WO2005106573A1 - Écran à cristaux liquides et processus de fabrication de celui-ci - Google Patents
Écran à cristaux liquides et processus de fabrication de celui-ci Download PDFInfo
- Publication number
- WO2005106573A1 WO2005106573A1 PCT/JP2004/006300 JP2004006300W WO2005106573A1 WO 2005106573 A1 WO2005106573 A1 WO 2005106573A1 JP 2004006300 W JP2004006300 W JP 2004006300W WO 2005106573 A1 WO2005106573 A1 WO 2005106573A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- electrode
- liquid crystal
- organic
- insulating film
- layer
- Prior art date
Links
- 239000004973 liquid crystal related substance Substances 0.000 title claims abstract description 129
- 238000000034 method Methods 0.000 title claims description 23
- 239000000758 substrate Substances 0.000 claims abstract description 53
- 210000002858 crystal cell Anatomy 0.000 claims description 44
- 238000004519 manufacturing process Methods 0.000 claims description 21
- 229910052751 metal Inorganic materials 0.000 claims description 17
- 239000002184 metal Substances 0.000 claims description 17
- 229920005989 resin Polymers 0.000 claims description 12
- 239000011347 resin Substances 0.000 claims description 12
- 230000015572 biosynthetic process Effects 0.000 claims description 11
- 239000007772 electrode material Substances 0.000 claims description 10
- 239000011810 insulating material Substances 0.000 claims description 4
- 238000001459 lithography Methods 0.000 claims description 4
- 238000000059 patterning Methods 0.000 claims description 3
- 230000001678 irradiating effect Effects 0.000 claims description 2
- 230000002708 enhancing effect Effects 0.000 abstract 1
- 239000010408 film Substances 0.000 description 64
- 239000011521 glass Substances 0.000 description 19
- 238000007789 sealing Methods 0.000 description 17
- 239000000463 material Substances 0.000 description 12
- PQXKHYXIUOZZFA-UHFFFAOYSA-M lithium fluoride Chemical compound [Li+].[F-] PQXKHYXIUOZZFA-UHFFFAOYSA-M 0.000 description 10
- 230000004048 modification Effects 0.000 description 9
- 238000012986 modification Methods 0.000 description 9
- 229920001721 polyimide Polymers 0.000 description 9
- 239000000853 adhesive Substances 0.000 description 8
- 230000001070 adhesive effect Effects 0.000 description 8
- 230000005525 hole transport Effects 0.000 description 7
- 229910052782 aluminium Inorganic materials 0.000 description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 6
- 239000011159 matrix material Substances 0.000 description 6
- 239000007769 metal material Substances 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 239000012299 nitrogen atmosphere Substances 0.000 description 5
- 229910052814 silicon oxide Inorganic materials 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 239000003822 epoxy resin Substances 0.000 description 4
- 230000020169 heat generation Effects 0.000 description 4
- 238000002347 injection Methods 0.000 description 4
- 239000007924 injection Substances 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 229920000647 polyepoxide Polymers 0.000 description 4
- 239000004642 Polyimide Substances 0.000 description 3
- 238000000151 deposition Methods 0.000 description 3
- 239000002019 doping agent Substances 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- 229910010272 inorganic material Inorganic materials 0.000 description 3
- 239000011147 inorganic material Substances 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- IBHBKWKFFTZAHE-UHFFFAOYSA-N n-[4-[4-(n-naphthalen-1-ylanilino)phenyl]phenyl]-n-phenylnaphthalen-1-amine Chemical compound C1=CC=CC=C1N(C=1C2=CC=CC=C2C=CC=1)C1=CC=C(C=2C=CC(=CC=2)N(C=2C=CC=CC=2)C=2C3=CC=CC=C3C=CC=2)C=C1 IBHBKWKFFTZAHE-UHFFFAOYSA-N 0.000 description 3
- 125000006850 spacer group Chemical group 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 235000018185 Betula X alpestris Nutrition 0.000 description 1
- 235000018212 Betula X uliginosa Nutrition 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- FCVHBUFELUXTLR-UHFFFAOYSA-N [Li].[AlH3] Chemical compound [Li].[AlH3] FCVHBUFELUXTLR-UHFFFAOYSA-N 0.000 description 1
- 150000001339 alkali metal compounds Chemical class 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- -1 lithium fluoride Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 238000000206 photolithography Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
- G02F1/1336—Illuminating devices
- G02F1/133602—Direct backlight
- G02F1/133603—Direct backlight with LEDs
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/80—Constructional details
- H10K59/805—Electrodes
- H10K59/8051—Anodes
- H10K59/80516—Anodes combined with auxiliary electrodes, e.g. ITO layer combined with metal lines
Definitions
- the present invention relates to a liquid crystal display device using a so-called organic EL lighting device as a backlight of a liquid crystal cell, and a method for manufacturing the same.
- Liquid crystal display devices are used in monitors, notebook computers, mobile phones, televisions, etc., and are widely used as representatives of flat panel displays. Since a liquid crystal cell is a non-light emitting element that does not emit light, a light source called a backlight that normally illuminates the liquid crystal cell from the backside is required.
- the most commonly used backlight is a so-called light guide system comprising a fluorescent tube and a light guide for turning light emitted from the fluorescent tube into a surface light source. .
- this light guide method requires a certain thickness (about three times that of the liquid crystal cell) to obtain uniform surface light emission, making it difficult to reduce the overall thickness of the liquid crystal display device. Was.
- an organic EL lighting device using an organic EL device as a surface light emitting device is very effective as a backlight for a liquid crystal display device because it can be made very thin.
- FIG. 9 is a schematic cross-sectional view showing one configuration example of a conventional organic EL lighting device.
- an anode 102 made of a transparent electrode such as ITO is formed on a transparent substrate 101 made of glass or the like, and an organic EL layer 103 containing an organic luminescent material is further formed thereon.
- Cathodes 104 made of a metal having a small work function such as L i, Mg and A 1 are sequentially laminated, and a sealing plate 105 made of glass or the like is further provided for protection from the outside air such as moisture and oxygen. It is bonded and sealed in a dry nitrogen atmosphere using a transparent substrate 101 and an adhesive 106.
- Patent Document 1 discloses a technique for reducing the resistance of a transparent electrode by using a low-resistance auxiliary electrode made of metal.
- the metal since the metal has light impermeability in the visible light castle, the metal is shielded from light by the luminescent capture electrode, and the brightness of the organic EL lighting device is reduced.
- Patent Document 2 This is a method in which an auxiliary electrode is provided in a portion of the liquid crystal display device other than the region where the display pixel electrode is formed, that is, in a portion that does not directly affect display. With this configuration, since the auxiliary electrode is provided at the light-impermeable portion of the liquid crystal display device, the decrease in brightness due to the light blocking of the auxiliary electrode is effectively eliminated in the entire liquid crystal display device.
- the metal material usually has poor surface flatness compared to ITO, so that a short circuit may occur between the auxiliary electrode and the cathode or a leak may occur between the two.
- Patent Document 1 Japanese Patent Application Laid-Open No. 2000-2000
- Patent Document 2 Japanese Patent Application Laid-Open No. 2000-15056 633
- the present invention has been made in view of the above-described problems, and achieves low power consumption by improving the luminous efficiency of an organic EL lighting device, and generates a short circuit between an auxiliary electrode and a second electrode. It is an object of the present invention to provide a liquid crystal display device having an organic EL lighting device with low power consumption and high reliability and capable of emitting clean uniform light, and a method of manufacturing the same.
- a liquid crystal display device includes a liquid crystal cell having a liquid crystal layer, a plurality of display pixels formed thereon, and an organic EL layer for illuminating the liquid crystal cell from behind a first electrode.
- the insulating film is formed on the first electrode so as to cover at least an upper surface of the auxiliary electrode.
- the insulating film may be formed on the first electrode so as to cover the entire surface of the trapping electrode.
- the method for manufacturing a liquid crystal display device includes a step of sequentially forming a first electrode, which is a transparent electrode, an electrode material and an insulating resin on a surface of a transparent substrate, and processing the insulating resin by lithography. Forming an electrode-shaped insulating film; processing the electrode material using the insulating film as a mask to pattern an auxiliary electrode; and forming the auxiliary electrode on the first electrode via the insulating film.
- Another aspect of the method for manufacturing a liquid crystal display device of the present invention includes a step of sequentially forming a first electrode, which is a transparent electrode, and an electrode material on a surface of a transparent substrate; Forming an insulating material on the first electrode so as to cover the auxiliary electrode; processing the insulating material to cover the auxiliary electrode according to the shape of the auxiliary electrode Forming a pattern, and sequentially forming an organic EL layer and a second electrode which is a metal electrode on the first electrode so as to cover the auxiliary electrode via the insulating film.
- Another aspect of the method for manufacturing a liquid crystal display device of the present invention includes a step of patterning an auxiliary electrode on a surface of a transparent substrate, and a first step of forming a transparent electrode on the transparent substrate so as to cover the auxiliary electrode.
- FIG. 1A and 1B are schematic plan views showing the configuration of the liquid crystal display device according to the first embodiment.
- FIG. 1C is a schematic cross-sectional view along the line II of FIG. 1B.
- FIG. 2 is a schematic cross-sectional view illustrating a configuration of an organic EL lighting device that is a component of the liquid crystal display device according to the first embodiment.
- FIG. 3 is a schematic cross-sectional view showing the configuration of a comparative example (conventional example) of an organic EL lighting device used for a backlight of a liquid crystal display device.
- 4A to 4F are schematic cross-sectional views illustrating a method for manufacturing the liquid crystal display device according to the first embodiment in the order of steps.
- FIG. 5 is a schematic cross-sectional view illustrating a configuration of an organic EL lighting device that is a component of a liquid crystal display device according to a modification of the first embodiment.
- 6A to 6G are schematic cross-sectional views illustrating a method for manufacturing a liquid crystal display according to a modification of the first embodiment in the order of steps.
- FIG. 7 is a schematic cross-sectional view illustrating a configuration of an organic EL lighting device that is a component of the liquid crystal display device according to the second embodiment.
- FIGS. 8A to 8G are schematic cross-sectional views illustrating a method for manufacturing the liquid crystal display device according to the second embodiment in the order of steps.
- FIG. 9 is a schematic cross-sectional view showing one configuration example of a conventional organic EL lighting device.
- FIG. 1A and 1B are schematic plan views showing the configuration of the liquid crystal display device according to the present embodiment
- FIG. 1C is a schematic cross-sectional view along the line I-I in FIG. 1B
- FIG. 2 is a schematic cross-sectional view illustrating a configuration of an organic EL lighting device that is a component of the liquid crystal display device according to the present embodiment.
- the liquid crystal display device 1 of the present embodiment includes a liquid crystal cell 2 as a display means and an organic EL lighting device 3 used as a backlight of the liquid crystal cell 2. ing.
- the liquid crystal cell 2 has a plurality of strip-shaped transparent electrodes 11 made of ITO or the like formed on the surface thereof, and an alignment film 12 formed on the transparent electrodes 11.
- a polarizing plate 19 is arranged on the back surface of 16 respectively.
- the transparent electrode 11 and the transparent electrode 14 are orthogonal to each other, the transparent electrode 11 and the transparent electrode 14 overlap each other via the liquid crystal layer 1.7 and the like.
- a plurality of display pixel electrodes (apertures) 10 are formed from the portions indicated by.
- liquid crystal cell is described as a simple matrix type in the text, an active matrix type liquid crystal cell provided with a switching element such as a thin film transistor (TFT) in a pixel portion is also described. This is applicable in the configuration of the present invention.
- TFT thin film transistor
- the organic EL lighting device 3 is, as shown in FIG. 2, a third transparent substrate made of glass or the like.
- An anode 22 which is a transparent electrode made of ITO or the like is formed on the surface of the auxiliary electrode 23, and an auxiliary electrode 23 is patterned on the anode 22, and an insulating film 2 is formed so as to cover the upper surface of the auxiliary electrode 23.
- an organic EL layer 25 and a cathode 26 as a metal electrode are sequentially formed on the anode 22 so as to cover the auxiliary electrode 23 and the insulating film 24, and are made of a barrier oxide or the like.
- a sealing plate 28 is provided above the cathode 26 via a hygroscopic material 27, and the sealing plate 28 is fixed by an adhesive (not shown).
- the capture electrodes 23 are arranged in a region other than the display pixel electrode 10, in other words, in a portion matching the non-formation region of the display surface element electrode 10, that is, arranged in a matrix as shown in FIGS. 1A and 1B.
- the display pixel electrodes 10 are provided in a lattice shape and are made of a metal such as aluminum, silver, chromium, or molybdenum.
- the insulating film 24 is made of an insulating inorganic material such as silicon oxide or a photosensitive resin material such as polyimide, and is made of the latter here.
- the upper surface of the auxiliary electrode 23 is formed in a shape following the auxiliary electrode 23.
- the insulating film 24 separates the upper surface of the auxiliary electrode 23 from the organic EL layer 25, and the auxiliary electrode 23 and the organic EL layer 25 are located above the auxiliary electrode 23. Insulated with
- FIG. 3 is a schematic cross-sectional view showing a configuration of a comparative example (conventional example) of an organic EL lighting device used as a backlight of a liquid crystal display device.
- the organic EL layer 25 is formed directly so as to cover the auxiliary electrode 23 without the insulating film 24 as in the present embodiment.
- the organic EL layer 25 has a two-layer structure of a hole transport layer / organic light emitting layer from the anode 22 side, and There are three-layer structure of a hole transport layer, an organic light-emitting layer, and an electron transport layer, or a four-layer structure of a hole injection layer, a hole transport layer, an organic light-emitting layer, and an electron transport layer.
- a hole transport layer there is a two-layer organic EL layer using ⁇ -NPD as a hole transport layer and Alq as an organic light emitting layer.
- the device having this configuration emits green light.
- organic EL elements having various luminescent colors can be formed.
- the cathode 26 is made of an alkali metal such as lithium and an alkali metal compound such as lithium fluoride, which have a small work function, to effectively inject electrons into the organic EL layer 25.
- aluminum monolithium alloy, lithium fluoride / aluminum two-layer birch is used as the cathode 26.
- the sealing plate 28 is made of glass or the like, and is used in a dry nitrogen atmosphere using the third transparent substrate 21 and, for example, an epoxy resin adhesive to protect the organic EL layer 25 from the outside air. And sealed.
- the liquid crystal cell 2 and the organic EL lighting device 3 face each other, and the polarizing plate 18 of the liquid crystal cell 2 and the third transparent substrate 21 of the organic EL lighting device 3 face each other.
- the grid-like auxiliary electrodes 23 are aligned between the matrix-arranged display pixel electrodes 10 which are regions where the display pixel electrodes 10 are not formed.
- the liquid crystal display device 1 is configured.
- FIGS. 4A to 4F are schematic cross-sectional views showing the method for manufacturing the liquid crystal display device according to the above-described present embodiment in the order of steps.
- the manufacturing process of the organic EL lighting device which is the main configuration of the liquid crystal display device according to the present embodiment, will be mainly described.
- an anode 22 made of ITO or the like is formed on a third transparent substrate 21 made of glass or the like, and an electrode material such as aluminum is formed on the anode 22.
- the polyimide film 32 is exposed and developed by photolithography, and the polyimide film 32 is processed to form an insulating film 24 as a pattern.
- the A1 film 31 is dry-etched using the insulating film 24 as a mask to form a pattern of auxiliary electrodes 2 and 3 following the shape of the insulating film 24.
- the auxiliary electrode 23 is formed so as to be located at a position matching the non-formation region of the display pixel electrode 10 when superimposed on the liquid crystal cell 2.
- an organic EL layer 25 is formed on the anode 22 by an evaporation method so as to cover the insulating film 24 and the auxiliary electrode 23.
- 2TNTATA as a hole injection layer
- ⁇ —NPD as a hole transport layer
- Alq as a light emitting layer
- a cathode 26 is formed on the organic EL layer 25 by depositing LiF to a thickness of 0.5 nm and A1 to a thickness of 200 nm.
- a third gas is applied with an epoxy resin adhesive under a dry nitrogen atmosphere.
- the sealing is performed by bonding the glass substrate 21 and the sealing plate 28.
- the organic EL lighting device 3 for backlight of the present embodiment is completed.
- the organic EL lighting device 3 emits green light.
- the liquid crystal cell 2 is manufactured by a known method. For example, a plurality of strip-shaped transparent electrodes 11 made of ITO or the like are patterned on the surface of a first transparent substrate 13 made of glass or the like, and then an alignment film 1 is formed so as to cover the transparent electrodes 11. After forming a plurality of strip-shaped transparent electrodes 14 made of ITO or the like and orthogonal to the transparent electrodes 11 on the surface of the second transparent substrate 16 made of glass or the like, the transparent electrodes 1 An alignment film 15 is formed so as to cover 4.
- the first and second transparent substrates 13 and 16 are connected to the transparent electrode 11 and the transparent electrode 11 through a spacer for controlling the thickness of the injected liquid crystal. 1 and 4 are orthogonally opposed to each other and bonded together. A crystal layer 17 is formed. Finally, polarizing plates 18 and 19 are formed on the back surfaces of the first and second transparent substrates 13 and 16. As shown by a circle C in the figure, a portion where the strip-shaped transparent electrodes 11 and 13 orthogonal to each other overlap is the display pixel electrode 10.
- the liquid crystal cell 2 and the organic EL lighting device 3 are connected to each other, and the polarizing plate 18 of the liquid crystal cell 2 and the third transparent substrate 21 of the organic EL lighting device 3 face each other.
- the liquid crystal display device 1 is completed by overlapping and fixing the lattice-shaped trapping electrodes 23 between the display pixel electrodes 10 arranged in a matrix, which is a formation region, so as to be aligned. In order to perform this superposition step reliably, it is desirable to provide an alignment mark at an appropriate portion of each of the liquid crystal cell 2 and the organic EL lighting device 3.
- the auxiliary electrode 23 made of a metal material is provided on the anode 22 that is a transparent electrode, the resistance value of the anode 22 can be reduced.
- a reliable OLED lighting device 3 for backlight which can prevent light emission unevenness and heat generation due to a voltage drop and achieve clean uniform light emission, is realized.
- the auxiliary electrode 23 is provided in a region where the display pixel electrode 10 of the liquid crystal cell 2 is not formed, a decrease in luminance of the organic EL lighting device 3 due to the light shielding of the auxiliary electrode 23 is suppressed.
- the insulating film 24 is formed on the trapping electrode 23, no current flows through the organic EL layer 25 in a portion of the organic EL layer 25 that is shielded from light by the auxiliary electrode 23. Low power consumption of lighting equipment is realized. Further, by forming the insulating film 24, it is possible to prevent short-circuit and leakage between the trapping electrode 23 and the cathode 26 due to poor flatness of the auxiliary electrode 23. As described above, a liquid crystal display device having an organic EL lighting device with high reliability and low power consumption capable of emitting clean uniform light is realized.
- FIG. 5 is a schematic cross-sectional view illustrating a configuration of an organic EL lighting device that is a component of the liquid crystal display device according to the present modification.
- the liquid crystal display device of this modification (the liquid crystal display device 41 shown in FIG. 6G) includes a liquid crystal cell 2 similar to the first embodiment, which is a liquid crystal cell, and an organic EL used as a backlight of the liquid crystal cell 2.
- the lighting device 42 is provided.
- an anode 22 which is a transparent electrode made of IT, etc. is formed on the surface of a third transparent substrate 21 made of glass or the like, and a trapping electrode 23 is formed on the anode 22 in a pattern.
- An insulating film 43 is formed so as to cover the entire surface of the auxiliary electrode 23, and an organic EL layer 25 and a cathode 26 which is a metal electrode are sequentially formed on the anode 22 so as to cover the insulating film 43.
- a sealing plate 28 is provided above the cathode 26 via a hygroscopic material 27 made of a barrier oxide or the like, and the sealing plate 28 is fixed by an adhesive (not shown). ing.
- the insulating film 43 is made of an insulating inorganic material such as silicon oxide or a photosensitive resin material such as polyimide. In this case, the former is used as the material, and the trapping electrode 23 is shaped like the auxiliary electrode 23. This insulating film 43 separates the trapping electrode 23 from the organic EL layer 25, and insulates the trapping electrode 23 from the organic EL layer 25. ing.
- the insulating film 43 is formed so as to cover the entire surface of the auxiliary electrode 23, and the trapping electrode 23 is insulated from the organic EL layer 25. Luminous efficiency can be improved. Furthermore, by forming the insulating film 43 so as to cover the entire surface of the auxiliary electrode 23, the auxiliary electrode 23 and the cathode 26 are separated by the insulating film 43 to ensure insulation. The above short leak is prevented.
- FIGS. 6A to 6G are schematic cross-sectional views illustrating a method of manufacturing the liquid crystal display device according to the above-described modification in the order of steps.
- the manufacturing process of the organic EL lighting device which is the main configuration of the liquid crystal display device according to the present modification, will be mainly described.
- an anode 22 made of ITO or the like is formed on a third transparent substrate 21 made of glass or the like, and an electrode material such as aluminum (A) is formed on the anode 22.
- an electrode material such as aluminum (A) is formed on the anode 22.
- the auxiliary film 23 is patterned by patterning the A1 film 31 into an electrode shape. At this time, the auxiliary electrode 23 overlaps the liquid crystal cell 2 It is formed so as to be located at a position matching the non-formation region of the display pixel electrode 10 when they are combined.
- a silicon oxide film 44 as an insulating inorganic material is formed on the anode 22 so as to cover the auxiliary electrode 23.
- the silicon oxide film 44 is patterned in a shape following the auxiliary electrode 23, and an insulating film 43 covering the entire surface of the capture electrode 23 is patterned. .
- an organic EL layer 25 is formed on the anode 22 by an evaporation method so as to cover the insulating film 43.
- 2TNATA as a hole injection layer
- a—NPD as a hole transport layer
- Alq as a light emitting layer
- a cathode 26 is formed on the organic EL layer 25 by depositing LiF to a thickness of 0.5 nm and Al to a thickness of 200 nm.
- a third gas is applied with an epoxy resin adhesive under a dry nitrogen atmosphere.
- the sealing is performed by bonding the glass substrate 21 and the sealing plate 28.
- the organic EL lighting device 42 for backlight of the present modified example is completed.
- the organic EL lighting device 42 emits green light.
- the liquid crystal cell 2 is manufactured by a known method. For example, a plurality of strip-shaped transparent electrodes 11 made of ITO or the like are patterned on the surface of a first transparent substrate 13 made of glass or the like, and then an alignment film 1 is formed so as to cover the transparent electrodes 11. After forming a plurality of strip-shaped transparent electrodes 14 made of ITO or the like and orthogonal to the transparent electrodes 11 on the surface of the second transparent substrate 16 made of glass or the like, the transparent electrodes 1 An alignment film 15 is formed so as to cover 4.
- the first and second transparent substrates 13 and 16 are connected to the transparent electrode 11 and the transparent electrode 11 through a spacer for controlling the thickness of the injected liquid crystal.
- 14 are arranged so as to be orthogonal to each other and bonded together, and a liquid crystal is injected into the inside to form a liquid crystal layer 17.
- polarizing plates 18 and 19 are formed on the back surfaces of the first and second transparent substrates 13 and 16. As shown by the circle C in the figure, stripes that are orthogonal to each other A portion where the transparent electrodes 11 and 13 overlap each other becomes a display pixel electrode 10.
- the liquid crystal cell 2 and the organic EL lighting device 42 are connected to each other, and the polarizing plate 18 of the liquid crystal cell 2 and the third transparent substrate 21 of the organic EL lighting device 3 face each other.
- a grid-like trapping electrode 23 is overlapped and fixed between the display pixel electrodes 10 arranged in a matrix shape, which is a formation area, so as to be aligned, and the liquid crystal display device 41 is completed. In order to surely perform this superposition step, it is desirable to provide an alignment mark at an appropriate portion of each of the liquid crystal cell 2 and the organic EL lighting device 42.
- the auxiliary electrode 23 made of a metal material is provided on the anode 22 that is a transparent electrode, the resistance value of the anode 22 can be reduced.
- An organic EL lighting device 42 for a backlight that can prevent light emission unevenness and heat generation due to a voltage drop and achieve clean uniform light emission is realized.
- the auxiliary electrode 23 is provided in a region where the display pixel electrode 10 of the liquid crystal cell 2 is not formed, a decrease in luminance of the organic EL lighting device 42 due to light shielding of the capture electrode 23 is suppressed.
- the insulating film 43 is formed so as to cover the entire surface of the auxiliary electrode 23, no current flows in a portion of the organic EL layer 25 shielded by the auxiliary electrode 23. Thus, low power consumption of the organic EL lighting device is realized. Further, by forming the insulating film 43, it is possible to prevent short-circuit and leakage between the auxiliary electrode 23 and the cathode 26 due to the poor flatness of the auxiliary electrode 23. As described above, a liquid crystal display device having an organic EL lighting device with high reliability and low power consumption capable of emitting clean uniform light is realized.
- the present embodiment differs from the first embodiment in that the configuration of the organic EL lighting device of the liquid crystal display device is slightly different.
- the same components as those of the liquid crystal display device according to the first embodiment are denoted by the same reference numerals, and description thereof is omitted.
- FIG. 7 is a schematic cross-sectional view illustrating the configuration of an organic EL lighting device that is a component of the liquid crystal display device according to the present embodiment.
- the liquid crystal display device of the present embodiment (the liquid crystal display device 51 shown in FIG. 8G) includes a liquid crystal cell 2 similar to that of the first embodiment and an organic EL device used as a backlight of the liquid crystal cell 2.
- L lighting device 52 is provided.
- a trapping electrode 23 is pattern-formed on the surface of a third transparent substrate 21 made of glass or the like, and ITO is formed on the third transparent substrate 21 so as to cover the auxiliary electrode 23.
- An anode 22 is formed as a transparent electrode made of the same material.
- An insulating film 53 is formed on the anode 22 at a position aligned above the trapping electrode 23, and the anode 2 is formed so as to cover the insulating film 53.
- An organic EL layer 25 and a cathode 26 serving as a metal electrode are sequentially formed on 2, and a sealing plate 28 is provided above the cathode 26 via a hygroscopic material 27 made of, for example, vacuum oxide. The sealing plate 28 is fixed by an adhesive (not shown).
- the insulating film 53 is made of silicon oxide, positive photosensitive polyimide, or the like, and is shaped like the auxiliary electrode 23 so as to be aligned with the upper surface of the auxiliary electrode 23 via the anode 22.
- the insulating film 43 separates the upper surface of the trapping electrode 23 from the organic EL layer 25.
- the trapping electrode 23 and the organic EL layer 25 are located above the trapping electrode 23. Insulated.
- an insulating film 53 is formed at a position aligned above the auxiliary electrode 23 to insulate the trapping electrode 23 from the organic EL layer 25, so that the organic EL lighting device 5 is formed. 2 can improve the luminous efficiency. Further, by forming the insulating film 53 at a position aligned above the trapping electrode 23, the trapping electrode 23 and the cathode 26 are separated by the insulating film 53 to ensure reliable insulation. And the short leak described above is prevented.
- FIGS. 8A to 8G are schematic sectional views showing the method for manufacturing the liquid crystal display device according to the above-described present embodiment in the order of steps.
- the manufacturing process of the organic EL lighting device which is the main configuration of the liquid crystal display device according to the present embodiment, will be mainly described.
- an aluminum (A 1) film 31 is formed as an electrode material on a third transparent substrate 21 made of glass or the like, and then the A 1 film 31 is formed into an electrode shape.
- the trapping electrode 23 is patterned to form a pattern.
- the capture electrode 23 is formed so as to be located at a position matching the non-formation region of the display pixel electrode 10 when it is overlapped with the liquid crystal cell 2.
- a positive electrode made of ITO or the like covers the auxiliary electrode 23.
- Form pole 2 2 a positive electrode made of ITO or the like.
- a positive photosensitive polyimide film 54 is applied on the anode 22 to form a film, and then the back surface of the transparent substrate 21 is irradiated with exposure light to form the auxiliary electrode 23.
- the positive photosensitive polyimide film 54 is exposed and imaged by photolithography using the mask as a mask, and as shown in FIG. 8D, the positive photosensitive polyimide film 54 is processed to form an electrode.
- An insulating film 53 is formed.
- an organic EL layer 25 is formed on the anode 22 by an evaporation method so as to cover the insulating film 53.
- 2 TNATA as the hole injection layer, ⁇ -NPD as the hole transport layer, and Alq as the light emitting layer are deposited from the anode 22 side, and the organic EL layer 25 is formed into a three-layer structure.
- a cathode 26 is formed on the organic EL layer 25 by depositing LiF to a thickness of 0.5 nm and A1 to a thickness of 200 nm.
- the liquid crystal cell 2 is manufactured by a known method. For example, a plurality of strip-shaped transparent electrodes 11 made of ITO or the like are patterned on the surface of a first transparent substrate 13 made of glass or the like, and then an alignment film 1 is formed so as to cover the transparent electrodes 11. After forming a plurality of strip-shaped transparent electrodes 14 made of ITO or the like and orthogonal to the transparent electrodes 11 on the surface of the second transparent substrate 16 made of glass or the like, the transparent electrodes 1 An alignment film 15 is formed so as to cover 4. '
- the first and second transparent substrates 13 and 16 are connected to the transparent electrode 11 and the transparent electrode 11 through a spacer for controlling the thickness of the injected liquid crystal.
- 14 are arranged so as to be orthogonal to each other and bonded together, and a liquid crystal is injected into the inside to form a liquid crystal layer 17.
- polarizing plates 18 and 19 are formed on the back surfaces of the first and second transparent substrates 13 and 16. As shown by a circle C in the figure, a portion where the stripe-shaped transparent electrodes 11 and 13 orthogonal to each other overlap is the display pixel electrode 10.
- the liquid crystal cell 2 and the organic EL lighting device 52 are opposed to each other, and the polarizing plate 18 of the liquid crystal cell 2 and the third transparent substrate 21 of the organic EL lighting device 3 face each other.
- a grid-like trapping electrode 23 is overlapped and fixed between the display pixel electrodes 10 arranged in a matrix, which is a formation area, so as to be aligned, and a liquid crystal display device 51 is completed. In order to surely perform this superposition process, it is desirable to provide an alignment mark at an appropriate portion of each of the liquid crystal cell 2 and the organic EL lighting device 52.
- the auxiliary electrode 23 made of a metal material is provided in the anode 22 which is a transparent electrode, so that the resistance value of the anode 22 can be reduced.
- the capture electrode 23 is provided in a region where the display pixel electrode 10 of the liquid crystal cell 2 is not formed, a decrease in the brightness of the organic EL lighting device 52 due to the shielding of the capture electrode 23 is suppressed.
- the insulating film 53 is formed above the auxiliary electrode 23, no current flows in the portion of the organic EL layer 25 that is shielded from light by the auxiliary electrode 23.
- the low power consumption of the lighting device 52 is realized.
- the insulating film 53 it is also possible to prevent short leakage between the auxiliary electrode 23 and the cathode 26 due to poor flatness of the auxiliary electrode 23.
- a liquid crystal display device having an organic EL lighting device with high reliability and low power consumption capable of emitting clean uniform light is realized.
- ADVANTAGE OF THE INVENTION According to this invention, the luminous efficiency of a backlight is improved, low power consumption is implement
- a liquid crystal display device having a possible low power consumption organic EL lighting device is realized.
Landscapes
- Physics & Mathematics (AREA)
- Nonlinear Science (AREA)
- Mathematical Physics (AREA)
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Electroluminescent Light Sources (AREA)
- Liquid Crystal (AREA)
Abstract
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/JP2004/006300 WO2005106573A1 (fr) | 2004-04-30 | 2004-04-30 | Écran à cristaux liquides et processus de fabrication de celui-ci |
TW093112448A TWI251700B (en) | 2004-04-30 | 2004-04-30 | Liquid crystal display and process for fabricating the same |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/JP2004/006300 WO2005106573A1 (fr) | 2004-04-30 | 2004-04-30 | Écran à cristaux liquides et processus de fabrication de celui-ci |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2005106573A1 true WO2005106573A1 (fr) | 2005-11-10 |
Family
ID=35241823
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2004/006300 WO2005106573A1 (fr) | 2004-04-30 | 2004-04-30 | Écran à cristaux liquides et processus de fabrication de celui-ci |
Country Status (2)
Country | Link |
---|---|
TW (1) | TWI251700B (fr) |
WO (1) | WO2005106573A1 (fr) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2419023A (en) * | 2004-10-07 | 2006-04-12 | Dainippon Printing Co Ltd | Luminescence display panel |
WO2007102103A1 (fr) * | 2006-03-09 | 2007-09-13 | Philips Intellectual Property & Standards Gmbh | Elements d'eclairage avec des electrodes segmentees |
WO2009001241A1 (fr) * | 2007-06-25 | 2008-12-31 | Koninklijke Philips Electronics N.V. | Dispositif fonctionnel organique et procédé de fabrication de celui-ci |
DE102008045948A1 (de) * | 2008-09-04 | 2010-03-11 | Osram Opto Semiconductors Gmbh | Verfahren zur Herstellung eines organischen strahlungsemittierenden Bauelements und organisches strahlungsemittierendes Bauelement |
WO2010089680A1 (fr) * | 2009-02-05 | 2010-08-12 | Philips Intellectual Property & Standards Gmbh | Dispositif électroluminescent |
JP2011249075A (ja) * | 2010-05-25 | 2011-12-08 | Nec Lighting Ltd | 有機エレクトロルミネッセンス照明装置の製造方法 |
WO2013004746A1 (fr) * | 2011-07-04 | 2013-01-10 | Commissariat à l'énergie atomique et aux énergies alternatives | Dispositif de type photodiode contenant une capacite pour la régulation du courant d'obscurite ou de fuite |
RU2507638C2 (ru) * | 2008-10-02 | 2014-02-20 | Конинклейке Филипс Электроникс Н.В. | Устройство oled с покрытой шунтирующей линией |
JP2015135821A (ja) * | 2015-03-02 | 2015-07-27 | Necライティング株式会社 | 有機エレクトロルミネッセンス照明装置及びその製造方法 |
WO2016034533A1 (fr) * | 2014-09-04 | 2016-03-10 | Osram Oled Gmbh | Composant optoélectronique et procédé de fabrication d'un composant optoélectronique |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101752401B (zh) * | 2008-12-11 | 2013-09-18 | 奇晶光电股份有限公司 | 双面显示装置及其制造方法 |
CN103024960A (zh) * | 2012-11-30 | 2013-04-03 | 昆山维信诺显示技术有限公司 | Oled照明面板及制备方法以及一种oled照明器件 |
KR101854701B1 (ko) | 2016-05-31 | 2018-05-04 | 엘지디스플레이 주식회사 | 유기 발광 장치 및 그의 제조 방법 |
CN109659446A (zh) * | 2018-12-21 | 2019-04-19 | 固安翌光科技有限公司 | 高可靠性oled屏体 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH09306668A (ja) * | 1996-05-13 | 1997-11-28 | Hokuriku Electric Ind Co Ltd | El素子とその製造方法 |
JPH1062789A (ja) * | 1996-08-23 | 1998-03-06 | Sharp Corp | 液晶表示装置及びその製造方法 |
JPH11339958A (ja) * | 1998-05-22 | 1999-12-10 | Casio Comput Co Ltd | 電界発光素子の製造方法 |
JP2001015268A (ja) * | 1999-06-29 | 2001-01-19 | Nippon Seiki Co Ltd | 有機エレクトロルミネセンス素子及びその製造方法 |
JP2001338770A (ja) * | 2000-05-26 | 2001-12-07 | Tohoku Pioneer Corp | 発光表示装置及びその製造方法 |
JP2002156633A (ja) * | 2000-11-20 | 2002-05-31 | Stanley Electric Co Ltd | 照明付き液晶表示装置および面状発光素子光源の製造方法 |
JP2003257663A (ja) * | 2002-03-04 | 2003-09-12 | Rohm Co Ltd | 有機el表示パネルおよびその製造方法 |
-
2004
- 2004-04-30 WO PCT/JP2004/006300 patent/WO2005106573A1/fr active Application Filing
- 2004-04-30 TW TW093112448A patent/TWI251700B/zh not_active IP Right Cessation
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH09306668A (ja) * | 1996-05-13 | 1997-11-28 | Hokuriku Electric Ind Co Ltd | El素子とその製造方法 |
JPH1062789A (ja) * | 1996-08-23 | 1998-03-06 | Sharp Corp | 液晶表示装置及びその製造方法 |
JPH11339958A (ja) * | 1998-05-22 | 1999-12-10 | Casio Comput Co Ltd | 電界発光素子の製造方法 |
JP2001015268A (ja) * | 1999-06-29 | 2001-01-19 | Nippon Seiki Co Ltd | 有機エレクトロルミネセンス素子及びその製造方法 |
JP2001338770A (ja) * | 2000-05-26 | 2001-12-07 | Tohoku Pioneer Corp | 発光表示装置及びその製造方法 |
JP2002156633A (ja) * | 2000-11-20 | 2002-05-31 | Stanley Electric Co Ltd | 照明付き液晶表示装置および面状発光素子光源の製造方法 |
JP2003257663A (ja) * | 2002-03-04 | 2003-09-12 | Rohm Co Ltd | 有機el表示パネルおよびその製造方法 |
Cited By (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2419023B (en) * | 2004-10-07 | 2008-08-27 | Dainippon Printing Co Ltd | Luminescence display panel |
US7482745B2 (en) | 2004-10-07 | 2009-01-27 | Dai Nippon Printing Co., Ltd. | Luminescence display panel displaying a predetermined pattern |
GB2419023A (en) * | 2004-10-07 | 2006-04-12 | Dainippon Printing Co Ltd | Luminescence display panel |
WO2007102103A1 (fr) * | 2006-03-09 | 2007-09-13 | Philips Intellectual Property & Standards Gmbh | Elements d'eclairage avec des electrodes segmentees |
WO2009001241A1 (fr) * | 2007-06-25 | 2008-12-31 | Koninklijke Philips Electronics N.V. | Dispositif fonctionnel organique et procédé de fabrication de celui-ci |
JP2012502411A (ja) * | 2008-09-04 | 2012-01-26 | オスラム オプト セミコンダクターズ ゲゼルシャフト ミット ベシュレンクテル ハフツング | 有機発光素子の製造方法および有機発光素子 |
DE102008045948A1 (de) * | 2008-09-04 | 2010-03-11 | Osram Opto Semiconductors Gmbh | Verfahren zur Herstellung eines organischen strahlungsemittierenden Bauelements und organisches strahlungsemittierendes Bauelement |
WO2010025696A2 (fr) * | 2008-09-04 | 2010-03-11 | Osram Opto Semiconductors Gmbh | Procédé pour produire un photoémetteur organique, et photoémetteur organique |
WO2010025696A3 (fr) * | 2008-09-04 | 2010-07-29 | Osram Opto Semiconductors Gmbh | Procédé pour produire un photoémetteur organique, et photoémetteur organique |
US8927325B2 (en) | 2008-09-04 | 2015-01-06 | Osram Opto Semiconductor Gmbh | Method for producing an organic radiation-emitting component and organic radiation-emitting component |
RU2507638C2 (ru) * | 2008-10-02 | 2014-02-20 | Конинклейке Филипс Электроникс Н.В. | Устройство oled с покрытой шунтирующей линией |
CN102308406A (zh) * | 2009-02-05 | 2012-01-04 | 皇家飞利浦电子股份有限公司 | 电致发光器件 |
US8334651B2 (en) | 2009-02-05 | 2012-12-18 | Koninklijke Philips Electronics N.V. | Electroluminescent device with electrical shunt |
WO2010089680A1 (fr) * | 2009-02-05 | 2010-08-12 | Philips Intellectual Property & Standards Gmbh | Dispositif électroluminescent |
JP2011249075A (ja) * | 2010-05-25 | 2011-12-08 | Nec Lighting Ltd | 有機エレクトロルミネッセンス照明装置の製造方法 |
WO2013004746A1 (fr) * | 2011-07-04 | 2013-01-10 | Commissariat à l'énergie atomique et aux énergies alternatives | Dispositif de type photodiode contenant une capacite pour la régulation du courant d'obscurite ou de fuite |
FR2977719A1 (fr) * | 2011-07-04 | 2013-01-11 | Commissariat Energie Atomique | Dispositif de type photodiode contenant une capacite pour la regulation du courant d'obscurite ou de fuite |
US9142789B2 (en) | 2011-07-04 | 2015-09-22 | Commissariat A L'energie Atomique Et Aux Energies Alternatives | Photodiode device containing a capacitor for controlling dark current or leakage current |
WO2016034533A1 (fr) * | 2014-09-04 | 2016-03-10 | Osram Oled Gmbh | Composant optoélectronique et procédé de fabrication d'un composant optoélectronique |
US10177340B2 (en) | 2014-09-04 | 2019-01-08 | Osram Oled Gmbh | Optoelectronic device and method of producing an optoelectronic device |
JP2015135821A (ja) * | 2015-03-02 | 2015-07-27 | Necライティング株式会社 | 有機エレクトロルミネッセンス照明装置及びその製造方法 |
Also Published As
Publication number | Publication date |
---|---|
TWI251700B (en) | 2006-03-21 |
TW200535516A (en) | 2005-11-01 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
KR101747737B1 (ko) | 발광 표시 패널 및 그의 제조 방법 | |
US6624572B1 (en) | Organic electroluminescence display panel and method for sealing the same | |
US9312316B2 (en) | Organic light emitting diode display and manufacturing method of the same | |
US8044582B2 (en) | Organic display apparatus comprising moisture propagation preventing means | |
US20080054800A1 (en) | Organic electroluminescent display device | |
JP4448148B2 (ja) | 有機発光装置 | |
JP2004006338A (ja) | 有機電界発光素子及びその製造方法 | |
JP2007123240A (ja) | 表示装置の製造方法および表示装置 | |
WO2005106573A1 (fr) | Écran à cristaux liquides et processus de fabrication de celui-ci | |
US8018143B2 (en) | Organic electroluminescent display device and method of manufacturing the same | |
TW201017877A (en) | Organic light emitting diode display device and manufacturing method thereof | |
US6781293B2 (en) | Organic EL device with high contrast ratio and method for manufacturing the same | |
KR20110035049A (ko) | 유기전계발광소자 및 이의 제조방법 | |
KR100681022B1 (ko) | 유기 전계발광표시소자 및 그 제조방법 | |
US7233020B2 (en) | Design for an organic light-emitting display that eliminates deterioration of the emission layer due to outgassing from an underlying layer | |
JP2003092192A (ja) | 有機エレクトロルミネッセンス表示装置およびその製造方法 | |
WO2004107821A1 (fr) | Panneau d'affichage electroluminescent organique | |
JP5063294B2 (ja) | 発光装置及びその製造方法 | |
JP2008243664A (ja) | 有機el素子の製造方法 | |
JP5330655B2 (ja) | 有機el表示装置 | |
JP3531597B2 (ja) | 有機電界発光装置 | |
KR100631121B1 (ko) | 유기전계발광표시소자 및 그 제조방법 | |
JP2002164164A (ja) | 有機el素子 | |
KR101427667B1 (ko) | 유기전계발광소자 | |
KR20100001103A (ko) | 발광 표시 패널의 제조 방법 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AK | Designated states |
Kind code of ref document: A1 Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BW BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE EG ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NA NI NO NZ OM PG PH PL PT RO RU SC SD SE SG SK SL SY TJ TM TN TR TT TZ UA UG US UZ VC VN YU ZA ZM ZW |
|
AL | Designated countries for regional patents |
Kind code of ref document: A1 Designated state(s): GM KE LS MW MZ NA SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LU MC NL PL PT RO SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
NENP | Non-entry into the national phase |
Ref country code: DE |
|
WWW | Wipo information: withdrawn in national office |
Country of ref document: DE |
|
122 | Ep: pct application non-entry in european phase |