WO2008049821A2 - Method and apparatus for liquefying hydrocarbon streams - Google Patents
Method and apparatus for liquefying hydrocarbon streams Download PDFInfo
- Publication number
- WO2008049821A2 WO2008049821A2 PCT/EP2007/061316 EP2007061316W WO2008049821A2 WO 2008049821 A2 WO2008049821 A2 WO 2008049821A2 EP 2007061316 W EP2007061316 W EP 2007061316W WO 2008049821 A2 WO2008049821 A2 WO 2008049821A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- streams
- heat exchangers
- refrigerant
- hydrocarbon
- stream
- Prior art date
Links
- 229930195733 hydrocarbon Natural products 0.000 title claims abstract description 108
- 150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 108
- 239000004215 Carbon black (E152) Substances 0.000 title claims abstract description 105
- 238000000034 method Methods 0.000 title claims abstract description 37
- 239000003507 refrigerant Substances 0.000 claims abstract description 117
- 238000001816 cooling Methods 0.000 claims abstract description 76
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 70
- 239000003345 natural gas Substances 0.000 claims abstract description 25
- 238000011144 upstream manufacturing Methods 0.000 claims 1
- 239000007788 liquid Substances 0.000 description 15
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 10
- 239000003949 liquefied natural gas Substances 0.000 description 10
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 10
- 239000007789 gas Substances 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 229910001868 water Inorganic materials 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
- 239000001294 propane Substances 0.000 description 5
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 4
- 235000013844 butane Nutrition 0.000 description 4
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- 239000001273 butane Substances 0.000 description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
- 230000009977 dual effect Effects 0.000 description 2
- 239000002737 fuel gas Substances 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 238000005057 refrigeration Methods 0.000 description 2
- -1 H2O Chemical class 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 238000005215 recombination Methods 0.000 description 1
- 230000006798 recombination Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
- F25J1/0279—Compression of refrigerant or internal recycle fluid, e.g. kind of compressor, accumulator, suction drum etc.
- F25J1/0294—Multiple compressor casings/strings in parallel, e.g. split arrangement
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/0002—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
- F25J1/0022—Hydrocarbons, e.g. natural gas
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
- F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
- F25J1/0042—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by liquid expansion with extraction of work
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
- F25J1/0047—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle
- F25J1/0052—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle by vaporising a liquid refrigerant stream
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
- F25J1/0047—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle
- F25J1/0052—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle by vaporising a liquid refrigerant stream
- F25J1/0055—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle by vaporising a liquid refrigerant stream originating from an incorporated cascade
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
- F25J1/0047—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle
- F25J1/0052—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle by vaporising a liquid refrigerant stream
- F25J1/0057—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle by vaporising a liquid refrigerant stream after expansion of the liquid refrigerant stream with extraction of work
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0211—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle
- F25J1/0214—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle as a dual level refrigeration cascade with at least one MCR cycle
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
- F25J1/0257—Construction and layout of liquefaction equipments, e.g. valves, machines
- F25J1/0269—Arrangement of liquefaction units or equipments fulfilling the same process step, e.g. multiple "trains" concept
- F25J1/0271—Inter-connecting multiple cold equipments within or downstream of the cold box
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
- F25J1/0279—Compression of refrigerant or internal recycle fluid, e.g. kind of compressor, accumulator, suction drum etc.
- F25J1/0292—Refrigerant compression by cold or cryogenic suction of the refrigerant gas
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2220/00—Processes or apparatus involving steps for the removal of impurities
- F25J2220/60—Separating impurities from natural gas, e.g. mercury, cyclic hydrocarbons
- F25J2220/62—Separating low boiling components, e.g. He, H2, N2, Air
Definitions
- the present invention relates to a method and apparatus for liquefying at least two hydrocarbon streams, such as at least two natural gas streams.
- LNG liquefied natural gas
- natural gas comprising predominantly methane
- the purified gas is processed through a plurality of cooling stages using heat exchangers to progressively reduce its temperature until liquefaction is achieved.
- the liquid natural gas is then further cooled and expanded through one or more expansion stages to final atmospheric pressure suitable for storage and transportation.
- the flashed vapour from each expansion stage can be used as a source of plant fuel gas .
- US 6,272,882 Bl relates to a process of liquefying a gaseous, methane-enriched feed to obtain a liquefied product.
- the liquefaction process comprises a number of steps, one of which is to separate the partly-condensed refrigerant for the main heat exchanger into a liquid heavy refrigerant fraction and a gaseous light refrigerant fraction.
- At least part of the liquid refrigerant fraction is cooled, liquefied and sub-cooled against off-gas removed from a flash vessel used after the main heat exchanger.
- the process of US 6,272,882 Bl shows a single 'train' for liquefaction.
- US 6,389,844 Bl relates to a plant for liquefying natural gas. More specifically, a pre-cooled dual heat exchanger, dual refrigerant system.
- the plant in US 6,389,844 Bl has a liquefaction capacity which is 40 to 60% higher than that of a single liquefaction train, and comprises one pre-cooling heat exchanger, and at least two main heat exchangers.
- Each main heat exchanger uses a main refrigerant which is separated into a heavy liquid fraction and a light gaseous fraction which are only seen to be cooled in the main heat exchanger, prior to expansion.
- the present invention provides a method of liquefying at least two hydrocarbon streams, such as at least two natural gas streams, the method at least comprising the steps of: (a) providing at least first and second hydrocarbon streams;
- a refrigerant circuit provides cooling to the one or more first heat exchangers and the one or more second heat exchangers, by passing separate streams of refrigerant through the one or more first heat exchangers of step (b) and through the one or more second heat exchangers of step (c) .
- the separate refrigerant streams after respectively passing through the first heat exchanger (s) the second heat exchanger (s) and/or having exchanged heat with the respective hydrocarbon streams, may be compressed, either commonly or separately.
- the present invention provides an apparatus for liquefying at least two hydrocarbon streams, such as at least two natural gas streams, the apparatus at least comprising: one or more first heat exchangers to cool a first hydrocarbon stream and to provide a first cooled hydrocarbon stream; one or more second heat exchangers to cool a second hydrocarbon stream and to provide a second cooled hydrocarbon stream; at least one liquefaction system arranged to liquefy said first and second cooled hydrocarbon streams; and a refrigerant circuit comprising at least two separate streams of refrigerant one of which to provide cooling to the one or more first heat exchangers and the other one of which to provide cooling to the one or more second heat exchangers.
- the refrigerant circuit may further be provided with at least one compressor for compressing the refrigerant streams, either commonly or separately, after having provided their cooling to the first and second heat exchanger ( s ) .
- the refrigerant circuit may further be provided with one or more common coolers for commonly cooling the compressed refrigerant streams.
- Figure 1 is a generalised scheme of part of a liquefaction plant according to one embodiment of the present invention.
- FIG. 2 is a more detailed scheme of the liquefaction plant in Figure 1.
- Described herein are methods and apparatuses wherein two hydrocarbon streams are cooled against a refrigerant in a refrigerant circuit, by passing a stream of the refrigerant through one or more first heat exchangers and passing a separate stream of the refrigerant through one or more second heat exchangers and subsequently compressing the separate streams of the refrigerant using at least one compressor.
- a reduction in the capital costs and running costs can be provided by commonality of elements and features in a single refrigerant circuit serving the different heat exchangers for the two hydrocarbon streams.
- the refrigerant circuit may involve any number of separate lines or streams of refrigerant to cool different hydrocarbon streams, and any number of common elements or features, including compressors, coolers, etc. Some refrigerant streams may be common and some may be separate.
- the first and second heat exchangers may be separate, and any alteration in existing first and second heat exchanger arrangements can be avoided to effect the invention .
- Embodiments of the invention comprise common cooling of two or more compressed refrigerant streams.
- the compressed refrigerant streams may be combined for commonly cooling through the one or more common coolers.
- the common or combined cooling will involve the refrigerant of the refrigeration circuit being condensed.
- the common cooling equates to common heat rejection from the separate refrigerant streams after their compression.
- One or more other coolers, being separate or integrated, may also be involved or associated with the compressors as is known in the art.
- the present invention can reduce the overall energy requirements of a method or plant or apparatus for treating, in particular liquefying, a hydrocarbon stream, and/or make the method, plant or apparatus more efficient and so more economical.
- the refrigerant of the refrigerant circuit may be a single component such as propane.
- propane Preferably it is a mixed refrigerant based on two or more components, said components preferably selected from the group comprising nitrogen, methane, ethane, ethylene, propane, propylene, butane and pentane .
- a first hydrocarbon stream is passed through one or more first heat exchangers to provide a first cooled hydrocarbon stream
- a second hydrocarbon stream is passed through one or more second heat exchangers to provide a second cooled hydrocarbon stream.
- each of the steps (b) and (c) comprises passing the hydrocarbon stream through 2, 3, 4 or 5 first and second heat exchangers, preferably two first heat exchangers and two second heat exchangers.
- the first and second cooled hydrocarbon streams could be further treated, for example liquefied.
- the first and second hydrocarbon streams are feed streams, preferably provided from a single feed stream. Where the first and second hydrocarbon streams are provided in this way, they may be equally or unequally divided; preferably they are the same.
- the feed stream can be divided by any suitable divider, stream splitter, or similar known in the art.
- a feed stream or streams can be liquefied by passing it through at least two cooling stages. Any number of cooling stages can be used, and each cooling stage can involve one or more heat exchangers, as well as optionally one or more steps, levels or sections . Each cooling stage may involve two or more heat exchangers either in series, or in parallel, or a combination of same.
- this involves the two cooling stages comprising a first cooling stage and a second cooling stage, the first stage being preferably a pre- cooling stage to cool below 0 0 C, and the second stage preferably being a main cryogenic stage to liquefy below -100 0 C.
- the method of treating hydrocarbon streams is part of a method of liquefying a hydrocarbon stream such as natural gas from a feed stream, wherein the method of treating comprises a first cooling stage, and there is a subsequent second cooling stage for liquefying the first and second cooled hydrocarbon streams .
- the hydrocarbon streams may be any suitable hydrocarbon-containing streams to be liquefied, but they are usually from a natural gas stream obtained from natural gas or petroleum reservoirs.
- the natural gas stream may also be obtained from another source, also including a synthetic source such as a Fischer-Tropsch process.
- natural gas is comprised substantially of methane.
- the feed stream comprises at least 60 mol% methane, more preferably at least 80 mol% methane .
- the natural gas may contain varying amounts of hydrocarbons heavier than methane such as ethane, propane, butanes and pentanes as well as some aromatic hydrocarbons.
- the natural gas stream may also contain non-hydrocarbons such as H2O, N2, CO2, H2S and other sulfur compounds, and the like.
- the hydrocarbon streams may be pre-treated before using them in the present invention.
- This pre-treatment may comprise removal of any undesired components present such as CO2 and H2S, or other steps such as pre-cooling, pre-pressurizing or the like. As these steps are well known to the person skilled in the art, they are not further discussed here.
- the method according to the present invention is applicable to various hydrocarbon feed streams, it is particularly suitable for natural gas streams to be liquefied. As the person skilled readily understands how to liquefy a hydrocarbon stream, this is not further discussed in detail herein.
- the liquefied natural gas may be further processed, if desired.
- the obtained LNG may be depressurized by means of a
- Joule-Thomson valve or by means of a cryogenic turbo- expander may involve one or more other or further refrigerant circuits, for example in or passing through a first cooling stage. Any other or further refrigerant circuits could optionally be connected with and/or concurrent with the refrigerant circuit for cooling the first and second hydrocarbon streams .
- Figure 1 shows a general arrangement of part of a liquefied natural gas (LNG) plant. It shows an initial feed stream 10 containing natural gas.
- natural gas usually includes some heavier hydrocarbons and impurities, e.g. carbon dioxide, nitrogen, helium, water and non-hydrocarbon acid gases.
- the feed stream 10 has usually been pre-treated to separate out these impurities as far as possible, and to provide a purified feed stock suitable for liquefying at cryogenic temperatures.
- the feed stream 10 is divided by a stream splitter 15 to provide first and second hydrocarbon streams 20, 20a prior to a first cooling stage 2.
- the feed stream 10 may be divided into any number of hydrocarbon streams, and Figure 1 shows the division into two hydrocarbon streams by way of preferred example only.
- the division of the feed stream 10 could be based on any ratio of mass and/or volume and/or flow rate.
- the ratio may be based on the size or capacity of the subsequent parts of the liquefaction stages or systems or units, or due to other considerations.
- One example of the ratio is an equal division of the feed stream mass.
- the first hydrocarbon stream 20 passes through a first set of two first heat exchangers 12, 14 to provide a first cooled hydrocarbon stream 30.
- the second hydrocarbon stream 20a passes through a second set of second heat exchangers 12a, 14a, which may be identical or different to the first set of first heat exchangers 12, 14, to provide a second cooled hydrocarbon stream 30a.
- the first heat exchangers 12, 14, and second heat exchangers 12a, 14a are provided with cooling by a first refrigerant circuit 100.
- the first refrigerant circuit 100 has two refrigerant streams 101 and 101a which separately cool the first heat exchangers 12, 14 and second heat exchangers 12a, 14a respectively.
- the refrigerant streams 101, 101a are passed into one or more separate compressors 32, 32a, before the compressed refrigerant streams 101d, lOle are combined to provide a single stream 101f for common heat rejection.
- the single stream 101f passes through one or more common water and/or air coolers, two of which coolers 34, 34a are shown in Figure 1.
- the (usually) condensed refrigerant stream 101g is then divided to provide the separate refrigerant streams 101, 101a for cooling.
- the first cooling stage 2 may comprise any number of heat exchangers for each hydrocarbon stream, and the feed stream 10 may be divided into more than two hydrocarbon streams .
- the first cooling stage 2 will generally cool the first and second hydrocarbon streams 20,20a to a temperature below 0 0 C, and preferably between -20 0 C to -60 0 C.
- the first and second cooled hydrocarbon streams 30, 30a pass through a second cooling stage 4, wherein they are liquefied by two separate liquefaction systems, each generally including at least one heat exchanger respectively, to provide separate liquefied streams 40, 40a respectively.
- Liquefaction systems and process conditions for liquefaction are well known in the art, and are not described further herein.
- the two liquefaction systems are symbolically represented by liquefaction heat exchangers 16 and 16a. These are also heat exchangers, but they are referred to as liquefaction heat exchangers merely in order to label them differently (by their function) from the first and second heat exchangers discussed hereinabove.
- Each of the liquefaction heat exchangers 16, 16a in the second cooling stage 4 of the example shown in Figure 1 uses a refrigerant circuit: the first liquefaction heat exchanger 16 uses a first refrigerant circuit 102, and the second liquefaction heat exchanger 16a uses a second refrigerant circuit 103.
- Each of these refrigerant circuits 102, 103 may use the same or different refrigerants.
- each uses the same refrigerant, and more preferably the refrigerant for each of the refrigerant circuits 102, 103 is a mixed refrigerant.
- the mixed refrigerant may be based on two or more components, preferably selected from the group comprising nitrogen, methane, ethane, ethylene, propane, propylene, butane and pentane .
- the first and second cooled hydrocarbon streams 30, 30a are cooled by the second cooling stage 4 to a temperature of at least below -100 0 C.
- the liquefied streams 40 and 40a are then combined. They may be combined in any known manner, and in any known combination of steps . Such combination of streams may be prior to or after any expansion of any of the liquefied streams 40, 40a.
- the combining of the liquefied streams may not require full integration or mixing for their subsequent passage through a gas/liquid separator. Preferably the streams are combined before passing through a gas/liquid separator.
- FIG. 1 Arrangements for combining streams are known to the person skilled in the art.
- the example arrangement shown in Figure 1 is for the combination of the liquefied streams 40, 40a using a combiner 18 known in the art, to provide a combined liquefied hydrocarbon stream 50.
- the combiner may be any suitable arrangement, generally involving a union or junction or piping or conduits, optionally involving one or more valves.
- the combined liquefied hydrocarbon stream 50 provided by the second cooling stage 4 can pass through a flash valve (not shown) and then on to a gas/liquid separator such as an end flash vessel 22, wherein the liquid stream is generally recovered as a liquefied hydrocarbon product stream 60, and the vapour is provided as a gaseous stream 70.
- the liquefied hydrocarbon stream 60 is then sent by one or more pumps (not shown) to storage and/or transportation facilities.
- Figure 2 shows a more detailed scheme of the embodiment of the present invention shown in Figure 1, wherein the feed stream 10 is divided into the first and second hydrocarbon streams 20a, 20b, which pass through the two separate but parallel and identical sets of first heat exchangers, 12, 14, and second heat exchangers 12a, 14a, as the first cooling stage 2.
- Both the sets of first and second heat exchangers 12, 14, 12a, 14a are provided with cooling by the one refrigerant circuit 100.
- the first refrigerant circuit 100 has the two refrigerant lines 101 and 101a which separately cool the first set of first heat exchangers 12, 14 at two different pressure levels in a manner known in the art, and cool the second set of second heat exchangers 12a, 14a at two different pressure levels in a manner known in the art, respectively.
- the refrigerant streams 101, 101a are passed into two sets of compressors 36 and 36a respectively.
- Each stream of compressed refrigerant is passed through separate water and/or air coolers 38, 38a respectively, and then combined to form a single refrigerant stream 101f.
- the separate coolers 38, 38a also provide cooling of the compressors 36, 36a in their recycle operation.
- the single refrigerant stream 101f then passes through a large water and/or air cooler 34, where the majority of the heat in the refrigerant is exchanged by being rejected to ambient, as condensation of the refrigerant takes place.
- the refrigerant then passes into an accumulator 42 known in the art. From the accumulator 42, a stream of refrigerant passes through a final and usually smaller water and/or air cooler 34a before being divided into the two refrigerant lines 101 and 101a.
- the large cooler 34 provides the same level of cooling as prior art coolers of separate refrigerant circuits used hitherto fro cooling two hydrocarbon streams.
- the cooling of the refrigerant in the first refrigerant circuit 100 is or need be carried out by a common cooling unit or units, such as the large cooler 34.
- the separate coolers 38 and 38a will provide some initial cooling, although they are dedicated to their compressors 36 and 36a to enable their recycling of gas in a manner known in the art.
- the ratio of cooling power of the large (and common) cooler 34 compared to the cooling power of the compressor coolers 38 and 38a can be from 5:1 up to 20:1 or more; but preferably approximately a 10:1 ratio.
- At least the majority of the cooling of the refrigerant in the refrigerant circuit 100 is provided by a common cooler or coolers after recombination of all the separate refrigerant streams (after their provision of cooling to the hydrocarbon streams in the relevant heat exchangers) .
- the arrangement of the first refrigeration circuit 100 in Figures 1 and 2 simplifies the cooling provided to one heat exchanger, or some of the heat exchangers or all of the heat exchangers, of the first cooling stage 2, or any cooling stage, configuration or arrangement.
- the arrangements shown in Figures 1 and 2 reduce the number of water and/or air units and accumulators required in a first refrigerant circuit 100, which can nevertheless still provide two refrigerant streams for separate sets of heat exchangers. It may be possible to further reduce the number of features regarding the first refrigerant circuit 100 by further combination of coolers, valves and/or compressors, in order to further reduce the capital and running costs of the first refrigerant circuit 100 and/or the first cooling stage 2.
- the liquefaction heat exchangers 16, 16a of the second cooling stage 4 are preferably spool-wound or spiral-wound cryogenic heat exchangers, whose operation is known in the art and whose cooling is provided by the second and third refrigerant circuits 102, 103 respectively .
- Each of the liquefaction heat exchangers 16, 16a provides a liquefied hydrocarbon stream 40, 40a, which streams 40, 40a are then combined into a combined liquefied hydrocarbon stream 50.
- the cooled combined liquefied hydrocarbon stream 50a passes through an expander, and into a gas/liquid separator, being an end flash vessel 22 known in the art.
- a liquefied hydrocarbon product stream 60 which can then be passed along by a pump 26 to storage and/or transportation, and a gaseous stream 70, which after any heat exchange, may be used as a fuel gas, and/or used in other parts of the LNG plant.
- the first, second and third refrigerant circuits 100, 102, 103 preferably use a mixed refrigerant.
- the second and third refrigerant circuits 102 and 103 preferably use the same mixed refrigerant .
- the mixed refrigerant of each refrigerant circuit may be based on two or more components, more preferably selected from the group comprising nitrogen, methane, ethane, ethylene, propane, propylene, butane and pentane.
- the average molar weight of the refrigerant in the first refrigerant circuit 100 is preferably higher than the average molar weight of refrigerant in the second and third refrigerant circuits 102 and 103.
- a stream 102e of vapourised refrigerant is provided, and compressed and cooled by two compressors and two water or air coolers, to provide a cooled refrigerant stream 102a.
- This cooled refrigerant stream 102a then passes through the set of two heat exchangers 12, 14 of one part of the first cooling stage 2, which provides some cooling to the second refrigerant.
- This further cooled refrigerant stream 102b is then passed into a gas/liquid separator 46.
- the separator 46 provides a light refrigerant fraction 102c, and a heavy refrigerant fraction 102d, which both pass into the liquefaction heat exchanger 16 to be cooled and expanded to use their cold energy in the liquefaction heat exchanger 16 in a manner known in the art.
- Table 1 gives a representative working example of temperatures, pressures and flows of streams at various parts an example process of the present invention referring to Figure 2.
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Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
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US12/446,543 US20100319396A1 (en) | 2006-10-23 | 2007-10-23 | Method and apparatus for liquefying hydrocarbon streams |
AU2007310940A AU2007310940B2 (en) | 2006-10-23 | 2007-10-23 | Method and apparatus for liquefying hydrocarbon streams |
JP2009532826A JP2010507771A (en) | 2006-10-23 | 2007-10-23 | Method and apparatus for liquefying a hydrocarbon stream |
EP07821680A EP2104824A2 (en) | 2006-10-23 | 2007-10-23 | Method and apparatus for cooling hydrocarbon streams |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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EP06122725.2 | 2006-10-23 | ||
EP06122725 | 2006-10-23 |
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WO2008049821A2 true WO2008049821A2 (en) | 2008-05-02 |
WO2008049821A3 WO2008049821A3 (en) | 2009-08-13 |
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PCT/EP2007/061316 WO2008049821A2 (en) | 2006-10-23 | 2007-10-23 | Method and apparatus for liquefying hydrocarbon streams |
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US (1) | US20100319396A1 (en) |
EP (1) | EP2104824A2 (en) |
JP (1) | JP2010507771A (en) |
AU (1) | AU2007310940B2 (en) |
RU (1) | RU2463535C2 (en) |
WO (1) | WO2008049821A2 (en) |
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US9046302B2 (en) * | 2009-10-27 | 2015-06-02 | Shell Oil Company | Apparatus and method for cooling and liquefying a fluid |
US10030908B2 (en) * | 2010-08-16 | 2018-07-24 | Korea Gas Corporation | Natural gas liquefaction process |
AU2014320450B2 (en) * | 2013-09-13 | 2017-09-21 | Shell Internationale Research Maatschappij B.V. | Natural gas liquefaction system and method of producing a liquefied natural gas stream |
US20150153100A1 (en) * | 2013-12-04 | 2015-06-04 | General Electric Company | System and method for hybrid refrigeration gas liquefaction |
JP2017032146A (en) * | 2014-01-31 | 2017-02-09 | 日揮株式会社 | Liquefaction gas manufacturing facility and liquefaction gas manufacturing method |
US20190162468A1 (en) * | 2017-11-27 | 2019-05-30 | Air Products And Chemicals, Inc. | Method and system for cooling a hydrocarbon stream |
GB201708514D0 (en) * | 2017-05-26 | 2017-07-12 | Bp Exploration Operating | Systems and methods for liquefaction of a gas with the aid of an end flash system |
EP3728971A1 (en) | 2017-12-22 | 2020-10-28 | ExxonMobil Upstream Research Company | System and method of de-bottlenecking lng trains |
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- 2007-10-23 WO PCT/EP2007/061316 patent/WO2008049821A2/en active Application Filing
- 2007-10-23 AU AU2007310940A patent/AU2007310940B2/en active Active
- 2007-10-23 JP JP2009532826A patent/JP2010507771A/en active Pending
- 2007-10-23 US US12/446,543 patent/US20100319396A1/en not_active Abandoned
- 2007-10-23 EP EP07821680A patent/EP2104824A2/en not_active Withdrawn
- 2007-10-23 RU RU2009119472/06A patent/RU2463535C2/en active
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WO2008049821A3 (en) | 2009-08-13 |
EP2104824A2 (en) | 2009-09-30 |
AU2007310940B2 (en) | 2010-11-11 |
AU2007310940A1 (en) | 2008-05-02 |
US20100319396A1 (en) | 2010-12-23 |
RU2009119472A (en) | 2010-11-27 |
RU2463535C2 (en) | 2012-10-10 |
JP2010507771A (en) | 2010-03-11 |
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