has a total average thickness of 150 nm to 240 nm.
[9] The cosmetic according to any one of [1] to [8], wherein the mica flake has an average particle size of 1 μm to 20 μm.
[10] The cosmetic according to any one of [1] to [9], wherein the mica flakes are synthetic mica flakes.
[11] The cosmetic according to any one of [1] to [10], wherein the coating layer contains at least one metal oxide selected from titanium oxide, tin oxide, zinc oxide and zirconium oxide as a main component.
[12] The cosmetic according to any one of [1] to [11], which is a foundation, a makeup base, or a face powder.

The cosmetic of the present invention comprises a mica flake having an average thickness in the range of 50 nm to 200 nm and an aspect ratio in the range of 5 to 1000, a coating covering the surface of the mica flake, and having a higher refractive index than the mica flake A cosmetic comprising a composite powder comprising a layer.

The cosmetic of the present invention contains a composite powder in which mica flakes coated with a coating layer having a refractive index higher than that of mica flakes are formed in a shape represented by a predetermined average thickness and aspect ratio. The rate is very high, improving the overall brightness of the cosmetics and at the same time keeping the chroma high. Thereby, the cosmetics with a bright and vivid finish can be provided.

In this specification, the term “process” is not limited to an independent process, and is included in this term if the intended action of this process is achieved even when it cannot be clearly distinguished from other processes. .
In the present specification, a numerical range indicated by using “to” indicates a range including the numerical values described before and after “to” as the minimum value and the maximum value, respectively.
Further, in the present invention, when referring to the amount of each component in the composition, when there are a plurality of substances corresponding to each component in the composition, the plurality present in the composition unless otherwise specified. Means the total amount of substances.
The present invention will be described below.

The mica flakes in the present invention are mica flakes having an average thickness in the range of 50 nm to 200 nm and an aspect ratio in the range of 5 to 1000.
By adopting such a mica flake shape, the powder alone has a high reflectance due to the reflectance of the mica flake itself in a wide wavelength region of visible light by the principle of thin film interference when the coating layer described later is provided. It becomes the powder which has.

In the present invention, “mica flake” means the whole aggregate of powder (individual flakes), and values such as average thickness and aspect ratio mean the average and aspect ratio of the whole mica flake as an aggregate. .

In the present invention, the “thickness” of the powder means the maximum length of an axis perpendicular to the reference plane, with the plane having the maximum area among the surfaces constituting one powder as the reference plane. “Horizontal” means the length of the long axis that is the maximum of the reference plane, and “Vertical” means the minimum length of the axis that is orthogonal to the long axis that is the maximum of the reference plane.

In the present invention, “average particle size” refers to what is generally used for tabular grains in the industry, that is, the sum of the length and width of one powder, ie, the length in the major axis direction. And the length in the minor axis direction is divided by 2.

The average thickness of mica flakes in the present invention is preferably 50 nm to 150 nm, more preferably 70 nm to 120 nm in order to further increase the reflectance of the mica flakes in a wide wavelength region of visible light by the principle of thin film interference. is there.
The thickness of mica flakes can be generally measured by measuring the powder into ultra-thin slices and then measuring by transmission electron micrograph, or by measuring by scanning electron micrograph after cutting the section. However, it is not limited to this. The average thickness of mica flakes is taken as the average of the thicknesses at 1000 locations by taking a transmission electron micrograph of each mica flake, measuring, for example, 10 locations of 100 powders (flakes) and measuring the respective thicknesses. That's fine.

The aspect ratio of the mica flakes is preferably 10 or more from the viewpoint of easily expressing so-called leafing properties in which the composite powder itself containing mica flakes is arranged along the skin surface when applied to the skin as a cosmetic. On the other hand, when applied to cosmetics as a flat powder having a high reflectivity, the particle size may not be small to some extent in order to achieve a natural finish. 10 to 300 are preferable. In general, the aspect ratio can be measured by observing the powder by scanning electron micrograph. The aspect ratio of the mica flake may be, for example, a value obtained by dividing the average particle diameter of 100 particles measured by observing the powder by the average thickness of the powder measured by the above method.

The average particle diameter of the mica flakes is preferably 1 μm to 20 μm, and more preferably 10 μm to 20 μm. If it is 1 micrometer or more, sufficient leafing property will be obtained, and if it is 20 micrometers or less, it can suppress a crack.

The mica flakes in the present invention desirably have a narrow thickness distribution. By using mica flakes with a narrow thickness distribution, both brightness and saturation are improved, and a bright and vivid finish is easily realized.
The narrow thickness distribution of mica flakes in the present invention means that most of the mica flakes used are concentrated in the vicinity of the average thickness, and in the mica flakes used, Smaller mica flakes may be present. Such a narrow thickness distribution can be expressed by the relationship between the average thickness (μ) of mica flakes and the standard deviation (σ), and σ / μ ≦ 1 is an index indicating that the substantial thickness distribution is narrow. It becomes.

From the viewpoint that the reflectance and interference color due to the interference of the mica flakes themselves are reflected in that of the composite powder, and the brightness and saturation are more compatible, the average thickness (μ) of the mica flakes and the standard deviation (σ) Is more preferably σ / μ ≦ 0.5, and even more preferably σ ≦ μ × 0.3.

The average thickness, aspect ratio, and average particle diameter of the mica flakes as described above may be any combination as long as two or more of these are combined, but the reflectivity is improved in a wider wavelength region. From the viewpoint of obtaining high mica flakes, preferably mica flakes having an average thickness of 50 nm to 150 nm and an aspect ratio of 5 to 400, and an average particle diameter of 1 μm to 20 μm can be obtained, and more preferably. In addition, mica flakes having an average thickness of 70 nm to 120 nm and an aspect ratio of 10 to 300 and an average particle diameter of 1 μm to 20 μm can be obtained.

Mica flakes have moderately low smoothness compared to glass flakes obtained by applying a metal alkoxide as a precursor to the substrate and peeling it off after forming on the substrate. It is known to be difficult. The mica flakes in the present invention may be natural mica flakes or synthetic mica flakes. Among them, synthetic mica flakes have high transparency and are particularly preferable for application to the present invention.

The synthetic mica flakes in the present invention can be distinguished from natural mica flakes based on the so-called impurity content in the mica. That is, the synthetic mica flakes are specified as those having an Fe content of less than 0.1% with respect to the mass of the mica flakes, which causes coloring that impairs transparency. In general, the content of Fe in mica flakes can be measured by fluorescent X-rays or the like.
The mica flakes having a specific shape in the present invention can be obtained by separating commercially available mica flakes in a layered manner by a known method and further classifying them.

The coating layer of the composite powder in the present invention covers the surface of mica flakes and has a higher refractive index than the mica flakes (refractive index: 1.58).
Here, the compound forming the coating layer is only required to have a higher refractive index than the mica flakes in order to obtain a high reflectance in a wavelength region having a wide visible range by the principle of thin film interference. The refractive index in this case is generally based on a value calculated from reflectance measurement or ellipsometer measurement when a thin film is formed on a reference plate with a known refractive index. When measured in this way, if the refractive index of the mica flakes is 1.58, for example, the refractive index of the coating layer is higher than 1.58, preferably 2.00 or higher, more preferably 2.20 or higher, 2.40 or more is more preferable.

Such a coating layer preferably contains a metal oxide as a main component. Examples of such metal oxides include titanium oxide (anatase type titanium dioxide: refractive index 2.52, rutile type titanium dioxide: refractive index 2.71), zirconium oxide (refractive index 2.40), tin oxide, and oxidation. Zinc (refractive index 1.95) or the like, or a combination of two or more thereof can be given. Among them, since it has a higher refractive index, it is preferable that the main component is at least one metal oxide selected from titanium oxide, tin oxide, and zinc oxide, and titanium oxide having a particularly high refractive index compared to mica flakes. Is most preferred.
The term “containing a metal oxide as a main component” means that the component mainly constituting the coating layer is a metal oxide. For example, the mass of the metal oxide is at least 90% by mass with respect to the total mass. Above, especially the case where 95 mass% or more is contained is said.

The method for coating the mica flakes with the coating layer may be any method known as a wet method or a vapor deposition method. For example, a method for hydrolyzing acidic sulfuric acid titanium oxysulfate at a boiling temperature (for example, JP-B 43-25644) and a method for hydrolyzing titanium tetrachloride (for example, JP-B 49-3824) are generally known. By these methods, for example, by coating a titanium oxide precursor and then heat-treating at 700 to 1000 ° C., a stable and high-density titanium oxide coating layer can be obtained.

The coating average thickness of the coating layer is preferably 25 nm to 90 nm from the viewpoint of improving the reflectance of the powder. If the average thickness is 25 nm or more, a sufficient increase in the reflectance of the powder can be expected. On the other hand, if the average thickness is 90 nm or less, the wavelength that gives the maximum and minimum of the reflection spectrum is sufficiently separated from each other. A decrease in average reflectance in the wavelength region of the entire light can be suppressed. The average thickness of the coating layer is more preferably 40 nm to 60 nm when the compound constituting the coating layer is titanium oxide.
Here, the distribution of the average thickness of the coating layer between the powders is preferably as small as possible. According to the above known method, the average thickness distribution of the coating layer between the powders is 10% or less calculated by multiplying the standard deviation divided by the average thickness by 100, more strictly 5%. It is known that the effect of improving the reflectance of the composite powder by thin film interference can be exhibited.

When the mica itself that is the substrate of the composite powder is macroscopically white, when the average thickness of the coating layer is less than 40 nm, the resulting composite powder is white with high thickness transparency. When the average thickness of the coating layer is 40 to 60 nm, the composite powder becomes highly transparent silver. Further, when the average thickness of the coating layer is gradually increased to 160 nm, the transparency of yellow, red, magenta, blue and green is improved. Coloring (interference color) having a color is recognized. Further, when the average thickness of the coating layer is increased, the same colors of golden, red, magenta, blue and green are repeatedly observed.
The mica according to the present invention is colored silver to golden by interference effect and thickness distribution control even on a single substrate, so that the composite powder has a slightly yellowish silver color when the average thickness of the coating layer is 40 to 60 nm. ~ Golden color, lightness can be improved without causing reduction in saturation, and is most preferably used.

These colors are clearly different from those of titanium oxide-coated mica, which is generally widely used for foundations and the like, and a more transparent feeling, higher reflectance, and bright interference colors are recognized. The reason is that mica flakes themselves have an interference color due to optical thin film interference whose thickness is controlled.

The composite powder in the present invention comprises the above-described mica flakes and a coating layer, and exhibits high transparency, color developability, and high reflectance as described above.
The average thickness of the composite powder as a whole (total average thickness) is a value obtained by adding twice the average thickness of the coating layer to the average thickness of the mica flakes. It is determined from the optimum thickness range of the coating layer. Accordingly, the total average thickness of the composite powder is preferably 100 nm to 330 nm, more preferably 120 nm to 300 nm, and still more preferably 150 nm to 240 nm.

The composite powder according to the present invention has mica flakes having an average thickness of 70 nm to 120 nm and an aspect ratio of 100 to 300, and an average thickness (μ) and standard deviation (σ) of σ / μ ≦ 0.3. It is composed of flakes and a coating layer having an average thickness of 40 nm to 60 nm, and the total average thickness of the composite powder is 150 nm to 240 nm. From the viewpoint, it is particularly preferable.

The cosmetic of the present invention is a cosmetic containing a composite powder composed of mica flakes having the above coating layer.
As described above, since this cosmetic contains a composite powder having high transparency, colorability and high reflectance, it has high visible light transparency, high brightness and saturation, and is used particularly as a foundation. In some cases, it can be a bright and vivid product.

The compounding amount of the composite powder in the cosmetic of the present invention varies depending on the type of the intended cosmetic, but is preferably used in the range of 1 to 80% by mass with respect to the total mass of solid components such as pigments. May be in the range of 2-50% by weight, more preferably 5-30% by weight. If the content is 1% by mass or more, brightness, saturation and color developability can be sufficiently expected. On the other hand, if it is 80 mass% or less, sufficient addition effects by other additives, for example, change in color tone, ease of preparation, or improvement in adhesion to the skin can be sufficiently obtained. In the present invention, the “solid component” means a component that is solid at 25 ° C. and 1 atm.

In the cosmetic of the present invention, in addition to the above composite powder, a commonly used pigment or the like can be used in combination as necessary. For example, titanium oxide, zinc oxide, zirconium oxide, yellow iron oxide, black iron oxide, petal, ultramarine, bitumen, and other inorganic pigments; pearlescent pigments such as mica titanium and bismuth oxychloride; tar dyes, natural dyes, silica beads Powders such as plastic beads such as nylon, acrylic and urethane; extender pigments such as talc, kaolin, mica and sericite; other mica, magnesium carbonate, calcium carbonate, aluminum silicate, magnesium silicate, clays, etc. Is done. You may use these substances individually or in combination of 2 or more types.

Also, in order to improve the dispersibility of the composite powder in the cosmetic of the present invention and to improve the feel, the composite powder may be subjected to surface treatment and modified. For example, known fluorine-containing surface treatment agent, methyl hydrogen polysiloxane, reactive alkyl polysiloxane, metal soap, hydrogenated lecithin, acylamino acid, acylated collagen aluminum, magnesium, calcium, titanium, zinc, zirconium, When a surface treatment is performed with a so-called hydrophobizing agent such as a metal salt selected from iron, the surface of the metal oxide coating layer changes from hydrophilic to hydrophobic. It is possible to improve the makeup and to impart water repellency, thereby reducing makeup collapse.

In addition to the above powder components, the cosmetics of the present invention include components blended in ordinary cosmetics, for example, various oils, surfactants, water-soluble substances, as long as the effects of the present invention are not impaired as necessary. A functional polymer, other powders, humectants, preservatives, drugs, ultraviolet absorbers, dyes, inorganic salts or organic acid salts, fragrances, chelating agents, pH adjusters, water and the like.

Examples of the oil include liquid paraffin, petrolatum, paraffin wax, squalane, beeswax, carnauba wax, olive oil, lanolin, higher alcohol, fatty acid, higher fatty acid, ester oil, ceresin, microcrystalline wax, candelilla wax, diglyceride, triglyceride, silicone oil. Oils commonly used in cosmetics such as perfluoropolyether, perfluorodecalin, perfluorooctane, jojoba oil, octyldodecyl myristate, and neopentyl glycol dioctanoate are used. Examples of the surfactant include polyoxyethylene alkyl ether, polyoxyethylene fatty acid ester, polyoxyethylene sorbitan fatty acid ester, glycerin fatty acid ester, polyglycerin fatty acid ester, polyoxyethylene glycerin fatty acid ester, polyoxyethylene hydrogenated castor oil, polyoxyethylene Nonionic surfactants such as oxyethylene sorbitol fatty acid esters; anionic surfactants typified by fatty acid soaps such as sodium stearate and triethanolamine palmitate; and cationic surfactants and amphoteric surfactants Surfactants that are widely used in cosmetics are used. Examples of water-soluble polymers include carboxymethylcellulose, methylcellulose, hydroxymethylcellulose, polyvinyl alcohol, polyvinylpyrrolidone, tragacanth gum, carrageenan, locust bean gum, dextrin, dextrin fatty acid ester, carboxyvinyl polymer, xanthan gum, gelatin, sodium alginate, gum arabic, etc. Water-soluble polymers widely used in cosmetics are used.

As a humectant, it is widely used in cosmetics such as sorbitol, xylitol, glycerin, maltitol, propylene glycol, 1,3-butylene glycol, 1,4-butylene glycol, sodium pyrrolidonecarboxylate, lactic acid, sodium lactate, polyethylene glycol, etc. Moisturizers are used. As the preservative, for example, a preservative widely used in cosmetics such as paraoxybenzoic acid alkyl ester, sodium benzoate, potassium sorbate and the like is used. As the drug, for example, drugs commonly used in cosmetics such as vitamins, herbal medicines, anti-inflammatory agents, and bactericides are used. Examples of UV absorbers include UV absorbers commonly used in cosmetics such as paraaminobenzoic UV absorbers, anthranyl UV absorbers, salicylic acid UV absorbers, cinnamic acid UV absorbers, and benzophenone UV absorbers. Is used.

Examples of the dye include Red No. 3, Red No. 104, Red No. 106, Red No. 201, Red No. 202, Red No. 204, Red No. 205, Red No. 220, Red No. 226, Red No. 227, Red No. 228, Red 230, Red 401, Red 505, Yellow 4, Yellow 5, Yellow 202, Yellow 203, Yellow 204, Yellow 401, Blue 1, Blue 2, Blue 201, Blue 404 Tar dyes such as Green No. 3, Green No. 201, Green No. 204, Green No. 205, Orange No. 201, Orange No. 203, Orange No. 204, Orange No. 206, Orange No. 207; Carminic acid, laccaic acid, bradylin, crocin A commonly used pigment for cosmetics such as natural pigments is used.

Examples of inorganic salts or organic acid salts include inorganic acids such as hydrochloric acid, sulfuric acid and nitric acid; oxycarboxylic acids such as citric acid, tartaric acid, lactic acid and malic acid; carboxylic acids such as formic acid, acetic acid and sorbic acid; or salicylic acid and benzoic acid An alkali metal salt, an alkaline earth metal salt or an aluminum salt of an aromatic carboxylic acid such as

Specific examples of preferred inorganic salts or organic acid salts include potassium sulfate, sodium sulfate, magnesium sulfate, aluminum sulfate, potassium nitrate, sodium nitrate, magnesium nitrate, aluminum nitrate, calcium nitrate, potassium chloride, magnesium chloride, sodium chloride, calcium chloride. , Aluminum chloride, potassium carbonate, sodium carbonate, aluminum carbonate, potassium acetate, sodium acetate, calcium acetate, magnesium acetate, sodium formate, potassium formate, magnesium formate, sodium citrate, sodium tartrate, potassium sorbate, sodium sorbate, salicylic acid Sodium, potassium benzoate, sodium benzoate, etc., especially potassium sulfate, magnesium sulfate, potassium chloride, magnesium chloride, aluminum chloride Um, sodium citrate, sodium tartrate, potassium sorbate, sodium salicylate and sodium benzoate preferred.

These inorganic salts or organic acid salts may be incorporated into the composition of the present invention in the form of a salt, but when the cosmetic of the present invention is produced, the corresponding acid substance and base substance form a salt. It may be added in the stoichiometric amount necessary for this. Moreover, water can be mix | blended in arbitrary quantity.

Since the cosmetic of the present invention has good brightness and saturation as described above, it can be used as various types of cosmetics including the cosmetic. Such cosmetics are preferably used for foundations such as powder foundations, oily foundations, creamy foundations, liquid foundations, concealers, etc., makeup bases, face powders, etc., and point makeup cosmetics such as lipsticks and blushers Can be used.

Since the cosmetics of the present invention have good saturation and lightness, they can reduce dullness and provide a good finish with a bright transparency when applied to any application such as a makeup base or foundation. Can do.

Hereinafter, the present invention will be described in detail with reference to examples. However, the present invention is not limited to them. Unless otherwise specified, “part” is based on mass.

[Examples 1 to 9, Comparative Examples 1 to 5]
<Production of composite powder>
Various composite powders listed in Table 1 were prepared by the following method.

Commercial synthetic phlogopite flakes were pulverized with a commercial pulverizer and further classified to obtain synthetic mica flakes having the desired thickness and aspect ratio shown in Table 1. The thickness was adjusted by repeating trial and error while changing the grinding conditions. The thickness distribution was adjusted by changing the classification conditions.

The average thickness was measured by measuring 10 thicknesses of 100 pieces of transmission electron micrographs of ultrathin sections of each plate-like powder, and measuring the thicknesses. The average thickness (μ) at 1000 locations. Was used. In addition, the thickness distribution was evaluated as a value of σ / μ by calculating a standard deviation (σ) from the thickness value of 1000 and the average thickness (μ).

Specifically, it was prepared by purchasing a thin product available as a commercially available synthetic phlogopite, and further grinding and classifying it. That is, PDM-40L (manufactured by Topy Industries, Ltd., synthetic phlogopite with a particle size of 40 μm and an average thickness of 290 nm) was pulverized by a commercially available pulverizer and classified, and the desired thickness and aspect ratio described in Table 1 were obtained. Synthetic mica flakes having were obtained.

Literature values were used for the refractive indexes of the mica of Examples and Comparative Examples. The refractive index of the coating layer is separately measured by forming a thin film with a thickness of 100 nm on optical glass with a known refractive index (BK-7, refractive index = 1.510), measuring the reflection spectrum, and fitting. did.
The aspect ratio is the size (vertical and horizontal) of 100 powders taken from a photograph taken with a scanning electron microscope of flat plate powders spread and dispersed horizontally on a support substrate. (Average value) was measured, and a value obtained by dividing the average value of 100 powders by the average value of thicknesses calculated by the above method was used.

The coating layer was formed by a known wet method described in JP-A-09-71417. That is, after adding a titanium oxide precursor (titanium oxysulfate aqueous solution and sulfuric acid) to a dispersion in which synthetic mica flakes are dispersed, heating, stirring, filtering, washing and drying are performed, and the precursor is heated at a high temperature (1000 ° C.). Heat treatment was performed to form a titanium oxide coating layer.
The average thickness of the coating layer was measured by observation with a transmission electron micrograph in the same manner as when measuring the average thickness of the synthetic mica flakes with respect to the average thickness of the composite powder, and the average thickness of the composite powder and the average thickness of the synthetic mica flakes. I asked for it. Regarding the distribution of the coating layer thickness of the composite powder, an ultra-thin slice having a thickness of 100 nm was separately prepared, and the coating thickness was measured for each of 10 fields with 10 transmission powders using a transmission electron microscope. The values calculated by multiplying the standard deviation divided by the average thickness by 100 were all 10% or less.

<Preparation of powder foundation>
Examples 1 to 9 and Comparative Example 1 were prepared by weighing each of the components of A phase and B phase described below (numerical values are parts by mass) and mixing them thoroughly with a Henschel mixer until the color material was elongated. ~ 4 powder foundations were prepared. The types of composite powder in the A phase were those listed in Table 1, respectively.

Phase A Sericite 47.1 parts Talc 21.2 parts Titanium oxide 9.0 parts Iron oxide (yellow) 1.8 parts Iron oxide (red) 0.54 parts Iron oxide (black) 0.27 parts Composite powder ( Table 1) 10.0 parts Methyl paraben 0.09 parts Phase B dimethicone (and) trimethylsiloxysilicate 2.985 parts dimethicone (20 cs) 7.0 parts tocopherol 0.005 parts phenoxyethanol 0.01 part

<Comparative Example 5>
A foundation (base formulation) of Comparative Example 5 was prepared in the same manner as in Example 1 except that 10.0 parts of the composite powder in Table 1 were replaced with 6.9 parts of sericite and 3.1 parts of talc. .

<Foundation application>
On a commercially available skin color stain sheet (Bioplate (manufactured by Beaulux Co., Ltd.). In the background of the skin color standard color, a sheet having a dark skin color circular portion having different concentrations of 5 levels corresponding to the normal portion and the stain portion) The foundations of Examples 1 to 9 and Comparative Examples 1 to 5 were uniformly applied at a coating amount of 0.3 (g / cm ³ ) to obtain samples.

<Foundation evaluation>
The skin color of the normal part of each sample coated with each foundation on the above skin color stain sheet is measured with a color difference meter CR-400 (manufactured by Konica Minolta Sensing Co., Ltd.), and the brightness L *, a * with a C light source is measured. , B *, and chroma C * were obtained.
Subsequently, the spot portion of each sample was measured, and the color difference ΔE * ab between the value obtained at the spot portion and the value obtained at the normal portion was calculated by the following equation. The value obtained for the darkest spot (spot-1) and the next darkest spot (spot-2) among the five stages of spots was used as the evaluation of the covering power. Moreover, the covering force with respect to the sheet was visually evaluated by a five-step evaluation (comparative example 5 was 3 points and uncoated was 0 points). The results are shown in Table 2.
Color difference (ΔE * ab) = {(ΔL) ² + (Δa) ² + (Δb) ² } ^1/2

As shown in Table 2, it can be seen that Examples 1 to 9 all have good brightness and saturation, a bright and vivid finish, and high covering power. In particular, it can be seen that Examples 5, 6, and 7 have both high brightness and saturation, and are bright and vivid.
On the other hand, in Comparative Examples 1 to 3 where the thickness of mica flakes is large, it is clear that such lightness and saturation cannot be achieved at a high level, and even if glass flakes having a narrow thickness distribution are used, saturation is not achieved. (See Comparative Example 4), it can be seen that the effects of the present invention cannot be obtained.

[Examples 10 to 18, Comparative Examples 6 to 10]
Each component of the A phase, B phase, and C phase described below was weighed separately. In addition, the kind of composite powder in A phase used the thing of Table 1, respectively. Phase B was added to the container of the homomixer, and phase A was gradually added while stirring, and then the container was heated to 80 ° C. and stirred until all the components in phase B were melted. Separately, the container to which Phase C was added was also heated to 80 ° C. and stirred until all components were dissolved. Subsequently, the mixture of the B phase and the A phase and the aqueous solution of the C phase are both cooled to 50 ° C., and the C phase is gradually added to the B phase while stirring with a homomixer and stirred until it is sufficiently emulsified. Each of the liquid foundations of Examples 10 to 18 including the same composite powder as that of Examples 1 to 9 and the same composite powder as that of Comparative Examples 1 to 5 are included or no composite powder is included. Each liquid foundation of Comparative Examples 6 to 10 was prepared.

Phase A Talc 3.9 parts Titanium oxide 9.6 parts Iron oxide (yellow) 0.8 parts Iron oxide (red) 0.2 parts Iron oxide (black) 0.02 parts Composite powder (Table 1) 5.0 Part B Phase Cyclomethicone 5.0 parts Cyclomethicone (and) dimethicone copolyol 15.0 parts Synthetic wax 0.10 parts Arachidyl behenate 0.3 parts Trihydroxystearin 0.4 parts Phenyl trimethicone 5.0 parts Tri Decylisononanoate 5.0 parts Laureth-7 0.5 part Phase C Deionized water 43.0 parts BG 8.0 parts NaCl 2.0 parts Na acetic anhydride 0.3 part Phenoxyethanol 0.2 part EDTA-2Na 0 .1 part

The liquid foundations of Examples 10 to 18 and Comparative Examples 6 to 10 were evaluated in the same manner as the above powder foundation.
As a result, the foundations of Examples 10 to 18 were all excellent in lightness and saturation.
In contrast, the foundations of Comparative Examples 6 to 9 and the liquid foundation (Comparative Example 10) of a general-purpose prescription not containing a composite powder could not achieve such high levels of brightness and saturation.

[Example 19]
Face powders were prepared in the same manner as in Examples 1 to 9, except that the B phase of the powder foundation of Examples 1 to 9 was not used. About the obtained face powder, the liquid foundation base formulation of Comparative Example 10 (not including the composite powder) was uniformly applied to the surface uniformly applied at a coating amount of 1.0 (mg / cm ³ ), and further 0.1 (mg / Samples uniformly coated with a coating amount of cm ³ ) were evaluated in the same manner as in Examples 1 to 9.
The obtained face powder, like the powder foundations of Examples 1 to 9, was excellent in brightness and saturation and had a bright and vivid finish.

Thus, according to the present invention, it is possible to obtain a preferable cosmetic such as a foundation or face powder having a bright and bright finish with both lightness and saturation being good.

The disclosure of Japanese Patent Application No. 2009-178258 filed on July 30, 2009 is incorporated herein by reference in its entirety.
All documents, patent applications, and technical standards mentioned in this specification are to the same extent as if each individual document, patent application, and technical standard were specifically and individually described to be incorporated by reference, Incorporated herein by reference.

Claims

Mica flakes having an average thickness in the range of 50 nm to 200 nm and an aspect ratio in the range of 5 to 1000;
A coating layer covering the surface of the mica flakes and having a higher refractive index than the mica flakes;
Cosmetics containing a composite powder consisting of
The cosmetic according to claim 1, wherein the mica flakes have an average thickness in the range of 50 nm to 150 nm and an aspect ratio in the range of 10 to 400.
The cosmetic according to claim 1, wherein the mica flakes have an average thickness in the range of 70 nm to 120 nm and an aspect ratio in the range of 10 to 300.
The cosmetic according to any one of claims 1 to 3, wherein an average thickness (μ) and standard deviation (σ) of the mica flakes satisfy σ / μ ≦ 0.5.
The cosmetic according to any one of claims 1 to 3, wherein an average thickness (μ) and standard deviation (σ) of the mica flakes satisfy σ / μ ≦ 0.3.
The cosmetic according to any one of claims 1 to 5, wherein an average thickness of the coating layer is in a range of 25 nm to 90 nm.
The cosmetic according to any one of claims 1 to 6, wherein an average thickness of the composite powder is in the range of 100 nm to 300 nm.
The composite powder is
The mica flakes having an average thickness of 70 nm to 120 nm and an aspect ratio of 10 to 300, and an average thickness (μ) and standard deviation (σ) of σ / μ ≦ 0.3;
The coating layer having an average thickness of 40 nm to 60 nm;
The cosmetic according to claim 1, wherein the composite powder has a total average thickness of 150 nm to 240 nm.
The cosmetic according to any one of claims 1 to 8, wherein the mica flake has an average particle diameter of 1 to 20 µm.
The cosmetic according to any one of claims 1 to 9, wherein the mica flakes are synthetic mica flakes.
The cosmetic according to any one of claims 1 to 10, wherein the coating layer contains, as a main component, at least one metal oxide selected from the group consisting of titanium oxide, tin oxide, zinc oxide, and zirconium oxide. .
The cosmetic according to any one of claims 1 to 11, which is a foundation, a makeup base or a face powder.