WO2007042085A1

WO2007042085A1 - Stabilisation of water-insoluble silicones

Info

Publication number: WO2007042085A1
Application number: PCT/EP2006/005705
Authority: WO
Inventors: Thomas Schröder; Dieter Goddinger; Hedwig Retzer
Original assignee: Henkel Kommanditgesellschaft Auf Aktien
Priority date: 2005-10-13
Filing date: 2006-06-14
Publication date: 2007-04-19
Also published as: DE102005049493A1

Abstract

Surfactant-containing cleaning products are described, containing a combination of active substances including (a) a washing base which contains at least one anionic surfactant, (b) a water-insoluble silicone, and (c) hardened castor oil in a weight ratio of (a):(b):(c) of (10-150) : (1.0-40): 1, in order to stabilise a water-insoluble silicone component. The stabilisation of the silicone component with hardened castor oil ensures a thorough and gentle cleaning of skin and/or hair, a stable silicone dispersion without phase separation, changes in viscosity or reduction in the foaming power during storage, and makes it possible to dispense with additional stabilisation of the compositions by means of gelling agents.

Description

"Stabilization of water-insoluble silicones"

The invention relates to surfactant-containing cleaning compositions which comprise a special combination of active substances for stabilizing a water-insoluble silicone component, and to a method for stabilizing water-insoluble silicone components in surfactant-containing formulations

Skin and hair cleansers, such as those commercially available as liquid soaps, shampoos, shower baths, bubble baths, shower gels, and wash gels, must not only have good irritability, but should also be well tolerated by the skin and mucous membranes if used frequently, do not cause excessive defatting or skin dryness

Usually, skin and hair cleansers are formulated based on anionic, nonionic and / or amphoteric surfactants, but most preferably on the basis of anionic surfactants. Although such compositions have a good washability, the cosmetic properties associated with them are inadequate. in particular due to the removal of skin and hair own lipids and proteins from the skin or the hair surface

In order to improve the cosmetic properties of the said cleaning agents, so-called conditioning agents were therefore additionally incorporated in the cleaning agents in the past. These are intended to compensate for or limit the harmful or undesired effects of formulations rich in surfactants. In addition, the conditioners should improve the natural cosmetic properties of the hair

For this purpose, water-insoluble oil and fat components, in particular water-insoluble silicone components, have been proposed as conditioning components. However, their incorporation into a cosmetically suitable, generally aqueous medium is problematic when using these highly effective insoluble components. Typically, these components typically have the disadvantage that they are present in one wassπgen medium difficult to keep in dispersion

To overcome these difficulties, the use of long-chain ester or Etherdenvate (as a dispersant) (EP 181 773) or polysaccharides, such as xanthan gum, (as gelling agent) (EP 190 010) has already been proposed to stable dispersion of water-insoluble particles in a wassπgen medium to keep

However, the use of the ester derivatives as dispersants is problematic due to crystallization, which over time causes an undesirable increase in the viscosity of the compositions The use of gelling agents also has disadvantages, since they can have a negative effect on the foam formation.

The object of the present invention was therefore to produce a surfactant-containing cleaning agent which ensures a thorough and gentle cleaning of the skin and / or the hair by the content of at least one water-insoluble silicone conditioning component, and by application of a stable dispersion of the conditioning without occurrence of the abovementioned disadvantages distinguished. Optimally, it should be possible to dispense with additional stabilization of the compositions by the additional use of gelling agents.

This object has been achieved by the provision of a surfactant-containing cleaning agent which comprises a combination of a) a washing base containing at least one anionic surfactant, b) a water-insoluble silicone and c) hardened castor oil in a weight ratio of the components a) to stabilize a water-insoluble silicone component ): c) of (10 - 150): (1, 0 - 40): 1.

It has been found that the stabilizing effect of the hardened castor oil makes it possible to completely eliminate additional stabilization of the silicone component in the cleaning compositions (for example, by the gelling agents mentioned above).

According to the invention, preference is given to detergents which comprise as wash base a mixture of at least one anionic surfactant with an amphoteric and / or zwitterionic and / or a nonionic surfactant.

The total surfactant content in the washing base is 5 to 35%, preferably 7 to 25% and in particular 8 to 15%, based on the total weight of the cleaning agent.

Suitable anionic surfactants in preparations according to the invention are all anionic surfactants suitable for use on the human body. These are characterized by a water-solubilizing, anionic group such as. As a carboxylate, sulfate, sulfonate or phosphate group and a lipophilic alkyl group having about 8 to 30 carbon atoms. In addition, glycol or polyglycol ether groups, ester, ether and amide groups and hydroxyl groups may be present in the molecule. Examples of suitable anionic surfactants are, in each case in the form of the sodium, potassium and ammonium as well as the mono-, di- and trialkanolammonium salts having 2 to 4 C atoms in the alkanol group, linear and branched fatty acids having 8 to 30 C atoms (Soap),

Ethercarbonsäuren the formula RO- (CH2-CH2θ) _χ -CH2-COOH, in which R is a linear alkyl group having 8 to 30 carbon atoms and x = 0 or 1 to 16, acylsarcosides having 8 to 24 carbon atoms in the acyl group . Acyltaurides having 8 to 24 C atoms in the acyl group, acyl isethionates having 8 to 24 C atoms in the acyl group,

Suϊfobernsteinsäuremono- and dialkyl esters having 8 to 24 carbon atoms in the alkyl group and sulfosuccinic monoalkylpolyoxyethylester having 8 to 24 carbon atoms in the alkyl group and 1 to 6 oxyethyl groups, linear alkanesulfonates having 8 to 24 carbon atoms, linear alpha-olefinsulfonates with 8 to 24 carbon atoms, alpha-sulfofatty acid methyl esters of fatty acids having 8 to 30 carbon atoms, alkyl sulfates and Alkylpolyglykolethersulfate the formula RO (CH ₂ -CH ₂ O) _x -OSO ₃ H, in the R is a preferably linear alkyl group with 8 bis 30 C-atoms and x = 0 or 1 to 12, mixtures of surface-active hydroxysulfonates according to DE-A-37 25 030, sulfated hydroxyalkylpolyethylene and / or hydroxyalkylene-propylene glycol ethers according to DE-A-37 23 354,

Sulfonates of unsaturated fatty acids having 8 to 24 carbon atoms and 1 to 6 double bonds according to DE-A-39 26 344,

Esters of tartaric acid and citric acid with alcohols which are addition products of about 2-15 molecules of ethylene oxide and / or propylene oxide onto fatty alcohols having 8 to 22 C atoms, alkyl and / or alkenyl ether phosphates of the formula (II),

O R ⁶ (OCH ₂ CH ₂ ) nOP-OR 7 (II) όx in the R ^{6 is} preferably an aliphatic hydrocarbon radical having 8 to 30 carbon atoms, R ^{7 is} hydrogen, a radical (CH ₂ CH ₂ O) _n R ⁶ or X, n is from 1 to 10 and X is hydrogen, an alkali or alkaline earth metal or NR ⁸ R ⁹ R ¹⁰ R ¹¹ , where R ⁸ to R ¹¹ independently of one another are a C 1 to C ₄ hydrocarbon radical, sulfated fatty acid alkylene glycol esters of Formula (III),

Ri 2 CO (AlkO) _n SO ₃ M (III) in the R ¹² CO- for a linear or branched, aliphatic, saturated and / or unsaturated acyl radical having 6 to 22 C atoms, Alk for CH ₂ CH ₂ , CHCH ₃ CH ₂ and / or CH ₂ CHCH ₃ , n is a number from 0.5 to 5 and M is a cation, as described in DE-OS 197 36 906.5,

Monoglyceride sulfates and monoglyceride ether sulfates of the formula (IV), as described, for example, in EP-B1 0 561 825, EP-B1 0 561 999, DE-A1 42 04 700 or A.K.Biswas et al. in J.Am.Oil. Chem. Soc. 37, 171 (1960) and F.U. Ahmed in J.Am.Oil.Chem.Soc. 67, 8 (1990),

CH ₂ O (CH ₂ CH ₂ O) _X -CORIS CHO (CH ₂ CH ₂ O) _y H (IV)

CH ₂ O (CH ₂ CH ₂ O) ₂ -SO ₃ X in which R ¹³ CO is a linear or branched acyl radical having 6 to 22 carbon atoms, x, y and z are in total 0 or numbers of 1 to 30, preferably 2 to 10, and X is an alkali or alkaline earth metal. Typical examples of monoglyceride (ether) sulfates suitable for the purposes of the invention are the reaction products of lauric acid monoglyceride, coconut fatty acid monoglyceride, palmitic acid monoglyceride, stearic acid monoglyceride, oleic acid monoglyceride and tallow fatty acid monoglyceride and their ethylene oxide adducts with sulfur trioxide or chlorosulfonic acid in the form of their sodium salts. Preference is given to using monoglyceride sulfates of the formula (VIII) in which R ¹³ CO is a linear acyl radical having 8 to 18 carbon atoms.

Preferred anionic surfactants are alkyl sulfates, alkyl polyglycol ether sulfates and ether carboxylic acid salts having from 10 to 18 carbon atoms in the alkyl group and up to 12 glycol ether groups in the molecule and sulfosuccinic acid mono- and dialkyl esters having 8 to 18 carbon atoms in the alkyl group and sulfosuccinic acid mono-alkyl polyoxyethyl esters having 8 to 18 C atoms in the alkyl group and 1 to 6 oxyethyl groups.

Particularly preferred anionic surfactants are the alkali metal or ammonium salts of lauryl ether sulfate having a degree of ethoxylation of 2 to 4 EO.

Zwitterionic surfactants are those surface-active compounds which carry at least one quaternary ammonium group and at least one -COO ^H or -SO ₃ '^"' group in the molecule: Particularly suitable zwitterionic surfactants are the so-called betaines such as N-alkyl-N, N-dimethylammonium glycinates, for example Kokosalkyldimethylammoniumglycinat, N-acyl-aminopropyl-N, N-dimethylammoniumglycinate, for example Kokosacylaminopropyl- dimethylammoniumglycinat, and 2-alkyl-3-carboxymethyl-3-hydroxyethyl-imidazolines each having 8 to 18 carbon atoms in the A preferred zwitterionic surfactant is the fatty acid amide derivative known by the INCI name Cocamidopropyl Betaine.

Amphoteric surfactants are to be understood as meaning those surface-active compounds which, apart from a C ₈ -C ₂₄ -alkyl or -acyl group in the molecule, contain at least one free amino group and at least one -COOH or -SO ₃ H group and are capable of forming internal salts , Examples of suitable ampholytic surfactants are N-alkylglycines, N-alkylpropionic acids, N-alkylaminobutyric acids, N-alkyliminodipropionic acids, N-hydroxyethyl-N-alkylamidopropylglycines, N-alkyltaurines, N-alkylsarcosines, 2-alkylaminopropionic acids and alkylaminoacetic acids each having about 8 to 24 C atoms in the alkyl group. Particularly preferred ampholytic surfactants are N-cocoalkylaminopropionate, cocoacylaminoethylaminopropionate and C ₁₂ -C ₁₈ acylsarcosine. Nonionic surfactants contain as hydrophilic group z. A polyol group, a polyalkylene glycol ether group or a combination of polyol and polyglycol ether groups. Such compounds are, for example

- Addition products of 2 to 50 moles of ethylene oxide and / or 0 to 5 moles of propylene oxide to linear and branched fatty alcohols having 8 to 30 carbon atoms, to fatty acids having 8 to 30 carbon atoms and to alkylphenols having 8 to 15 carbon atoms in the Alkyl group, with a methyl or C ₂ -C ₆ - alkyl radical endgruppenverschlossene addition products of 2 to 50 moles of ethylene oxide and / or 0 to 5 moles of propylene oxide to linear and branched fatty alcohols having 8 to 30 carbon atoms, to fatty acids having 8 to 30 C. Atoms and alkylphenols having 8 to 15 C

Atoms in the alkyl group, such as those available under the trade names Dehydol ^®

LS, Dehydrol® ^® LT (Cognis) available types,

Ci ₂ -C ₃ o fatty acid mono- and diesters of addition products of 1 to 30 moles of ethylene oxide

glycerin,

Addition products of from 5 to 60 mol of ethylene oxide onto castor oil and hydrogenated castor oil, for example castor oil-hydrogenated + 40 EO, as it is commercially available, for example, under the trade name Cremophor CO 455 from SHC,

Polyol fatty acid esters, such as the commercial product Hydagen ^® HSP (Cognis) or

Sovermol types (Cognis), alkoxylated triglycerides, alkoxylated fatty acid alkyl esters of the formula (V)

in the R -, 14 CO for a linear or branched, saturated and / or unsaturated acyl radical having 6 to 22 carbon atoms, R ¹⁵ for hydrogen or methyl, R ¹⁶ for linear or branched alkyl radicals having 1 to 4 carbon atoms and w for numbers of 1 to 20, amine oxides,

Hydroxy mixed ethers, as described, for example, in DE-OS 19738866, sorbitan fatty acid esters and addition products of ethylene oxide onto sorbitan fatty acid esters, for example the polysorbates,

Sugar fatty acid esters and addition products of ethylene oxide with sugar fatty acid esters, addition products of ethylene oxide onto fatty acid alkanolamides and fatty amines, fatty acid N-alkylglucamides,

Alkyl polyglycosides corresponding to the general formula RO- (Z) _x where R is alkyl, Z is sugar and x is the number of sugar units. The alkyl polyglycosides which can be used according to the invention can only contain one particular alkyl radical R. Usually, however, these compounds are prepared starting from natural fats and oils or mineral oils. In this case, the alkyl radicals R are mixtures corresponding to the starting compounds or corresponding to the particular work-up of these compounds. Particularly preferred are those alkyl polyglycosides in which R

essentially of C ₈ - and C ₁₀ alkyl groups, mainly of C ₁₂ - and C ₁₄ alkyl groups, essentially of C ₈ - to C ₆ -alkyl or substantially of C ₂ - to C ₁₆ -alkyl or substantially from Ci ₆ to C ₁₈ alkyl groups.

As sugar building block Z it is possible to use any desired mono- or oligosaccharides. Usually, sugars with 5 or 6 carbon atoms and the corresponding oligosaccharides are used. Such sugars are, for example, glucose, fructose, galactose, arabinose, ribose, xylose, lyxose, allose, altrose, mannose, gulose, idose, talose and sucrose. Preferred sugar building blocks are glucose, fructose, galactose, arabinose and sucrose; Glucose is particularly preferred.

The alkyl polyglycosides which can be used according to the invention contain on average from 1.1 to 5 sugar units. Alkyl polyglycosides having x values of 1.1 to 2.0 are preferred. Very particular preference is given to alkyl glycosides in which x is 1: 1 to 1, 8.

The alkoxylated homologs of said alkyl polyglycosides can also be used according to the invention. These homologs may contain on average up to 10 ethylene oxide and / or propylene oxide units per alkyl glycoside unit.

The preferred nonionic surfactants are the alkylene oxide addition products of saturated linear fatty alcohols and fatty acids having in each case 2 to 30 moles of ethylene oxide per mole of fatty alcohol or fatty acid. Preparations having excellent properties are also obtained if they contain fatty acid esters of ethoxylated glycerol as nonionic surfactants.

These connections are identified by the following parameters. The alkyl radical R contains 6 to 22 carbon atoms and may be both linear and branched. Preference is given to primary linear and methyl-branched in the 2-position aliphatic radicals. Such alkyl radicals are, for example, 1-octyl, 1-decyl, 1-lauryl, 1-myristyl, 1-cetyl and 1-stearyl. Particularly preferred are 1-octyl, 1-decyl, 1-lauryl, 1-myristyl. When using so-called "oxo-alcohols" as starting materials, compounds with an odd number of carbon atoms in the alkyl chain predominate.

The compounds used as surfactant with alkyl groups may each be uniform substances. However, it is generally preferred to use native vegetable or animal raw materials in the production of these substances, so that substance mixtures having different alkyl chain lengths depending on the respective raw material are obtained. In the case of the surfactants which are adducts of ethylene oxide and / or propylene oxide with fatty alcohols or derivatives of these addition products, both products with a "normal" homolog distribution and those with a narrow homolog distribution can be used. By "normal" homolog distribution are meant mixtures of homologues which are obtained in the reaction of fatty alcohol and alkylene oxide using alkali metals, alkali metal hydroxides or alkali metal alcoholates as catalysts. Narrowed homolog distributions, on the other hand, are obtained when, for example, hydrotalcites, alkaline earth metal salts of ether carboxylic acids, alkaline earth metal oxides, hydroxides or alcoholates are used as catalysts. The use of products with narrow homolog distribution may be preferred.

According to a further embodiment of the invention, the surfactant-containing cleaning agents may further contain cationic surfactants of the quaternary ammonium compound type, the esterquats and the amidoamines.

Preferred quaternary ammonium compounds are ammonium halides, in particular chlorides and bromides, such as alkyltrimethylammonium chlorides, dialkyldimethylammonium chlorides and trialkyl methylammonium chlorides, eg. Cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, distearyldimethylammonium chloride, lauryldimethylammonium chloride, lauryldimethylbenzylammonium chloride and tricetylmethylammonium chloride, as well as the imidazolium compounds known under the INCI names Quaternium-27 and Quaternium-83. The long alkyl chains of the above-mentioned surfactants preferably have 10 to 18 carbon atoms.

Esterquats are known substances which contain both at least one ester function and at least one quaternary ammonium group as a structural element. Preferred ester quats are quaternized ester salts of fatty acids with thethanolamine, quaternized ester salts of fatty acids with diethanolalkylamines and quaternized ester salts of fatty acids with 1,2-dihydroxypropyldialkylamines. Such products are marketed under the trade names Stepantex® ^®, ^® and Dehyquart® Armocare® ^®. The products Armocare ^® VGH-70, a N, N-bis (2-palmitoyloxyethyl) dimethylammonium chloride, as well as Dehyquart ^® F-75, Dehyquart ^® C-4046, Dehyquart ^® L80 and Dehyquart ^® AU-35 are examples of such esterquats.

The alkylamidoamines are usually prepared by amidation of natural or synthetic fatty acids and fatty acid cuts with dialkylaminoamines. An inventively particularly suitable compound from this group is that available under the name Tegoamid ^® S 18 commercially stearamidopropyl dimethylamine.

The cationic surfactants are contained in the agents according to the invention preferably in amounts of 0.05 to 10 wt .-%, based on the total agent. Amounts of 0.1 to 5 wt .-% are particularly preferred. Another essential component in the detergents according to the invention is the water-insoluble silicone component.

According to the invention suitable silicones cause a variety of effects. For example, at the same time they influence the dry and wet combability, the grip of dry and wet hair and the shine. By the term silicones the skilled person understands several structures of organosilicon compounds.

Particularly suitable according to the invention are the so-called dimethicones. These may be both linear and branched as well as cyclic or cyclic and branched. Linear dimethicones can be represented by the following structural formula (S2 - 1):

(SiR ¹ ₃ ) - O - (SiR ² ₂ - O -) χ - (SiR ¹ ₃ ) (S2 - I)

Branched dimethicones can be represented by the structural formula (S2 - II):

R ²

I (SiR ¹ ₃ ) - O - (SiR ² ₂ - O -) _x - Si - O - (SiR ² ₂ - O -) _y - (SiR ¹ ₃ )

I

O - (SiR ² ₂ -O-) _z - (SiR ¹ ₃ )

The radicals R ¹ and R ² are each independently hydrogen, a methyl radical, a C ² to C 30 linear, saturated or unsaturated hydrocarbon radical, a phenyl radical and / or an aryl radical. Non-limiting examples of the groups represented by R ¹ and R ² include alkyl groups such as methyl, ethyl, propyl, isopropyl, butyl, isobutyl, pentyl, isopentyl, neopentyl, amyl, isoamyl, hexyl, isohexyl and the like; Alkenyl radicals such as vinyl, halovinyl, alkylvinyl, allyl, haloallyl, alkylallyl; Cycloalkyl radicals such as cyclobutyl, cyclopentyl, cyclohexyl and the like; Phenyl radicals, benzyl radicals, halohydrocarbon radicals such as 3-chloropropyl, 4-bromobutyl, 3,3,3-trifluoropropyl, chlorocyclohexyl, bromophenyl, chlorophenyl and the like, and sulfur containing radicals such as mercaptoethyl, mercaptopropyl, mercaptohexyl, mercaptophenyl and the like; Preferably, R ¹ and R ^{2 is} an alkyl radical containing from 1 to about 6 carbon atoms, and most preferably R ¹ and R ^{2 are} methyl. Examples of R ¹ include methylene, ethylene, propylene, hexamethylene, decamethylene, -CH ₂ CH (CH ₃ ) CH ₂ -, phenylene, naphthylene, -CH ₂ CH ₂ SCH ₂ CH ₂ -, -CH ₂ CH ₂ OCH ₂ - , - OCH ₂ CH ₂ -, -OCH ₂ CH ₂ CH ₂ -, -CH ₂ CH (CH ₃ ) C (O) OCH ₂ -, - (CH ₂ J ₃ CC (O) OCH ₂ CH ₂ -, - C ₆ H ₄ C ₆ H ₄ -, -C ₆ H ₄ CH ₂ C ₆ H ₄ -; and - (CH ₂ ) ₃ C (O) SCH ₂ CH ₂ - Preferred as R ¹ and R ² are methyl Particularly preferred among the C2 to C22 alkyl radicals are lauryl, stearyl and behenyl radicals The numbers x, y and z are integers and each independently run from 0 to 50,000. Particular preference is given in accordance with the invention to the linear polydialkylsiloxanes, the polyalkylaryl siloxanes, the polydiarylsiloxanes and / or the dihydroxypolydimethylsiloxanes.

The molecular weights of the dimethicones suitable according to the invention are between 1000 D and 10,000,000 D.

The viscosities of the present invention suitable dimethicones are usually between 0.01 and 10,000,000 cPs measured at 25 ⁰ C using a glass capillary viscometer according to the Dow Corning Corporate Test Method CTM 0004 of 20 July 1970. Preferred viscosities are between 0.1 and 5,000,000 cPs, completely particularly preferred viscosities are between 0.1 and 3,000,000 cps. The most preferred viscosity range of dimethicones is between 0.6 and 600,000 cps.

Of course, the teaching of the invention also includes that the dimethicones may already be present as an emulsion. In this case, the corresponding emulsion of the dimethicones can be prepared both after the preparation of the corresponding dimethicones from these and the usual methods of emulsification known to the person skilled in the art. For this purpose, both cationic, anionic, nonionic or zwitterionic surfactants and emulsifiers can be used as auxiliaries for the preparation of the corresponding emulsions. Of course, the emulsions of dimethicones can also be prepared directly by an emulsion polymerization process. Such methods are also well known to the person skilled in the art. For example, reference may be made to the Encyclopedia of Polymer Science and Engineering, Volume 15, Second Edition, pages 204 to 308, John Wiley & Sons, Inc. 1989. This reference is expressly incorporated herein by reference.

When the dimethicones of the invention are used as an emulsion, the droplet size of the emulsified particles according to the invention is 0.01 μm to 10000 μm, preferably 0.01 to 100 μm, very particularly preferably 0.01 to 20 μm and most preferably 0.01 to 10 microns. The particle size is determined by the method of light scattering.

If branched dimethicones are used, it is to be understood that the branching is greater than a random branching, which occurs by impurities of the respective monomers randomly. For the purposes of the present invention, branched dimethicones are therefore to be understood as meaning that the degree of branching is greater than 0.01%. Preferably, a degree of branching is greater than 0.1%, and most preferably greater than 0.5%. The degree of branching is determined from the ratio of unbranched monomers, that is, the amount of monofunctional siloxane, to the branching monomers, that is, the amount of tri- and tetrafunctional siloxanes. According to the invention, both low-branched and highly branched dimethicones can be very particularly preferred. The water-insoluble silicone component according to the invention is used in the cleaning compositions - based on their total weight - usually in an amount of 0.01 to 10%, preferably in an amount of 0.1 to 5% and in particular in an amount of 0.2 to 3% ,

A third mandatory component in the detergents of the invention is the hardened castor oil.

According to the invention, these are to the hydrogenated under the INCI name "Hydrogenated Castor OiI" castor oil, as it is available, for example from the company Cognis under the name Cutina HR ^® commercially.

The hydrogenated castor oil is used in the compositions according to the invention - based on their total weight - in an amount of 0.01 to 5%, preferably in an amount of 0.05 to 3% and in particular in an amount of 0.1 to 2% ,

In a particularly preferred embodiment of the invention, the surfactant-containing cleaning agents further comprise at least one cationic polymer.

Cationic polymers are polymers which have groups in the main and / or side chain which may be "temporary" or "permanent" cationic. According to the invention, "permanently cationic" refers to those polymers which have a cationic group independently of the pH of the agent These are generally polymers which contain a quaternary nitrogen atom, for example in the form of an ammonium group Preferred cationic groups are quaternary ammonium groups In particular those polymers in which the quaternary ammonium group is bonded via a C _1-4 hydrocarbon group to a polymer main chain built up from acrylic acid, methacrylic acid or derivatives thereof have proved to be particularly suitable Homopolymers of the general formula (IV)

R17

- [CH ₂ -C] _n X- (VI)

CO-O- (CH ₂ ) mN ⁺ Ri8Ri9R20

in which R ¹⁷ = -H or -CH _3, R ^18, R ¹⁹ and R ²⁰ are independently selected from Ci _-4 - alkyl, -alkenyl or -hydroxyalkyl groups, m = 1, 2, 3 or 4, n is a natural number and X ^"is a physiologically acceptable organic or inorganic anion, as well as copolymers consisting essentially of the monomer units listed in formula (III) and nonionic Monomer units are particularly preferred cationic polymers. In the context of these polymers, preference is given to those according to the invention for which at least one of the following conditions applies:

R ¹⁷ is a methyl group

R ¹⁸ , R ¹⁹ and R ²⁰ are methyl groups m has the value 2.

Suitable physiologically tolerated counterions X ^" are, for example, halide ions, sulfate ions, phosphate ions, methosulfate ions and organic ions such as lactate, citrate, tartrate and acetate ions, preference being given to halide ions, in particular chloride.

A suitable homopolymer is, if desired, crosslinked,

Poly (methacryloyloxyethylthmethylarnmonium chloride) with the INCI name Polyquaternium-37. If desired, the crosslinking can be carried out with the aid of poly olefinically unsaturated compounds, for example divinylbenzene, tetraallyloxyethane, methylenebisacrylamide, diallyl ether, polyallylpolyglyceryl ethers, or allyl ethers of sugars or sugar derivatives such as erythritol, pentaerythritol, arabitol, mannitol, sorbitol, sucrose or glucose. Methylenebisacrylamide is a preferred crosslinking agent.

The homopolymer is preferably used in the form of a nonaqueous polymer dispersion which should not have a polymer content of less than 30% by weight. Such polymer dispersions are available under the names Salcare ^® SC 95 (about 50% polymer content, additional components: mineral oil (INCI name: Mineral Oil) and tridecyl-polyoxypropylene-polyoxyethylene-ether (INCI name: PPG-1 trideceth-6) ) and Salcare ^® SC 96 (about 50% polymer content, additional components: mixture of diesters of propylene glycol with a mixture of caprylic and Caphnsäure (INCI name: propylene glycol Dicaprylate / Dicaprate) and tridecyl polyoxypropylene-polyoxyethylene-ether (INCI Designation: PPG-1-trideceth-6)) are commercially available.

Copolymers with monomer units of the formula (VI) contain as nonionic monomer units preferably acrylamide, methacrylamide, acrylic acid-C 1 -C 4 alkyl esters and methacrylic acid C 1 -C 4 -alkyl esters. Among these nonionic monomers, the acrylamide is particularly preferred. These copolymers can also be crosslinked, as described above in the case of the homopolymers. A copolymer preferred according to the invention is the crosslinked acrylamide-methacryloyloxyethyltrimethylammonium chloride copolymer. Such copolymers in which the monomers are present in a weight ratio of about 20:80, commercially available as about 50% non-aqueous polymer dispersion under the name Salcare ^® SC 92nd Other preferred cationic polymers are, for example, quaternized cellulose derivatives, such as are available under the names of Celquat ^® and Polymer JR ^® commercially. The compounds Celquat ^® H 100, Celquat L 200 and Polymer JR ^® ^® 400 are preferred quaternized cellulose derivatives

- cationic alkyl polyglycosides according to DE-PS 44 13 686, cationized honey, for example the commercial product Honeyquat ^® 50, cationic guar derivatives, in particular the products sold under the trade name Cosmedia Guar ^® and Jaguar ^®,

Q2-7224 polysiloxanes with quaternary groups, such as the commercially available products (manufacturer: Dow Corning; a stabilized trimethyl silylamodimethicon), Dow Corning ^® 929 Emulsion (containing a hydroxylamino-modified silicone which is also known as amodimethicone ), SM-2059 (manufacturer: General Electric), SLM-55067 (manufacturer: Wacker) and Abil ^® -Quat 3270 and 3272 (manufacturer: Th Goldschmidt; diquaternary polydimethylsiloxanes, quaternium-80), polymeric dimethyldiallylammonium salts and their copolymers with esters. and amides of acrylic acid and methacrylic acid. Under the names Merquat ^® 100 (Poly (dimethyldiallylammoniumchlohd)) and Merquat ^® 550 (dimethyldiallylammonium chloride-acrylamide copolymer) commercially available products are examples of such cationic polymers,

Copolymers of vinylpyrrolidone with quaternized derivatives of dialkylaminoalkyl acrylate and methacrylate, such as diethyl sulfate quaternized vinylpyrrolidone-dimethylaminoethyl methacrylate copolymers. Such compounds are sold under the names Gafquat ^® 734 and Gafquat ^® 755 commercially,

Vinylpyrrolidone-Vinylimidazoliummethochlorid copolymers, such as those available under the names Luviquat ^® FC 370, FC 550, FC 905 and HM 552, quaternized polyvinyl alcohol, as well as those under the names Polyquaternium 2, Polyquaternium 17, Polyquaternium 18 and

Polyquaternium 27 known polymers with quaternary nitrogen atoms in the polymer main chain.

Can be used as cationic polymers (. B. commercial product, Quatrisoft ^® LM 200) under the designations Polyquaternium-24, known polymers. Also usable in the invention are the copolymers of vinylpyrrolidone, such as the commercial products Copolymer 845 (manufactured by ISP), Gaffix ^® VC 713 (manufactured by ISP), Gafquat ^® ASCP 1011, Gafquat ^® HS 110, Luviquat ^® 8155 and Luviquat ^® MS 370 available are. Other cationic polymers of the invention are the "temporarily cationic" polymers. These polymers usually contain an amino group present at certain pH values as a quaternary ammonium group and thus cationic are preferred, for example, chitosan and its derivatives, such as, for example, under the trade designations Hydagen ^®. , Hydagen® ^® HCMF, Kytamer ^® PC and Chitolam ^® NB / 101 are freely available commercially CMF. chitosans are deacetylated, in different degrees of deacetylation and varying degrees of degradation (molecular weights) are commercially available. Their preparation is, for example, in DE 44 40 625 A1 and described in DE 1 95 03 465 A1.

Particularly useful chitosans have a degree of deacetylation of at least 80% and a molecular weight of 5 ^'10 ⁵ to ^5' 10 ⁶ (g / mol).

For the production of preparations according to the invention, the chitosan must be converted into the salt form. This can be done by dissolving in dilute aqueous acids. As acids, both mineral acids, e.g. Hydrochloric acid, sulfuric acid and phosphoric acid as well as organic acids, e.g. low molecular weight carboxylic acids, polycarboxylic acids and hydroxycarboxylic acids suitable. Furthermore, higher molecular weight alkyl sulfonic acids or alkyl sulfuric acids or organophosphoric acids can be used, provided that they have the required physiological compatibility. Suitable acids for converting the chitosan into the salt form are e.g. Acetic acid, glycolic acid, tartaric acid, malic acid, citric acid, lactic acid, 2-pyrrolidinone-5-carboxylic acid, benzoic acid or salicylic acid. Preferred are low molecular weight hydroxycarboxylic acids such as e.g. Glycolic acid or lactic acid.

In a particularly preferred embodiment of the invention as a cationic polymer at least one polymer selected from the group of cationic guar derivatives (Jaguar ^® types), Polyquaternium-7 (Merquat 550), Polyquaternium-6, or Polyquaternium-10 contained in the cleaning agents.

The cationic polymers are contained in the agents according to the invention preferably in amounts of 0.1 to 5 wt .-%, based on the total agent. Amounts of from 0.2 to 3, especially from 0.5 to 2 wt .-%, are particularly preferred.

In a further preferred embodiment of the invention, the surfactant-containing cleaning agents also contain at least one constituent from the group of water-insoluble oil components, vitamins, provitamins, protein hydrolysates, plant extracts, UV filters, amino acids, water-soluble silicones and / or water-insoluble silicones and / or the amodimethicones.

Suitable water-insoluble oil components according to the invention are vegetable, mineral or synthetic oils, as well as mixtures of these components. As natural (vegetable) oils usually triglycerides and mixtures of triglycerides are used. Preferred natural oils according to the invention are coconut oil, (sweet) almond oil, walnut oil, peach kernel oil, avocado oil, tea tree oil, soybean oil, sesame oil, sunflower oil, tsubaki oil, evening primrose oil, rice bran oil, palm kernel oil, mango seed oil, meadowfoam seed oil, thistle oil, macadamia nut oil, Grapeseed oil, apricot oil, babushu oil, olive oil, wheat germ oil, pumpkin seed oil, mallow oil, hazelnut oil, safflower oil, canola oil, sasanqua oil, jojoba oil and shea butter.

In particular, mineral oils, paraffin oils, isoparaffin oils and synthetic hydrocarbons are used as mineral oils. An inventively employable hydrocarbon is for example the commercial product available as a 1, 3-di- (2-ethylhexyl) cyc! Ohexan (Cetiol ^® S).

Suitable synthetic oils are silicone compounds, in particular dialkyl and alkylaryl silicones, such as, for example, dimethylpolysiloxane and methylphenylpolysiloxane, and also their hydroxy-terminated, alkoxylated and quaternized analogs. Examples of such silicones are those sold by Dow Corning under the names DC 190, DC 200, DC 344 and DC 345 (cyclomethicone).

As an oil component can continue to serve a dialkyl ether.

Dialkyl ethers which can be used according to the invention are in particular di-n-alkyl ethers having a total of from 12 to 36 carbon atoms, in particular 12 to 24 carbon atoms, such as, for example, di-n-octyl ether, di-n-decyl ether, di-n-nonyl ether, di-n-alkyl ether. n-undecyl ether, di-n-dodecyl ether, n-hexyl n-octyl ether, n-octyl n-decyl ether, n-decyl n-undecyl ether, n-undecyl n-dodecyl ether and n-hexyl n-undecyl ether, and Di-tert-butyl ether, di-isopentyl ether, di-3-ethyl decyl ether, tert-butyl n-octyl ether, iso-pentyl n-octyl ether and 2-methylpentyl n-octyl ether.

According to the invention particularly preferred is the di-n-octyl ether, which is commercially available under the name Cetiol ^® OE.

The cleaning agents according to the invention preferably contain the water-insoluble oil component in an amount range from 0.1 to 5% by weight, in particular from 0.5 to 2% by weight, based on the total weight of the composition.

In a further preferred embodiment of the invention, the effect of the active compound combination according to the invention can be further optimized by further fatty substances. Other fatty substances are to be understood fatty acids, fatty alcohols and natural and synthetic waxes, which may be present both in solid form and liquid in aqueous dispersion.

The fatty acids used can be linear and / or branched, saturated and / or unsaturated fatty acids having 6 to 30 carbon atoms. Preference is given to fatty acids having 10 to 22 carbon atoms. These include, for example, the isostearic acids, such as Commercial products Emersol ^® 871 and Emersol ^® 875, and isopalmitic acids such as the commercial product Edenor ^® IP 95, and all other products sold under the trade names Edenor ^® (Cognis) fatty acids. Other typical examples of such fatty acids are caproic, caprylic, 2-ethylhexanoic, capric, lauric, isotridecanoic, myristic, palmitic, palmitoleic, stearic, isostearic, oleic, elaidic, petroselic, linoleic, linolenic and erucic acid and their technical mixtures, which are obtained, for example, in the pressure splitting of natural fats and oils, in the oxidation of aldehydes from Roelen's oxo synthesis or the dimerization of unsaturated fatty acids. Particularly preferred are usually the fatty acid cuttings obtainable from coconut oil or palm oil; In particular, the use of stearic acid is usually preferred.

The amount used is 0.1 - 15 wt.%, Based on the total mean. In a preferred embodiment, the amount is 0.5-10% by weight, very particularly preferably amounts of 1-5% by weight.

As fatty alcohols it is possible to use saturated, mono- or polyunsaturated, branched or unbranched fatty alcohols with C ₆ -C ₃₀ -, preferably C ₁₀ -C ₂₂ - and very particularly preferably C ₁₂ -C ₂₂ -carbon atoms. Decanols, octanols, dodecadienol, decadienol, oleyl alcohol, eruca alcohol, ricinoleic alcohol, stearyl alcohol, isostearyl alcohol, cetyl alcohol, lauryl alcohol, myristyl alcohol, arachidyl alcohol, caprylic alcohol, capric alcohol, linoleyl alcohol, linolenyl alcohol and behenyl alcohol are, for example, decanol, octanolol, dodecadienol, decadienol , as well as their Guerbet alcohols, this list should have exemplary and non-limiting character. However, the fatty alcohols are derived from preferably natural fatty acids, which can usually be based on recovery from the esters of fatty acids by reduction. Also usable according to the invention are those fatty alcohol cuts which are produced by reduction of naturally occurring triglycerides such as beef tallow, palm oil, peanut oil, rapeseed oil, cottonseed oil, soybean oil, sunflower oil and linseed oil or fatty acid esters formed from their transesterification products with corresponding alcohols, and thus represent a mixture of different fatty alcohols. Such substances are, for example, under the names Stenol ^® such as Stenol ^® 1618 or Lanette ^® such as Lanette ^® O or Lorol ^®, for example, Lorol ^® C8, Lorol C14 ^®, Lorol C18 ^®, ^® Lorol C8-18, HD-Ocenol ^®, Crodacol ^® such as Crodacol ^® CS, Novol ^®, Eutanol ^® G, Guerbitol ^® 16, Guerbitol ^® 18, Guerbitol ^® 20, Isofol ^® 12, Isofol ^® 16, Isofol ^® 24, Isofol ^® 36, Isocarb ^® 12, Isocarb ^® 16 or Isocarb® ^® 24 available for purchase. Of course, the invention also wool wax alcohols, as are commercially available, for example under the names of Corona ^®, White Swan ^®, Coronet ^® or Fluilan ^® can be used.

The fatty alcohols are used in amounts of from 0.1 to 20% by weight, based on the total preparation, preferably in amounts of from 0.1 to 10% by weight. The natural or synthetic waxes used according to the invention are solid paraffins or isoparaffins, carnauba waxes, beeswaxes, candelilla waxes, ozokerites, ceresin, spermaceti, sunflower wax, fruit waxes such as apple wax or citrus wax, microwaxes of PE or PP. Such waxes are available, for example, from Kahl & Co., Trittau.

Other fatty substances are, for example

Esteröle. Ester oils are to be understood as meaning the esters of C ₆ - C ₃₀ fatty acids with C ₂ - C ₃₀ fatty alcohols. The monoesters of the fatty acids with alcohols having 2 to 24 carbon atoms are preferred. Examples of fatty acid components used in the esters are caproic acid, caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, isotridecanoic acid, myristic acid, palmitic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, linolenic acid, elaeostearic acid, arachidic acid, Gadoleic acid, behenic acid and erucic acid and their technical mixtures which are obtained, for example, in the pressure splitting of natural fats and oils, in the oxidation of aldehydes from Roelen's oxo synthesis or the dimerization of unsaturated fatty acids. Examples of fatty alcohol moieties in the ester oils are isopropyl alcohol, caproic alcohol, capryl alcohol, 2-ethylhexyl alcohol, capric alcohol, lauryl alcohol, isotridecyl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, linolyl alcohol, linolenyl alcohol, elaeostearyl alcohol, arachyl alcohol, gadoleyl alcohol, Behenyl alcohol, erucyl alcohol and brassidyl alcohol and their technical mixtures, for example, in the high-pressure hydrogenation of technical methyl esters based on fats and oils or aldehydes from the Roelen oxo synthesis and as a monomer fraction in the dimerization of unsaturated fatty alcohols incurred. According to the invention particularly preferably isopropyl myristate (IPM Rilanit ^®), isononanoic acid C16-18 alkyl ester (Cetiol ^® SN), 2-ethylhexyl palmitate (Cegesoft ^® 24), stearic acid-2-ethylhexyl ester (Cetiol ^® 868), cetyl oleate, glycerol tricaprylate, Kokosfettalkohol- caprinaÜ caprylate (Cetiol ^® LC), n-butyl stearate, oleyl erucate (Cetiol ^® J 600), isopropyl palmitate (Rilanit ^® IPP), oleyl Oleate (Cetiol ^®), hexyl laurate (Cetiol ^® A), di-n-butyl adipate (Cetiol ^® B), myristyl myristate (Cetiol ^® MM), Cetearyl Isononanoate (Cetiol ^® SN), decyl oleate (Cetiol ^® V).

Dicarboxylic acid esters such as di-n-butyl adipate, di- (2-ethylhexyl) adipate, di- (2-ethylhexyl) succinate and di-isotridecyl acelate, and diol esters such as ethylene glycol dioleate, ethylene glycol diisotridecanoate, propylene glycol di (2) ethylhexanoate), propylene glycol diisostearate, propylene glycol di-pelargonat, butanediol di-isostearate, Neopentylglykoldicaprylat, symmetrical, asymmetric or cyclic esters of carbonic acid with fatty alcohols, for example described in DE-OS 197 56 454, glycerol carbonate or dicaprylyl carbonate (Cetiol ^® CC), ethoxylated or non-ethoxylated mono, - di- and trifatty acid esters of saturated and / or unsaturated linear and / or branched fatty acids with glycerol, such as Monomuls ^® 90-018, Monomuls ^® 90-L12, Cetiol ^® HE or Cutina ^® MD. The amount used is 0.1-50 wt.% Based on the total agent, preferably 0.1 to 20 wt.% And particularly preferably 0.1 to 15 wt.% Based on the total agent.

The total amount of oil and fat components in the compositions according to the invention is usually from 6 to 45% by weight, based on the total agent. Amounts of 10-35% by weight are preferred according to the invention.

In accordance with the invention preferred vitamins, provitamins and vitamin precursors and derivatives thereof are those representatives which are usually assigned to the groups A, B, C, E, F and H.

The group of substances called vitamin A includes retinol (vitamin A ₁ ) and 3,4-didehydroretinol (vitamin A ₂ ). The ß-carotene is the provitamin of retinol. As vitamin A component according to the invention, for example, vitamin A acid and its esters, vitamin A aldehyde and vitamin A alcohol and its esters such as the palmitate and the acetate into consideration. The agents according to the invention preferably contain the vitamin A component in amounts of 0.01-1% by weight, based on the total preparation.

The vitamin B group or the vitamin B complex include u. a.

Vitamin B ₁ (thiamine)

Vitamin B ₂ (riboflavin)

Vitamin B ₃ . Under this designation are often the compounds nicotinic acid and

Nicotinic acid amide (niacinamide). Preferred according to the invention is the nicotinic acid amide, which is preferably present in the agents according to the invention in amounts of from 0.05 to 1% by weight, based on the total agent.

Vitamin B ₅ (pantothenic acid, panthenol and pantolactone). Panthenol and / or pantolactone are preferably used in the context of this group. Derivatives of panthenol which can be used according to the invention are, in particular, the esters and ethers of panthenol and also cationically derivatized panthenols. Individual representatives are, for example, the panthenol triacetate, the panthenol monoethyl ether and its monoacetate and also the cationic panthenol derivatives disclosed in WO 92/13829. Vitamin B ₆ (pyridoxine and pyridoxamine and pyridoxal).

The said compounds of the vitamin B group are preferably contained in the agents according to the invention in amounts of 0.01-2% by weight, based on the total agent. Amounts of 0.03 - 1 wt .-% are particularly preferred.

Vitamin C (ascorbic acid). Vitamin C is used in the compositions according to the invention preferably in amounts of 0.01 to 3 wt .-%, based on the total agent. The use in form Palmitinsäureesters, glucosides or phosphates may be preferred. The use in combination with tocopherols may also be preferred.

Vitamin E (tocopherols, especially α-tocopherol). Tocopherol and its derivatives, which include in particular the esters such as the acetate, the nicotinate, the phosphate and the succinate, are preferably present in the agents used according to the invention in amounts of 0.01-1% by weight, based on the total agent ,

Vitamin F. The term "vitamin F" is usually understood as meaning essential fatty acids, in particular linoleic acid, linolenic acid and arachidonic acid.

Vitamin H. Vitamin H is the compound (3aS, 4S, 6aR) -2-oxohexahydrothienol [3,4-c /] - imidazole-4-valeric acid, for which, however, the common name biotin has become established. Biotin is contained in the agents used according to the invention preferably in amounts of 0.0001 to 1, 0 wt .-%, in particular in amounts of 0.001 to 0.01 wt .-%.

Protein hydrolyzates in the context of the invention are understood as meaning protein hydrolyzates and / or amino acids and their derivatives (H).

Protein hydrolysates are product mixtures obtained by acid, alkaline or enzymatically catalyzed degradation of proteins (proteins). According to the invention, the term protein hydrolyzates also means total hydrolyzates as well as individual amino acids and their derivatives as well as mixtures of different amino acids. Furthermore, according to the invention, polymers made up of amino acids and amino acid derivatives are understood by the term protein hydrolyzates. The latter include, for example, polyalanine, polyasparagine, polyserine, etc. Further examples of compounds which can be used according to the invention are L-alanyl-L-proline, polyglycine, glycyl-L-glutamine or D / L-methionine-S-methylsulfonium chloride. Of course, according to the invention, β-amino acids and their derivatives such as β-alanine, anthranilic acid or hippuric acid can also be used. The molecular weight of the protein hydrolysates which can be used according to the invention is between 75, the molecular weight for glycine, and 200,000, preferably the molecular weight is 75 to 50,000 and very particularly preferably 75 to 20,000 daltons. Of course, the present teaching according to the invention also encompasses that in the case of the amino acids, these may be present in the form of derivatives such as, for example, the N-acyl derivatives, the N-alkyl or the O-esters. In the case of N-acyl derivatives, the acyl group is a formyl radical, an acetyl radical, a propionyl radical, a butyryl radical or the radical of a straight-chain, branched or unbranched, saturated or unsaturated fatty acid having a chain length of 8 to 30 carbon atoms. In the case of an N-alkyl derivative, the alkyl group may be linear, branched, saturated or unsaturated and has a C chain length of 1 to 30 carbon atoms. In the case of O-esters, the alcohols on which the esterification is based are methanol, ethanol, isopropanol, propanol, butanol, isobutanol, pentanol, neopentanol, isopentanol, hexanols, heptanols, caprylic or caproic alcohol, octanols, nonanols, decanols, dodecanols, lauranols, in particular saturated or unsaturated, linear or branched alcohols having a C chain length of 1 to 30 carbon atoms. Of course, the amino acids on both the N-atom and on O atom be derivatized simultaneously. Of course, the amino acids can also be used in salt form, in particular as mixed salts together with edible acids. This may be preferred according to the invention.

Examples of amino acids and their derivatives as protein hydrolysates according to the invention are: alanine, arginine, carnitine, creatine, citrulline, cystathionine, cysteine, cystine, cystic acid, glycine, histidine, homocysteine, homoserine, isoleucine, lanthionine, leucine, lysine, methionine, norleucine , Norvaline, ornithine, phenylalanine, proline, hydroxyproline, sarcosine, serine, threonine, tryptophan, thyronine, tyrosine, valine, aspartic acid, asparagine, glutamic acid and glutamine. Preferred amino acids are alanine, arginine, glycine, histidine, lanthionine, leucine, lysine, proline, hydroxyproline serine and asparagine. Alanine, glycine, histidine, lysine, serine and arginine are very particularly preferably used. Most preferably, glycine, histidine, lysine and serine are used.

According to the invention, protein hydrolysates of both vegetable and animal or marine or synthetic origin can be used.

Animal protein hydrolysates are, for example, elastin, collagen, keratin, silk and milk protein hydrolysates, which may also be present in the form of salts. Such products are, for example, under the trademarks Dehylan ^® (Cognis), Promois® ^® (Interorgana) Collapuron ^® (Cognis), Nutrilan® ^® (Cognis), Gelita-Sol ^® (German Gelatinefabriken Stoess & Co), Lexein ^® (Inolex) and kerasol tm ^® (Croda) sold.

Preferred according to the invention is the use of protein hydrolysates of plant origin, eg. Soybean, almond, pea, potato and wheat protein hydrolysates. Such products are, for example, under the trademarks Gluadin ^® (Cognis), diamine ^® (Diamalt) ^® (Inolex), Hydrosoy ^® (Croda), hydro Lupine ^® (Croda), hydro Sesame ^® (Croda), Hydro tritium ^® (Croda) and Crotein ^® (Croda) available.

Further preferred protein hydrolysates according to the invention are of maritime origin. These include, for example, collagen hydrolyzates of fish or algae as well as protein hydrolysates of mussels or pearl hydrolyzates.

The protein hydrolysates or their derivatives are preferably contained in the preparations used according to the invention in amounts of from 0.1 to 10% by weight, based on the total agent. Amounts of 0.1 to 5 wt .-% are particularly preferred.

According to the invention surfactant-containing detergents are the plant extracts of green tea, oak bark, stinging nettle, witch hazel, hops, henna, camomile, burdock root, horsetail, hawthorn, linden, almond, aloe vera, spruce needle, horse chestnut, sandalwood, juniper, coconut, mango, apricot , Lime, Wheat, Kiwi, Melon, Orange, Grapefruit, Sage, Rosemary, Birch, Mallow, Meadowfoam, Quenelle, Yarrow, Thyme, Melissa, Hauhechel, Coltsfoot, Vanilla, Marshmallow, Meristem, Ginseng and Ginger root included.

Particularly preferred according to the invention are the extracts of green tea, almond, aloe vera, coconut, mango, apricot, lime, wheat, vanilla, kiwi and melon, and particularly preferably the extracts of aloe vera, vanilla and melon.

Usually these extracts are produced by extraction of the whole plant. However, in individual cases it may also be preferred to prepare the extracts exclusively from flowers and / or leaves of the plant.

As extraction agent for the preparation of said plant extracts water, alcohols and mixtures thereof can be used. Among the alcohols are lower alcohols such as ethanol and isopropanol, but especially polyhydric alcohols such as ethylene glycol and propylene glycol, both as sole extractant and in admixture with water, are preferred. Plant extracts based on water / propylene glycol in a ratio of 1:10 to 10: 1 have proven to be particularly suitable.

The plant extracts can be used according to the invention both in pure and in diluted form. If they are used in diluted form, they usually contain about 2 to 80 wt .-% of active substance and as a solvent used in their extraction agent or extractant mixture.

The plant extracts are used in the cleaning agent according to the invention - based on its weight - in an amount of 0.01 to 5 wt .-%, preferably 0.02 to 4 wt .-% and in particular 0.05 to 3 wt .-%.

Furthermore, in a preferred embodiment of the invention, the effect of the preparations can be increased by UV filters. The UV filters to be used according to the invention are not subject to any general restrictions with regard to their structure and their physical properties. On the contrary, all UV filters which can be used in the cosmetics sector and whose absorption maximum lies in the UVA (315-400 nm), in the UVB (280-315 nm) or in the UVC (<280 nm) range are suitable. UV filters with an absorption maximum in the UVB range, in particular in the range from about 280 to about 300 nm, are particularly preferred.

The UV filters used according to the invention can be selected, for example, from substituted benzophenones, p-aminobenzoic acid esters, diphenylacrylic acid esters, cinnamic acid esters, salicylic acid esters, benzimidazoles and o-aminobenzoic acid esters.

Examples of UV filters which can be used according to the invention are 4-aminobenzoic acid, N, N, N-trimethyl-4- (2-oxoborn-3-ylidenemethyl) aniline-methylsulfate, SSδ-trimethyl-cyclohexylsalicylate (homosalates), 2- Hydroxy-4-methoxy-benzophenone (benzophenone-3; Uvinul ^® M 40, Uvasorb MET ^®, ^® Neo Heliopan BB, Eusolex ^® 4360), 2-phenylbenzimidazole-5-sulfonic acid and potassium, sodium and triethanolamine salts (Phenylbenzimidazole sulfonic acid; Parsol ^® HS; Neo Heliopan Hydro ^®), 3,3 '- (1, 4- phenylenedimethylene) bis (7,7-dimethyl-2-oxo-bicyclo [2.2.1] hept-1-yl methane-sulfonic acid) and salts thereof, 1- (4-tert-butylphenyl) -3- (4-methoxyphenyl) propane-1, 3-dione (butyl methoxydibenzoylmethane; Parsol ^® 1789 Eusolex ^® 9020), α- ( 2-oxoborn-3-ylidene) toluene-4-sulfonic acid and salts thereof, ethδxylierte 4-aminobenzoic acid ethyl ester (PEG-25 PABA; Uvinul ^® P 25), 4-methylaminobenzoic acid di- 2-ethylhexyl (octyl dimethyl PABA; Uvasorb ^® DMO, Escalol ^® 507, Eusolex ^® 6007), salicylic acid 2-ethylhexyl (octyl salicylate; Escalol ^® 587, Neo Heliopan ^® OS, Uvinul ^® O18), 4-methoxycinnamic acid isopentyl (isoamyl p-methoxycinnamate; Neo Heliopan ^® E 1000), 4-methoxycinnamic acid 2-ethyl lhexyl ester (octyl methoxycinnamate; Parsol ^® MCX, Escalol ^® 557, Neo Heliopan AV ^®), 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid and its sodium salt (Benzophenone-4; Uvinul ^® MS 40; Uvasorb S 5 ^®), 3- (4'- methylbenzylidene) -D, L-camphor (camphor 4- methylbenzylidene; Parsol ^® 5000, Eusolex ^® 6300), 3-benzylidene camphor (3-benzylidene camphor), 4-isopropylbenzyl, 2,4,6-trianilino- (p- carbo-2'-ethylhexyl-1'-oxy) -1,3,5-triazine, 3-imidazol-4-yl-acrylic acid and its ethyl ester, polymers of N - {(2 and 4) - [2-oxoboronyl] 3- ylidenemethyl] benzyl} -acrylamids, 2,4-dihydroxy (benzophenone-1; Uvasorb ^® 20 H, Uvinul ^® 400) 1, 1 '-Diphenylacrylonitrilsäure-2-ethylhexyl ester (Octocrylene; Eusolex ^® OCR, Neo Heliopan ^® Type 303, Uvinul ^® N 539 SG) ₁ o-aminobenzoic acid menthyl ester (menthyl Anthranilate; Neo Heliopan MA ^®), 2,2 ', 4,4'-tetrahydroxy benzophenone (benzophenone-2; Uvinul ^® D-50), 2 2,2'-Dihydroxy-4,4'-dimethoxybenzophenone (benzophenone-6), 2,2'-dihydroxy-4,4'-dimethoxybenzophenone-5-sodium ulfonate and 2-cyano-3,3-diphenylacrylic acid 2'-ethylhexyl ester. Preference is given to A-aminobenzoic acid, N ₁ N, N-trimethyl-4- (2-oxoborn-3-ylidenemethyl) aniline methylsulfate, 3,3,5-trimethylcyclohexylsalicylate, 2-hydroxy-4-methoxybenzophenone , 2-phenylbenzimidazole-5-sulfonic acid and its potassium, sodium and triethanolamine salts, 3,3 '- (1, 4-phenylenedimethylene) - bis (7,7-dimethyl-2-oxo-bicyclo- [2.2.1] hept-1-yl-methanesulfonic acid) and its salts, 1- (4-tert-butylphenyl) -3- (4-methoxyphenyl) -propane-1,3-dione, α- (2-oxoborn-3-ylidene ) -toluene-4-sulfonic acid and its salts, ethoxylated 4-aminobenzoic acid ethyl ester, 2-ethylhexyl 4-dimethylaminobenzoate, 2-ethylhexyl salicylate, isopentyl 4-methoxycinnamate, 2-ethylhexyl A-methoxycinnamate, 2- Hydroxy-4-methoxybenzophenone-5-sulfonic acid and its sodium salt, 3- (4'-ethylbenzylidene) -D, L-camphor, 3-benzylidene-camphor, 4-isopropylbenzyl salicylate, 2,4,6-trianilino (p -carbo-2'-ethylhexyl-1'-oxi) -1, 3,5-triazine, 3-imidazol-4-yl-acrylic acid and its ethyl ester, polymers of the N- {(2 and 4) - [2-oxoborn-3-ylidenemethyl] benzyl} -acrylamide. Very particularly preferred according to the invention are 2-hydroxy-4-methoxybenzophenone, 2-phenylbenzimidazole-5-sulfonic acid and its potassium, sodium and triethanolamine salts, 1- (4-tert-butylphenyl) -3- (4-methoxyphenyl) -propane-1,3-dione, 4-methoxycinnamic acid 2-ethylhexyl ester and 3- (4'-methylbenzylidene) -D, L-camphor.

Preference is given to those UV filters whose molar extinction coefficient at the absorption maximum is above 15,000, in particular above 20,000. Furthermore, it has been found that in structurally similar UV filters in many cases, the water-insoluble compound in the teaching of the invention has the higher effect compared to such water-soluble compounds that differ from it by one or more additional ionic groups. For the purposes of the invention, water-insoluble UV filters are those which dissolve in water at not more than 1% by weight, in particular not more than 0.1% by weight, at 20 ^° C. Furthermore, these compounds should be soluble in the usual cosmetic oil components at room temperature to at least 0.1, in particular at least 1 wt .-%). The use of water-insoluble UV filters may therefore be preferred according to the invention.

According to a further embodiment of the invention, preference is given to those UV filters which have a cationic group, in particular a quaternary ammonium group.

These UV filters have the general structure U - Q.

The structural part U stands for a UV-absorbing group. This group can be in the

Derive principle of the known, usable in the cosmetics sector, above UV filters in which a group, usually a hydrogen atom, of the UV filter is replaced by a cationic group Q, in particular with a quaternary amino function.

Compounds from which the structural part U can derive are, for example

substituted benzophenones, p-aminobenzoic acid esters,

diphenylacrylic,

cinnamic,

salicylic acid,

Benzimidazoles and o-aminobenzoic acid esters.

Structural parts U which are derived from cinnamic acid amide or from N, N-dimethylaminobenzoic acid amide are preferred according to the invention.

The structural parts U can in principle be selected such that the absorption maximum of the UV filters can be in both the UVA (315-400 nm) and in the UVB (280-315 nm) or in the UVC (<280 nm) range. UV filters with an absorption maximum in the UVB range, in particular in the range from about 280 to about 300 nm, are particularly preferred.

Furthermore, the structural part U, also as a function of structural part Q, is preferably chosen such that the molar extinction coefficient of the UV filter at the absorption maximum is above 15,000, in particular above 20,000. The structural part Q preferably contains, as a cationic group, a quaternary ammonium group. This quaternary ammonium group can in principle be connected directly to the structural part U, so that the structural part U represents one of the four substituents of the positively charged nitrogen atom. Preferably, however, one of the four substituents on the positively charged nitrogen atom is a group, especially an alkylene group of 2 to 6 carbon atoms, which functions as a compound between the structural portion U and the positively charged nitrogen atom.

Advantageously, the group Q has the general structure - (CH ₂ ) χ-N ⁺ R ¹ R ² R ³ X ^" , in which x is an integer from 1 to 4, R ¹ and R ² independently of one another are C 1 Alkyl groups, R ³ is a Ci. ₂₂ alkyl group or a benzyl group and X ^"is a physiologically acceptable anion. In the context of this general structure, x preferably represents the number 3, R ¹ and R ² each represent a methyl group and R ^{3 represents} either a methyl group or a saturated or unsaturated, linear or branched hydrocarbon chain having 8 to 22, in particular 10 to 18, carbon atoms.

Physiologically acceptable anions are, for example, inorganic anions such as halides, in particular chloride, bromide and fluoride, sulfate ions and phosphate ions and organic anions such as lactate, citrate, acetate, tartrate, methosulfate and tosylate.

Two preferred UV filters with cationic groups are the commercially available compounds cinnamic acid-trimethylammonium chloride (lncroquat ^® UV-283) and dodecyl tosylate (Escalol ^® HP 610).

Of course, the teaching of the invention also includes the use of a combination of several UV filters. In the context of this embodiment, the combination of at least one water-insoluble UV filter with at least one UV filter with a cationic group is preferred.

The UV filters (I) are contained in the compositions according to the invention usually in amounts of 0.1-5 wt .-%, based on the total agent. Levels of 0.4-2.5 wt .-% are preferred.

According to a further preferred embodiment of the invention, the surfactant-containing cleaning agents also contain at least one further water-insoluble silicone, a water-soluble silicone and / or an amino-functionalized silicone.

Dimethiconols form the first group of silicones which are particularly preferred according to the invention. The dimethiconols according to the invention can be both linear and branched as well as cyclic or cyclic and branched. Linear dimethiconols can be represented by the following structural formula (S1-I):

(SiOHR ¹ ₂ ) - O - (SiR ² Z - O -) _x - (SiOHR ¹ ₂ ) (S1 - I) Branched dimethiconols can be represented by the structural formula (S1-II):

R ²

I (SiOHR ¹ ₂ ) -O- (SiR ² ₂ -O-) χ-Si-O- (SiR ² ₂ -O-) r (SiOHR ¹ ₂ )

I (SiR ² ₂ -O-) _z - (SiOHR ¹ ₂ )

The radicals R ¹ and R ² are each independently hydrogen, a methyl radical, a C ² to C 30 linear, saturated or unsaturated hydrocarbon radical, a phenyl radical and / or an aryl radical. Non-limiting examples of the groups represented by R ¹ and R ² include alkyl groups such as methyl, ethyl, propyl, isopropyl, butyl, isobutyl, pentyl, isopentyl, neopentyl, amyl, isoamyl, hexyl, isohexyl and the like; Alkenyl radicals such as vinyl, halovinyl, alkylvinyl, allyl, haloallyl, alkylallyl; Cycloalkyl radicals such as cyclobutyl, cyclopentyl, cyclohexyl and the like; Phenyl radicals, benzyl radicals, halohydrocarbon radicals such as 3-chloropropyl, 4-bromobutyl, 3,3,3-trifluoropropyl, chlorocyclohexyl, bromophenyl, chlorophenyl and the like, and sulfur containing radicals such as mercaptoethyl, mercaptopropyl, mercaptohexyl, mercaptophenyl and the like; Preferably, R ¹ and R ^{2 is} an alkyl radical containing from 1 to about 6 carbon atoms, and most preferably R ¹ and R ^{2 are} methyl. Examples of R ¹ include methylene, ethylene, propylene, hexamethylene, decamethylene, -CH ₂ CH (CH ₃ ) CH ₂ -, phenylene, naphthylene, -CH ₂ CH ₂ SCH ₂ CH ₂ -, -CH ₂ CH ₂ OCH ₂ - , - OCH ₂ CH ₂ -, -OCH ₂ CH ₂ CH ₂ -, -CH ₂ CH (CH ₃ ) C (O) OCH ₂ -, - (CH ₂ J ₃ CC (O) OCH ₂ CH ₂ -, - C ₆ H ₄ C ₆ H ₄ -, -C ₆ H ₄ CH ₂ C ₆ H ₄ -; and - (CH ₂ ) ₃ C (O) SCH ₂ CH ₂ - Preferred as R ¹ and R ² are methyl Particularly preferred lauryl, stearyl and behenyl radicals are the C2 to C22 alkyl radicals The numbers x, y and z are integers and each independently run from 0 to 50,000 the Dimethicone lie between 1,000 D and 10000000 D. the viscosities are between 100 and 10,000,000 cPs measured at 25 ⁰ C by means of a glass capillary viscometer according to Dow Corning Corporate test method CTM 0004 dated 20 July 1970. Preferred viscosities are from 1000 to 5,000,000 cPs, Particularly preferred viscosities are between 10,000 and 3,000,000 cps. The most preferred range is between 50,000 and 2,000,000 cps.

Of course, the teaching of the invention also includes that the dimethiconols may already be present as an emulsion. In this case, the corresponding emulsion of the dimethiconols can be prepared both after the preparation of the corresponding dimethiconols from these and the usual methods of emulsification known to the person skilled in the art. For this purpose, both cationic, anionic, nonionic or zwitterionic surfactants and emulsifiers can be used as auxiliaries for the preparation of the corresponding emulsions. Of course, the emulsions of the dimethiconols can also be prepared directly by an emulsion polymerization process. Such methods are also well known to the person skilled in the art. For example, reference may be made to the "Encyclopedia of Polymer Science and Engineering, Volume 15, Second Edition," Pages 204 to 308, John Wiley & Sons, Inc. 1989. This reference is expressly incorporated herein by reference.

When the dimethiconols of the invention are used as an emulsion, the droplet size of the emulsified particles is according to the invention from 0.01 μm to 10000 μm, preferably from 0.01 to 100 μm, very particularly preferably from 0.01 to 20 μm and most preferably from 0.01 to 10 microns. The particle size is determined by the method of light scattering.

If branched dimethiconols are used, it is to be understood that the branching is greater than a random branching, which occurs by impurities of the respective monomers randomly. For the purposes of the present invention, branched dimethiconols are therefore to be understood as meaning that the degree of branching is greater than 0.01%. Preferably, a degree of branching is greater than 0.1%, and most preferably greater than 0.5%. The degree of branching is determined from the ratio of unbranched monomers, that is, the amount of monofunctional siloxane, to the branching monomers, that is, the amount of tri- and tetrafunctional siloxanes. According to the invention, both low-branched and highly branched dimethiconols can be very particularly preferred.

Examples of such products include the following commercial products: Botanisil NU-150M (Botanigenics), Dow Coming 1-1254 Fluid, Dow Corning 2-9023 Fluid, Dow Corning 2-9026 Fluid, Ultrapure Dimethiconol (Ultra Chemical), Unisil SF- R (Universal Preserve), X-21-5619 (Shin-Etsu Chemical Co.), Abil OSW 5 (Degussa Care Specials), ACC DL-9430 Emulsion (Taylor Chemical Company), AEC Dimethiconol & Sodium Dodecylbenzenesulfonate (A & E Connock (Perfumery & Cosmetics) Ltd.), BC Dimethiconol Emulsion 95 (Basildon Chemical Company, Ltd.), Cosmetic Fluid 1401, Cosmetic Fluid 1403, Cosmetic Fluid 1501, Cosmetic Fluid 1401 DC (all aforementioned Chemsil Silicones, Inc.), Dow Corning 1401 Fluid, Dow Corning 1403 Fluid, Dow Corning 1501 Fluid, Dow Corning 1784 HVF Emulsion, Dow Corning 9546 Silicone Elastomer Blend (all aforementioned Dow Corning Corporation), Dub Gel Sl 1400 (Stearinerie Dubois FiIs), HVM 4852 Emulsion (Crompton Corporation), Jeesilc 6056 (Jeen International Corporation), Lubrasil, Lubrasil DS (both Guardian Laboratories), Nonychosine E, Nonychosine V (both exsymol), SanSurf Petrolatum-25, Satin Finish (both Collaborative Laboratories, Inc.), Silatex-D30 (Cosmetic Ingredient Resources), Silsoft 148 , Silsoft E-50, Silsoft E-623 (all aforementioned Crompton Corporation), SM555, SM2725, SM2765, SM2785 (all aforementioned GE Silicones), Taylor T-SiI CD-1, Taylor TME-4050E (all Taylor Chemical Company Wacker-Belsil CM 3092, Wacker-Belsil CM 5040, Wacker-Belsil DM 3096, Wacker-Belsil DM 3112 VP, Wacker-Belsil DM 8005 VP, Wacker-Belsil DM 60081 VP (all Wacker-Chemie GmbH mentioned above).

When the dimethiconols (S1) are contained in the base composition, these compositions contain 0.01 to 10% by weight, preferably 0.1 to 8% by weight, more preferably 0.25 to 7.5% by weight and in particular 0.5 to 5% by weight of dimethiconol based on the composition.

Dimethicone copolyols (S3) form another group of preferred silicones. Dimethiconols can be represented by the following structural formulas:

(SiR ¹ ₃₎ - O - (SiR ² ₂ - O -) χ - (Sirpe - O -) _y - (SiR ¹ ₃₎ (S3 - I)

or by the following structural formula:

PE - (SiR ¹ ₂ ) - O - (SiR ² _Z - O -) _x - (SiR ¹ ₂ ) - PE (S3 - II)

Branched dimethicone copolyols can be represented by the structural formula (S3-III):

R ²

I PE - (SiR ¹ ₂ ) - O - (SiR ² ₂ - O -) _x - Si - O - (SiR ² ₂ - O -) _y - (SiR ¹ ₂ ) - PE (S3 - III)

I (SiR ² ₂ - O -) _z - (SiR ¹ ₂ ) - PE

or by the structural formula (S3 - IV):

R ² I (SiR ¹ ₃ ) - O - (SiR ² ₂ - O -) _x - Si - O - (SiR ² PE - O - J y - (SiR ¹ ₃ ) (S3 - IV)

I (SiR ² ₂ -O-) _z - (SiR ¹ ₃ )

The radicals R ¹ and R ² are each independently hydrogen, a methyl radical, a C ² to C 30 linear, saturated or unsaturated hydrocarbon radical, a phenyl radical and / or an aryl radical. Non-limiting examples of the groups represented by R ¹ and R ² include alkyl groups such as methyl, ethyl, propyl, isopropyl, butyl, isobutyl, pentyl, isopentyl, neopentyl, amyl, isoamyl, hexyl, isohexyl and the like; Alkenyl radicals such as vinyl, halovinyl, alkylvinyl, allyl, haloallyl, alkylallyl; Cycloalkyl radicals such as cyclobutyl, cyclopentyl, cyclohexyl and the like; Phenyl radicals, benzyl radicals, halohydrocarbon radicals such as 3-chloropropyl, 4-bromobutyl, 3,3,3-trifluoropropyl, chlorocyclohexyl, bromophenyl, chlorophenyl and the like, and sulfur containing radicals such as mercaptoethyl, mercaptopropyl, mercaptohexyl, mercaptophenyl and the like; preferably R ¹ and R ^{2 is} an alkyl radical containing from 1 to about 6 carbon atoms, and most preferably R ¹ and R ^{2 are} methyl. Examples of R ¹ include methylene, ethylene, propylene, hexamethylene, decamethylene, -CH ₂ CH (CH ₃ ) CH ₂ -, phenylene, naphthylene, -CH ₂ CH ₂ SCH ₂ CH ₂ -, -CH ₂ CH ₂ OCH ₂ - , - OCH ₂ CH ₂ -, -OCH ₂ CH ₂ CH ₂ -, -CH ₂ CH (CH ₃ ) C (O) OCH ₂ -, - (CH ₂ J ₃ CC (O) OCH ₂ CH ₂ -, - C ₆ H ₄ C ₆ H ₄ -, -C ₆ H ₄ CH ₂ C ₆ H ₄ -; and - (CH ₂ ) ₃ C (O) SCH ₂ CH ₂ - Preferred as R ¹ and R ² are methyl Particularly preferred among the C2 to C22 alkyl radicals are lauryl, stearyl and behenyl radicals PE is a polyoxyalkylene radical Preferred polyoxyalkylene radicals are derived from ethylene oxide, propylene oxide and glycerol. y and z are integers and are each independently from O to 50,000. the molecular weights of Dimethicone lie between 1,000 D and 10000000 D. the viscosities are between 100 and 10,000,000 cPs measured at 25 ⁰ C by means of a glass capillary viscometer according to Dow Corning Corporate Test method CTM 0004 from July 20, 1970. Preferred viscosities are between 1,000 and 5,000,000 cPs, and particularly preferred viscosities are between 10,000 and 3,000,000 cPs. The most preferred range is between 50,000 and 2,000,000 cps.

Of course, the teaching of the invention also includes that the Dimethiconcopolymere can already be present as an emulsion. In this case, the corresponding emulsion of the dimethicone copolyols can be prepared both after the preparation of the corresponding dimethicone copolyols from these and the usual methods of emulsification known to the person skilled in the art. For this purpose, both cationic, anionic, nonionic or zwitterionic surfactants and emulsifiers can be used as auxiliaries for the preparation of the corresponding emulsions. Of course, the emulsions of dimethicone copolyols can also be prepared directly by an emulsion polymerization process. Such methods are also well known to the person skilled in the art. For example, reference may be made to the Encyclopedia of Polymer Science and Engineering, Volume 15, Second Edition, pages 204 to 308, John Wiley & Sons, Inc. 1989. This reference is expressly incorporated herein by reference.

When the dimethicone copolyols according to the invention are used as emulsion, the droplet size of the emulsified particles according to the invention is 0.01 μm to 10000 μm, preferably 0.01 to 100 μm, very particularly preferably 0.01 to 20 μm and most preferably 0.01 to 10 microns. The particle size is determined by the method of light scattering.

If branched dimethicone copolyols are used, it is to be understood that the branching is greater than a random branching, which occurs by impurities of the respective monomers randomly. For the purposes of the present invention, branched dimethicone copolyols are therefore to be understood as meaning that the degree of branching is greater than 0.01%. Preferably, a degree of branching is greater than 0.1%, and most preferably greater than 0.5%. The degree of branching is from the ratio of unbranched monomers, that is, the amount of monofunctional siloxane, to the branching monomers, that is, the amount of tri- and tetrafunctional siloxanes. According to the invention, both low-branched and highly branched dimethicone copolyols can be very particularly preferred.

When the dimethicone copolyols (S3) are contained in the base composition, these compositions contain from 0.01 to 10% by weight, preferably 0.1 to 8% by weight, more preferably 0.25 to 7.5% by weight and especially 0 , 5 to 5 wt.% Dimethiconecopolyol based on the composition.

Aminofunctional silicones, or also called amodimethicones (S4), are silicones which have at least one (optionally substituted) amino group.

Such silicones may e.g. by the formula (S4-I)

M (.. R _a Q _b Si0 ₍₄ _a _{b) / 2) x} (R _c Si0 ₍₄ _{^) / 2) y} M (S4 - I)

Will be described, wherein in the above formula R is a hydrocarbon or a hydrocarbon radical having from 1 to about 6 carbon atoms, Q is a polar radical of the general formula -R ¹ HZ, wherein R ^{1 is} a divalent connecting group attached to hydrogen and the Z is an organic, amino-functional radical containing at least one amino-functional group, carbon and hydrogen atoms, carbon, hydrogen and oxygen atoms or carbon, hydrogen and nitrogen atoms; "a" assumes values in the range of about 0 to about 2, "b" assumes values in the range of about 1 to about 3, "a" + "b" is less than or equal to 3, and "c" is a number in the range from about 1 to about 3, and x is a number ranging from 1 to about 2,000, preferably from about 3 to about 50, and most preferably from about 3 to about 25, and y is a number ranging from about 20 to about 10,000 , preferably from about 125 to about 10,000, and most preferably from about 150 to about 1,000, and IvI is a suitable silicone end group as known in the art, preferably trimethylsiloxy. Non-limiting examples of the groups represented by R include alkyl groups such as methyl, ethyl, propyl, isopropyl, isopropyl, butyl, isobutyl, amyl, isoamyl, hexyl, isohexyl and the like; Alkenyl radicals such as vinyl, halovinyl, alkylvinyl, allyl, haloallyl, alkylallyl; Cycloalkyl radicals such as cyclobutyl, cyclopentyl, cyclohexyl and the like; Phenyl radicals, benzyl radicals, halohydrocarbon radicals such as 3-chloropropyl, 4-bromobutyl, 3,3,3-trifluoropropyl, chlorocyclohexyl, bromophenyl, chlorophenyl and the like, and sulfur containing radicals such as mercaptoethyl, mercaptopropyl, mercaptohexyl, mercaptophenyl and the like; preferably R is an alkyl radical containing from 1 to about 6 carbon atoms, and most preferably R is methyl. Examples of R ¹ include methylene, ethylene, propylene, hexamethylene, decamethylene, -CH ₂ CH (CH ₃ ) CH ₂ -, phenylene, naphthylene, -CH ₂ CH ₂ SCH ₂ CH ₂ -, -CH ₂ CH ₂ OCH ₂ - , -OCH ₂ CH ₂ -, -OCH ₂ CH ₂ CH ₂ -, -CH ₂ CH (CH ₃ ) C (O) OCH ₂ -, - (CH ₂ J ₃ CC (O) OCH ₂ CH ₂ -, - C ₆ H ,, C ₆ H ₄ -, -C ₆ H ₄ CH ₂ C ₆ H ₄ -; and - (CH ₂ ) ₃ C (O) SCH ₂ CH ₂ -. Z is an organic, amino-functional radical containing at least one functional amino group. A possible formula for Z is NH (CH ₂ ) _Z NH ₂ , wherein z is 1 or more. Another possible formula for Z is -NH (CH ₂ ) _Z (CH ₂ Jz ₂ NH, wherein both z and zz are independently 1 or more, this structure comprising diamino ring structures, such as piperazinyl, Z is most preferably a - . NHCH ₂ CH ₂ NH ₂ radical another possible formula for Z is - N (CH ₂₎ _Z (CH ₂₎ _Z2 NX ₂ or -NX ₂ wherein each X of X ₂ is independently selected from the group consisting of hydrogen and alkyl groups of 1 to 12 carbon atoms, and z is 0.

Q is most preferably a polar, amine functional group of the formula -CH ₂ CH ₂ CH ₂ NHCH ₂ CH ₂ NH ₂ . In the formulas, "a" assumes values in the range of about 0 to about 2, "b" assumes values in the range of about 2 to about 3, "a" + "b" is less than or equal to 3, and "c "is a number in the range of about 1 to about 3. the molar ratio of R _a Q _b SiO _{/ 2} units to R _c SiO _(4κ ₍₄ _a. _{_b.);} y ₂ units is in the range of about From 1: 2 to 1:65, preferably from about 1: 5 to about 1: 65, and most preferably from about 1: 15 to about 1: 20. When one or more silicones of the above formula are employed then the various variable substituents in of the above formula may be different for the various silicone components present in the silicone blend.

Preferred agents according to the invention are characterized in that they contain an amino-functional silicone of the formula (S4-II)

R ' _a G ₃ . _a -Si (OSiG ₂ ) _n - (OSiG _b R ' _2, _b ) _m -O-SiG ₃ . _a -R _'a (S4 - II),

contain, in which means:

G is -H, a phenyl group, -OH, -O-CH ₃ , -CH ₃ , -CH ₂ CH ₃ , -CH ₂ CH ₂ CH ₃ , -CH (CH ₃ J ₂ , -

CH ₂ CH ₂ CH ₂ H ₃ , -CH ₂ CH (CH ₃ ) ₂ , -CH (CH ₃ ) CH ₂ CH ₃ , -C (CH ₃ J ₃ ; a is a number between 0 and 3, in particular 0 b is a number between 0 and 1, in particular 1, m and n are numbers whose sum (m + n) is between 1 and 2000, preferably between 50 and 150, where n preferably values from 0 to 1999 and in particular from 49 to 149 and m preferably assumes values from 1 to 2000, in particular from 1 to 10,

R ^' is a monovalent radical selected from o -N (R ¹¹ J-CH ₂ -CH ₂ -N (R ") ₂ o -N (R ¹¹ J ₂ o -N ⁺ (R ¹¹ J ₃ A ^" o -N ⁺ H (R ¹¹ J ₂ A ^" o -N ⁺ H ₂ (R ¹¹ JA- O -N (R ¹¹ J-CH ₂ -CH ₂ -N ⁺ R ¹¹ H ₂ A ^" where each R "is the same or various radicals from the group -H, -phenyl, -benzyl, the d. ^ - alkyl radicals, preferably -CH ₃ , -CH ₂ CH ₃ , -CH ₂ CH ₂ CH ₃ , - CH (CH ₃ ) _2l -CH ₂ CH ₂ CH ₂ H ₃ , -CH ₂ CH (CH ₃ ) ₂ , -CH (CH ₃ ) CH ₂ CH ₃ , -C (CH ₃ J ₃ , and A is an anion which is preferably selected from chloride, bromide, iodide or methosulfate.

Particularly preferred agents according to the invention are characterized in that they contain an amino-functional silicone of the formula (S4-III)

(CH ₃ ) ₃ Si - [O-Si (CH ₃ ) ₂ ] _n [OSi (CH ₃ )] _m - OSi (CH ₃ ) ₃ (S 4 - III),

I CH ₂ CH (CH ₃ ) CH ₂ NH (CH ₂ ) ₂ NH ₂

in which m and n are numbers whose sum (m + n) is between 1 and 2000, preferably between 50 and 150, where n preferably values of 0 to 1999 and in particular of 49 to 149 and m preferably values of 1 to 2000 , in particular from 1 to 10 assumes.

These silicones are referred to as trimethylsilylamodimethicones according to the INCI declaration.

Agents according to the invention which are characterized in that they contain an amino-functional silicone of the formula (S4-IV) are also particularly preferred.

R- [Si _(CH3 J ₂ -O] _n [Si (R) -O] _m - [Si (CH ₃₎ _2] _n2 -R (S4 - IV),

I (CH ₂ ) ₃ NH (CH ₂ ) ₂ NH ₂

in which R is -OH, -O-CH ₃ or a -CH ₃ group and m, n1 and n2 are numbers whose sum (m + n1 + n2) is between 1 and 2,000, preferably between 50 and 150 , where the sum (n1 + n2) preferably assumes values from 0 to 1999 and in particular from 49 to 149 and m preferably values from 1 to 2000, in particular from 1 to 10.

These silicones are referred to as amodimethicones according to the INCI declaration.

Regardless of which amino-functional silicones are used, agents according to the invention are preferred in which the amino-functional silicone has an amine number above 0.25 meq / g, preferably above 0.3 meq / g and in particular above 0.4 meq / g , The amine number stands for the milliequivalents of amine per gram of amino-functional silicone. It can be determined by titration and also expressed in mg KOH / g.

When the amodimethicones (S4) are contained in the base composition, these compositions contain 0.01 to 10% by weight, preferably 0.1 to 8% by weight, more preferably 0.25 to 7.5% by weight and in particular 0.5 to 5% by weight of amodimethicone based on the composition.

If different silicones are used as a mixture, the mixing ratio is largely variable. Preferably, however, all silicones used for mixing are used in a ratio of 5: 1 to 1: 5 in the case of a binary mixture. A ratio of 3: 1 to 1: 3 is particularly preferred. Very particularly preferred mixtures contain all the silicones contained in the mixture largely in a ratio of about 1: 1, in each case based on the amounts used in wt.%.

When the silicone mixture is contained in the base composition, these compositions contain 0.01 to 10% by weight, preferably 0.1 to 8% by weight, more preferably 0.25 to 7.5% by weight, and especially 0.5 to 5% by weight of silicone mixture based on the composition.

In a further preferred embodiment, the effect of the active ingredient according to the invention can be increased by emulsifiers. Such emulsifiers are, for example

Addition products of 4 to 30 moles of ethylene oxide and / or 0 to 5 moles of propylene oxide to linear fatty alcohols having 8 to 22 carbon atoms, to fatty acids having 12 to 22 carbon atoms and to alkylphenols having 8 to 15 carbon atoms in the alkyl group,

C ₂ -C ₂₂ fatty acid monoesters and diesters of addition products of 1 to 30 mol ethylene oxide onto polyols containing 3 to 6 carbon atoms, in particular glycerol,

Ethylene oxide and polyglycerol addition products to methyl glucoside fatty acid esters, fatty acid alkanolamides and fatty acid glucamides,

C ₈ -C ₂₂ -alkyl mono- and oligoglycosides and their ethoxylated analogues, with degrees of oligomerization of from 1.1 to 5, in particular from 1.2 to 2.0, and glucose being preferred as the sugar component,

Mixtures of alkyl (oligo) glucosides and fatty alcohols to example, the commercially available product ^® Montanov 68,

Addition products of 5 to 60 moles of ethylene oxide with castor oil and hydrogenated castor oil, partial esters of polyols having 3 to 6 carbon atoms with saturated fatty acids having 8 to 22 carbon atoms,

Sterols. Sterols are understood to mean a group of steroids which have a hydroxyl group on C-atom 3 of the steroid skeleton and are isolated both from animal tissue (zoosterols) and from vegetable fats (phytosterols). Examples of zoosterols are cholesterol and lanosterol. Examples of suitable phytosterols are ergosterol, stigmasterol and sitosterol. Mushrooms and yeasts are also used to isolate sterols, the so-called mycosterols. Phospholipids. These include, in particular, the glucose phospholipids which are obtained, for example, as lecithins or phosphatidylcholines from, for example, egg yolks or plant seeds (for example soybeans).

Fatty acid esters of sugars and sugar alcohols, such as sorbitol,

Polyglycerols and polyglycerol derivatives such as polyglycerol poly-12-hydroxystearate

(Dehymuls ^® PGPH commercial product)

Linear and branched fatty acids having 8 to 30 carbon atoms and their Na, K, ammonium, Ca,

Mg and Zn salts.

The agents according to the invention preferably contain the emulsifiers in amounts of 0.1-25% by weight, in particular 0.5-15% by weight, based on the total agent.

The compositions according to the invention may preferably contain at least one nonionic emulsifier having an HLB value of 8 to 18, according to the methods described in the Römpp-Lexikon Chemie (Hrg. J. Falbe, M. Regitz), 10th edition, Georg Thieme Verlag Stuttgart, New York, (1997), page 1764, listed definitions. Nonionic emulsifiers having an HLB value of 10 to 15 may be particularly preferred according to the invention.

As further advantageous, it has been found that further polymers can further support the action of the preparations according to the invention. In a preferred embodiment, polymers are therefore added to the compositions according to the invention, both anionic, amphoteric and nonionic polymers having proven effective.

The anionic polymers which can support the action of the preparations according to the invention are anionic polymers which have carboxylate and / or sulfonate groups. Examples of anionic monomers from which such polymers may consist are acrylic acid, methacrylic acid, crotonic acid, maleic anhydride and 2-acrylamido-2-methylpropanesulfonic acid. The acidic groups may be wholly or partly present as sodium, potassium, ammonium, mono- or triethanolammonium salt. Preferred monomers are 2-acrylamido-2-methylpropanesulfonic acid and acrylic acid.

Anionic polymers which contain 2-acrylamido-2-methylpropanesulfonic acid as the sole or co-monomer can be found to be particularly effective, it being possible for all or some of the sulfonic acid group to be present as sodium, potassium, ammonium, mono- or triethanolammonium salt ,

More preferably, the homopolymer of 2-acrylamido-2-methyl propane sulfonic acid, which is available for example under the name Rheothik ^® 11-80 is commercially. Within this embodiment, it may be preferable to use copolymers of at least one anionic monomer and at least one nonionic monomer. With regard to the anionic monomers, reference is made to the substances listed above. Preferred nonionic monomers are acrylamide, methacrylamide, acrylic esters, methacrylic esters, vinylpyrrolidone, vinyl ethers and vinyl esters.

Preferred anionic copolymers are acrylic acid-acrylamide copolymers and in particular polyacrylamide copolymers with sulfonic acid-containing monomers. A particularly preferred anionic copolymer consists of 70 to 55 mol% of acrylamide and 30 to 45 mol% of 2-acrylamido-2-methylpropanesulfonic acid, wherein the sulfonic acid group is wholly or partly in the form of sodium, potassium, ammonium, mono- or triethanolammonium Salt is present. This copolymer may also be crosslinked, with crosslinking agents preferably polyolefinically unsaturated compounds such as tetraallyloxyethane, allylsucrose, allylpentaerythritol and methylene-bisacrylamide are used. Such a polymer is contained in the commercial product Sepigel ^® 305 from SEPPIC. Use of this compound, in addition to the polymer component is a hydrocarbon mixture (C ₁₃ -C ₄ - isoparaffin) and a non-ionic emulsifier (Laureth-7), has proved to be particularly advantageous in the context of the teaching according to the invention.

Also sold under the name Simulgel ^® 600 as a compound with isohexadecane and polysorbate-80 Natriumacryloyldimethyltaurat copolymers have proved to be particularly effective according to the invention.

Likewise preferred anionic homopolymers are uncrosslinked and crosslinked polyacrylic acids. Allyl ethers of pentaerythritol, sucrose and propylene may be preferred crosslinking agents. Such compounds are for example available under the trademark Carbopol ^® commercially.

Copolymers of maleic anhydride and methyl vinyl ether, especially those with crosslinks, are also color-retaining polymers. A 1, 9-decadiene crosslinked maleic acid methyl vinyl ether copolymer is available under the name Stabileze® ^® QM.

Furthermore, amphoteric polymers can be used as polymers to increase the activity of the preparations according to the invention. The term amphoteric polymers includes both those polymers which contain both free amino groups and free -COOH or SO ₃ H groups in the molecule and are capable of forming internal salts, as well as zwitterionic polymers which contain quaternary ammonium groups and -COO in the molecule ^' or -SO ₃ ^' groups, and those polymers comprising -COOH or SO ₃ H groups and quaternary ammonium groups.

An example of the present invention amphopolymer suitable is that available under the name Amphomer ^® acrylic resin which is a copolymer of tert-butylaminoethyl methacrylate, N- (1, 1, 3,3-tetramethylbutyl) acrylamide and two or more monomers from the group of acrylic acid, methacrylic acid and their simple esters.

Further amphoteric polymers which can be used according to the invention are the compounds mentioned in British Patent Application 2,104,091, European Patent Application 47,714, European Offenlegungsschrift 217,274, European Offenlegungsschrift 283,817 and German Offenlegungsschrift 28 17 369.

Preferably used amphoteric polymers are those polymers which are composed essentially

(a) monomers having quaternary ammonium groups of the general formula (G3-I), R ¹ -CH = CR ² -CO-Z- (C _n H _2n ) -N ^(+> R ³ R ⁴ R ⁵ A ^H (G ³ I) in which R ¹ and R ^{2 are} independently of one another hydrogen or a methyl group and R ³ , R ⁴ and R ⁵ are each independently alkyl groups having 1 to 4 carbon atoms, Z is an NH group

(-) or an oxygen atom, n is an integer from 2 to 5 and A is the anion of an organic or inorganic acid, and

(B) monomeric carboxylic acids of the general formula (G3-II), R ⁶ -CH = CR ⁷ -COOH (G3-II) in which R ⁶ and R ^{7 are} independently hydrogen or methyl groups.

These compounds can be used both directly and in salt form, which is obtained by neutralization of the polymers, for example with an alkali metal hydroxide, according to the invention. With regard to the details of the preparation of these polymers is expressly made to the content of German Patent Application 39 29 973 reference. Very particular preference is given to those polymers in which monomers of the type (a) are used in which R ³ , R ⁴ and R ^{5 are} methyl groups, Z is an NH group and A ^{() is} a halide, methoxysulfate or ethoxysulfate ion is; Acrylamidopropyl trimethyl ammonium chloride is a particularly preferred monomer (a). Acrylic acid is preferably used as monomer (b) for the stated polymers.

In a further embodiment, the agents according to the invention may contain nonionogenic polymers.

Suitable nonionic polymers are, for example:

Vinylpyrrolidone / vinyl ester copolymers, as sold, for example, under the trademark Luviskol ^® (BASF). Luviskol ^® VA 64 and Luviskol ^® VA 73, each vinylpyrrolidone / vinyl acetate copolymers are also preferred nonionic polymers.

Cellulose ethers such as hydroxypropyl cellulose, hydroxyethyl cellulose and hydroxypropylcellulose Methylhy- as they are for example sold under the trademark Culminal® ^® and Benecel ^® (AQUALON). shellac Polyvinylpyrrolidones, as sold for example under the name Luviskol ^® (BASF).

Siloxanes. These siloxanes may be both water-soluble and water-insoluble. Both volatile and nonvolatile siloxanes are suitable, nonvolatile siloxanes being understood as meaning those compounds whose boiling point is above 200 ^° C. under normal pressure. Preferred siloxanes are polydialkylsiloxanes, such as, for example, polydimethylsiloxane, polyalkylarylsiloxanes, for example polyphenylmethylsiloxane, ethoxylated polydialkylsiloxanes and polydialkylsiloxanes which contain amine and / or hydroxyl groups. - Glycosidically substituted silicones according to EP 0612759 B1.

It is also possible according to the invention that the preparations used contain a plurality, in particular two, different polymers of the same charge and / or in each case an ionic and an amphoteric and / or nonionic polymer.

The polymers are contained in the agents used according to the invention preferably in amounts of 0.05 to 10 wt .-%, based on the total agent. Amounts of 0.1 to 5, in particular from 0.1 to 3 wt .-%, are particularly preferred.

Other active ingredients, auxiliaries and additives are, for example

Thickeners such as agar-agar, guar gum, alginates, xanthan gum, gum arabic, karaya

Gum, locust bean gum, linseed gums, dextrans, cellulose derivatives, e.g. B.

Methylcellulose, hydroxyalkylcellulose and carboxymethylcellulose, starch fractions and

Derivatives such as amylose, amylopectin and dextrins, clays such. B. bentonite or fully synthetic

Hydrocolloids such. As polyvinyl alcohol, hair conditioning compounds such as phospholipids, such as soybean lecithin, egg lecithin and

Cephalins, as well as silicone oils,

Perfume oils, dimethylisosorbide and cyclodextrins,

Solvents and mediators such as ethanol, isopropanol, ethylene glycol, propylene glycol, glycerol and diethylene glycol, fiber-structure-improving active compounds, in particular mono-, di- and oligosaccharides, such as, for example, glucose, galactose, fructose, fructose and lactose,

Defoamers like silicones,

Dyes for staining the agent,

Anti-dandruff agents such as Piroctone Olamine, Zinc Omadine and Climbazole,

Active ingredients such as allantoin and bisabolol, cholesterol,

Bodying agents such as sugar esters, polyol esters or polyol alkyl ethers,

Fats and waxes such as spermaceti, beeswax, montan wax and paraffins,

fatty acid,

Complexing agents such as EDTA, NTA ₁ β-alaninediacetic acid and phosphonic acids,

Swelling and penetration substances such as primary, secondary and tertiary phosphates, Opacifiers such as latex, styrene / PVP and styrene / acrylamide copolymers,

Pearlescing agents such as ethylene glycol mono- and distearate and PEG-3-distearate,

pigments

Propellants such as propane-butane mixtures, N ₂ O, dimethyl ether, CO ₂ and air,

Antioxidants.

With regard to further optional components as well as the amounts of these components used, reference is expressly made to the relevant manuals known to the person skilled in the art, eg. B. the monograph by K. H. Schrader, bases and formulations of cosmetics, 2nd edition, Hüthig book Verlag Heidelberg, 1989, referenced.

The cleaning agents according to the invention are not subject to any restrictions with regard to their formulation form and can be formulated as emulsion, cream, solution, gel or mousse.

A second subject of the invention is a process for stabilizing water-insoluble silicones in surfactant systems, which comprises introducing hardened castor oil into the surfactant mixture with the water-insoluble silicone.

In a particularly preferred embodiment of this process, the hardened castor oil is introduced into the surfactant mixture in a finely distributed manner by means of a hot process.

A third object of the invention is the use of hardened castor oil for stabilizing water-insoluble silicone components in surfactant systems.

Particularly preferred is the use of the hardened castor oil, which is introduced via a hot process finely distributed in the surfactant mixture.

The following examples are intended to illustrate the invention without limiting it thereto.

Unless stated otherwise, the quantities given in the examples relate to% by weight.

Examples:

The following shampoos 1 to 10 were prepared by a usual method. The Hydrogenated Castor OiI was melted prior to addition to the water-surfactant mixture and added with stirring.

kV: no change

S .: Separation phenomena

LS .: slight separation phenomena

Examples 1, 3, 5, 7 and 9 show that stabilization of the hydrogenated castor oil does not lead to phase separation of the silicone component even after prolonged storage at elevated temperatures.

An addition of gelling agents (Examples 7 to 10) is not necessary for the stabilization, as shown in particular Examples 1, 3 and 5 compared to Examples 7 and 9.

Claims

claims:

1. Surfactant-containing cleaning agent, characterized in that it comprises for stabilizing a water-insoluble silicone component, the following active ingredient combination of a) a washing base containing at least one anionic surfactant, b) a water-insoluble silicone and c) hardened castor oil in a weight ratio a): b): c ) of (10 - 150): (1, 0 - 40): 1.

2. Surfactant-containing cleaning agent according to claim 1, characterized in that the washing base comprises a mixture of at least one anionic surfactant with an amphoteric and / or zwitterionic and / or a nonionic surfactant.

3. Surfactant-containing cleaning agent according to any one of claims 1 or 2, characterized in that it contains - based on its total weight - 5 to 35%, preferably 7 to 25% and in particular 8 to 15% of the washing base a).

4. Surfactant-containing cleaning agent according to one of claims 1 to 3, characterized in that it contains water-insoluble silicones from the group of polydialkylsiloxanes, polyalkylaryl siloxanes and / or polydiarylsiloxanes and / or dihydroxypolydimethylsiloxanes.

5. surfactant-containing cleaning agent according to one of claims 1 to 4, characterized in that the water-insoluble silicone has a viscosity in the range of 0.600 to 600,000 cSt.

6. Surfactant-containing cleaning agent according to any one of claims 1 to 5, characterized in that it contains - based on its total weight - 0.01 to 10%, preferably 0.1 to 5% and in particular 0.2 to 3% of the water-insoluble silicone.

7. Surfactant-containing cleaning agent according to any one of claims 1 to 6, characterized in that it is the hardened castor oil - based on its total weight - in an amount of 0.01 to 5%, preferably 0.05 to 3% and in particular 0.1 to 2%, contains.

8. surfactant-containing cleaning agent according to any one of claims 1 to 7, characterized in that it further contains at least one cationic polymer.

9. surfactant-containing cleaning agent according to any one of claims 1 to 8, characterized in that further at least one member selected from the group of water-insoluble oil components, vitamins, provitamins, protein hydrolysates, plant extracts, UV filters, amino acids, water-insoluble silicones containing water-soluble and / or amodimethicones.

10. surfactant-containing cleaning agent according to claim 9, characterized in that it contains as water-insoluble oil component mineral, vegetable, animal and / or synthetic oils.

11. A method for stabilizing water-insoluble silicones in surfactant systems, characterized in that hardened castor oil is introduced into the surfactant mixture with the water-insoluble silicone.

12. The method according to claim 11, characterized in that the hardened castor oil is introduced via a hot process finely distributed in the surfactant mixture.

13. Use of hardened castor oil for stabilizing water-insoluble silicone components in surfactant systems.

14. Use according to claim 13, characterized in that the hardened castor oil is introduced via a hot process finely distributed in the surfactant mixture.