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WO2006007268A1 - Vulcanisats a base d'elastomere et de silicone - Google Patents

Vulcanisats a base d'elastomere et de silicone Download PDF

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Publication number
WO2006007268A1
WO2006007268A1 PCT/US2005/019320 US2005019320W WO2006007268A1 WO 2006007268 A1 WO2006007268 A1 WO 2006007268A1 US 2005019320 W US2005019320 W US 2005019320W WO 2006007268 A1 WO2006007268 A1 WO 2006007268A1
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WO
WIPO (PCT)
Prior art keywords
elastomer
organopolysiloxane
cure
silicone
groups
Prior art date
Application number
PCT/US2005/019320
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English (en)
Inventor
Igor Chorvath
Lauren Marie Tonge
Original Assignee
Dow Corning Corporation
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Filing date
Publication date
Application filed by Dow Corning Corporation filed Critical Dow Corning Corporation
Priority to JP2007519230A priority Critical patent/JP2008505207A/ja
Priority to US11/596,944 priority patent/US20070249772A1/en
Priority to EP05756147A priority patent/EP1789496A1/fr
Publication of WO2006007268A1 publication Critical patent/WO2006007268A1/fr

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08L27/16—Homopolymers or copolymers or vinylidene fluoride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L21/00—Compositions of unspecified rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/20—Polysiloxanes containing silicon bound to unsaturated aliphatic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
    • C08G77/26—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen nitrogen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
    • C08G77/28—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen sulfur-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/70—Siloxanes defined by use of the MDTQ nomenclature
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms

Definitions

  • the present invention relates to a method of making an elastomeric composition comprising silicone and another elastomer based on static vulcanization of the silicone.
  • the invention further relates to the product prepared by the method, and the cured elastomeric composition obtained therefrom.
  • Silicone rubber is characterized by good high and low temperature properties, weather resistance and processing characteristics.
  • U.S. 4,942,202 teaches a rubber composition and vulcanized rubber products.
  • the '202 compositions are prepared by reacting an organic peroxide, under shear deformation, with (I) a silicone rubber, (II) a saturated elastomer that fails to react with an organic peroxide when it is used alone, and (III) another elastomer that is co-crosslinkable with the silicone rubber in the presence of an organic peroxide.
  • the other elastomer (III) is also co- crosslinkable or highly miscible with component (II).
  • U.S. 5,010,137 teaches rubber compositions, which include elastomers, and oil seals and rubber hoses obtained therefrom.
  • the '137 compositions are obtained by compounding a polyorganohydrogensiloxane and a group VIII transition metal compound with a rubber- forming polymer comprising (I) a vinyl containing polyorganosiloxane and (II) an organic rubber, and subjecting the resulting compound to hydrosilylation while effecting shear deformation.
  • U.S. 5,171,787 teaches silicone-based composite rubber compositions and uses thereof.
  • the '787 compositions are prepared by compounding a (A) rubber forming polymer comprising a polyorganosiloxane and an organic rubber, (B) a silicon compound having at least two hydrolyzable groups per molecule, and (C) a heavy metal compound, amine, or quaternary ammonium salt which catalyzes the hydrolysis and condensation reaction; and allowing the resulting formulation to undergo hydrolysis and condensation reactions while the formulation is kept from being deformed by shearing; and a crosslinking agent subsequently added followed by crosslinking of said organic rubber.
  • A rubber forming polymer comprising a polyorganosiloxane and an organic rubber
  • B a silicon compound having at least two hydrolyzable groups per molecule
  • C a heavy metal compound, amine, or quaternary ammonium salt which catalyzes the hydrolysis and condensation reaction
  • 5,350,804 teaches a composite rubber composition which comprises (a) an organic rubbery elastomer composition having a Mooney viscosity of at least 70 at 100°C forming the matrix phase of the composite rubber composition; and (b) cured silicone rubber as a dispersed phase in the matrix phase.
  • the present invention provides elastomeric compositions based on the incorporation of silicones with other elastomers using a static vulcanization process. These elastomeric compositions result from the new mixing processes of the present invention. These new mixing processes provide compositions having significant quantities of a silicone rubber based composition incorporated into another elastomer. However, the resulting cured elastomeric composition prepared from the elastomeric compositions of the present invention, maintain many of the desirable physical property attributes of the elastomers.
  • This invention provides a method for preparing an elastomeric composition containing both an elastomer and a silicone wherein a silicone base is mixed with another elastomer, and the silicone base is subsequently statically vulcanized within the elastomer.
  • the present invention relates to a method for preparing an elastomeric composition comprising:
  • the invention further relates to the elastomer compositions obtained by the present method and cured elastomeric compositions prepared therefrom.
  • Component (A) is an elastomer having a glass transition temperature (Tg) below room temperature, alternatively below 23°C, alternatively, below 15°C, alternatively below 0°C.
  • Glass transition temperature means the temperature at which a polymer changes from a glassy vitreous state to a rubbery state.
  • the glass transition temperature can be determined by conventional methods, such as dynamic mechanical analysis (DMA) and Differential Scanning Calorimetry (DSC).
  • DMA dynamic mechanical analysis
  • DSC Differential Scanning Calorimetry
  • an "elastomer” excludes silicone based elastomers also known as silicone rubbers.
  • the elastomeric component (A) can be selected from any of the major classes of elastomers and rubbers (ASTM nomenclature shown in parentheses) that are known in the art as natural rubber (NR), isoprene rubber (IR), styrene- butadiene rubber (SBR), butadiene rubber (BR), chloroprene rubber (CR), chlorinated polyethylene (CPE), butyl rubber, acrylonitrile-butadiene rubber (NBR), chlorosulfonated polyethylene (CSM), acrylic rubber (ACM), epichlorohydrin rubber (ECO), ethylene-vinyl acetate rubber (EVM), ethylene-acrylic rubber, ethylene- ⁇ -olefin copolymerized rubber, ethylene- ⁇ -olefin-diene terpolymerized rubber (EPDM), fluorocarbon elastomers (FKM), and hydrogenated nitrile rubber (HNBR).
  • ASTM nomenclature shown in parentheses that are
  • the elastomer is a high performance elastomer selected from chlorosulfonated polyethylene (CSM), chlorinated polyethylene (CPE/CM), ethylene-vinyl acetate rubber (EVM), epichlorohydrin rubber (ECO), and acrylic rubber (ACM).
  • CSM chlorosulfonated polyethylene
  • CPE/CM chlorinated polyethylene
  • EVM ethylene-vinyl acetate rubber
  • ECO epichlorohydrin rubber
  • ACM acrylic rubber
  • the elastomer is selected from ethylene- ⁇ -olefin-diene terpolymerized rubber (EPDM), hydrogenated nitrile rubber (HNBR), and fluorocarbon elastomers (FKM).
  • (A) is selected from an elastomer comprising a polymer that can react with the compatibilizer (B) and optionally catalyst (C) to produce a modified elastomer.
  • any elastomer or modified elastomers can be selected as component (A) providing that the elastomer contains at least one group capable of reacting with at least a portion of the silicone base.
  • the elastomer should be capable of reacting with the silicone base via the operative cure mechanism selected for the organopolysiloxane.
  • a cure agent (F) is added to the organopolysiloxane, component (D), and optionally crosslinker component (E), to cure the organopolysiloxane via a static vulcanization process.
  • the cure chemistry occurring at the surface of the silicone compound can also react with the elastomer, which furthers the dispersion of the silicone within the elastomer.
  • the reactive groups on the elastomer include methyl, methylene, vinyl, and halogens.
  • a methyl or methylene group on the elastomer could react with a peroxide, selected as the cure agent for the silicone compound, thus forming a bond between the organopolysiloxane and the elastomer.
  • a vinyl group on the elastomer could react via the addition cure mechanism or radical cure mechanism.
  • the elastomer, component (A) can be a mixture of polymers.
  • at least 2 wt. %, alternatively at least 5 wt. %, or alternatively at least 10% of the elastomer composition should contain a polymer having a reactive group capable of reacting with the cure chemistry of the organopolysiloxane.
  • Optional compatibilizer (B) can be selected from any hydrocarbon, organosiloxane, fluorocarbon, or combinations thereof that would be expected to modify the elastomer in a manner to enhance the mixing of the silicone base (D) with the elastomer (A) to produce a mixture having a continuous elastomer phase and a discontinuous (i.e. internal phase) silicone phase.
  • the compatibilizer can be one of two types.
  • the compatibilizer is selected from any hydrocarbon, organosiloxane, fluorocarbon , or combinations thereof, that would not be expected to react with the elastomer (A), yet still enhance the mixing of the elastomer with the silicone base.
  • the compatibilizer is selected from any hydrocarbon, organosiloxane, or fluorocarbon or combinations thereof that could react chemically with the elastomers and or silicone rubber.
  • the compatibilizer must not prevent the static cure of the organopolysiloxane component, described infra.
  • the compatibilizer (B) can be selected from any compatibilizer known in the art to enhance the mixing of a silicone base with an elastomer.
  • the compatibilizer (B) can be selected from (B 1 ) organic (i.e., non-silicone) compounds which contain 2 or more olefin groups, (B ) organopolysiloxanes containing at least 2 alkenyl groups,(B ) olefin-functional silanes which also contain at least one hydrolyzable group or at least one hydroxyl group attached to a silicon atom thereof, (B 4 ) an organopolysiloxane having at least one organofunctional groups selected from amine, amide, isocyanurate, phenol, acrylate, epoxy, and thiol groups, (B ) an dehydrofluorination agent, and any combinations of (B ), (B ), (B 3 ), (B 4 ), and (B 5 ).
  • Organic compatibilizer (B') can be illustrated by compounds such as diallyphthalate, triallyl isocyanurate, 2,4,6-triallyloxy-l,3,5-triazine, triallyl trimesate, 1,5-hexadiene, low molecular weight polybutadienes, 1,7-octadiene, 2,2'-diallylbisphenol A, N,N'-diallyl tartardiamide, diallylurea, diallyl succinate and divinyl sulfone, inter alia.
  • Compatibilizer (B") may be selected from linear, branched or cyclic organopolysiloxanes having at least 2 alkenyl groups in the molecule.
  • organopolysiloxanes examples include divinyltetramethyldisiloxane, cyclotrimethyltrivinyltrisiloxane, cyclo-tetramethyltetravinyltetrasiloxane, hydroxy end-blocked polymethylvinylsiloxane, hydroxy terminated polymethylvinylsiloxane-co-polydimethylsiloxane, dimethylvinylsiloxy terminated polydimethylsiloxane, tetrakis(dimethylvinylsiloxy)silane and tris(dimethylvinylsiloxy)phenylsilane.
  • compatibilizer (B) is a hydroxy terminated polymethylvinylsiloxane [HO(MeViSiO) x H] oligomer having a viscosity of about 25 - 100 m Pa-s, containing 20- 35% vinyl groups and 2 - 4% silicon-bonded hydroxy groups.
  • Compatibilizer (B') is a silane, which contains at least one alkylene group, typically comprising vinylic unsaturation, as well as at least one silicon-bonded moiety selected from hydrolyzable groups or a hydroxyl group.
  • Suitable hydrolyzable groups include alkoxy, aryloxy, acyloxy or amido groups.
  • silanes examples include vinyltriethoxysilane, vinyltrimethoxysilane, hexenyltriethoxysilane, hexenyltrimethoxy, methylvinyldisilanol, octenyltriethoxysilane, vinyltriacetoxysilane, vinyltris(2-ethoxyethoxy)silane, methylvinylbis(N-methylacetamido)silane, methylvinyldisilanol.
  • Compatibilizer (B") is an organopolysiloxane having at least one organofunctional groups selected from amine, amide, isocyanurate, phenol, acrylate, epoxy, and thiol groups.
  • a portion of the curable organopolysiloxane of the silicone base component (D) described infra can also function as a compatibilizer.
  • a catalyst (C) can be used to first react a portion of the curable organopolysiloxane of silicone base (D) with the elastomer to produce a modified elastomer. The modified elastomer is then further mixed with the remaining silicone base (D) containing the curable organopolysiloxane, and the organopolysiloxane is statically vulcanized as described infra.
  • the amount of compatibilizer used per 100 parts of elastomer can be determined by routine experimentation. Typically, 0.05 to 15 parts by weight, alternatively 0.05 to 10 parts by weight, or alternatively 0.1 to 5 parts of the compatibilizer is used for each 100 parts of elastomer (A).
  • Optional component (C) is a catalyst.
  • the catalyst is used in the chemically modified embodiment.
  • it is typically a radical initiator selected from any organic compound, which is known in the art to generate free radicals at elevated temperatures.
  • the initiator is not specifically limited and may be any of the known azo or diazo compounds, such as 2,2'-azobisisobutyronitrile, but it is preferably selected from organic peroxides such as hydroperoxides, diacyl peroxides, ketone peroxides, peroxyesters, dialkyl peroxides, peroxydicarbonates, peroxyketals, peroxy acids, acyl alkylsulfonyl peroxides and alkyl monoperoxydicarbonates.
  • the modification temperature depends upon the type of elastomer and compatibilizer chosen and is typically as low as practical consistent with uniform mixing of components (A) through (C).
  • suitable peroxides which may be used according to the method of the present invention include: 2,5- dimethyl-2,5-di(tert-butylperoxy)hexane; benzoyl peroxide; dicumyl peroxide; t-butyl peroxy O-toluate; cyclic peroxyketal; t-butyl hydroperoxide; t-butyl peroxypivalate; lauroyl peroxide; t- amyl peroxy 2-ethylhexanoate; vinyltris(t-butyl peroxy)silane; di-t-butyl peroxide, 1 ,3 -bis(t-butylperoxyisopropyl) benzene; 2,2,4-trimethylpentyl-2-hydroperoxide;
  • Component (D) is a silicone base comprising a curable organopolysiloxane (D') and optionally, a filler (D").
  • a curable organopolysiloxane is defined herein as any organopolysiloxane having at least two curable groups present in its molecule.
  • Organopolysiloxanes are well known in the art and are often designated as comprising any number of M units (R 3 SiO 0-5 ), D units (R 2 SiO), T units (RSiO 1-5 ), or Q units (SiO 2 ) where R is independently any monovalent hydrocarbon group.
  • the organopolysiloxane in the silicone base (D) must have at least two curable groups in its molecule.
  • a curable group is defined as any hydrocarbon group that is capable of reacting with itself or another hydrocarbon group, or alternatively with a crosslinker to crosslink the organopolysiloxane. This crosslinking results in a cured organopolysiloxane.
  • organopolysiloxanes that can be used in the silicone base are the organopolysiloxanes that are known in the art to produce silicone rubbers upon curing. Representative, non-limiting examples of such organopolysiloxanes are disclosed in
  • organopolysiloxanes can be cured via a number of crosslinking mechanisms employing a variety of cure groups on the organopolysiloxane, cure agents, and optional crosslinking agent. While there are numerous crosslinking mechanisms, three of the more common crosslinking mechanisms used in the art to prepare silicone rubbers from curable organopolysiloxanes are free radical initiated crosslinking, hydrosilylation or addition cure, and condensation cure.
  • the curable organopolysiloxane can be selected from, although not limited to, any organopolysiloxane capable of undergoing any one of these aforementioned crosslinking mechanisms.
  • the selection of components (D), (E), and (F) are made consistent with the choice of cure or crosslinking mechanisms. For example if hydrosilylation or addition cure is selected, then a silicone base comprising an organopolysiloxane with at least two vinyl groups (curable groups) would be used as component (D'), an organohydrido silicon compound would be used as component (E), and a platinum catalyst would be used as component (F).
  • a silicone base comprising an organopolysiloxane having at least 2 silicon bonded hydroxy groups (ie silanol, considered as the curable groups) would be selected as component (D) and a condensation cure catalyst known in the art, such as a tin catalyst, would be selected as component (F).
  • a condensation cure catalyst known in the art, such as a tin catalyst, would be selected as component (F).
  • any organopolysiloxane can be selected as component (D), and a free radical initiator would be selected as component (F) if the combination will cure within the time and temperature constraints of the static vulcanization step (II).
  • any alkyl group, such as methyl, can be considered as the curable groups, since they would crosslink under such free radical initiated conditions.
  • the quantity of the silicone phase, as defined herein as the combination of components (D), (E) and (F), used can vary depending on the amount of elastomer (A) used.
  • It is convenient to report the weight ratio of elastomer (A) to the silicone base (D) which typically ranges from 95:5 to 30:70, alternatively 90:10 to 40:60, alternatively 80:20 to 40:60.
  • the selection of components (D), (E), and (F) can be made to produce a silicon rubber during the vulcanization process via hydrosilylation cure techniques.
  • This embodiment is herein referred to as the hydrosilylation cure embodiment.
  • (D') is selected from a diorganopolysiloxane gum, which contains at least 2 alkenyl groups having 2 to 20 carbon atoms and optionally (D"), a reinforcing filler.
  • the alkenyl group is specifically exemplified by vinyl, allyl, butenyl, pentenyl, hexenyl and decenyl, preferably vinyl or hexenyl.
  • the position of the alkenyl functionality is not critical and it may be bonded at the molecular chain terminals, in non-terminal positions on the molecular chain or at both positions.
  • the alkenyl group is vinyl or hexenyl and that this group is present at a level of 0.0001 to 3 mole percent, alternatively 0.0005 to 1 mole percent, in the diorganopolysiloxane.
  • the remaining (i.e., non- alkenyl) silicon-bonded organic groups of the diorganopolysiloxane are independently selected from hydrocarbon or halogenated hydrocarbon groups, which contain no aliphatic unsaturation.
  • alkyl groups having 1 to 20 carbon atoms such as methyl, ethyl, propyl, butyl, pentyl and hexyl
  • cycloalkyl groups such as cyclohexyl and cycloheptyl
  • aryl groups having 6 to 12 carbon atoms such as phenyl, tolyl and xylyl
  • aralkyl groups having 7 to 20 carbon atoms such as benzyl and phenylethyl
  • halogenated alkyl groups having 1 to 20 carbon atoms such as 3,3,3-trifluoropropyl and chloromethyl.
  • the non-alkenyl silicon-bonded organic groups in the diorganopolysiloxane makes up at least 85, or alternatively at least 90 mole percent, of the organic groups in the diorganopolysiloxanes.
  • polydiorganosiloxane (D 1 ) can be a homopolymer, a copolymer or a terpolymer containing such organic groups.
  • examples include homopolymers comprising dimethylsiloxy units, homopolymers comprising 3,3,3-trifluoropropylmethylsiloxy units, copolymers comprising dimethylsiloxy units and phenylmethylsiloxy units, copolymers comprising dimethylsiloxy units and 3,3,3-Mfluoropropylmethylsiloxy units, copolymers of dimethylsiloxy units and diphenylsiloxy units and interpolymers of dimethylsiloxy units, diphenylsiloxy units and phenylmethylsiloxy units, among others.
  • diorganopolysiloxane (D') include: trimethylsiloxy-endblocked dimethylsiloxane-methylvinylsiloxane copolymers; trimethylsiloxy-endblocked methylphenylsiloxane-dimethylsiloxane-methylvinylsiloxane copolymers; trimethylsiloxy-endblocked 3,3,3-trifluoropropylmethyl siloxane copolymers; trimethylsiloxy-endblocked 3,3,3 -trifluoropropylmethyl-methylvinylsiloxane copolymers; dimethylvinylsiloxy-endblocked dimethylpolysiloxanes; dimethylvinylsiloxy-endblocked dimethylsiloxane-methylvinylsiloxane copo
  • Typical systems for low temperature applications include methylphenylsiloxane- dimetiiylsiloxane-methylvinylsiloxane copolymers and diphenylsiloxane-dimethylsiloxane- methylvinylsiloxane copolymers, particularly wherein the molar content of the dimethylsiloxane units is about 85-95%.
  • the organopolysiloxane may also consist of combinations of two or more organopolysiloxanes.
  • diorganopolysiloxane (D') is a linear polydimethylsiloxane homopolymer and is preferably terminated with a vinyl group at each end of its molecule or it is such a homopolymer, which also contains at least one vinyl group along its main chain.
  • the preferred diorganopolysiloxane is a diorganopolysiloxane gum with a molecular weight sufficient to impart a Williams plasticity number of at least about 30 as determined by the American Society for Testing and Materials (ASTM) test method 926. Although there is no absolute upper limit on the plasticity of component (D'), practical considerations of processability in conventional mixing equipment generally restrict this value. Typically, the plasticity number should be 40 to 200, or alternatively 50 to 150.
  • Optional component (D") is any filler which is known to reinforce diorganopolysiloxane (D 1 ) and is preferably selected from finely divided, heat stable minerals such as fumed and precipitated forms of silica, silica aerogels and titanium dioxide having a specific surface area of at least about 50 m ⁇ /gram.
  • the fumed form of silica is a typical reinforcing filler based on its high surface area, which can be up to 450 m ⁇ /gram.
  • a fumed silica having a surface area of 50 to 400 m ⁇ /g, or alternatively 90 to 380 m ⁇ /g can be used.
  • the filler is added at a level of about 5 to about 150 parts by weight, alternatively 10 to 100 or alternatively 15 to 70 parts by weight, for each 100 parts by weight of diorganopolysiloxane
  • the filler is typically treated to render its surface hydrophobic, as typically practiced in the silicone rubber art. This can be accomplished by reacting the silica with a liquid organosilicon compound, which contains silanol groups or hydrolyzable precursors of silanol groups.
  • Compounds that can be used as filler treating agents include such ingredients as low molecular weight liquid hydroxy- or alkoxy-terminated polydiorganosiloxanes, hexaorganodisiloxanes, cyclodimethylsilazanes and hexaorganodisilazanes.
  • Component (D) may also contain other materials commonly used in silicone rubber formulations including, but not limited to, antioxidants, crosslinking auxiliaries, processing agents, pigments, and other additives known in the art which do not interfere with step (II) described infra.
  • compound (E) is added and is an organohydrido silicon compound (E'), that crosslinks with the diorganopolysiloxane (D').
  • the organohydrido silicon compound is an organopolysiloxane which contains at least 2 silicon-bonded hydrogen atoms in each molecule which are reacted with the alkenyl functionality of (D') during the static vulcanization step (II) of the present method.
  • a further (molecular weight) limitation is that Component (E') must have at least about 0.1 weight percent hydrogen, alternatively 0.2 to 2 or alternatively 0.5 to 1.7, percent hydrogen bonded to silicon.
  • the diorganopolysiloxane (D') or component (E'), or both must have a functionality greater than 2 to cure the diorganopolysiloxane (i.e., the sum of these functionalities must be greater than 4 on average).
  • the position of the silicon-bonded hydrogen in component (E') is not critical, and it may be bonded at the molecular chain terminals, in non-terminal positions along the molecular chain or at both positions.
  • the silicon-bonded organic groups of component (E') are independently selected from any of the saturated hydrocarbon or halogenated hydrocarbon groups described above in connection with diorganopolysiloxane (D'), including preferred embodiments thereof.
  • component (E') is also not critical and is exemplified by straight-chain, partially branched straight-chain, branched, cyclic and network structures, network structures, linear polymers or copolymers being typical. It will, of course, be recognized that this component must be compatible with D 1 (i.e., it is effective in curing the diorganopolysiloxane).
  • Component (E') is exemplified by the following: low molecular weight siloxanes such as PhSi(OSiMe2H)3 ; trimethylsiloxy-endblocked methylhydridopolysiloxanes; trimethylsiloxy-endblocked dimethylsiloxane-methylhydridosiloxane copolymers; dimethylhydridosiloxy-endblocked dimethylpolysiloxanes; dimethylhydrogensiloxy-endblocked methylhydrogenpolysiloxanes; dimethylhydridosiloxy-endblocked dimethylsiloxane-methylhydridosiloxane copolymers; cyclic methylhydrogenpolysiloxanes; cyclic dimethylsiloxane-methylhydridosiloxane copolymers; tetraMs(dmiethylhydrogensiloxy)silane; trimethylsiloxy-endblockedmethylhydridosiloxane polymers containing Si ⁇ 4/2 units
  • Typical organohydrido silicon compounds are polymers or copolymers comprising RHSiO units terminated with either R 3 SiOi/2 or HR2SiOj/2 units wherein R is independently selected from alkyl radicals having 1 to 20 carbon atoms, phenyl or trifluoropropyl, typically methyl. Also, typically the viscosity of component (E') is about 0.5 to 3,000 mPa-s at 25°C, alternatively 1 to 2000 mPa-s. Component (E') typically has 0.5 to 1.7 weight percent hydrogen bonded to silicon.
  • component (E') is selected from a polymer consisting essentially of methylhydridosiloxane units or a copolymer consisting essentially of dimethylsiloxane units and methylhydridosiloxane units, having 0.5 to 1.7 weight percent hydrogen bonded to silicon and having a viscosity of 1 to 2000 mPa-s at 25 0 C.
  • a typical system has terminal groups selected from trimethylsiloxy or dimethylhydridosiloxy groups.
  • component (E 1 ) is selected from copolymer or network structures comprising resin units.
  • the copolymer or network structures units comprise RS1O3/2 units or Si ⁇ 4/2 units, and may also contain R 3 Si0y2 > R2S1O2/2 3 ⁇ or RSiO 3 /2 units wherein R is independently selected from hydrogen or alkyl radicals having 1 to 20 carbon atoms, phenyl or trifluoropropyl, typically methyl. It is understood that sufficient R as hydrogen is selected such that component (E') typically has 0.5 to 1.7 weight percent hydrogen bonded to silicon. Also, typically the viscosity of component (E') is about 0.5 to 3,000 mPa-s at 25°C, alternatively 1 to 2000 mPa-s. Component (E') may also be a combination of two or more of the above described systems.
  • the organohydrido silicon compound (E') is used at a level sufficient to cure diorganopolysiloxane (D 1 ) in the presence of component (F), described infra. Typically, its content is adjusted such that the molar ratio of SiH therein to Si-alkenyl in (D') is greater than 1. Typically, this SiH/alkenyl ratio is below about 50, alternatively 1 to 20 or alternatively 1 to 12. These SiH-functional materials are well known in the art and many are commercially available.
  • component (F) is a hydrosilation catalyst (F'), that accelerates the cure of the diorganopolysiloxane.
  • platinum catalysts such as platinum black, platinum supported on silica, platinum supported on carbon, chloroplatinic acid, alcohol solutions of chloroplatinic acid, platinum/olefin complexes, platinum/alkenylsiloxane complexes, platinum/beta-diketone complexes, platinum/phosphine complexes and the like; rhodium catalysts, such as rhodium chloride and rhodium chloride/di(n-butyl)sulfide complex and the like; and palladium catalysts, such as palladium on carbon, palladium chloride and the like.
  • platinum catalysts such as platinum black, platinum supported on silica, platinum supported on carbon, chloroplatinic acid, alcohol solutions of chloroplatinic acid, platinum/olefin complexes, platinum/alkenylsiloxane complexes, platinum/beta-diketone complexes, platinum/phosphine complexes and the like
  • rhodium catalysts
  • Component (F') is typically a platinum-based catalyst such as chloroplatinic acid; platinum dichloride; platinum tetrachloride; a platinum complex catalyst produced by reacting chloroplatinic acid and divinyltetramethyldisiloxane which is diluted with dimethylvinylsiloxy endblocked polydimethylsiloxane, prepared according to U.S. Patent No. 3,419,593 to Willing; and a neutralized complex of platinous chloride and divinyltetramethyldisiloxane, prepared according to U.S. Patent No. 5,175,325 to Brown et al. , these patents being hereby incorporated by reference.
  • catalyst (F) is a neutralized complex of platinous chloride and divinyltetramethyldisiloxane.
  • Component (F') is added to the present composition in a catalytic quantity sufficient to promote the reaction between organopolysiloxane (D 1 ) and component (E') so as to cure the organopolysiloxane within the time and temperature limitations of the static vulcanization step (II).
  • the hydrosilylation catalyst is added so as to provide about 0.1 to 500 parts per million (ppm) of metal atoms based on the total weight of the elastomeric composition, alternatively 0.25 to 50 ppm.
  • components (D), (E), and (F) are selected to provide a condensation cure of the organopolysiloxane.
  • an organopolysiloxane having at least 2 silicon bonded hydroxy groups i.e. silanol, considered as the curable groups
  • a organohydrido silicon compound would be selected as the optional crosslinking agent (E)
  • a condensation cure catalyst known in the art, such as a tin catalyst would be selected as component (F).
  • the organopolysiloxanes useful as condensation curable organopolysiloxanes is any organopolysiloxane which contains at least 2 silicon bonded hydroxy groups (or silanol groups (SiOH)) in its molecule.
  • any of the organopolysiloxanes described infra as component (D) in the addition cure embodiment can be used as the organopolysiloxane in the condensation cure embodiment if at least two SiOH groups are additionally present,, although the alkenyl group would not be necessary in the condensation cure embodiment.
  • the organohydrido silicon compound useful as the optional crosslinking agent (E) is the same as described infra for component (E).
  • the condensation catalyst useful as the curing agent in this embodiment is any compound which will promote the condensation reaction between the SiOH groups of diorganopolysiloxane (D) and the SiH groups of organohydrido silicon compound (E) so as to cure the former by the formation of -Si-O-Si- bonds.
  • Suitable catalysts include metal carboxylates, such as dibutyltin diacetate, dibutyltin dilaurate, tin tripropyl acetate, stannous octoate, stannous oxalate, stannous naphthanate; amines, such as triethyl amine, ethylenetriamine; and quaternary ammonium compounds, such as benzyltrimethylammoniumhydroxide, beta-hydroxyethylltrimethylammonium-2-ethylhexoate and beta-hydroxyethylbenzyltrimethyldimethylammoniumbutoxide (see, e.g., U.S. 3,024,210).
  • metal carboxylates such as dibutyltin diacetate, dibutyltin dilaurate, tin tripropyl acetate, stannous octoate, stannous oxalate, stannous naphthanate
  • amines such as trie
  • components (D), (E), and (F) can be selected to provide a free radical cure of the organopolysiloxane.
  • the organopolysiloxane can be any organopolysiloxane but typically, the organopolysiloxane has at least 2 alkenyl groups.
  • any of the organopolysiloxane described supra as suitable choices for (D') in the addition cure embodiment can also be used in the free radical embodiment of the present invention.
  • a crosslinking agent (E) is not required, but may aid in the free radical cure embodiment.
  • the cure agent (F) can be selected from any of the free radical initiators described supra for the selection of component (C).
  • a minor amount i.e., less than 50 weight percent of the total composition
  • one or more optional additive (G) can be incorporated in the elastomeric compositions of the present invention.
  • additives can be illustrated by the following non-limiting examples: extending fillers such as quartz, calcium carbonate, and diatomaceous earth; pigments such as iron oxide and titanium oxide; fillers such as carbon black and finely divided metals; heat stabilizers such as hydrated cerric oxide, calcium hydroxide, magnesium oxide; and flame retardants such as halogenated hydrocarbons, alumina trihydrate, magnesium hydroxide, wollastonite, organophosphorous compounds and other fire retardant (FR) materials.
  • FR fire retardant
  • step (I) can be performed in any device that is capable of uniformly mixing the components (B) through (G) with (A) the elastomer.
  • the mixing by an extrusion process is conducted on a twin-screw extruder.
  • the order of mixing components (A) through (F) is not critical.
  • (G) would be added after (F) but it is not critical as long as (G) does not interfere with cure of the organopolysiloxane (e.g., (G) can be premixed with the elastomer (A) and/or with the silicone base (D).
  • components (D) through (F) are uniformly mixed first to form a silicone compound.
  • Components (A) through (C) are mixed with a silicone compound in step (I).
  • the mixing for step (I) is provided from a twin-screw extruder.
  • the time period for mixing in a twin screw extruder is less than 3 minutes, or alternatively less than 2 minutes.
  • the second step (II) of the method of the present invention is statically vulcanizing the organopolysiloxane.
  • the static vulcanizing step cures the organopolysiloxane.
  • Step (II) occurs following the mixing step (I).
  • Static vulcanization refers to vulcanizing the organopolysiloxane without further mixing of the product of step (I).
  • the product of mixing from step (I) can be simply subjected to a process to cure the organopolysiloxane, such as heating the product of step (I).
  • the product of step (I) is heated at a temperature sufficient to cure the organopolysiloxane. This temperature will depend on whether a cure agent is present and its chemical nature.
  • the cure agent is present and is an organic peroxide, as discussed supra. In this embodiment, half life of the organic peroxide much be short enough for time and temperature constraints of step (II).
  • the present invention also relates to the elastomeric compositions prepared according to the methods taught herein, and further to the cured elastomeric compositions prepared therefrom.
  • the inventors believe the techniques of the present invention provide unique and useful elastomeric compositions, as demonstrated by the inherent physical properties of the elastomeric compositions, vs compositions of similar combinations of elastomers and silicone bases prepared by other methods or techniques.
  • the cured elastomer compositions, as described infra, prepared from the elastomeric compositions of the present invention also possess unique and useful properties.
  • cured elastomers prepared from the elastomeric compositions of the present invention have surprisingly good low and high temperature properties and improved processability.
  • the cured elastomeric compositions of the present invention can be prepared by curing the elastomer component (A) of the elastomeric composition of the present invention via known curing techniques. Curing of elastomers, and additional components added prior to curing, are well known in the art and will depend on the selection of elastomers (A). Any of these known techniques, and additives, can be used to cure the elastomeric compositions of the present invention and prepare cured elastomers therefrom.
  • Additional components can be added to the elastomeric compositions prior to curing the elastomer component. These include blending other elastomers or other elastomeric compositions into the elastomeric compositions of the present invention. These additional components can also be any component or ingredient typically added to an elastomer or elastomer gum for the purpose of preparing a cured elastomer composition. Typically, these components can be selected from, fillers, processing aids, and curatives. Many commercially available elastomers can already comprise these additional components. Elastomers having these additional components can be used as component (A), described supra, providing they do not prevent the static vulcanization of the silicone base in step (II) of the method of this invention.
  • the cured elastomer composition may also comprise a filler.
  • fillers include carbon black; coal dust fines; silica; metal oxides, e.g., iron oxide and zinc oxide; zinc sulfide; calcium carbonate; wollastonite, calcium silicate, barium sulfate, and others known in the art.
  • the cured elastomer compositions are useful in a variety of applications such as to construct various articles of manufacture illustrated by but not limited to O-rings, gaskets, seals, liners, hoses, tubing, diaphragms, boots, valves, belts, blankets, coatings, rollers, molded goods, extruded sheet, caulks, and extruded articles, for use in applications areas which include but not are limited to transportation including automotive, watercraft, and aircraft; chemical and petroleum plants; electrical: wire and cable: food processing equipment; nuclear power plants; aerospace; medical applications; and the oil and gas drilling industry and other applications which typically use high performance elastomers such as ECO, FKM, HNBR, acrylic rubbers and silicone elastomers.
  • GP-50 is a silicone rubber base marketed by Dow Corning Corporation (Midland, MI) as
  • LS-2840 is a silicone rubber base marketed by Dow Corning Corporation (Midland, MI) as Silastic® LS-2840 Fluorosilicone Rubber.
  • LS 5-2040 is a silicone rubber base marketed by Dow Corning Corporation (Midland, MI) as Silastic® LS 5-2040 Fluorosilicone Rubber.
  • LS 4-9040 is a silicone rubber base marketed by Dow Corning Corporation (Midland, MI) as Silastic® LS 4-9040 Fluorosilicone Rubber.
  • HT-I is a masterbatch of eerie hydroxide in a dimethyl silicone rubber carrier and is marketed by Dow Corning Corporation (Midland, MI) as Silastic® HT-I Modifier.
  • TAIC is Triallyl-l,3,5-triazine-2,4,6-(lH,3H,5H)-trione (CAS# 1025-15-6), also known as triallyl isocyanurate, marketed by Aldrich Chemical Company, Inc.
  • Luperox F is Di-(2-tert-butylperoxyisopropyl) benzene(s) and is marketed by Atofina Chemicals, Inc. as LUPEROX® F.
  • VAROX is 2,5-dimethyl-2,5-di(tert-butylperoxy)hexane on an inert filler marketed by R.T. Vanderbilt, Company, Inc. as VAROX® DBPH-50.
  • N990 is carbon black (CAS# 1333-86-4) marketed by Degussa Engineered Carbons as Thermal Black N 990.
  • Austin Black is a carbon black marketed by Coal Fillers Incorporated as Austin Black®.
  • ZnO is zinc oxide USP powder (CAS# 1314-13-2) CP. Hall and the Zinc Corporation of America.
  • Silicone Compound A is a silicone compound based on Silastic® LCS-755 Silicone Rubber (100 parts) marketed by Dow Corning Corporation (Midland, MI) 5 9330 Zinc Oxide Transparent (5 parts) marketed by Akrochem Corporation and VAROX (0.4 parts).
  • EPDM is a low-diene containing ethylene-propylene terpolymer (EPDM) and marketed by Dupont Dow Elastomers, LLC as Nordel®IP NDR 3640.00.
  • G902 is 1-Propene, 1,1,2,3,3,3-hexafluoro-polymer with 1,1-difluoroethene and tetrafluoroethene Iodine modified fluoroelastomer (CAS# 25190-89-0) and is marketed by Daikin America, Inc. as DAI-ELTM Fluoroelastomer G-902.
  • GP-50 (60 g) and Luperox F (0.2 g) were mixed on a 2-roll mill to form a silicone compound.
  • This silicone compound (60.2 g) and EPDM (140 g) were added to a 379 ml Haake mixer equipped with Banbury rotors at 15O 0 C and 100 rpm (revolutions per minute). After about 2.5 minutes and before a torque increase, the material temperature was removed and placed in a press for 10 minutes at 177 0 C. The elastomeric composition was split into to portions. IA was further compounded as is. IB was heat aged for 16 hr/90 0 C, then compounded.
  • EPDM elastomeric compositions 50 g were compounded on a 2-roll mill with Varox (3g) and N990 (8 g), Austin Black (4 g) and ZnO (2 g) and the components were mixed until homogenous.
  • Example 1 The resulting elastomeric blends (50 g) were compounded on a 2-roll mill with Luperox F (0.05g), Varox (3g) and N990 (8 g), Austin Black (4 g) and ZnO (2 g) to give the same final ingredients as Example 1, and the components were mixed until homogenous. [0061] Examples 1-2 were pressed cured at 177 °C for 20 minutes. The physical properties of the resulting cured elastomeric compositions and the blend are summarized in Table 1.
  • Sample 3B is the same as Sample 3 A except, for Sample 3B, the blend was allowed to reach 16O 0 C, react and was then removed five minutes after a torque increase to give a FKM elastomeric composition with a ML (1+10) @ 121 0 C of 67.
  • the resulting FKM elastomeric compositions (100 parts) were compounded in the Haake then on a mill until uniform with ZnO (3.44 parts), Varox (2.06 parts), and TAIC (2.75 parts). The samples were press cured for 10 minutes at 160 0 C, and then post-cured for 4 hours at 200 °C.
  • Sample 3 A had a Shore A Durometer of 60, a Tensile Strength of 7.39 Mpa, an Elongation of 320%, and a permeation of 708 mnvgm/daym .
  • Sample 3B had a Shore A Durometer of 61, Tensile Strength of 9.45 MPa, an Elongation of 295%, and a permeation of 2508 mm-gm/m 2 -day.
  • LS-2840 100 parts
  • ZnO 5 parts
  • HT-I 1 part
  • Varox 0.8 parts
  • This silicone compound (257 g) and G902 (229 g) were added to a 310 ml Haake mixer equipped with banbury rollers at 15O 0 C and 125 rpm (revolutions per minute).
  • Sample 4A the blend was removed when it reached 15O 0 C and before a torque increase, then placed in a press for 10 minutes at 177 0 C to form a FKM elastomeric composition.
  • Sample 4B the blend was allowed to react in the Haake and removed five minutes after a torque increase.
  • Sample 5A and 5B were prepared the same as Sample 4A and 4B except LS-2840 was replaced with LS 5-2040.
  • the physical properties are listed in Table 2.
  • Example 6 [0066] Sample 6A and 6B were prepared the same as Sample 4A and 4B except LS-2840 was replaced with LS 4-9040 and 252g of the silicone compound was used. The physical properties are listed in Table 2. Table 2
  • a FKM elastomeric composition was prepared using a 25 mm Werner and Pfleiderer twin-screw extruder with the processing section heated to 50°C and a screw speed of 300 rpm at an output rate of 20 kg/hr.
  • the process began with the addition of Silicone Compound A at a feed rate of 70 grams/minute, followed by fluorocarbon elastomer (G902) to the extruder at a feed rate of 264 grams/minute.
  • the blend was extruded in strips into a 12-foot horizontal oven set at 350 0 C.
  • the resulting FKM elastomeric composition (100 parts) was compounded in a Haake then on a mill until uniform with ZnO (3.69 parts), Varox (2.21 parts), and TAIC (2.95 parts). The sample was press cured for 10 minutes at 160 °C, and then post-cured for 4 hours at 200°C to give a Shore A Durometer of 63, a Tensile Strength of 9.3 MPa, an Elongation of 395 % and a permeation of 634 mm-gm/m 2 -day.

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Abstract

L'invention concerne un procédé de préparation d'une composition élastomère, ce procédé consistant à : (I) mélanger (A) un élastomère, (B) un agent de compatibilité facultatif, (C) un catalyseur facultatif, (D) une base de silicone comprenant un organopolysiloxane pouvant être vulcanisé, (E) un agent de réticulation facultatif, (F) un agent de vulcanisation dans une quantité suffisante pour vulcaniser ledit organopolysiloxane ; et (II) vulcaniser statiquement l'organopolysiloxane, le rapport pondéral entre l'élastomère (A) et la base de silicone (D) dans la composition élastomère étant compris entre 95:5 et 30:70. Les compositions à base d'élastomère obtenues par ce procédé et les compositions élastomères vulcanisées préparées à partir de celles-ci possèdent de bonnes propriétés à basse température et à haute température.
PCT/US2005/019320 2004-06-30 2005-06-01 Vulcanisats a base d'elastomere et de silicone WO2006007268A1 (fr)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008154327A1 (fr) 2007-06-08 2008-12-18 Dow Corning Corporation Élastomères de silicone pour performance améliorée à haute température
WO2008154319A1 (fr) * 2007-06-08 2008-12-18 Dow Corning Corporation Élastomères de fluorosilicone pour performance améliorée à haute température
WO2011037747A3 (fr) * 2009-09-22 2011-07-21 Union Carbide Chemicals & Plastics Technology Llc Articles flexibles, moulés ou extrudés, et composés semi-conducteurs pour leur fabrication
US10150867B2 (en) 2014-06-27 2018-12-11 Dow Global Technologies Llc In-situ compatibilization of silicone rubber/polyolefin elastomer blends by forming ionomers for cold shrink splice and preparation method thereof
US10347391B2 (en) 2014-06-27 2019-07-09 Dow Global Technologies Llc Cold shrink article for electrical device
WO2021082243A1 (fr) * 2019-10-31 2021-05-06 歌尔股份有限公司 Membrane vibrante pour dispositif de production de son miniature et dispositif de production de son miniature
US11981814B2 (en) 2017-09-11 2024-05-14 Dow Toray Co., Ltd. Cured silicone elastomer having radical reactivity and use of same

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103524906B (zh) * 2013-09-30 2016-03-02 芜湖航天特种电缆厂 一种耐刮擦电缆橡胶护套料及其制备方法
CN103985454A (zh) * 2014-04-24 2014-08-13 安徽徽宁电器仪表集团有限公司 连体型电缆
KR102154468B1 (ko) * 2020-04-29 2020-09-09 김회복 진공 리프팅 장치용 탄성 흡착패드의 제조방법 및 이에 의해 제조된 탄성 흡착패드

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0279414A2 (fr) * 1987-02-16 1988-08-24 Japan Synthetic Rubber Co., Ltd. Composition de caoutchouc et son emploi dans la fabrication d'un joint ou tube
US4942202A (en) * 1987-10-30 1990-07-17 Japan Synthetic Rubber Co., Ltd. Rubber composition and vulcanized rubber product
EP0380104A2 (fr) * 1989-01-26 1990-08-01 Dow Corning Toray Silicone Company Ltd. Compositions en caoutchouc fluoré à propriétés mécaniques et façonnage modifiées
EP0508464A1 (fr) * 1991-04-11 1992-10-14 Sumitomo Chemical Company Limited Composition de caoutchouc
WO2003104322A1 (fr) * 2002-06-06 2003-12-18 Dow Corning Corporation Vulcanisats au silicone elastomere de fluorocarbure

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0279414A2 (fr) * 1987-02-16 1988-08-24 Japan Synthetic Rubber Co., Ltd. Composition de caoutchouc et son emploi dans la fabrication d'un joint ou tube
US4942202A (en) * 1987-10-30 1990-07-17 Japan Synthetic Rubber Co., Ltd. Rubber composition and vulcanized rubber product
EP0380104A2 (fr) * 1989-01-26 1990-08-01 Dow Corning Toray Silicone Company Ltd. Compositions en caoutchouc fluoré à propriétés mécaniques et façonnage modifiées
EP0508464A1 (fr) * 1991-04-11 1992-10-14 Sumitomo Chemical Company Limited Composition de caoutchouc
WO2003104322A1 (fr) * 2002-06-06 2003-12-18 Dow Corning Corporation Vulcanisats au silicone elastomere de fluorocarbure

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008154327A1 (fr) 2007-06-08 2008-12-18 Dow Corning Corporation Élastomères de silicone pour performance améliorée à haute température
WO2008154319A1 (fr) * 2007-06-08 2008-12-18 Dow Corning Corporation Élastomères de fluorosilicone pour performance améliorée à haute température
US8404770B2 (en) 2007-06-08 2013-03-26 Dow Corning Corporatioin Silicone elastomers for high temperature performance
KR101562198B1 (ko) 2007-06-08 2015-10-23 다우 코닝 코포레이션 고온 성능을 위한 플루오로실리콘 탄성중합체
WO2011037747A3 (fr) * 2009-09-22 2011-07-21 Union Carbide Chemicals & Plastics Technology Llc Articles flexibles, moulés ou extrudés, et composés semi-conducteurs pour leur fabrication
US8603635B2 (en) 2009-09-22 2013-12-10 Union Carbide Chemicals & Plastics Technology Llc Flexible, molded or extruded articles and semiconductive compounds for their manufacture
US10150867B2 (en) 2014-06-27 2018-12-11 Dow Global Technologies Llc In-situ compatibilization of silicone rubber/polyolefin elastomer blends by forming ionomers for cold shrink splice and preparation method thereof
US10347391B2 (en) 2014-06-27 2019-07-09 Dow Global Technologies Llc Cold shrink article for electrical device
US10453586B2 (en) 2014-06-27 2019-10-22 Dow Global Technologies Llc Cold shrink article for electrical device
US11981814B2 (en) 2017-09-11 2024-05-14 Dow Toray Co., Ltd. Cured silicone elastomer having radical reactivity and use of same
WO2021082243A1 (fr) * 2019-10-31 2021-05-06 歌尔股份有限公司 Membrane vibrante pour dispositif de production de son miniature et dispositif de production de son miniature

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