WO2008151363A1

WO2008151363A1 - Apparatus for and method of treating waste containing plastic material

Info

Publication number: WO2008151363A1
Application number: PCT/AU2008/000834
Authority: WO
Inventors: Martin Löffler; Thomas Kaiser; Siegfried Römer; Richard Schimko; Carlos Ramon Maria Sorentino
Original assignee: Rft Plastics Inc.
Priority date: 2007-06-12
Filing date: 2008-06-12
Publication date: 2008-12-18
Also published as: DE102007027629A1; AU2008202608A1; US20090014311A1

Abstract

Apparatus and method for treating waste products containing plastic materials by pyrolysis is disclosed. The method includes pyrolytically decomposing the waste products containing plastic materials by thermolysis to obtain useful liquid and gaseous organic raw materials. Preferably, the method is carried out continuously.

Description

APPARATUS FOR AND METHOD OF TREATING WASTE CONTAINING

PLASTIC MATERIAL

CROSS-REFERENCE TO RELATED APPLICATION The present application claims priority from German patent application

10 2007 027629.1 filed on 12 June 2007, the contents of which is incorporated herein by reference.

FIELD OF THE INVENTION The present invention relates to an apparatus for and a method of a method of obtaining liquid and gaseous organic raw materials from waste containing plastic material by way of thermolysis.

BACKGROUND OF THE INVENTION There are methods that can be used to process hydrocarbon-containing and/or halogenated waste products to produce useful raw materials by incinerating them at high temperature in an open flame and utilizing the energy obtained from this.

Unfortunately, during the incineration of hydrocarbon-containing and/or halogenated waste products a large number of different reaction products are obtained which are questionable in varying degrees as regards their environmental compatibility. Moreover, these processes tend to be conducted at temperatures of between 800 to 1600°C which can result complete degradation of the potentially useful waste products and the production of toxic by-products.

EP-A-O 592 057 discloses a process for the pyrolysis of used vehicle tyres, and an apparatus for carrying out the process. The pyrolysis takes place with the exclusion of air and water and is operated under reduced pressure at an operating temperature of 450-550°C, preferably below 500°C. This process can have limited applicability with respect to the types of waste materials which maybe processed, for example, upon thermolysis or pyrolysis some plastic materials there is a tendency to give off large amounts of gas in a short time severely disrupting the efficacy of the overall process.

Another common disadvantage of the known methods and apparatus for processing of hydrocarbon containing waste materials is that the resultant product mixture is of a low grade and only contains relatively small amounts of high-grade fractions such as gasoline and kerosene. Moreover, many of the known processes are batch processes which generally do not easily lend themselves to economical scaling. It is desirable that the present invention provide an apparatus and a method with which it is possible to process a wide variety of plastic wastes which, for example, contain polyethylene, polypropylene or polystyrene.

In that respect the apparatus and the method are to be such that as far as possible no harmful substances such as for example dioxins are produced in the thermolysis of the plastic material-containing waste.

SUMMARY OF THE INVENTION

In accordance with the invention there is provided an apparatus having a container which is closed except for inlets and outlets and which in operation is to be filled with a liquid metal bath up to a liquid metal level and which has a gas space above the liquid metal level. In addition the container has a waste feed opening for feeding waste to be treated and a residual material outlet opening for solid waste residues. Arranged between the waste feed opening and the residual material outlet opening is a substantially horizontally extending waste conveyor device which is adapted to convey waste, at least in portion-wise manner, beneath the liquid metal level from the waste feed opening to the residual material outlet opening and in that operation to periodically dip the waste which floats up in the liquid metal bath deeper into the liquid metal bath. The apparatus also has a gas feed line for an inert gas, which opens into the gas space, and a gas outlet which is connected to the gas feed line to afford a gas circuit, by way of conduits. Arranged in the gas circuit is a condenser for condensing condensable gas constituents of the gas which is flushed out of the gas space and which is produced by thermolysis or pyrolysis. Opening into the condenser is a carrier liquid feed line by way of which a for example parafins-dissolving carrier liquid can be introduced into the condenser in such a way that for example condensed parafins which are deposited at the condenser walls can be dissolved by the carrier liquid and flushed away. Arranged at the base point of the condenser is a liquid discharge line in order to be able to discharge the carrier liquid together with the thermolysis products dissolved therein. In addition condensed, liquid thermolysis products such as for example oils can also be discharged by way of the liquid discharge line.

Preferably a sacrificial tub is provided for the liquid metal bath, which tub can be replaced without the complete container having to be renewed. That is advantageous because the liquid metal used is preferably liquid tin which results in severe corrosion of other metals. Some of the component parts of the apparatus including the container and the waste conveyor device preferably comprise stainless steel of type 1.43.01.

The conveyor device is preferably enclosed by its own casing within the container. The casing extends in a first portion of the conveyor device near the waste feed opening, in part above the liquid metal level, so that its own gas space is formed within the casing. In the further configuration of the conveyor device, to a position in the proximity of the residual material outlet opening, the casing of the conveyor device and thus the conveyor device itself extends beneath the level of the liquid metal.

The conveyor device preferably has conveyor elements which are arranged around an at least approximately horizontally extending axis of rotation of the conveyor device.

It is advantageous if the axis of rotation and thus the conveyor device are not oriented exactly horizontally but rise slightly in the conveyor direction. That promotes transportation of the waste which has a tendency to float up in the liquid metal bath. The conveyor elements preferably include rotating blade-like entrainment members which rotate about the axis of rotation and which extend at least approximately as far as the casing of the conveyor device and which preferably go in the proximity of the axis of rotation into a chute plate extending inclinedly relative to the axis of rotation. In that case the chute plate is arranged in such a way that it moves away from an edge of the entrainment members, which is near the casing, to an increasing extent in the conveyor direction, and is also arranged on the flat side of the entrainment member, which leads in the direction of rotation, so that waste material engaged by the entrainment member is pushed in a downward movement of the entrainment member beyond the horizontal by buoyancy forces along the entrainment member in the direction of the axis of rotation of the conveyor device and there encounters the chute plate. As. a consequence of the orientation of the chute plate the waste residues which tend to float up then slide along the chute plate in the conveyor direction into a next longitudinal portion of the conveyor device, which also has an entrainment member with a chute adjoining same. Besides those entrainment members the conveyor device preferably has further entrainment plates which extend in the longitudinal direction of the conveyor device in parallel relationship with the axis of rotation and which extend in the radial direction to close to the casing wall. In comparison with the entrainment members however the entrainment plates are substantially shorter in the radial direction. The conveyor device preferably has a plurality of longitudinal portions with a respective entrainment member and a chute. One or two first longitudinal portions of the conveyor device, which are near the waste feed opening, are of a larger diameter than further longitudinal portions, adjoining same, of the conveyor device. The larger diameter of the conveyor device in its initial region also results in a casing of larger diameter which - as already mentioned - projects upwardly at least in part beyond the liquid metal level. That part of the casing of the conveyor device has its own gas space for receiving the pyrolysis gases which are almost abruptly produced when the waste to be treated dips into the liquid metal bath.

Preferably for feeding the waste there is provided a waste feed means which passes through an outer upper wall of the container and which opens from above into the casing of the conveyor device.

At the end of the conveyor device in the proximity of the residual material outlet the casing of the conveyor device, on its top side, beneath the liquid metal level, also has an opening which opens into a discharge chamber whose flat bottom extends precisely at the level of the liquid metal surface. By virtue of the opening at the end of the conveyor device, solid residual materials of the waste can float up to the level of the liquid metal. Preferably arranged in the discharge chamber is a rotating bladed wheel having blades which extend as far as the bottom of the discharge chamber and the edge of the discharge chamber. Those blades are of such a configuration that they pass uniformly over an entry opening of the discharge chamber, which opening is in communication with the outlet opening of the casing of the conveyor device at its end, and in so doing entrain solid residues which are floating on the surface of the liquid metal. Arranged in the bottom of the discharge chamber, on the side remote from the entry opening, is a fall opening through which residual materials transported by the blades of the bladed wheel can drop out of the discharge chamber. The individual longitudinal portions of the conveyor device are preferably fixedly connected together so that they can rotate jointly at the same speed about a common axis of rotation. Alternatively it can also be provided that individual longitudinal portions of the conveyor device can move at different speeds of rotation.

Preferably electrical heating elements are provided for heating the liquid metal bath. Preferably, tubular heating element receiving means which are accessible from an upper cover of the container and which extend to below the level of the liquid metal are provided for receiving the electrical heating elements. Preferably the arrangement has a plurality of those heating element receiving means so that the liquid metal can be heated with a plurality of electrical heating elements. The arrangement of the heating element receiving means, extending from an upper cover of the container, has the advantage that no liquid metal can escape to the exterior from the container through the heating element receiving means, in the event of damage to the heating element receiving means.

The method according to the invention for the treatment of plastic material- containing waste comprises the following steps: introducing waste into a container containing a liquid metal bath and a gas atmosphere thereabove; immersing the waste into the liquid metal bath; conveying the waste within the liquid metal bath and thereby producing thermolysis gas and solid residue materials; flushing the gas atmosphere with an inert gas; separating the thermolysis gas from the inert gas in a condenser; dissolving condensed pyrolysis gas in a carrier liquid; draining the carrier liquid and liquid condensed thermolysis products from the condenser, and removing remaining solid materials from the liquid metal bath.

Preferably the method is carried out continuously.

Preferably an oil or tuluol is used as the carrier liquid.

Preferably lime is added to the liquid metal bath for binding chlorine which is produced in the course of the thermolysis operation. Preferably the method is carried out at temperatures of between 450°C and 500°C.

Preferably tin is entirely or predominantly used as the metal for the liquid metal bath.

Preferably the method is carried out in such a way that the residence time of waste to be treated in the liquid metal bath is about two minutes. Preferably the waste to be treated is conveyed in an at least approximately horizontal direction in the liquid metal bath.

Further advantages of the invention and further preferred variants will be apparent from the description hereinafter of a preferred embodiment by way of example and further appending claims.

BRIEF DESCRIPTION OF THE DRAWINGS

The invention will now be described in greater detail by means of an embodiment by way of example with reference to the Figures in which:

Figure Ia shows an external top view of the apparatus for the treatment of waste, Figure Ib shows an external bottom view of the apparatus for the treatment of waste,

Figure 2 shows a section through the apparatus for the treatment of waste,

Figure 3 shows a view of the apparatus with the cover removed, Figures 4a, 4b and 4c show perspective views of the conveyor device from the outside,

Figure 5 shows a perspective view of rotating conveyor elements of the conveyor device, and

Figure 6 shows a perspective view of a bladed wheel for the discharge of solid waste residues from a discharge chamber of the apparatus.

DETAILED DESCRIPTION OF THE INVENTION

As can be seen from Figure Ia and Ib the apparatus 10 for the treatment of waste materials has a container 12 with a tub-like lower portion 14 and a three-part cover 16. The apparatus has a first electric drive 18 for driving rotating conveyor elements in the interior of the container. The apparatus has a second electric drive 20 for driving a bladed wheel for the discharge of solid waste residues.

A central portion 22 of the three-part cover 16 has a total often heating element receiving means 24 which project from the cover 16 in the direction of the bottom of the tub-shaped lower portion 14 of the container 12. A respective electrical heating element can be introduced into each of the heating element receiving means 24.

Figure 2 shows a view in longitudinal section through the container 12 and discloses a conveyor device 30 which is arranged in the container, as an external view. The conveyor device 30 has a waste feed opening which is connected to a waste feed line 32. Provided at the other longitudinal end of the conveyor device 30 is a residual material outlet opening which is connected by way of a short pipe connection 34 to a discharge chamber 36 of the apparatus 10. The conveyor device 30 is enclosed by a casing 40 disposed in the container 12.

Figure 3 shows the apparatus for the treatment of waste with the cover removed. That means that the conveyor device 30 in the interior of the tub-shaped lower portion

14 of the container 12 can be clearly seen, and it is also possible to clearly see the gas discharge lines 42 as well as the discharge chamber 38, with a bladed wheel 46 arranged therein.

Figures 4a, b and c illustrate the complete conveyor device 30 including the first electric drive 18 and the discharge chamber 38. Connected to the casing 40 of the conveyor device are gas discharge lines 42 which serve for the discharge of vapours and gases produced as a consequence of the thermolysis operation. Figure 4a also clearly shows the waste feed opening 44 for the feed of waste to be treated, to the conveyor device 30.

Figure 5 shows the rotating conveyor elements 50 disposed in the interior of the casing 40 of the conveyor device 30. The conveyor elements 50 have a total of four longitudinal portions of which two longitudinal elements 52 which are near the waste feed opening are of a larger diameter than four other longitudinal portions 54. Each longitudinal portion 52 or 54 of the rotating conveyor elements 50 has an entrainment member 56 which extends as far as the casing of the conveyor device 30 and which in the proximity of an axis of rotation of the rotating conveyor elements 50 goes into a chute 58, the chute plate bottom 60 of which extends inclinedly with respect to the axis of rotation.

In operation the rotating conveyor elements 50 rotate in a counter-clockwise direction in relation to Figure 5. Waste material is engaged by a respective entrainment member 56 and when an entrainment member 56 moves downwardly in its downward movement beyond the horizontal, as a result of buoyancy forces, it slides in the direction of the chute 58. As a consequence of the chute bottom 60 extending inclinedly with respect to the axis of rotation of the rotating conveyor elements 50 the upwardly floating waste substances are conveyed in the conveyor direction into the next longitudinal portion of the rotating conveyor elements 50 until the rotating waste materials reach the end of the rotating conveyor elements, which is shown at top left in relation to Figure 5.

Besides the entrainment members 56 the rotating conveyor elements 50 have a plurality of entrainment plates 62 which project from the inside as far as the casing 40 of the conveyor device 30.

In the fourth longitudinal portion of the conveyor device 30 the rotating conveyor elements 50, instead of the entrainment plates, have a plurality of shafts with freely rotating toothed wheels 64 which are arranged thereon and which have an axis of rotation extending parallel to the axis of rotation of the rotating conveyor elements and which project to close to the casing 40 of the conveyor device 30. The wheels 64 are suitable for comminuting solid waste constituents which pass between the casing 40 of the conveyor device 30 and the wheels 64.

Finally Figure 6 shows a portion 70 of the cover 16, which covers the discharge chamber 38. In addition Figure 6 shows the bladed wheel 46 and the second electric drive 20 for driving the bladed wheel 46. The bladed wheel 46 is arranged in such a way that it passes over the bottom 72 of the discharge chamber 38. The bottom 72 of the discharge chamber 38 is disposed exactly at the level of the surface of the liquid metal in the container 12. Upwardly floating solid waste residue materials which issue from the conveyor device 30 by way of the connection 36 therefrom float in the entry opening of the discharge chamber 38 on the surface of the liquid metal bath and can thus be engaged by the blades 48 of the bladed wheel 46 when the bladed wheel 46 rotates. The waste residues are thereby conveyed by the blades of the bladed wheel 46 to the residual material outlet opening 76 in the bottom 74 of the discharge chamber 38. The discharge chamber 38 is of a round configuration in plan, the diameter thereof corresponding to the width of the blades 48 of the bladed wheel 46. It will be appreciated by persons skilled in the art that numerous variations and/or modifications may be made to the invention as shown in the specific embodiments without departing from the scope of the invention as broadly described. The present embodiments are, therefore, to be considered in all respects as illustrative and not restrictive. Any discussion of documents, acts, materials, devices, articles or the like which has been included in the present specification is solely for the purpose of providing a context for the present invention. It is not to be taken as an admission that any or all of these matters form part of the prior art base or were common general knowledge in the field relevant to the present invention as it existed before the priority date of each claim of this application.

Throughout this specification the word "comprise", or variations such as "comprises" or "comprising", will be understood to imply the inclusion of a stated element, integer or step, or group of elements, integers or steps, but not the exclusion of any other element, integer or step, or group of elements, integers or steps.

Claims

CLAIMS:

1. An apparatus for the treatment of waste containing plastic material, comprising: a container which is closed except for inlets and outlets and which in operation is to be filled with a liquid metal bath up to a liquid metal level and has a gas space above the liquid metal level; a waste feed opening for waste to be treated; a residual material outlet opening for solid waste residues; a waste conveyor device which extends substantially horizontally between the waste feed opening and the residual material outlet opening and which is adapted to convey waste at least in portion- wise manner beneath the liquid metal level from the waste feed opening to the residual material outlet opening and in so doing to periodically immerse waste which floats upwardly deeper into the liquid metal bath; a gas feed line for an inert gas, which opens into the gas space; a gas outlet connected to the gas feed line by way of conduits to afford a gas circuit; a condenser arranged in the gas circuit for condensable gas constituents; a feed line opening into the condenser for a carrier liquid; and a liquid discharge line arranged in a base point of the condenser.

2. The apparatus according to claim 1, wherein the conveyor device is enclosed by its own casing within the container, a first portion of the conveyor device extending close to the waste feed opening in part above the liquid metal level, further portions of the conveyor device extending into the proximity of the residual material outlet opening beneath the liquid metal level.

3. The apparatus according to claim 1 or 2, wherein the conveyor device comprises a plurality of conveyor elements which are arranged around an at least approximately horizontally extending axis of rotation of the conveyor device.

4. The apparatus according to claim 3, wherein the conveyor elements of the conveyor device comprise rotationally moving, blade-like entrainment members which extend at least approximately to the casing of the conveyor device.

5. The apparatus according to claim 4, wherein the entrainment members of the conveyor device extend in a plane extending at least approximately parallel to the axis of rotation and transversely with respect to the direction of rotation.

6. The apparatus according to claim 1, wherein the conveyor elements comprise chutes which adjoin the entrainment members near the axis of rotation and comprise a chute bottom extending inclinedly with respect to the axis of rotation.

7. The apparatus according to claim 3, wherein the conveyor device further comprises entrainment plates which in comparison with the entrainment members are of a shorter extent in relation to the radial direction, are at a greater spacing relative to the axis of rotation, and also extend to close to the casing of the conveyor device.

8. The apparatus according to claim 2, wherein the casing of the conveyor device further comprises an opening at the end of the conveyor device in the proximity of the residual material outlet on its top side beneath the liquid material level, which opening opens into a discharge chamber whose flat bottom extends at the level of the surface of the liquid metal.

9. The apparatus according to claim 8, wherein the discharge chamber further comprises a rotating bladed wheel, the wheel comprising blades which extend to the bottom of the discharge chamber and to the edge of the discharge chamber.

10. A method of treating plastic material-containing WaSIe₁ comprising: introducing waste into a container containing a liquid metal bath and a gas atmosphere thereabove; immersing the waste into the liquid metal bath; conveying the waste within the liquid metal bath_α aad thereby producing thermolysis gas and solid residue materials; flushing the gas atmosphere with an inert gas; separating the thermolysis gas from the inert gas in a condenser; dissolving condensed pyrolysis gas in a carrier liquid; draining the carrier liquid and liquid condensed thermolysis products from the condenser, and removing remaining solid materials from the liquid metal bath.

11. The method according to claim 10, wherein the method is carried out continuously.

12. The method according to claim 10, wherein the carrier liquid comprises an oil or tuluol.

13. The method according to claim 10, wherein the liquid metal bath further comprises lime for binding chlorine.

14. The method according to claim 10, carried out at temperatures of between 450⁰C and 500⁰C.

15. The method according to claim 10, wherein the liquid metal bath comprises tin.

16. The method according to claim 10, wherein the residence time of waste to be treated in the liquid metal bath is about two minutes.

17. The method according to claim 10, wherein the waste to be treated is conveyed in the liquid metal bath in an at least approximately horizontal direction.