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WO2009150352A3 - Process for producing compounds of the c<sb>x</sb>h<sb>y</sb>o<sb>2</sb> type by reduction of carbon dioxide (co<sb>2</sb>) and/or carbon monoxide (co) - Google Patents

Process for producing compounds of the c<sb>x</sb>h<sb>y</sb>o<sb>2</sb> type by reduction of carbon dioxide (co<sb>2</sb>) and/or carbon monoxide (co) Download PDF

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Publication number
WO2009150352A3
WO2009150352A3 PCT/FR2009/050909 FR2009050909W WO2009150352A3 WO 2009150352 A3 WO2009150352 A3 WO 2009150352A3 FR 2009050909 W FR2009050909 W FR 2009050909W WO 2009150352 A3 WO2009150352 A3 WO 2009150352A3
Authority
WO
WIPO (PCT)
Prior art keywords
membrane
reduction
type
carbon dioxide
steam
Prior art date
Application number
PCT/FR2009/050909
Other languages
French (fr)
Other versions
WO2009150352A2 (en
Inventor
Béatrice Sala
Olivier Lacroix
Original Assignee
Areva
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Areva filed Critical Areva
Priority to EP09761903A priority Critical patent/EP2282983A2/en
Priority to RU2010151465/04A priority patent/RU2493293C2/en
Priority to US12/992,740 priority patent/US20110132770A1/en
Priority to JP2011508988A priority patent/JP2011521104A/en
Priority to CN2009801219418A priority patent/CN102056866A/en
Priority to BRPI0912654A priority patent/BRPI0912654A2/en
Publication of WO2009150352A2 publication Critical patent/WO2009150352A2/en
Publication of WO2009150352A3 publication Critical patent/WO2009150352A3/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00Electrolytic production of organic compounds
    • C25B3/20Processes
    • C25B3/25Reduction

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The present invention relates to a process for electrolysing steam introduced under pressure into an anode compartment (32) of an electrolyser (30) provided with a proton-conducting membrane (31) made of a material that allows protonated species to be incorporated into this membrane under steam, water injected in steam form being oxidized at the anode (32) so as to generate protonated species in the membrane that migrate within this same membrane and are reduced at the surface of the cathode (33) in the form of reactive hydrogen atoms capable of reducing carbon dioxide and/or carbon monoxide, said process comprising the following steps: injection of CO2 and/or CO under pressure into the cathode compartment (33) of the electrolyser (30); - reduction of the CO2 and/or CO injected into the cathode compartment (33) by said reactive hydrogen atoms generated, in such a way that the CO2 and/or the CO form compounds of the CxHyOz type where x>1, y is between 0 and 2x+2 and z is between 0 and 2x.
PCT/FR2009/050909 2008-05-15 2009-05-15 Process for producing compounds of the c<sb>x</sb>h<sb>y</sb>o<sb>2</sb> type by reduction of carbon dioxide (co<sb>2</sb>) and/or carbon monoxide (co) WO2009150352A2 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
EP09761903A EP2282983A2 (en) 2008-05-15 2009-05-15 PROCESS FOR PRODUCING COMPOUNDS OF THE CXHYO2 TYPE BY REDUCTION OF CARBON DIOXIDE (CO2) AND/OR CARBON MONOXIDE (CO)& xA;
RU2010151465/04A RU2493293C2 (en) 2008-05-15 2009-05-15 METHOD OF PRODUCING CxHyOz TYPE COMPOUNDS BY REDUCING CARBON DIOXIDE (CO2) AND/OR CARBON MONOXIDE (CO)
US12/992,740 US20110132770A1 (en) 2008-05-15 2009-05-15 Process for producing compounds of the cxhyoz type by reduction of carbon dioxide (co2) and/or carbon monoxide (co)
JP2011508988A JP2011521104A (en) 2008-05-15 2009-05-15 Process for producing CXHYOZ type compounds by reduction of carbon dioxide (CO2) and / or carbon monoxide (CO)
CN2009801219418A CN102056866A (en) 2008-05-15 2009-05-15 Process for producing compounds of the CxHyO2 type by reduction of carbon dioxide (CO2) and/or carbon monoxide (CO)
BRPI0912654A BRPI0912654A2 (en) 2008-05-15 2009-05-15 process of producing cxhyoz-type compounds by reducing carbon dioxide (co2) and / or carbon monoxide (co)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0853161 2008-05-15
FR0853161A FR2931168B1 (en) 2008-05-15 2008-05-15 PROCESS FOR PRODUCING CXHYOZ COMPOUNDS BY REDUCING CARBON DIOXIDE (CO2) AND / OR CARBON MONOXIDE (CO)

Publications (2)

Publication Number Publication Date
WO2009150352A2 WO2009150352A2 (en) 2009-12-17
WO2009150352A3 true WO2009150352A3 (en) 2010-02-18

Family

ID=40122470

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FR2009/050909 WO2009150352A2 (en) 2008-05-15 2009-05-15 Process for producing compounds of the c<sb>x</sb>h<sb>y</sb>o<sb>2</sb> type by reduction of carbon dioxide (co<sb>2</sb>) and/or carbon monoxide (co)

Country Status (8)

Country Link
US (1) US20110132770A1 (en)
EP (1) EP2282983A2 (en)
JP (1) JP2011521104A (en)
CN (1) CN102056866A (en)
BR (1) BRPI0912654A2 (en)
FR (1) FR2931168B1 (en)
RU (1) RU2493293C2 (en)
WO (1) WO2009150352A2 (en)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2927350A1 (en) 2014-04-02 2015-10-07 Beatrice Sala Electrochemical cell for the electrolysis of water in steam or liquid form, manufacturing method and uses
EP2691560B1 (en) 2011-03-26 2017-08-16 Honda Motor Co., Ltd. Method for the production of carbon nanotubes
FR2981369B1 (en) * 2011-10-12 2013-11-15 Areva METHOD AND SYSTEM FOR TREATING CARBON GASES BY ELECTROCHEMICAL HYDROGENATION FOR OBTAINING A CXHYOZ-TYPE COMPOUND
FR2981368B1 (en) * 2011-10-12 2013-11-15 Areva PROCESS FOR GENERATING HYDROGEN AND OXYGEN BY ELECTROLYSIS OF WATER VAPOR
PT106860A (en) 2013-03-28 2014-09-29 Cuf Químicos Ind S A ELECTRODE / ELECTROLYTE ASSEMBLY, REACTOR AND METHOD FOR DIRECT AMMINATION OF HYDROCARBONS
FR3004179B1 (en) 2013-04-08 2015-05-01 Commissariat Energie Atomique METHODS FOR OBTAINING COMBUSTIBLE GAS FROM WATER ELECTROLYSIS (EHT) OR CO-ELECTROLYSIS WITH H2O / CO2 WITHIN THE SAME ENCLOSURE, CATALYTIC REACTOR AND SYSTEM THEREOF
JP6610917B2 (en) * 2014-02-07 2019-11-27 パナソニックIpマネジメント株式会社 Steam electrolysis hydrogenation equipment
JP6292381B2 (en) * 2014-02-07 2018-03-14 パナソニックIpマネジメント株式会社 Steam electrolysis hydrogenation equipment
DE102015209509A1 (en) * 2015-05-22 2016-11-24 Siemens Aktiengesellschaft Electrolysis system for electrochemical carbon dioxide utilization with proton donor unit and reduction process
JP6622237B2 (en) 2017-03-14 2019-12-18 株式会社東芝 Carbon dioxide electrolyzer
WO2018170243A1 (en) * 2017-03-16 2018-09-20 Battelle Energy Alliance, Llc Methods and systems for carbon dioxide hydrogenation
US11001549B1 (en) 2019-12-06 2021-05-11 Saudi Arabian Oil Company Electrochemical reduction of carbon dioxide to upgrade hydrocarbon feedstocks
CN111215111B (en) * 2020-01-13 2022-07-19 山西大学 Carbon dioxide electrochemical reduction catalyst rich in oxygen vacancies and preparation method and application thereof
US11426708B2 (en) 2020-03-02 2022-08-30 King Abdullah University Of Science And Technology Potassium-promoted red mud as a catalyst for forming hydrocarbons from carbon dioxide
US11420915B2 (en) 2020-06-11 2022-08-23 Saudi Arabian Oil Company Red mud as a catalyst for the isomerization of olefins
US11495814B2 (en) 2020-06-17 2022-11-08 Saudi Arabian Oil Company Utilizing black powder for electrolytes for flow batteries
US12000056B2 (en) 2020-06-18 2024-06-04 Saudi Arabian Oil Company Tandem electrolysis cell
ES2942302T3 (en) * 2020-10-21 2023-05-31 Carretera De Terrassa 121 Process to produce functionalized organic molecules
US11814289B2 (en) 2021-01-04 2023-11-14 Saudi Arabian Oil Company Black powder catalyst for hydrogen production via steam reforming
US11427519B2 (en) 2021-01-04 2022-08-30 Saudi Arabian Oil Company Acid modified red mud as a catalyst for olefin isomerization
US11820658B2 (en) 2021-01-04 2023-11-21 Saudi Arabian Oil Company Black powder catalyst for hydrogen production via autothermal reforming
US11724943B2 (en) 2021-01-04 2023-08-15 Saudi Arabian Oil Company Black powder catalyst for hydrogen production via dry reforming
US11718522B2 (en) 2021-01-04 2023-08-08 Saudi Arabian Oil Company Black powder catalyst for hydrogen production via bi-reforming
CN113106485A (en) * 2021-04-25 2021-07-13 中国华能集团清洁能源技术研究院有限公司 Double-function electrode structure for electrolyzing water
US12018392B2 (en) 2022-01-03 2024-06-25 Saudi Arabian Oil Company Methods for producing syngas from H2S and CO2 in an electrochemical cell

Citations (4)

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US4547273A (en) * 1984-06-07 1985-10-15 Energy Conversion Devices, Inc. Mobile atom insertion reaction, mobile atom transmissive membrane for carrying out the reaction, and reactor incorporating the mobile atom transmissive membrane
JP2006054170A (en) * 2004-07-07 2006-02-23 Central Res Inst Of Electric Power Ind Proton conductive oxide membrane-hydrogen permeable membrane composite membrane electrolyte, and electrochemical device using the same
WO2007145586A1 (en) * 2006-06-16 2007-12-21 Morphic Technologies Aktiebolag (Publ.) A method and a reactor for making methanol
WO2008017838A1 (en) * 2006-08-08 2008-02-14 Itm Power (Research) Ltd. Fuel synthesis

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DE2806984C3 (en) * 1978-02-18 1980-09-25 Kernforschungsanlage Juelich Gmbh, 5170 Juelich Process for producing hydrogen and oxygen and an electrolytic cell for carrying out this process
NO311081B1 (en) * 1999-12-09 2001-10-08 Norske Stats Oljeselskap Optimized FT synthesis by reforming and recycling tail gas from FT synthesis
DK1730327T3 (en) * 2004-03-26 2014-07-28 Univ St Andrews ADHD electrolysis
JP5155147B2 (en) * 2005-03-16 2013-02-27 フュエルコア エルエルシー Systems, methods, and compositions for producing synthetic hydrocarbon compounds
AU2008247280A1 (en) * 2007-05-04 2008-11-13 Principle Energy Solutions, Inc. Production of hydrocarbons from carbon and hydrogen sources
FR2916653B1 (en) * 2007-06-01 2011-05-06 Areva Np METHOD FOR OPTIMIZING THE IONIC CONDUCTIVITY OF A CONDUCTIVE ION MEMBRANE

Patent Citations (4)

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Publication number Priority date Publication date Assignee Title
US4547273A (en) * 1984-06-07 1985-10-15 Energy Conversion Devices, Inc. Mobile atom insertion reaction, mobile atom transmissive membrane for carrying out the reaction, and reactor incorporating the mobile atom transmissive membrane
JP2006054170A (en) * 2004-07-07 2006-02-23 Central Res Inst Of Electric Power Ind Proton conductive oxide membrane-hydrogen permeable membrane composite membrane electrolyte, and electrochemical device using the same
WO2007145586A1 (en) * 2006-06-16 2007-12-21 Morphic Technologies Aktiebolag (Publ.) A method and a reactor for making methanol
WO2008017838A1 (en) * 2006-08-08 2008-02-14 Itm Power (Research) Ltd. Fuel synthesis

Also Published As

Publication number Publication date
JP2011521104A (en) 2011-07-21
WO2009150352A2 (en) 2009-12-17
FR2931168A1 (en) 2009-11-20
EP2282983A2 (en) 2011-02-16
RU2493293C2 (en) 2013-09-20
FR2931168B1 (en) 2010-07-30
RU2010151465A (en) 2012-06-20
US20110132770A1 (en) 2011-06-09
BRPI0912654A2 (en) 2016-07-05
CN102056866A (en) 2011-05-11

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