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WO2011013292A1 - Web stretching method and method for producing retardation film - Google Patents

Web stretching method and method for producing retardation film Download PDF

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Publication number
WO2011013292A1
WO2011013292A1 PCT/JP2010/004022 JP2010004022W WO2011013292A1 WO 2011013292 A1 WO2011013292 A1 WO 2011013292A1 JP 2010004022 W JP2010004022 W JP 2010004022W WO 2011013292 A1 WO2011013292 A1 WO 2011013292A1
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WO
WIPO (PCT)
Prior art keywords
web
fluid
heating chamber
stretching method
conveyance
Prior art date
Application number
PCT/JP2010/004022
Other languages
French (fr)
Japanese (ja)
Inventor
福井剛
稲澤弘志
大田一英
久保賢司
中村琢司
藤井正
Original Assignee
東洋鋼鈑株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 東洋鋼鈑株式会社 filed Critical 東洋鋼鈑株式会社
Priority to KR1020117026494A priority Critical patent/KR101765138B1/en
Priority to CN201080031418.9A priority patent/CN102625746B/en
Priority to JP2011524626A priority patent/JP5530443B2/en
Publication of WO2011013292A1 publication Critical patent/WO2011013292A1/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C55/00Shaping by stretching, e.g. drawing through a die; Apparatus therefor
    • B29C55/02Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets
    • B29C55/04Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets uniaxial, e.g. oblique
    • B29C55/06Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets uniaxial, e.g. oblique parallel with the direction of feed
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/30Polarising elements
    • G02B5/3083Birefringent or phase retarding elements
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2995/00Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0018Properties of moulding materials, reinforcements, fillers, preformed parts or moulds having particular optical properties, e.g. fluorescent or phosphorescent
    • B29K2995/0034Polarising

Definitions

  • the present invention relates to a method for stretching a web film-like object (hereinafter referred to as a web) such as a thermoplastic resin film, and relates to a method for producing a retardation film suitable for a liquid crystal display device based on the web stretching method.
  • a web film-like object hereinafter referred to as a thermoplastic resin film
  • a retardation film made of a thermoplastic resin film is used.
  • This retardation film usually develops in-plane retardation (Re) and thickness direction retardation (Rth) by stretching in the longitudinal (longitudinal) direction and transverse (width) direction.
  • Re in-plane retardation
  • Th thickness direction retardation
  • the viewing angle of the liquid crystal display device is increased.
  • Longitudinal stretching method in which a heating chamber is installed between conveyance guides (nip rolls) having different peripheral speeds as described in Patent Document 1, as stretching in the longitudinal direction when stretching a retardation film Is widely known.
  • the method of transporting the retardation film it is usually transported into a heating chamber through a transport guide, and is transported through a transport guide that is also installed in this heating chamber as appropriate. At this time, it is necessary to adjust the film width at the time of stretching the film, and to prevent variation in the peeling point due to the adhesion of the film to the conveyance guide (pass roll) provided in the heating chamber between the conveyance guides. As described above, a method is also known in which air is ejected from a conveyance guide to facilitate separation from the conveyance guide.
  • Patent Document 1 requires a long heating chamber in the moving direction of the film, and it may be difficult to provide equipment. Also, in actual production, the resin becomes longer in the moving direction of the film, so that the resin is bent due to its own weight, and it is difficult to stretch with high accuracy.
  • the web stretching method of the present invention moves the web through the transport guide while heating the web at a temperature capable of stretching in a heating chamber having at least one transport guide.
  • a web stretching method in which the fluid is ejected from a fluid ejection hole formed on a surface of the transport guide to form a fluid layer on the surface of the transport guide, and the web is heated in the heating chamber. By moving on the fluid layer, the moving direction of the web is changed without the web coming into contact with the conveyance guide.
  • a plurality of fluid discharge holes are formed on the surface of the transport guide, and an introduction flow path leading to the fluid discharge hole is formed inside the transport guide.
  • the fluid layer is formed by the fluid discharged from the plurality of fluid discharge holes.
  • a plurality of the fluid discharge holes are provided in a direction perpendicular to the moving direction of the web and the moving direction.
  • the two fluid ejection holes are arranged so that a virtual line connecting two fluid ejection holes adjacent in a direction intersects the moving direction.
  • a plurality of the conveyance guides are arranged in a heating chamber, and the web is located on a vertical upper side of the plurality of conveyance guides.
  • the discharge amount of the fluid discharged from the transport guide passing therethrough is larger than the discharge amount of the fluid discharged from the transport guide passing through the vertical lower side of the web.
  • the web stretching method of the present invention is characterized in that, in any one of the above (1) to (4), the stretchable temperature is a temperature equal to or higher than the glass transition point of the web.
  • the temperature of the fluid discharged from the fluid discharge hole is the same as that in the heating chamber. .
  • the method for producing a retardation film of the present invention is characterized in that the retardation film is stretched using the web stretching method described in any of (1) to (6) above.
  • the present invention it is possible to shorten the length of the moving direction of the web in the heating chamber as compared with the case where the web is not changed in direction in the heating chamber, and the web to be stretched is not separated from the conveyance guide in the heating chamber. It can be conveyed in contact. Thereby, it is possible to realize uniform stretching of the web without causing problems such as variations in the film tension in the width direction of the web, generation of wrinkles and rubbing.
  • FIG. 3 is a perspective view of a conveyance guide according to Embodiment 1.
  • FIG. 3 is a schematic diagram illustrating a cross section of a conveyance guide according to Embodiment 1.
  • FIG. It is an expanded view which shows arrangement
  • It is explanatory drawing which shows the structure of the heating chamber regarding Example 2, and a web conveyance mechanism.
  • At least one conveyance guide is disposed in the heating chamber, and the inlet side roll and the outlet side roll provided at each of the inlet and outlet of the heating chamber are driven.
  • the web is conveyed to the heating chamber.
  • the web moves through the conveyance guide while being heated at a temperature equal to or higher than the glass transition point of the web.
  • fluid is discharged from the fluid discharge holes formed on the surface of the transport guide to form a fluid layer on the surface of the transport guide.
  • the web moves on the fluid layer to change the moving direction of the web without contacting the web with the conveyance guide.
  • the web is preferably a thermoplastic resin film that exhibits birefringence when stretched.
  • a thermoplastic resin film that exhibits birefringence when stretched.
  • a cellulose resin a vinyl chloride resin, a polycarbonate resin, an acrylonitrile resin, an olefin resin, or a polymethyl methacrylate resin.
  • polysulfone resins polyarylate resins, polyether sulfone resins, polynorbornene resins, and the like.
  • the heating chamber is provided with a heating space, which includes a heating furnace in which a gas whose temperature is adjusted is circulated, and a heating tank in which a liquid is circulated.
  • a heating space which includes a heating furnace in which a gas whose temperature is adjusted is circulated, and a heating tank in which a liquid is circulated.
  • An inlet and an outlet are formed in the heating chamber, and the web is conveyed from the inlet to the heating chamber, heated at a predetermined temperature, and then discharged from the outlet.
  • the size of the heating chamber is not particularly limited because it is appropriately set depending on the shape and size of the web being conveyed.
  • the entrance side roll and the exit side roll are preferably made of metal, but not limited to metal, if the roll has heat resistance to the temperature of the heating chamber, other known members such as reinforced plastic can be used. Also good.
  • the shape and diameter of the roll are not limited to the cylindrical shape but may be other shapes such as an elliptical shape as long as the web conveyance is not hindered, and the diameter can be set as appropriate.
  • the conveyance guide has a long columnar shape, and the upper surface thereof is provided with a so-called bowl-shaped cylindrical curved surface web floating surface, and a plurality of fluid discharge holes provided in a predetermined arrangement on the web floating surface.
  • the web can be lifted and conveyed by discharging a fluid such as a compressed air or a processing gas or a liquid such as an aqueous solution, a processing liquid, or water.
  • a fluid such as a compressed air or a processing gas or a liquid such as an aqueous solution, a processing liquid, or water.
  • the shape of the web floating surface of the conveyance guide is a drum shape (convex shape) with a raised central portion, in addition to a straight cylindrical shape, depending on the shape of the end face when the plate-like members are combined radially.
  • drum shape concave shape
  • a plurality of conveyance guides may be arranged according to the conveyance distance of the web.
  • a plurality of fluid ejection holes are formed on the surface of the transport guide, and an introduction flow path for fluid ejected from the fluid ejection holes is provided therein. Since fluid is discharged from the fluid discharge hole and a fluid layer is formed on the surface of the conveyance guide, the web does not directly contact the conveyance guide, suppressing variations in tension, generation of wrinkles and scuffs, The web can be stretched uniformly.
  • a plurality of fluid discharge holes formed on the surface of the conveyance guide are provided in the direction of movement of the web and the direction orthogonal to the direction. The shape of the fluid discharge hole is a quadrangle, but may be other polygons or circles.
  • the arrangement of the plurality of fluid ejection holes formed on the surface of the transport guide is not particularly limited.
  • an imaginary line connecting two adjacent fluid discharge holes in the moving direction of the web is arranged at a position shifted so as to intersect the moving direction at an angle of, for example, 5 to 30 degrees. Also good.
  • the positional relationship between the holes adjacent to the moving direction of the web may be shifted by a predetermined interval with respect to the orthogonal direction.
  • fluid is discharged at a predetermined pressure to form a fluid layer.
  • the discharged fluid is preferably discharged after being heated to a temperature equal to or higher than the glass transition point of the web. That is, in order to stretch the web, it is necessary to heat the fluid layer to a temperature equal to or higher than the glass transition point.
  • the kind of fluid discharged from the fluid discharge hole is not limited, fluids such as gas such as compressed air and processing gas, and liquid such as aqueous solution, processing liquid, and water are exemplified.
  • the thickness of the fluid layer formed on the conveyance guide (approximately equal to the flying height of the web) can be set as appropriate as long as the web does not contact the conveyance guide. For example, the thickness is set within 2 mm as a guide. .
  • the amount of fluid discharged from the conveyance guide in which the web passes vertically above among the plurality of conveyance guides is such that the web passes vertically below. It is desirable that the discharge amount of the fluid discharged from the transport guide is larger.
  • the web passes through the vertical upper side, it is more likely to come into contact with the conveyance guide as compared with passing through the vertical lower side due to the influence of gravity. Therefore, by making the fluid layer of the conveyance guide through which the web passes at least vertically above relatively thick, the web can be prevented from coming into contact with the conveyance guide.
  • the web stretching method described above is particularly suitable for the production of a retardation film. That is, a uniform retardation film free from variations in film tension and wrinkles can be produced by applying the web stretching method described above to stretch the retardation film.
  • FIG. 1 is an explanatory view showing a structure of a heating chamber and a web levitation conveyance device related to Example 1
  • FIG. 2A is a perspective view of a conveyance guide according to Example 1
  • FIG. 3 is a developed view showing the arrangement of fluid discharge holes formed on the surface of the conveyance guide
  • FIG. 4 is a structure of a heating chamber and web floating conveyance relating to Example 2
  • FIG. 5 is an explanatory view showing a structure of a heating chamber and a web levitation conveyance apparatus according to the third embodiment.
  • the apparatus shown in FIG. 1 is a so-called longitudinal uniaxial stretching apparatus, and performs a stretching process along the moving direction of the web (lateral direction in FIG. 1).
  • an inlet side roll 4 and an outlet side roll 5 are arranged on the inlet 22 and outlet 23 sides of the heating chamber 2, respectively.
  • the temperature in the heating chamber 2 is set to be not lower than the glass transition temperature of the web 8 and not higher than the melting temperature.
  • the web 8 unwound from the unwinding roll P is introduced into the heating chamber 2 from the inlet 22 through the inlet-side roll 4, and three conveyance guides 1 a arranged on a straight line connecting the inlet 22 and the outlet 23.
  • a plurality of fluid discharge holes 9 are formed in at least a part of the surface of the conveyance guide 1 having the roll diameter 6 and the roll width 7 that faces the web 8. .
  • the inside of the conveyance guide 1 has a hollow shape 101, and the heated air sent from the blower 3 passes through the hollow shape 101 and is discharged from the fluid discharge hole 9.
  • a fluid layer 11 is formed near the surface of the transport guide 1 by the pressurized heated air discharged from the plurality of fluid discharge holes 9. Then, the web 8 is levitated and conveyed through the fluid layer 11.
  • the conveyance guide 1 is not what rotates itself, but is arrange
  • the some conveyance guide 1 is arrange
  • the fluid discharged from the fluid discharge holes 9 on the surfaces of the transport guides 1a and 1c may have a higher discharge pressure than the fluid discharged to the upper side of the transport guide 1b due to gravity. Accordingly, the discharge pressure of the fluid discharged to the upper side of the transfer guide 1b is set higher than the discharge pressure of the fluid discharged from the fluid discharge hole 9 on the surfaces of the transfer guides 1a and 1c, thereby the transfer guides 1a and 1b. It is possible to form the fluid layer 11 having the same thickness and the same amount of fluid on 1c.
  • a plurality of fluid discharge holes 9 formed in the axial direction of the conveyance guide 1 form a fluid discharge hole array 19a, and adjacent fluids
  • the arrangement of the fluid ejection holes in the ejection hole array is not arranged on the same straight line in the circumferential direction (movement direction 10) of the transport guide 1. That is, the fluid discharge holes 9 are arranged in the orthogonal direction 13 at intervals of a fluid discharge hole distance 9a, and the fluid discharge hole rows are arranged at intervals of a fluid discharge hole distance 9b.
  • the imaginary line 14 connecting two adjacent fluid ejection holes in the movement direction 10 has the fluid ejection holes 9 arranged in an oblique direction so as to intersect the movement direction 10. More specifically, as shown in FIG. 3, the fluid discharge holes 9 d and 9 e adjacent to each other with respect to the moving direction 10 are arranged so as to be shifted from each other with respect to the orthogonal direction 13 by a shift width 9 c. By arranging in this way, the fluid discharged from the fluid discharge holes 9 is uniform with respect to the web 8, and the thickness and the amount of fluid of the formed fluid layer 11 are adjusted to be uniform. Then, it is conveyed along the moving direction 10.
  • Example 1 Example 1 is shown below.
  • Web material Polynorbornene resin film (glass transition temperature Tg: 120 ° C.)
  • Web size size: thickness 150 ⁇ m, width 250 mm Stretch ratio: 2.0 times ⁇ Structure and conditions in heating chamber >> Heating space temperature: 140 ° C.
  • the stretching section (length in the moving direction of the web) between the inlet side roll 4 and the outlet side roll 5 is 800 mm, the peripheral speed of the inlet side roll 4 is 1.0 m / min, and the peripheral speed of the outlet side roll 5 is 2 0.0 m / min.
  • the fluid layer 11 is formed by a substantially static pressure air layer by heated air in the heating chamber set at 140 ° C. by the three conveyance guides 1a, 1b, 1c, and the surface of the fluid layer 11 is the web 8 Functioned as a transfer surface. Note that heated air set at 140 ° C. was discharged as the fluid.
  • the average value of the retardation was 140 nm and the retardation value between two points 10 mm apart. It was found that the variation was 10% at the maximum and the difference between the maximum value and the minimum value for the orientation angle was 1.0 °, and the web was uniformly stretched throughout. Also, no wrinkles or scuffs on the web surface were observed.
  • FIG. 4 shows a longitudinal uniaxial stretching apparatus according to Example 2 to which the present invention is applied.
  • the three conveyance guides 1 arranged in the heating chamber are arranged in the heating chamber 2 with a difference in height, and the stretching section (the length in the moving direction of the web) is set to 1200 mm. There is a difference from the first embodiment.
  • a retardation film was produced in the same manner as in Example 1 except for the points described above.
  • FIG. 5 shows a longitudinal uniaxial stretching apparatus according to Example 3 to which the present invention is applied.
  • the third embodiment is different from the first and second embodiments in that the number of conveyance guides 1 arranged in the heating chamber is one.
  • the conveyance guide 1 is positioned above the heating space 21 of the heating chamber 2, and the web 8 passes through the conveyance guide 1.
  • the blower 3 controls heated air discharged from the fluid discharge holes 9 formed on the surface of the single conveyance guide 1. In addition, it carried out similarly to Example 1 or Example 2 except the above-mentioned point, and manufactured the phase difference film.
  • the heating chamber can be reduced in size and the cost can be reduced as compared with the case where the web is not turned in the heating chamber.
  • problems such as variations in film tension in the width direction, generation of wrinkles and rubbing are not caused. This makes it possible to uniformly stretch the web while suppressing the manufacturing cost, and has an extremely advantageous effect when manufacturing the retardation film.
  • a present Example is not limited to what was mentioned above, Unless it deviates from the meaning of this invention, it can change suitably in view of technical common sense.
  • the fluid discharge hole 9 is formed on the upper surface side of the conveyance guide 1 arranged in the center.
  • the transport guide 1 may have a fluid discharge hole 9 on the upper surface side.
  • the fluid discharge holes 9 formed on the surface of the transport guide 1 are alternately formed on the upper surface side and the lower surface side, but the fluid discharge holes 9 are formed on the same side for the three transport guides 1. It may be.
  • the fluid discharge holes 9 are formed on the lower side of the three conveyance guides 1, the web is conveyed on the lower side of the conveyance guide 1b in FIG. That is, the web passes under the conveyance guides 1a, 1b, and 1c.
  • the peripheral speed of the inlet-side roll 4 and the peripheral speed of the outlet-side roll 5 can be appropriately set according to the draw ratio, the material of the web, and the like.
  • the number of the conveyance guides 1 arranged in the heating space 21 is not limited to one or three, and the arrangement position and the number can be appropriately set as long as the space of the heating space 21 is effectively used.
  • the present invention is suitable for a stretching method and a stretching apparatus for stretching a web, and can also be applied to a manufacturing method and a manufacturing apparatus for manufacturing a retardation film using the web. Extremely high.

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  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
  • Polarising Elements (AREA)

Abstract

Provided are a web stretching method and a method for producing a retardation film, by which a length in the film moving direction can be shortened in a heating chamber, and variability of the film tension in the width direction as well as scratches, etc., can be prevented. When a web (8) is transferred into a heating chamber (2) and is stretched, by pinch rolls arranged at an entrance side and an exit side of a heating chamber (2), at least one transfer guide (1) is arranged in a heating space (21). Further, heated fluid is discharged from a plurality of fluid discharge holes (9) formed on a surface of the transfer guide (1) to form a fluid layer (11), and the web (8) can be moved without being in contact with the transfer guide (1) using the fluid layer (11) as a transfer surface. Thereby, a film can be uniformly stretched while suppressing the production cost.

Description

ウェブ延伸方法及び位相差フィルムの製造方法Web stretching method and retardation film manufacturing method
 本発明は、熱可塑性樹脂フィルムなどのウェブフィルム状の物体(以下ウェブと称する)の延伸方法に係り、このウェブ延伸方法に基づいた液晶表示装置に好適な位相差フィルムの製造方法に関する。 The present invention relates to a method for stretching a web film-like object (hereinafter referred to as a web) such as a thermoplastic resin film, and relates to a method for producing a retardation film suitable for a liquid crystal display device based on the web stretching method.
 液晶表示装置等の光学機器では、熱可塑性樹脂フィルムからなる位相差フィルムが用いられている。この位相差フィルムは、通常、縦(長手)方向、横(幅)方向に延伸することによって、面内レターデーション(Re)、厚み方向のレターデーション(Rth)を発現させ、このレターデーションの発現によって液晶表示装置の視野角拡大を図ることが実施されている。
 位相差フィルムを延伸する際における縦方向の延伸としては、特許文献1に記載されているように、周速度の異なる搬送ガイド(ニップロール)の間に加熱室を設置した長スパン型の縦延伸方法が広く知られている。
In an optical apparatus such as a liquid crystal display device, a retardation film made of a thermoplastic resin film is used. This retardation film usually develops in-plane retardation (Re) and thickness direction retardation (Rth) by stretching in the longitudinal (longitudinal) direction and transverse (width) direction. Thus, the viewing angle of the liquid crystal display device is increased.
Longitudinal stretching method in which a heating chamber is installed between conveyance guides (nip rolls) having different peripheral speeds as described in Patent Document 1, as stretching in the longitudinal direction when stretching a retardation film Is widely known.
 一方、位相差フィルムの搬送方法に関しては、通常は搬送ガイドを介して加熱室内に搬送され、この加熱室内でも適宜設置される搬送ガイドを介して搬送される。このときフィルム延伸時のフィルム幅を調整し、搬送ガイド間の加熱室内に設けられる搬送ガイド(パスロール)へのフィルムの密着による剥離点のばらつきを防ぐことが必要になるが、例えば特許文献2のように、搬送ガイドから空気を噴出して当該搬送ガイドからの剥離を容易にする方法も知られている。 On the other hand, regarding the method of transporting the retardation film, it is usually transported into a heating chamber through a transport guide, and is transported through a transport guide that is also installed in this heating chamber as appropriate. At this time, it is necessary to adjust the film width at the time of stretching the film, and to prevent variation in the peeling point due to the adhesion of the film to the conveyance guide (pass roll) provided in the heating chamber between the conveyance guides. As described above, a method is also known in which air is ejected from a conveyance guide to facilitate separation from the conveyance guide.
特開2008-221722号公報JP 2008-221722 A 特開平9-76343号公報JP-A-9-76343
 しかしながら上記従来の技術では以下に示す課題があった。
 すなわち上記特許文献1に記載の技術では、フィルムの移動方向に向けて長い加熱室が必要となり、設備を設けることが困難な場合がある。また、実際の製造においても、フィルムの移動方向に樹脂が長くなる分、樹脂の自重により撓みが生じてしまい精度の良い延伸が困難となる。
However, the above conventional techniques have the following problems.
That is, the technique described in Patent Document 1 requires a long heating chamber in the moving direction of the film, and it may be difficult to provide equipment. Also, in actual production, the resin becomes longer in the moving direction of the film, so that the resin is bent due to its own weight, and it is difficult to stretch with high accuracy.
 このような問題点に対しては、例えば上記特許文献2に記載の技術を用いて加熱室内で搬送ガイドによりフィルムの方向を変えることで、加熱室内におけるフィルムの移動方向に対する長さを短くし、これにより樹脂の撓みを防止することも考えられる。 For such a problem, for example, by changing the direction of the film by the conveyance guide in the heating chamber using the technique described in Patent Document 2, the length with respect to the moving direction of the film in the heating chamber is shortened, It is also conceivable to prevent the resin from bending.
 しかしながら上記特許文献2に記載の技術では、あくまでも樹脂は搬送ガイド等に接して搬送されるため、たとえ空気の吐出によりフィルムの剥離が容易になったとしても樹脂の表面にシワや擦り疵が発生する場合がある。そのため、幅方向でのフィルム張力のばらつき、シワや擦り疵の発生など種々の問題が生じてしまう。
 本発明はこのような課題を解決するものであり、加熱室内においてフィルムの移動方向における長さを短くしつつ、且つ、幅方向でのフィルム張力のばらつきや擦り疵等のないウェブ延伸方法および位相差フィルムの製造方法を提供することを目的とする。
However, in the technique described in Patent Document 2, since the resin is transported in contact with a transport guide or the like, wrinkles or scuffs are generated on the surface of the resin even if the film is easily peeled off by air discharge. There is a case. For this reason, various problems such as variations in film tension in the width direction, generation of wrinkles and scuffs, and the like occur.
The present invention solves such problems, and reduces the length in the moving direction of the film in the heating chamber, and does not cause variations in the film tension or scratches in the width direction. It aims at providing the manufacturing method of a phase difference film.
(1)上記課題を解決するため、本発明のウェブ延伸方法は、少なくとも一つの搬送ガイドを有する加熱室内において、ウェブを延伸可能な温度で加熱しながら前記搬送ガイドを介して移動させ、前記ウェブの移動方向に延伸するウェブ延伸方法であって、前記搬送ガイドの表面に形成された流体吐出孔から流体を吐出して前記搬送ガイドの表面に流体層を形成し、前記加熱室内にて前記ウェブが前記流体層上を移動することによって前記搬送ガイドに前記ウェブが接触することなく前記ウェブの移動方向を変化させることを特徴とする。 (1) In order to solve the above-described problem, the web stretching method of the present invention moves the web through the transport guide while heating the web at a temperature capable of stretching in a heating chamber having at least one transport guide. A web stretching method in which the fluid is ejected from a fluid ejection hole formed on a surface of the transport guide to form a fluid layer on the surface of the transport guide, and the web is heated in the heating chamber. By moving on the fluid layer, the moving direction of the web is changed without the web coming into contact with the conveyance guide.
(2)本発明のウェブ延伸方法は、上記(1)において、前記搬送ガイドの表面に複数の流体吐出孔が形成され、前記搬送ガイドの内部に前記流体吐出孔に通ずる導入流路が形成され、前記複数の流体吐出孔から吐出される前記流体によって前記流体層を形成することを特徴とする。 (2) In the web stretching method of the present invention, in the above (1), a plurality of fluid discharge holes are formed on the surface of the transport guide, and an introduction flow path leading to the fluid discharge hole is formed inside the transport guide. The fluid layer is formed by the fluid discharged from the plurality of fluid discharge holes.
(3)本発明のウェブ延伸方法は、上記(1)又は(2)において、前記流体吐出孔は前記ウェブの移動方向と該方向に直交する直交方向に向けて複数設けられており、前記移動方向において隣り合う2つの前記流体吐出孔が結ぶ仮想線が前記移動方向と交わるように、前記2つの流体吐出孔が配置されていることを特徴とする。 (3) In the web stretching method of the present invention, in the above (1) or (2), a plurality of the fluid discharge holes are provided in a direction perpendicular to the moving direction of the web and the moving direction. The two fluid ejection holes are arranged so that a virtual line connecting two fluid ejection holes adjacent in a direction intersects the moving direction.
(4)本発明のウェブ延伸方法は、上記(1)乃至(3)のいずれかにおいて、前記搬送ガイドは加熱室内において複数配置され、前記複数の搬送ガイドのうち、前記ウェブがその鉛直上側を通過する搬送ガイドから吐出される前記流体の吐出量は、前記ウェブがその鉛直下側を通過する搬送ガイドから吐出される前記流体の吐出量よりも多いことを特徴とする。 (4) In the web stretching method of the present invention, in any one of the above (1) to (3), a plurality of the conveyance guides are arranged in a heating chamber, and the web is located on a vertical upper side of the plurality of conveyance guides. The discharge amount of the fluid discharged from the transport guide passing therethrough is larger than the discharge amount of the fluid discharged from the transport guide passing through the vertical lower side of the web.
(5)本発明のウェブ延伸方法は、上記(1)乃至(4)のいずれかにおいて、前記延伸可能な温度が、前記ウェブのガラス転移点以上の温度であることを特徴とする。 (5) The web stretching method of the present invention is characterized in that, in any one of the above (1) to (4), the stretchable temperature is a temperature equal to or higher than the glass transition point of the web.
(6)本発明のウェブ延伸方法は、上記(1)乃至(5)のいずれかにおいて、前記流体吐出孔から吐出される流体の温度が、前記加熱室内と同じ温度であることを特徴とする。 (6) In the web stretching method of the present invention, in any one of the above (1) to (5), the temperature of the fluid discharged from the fluid discharge hole is the same as that in the heating chamber. .
(7)本発明の位相差フィルムの製造方法は、上記(1)乃至(6)のいずれかに記載のウェブ延伸方法を利用して位相差フィルムを延伸することを特徴とする。 (7) The method for producing a retardation film of the present invention is characterized in that the retardation film is stretched using the web stretching method described in any of (1) to (6) above.
 本発明によれば、加熱室内でウェブを方向転換させない場合と比べて、加熱室におけるウェブの移動方向の長さを短くすることが可能となり、且つ、延伸するウェブは加熱室内では搬送ガイドから非接触の状態で搬送することができる。これによりウェブの幅方向でのフィルム張力のばらつき、シワや擦り疵の発生などの問題を生じることがなく、均一にウェブを延伸することが実現できる。 According to the present invention, it is possible to shorten the length of the moving direction of the web in the heating chamber as compared with the case where the web is not changed in direction in the heating chamber, and the web to be stretched is not separated from the conveyance guide in the heating chamber. It can be conveyed in contact. Thereby, it is possible to realize uniform stretching of the web without causing problems such as variations in the film tension in the width direction of the web, generation of wrinkles and rubbing.
実施例1に関する加熱室の構造およびウェブ搬送機構を示す説明図である。It is explanatory drawing which shows the structure of the heating chamber regarding Example 1, and a web conveyance mechanism. 実施例1に係る搬送ガイドの斜視図である。3 is a perspective view of a conveyance guide according to Embodiment 1. FIG. 実施例1に係る搬送ガイドの断面を示す模式図である。3 is a schematic diagram illustrating a cross section of a conveyance guide according to Embodiment 1. FIG. 搬送ガイドの表面に形成される流体吐出孔の配置を示す展開図である。It is an expanded view which shows arrangement | positioning of the fluid discharge hole formed in the surface of a conveyance guide. 実施例2に関する加熱室の構造およびウェブ搬送機構を示す説明図である。It is explanatory drawing which shows the structure of the heating chamber regarding Example 2, and a web conveyance mechanism. 実施例3に関する加熱室の構造およびウェブ搬送機構を示す説明図である。It is explanatory drawing which shows the structure of the heating chamber regarding Example 3, and a web conveyance mechanism.
 本発明の好適な実施形態では、ウェブを延伸する際に、少なくとも一つの搬送ガイドを加熱室内に配置し、加熱室の入口および出口の各々に設けられた入口側ロールと出口側ロールの駆動によってウェブは加熱室へ搬送される。加熱室内では、ウェブは当該ウェブのガラス転移点以上の温度で加熱されながら搬送ガイドを介して移動する。この際、搬送ガイドの表面に形成された流体吐出孔から流体を吐出して搬送ガイドの表面に流体層を形成する。少なくとも加熱室内においてウェブはこの流体層上を移動することにより、搬送ガイドにウェブが接触することなくウェブの移動方向を変化させる。 In a preferred embodiment of the present invention, when the web is stretched, at least one conveyance guide is disposed in the heating chamber, and the inlet side roll and the outlet side roll provided at each of the inlet and outlet of the heating chamber are driven. The web is conveyed to the heating chamber. In the heating chamber, the web moves through the conveyance guide while being heated at a temperature equal to or higher than the glass transition point of the web. At this time, fluid is discharged from the fluid discharge holes formed on the surface of the transport guide to form a fluid layer on the surface of the transport guide. At least in the heating chamber, the web moves on the fluid layer to change the moving direction of the web without contacting the web with the conveyance guide.
 ウェブは、延伸処理することによって複屈折性を示す熱可塑性樹脂フィルムが好適であり、例えばセルロース系樹脂、塩化ビニル系樹脂、ポリカーボネート系樹脂、アクリロニトリル系樹脂、オレフィン系樹脂、ポリメタクリル酸メチル系樹脂、ポリサルホン系樹脂、ポリアリレート系樹脂、ポリエーテルサルホン系樹脂、ポリノルボルネン系樹脂等が挙げられる。 The web is preferably a thermoplastic resin film that exhibits birefringence when stretched. For example, a cellulose resin, a vinyl chloride resin, a polycarbonate resin, an acrylonitrile resin, an olefin resin, or a polymethyl methacrylate resin. And polysulfone resins, polyarylate resins, polyether sulfone resins, polynorbornene resins, and the like.
 加熱室は加熱空間を備えており、この加熱空間は加熱温調された気体を循環させた加熱炉、液体を循環させた加熱タンクなどがある。また、加熱室には入口と出口が形成され、この入口からウェブが加熱室へ搬送され、所定の温度で熱された後に出口から排出される。加熱室の大きさは、搬送されるウェブの形状や大きさにより適宜設定されるので特に限定はされない。 The heating chamber is provided with a heating space, which includes a heating furnace in which a gas whose temperature is adjusted is circulated, and a heating tank in which a liquid is circulated. An inlet and an outlet are formed in the heating chamber, and the web is conveyed from the inlet to the heating chamber, heated at a predetermined temperature, and then discharged from the outlet. The size of the heating chamber is not particularly limited because it is appropriately set depending on the shape and size of the web being conveyed.
 ウェブの搬送に際しては、入口側ロールと出口側ロールとの周速差によりウェブを搬送して延伸を行う。すなわち、入口側ロールよりも出口側ロールの周速を速めることにより、ウェブが出口側ロールに向けた移動方向に引っ張られた状態となり、ウェブの延伸が可能となる。
 入口側ロールと出口側ロールは金属製のものが好ましく使用されるが、金属に限らず加熱室の温度に対して耐熱性を有していれば、強化プラスチックなど他の公知の部材を用いてもよい。ロールの形状や径も、ウェブの搬送に支障がでない範囲であれば、円筒状に限らず楕円形状など他の形状としてもよいし、その径も適宜設定可能である。
When the web is transported, the web is transported and stretched by the difference in peripheral speed between the inlet side roll and the outlet side roll. That is, by increasing the peripheral speed of the outlet side roll rather than the inlet side roll, the web is pulled in the moving direction toward the outlet side roll, and the web can be stretched.
The entrance side roll and the exit side roll are preferably made of metal, but not limited to metal, if the roll has heat resistance to the temperature of the heating chamber, other known members such as reinforced plastic can be used. Also good. The shape and diameter of the roll are not limited to the cylindrical shape but may be other shapes such as an elliptical shape as long as the web conveyance is not hindered, and the diameter can be set as appropriate.
 搬送ガイドは、長尺円柱状の形状を有してその上面がいわゆる蒲鉾型の円筒曲面状のウェブ浮上面を備えており、そのウェブ浮上面に所定配置で設けられた多数の流体吐出孔から圧縮空気や処理ガスなどの気体や、水溶液や処理液、水などの液体からなる流体を吐出して、ウェブを浮上させて搬送することができる。
 また、搬送ガイドのウェブ浮上面の形状は、板状部材を放射状に組み合わせたときの端面の形状により、ストレートの円筒型とする場合の他、中央部が盛り上がった太鼓型(凸状)とする場合、逆に中央部がへこんで両端が盛り上がった鼓型(凹状)とする場合、など種々の形状が考えられる。太鼓型や鼓型にすると搬送中におけるウェブの皺取り効果が期待できる。
 なお搬送ガイドはウェブの搬送距離に応じて複数配置してもよい。
The conveyance guide has a long columnar shape, and the upper surface thereof is provided with a so-called bowl-shaped cylindrical curved surface web floating surface, and a plurality of fluid discharge holes provided in a predetermined arrangement on the web floating surface. The web can be lifted and conveyed by discharging a fluid such as a compressed air or a processing gas or a liquid such as an aqueous solution, a processing liquid, or water.
In addition, the shape of the web floating surface of the conveyance guide is a drum shape (convex shape) with a raised central portion, in addition to a straight cylindrical shape, depending on the shape of the end face when the plate-like members are combined radially. In this case, conversely, various shapes such as a drum shape (concave shape) in which the central portion is dented and both ends are raised are conceivable. If the drum type or the drum type is used, a web scooping effect during conveyance can be expected.
A plurality of conveyance guides may be arranged according to the conveyance distance of the web.
 本発明においては、前記搬送ガイドの表面には複数の流体吐出孔が形成されるとともに、その内部には流体吐出孔から吐出される流体の導入流路を有している。この流体吐出孔より流体が吐出されて搬送ガイドの表面に流体層が形成されるので、ウェブは搬送ガイドに直接接触することがなく、張力のばらつき、シワや擦り疵の発生などを抑制し、均一にウェブを延伸することが可能となる。
 搬送ガイドの表面に形成される流体吐出孔は、ウェブの移動方向と該方向に直行する方向に向けて複数設けられる。流体吐出孔の形状は四角形であるが、他の多角形や円等でもよい。
In the present invention, a plurality of fluid ejection holes are formed on the surface of the transport guide, and an introduction flow path for fluid ejected from the fluid ejection holes is provided therein. Since fluid is discharged from the fluid discharge hole and a fluid layer is formed on the surface of the conveyance guide, the web does not directly contact the conveyance guide, suppressing variations in tension, generation of wrinkles and scuffs, The web can be stretched uniformly.
A plurality of fluid discharge holes formed on the surface of the conveyance guide are provided in the direction of movement of the web and the direction orthogonal to the direction. The shape of the fluid discharge hole is a quadrangle, but may be other polygons or circles.
 搬送ガイドの表面に形成される複数の流体吐出孔の配置は特に制限はない。
 例えば、ウェブの移動方向、および/又は該移動方向に直交する直交方向に沿って整列した配置とすることや、直交からずれた配置とすることも可能である。
 直交からずれた配置としては、例えばウェブの移動方向において隣り合う2つの流体吐出孔が結ぶ仮想線が、この移動方向と例えば5乃至30度の角度で交わるようにずれた位置に配置されていてもよい。
 言い換えると、ウェブの移動方向に対して隣り合う孔の位置関係を、直交方向に関して互いに所定の間隔だけずらして配置してもよい。
The arrangement of the plurality of fluid ejection holes formed on the surface of the transport guide is not particularly limited.
For example, it is also possible to arrange the webs in a moving direction and / or along an orthogonal direction orthogonal to the moving direction, or to deviate from the orthogonal direction.
For example, an imaginary line connecting two adjacent fluid discharge holes in the moving direction of the web is arranged at a position shifted so as to intersect the moving direction at an angle of, for example, 5 to 30 degrees. Also good.
In other words, the positional relationship between the holes adjacent to the moving direction of the web may be shifted by a predetermined interval with respect to the orthogonal direction.
 搬送ガイドの表面に形成された流体吐出孔から、所定の圧力にて流体が吐出され流体層が形成される。この場合、吐出される流体は、ウェブのガラス転移点以上の温度まで加熱されてから吐出されることが好ましい。すなわち、ウェブを延伸するために、流体層もガラス転移点以上の温度まで加熱しておくことが必要である。
 流体吐出孔より吐出される流体の種類に限定はないが、圧縮空気や処理ガスなどの気体や、水溶液や処理液、水などの液体からなる流体が例示される。
 また、搬送ガイド上に形成される流体層の厚さ(ウェブの浮上量とほぼ等しい)は、ウェブが搬送ガイドに接触しない範囲で適宜設定可能であるが、例えば2mm以内を目安に設定される。
From a fluid discharge hole formed on the surface of the conveyance guide, fluid is discharged at a predetermined pressure to form a fluid layer. In this case, the discharged fluid is preferably discharged after being heated to a temperature equal to or higher than the glass transition point of the web. That is, in order to stretch the web, it is necessary to heat the fluid layer to a temperature equal to or higher than the glass transition point.
Although the kind of fluid discharged from the fluid discharge hole is not limited, fluids such as gas such as compressed air and processing gas, and liquid such as aqueous solution, processing liquid, and water are exemplified.
The thickness of the fluid layer formed on the conveyance guide (approximately equal to the flying height of the web) can be set as appropriate as long as the web does not contact the conveyance guide. For example, the thickness is set within 2 mm as a guide. .
 なお、搬送ガイドが加熱室に複数配置される場合には、複数の搬送ガイドのうち、ウェブが鉛直上側を通過する搬送ガイドから吐出される流体の吐出量は、ウェブが鉛直下側を通過する搬送ガイドから吐出される流体の吐出量よりも多いことが望ましい。鉛直上側をウェブが通過する場合には、重力の影響で鉛直下側を通過するに比してより搬送ガイドに接触しやすい。したがって、少なくとも鉛直上側をウェブが通過する搬送ガイドの流体層を相対的に厚くすることにより、搬送ガイドへウェブが接触することを抑制できる。 When a plurality of conveyance guides are arranged in the heating chamber, the amount of fluid discharged from the conveyance guide in which the web passes vertically above among the plurality of conveyance guides is such that the web passes vertically below. It is desirable that the discharge amount of the fluid discharged from the transport guide is larger. When the web passes through the vertical upper side, it is more likely to come into contact with the conveyance guide as compared with passing through the vertical lower side due to the influence of gravity. Therefore, by making the fluid layer of the conveyance guide through which the web passes at least vertically above relatively thick, the web can be prevented from coming into contact with the conveyance guide.
 本実施の形態では、上述したウェブの延伸方法は、位相差フィルムの製造にとくに好適である。すなわち上記したいずれかに記載のウェブの延伸方法を適用して位相差フィルムを延伸することにより、フィルム張力のばらつきやシワのない均一な位相差フィルムを製造することができる。 In the present embodiment, the web stretching method described above is particularly suitable for the production of a retardation film. That is, a uniform retardation film free from variations in film tension and wrinkles can be produced by applying the web stretching method described above to stretch the retardation film.
 以下、本発明を適用したウェブ延伸方法および位相差フィルムの製造方法に係る実施例について図を参照しながら説明する。本実施例では位相差フィルムを製造するに際し、その材料となるウェブに対して本発明のウェブ延伸方法を利用する態様を説明するものである。 Hereinafter, examples relating to a web stretching method and a retardation film manufacturing method to which the present invention is applied will be described with reference to the drawings. In this example, when a retardation film is produced, an embodiment in which the web stretching method of the present invention is used for a web as a material thereof will be described.
 図1は、実施例1に関する加熱室の構造およびウェブ浮上搬送装置を示す説明図であり、図2(a)は、実施例1に係る搬送ガイドの斜視図であり、図2(b)は搬送ガイドの断面を示す模式図であり、図3は搬送ガイドの表面に形成される流体吐出孔の配置を示す展開図であり、図4は、実施例2に関する加熱室の構造およびウェブ浮上搬送装置を示す説明図であり、図5は実施例3に関する加熱室の構造およびウェブ浮上搬送装置を示す説明図である。 FIG. 1 is an explanatory view showing a structure of a heating chamber and a web levitation conveyance device related to Example 1, FIG. 2A is a perspective view of a conveyance guide according to Example 1, and FIG. FIG. 3 is a developed view showing the arrangement of fluid discharge holes formed on the surface of the conveyance guide, and FIG. 4 is a structure of a heating chamber and web floating conveyance relating to Example 2; FIG. 5 is an explanatory view showing a structure of a heating chamber and a web levitation conveyance apparatus according to the third embodiment.
<実施例1>
 図1に示す装置は、いわゆる縦一軸延伸装置であり、ウェブの移動方向(図1において横方向)に沿って延伸処理をする。
 図1に示すように、加熱室2の入口22および出口23の側それぞれには、入口側ロール4と出口側ロール5が配置されている。加熱室2内の温度は、ウェブ8のガラス転移温度以上、融解温度以下に設定されている。
 巻き戻しロールPより巻き戻されたウェブ8は、入口側ロール4を通って入口22より加熱室2内に導入され、入口22および出口23を結ぶ一直線上に配置された3つの搬送ガイド1a、1b、1cの間を移動して出口23より加熱室2外に排出される。その後、出口側ロール5を通り、巻き取りロールQに巻き取られる。
 入口側ロール4と出口側ロール5は、ウェブ8の移動方向に回転している。出口側ロール5の回転速度は入口側ロール4の回転速度よりも速いため、入口側ロール4と出口側ロール5の間を移動するウェブ8は、ガラス転移温度以上に加熱された状態で移動方向に引っ張られ、延伸する。
 なお、加熱室2の外にはブロワ3が配置され、ブロワ3から送られた加熱空気は移動パイプ31を移動して搬送ガイド1の表面上の流体吐出孔9から吐出する。
<Example 1>
The apparatus shown in FIG. 1 is a so-called longitudinal uniaxial stretching apparatus, and performs a stretching process along the moving direction of the web (lateral direction in FIG. 1).
As shown in FIG. 1, an inlet side roll 4 and an outlet side roll 5 are arranged on the inlet 22 and outlet 23 sides of the heating chamber 2, respectively. The temperature in the heating chamber 2 is set to be not lower than the glass transition temperature of the web 8 and not higher than the melting temperature.
The web 8 unwound from the unwinding roll P is introduced into the heating chamber 2 from the inlet 22 through the inlet-side roll 4, and three conveyance guides 1 a arranged on a straight line connecting the inlet 22 and the outlet 23. It moves between 1 b and 1 c and is discharged out of the heating chamber 2 through the outlet 23. After that, it passes through the outlet side roll 5 and is taken up by the take-up roll Q.
The inlet side roll 4 and the outlet side roll 5 rotate in the moving direction of the web 8. Since the rotational speed of the exit side roll 5 is faster than the rotational speed of the entrance side roll 4, the web 8 moving between the entrance side roll 4 and the exit side roll 5 is moved in the moving direction in a state of being heated to the glass transition temperature or higher. Is pulled and stretched.
A blower 3 is disposed outside the heating chamber 2, and heated air sent from the blower 3 moves through the moving pipe 31 and is discharged from the fluid discharge hole 9 on the surface of the transport guide 1.
 次に、搬送ガイドについて説明する。 図2(a)及び(b)に示すように、ロール径6およびロール幅7を有する搬送ガイド1の表面のうち、少なくともウェブ8と対向する一部分には流体吐出孔9が複数形成されている。
 搬送ガイド1の内部は中空形状101となっており、ブロワ3から送られた加熱空気が中空形状101を通過して流体吐出孔9から吐出される。
 図2(b)に示すように、搬送ガイド1の表面付近には、複数の流体吐出孔9からそれぞれ吐出された加圧加熱空気により流体層11が形成される。そしてこの流体層11を介してウェブ8が浮上搬送される。
 なお、搬送ガイド1は、自身が回転するものではなく、搬送ガイドの一部に形成される固定部材12により加熱空間21内に配置固定されている。
Next, the conveyance guide will be described. As shown in FIGS. 2A and 2B, a plurality of fluid discharge holes 9 are formed in at least a part of the surface of the conveyance guide 1 having the roll diameter 6 and the roll width 7 that faces the web 8. .
The inside of the conveyance guide 1 has a hollow shape 101, and the heated air sent from the blower 3 passes through the hollow shape 101 and is discharged from the fluid discharge hole 9.
As shown in FIG. 2 (b), a fluid layer 11 is formed near the surface of the transport guide 1 by the pressurized heated air discharged from the plurality of fluid discharge holes 9. Then, the web 8 is levitated and conveyed through the fluid layer 11.
In addition, the conveyance guide 1 is not what rotates itself, but is arrange | positioned and fixed in the heating space 21 by the fixing member 12 formed in a part of conveyance guide.
 なお、複数の搬送ガイド1が加熱室2に配置された際に、各々の搬送ガイドから吐出する流体の量を変化させることも可能である。
 すなわち、図1に示す実施形態の場合、ウェブ8は、搬送ガイド1a及び1cの下側、搬送ガイド1bの上側を移動する。この場合、搬送ガイド1a及び1cの表面上の流体吐出孔9から吐出される流体は、重力により、搬送ガイド1bの上側に吐出される流体よりも吐出圧力が高くなることが考えられる。
 そこで、搬送ガイド1bの上側に吐出される流体の吐出圧力を、搬送ガイド1a及び1cの表面上の流体吐出孔9から吐出される流体の吐出圧力よりも高くすることにより、搬送ガイド1a、1b、1c上に同じ厚さ、同じ流体量の流体層11を形成することが可能である。
In addition, when the some conveyance guide 1 is arrange | positioned in the heating chamber 2, it is also possible to change the quantity of the fluid discharged from each conveyance guide.
That is, in the case of the embodiment shown in FIG. 1, the web 8 moves below the conveyance guides 1a and 1c and above the conveyance guide 1b. In this case, the fluid discharged from the fluid discharge holes 9 on the surfaces of the transport guides 1a and 1c may have a higher discharge pressure than the fluid discharged to the upper side of the transport guide 1b due to gravity.
Accordingly, the discharge pressure of the fluid discharged to the upper side of the transfer guide 1b is set higher than the discharge pressure of the fluid discharged from the fluid discharge hole 9 on the surfaces of the transfer guides 1a and 1c, thereby the transfer guides 1a and 1b. It is possible to form the fluid layer 11 having the same thickness and the same amount of fluid on 1c.
 同様の理由で、流体の吐出圧力のみならず、流体量を変化させることも可能である。すなわち、搬送ガイド1bの上側に吐出される流体の量を、搬送ガイド1a及び1cの表面上の流体吐出孔9から吐出される流体の量よりも多くすることにより、流体層11の厚さ等を調整することも可能である。 For the same reason, it is possible to change not only the fluid discharge pressure but also the fluid amount. That is, by increasing the amount of fluid discharged to the upper side of the conveyance guide 1b more than the amount of fluid discharged from the fluid discharge holes 9 on the surfaces of the conveyance guides 1a and 1c, the thickness of the fluid layer 11 and the like It is also possible to adjust.
 次に、図3を参照して搬送ガイド1の表面に形成されている流体吐出孔9について説明する。
 図3に示すように、搬送ガイド1の軸方向(ウェブの移動方向10と直交する直交方向13)に複数形成された流体吐出孔9が流体吐出孔列19aを形成しており、隣接する流体吐出孔列の流体吐出孔の配置が、搬送ガイド1の周方向(移動方向10)において同一直線上には配置されていない。
 すなわち、流体吐出孔9は、直交方向13には流体吐出孔間距離9aの間隔で配置され、流体吐出孔列は流体吐出孔間距離9bの間隔で配置されている。
Next, the fluid discharge holes 9 formed on the surface of the conveyance guide 1 will be described with reference to FIG.
As shown in FIG. 3, a plurality of fluid discharge holes 9 formed in the axial direction of the conveyance guide 1 (orthogonal direction 13 orthogonal to the moving direction 10 of the web) form a fluid discharge hole array 19a, and adjacent fluids The arrangement of the fluid ejection holes in the ejection hole array is not arranged on the same straight line in the circumferential direction (movement direction 10) of the transport guide 1.
That is, the fluid discharge holes 9 are arranged in the orthogonal direction 13 at intervals of a fluid discharge hole distance 9a, and the fluid discharge hole rows are arranged at intervals of a fluid discharge hole distance 9b.
 さらに、移動方向10において隣り合う2つの流体吐出孔が結ぶ仮想線14は、移動方向10と交わるように流体吐出孔9が斜め方向に配置されている。
 より具体的には、図3に示すとおり、移動方向10を基準に隣り合う流体吐出孔9dと9eは、直交方向13に対して互いにずれるようにズレ幅9cだけずれて配置されている。
 このように配置することで、流体吐出孔9から吐出される流体がウェブ8に対して均一となり、形成される流体層11の厚さや流体量を均一となるように調整されて、ウェブ8は、移動方向10に沿って搬送されるようになる。
Further, the imaginary line 14 connecting two adjacent fluid ejection holes in the movement direction 10 has the fluid ejection holes 9 arranged in an oblique direction so as to intersect the movement direction 10.
More specifically, as shown in FIG. 3, the fluid discharge holes 9 d and 9 e adjacent to each other with respect to the moving direction 10 are arranged so as to be shifted from each other with respect to the orthogonal direction 13 by a shift width 9 c.
By arranging in this way, the fluid discharged from the fluid discharge holes 9 is uniform with respect to the web 8, and the thickness and the amount of fluid of the formed fluid layer 11 are adjusted to be uniform. Then, it is conveyed along the moving direction 10.
 以下に、実施例1に関する諸条件を以下に示す。
≪ウェブの延伸条件≫
 ウェブの材料:ポリノルボルネン系樹脂フィルム(ガラス転移温度Tg:120℃)
 ウェブの大きさ(サイズ):厚さ150μm、幅250mm
 延伸倍率:2.0倍
≪加熱室内の構造・条件≫
 加熱空間の温度:140℃(延伸時のウェブ温度は140℃)
 搬送ガイドの本数:3
 流体吐出孔から吐出する流体の温度:140℃
≪搬送ガイドの構造≫
 流体吐出孔の形状:
  ・サイズ:0.5mm幅×0.15mm高さ×20mm深さ
  ・直交方向13において隣接する流体吐出孔間の距離9a:1.0mm
  ・移動方向10において隣接する流体吐出孔間の距離9b:2.0mm
  ・移動方向10において隣接する流体吐出孔の、直交方向13における流体吐出孔間のズレ幅9c:0.2mm
 流体吐出孔9の総数:(搬送ガイドの円弧面180°に対し)22000個/本
 搬送面の形状:
  ・ロール径6:95mmφ
  ・ロール幅7:300mm
  ・ウェブ巻き付け角θ:180°以下
≪ブロワ3≫ ただしブロワ1機で搬送ガイド3本を制御
 モーター出力:1.5kW
 最大静圧:12kPa
 最大風量:5m/min
≪試験時の測定データ≫
 ウェブへの浮上圧:4~6kPa(搬送ガイド内部の中空形状101での圧力を測定)
 延伸時のウェブへの張力(ロール4~5間で測定):ウェブ温度140℃の時で10~30N
 ウェブの浮上量(流体層11の厚さとほぼ同義):2mm以内(目測)
Below, the various conditions regarding Example 1 are shown below.
≪Web stretch conditions≫
Web material: Polynorbornene resin film (glass transition temperature Tg: 120 ° C.)
Web size (size): thickness 150 μm, width 250 mm
Stretch ratio: 2.0 times << Structure and conditions in heating chamber >>
Heating space temperature: 140 ° C. (web temperature during stretching is 140 ° C.)
Number of transport guides: 3
Temperature of fluid discharged from fluid discharge hole: 140 ° C
<< Construction of transport guide >>
Fluid discharge hole shape:
-Size: 0.5 mm width x 0.15 mm height x 20 mm depth-Distance 9a between adjacent fluid discharge holes in the orthogonal direction 13: 1.0 mm
-Distance 9b between adjacent fluid discharge holes in the moving direction 10: 2.0 mm
-Deviation width 9c between fluid ejection holes in the orthogonal direction 13 between adjacent fluid ejection holes in the moving direction 10: 0.2 mm
Total number of fluid discharge holes 9: 22,000 / (conveying guide arcuate surface 180 °) Shape of conveying surface:
・ Roll diameter 6: 95mmφ
・ Roll width 7: 300mm
・ Web wrap angle θ: 180 ° or less ≪Blower 3≫ However, three blower guides are controlled by one blower. Motor output: 1.5 kW
Maximum static pressure: 12kPa
Maximum air volume: 5m 3 / min
≪Measurement data at the time of test≫
Floating pressure on the web: 4-6 kPa (Measures the pressure in the hollow shape 101 inside the conveyance guide)
Tension on the web during stretching (measured between rolls 4-5): 10-30 N at web temperature 140 ° C
Web flying height (substantially synonymous with the thickness of the fluid layer 11): within 2 mm (measurement)
 入口側ロール4と出口側ロール5の間の延伸区間(ウェブの移動方向の長さ)を800mmとし、入口側ロール4の周速度は1.0m/min、出口側ロール5の周速度は2.0m/minとした。 The stretching section (length in the moving direction of the web) between the inlet side roll 4 and the outlet side roll 5 is 800 mm, the peripheral speed of the inlet side roll 4 is 1.0 m / min, and the peripheral speed of the outlet side roll 5 is 2 0.0 m / min.
 以上の条件で、140℃に設定された加熱室内に3本の搬送ガイド1a、1b、1cにより加熱空気によるほぼ静圧空気層による流体層11を形成し、この流体層11の表面がウェブ8の搬送面として機能した。なお流体としては140℃に設定した加熱空気を吐出させた。 Under the above conditions, the fluid layer 11 is formed by a substantially static pressure air layer by heated air in the heating chamber set at 140 ° C. by the three conveyance guides 1a, 1b, 1c, and the surface of the fluid layer 11 is the web 8 Functioned as a transfer surface. Note that heated air set at 140 ° C. was discharged as the fluid.
 得られた延伸ウェブの全幅について、波長590nmでのレターデーション値及び配向角を、幅方向に10mm間隔で測定したところ、レターデーションの平均値は140nm、10mm離れた2点間のレターデーション値の変動は最大10%、配向角については最大値と最小値の差が1.0°とウェブが全体にわたって均一に延伸されていることが判明した。また、ウェブ表面へのシワ及び擦り疵は観察されなかった。 When the retardation value and the orientation angle at a wavelength of 590 nm were measured at intervals of 10 mm in the width direction for the entire width of the obtained stretched web, the average value of the retardation was 140 nm and the retardation value between two points 10 mm apart. It was found that the variation was 10% at the maximum and the difference between the maximum value and the minimum value for the orientation angle was 1.0 °, and the web was uniformly stretched throughout. Also, no wrinkles or scuffs on the web surface were observed.
<実施例2>
 図4に、本発明を適用した実施例2に係る縦一軸延伸装置を示す。実施例2は、加熱室内に配置された3本の搬送ガイド1を互いに高低差をつけて加熱室2内に配置し、延伸区間(ウェブの移動方向の長さ)を1200mmとした点において、実施例1との差違がある。
<Example 2>
FIG. 4 shows a longitudinal uniaxial stretching apparatus according to Example 2 to which the present invention is applied. In Example 2, the three conveyance guides 1 arranged in the heating chamber are arranged in the heating chamber 2 with a difference in height, and the stretching section (the length in the moving direction of the web) is set to 1200 mm. There is a difference from the first embodiment.
 このように、高低差を設けて搬送ガイド1を加熱室2内に複数配置すれば、加熱空間21のスペースを有効に利用でき、装置の大型化を抑制しつつ延伸区間を長めにとることが可能となる。なお上記した点以外は、実施例1と同様に行って位相差フィルムを製造した。 Thus, if a plurality of conveyance guides 1 are arranged in the heating chamber 2 with a difference in height, the space of the heating space 21 can be used effectively, and the stretching section can be made long while suppressing the enlargement of the apparatus. It becomes possible. A retardation film was produced in the same manner as in Example 1 except for the points described above.
 本実施例においても、得られた延伸ウェブの全幅について、波長590nmでの面内レターデーション値及び配向角を幅方向に10mm間隔で測定したところ、面内レターデーションの平均値は180nm、10mm離れた2点間のレターデーション値の変動は最大10%、配向角については最大値と最小値の差が1.0°とウェブが全体にわたって均一に延伸されていることが判明した。また、実施例1と同様に、ウェブ表面へのシワ及び擦り疵は観察されなかった。 Also in this example, when the in-plane retardation value and orientation angle at a wavelength of 590 nm were measured at intervals of 10 mm in the width direction for the entire width of the obtained stretched web, the average value of in-plane retardation was 180 nm and 10 mm apart. Further, it was found that the fluctuation of the retardation value between the two points was 10% at the maximum and the difference between the maximum value and the minimum value was 1.0 ° for the orientation angle, so that the web was uniformly stretched throughout. In addition, as in Example 1, wrinkles and scuffs on the web surface were not observed.
<実施例3>
 図5に、本発明を適用した実施例3に係る縦一軸延伸装置を示す。実施例3は、加熱室内に配置される搬送ガイド1を1本にした点で、実施例1及び2との差違がある。
<Example 3>
FIG. 5 shows a longitudinal uniaxial stretching apparatus according to Example 3 to which the present invention is applied. The third embodiment is different from the first and second embodiments in that the number of conveyance guides 1 arranged in the heating chamber is one.
 図5のとおり、搬送ガイド1は、加熱室2の加熱空間21の上方部に位置しており、この搬送ガイド1の上方をウェブ8が通過する態様となっている。またブロワ3は、1本の搬送ガイド1の表面に形成された流体吐出孔9から吐出される加熱空気を制御する。なお上記した点以外は、実施例1又は実施例2と同様に行って位相差フィルムを製造した。 As shown in FIG. 5, the conveyance guide 1 is positioned above the heating space 21 of the heating chamber 2, and the web 8 passes through the conveyance guide 1. The blower 3 controls heated air discharged from the fluid discharge holes 9 formed on the surface of the single conveyance guide 1. In addition, it carried out similarly to Example 1 or Example 2 except the above-mentioned point, and manufactured the phase difference film.
 以上説明したとおり、本発明を適用したウェブ延伸方法および位相差フィルムの製造方法によれば、加熱室内でウェブを方向転換させない場合と比べて加熱室を小型化できてコスト削減が可能となる。これに加えてさらに、延伸するウェブは加熱室内では搬送ガイドと非接触の状態で搬送されるため幅方向でのフィルム張力のばらつきや、シワや擦り疵の発生などの問題を生じることがない。これにより製造コストを抑制しつつウェブを均一に延伸することが可能となり、位相差フィルムを製造する際に極めて有利な効果を奏する。 As described above, according to the web stretching method and the retardation film manufacturing method to which the present invention is applied, the heating chamber can be reduced in size and the cost can be reduced as compared with the case where the web is not turned in the heating chamber. In addition, since the web to be stretched is conveyed in a non-contact state with the conveyance guide in the heating chamber, problems such as variations in film tension in the width direction, generation of wrinkles and rubbing are not caused. This makes it possible to uniformly stretch the web while suppressing the manufacturing cost, and has an extremely advantageous effect when manufacturing the retardation film.
<その他の変形例>
 なお本実施例は上記したものに限定されず、本発明の趣旨を逸脱しない限りで技術常識を鑑みて適宜変更が可能である。
 例えば3本の搬送ガイド1を加熱室2内に配置する際には、中央に配置される搬送ガイド1の上面側に流体吐出孔9が形成されたが、これを下面側とし、両サイドの搬送ガイド1は上面側に流体吐出孔9を形成してもよい。
<Other variations>
In addition, a present Example is not limited to what was mentioned above, Unless it deviates from the meaning of this invention, it can change suitably in view of technical common sense.
For example, when the three conveyance guides 1 are arranged in the heating chamber 2, the fluid discharge hole 9 is formed on the upper surface side of the conveyance guide 1 arranged in the center. The transport guide 1 may have a fluid discharge hole 9 on the upper surface side.
 また図1では、搬送ガイド1の表面に形成される流体吐出孔9は交互に上面側と下面側に形成されたが、3本の搬送ガイド1について同一の側に流体吐出孔9が形成されていてもよい。3本の搬送ガイド1の下側に流体吐出孔9を形成した場合には、図1においてウェブは搬送ガイド1bの下側を搬送される。すなわち、搬送ガイド1a、1b、および1cの下側をウェブが通過することになる。さらに入口側ロール4の周速度や出口側ロール5の周速度も、延伸倍率やウェブの材質などに応じて適宜設定が可能である。 In FIG. 1, the fluid discharge holes 9 formed on the surface of the transport guide 1 are alternately formed on the upper surface side and the lower surface side, but the fluid discharge holes 9 are formed on the same side for the three transport guides 1. It may be. When the fluid discharge holes 9 are formed on the lower side of the three conveyance guides 1, the web is conveyed on the lower side of the conveyance guide 1b in FIG. That is, the web passes under the conveyance guides 1a, 1b, and 1c. Furthermore, the peripheral speed of the inlet-side roll 4 and the peripheral speed of the outlet-side roll 5 can be appropriately set according to the draw ratio, the material of the web, and the like.
 加熱空間21に配置される搬送ガイド1の本数も1本または3本に限られず、加熱空間21のスペースを有効に利用する限りにおいて配置位置や本数は適宜設定可能である。 The number of the conveyance guides 1 arranged in the heating space 21 is not limited to one or three, and the arrangement position and the number can be appropriately set as long as the space of the heating space 21 is effectively used.
 なお、搬送ガイド1の全周囲方向に流体吐出孔9を設け、且つ、搬送ガイド1を回転可能に取り付けることで、搬送ガイド1を回転させながらウェブを搬送することも可能である。 In addition, it is also possible to convey the web while rotating the conveyance guide 1 by providing the fluid discharge holes 9 in the entire circumference direction of the conveyance guide 1 and attaching the conveyance guide 1 to be rotatable.
 本発明は、ウェブを延伸する延伸方法および延伸装置に好適であり、さらにこのウェブを利用した位相差フィルムを製造する製造方法および製造装置にも適用することができ、産業上の利用可能性が極めて高い。 The present invention is suitable for a stretching method and a stretching apparatus for stretching a web, and can also be applied to a manufacturing method and a manufacturing apparatus for manufacturing a retardation film using the web. Extremely high.
1、1a、1b、1c 搬送ガイド
2   加熱室
21  加熱空間
22  入口
23  出口
3   ブロワ
31  移動パイプ
4   入口側ロール
5   出口側ロール
6   ロール径
7   ロール幅
8   ウェブ
9   流体吐出孔
9a、9b  流体吐出孔間距離
9c  ズレ幅
9d、9e  流体吐出孔
10  移動方向
11  流体層
12  固定部材
13  直交方向
14  仮想線
19a 流体吐出孔列
101 搬送ガイド内部の中空形状
P   巻き戻しロール
Q   巻き取りロール
1, 1a, 1b, 1c Conveying guide 2 Heating chamber 21 Heating space 22 Inlet 23 Outlet 3 Blower 31 Moving pipe 4 Inlet side roll 5 Outlet side roll 6 Roll diameter 7 Roll width 8 Web 9 Fluid ejection holes 9a, 9b Fluid ejection holes Distance 9c Deviation width 9d, 9e Fluid discharge hole 10 Movement direction 11 Fluid layer 12 Fixing member 13 Orthogonal direction 14 Virtual line 19a Fluid discharge hole array 101 Hollow shape P inside the conveyance guide Rewinding roll Q Winding roll

Claims (7)

  1.  少なくとも一つの搬送ガイドを有する加熱室内において、ウェブを延伸可能な温度で加熱しながら前記搬送ガイドを介して移動させ、前記ウェブの移動方向に延伸するウェブ延伸方法であって、
     前記搬送ガイドの表面に形成された流体吐出孔から流体を吐出して前記搬送ガイドの表面に流体層を形成し、
     前記加熱室内にて前記ウェブが前記流体層上を移動することによって前記搬送ガイドに前記ウェブが接触することなく前記ウェブの移動方向を変化させることを特徴とするウェブ延伸方法。
    In a heating chamber having at least one conveyance guide, the web is stretched in the moving direction of the web by moving the web through the conveyance guide while being heated at a temperature at which the web can be stretched,
    Fluid is discharged from a fluid discharge hole formed on the surface of the transport guide to form a fluid layer on the surface of the transport guide;
    A web stretching method, wherein the web moves in the heating chamber to change the moving direction of the web without contacting the web with the transport guide.
  2.  前記搬送ガイドの表面に複数の流体吐出孔が形成され、
    前記搬送ガイドの内部に前記流体吐出孔に通ずる導入流路が形成され、
    前記複数の流体吐出孔から吐出される前記流体によって前記流体層を形成することを特徴とする請求項1に記載のウェブ延伸方法。
    A plurality of fluid discharge holes are formed on the surface of the transport guide,
    An introduction flow path leading to the fluid discharge hole is formed inside the conveyance guide,
    The web stretching method according to claim 1, wherein the fluid layer is formed by the fluid ejected from the plurality of fluid ejection holes.
  3.  前記流体吐出孔は、前記ウェブの移動方向と該方向に直交する直交方向に向けて複数設けられており、
     前記移動方向において隣り合う2つの前記流体吐出孔が結ぶ仮想線が前記移動方向と交わるように、前記2つの流体吐出孔が配置されていることを特徴とする請求項1又は2に記載のウェブ延伸方法。
    A plurality of the fluid discharge holes are provided in a direction perpendicular to the moving direction of the web and the direction perpendicular thereto.
    3. The web according to claim 1, wherein the two fluid ejection holes are arranged so that a virtual line connecting the two fluid ejection holes adjacent in the movement direction intersects the movement direction. 4. Stretching method.
  4.  前記搬送ガイドは加熱室内において複数配置され、
     前記複数の搬送ガイドのうち、前記ウェブがその鉛直上側を通過する搬送ガイドから吐出される前記流体の吐出量は、前記ウェブがその鉛直下側を通過する搬送ガイドから吐出される前記流体の吐出量よりも多いことを特徴とする請求項1乃至3のいずれか1項に記載のウェブ延伸方法。
    A plurality of the conveyance guides are arranged in the heating chamber,
    Of the plurality of transport guides, the amount of fluid discharged from the transport guide through which the web passes vertically above is the amount of fluid discharged from the transport guide through which the web passes below vertical. The web stretching method according to claim 1, wherein the web stretching method is more than the amount.
  5.  前記延伸可能な温度が、前記ウェブのガラス転移点以上の温度であることを特徴とする請求項1乃至4のいずれか1項に記載のウェブ延伸方法。 The web stretching method according to any one of claims 1 to 4, wherein the stretchable temperature is a temperature equal to or higher than a glass transition point of the web.
  6.  前記流体吐出孔から吐出される流体の温度が、前記加熱室内と同じ温度であることを特徴とする請求項1乃至5のいずれか1項に記載のウェブ延伸方法。 The web stretching method according to any one of claims 1 to 5, wherein the temperature of the fluid discharged from the fluid discharge hole is the same as that in the heating chamber.
  7.  請求項1乃至6のいずれか1項に記載のウェブ延伸方法を用いて、位相差フィルムを延伸することを特徴とする位相差フィルムの製造方法。 A method for producing a retardation film, comprising: stretching a retardation film using the web stretching method according to any one of claims 1 to 6.
PCT/JP2010/004022 2009-07-30 2010-06-17 Web stretching method and method for producing retardation film WO2011013292A1 (en)

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JPH0976343A (en) * 1995-09-19 1997-03-25 Sekisui Chem Co Ltd Production of stretched film
JP2002333521A (en) * 2001-05-07 2002-11-22 Nitto Denko Corp Method for manufacturing aligned film, polarizing film, polarizing plate and liquid crystal display device
JP2008221722A (en) * 2007-03-14 2008-09-25 Fujifilm Corp Process and apparatus for longitudinally stretching thermoplastic resin film
JP2009190320A (en) * 2008-02-15 2009-08-27 Fujifilm Corp Longitudinal stretching method of thermoplastic resin film and longitudinal stretching apparatus
JP2009226847A (en) * 2008-03-25 2009-10-08 Toray Ind Inc Floating type longitudinally orienting device and forming method of thermoplastic resin film

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DE69424569T2 (en) * 1993-01-25 2001-01-18 Daikin Industries, Ltd. Porous film made of polytetrafluoroethylene
JP2009093169A (en) * 2007-09-21 2009-04-30 Sumitomo Chemical Co Ltd Method for producing retardation film made of thermoplastic resin

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Publication number Priority date Publication date Assignee Title
JPH0976343A (en) * 1995-09-19 1997-03-25 Sekisui Chem Co Ltd Production of stretched film
JP2002333521A (en) * 2001-05-07 2002-11-22 Nitto Denko Corp Method for manufacturing aligned film, polarizing film, polarizing plate and liquid crystal display device
JP2008221722A (en) * 2007-03-14 2008-09-25 Fujifilm Corp Process and apparatus for longitudinally stretching thermoplastic resin film
JP2009190320A (en) * 2008-02-15 2009-08-27 Fujifilm Corp Longitudinal stretching method of thermoplastic resin film and longitudinal stretching apparatus
JP2009226847A (en) * 2008-03-25 2009-10-08 Toray Ind Inc Floating type longitudinally orienting device and forming method of thermoplastic resin film

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JPWO2011013292A1 (en) 2013-01-07
JP5530443B2 (en) 2014-06-25

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