WO2005094134A1 - 有機エレクトロルミネッセンス素子及びその製造方法並びに表示装置 - Google Patents
有機エレクトロルミネッセンス素子及びその製造方法並びに表示装置 Download PDFInfo
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- WO2005094134A1 WO2005094134A1 PCT/JP2004/004415 JP2004004415W WO2005094134A1 WO 2005094134 A1 WO2005094134 A1 WO 2005094134A1 JP 2004004415 W JP2004004415 W JP 2004004415W WO 2005094134 A1 WO2005094134 A1 WO 2005094134A1
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- WIPO (PCT)
- Prior art keywords
- film
- conductive film
- light
- layer
- organic electroluminescent
- Prior art date
Links
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Classifications
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B33/00—Electroluminescent light sources
- H05B33/12—Light sources with substantially two-dimensional radiating surfaces
- H05B33/26—Light sources with substantially two-dimensional radiating surfaces characterised by the composition or arrangement of the conductive material used as an electrode
- H05B33/28—Light sources with substantially two-dimensional radiating surfaces characterised by the composition or arrangement of the conductive material used as an electrode of translucent electrodes
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K50/00—Organic light-emitting devices
- H10K50/80—Constructional details
- H10K50/805—Electrodes
- H10K50/81—Anodes
- H10K50/818—Reflective anodes, e.g. ITO combined with thick metallic layers
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K50/00—Organic light-emitting devices
- H10K50/80—Constructional details
- H10K50/85—Arrangements for extracting light from the devices
- H10K50/856—Arrangements for extracting light from the devices comprising reflective means
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/80—Constructional details
- H10K59/875—Arrangements for extracting light from the devices
- H10K59/878—Arrangements for extracting light from the devices comprising reflective means
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K2102/00—Constructional details relating to the organic devices covered by this subclass
- H10K2102/301—Details of OLEDs
- H10K2102/302—Details of OLEDs of OLED structures
- H10K2102/3023—Direction of light emission
- H10K2102/3026—Top emission
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K2102/00—Constructional details relating to the organic devices covered by this subclass
- H10K2102/301—Details of OLEDs
- H10K2102/302—Details of OLEDs of OLED structures
- H10K2102/3023—Direction of light emission
- H10K2102/3031—Two-side emission, e.g. transparent OLEDs [TOLED]
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K50/00—Organic light-emitting devices
- H10K50/80—Constructional details
- H10K50/805—Electrodes
- H10K50/81—Anodes
- H10K50/813—Anodes characterised by their shape
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K50/00—Organic light-emitting devices
- H10K50/80—Constructional details
- H10K50/805—Electrodes
- H10K50/82—Cathodes
- H10K50/822—Cathodes characterised by their shape
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/10—OLED displays
- H10K59/12—Active-matrix OLED [AMOLED] displays
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/10—OLED displays
- H10K59/17—Passive-matrix OLED displays
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/80—Constructional details
- H10K59/805—Electrodes
- H10K59/8051—Anodes
- H10K59/80515—Anodes characterised by their shape
Definitions
- the present invention relates to an organic electroluminescent device, a method of manufacturing the same, and a display device and a method of manufacturing the same.
- the present invention relates to an organic electroluminescent device excellent in luminous efficiency.
- the present invention relates to a sense element and a method for manufacturing the same, and a display device having such an organic electroluminescent element.
- a display device using an organic electroluminescent device has attracted a great deal of attention as a display device that can be made thinner and lighter than conventional CRTs and LCDs. Since the organic electroluminescence element is a self-luminous type, it has high visibility, does not have a viewing angle dependency, and can use a flexible film substrate. There are various advantages. Further, in order to realize a high-definition display, development of an active matrix display device having a switching element such as a thin film transistor in addition to an organic electroluminescent element is under development.
- an anode electrode made of a transparent conductive film such as ITO (indium oxide doped with tin) is formed on an insulating substrate made of a glass substrate.
- an organic electroluminescent layer including a light emitting layer that generates light by recombination of electrons and holes is formed on the organic electroluminescent layer.
- a force sword electrode made of an A1 (aluminum) film, an Mg (magnesium) -Ag (silver) alloy film, or the like is formed on the organic electroluminescent layer.
- the organic electroluminescence element having the anode electrode, the organic electroluminescence layer, and the power source electrode is formed on the insulating substrate.
- a thin film transistor for controlling a drive voltage applied to an organic electroluminescence element is used.
- a switching element such as a transistor is formed between the insulating substrate and the organic electroluminescent element.
- the display device having such a structure is a so-called bottom emission type in which light generated in the light emitting layer of the organic electroluminescent layer is extracted from the insulating substrate side.
- light emitting layers having different light emitting wavelengths are separately formed in the pixel region.
- a deposition mask in which a region serving as a pixel is exposed is brought into close contact with a substrate, and a light-emitting layer for forming each color of RGB is formed by moving the deposition mask in the order of RGB, for example.
- a light-emitting layer is formed by using a light transmissive force source electrode and a light-reflective Cr (chromium) thin film as an anode electrode.
- the light generated in step (1) is reflected to the force source electrode side, and light is extracted from the force source electrode.
- Cr has a very low light reflectance, the light generated in the light emitting layer cannot be sufficiently reflected to the force source electrode side.
- an electrode layer made of an ITO film is directly formed on a reflective layer made of an A1 film.
- the electrical connection between the A1 film and the ITO film was not good, it was difficult to use the reflective layer as an electrode.
- An object of the present invention is to provide an organic electroluminescent device capable of realizing high luminous efficiency, a method for producing the same, and a display device having such an organic electroluminescent device.
- Patent Document 1
- Patent Document 2
- An organic electroluminescence device characterized by the above feature is provided.
- An organic EL device having an organic EL device is provided.
- a first conductive film formed on a substrate and having light reflectivity, and an insulating layer formed on the first conductive film and having light transmittance.
- An anode electrode formed on the insulating layer and having a light-transmitting second conductive film; an organic electroluminescent layer formed on the anode electrode; and the organic electroluminescent layer
- An organic electroluminescence device comprising: a light-transmitting force source electrode formed thereon.
- a first conductive film having a light reflection property is formed on a substrate, and a first conductive film is formed on the first conductive film so as to cover the first conductive film.
- a step of forming a switching element on a substrate and a step of forming a first insulating layer on the substrate on which the switching element is formed.
- Having a second conductive film electrically connected to the electrode of the switching element and having optical transparency Forming a node electrode, forming an organic electroluminescent layer on the anode electrode, and forming a light transmissive power source electrode on the organic electroluminescent layer.
- a third conductive layer electrically connected to each of the first conductive film and the second conductive film is provided between the first conductive film and the second conductive film.
- a light-transmissive second conductive film is provided on a light-reflective first conductive film formed on a substrate via a light-transmissive insulating layer.
- An anode electrode is formed, and the light generated in the organic electroluminescent layer is extracted from the cathode electrode side by the first conductive film below the anode electrode, so that the light generated in the organic electroluminescent layer is extracted from the force electrode side. Since it is taken out, high luminous efficiency can be realized without deteriorating device characteristics.
- FIG. 1 is a schematic diagram showing the structure of the display device according to the first embodiment of the present invention.
- FIG. 2 is a schematic diagram showing an example of the structure of a pot-to-emission type display device using an organic electorophore luminescence element.
- FIG. 3 is a process sectional view illustrating the method for manufacturing the display device according to the first embodiment of the present invention.
- FIG. 4 is a process sectional view (part 2) illustrating the method for manufacturing a display device according to the first embodiment of the present invention.
- FIG. 5 is a schematic diagram showing the structure of the display device according to the second embodiment of the present invention.
- FIG. 6 is a process cross-sectional view (part 1) illustrating the method for manufacturing a display device according to the second embodiment of the present invention.
- FIG. 7 is a process cross-sectional view (part 2) illustrating the method for manufacturing a display device according to the second embodiment of the present invention.
- FIG. 8 is a schematic diagram showing the structure of the display device according to the third embodiment of the present invention.
- FIG. 9 is a sectional view showing the structure of the display device according to the fourth embodiment of the present invention.
- FIG. 10 is a sectional view showing the structure of the display device according to the fifth embodiment of the present invention.
- FIG. 11 is a cross-sectional view showing an example of the structure of a bottom emission type display device using a thin film transistor as a switching element together with an organic electroluminescent element.
- FIG. 12 is a process cross-sectional view (part 1) illustrating the method for manufacturing a display device according to the fifth embodiment of the present invention.
- FIG. 13 is a process sectional view illustrating the method for manufacturing the display device according to the fifth embodiment of the present invention. (Part 2).
- FIG. 14 is a sectional view showing the structure of the display device according to the sixth embodiment of the present invention.
- FIG. 15 is a graph showing the characteristics of the display device according to the sixth embodiment of the present invention.
- FIG. 16 is a cross-sectional view showing a structure of a display device using a Cr film as an anode electrode.
- FIG. 17 is a process cross-sectional view (part 1) illustrating the method for manufacturing a display device according to the sixth embodiment of the present invention.
- FIG. 18 is a process cross-sectional view (part 2) illustrating the method for manufacturing a display device according to the sixth embodiment of the present invention.
- FIG. 19 is a sectional view showing the structure of the display device according to the seventh embodiment of the present invention.
- FIG. 20 is a process cross-sectional view (part 1) illustrating the method for manufacturing a display device according to the seventh embodiment of the present invention.
- FIG. 21 is a process cross-sectional view (part 2) illustrating the method for manufacturing a display device according to the seventh embodiment of the present invention.
- FIG. 22 is a process cross-sectional view (part 3) illustrating the method for manufacturing a display device according to the seventh embodiment of the present invention.
- FIG. 1 is a schematic diagram showing the structure of the display device according to the present embodiment
- FIG. 2 is a schematic diagram showing the structure of a bottom emission type display device using an organic electroluminescence element
- FIG. 7 is a sectional view showing a step of the method for manufacturing a display device according to (1).
- FIG. 1A is a plan view showing the structure of the display device according to the present embodiment
- FIG. 1B is a cross-sectional view taken along the line XX ′ of FIG. 1A.
- the display device according to the present embodiment is a passive matrix type display device having an organic electroluminescence element formed on an insulating substrate.
- FIG. 1 shows the structure for one pixel, a plurality of pixels are actually arranged in a matrix.
- a light reflecting film 12 made of an A1 film having light reflectivity is formed on an insulating substrate 10 made of a glass substrate.
- a transparent conductive film 14 made of an ITO film having a light transmitting property is formed on the light reflecting film 12.
- “having light reflectivity” means that the light reflectance is 50% or more, and more preferably 80% or more.
- having light transmittance means that light transmittance is 50% or more, more preferably 80% or more.
- the anode electrode 16 having the light reflecting film 12 and the transparent conductive film 14 is formed on the insulating substrate 10.
- an organic electroluminescent layer 18 formed by sequentially stacking a hole injection layer, a hole transport layer, a light emitting layer, an electron transport layer, and an electron injection layer is formed. Have been.
- a cathode electrode 20 made of a light-transmitting A 1 / ITO laminated film is formed.
- the organic electroluminescent device having the anode electrode 16, the organic electroluminescent layer 18, and the cathode electrode 20 is formed on the insulating substrate 10.
- the anode electrode 16 is formed on the insulating substrate 10 so as to extend in a predetermined direction (vertical direction in FIG. 1A).
- the transparent conductive film 14 is formed wider than the light reflection film 12.
- the force source electrode 20 is formed on the insulating substrate 10 on which the anode electrode 16 is formed so as to extend in a direction perpendicular to the anode electrode 16 (the left-right direction in FIG. 1A).
- An organic electroluminescence layer 18 having a rectangular shape wider than the intersection region is formed between the regions where the anode electrode 16 and the cathode electrode 20 intersect. Thus, a pixel region in which the organic electroluminescent device having the above structure is formed is formed.
- the anode electrode 16 in the organic electroluminescence element, includes a light reflective film 12 having light reflectivity and a transparent conductive film 14 having light transmissivity.
- the main feature is that the film 12 is covered with the transparent conductive film 14.
- electrons are injected into the organic electroluminescence layer 18 from the force source electrode 20, and holes are injected into the organic electroluminescence layer 18 from the transparent conductive film 14 of the anode electrode 16. Is done.
- the injected electrons are transported to the light emitting layer by the electron transport layer, and the injected holes are transported to the light emitting layer by the hole transport layer.
- the electrons and holes transported to the light-emitting layer recombine in the light-emitting layer to emit light.
- the light generated in the light emitting layer is reflected by the light reflecting film 12 to the force source electrode 20 side, and is extracted from the light transmissive force source electrode 20 side.
- the display device is of a top emission type in which light is extracted from the cathode electrode 20 side opposite to the insulating substrate 10 due to the presence of the light reflection film 12. Therefore, when another element is formed between the insulating substrate 10 and the organic electroluminescent element, light can be extracted from a region where the other element is formed. That is, the light emitting area of the organic EL luminescence element is not limited by other elements, and high luminous efficiency can be realized. For example, when an organic EL device is formed on an insulating substrate on which a switching element such as a thin film transistor is formed via an interlayer insulating film, the light emitting area is not limited by the switching element and high light emission is obtained. Efficiency can be realized.
- the display device shown in FIG. 2 is a bottom emission type display device using an organic electroluminescence device.
- FIG. 2A is a plan view showing a structure of a bottom emission type display device using an organic electroluminescent device
- FIG. 2B is a sectional view taken along line XX ′ of FIG. 2A.
- FIG. 2 shows the structure of one pixel, a plurality of pixels are actually arranged in a matrix.
- a transparent anode electrode 102 made of an ITO film is formed on an insulating substrate 100 made of a glass substrate.
- an organic electroluminescent layer 104 formed by sequentially stacking a hole transport layer, a light emitting layer, and an electron transport layer is formed.
- a force source electrode 106 made of an A1 film or a Mg—Ag alloy film is formed. ing.
- the organic electroluminescence element having the anode electrode 102, the organic electroluminescence layer 104, and the power source electrode 106 is formed on the insulating substrate 100.
- the light reflection film 12 made of the A1 film is covered with the transparent conductive film 14 made of the ITO film so that the surface is not exposed. I have.
- the transparent conductive film 14 made of the ITO film is formed so as to cover the light reflection film 12 made of the A1 film, the corrosion of the light reflection film 12 due to the battery effect is prevented. Has been prevented.
- whiskers may be generated between the light reflecting film 12 made of the A1 film and the transparent conductive film 14 made of the ITO film due to heat generation when a driving voltage is applied to the organic electroluminescence element. is there. Such whiskers can be one of the causes of a short circuit between electrodes.
- the transparent conductive film 14 made of the ITO film is formed so as to cover the light reflecting film 12 made of the A1 film. Short circuit with 20 can be prevented.
- the A1 film has a higher reflectivity than the conventionally used Cr film, and is suitable as a light reflection film of an organic electroluminescent device.
- the A1 film is used as the light reflecting film, the above-described problem occurs.
- the display device according to the present invention realizes higher luminous efficiency than before by forming an ITO film so as to cover the A1 film without inconvenience such as a short circuit between a corrosion electrode and an anode.
- the organic electroluminescent layer 18 is formed on a transparent conductive film 14 made of an ITO film, similarly to the conventional organic electroluminescent element. For this reason, a top emission type display device having high luminous efficiency is constructed using the organic electroluminescent layer 18 having the same material and structure as the conventional organic electroluminescent device as the organic electroluminescent layer 18 as it is. can do.
- an A1 film 22 having a thickness of, for example, 150 nm is formed on an insulating substrate 10 made of a glass substrate by, for example, a sputtering method (see FIG. 3A).
- the A1 film 22 is patterned into a predetermined shape by photolithography and etching.
- the light reflecting film 12 made of the A1 film 22 is formed on the insulating substrate 10 (see FIG. 3B).
- a 70 nm-thick ITO film 24 is formed by, for example, a sputtering method (see FIG. 3C).
- the ITO film 24 is patterned into a predetermined shape by photolithography and etching. At this time, the ITO film 24 is patterned into a shape and a size covering the light reflecting film 12 so that the surface of the light reflecting film 12 is not exposed. Thus, a transparent conductive film 14 made of the ITO film 24 is formed (see FIG. 4A). During the patterning of the ITO film 24, the surface of the light reflecting film 12 consisting of the A1 film 22 below the IT film 24 is not exposed, so that the light reflecting film 12 is corroded by the battery effect. Can be prevented.
- an evaporation mask having a predetermined size is formed by, for example, a vacuum evaporation method.
- An organic electroluminescent layer 18 having an electron transport layer made of a film and an electron injection layer made of a LiF film is formed (see FIG. 4B).
- a 10 nm-thick A 1 A film and an ITO film having a thickness of, for example, 30 nm are sequentially formed to form an A 1 ZITO laminated film.
- a force source electrode 20 composed of the A1ZITO laminated film is formed (see FIG. 4C).
- the display device shown in FIG. 1 is manufactured.
- the light reflective film 12 having light reflectivity and the transparent conductive film 14 having light transmissivity are formed by the anode electrode 16. Therefore, a top-emission display device having high luminous efficiency can be realized.
- the light reflecting film 12 is covered with the transparent conductive film 14, the element characteristics due to corrosion of the light reflecting film 12 and whiskers generated between the light reflecting film 12 and the transparent conductive film 14, etc. Degradation can be suppressed.
- the organic electroluminescent layer 18 is formed on the transparent conductive film 14 in the same manner as the conventional organic electroluminescent element, the organic electroluminescent layer 18 is the same as the conventional organic electroluminescent element.
- the organic electroluminescent layer having the above material and structure can be used as it is.
- FIG. 5 is a schematic diagram showing the structure of the display device according to the present embodiment.
- FIGS. 6 and 7 are display devices according to the present embodiment.
- FIG. 7 is a process cross-sectional view illustrating the manufacturing method of the third embodiment.
- the same components as those of the display device and the method of manufacturing the same according to the first embodiment shown in FIGS. 1, 3, and 4 are denoted by the same reference numerals, and description thereof will be omitted or simplified.
- the display device according to the present embodiment is a passive matrix type display device having an organic electroluminescence device formed on an insulating substrate, similarly to the display device according to the first embodiment.
- the configuration is the same as that of the display device according to the first embodiment.
- the display device according to the present embodiment has the following features in that conduction between the light reflection film 12 and the transparent conductive film 14 is ensured, and holes can be injected from the light reflection film 12. This is different from the display device according to the first embodiment.
- FIG. 5A is a plan view showing the structure of the display device according to the present embodiment
- FIG. 5B is a cross-sectional view taken along the line ⁇ - ⁇ ′ of FIG. 5A.
- FIG. 5 shows the structure of one pixel, a plurality of pixels are actually arranged in a matrix.
- a light reflecting film 12 made of an A1 film having light reflectivity is formed on an insulating substrate 10 made of a glass substrate.
- an intervening film 30 made of a light reflecting Mo (molybdenum) film is formed on the periphery of the light reflecting film 12.
- a transparent conductive film 14 made of a light-transmitting ITO film is formed on the light reflecting film 12 in which the intervening film 30 is formed on the peripheral portion.
- the intervening film 30 is electrically connected to each of the light reflecting film 12 and the transparent conductive film 14.
- the intervening film 30 electrically connects the transparent conductive film 14 and the light reflecting film 12. The connection has been improved and continuity between them has been ensured.
- the anode electrode 32 having the light reflecting film 12, the transparent conductive film 14, and the intervening film 30 for improving the electrical connection between the two is formed on the insulating substrate 10. .
- an organic electroluminescent layer 18 in which a hole injection layer, a hole transport layer, a light emitting layer, an electron transport layer, and an electron injection layer are sequentially laminated is formed on the anode electrode 32.
- a cathode electrode 20 made of a light-transmitting A 1 ZITO laminated film is formed.
- the anode electrode 32 and the organic element are placed on the insulating substrate 10.
- An organic electroluminescent element having a luminescent layer 18 and a cathode electrode 20 is formed.
- the anode electrode 32 is formed on the insulating substrate 10 so as to extend in a predetermined direction (vertical direction in FIG. 5A).
- the intervening film 30 is formed in a frame shape on the periphery of the light reflecting film 12.
- the transparent conductive film 14 is formed wider than the light reflection film 12 on which the intervening film 30 is formed.
- the force source electrode 20 is formed on the insulating substrate 10 on which the anode electrode 16 is formed so as to extend in a direction perpendicular to the anode electrode 16 (the left-right direction in FIG. 5A).
- the organic electroluminescent layer 18 is formed in a rectangular shape wider than the intersection region between both the region where the anode electrode 32 and the force electrode 20 intersect.
- the pixel region in which the organic EL luminescence element having the above structure is formed is formed.
- the display device is, in the organic electroluminescence element, a light reflection film 12 having light reflectivity, and a light reflection film 12 and a light reflection film 12 formed on a peripheral portion of the light reflection film 12.
- An intervening film 30 electrically connected to each of the transparent conductive films 14 formed thereon to ensure conduction between the two, and a light reflection in which the intervening film 30 is formed on the periphery.
- the main feature is that the anode electrode 32 has the transparent conductive film 14 having light transmittance formed on the film 12, and the light reflecting film 12 is covered with the transparent conductive film 14. is there.
- the display device Since the electrical connection between the A1 film and the ITO film is not good, in the display device according to the first embodiment, in the anode electrode 16, the light reflecting film 12 composed of the A1 film and the transparent conductive film composed of the ITO film are used. In some cases, the conduction with the membrane 14 may not be sufficiently ensured.
- the periphery of the anode electrode 32 has an A 1 ZMo ZITO structure. Therefore, the light reflecting film 12 made of the A1 film and the transparent conductive film 1 made of the ITO film are formed by the intervening film 30 made of the Mo film electrically connected to each of the A1 film and the ITO film. The electrical connection between them has been improved and continuity between them has been ensured. Therefore, holes can be injected from the light reflecting film 12 into the organic electorifice luminescence layer 18.
- the intervening film 30 is located at the periphery of the light reflecting film 12. Light generated in the organic electroluminescent layer 18 is sufficiently reflected by the light reflecting film 12 having a higher reflectivity than the intervening film 30 toward the force source electrode 20 because the light reflecting film 12 has a higher reflectance than the intervening film 30. be able to.
- the transparent conductive film 14 is formed so as to cover the light reflecting film 12 in which the intervening film 30 is formed on the peripheral portion, the light reflecting film 1 is formed similarly to the display device according to the first embodiment. 2 can prevent corrosion. Further, it is possible to prevent a short circuit between the anode electrode 32 and the force source electrode 20 due to the whiskers generated between the light reflecting film 12 and the transparent conductive film 14 due to heat generation at the time of application of the driving voltage. .
- the organic electroluminescent layer 18 of the conventional organic electroluminescent element can be used as it is as the organic electroluminescent layer 18.
- an A1 film 22 having a thickness of, for example, 150 nm is formed on an insulating substrate 10 made of a glass substrate by, for example, a sputtering method.
- a Mo film 34 having a thickness of, for example, lOnm is formed on the one film 22 by, for example, a sputtering method (see FIG. 6A).
- a resist film 36 is formed on the Mo film 34 by, for example, a spin coating method. Thereafter, the resist film 36 is patterned using photolithography, so that the resist film 36 is left so as to cover a region where the light reflection film 12 where the A1 film 22 should be left to be formed is to be formed. . At this time, the peripheral portion of the resist film 36 covering the region where the intervening film 30 for forming the Mo film 34 is to be formed is thick, so that the Mo film 34 is removed and the A 1 film 22 is removed. The resist film 36 is left so that the thickness of the portion other than the peripheral portion of the resist film 36 covering the region to be left becomes thinner (see FIG. 6B).
- the setting of the thickness of the resist film 36 can be performed, for example, by adjusting the exposure amount using a mask used in photolithography. Specifically, for example, in a mask used for photolithography, a portion where the resist film 36 that covers the region where the intervening film 30 where the Mo film 34 is to be left to be formed is to be exposed is made a normal opening. On the other hand, the resist film covering the region where the Mo film 34 is removed and the A 1 film 22 is to be left. 3 Make the part to be exposed 6 a slit shape. When the resist film 36 is developed using such a mask, the Mo film 34 is removed, and the resist film 36 covering the region where the A1 film 22 should remain is formed in the region where the intervening film 30 is to be formed.
- Exposure is insufficient compared with the resist film 36 covering the surface.
- the thickness of the resist film 36 can be reduced.
- unnecessary A1 film 22 and Mo film 34 other than the region where the anode electrode 32 is formed are removed by, for example, wet etching. See Figure 6C).
- wet etching for example, an etching solution in which phosphoric acid, nitric acid, acetic acid, and water are mixed can be used.
- the resist film 36 is etched back by, for example, an ashing process, the Mo film 34 is removed, and the thin portion of the resist film 36 covering a region where the A 1 film 22 is to be left is removed. An opening 38 is formed in the resist film 36. On the other hand, the thick portion of the resist film 36 covering the region where the intervening film 30 is to be formed is left (see FIG. 6D).
- the Mo film 34 exposed at the bottom of the opening 38 is removed by, for example, wet etching.
- wet etching as in the case where the unnecessary Mo film 34 and the A1 film 22 are removed in FIG. 6C, for example, etching, for example, mixing phosphoric acid, nitric acid, acetic acid, and water is performed. Liquids can be used.
- a light reflecting film 12 made of the A1 film 22 and an intervening film 30 made of the Mo film 34 formed on the periphery of the light reflecting film 12 are formed (see FIG. 7A). See).
- an ITO film 24 of, eg, a 70 nm-thickness is formed on the insulating substrate 10 on which the light reflection film 12 and the intervening film 30 are formed, for example, by a sputtering method (see FIG. 7B). ).
- the IT film 24 is patterned into a predetermined shape by photolithography and etching.
- the ITO film 24 is formed in a shape and size covering the light reflecting film 12 so that the surface of the light reflecting film 12 in which the intervening film 30 is formed on the peripheral portion does not become exposed. 'Patterning'.
- the description of the ITO film 24 A conductive film 14 is formed (see FIG. 7C).
- the organic electroluminescent layer 18 and the power source electrode 20 are formed in the same manner as in the method of manufacturing the display device according to the first embodiment shown in FIGS.
- the display device according to the embodiment is manufactured.
- the light reflective film 12 having light reflectivity and the transparent conductive film 14 having light transmissivity are formed by the anode electrode 3. 2, the top emission type display device having high luminous efficiency can be realized.
- the light reflecting film 12 is covered with the transparent conductive film 14, the light reflecting film 12 is corroded, and the light reflecting film 12 and the whisker generated between the transparent conductive film 14 and the like are used. It is possible to suppress the deterioration of the element characteristics.
- the light reflecting film 12 and the transparent conductive film 14 formed on the light reflecting film 12 are electrically connected to each other, and the conduction between the two. Since the intervening film 30 is formed to secure the holes, holes can be injected from the light reflecting film 12 into the organic electroluminescence layer 18.
- the organic electroluminescence layer 18 is formed on the transparent conductive film 14 similarly to the conventional organic electroluminescence element, the organic electroluminescence layer 18 is formed as the organic electroluminescence layer 18 with the conventional organic electroluminescence element.
- An organic electroluminescent layer having a similar material and structure can be used as it is.
- FIG. 8 is a schematic diagram illustrating the structure of the display device according to the present embodiment. Note that the same components as those of the display device according to the first and second embodiments shown in FIGS. 1 and 5 are denoted by the same reference numerals, and description thereof will be omitted or simplified.
- the display device in one pixel on which the organic electroluminescence element formed on the insulating substrate is formed, light generated in the light emitting layer of the organic electroluminescence layer is opposite to that of the insulating substrate.
- FIG. 8A is a plan view showing the structure of the display device according to the present embodiment
- FIG. 8B is a sectional view taken along the line ⁇ ⁇ ′ of FIG. 8A
- FIG. 8C is a sectional view taken along the line ⁇ —Y ′ of FIG. .
- FIG. 8 shows the structure of one pixel, a plurality of pixels are actually arranged in a matrix.
- a transparent conductive film 14 and an organic electroluminescent layer 18 are formed on an insulating substrate 10 made of a glass substrate, similarly to the display devices according to the first and second embodiments.
- the force source electrode 20 is formed.
- the pixel region where the transparent conductive film 14 and the force electrode 20 intersect is divided into two regions having substantially the same area by a boundary orthogonal to the extending direction of the transparent conductive film 14.
- a light reflecting film 12 is formed below the transparent conductive film 14, and an upper surface on which an anode electrode 32 having the light reflecting film 12 and the transparent conductive film 14 is formed
- a light emitting section 40 is provided.
- the upper surface light emitting section 40 has a cross-sectional structure shown in FIG.
- the cross-sectional structure shown in FIG. 8 is similar to the display device according to the second embodiment. That is, on the insulating substrate 10, the light reflecting film 12 made of the A1 film having light reflectivity is formed. On the periphery of the light reflection film 12, an intervening film 30 made of a Mo film having light reflectivity is formed. A transparent conductive film 14 made of a light-transmitting ITO film is formed on the light reflecting film 12 in which the intervening film 30 is formed on the peripheral portion.
- the intervening film 30 is electrically connected to each of the light reflecting film 12 and the transparent conductive film 14.
- the intervening film 30 electrically connects the transparent conductive film 14 to the light reflecting film 12. The connection has been improved and continuity between them has been ensured.
- the anode electrode 32 having the light reflection film 12, the transparent conductive film 14, and the intervening film 30 for improving the electrical connection between the two is formed on the insulating substrate 10.
- an organic electroluminescence layer 18 formed by sequentially stacking a hole injection layer, a hole transport layer, a light emitting layer, an electron transport layer, and a kasumi injection layer is formed. ing.
- an organic electrode port having an anode electrode 32 having a light reflection film 12, an organic electroluminescent layer 18, and a cathode electrode 20 on the insulating substrate 10 in the top emission section 4 O.
- a luminescence element is formed.
- light generated in the organic electroluminescent layer 18 is reflected by the light reflecting film 12 to the force source electrode 20 side, and is extracted from the light transmitting cathode electrode 20 side.
- the double-sided light emitting section 44 has a sectional structure shown in FIG. 8C. That is, on the insulating substrate 10, the anode electrode 42 made of the transparent conductive film 14 common to the upper surface light emitting portion 40 is formed. Unlike the top emission section 40, the light reflection film 12 is not formed in the double-side emission section 44, and the transparent conductive film 14 is directly formed on the insulating substrate 10. On the anode electrode 42, an organic electroluminescent layer 18 common to the upper surface light emitting portion 40 is formed. On the organic electroluminescence layer 18, a cathode electrode 20 having the same light transmittance as the upper surface light emitting portion 40 is formed.
- the organic electroluminescent element having the anode electrode 42, the organic electroluminescent layer 18 and the cathode electrode 20 is formed on the insulating substrate 10 in the double-sided light emitting section 44.
- the double-sided light emitting section 4 light generated in the organic electroluminescence layer 18 is extracted from both sides of the cathode electrode 20 side and the insulating substrate 10 side since the light reflection film 12 is not formed.
- the same pixel is provided with a region where the light reflection film 12 is formed and a region where the light reflection film 12 is not formed, that is, the transparent conductive film 1 common to the anode electrodes 32 and 42.
- the top emission type area and the dual emission type area may be provided in the same pixel.
- the top light-emitting portion 40 and the double-sided light-emitting portion 44 have substantially the same shape, but the shapes of the two light-emitting portions 40 and 44 are not limited to this. .
- the shape of both the light emitting portions 40 and 44 can be made a desired shape. This makes it possible to set desired emission characteristics, such as luminance, according to the use, function, and the like of the display device.
- the same anode electrode 32 as that of the display device according to the second embodiment is used in the top light emitting section 40, but the first embodiment in which the intervening film 30 is not formed is used.
- An anode electrode 16 similar to that of the display device may be used in the top emission section 40.
- the light reflection film 12 is partially formed in the same pixel. However, for a plurality of pixels arranged in a matrix, the light reflection film 12 is not formed. ! It is also possible to provide a single pixel and a pixel on which the light reflection film 12 is not formed, and mix a top emission pixel and a dual emission pixel.
- FIG. 9 is a sectional view showing the structure of the display device according to the present embodiment.
- the same components as those of the display device according to the first embodiment and the method of manufacturing the same shown in FIGS. 1, 3, and 4 are denoted by the same reference numerals, and description thereof will be omitted or simplified.
- the display device according to the present embodiment is characterized mainly in that the unevenness is formed on the surface of the insulating substrate 10 in the display device according to the first embodiment.
- smooth irregularities are formed on the surface of the insulating substrate 10 made of a glass substrate.
- an anode electrode 16 having a light reflection film 12 and a transparent conductive film 14 is formed on an insulating substrate 10 having smooth irregularities formed on its surface.
- a toroluminescence layer 18 and a force source electrode 20 are formed.
- the anode electrode 16 formed on the insulating substrate 10, the organic electroluminescent layer 18, and the force are formed by the smooth protrusions formed on the surface of the insulating substrate 10.
- the area of the source electrode 20 is larger than that formed on the insulating substrate 10 having a flat surface with no irregularities. Thereby, the luminous efficiency can be further improved.
- the following method can be used.
- the irregularities can be directly formed on the surface of the insulating substrate 10.
- a predetermined pattern made of a resin or the like is formed on the insulating substrate 10 using an exposure method, so that the surface of the insulating substrate 10 is Irregularities due to the presence or absence of a resin or the like can be formed.
- the display device according to the present embodiment forms smooth irregularities on the surface of the insulating substrate 10 using the above-described method, the display device shown in FIGS. 3A to 3C and FIGS. 4A to 4C
- the display device can be manufactured in the same manner as the method of manufacturing the display device according to the first embodiment.
- the smooth unevenness is formed on the surface of the insulating substrate 10 on which the organic electroluminescence element is formed, the luminous efficiency can be further improved.
- FIG. 10 is a cross-sectional view showing the structure of the display device according to the present embodiment.
- FIG. 11 shows an example of the structure of a bottom emission type display device using a thin film transistor as a switching element together with an organic electroluminescent device.
- FIGS. 12 and 13 are sectional views showing the steps of the method for manufacturing the display device according to the present embodiment.
- the same components as those in the display device according to the second embodiment and the method for manufacturing the same shown in FIGS. 5 to 7 are denoted by the same reference numerals, and description thereof will be omitted or simplified.
- a thin film transistor is provided as a switching element together with an organic electroluminescent element similar to the display device according to the second embodiment, and a driving voltage applied to the organic electroluminescence element by the thin film transistor is provided.
- FIG. 10 shows the structure of one pixel, a plurality of pixels are actually arranged in a matrix.
- a buffer layer 46 made of a silicon oxide film is formed on an insulating substrate 10 made of a glass substrate.
- a channel layer 48 made of a polysilicon film is formed.
- a gate electrode 52 is formed via a gate insulating film 50 made of a silicon oxide film.
- a source region 54 and a drain region 56 are formed in the channel layer 48 on both sides of the gate electrode 52, respectively.
- the gate electrode 52, the source region 54 and the drain region 56 formed in the channel layer 48 are provided, and the drive voltage applied to the organic electroluminescent device is controlled. Thin film transistor is formed.
- an interlayer insulating film 58 is formed on the insulating substrate 10 on which the thin film transistors are formed.
- the source electrode 62 connected to the source region 54 via the contact hole 60 and the drain electrode 66 connected to the drain region 56 via the contact hole 64 are formed respectively.
- interlayer insulating film 58 On the interlayer insulating film 58 on which the source electrode 62 and the drain electrode 66 are formed, an interlayer insulating film 68 is formed. A contact hole 70 reaching source electrode 62 is formed in interlayer insulating film 68.
- a light reflecting film 12 made of an A1 film having light reflectivity is formed in a region including the contact hole 70.
- an intervening film 30 made of a Mo film having light reflectivity is formed on the periphery of the light reflecting film 12.
- a transparent conductive film 14 made of a light-transmitting ITO film is formed on the light reflecting film 12 having the intervening film 30 formed on the peripheral portion.
- the intervening film 30 is electrically connected to each of the light reflecting film 12 and the transparent conductive film 14, and is electrically connected between the transparent conductive film 14 and the light reflecting film 12 by the intervening film 30. Has been improved and conduction between the two has been ensured.
- the anode electrode 32 having the light reflecting film 12, the transparent conductive film 14, and the intervening film 30 for ensuring conduction between the two is formed on the interlayer insulating film 68. ing.
- the anode electrode 32 is electrically connected to the source electrode 62 of the thin film transistor via a contact hole 70 formed in the interlayer insulating film 68.
- the organic electroluminescent layer 18 is formed by sequentially stacking a layer and an electron injection layer.
- a cathode electrode 20 made of a light-transmitting A 1 / ITO laminated film is formed on the organic electroluminescent element having the anode electrode 32, the organic electroluminescent layer 18 and the force electrode 20 is formed on the interlayer insulating film 68.
- the display device according to the present embodiment is of a top emission type in which light is extracted from the cathode electrode 20 side opposite to the edge substrate 10 due to the presence of the light reflection film 12. Therefore, the light emitting area is not limited by the thin film transistor formed on the insulating substrate 10, and high light emitting efficiency can be realized.
- the display device shown in FIG. 11 is a bottom emission type display device using an organic electroluminescence element and a thin film translator as a switching element. Device.
- FIG. 11 shows the structure of one pixel, a plurality of pixels are actually arranged in a matrix.
- a buffer layer 108 is formed on an insulating substrate 100 i made of a glass substrate.
- a channel layer 110 is formed on the buffer layer 108.
- a gate electrode 114 is formed on the channel layer 110 by forming a gate insulating film 112 thereon.
- a source region 116 and a drain region 118 are formed in the channel layer 110 on both sides of the gate electrode 114, respectively.
- a thin-film transistor having the gate electrode 114, the source region 116 formed in the channel layer 111, and the drain region 118 is formed. .
- a layer insulating film 120 is formed on the insulating substrate 100 on which the thin film transistor is formed.
- the source electrode 124 connected to the source region 116 via the contact hole L22, and the drain region 124 via the contact hole 126 A drain electrode 128 connected to the drain electrode 18 is formed.
- the source electrode 1 On the interlayer color border film 120 on which the source electrode 124 and the drain electrode 128 are formed Has an interlayer insulating film 130 formed thereon.
- the source electrode 1 On the interlayer color border film 120 on which the source electrode 124 and the drain electrode 128 are formed Has an interlayer insulating film 130 formed thereon.
- a transparent anode electrode 102 made of an ITO film and an organic electroluminescent layer 10 are formed in a region including the contact holes 13. 4 and an organic electroluminescent device having a force source electrode 106 composed of an A1 film, a Mg—Ag alloy film, or the like.
- the anode electrode 102 is made of a contact wheel 1 formed on the interlayer insulating film 130.
- the thin-film transistor formed between the insulating substrate 10 and the organic electroluminescent element limits the emission area of the organic electroluminescent element, and achieves high luminous efficiency as in the display device according to the present embodiment. It is difficult to achieve.
- the display device according to the present embodiment has the anode electrode 32 having the same structure as the display device according to the second embodiment, the light reflection film 12 made of the A1 film and the ITO film are formed by the intervening film 30.
- the electrical connection with the transparent conductive film 14 is improved, and conduction between the user is ensured.
- holes can be injected into the organic electroluminescence layer 18 from the light reflection film 12 electrically connected to the source electrode 2 of the thin film transistor.
- the transparent conductive film 14 is formed so as to cover the light reflecting film 12 in which the intervening film 30 is formed on the peripheral portion, corrosion of the light reflecting film 12 can be prevented.
- an organic electroluminescent layer having the same material and structure as the organic electroluminescent layer of the conventional organic electroluminescent element can be used as it is.
- a buffer layer 46 made of, for example, a 300-nm-thick silicon oxide film is formed on an insulating substrate 10 made of a glass substrate by, for example, a CVD method.
- a polysilicon film having a thickness of, for example, 40 nm is formed on the buffer layer 46 by, for example, the CVD method.
- an amorphous silicon film may be formed instead of the polysilicon film, and this may be crystallized by a laser annealing method or the like to form a polysilicon film.
- the polysilicon film is patterned by photolithography and dry etching to form a channel layer 48 made of a polysilicon film (see FIG. 12A).
- a silicon oxide film having a thickness of, for example, 100 nm is formed on the buffer layer 46 on which the channel layer 48 is formed, for example, by a CVD method.
- an A 1 Nd (aluminum neodymium alloy) film having a thickness of, for example, 300 nm is formed by, for example, a sputtering method.
- the silicon oxide film and the A1Nd film are patterned by photolithography and dry etching, and the gate insulating film 50 made of a silicon oxide film and the A1Nd film are formed on the channel layer 48.
- the gate electrode 52 is formed.
- phosphorus is ion-implanted by, for example, an ion implantation method to form a source region 54 and a drain region 56 in the channel layer 48 on both sides of the gate electrode 52, respectively.
- a thin film transistor having the gate electrode 52, the source region 54 and the drain region 56 formed in the channel layer 48 is formed on the insulating substrate 10 (see FIG. 12B).
- an interlayer insulating film 58 made of, for example, a silicon nitride film having a thickness of, for example, 300 nm is formed on the insulating substrate 10 on which the thin film transistors are formed, for example, by a CVD method.
- a contact hole 60 reaching the source region 54 and a contact hole 64 reaching the drain region 56 are formed in the insulating film 58 by photolithography and dry etching (FIG. 12C). See).
- contact holes 60 and 64 were formed by, for example, a sputtering method.
- a Ti (titanium) ZA1 / Ti film having a thickness of 100 nmZlOOnmZlOOnm is formed on the formed interlayer insulating film 58.
- the TiZAl / Ti film is patterned by photolithography and dry etching to form a source electrode 62 and a drain electrode 66 made of a Ti / A1 / Ti film, respectively (see FIG. 13A). See).
- an interlayer insulating film 68 made of a photosensitive resin having a thickness of, for example, 3.0 / 1 m is formed on the interlayer insulating film 58 on which the source electrode 62 and the drain electrode 66 are formed by, for example, a CVD method.
- a contact hole 70 reaching the source electrode 62 is formed in the interlayer insulating film 68 by lithography (see FIG. 13B).
- the anode electrode 32 connected to the source electrode 62 via the contact hole 70 is formed on the interlayer insulating film 68 on which the contact hole 70 is formed in the same manner as in the method of manufacturing the display device according to the second embodiment.
- the organic electroluminescent layer 18 and the cathode electrode 20 are formed (see FIG. 13C).
- the display device according to the present embodiment shown in FIG. 10 is manufactured.
- the light reflective film 12 having light reflectivity and the transparent conductive film 14 having light transmissivity Since the anode electrode 32 has the anode electrode 32, a top emission type display device having high luminous efficiency can be realized without being restricted by the thin film transistor formed below the organic electroluminescence element.
- the light reflecting film 12 is covered with the transparent conductive film 14, the light reflecting film 12 is corroded, and the element characteristics are deteriorated by whiskers generated between the light reflecting film 12 and the transparent conductive film 14. Can be suppressed.
- the light reflecting film 12 and the transparent conductive film 14 formed on the light reflecting film 12 are electrically connected to each other to secure conduction between the two. Since the intervening film 30 is formed, holes can be injected into the organic electroluminescent layer 18 from the light reflecting film 12 electrically connected to the source electrode 62 of the thin film transistor. Further, since the organic electroluminescent layer 18 is formed on the transparent conductive film 14 similarly to the conventional organic electroluminescent element, the organic electroluminescent layer 18 is used as the conventional organic electroluminescent layer 18 and the organic luminescent layer. An organic electroluminescent layer having the same material and structure as the element can be used as it is.
- the same organic electroluminescence element as that of the display device according to the second embodiment is formed on the interlayer insulating film 68, but is similar to that of the display device according to the first or third embodiment.
- the organic electroluminescent device of the present invention may be formed.
- the intervening film 30 is not formed between the light reflecting film 12 and the transparent conductive film 14 as in the display device according to the first embodiment, the contact hole 70 reaching the source electrode 62 is used. It is desirable that the transparent conductive film 14 be directly connected to the source electrode 62 by a means such as not embedding the light reflection film 12 therein.
- the smooth unevenness is formed on the surface of the interlayer insulating film 68 to form the smooth unevenness.
- An organic electroluminescence element may be formed on the interlayer insulating film 68.
- FIG. 14 is a cross-sectional view showing the structure of the display device according to the present embodiment
- FIG. 15 is a graph showing the characteristics of the display device according to the present embodiment
- FIG. 16 is the structure of the display device using a Cr film as the anode electrode.
- FIG. 17 and FIG. 18 are process cross-sectional views illustrating the method of manufacturing the display device according to the present embodiment.
- the same components as those of the display device according to the first embodiment and the method of manufacturing the same shown in FIGS. 1, 3, and 4 are denoted by the same reference numerals, and description thereof will be omitted or simplified.
- the display device according to the present embodiment is a passive matrix type display device having an organic electroluminescence element formed on an insulating substrate, similarly to the display device according to the first embodiment. This is the same as the display device according to the first embodiment.
- the display device according to the present embodiment is different from the first embodiment in that an anode electrode made of a transparent conductive film is formed on a light reflection film via an insulating layer having light transmittance. Display device.
- FIG. 14 shows the structure of one pixel, a plurality of pixels are actually arranged in a matrix.
- a light reflecting film 72 made of an A1 film having light reflectivity is formed on an insulating substrate 10 made of a glass substrate.
- the light reflection film 72 may have a predetermined shape for each pixel, or may be formed over the entire display area where the pixels are arranged.
- an insulating layer 74 made of a photosensitive resin having a light transmitting property is formed on the light reflecting film 72.
- a photosensitive resin that is the material of the insulating layer 74
- an acryl resin is used as the photosensitive resin that is the material of the insulating layer 74.
- the insulating layer 74 is formed so as to cover the light reflecting film 72 so that the surface of the light reflecting film 72 is not exposed.
- an anode electrode 76 made of a transparent conductive film of ITO having light transmittance is formed.
- an organic electroluminescent layer 18 in which a hole injection layer, a hole transport layer, a light emitting layer, an electron transport layer, and an electron injection layer are sequentially laminated is formed.
- a light-transmissive A 1 film formed with a thin film thickness, a light-transmissive Ag film formed with a thin film thickness, and a light-transmissive ITO film And a transparent conductive film are sequentially laminated to form a cathode electrode 20.
- electrons are injected from the power source electrode 20 into the organic electroluminescence layer 18, and holes are injected from the anode electrode 76 into the organic electroluminescence layer 18.
- the injected electrons are transported to the light emitting layer by the electron transport layer, and the injected holes are transported to the light emitting layer by the hole transport layer.
- the electrons and holes thus transported to the light emitting layer recombine in the light emitting layer to emit light.
- the light generated in the light emitting layer is emitted to the anode electrode 76 side and the force source electrode 20 side.
- Light emitted to the anode electrode 76 side has light transmittance
- a light-transmissive cathode is reflected by the light reflecting film 72 through the insulating layer 74 toward the cathode electrode 20 side, and is transmitted through the insulating layer 74, the anode electrode 76, and the organic electroluminescent layer 18.
- the electrode 20 side is taken out.
- the light emitted to the side of the cathode electrode 20 is extracted as it is from the side of the force source electrode 20 having light transmittance. In this way, the light generated in the light emitting layer is extracted from the force source electrode 20 having light transmittance.
- the display device according to the present embodiment is opposite to the insulating substrate 10 due to the presence of the light reflecting film 72 formed under the anode electrode 76 made of the transparent conductive film via the insulating layer 74. It is of a top emission type in which light is extracted from the side of the power source electrode 20 on the side. Therefore, similarly to the display device according to the first embodiment, when another element is formed between the insulating substrate 10 and the organic electroluminescence element, light is also emitted from a region where the other element is formed. Can be taken out. That is, the emission area of the organic electroluminescence element is not limited by other elements, and high emission efficiency can be realized.
- the light reflecting film 72 may be formed wider than the light emitting region where the anode electrode 76 and the force electrode 20 overlap. No. By forming the light reflecting film 72 wide as described above, it is possible to suppress the light emission of the organic electroluminescent device from affecting the characteristics of other devices.
- the thickness of the light-transmitting insulating layer 74 formed between the anode electrode 76 and the light reflecting film 72 is desirably set to 1 ⁇ or more. This is because, if the thickness of the insulating layer 74 is set to be smaller than 1 ⁇ , the light may be dimmed in the insulating layer 74 due to the influence of light interference, and sufficient luminous efficiency may not be obtained. That's why.
- FIG. 15 shows the luminance of the display device according to the present embodiment and the display device using the anode electrode made of the Cr film shown in FIG. 16 by changing the current density injected into the organic electroluminescence layer.
- 9 is a graph showing the result of comparing the characteristics of both display devices. The horizontal axis of the graph shown in FIG.
- plots indicated by hatching indicate the measurement results of the display device according to the present embodiment
- plots indicated by ⁇ indicate the anode made of the Cr film shown in FIG. 16.
- 9 shows measurement results of a display device using a single electrode.
- an Al film having a thickness of 100 nm is used as the light reflecting film 72
- an acrylic resin layer having a thickness of 3.0 / m is used as the insulating layer 74
- a A 0 nm ITO film was used.
- the display device shown in FIG. 16 comparing the characteristics with the display device according to the present embodiment is a top emission type display device using a Cr film for the anode electrode.
- an anode electrode 134 made of a Cr film is formed on an insulating substrate 100 made of a glass substrate.
- an organic electroluminescence layer 104 is formed on the negative electrode 134.
- a force source electrode 106 is formed on the organic electroluminescence layer 104.
- the materials and materials of the organic electroluminescent layer 104 and the cathode electrode 106 are different.
- the structure and the structure were the same as those of the display device according to the present embodiment in which the characteristics were compared.
- the display device according to the present embodiment is more effective than the display device using a Cr film for the anode electrode 134 shown in FIG. About twice the brightness is obtained. Therefore, according to the display device of the present embodiment in which the light reflecting film 72 is formed below the anode electrode 76 made of a transparent conductive film with the light transmitting insulating layer 74 interposed therebetween, the Cr film is simply formed on the anode electrode. It can be said that the luminous efficiency can be effectively improved as compared with the case where is used.
- the organic electroluminescent layer 18 has an anode electrode made of a transparent conductive film similarly to the conventional organic electroluminescent device. It is formed on. this Therefore, a top emission type display device having high luminous efficiency is formed by using the organic electroluminescence layer 18 having the same material and structure as the conventional organic electroluminescence layer as the organic electroluminescence layer 18 as it is. can do.
- an insulating layer 74 is interposed between an anode electrode 76 made of a transparent conductive film and a light reflection film 72 made of an A1 film.
- the surface is covered with an insulating layer 74 so as not to be exposed. Therefore, similarly to the display device according to the first embodiment, when the ITO film is patterned in the manufacturing process, it is possible to prevent the light reflecting film 72 made of the A1 film from being corroded by the battery effect. .
- an insulating layer 74 is formed between the light reflection film 72 made of the A1 film and the anode electrode 76 made of the transparent conductive film. Therefore, as in the case of using an anode electrode in which an ITO film is formed directly on an A1 film, heat is generated when a drive voltage is applied to the organic electroluminescence element, and a window that causes a short circuit between the electrodes is generated. No scarring occurs.
- an Al film having a thickness of, for example, 150 nm is formed on an insulating substrate 10 made of a glass substrate, for example, by a sputtering method.
- the A1 film may be patterned into a predetermined shape for each pixel by photolithography and etching. Alternatively, the A1 film may be left on the entire surface of the insulating substrate 10 which is a display region in which pixels are arranged. Thus, the light reflecting film 72 made of the A1 film is formed on the insulating substrate 10 (see FIG. 17A).
- an acrylic photosensitive resin is applied on the light reflection film 72 by, for example, a spin coating method. Subsequently, after exposing the applied photosensitive resin using a predetermined mask, the exposed photosensitive resin is developed using a predetermined developing solution.
- an insulating layer 74 made of a photosensitive resin having a thickness of, for example, 3.0 / im is formed by photolithography (see FIG. 17B).
- the insulating layer 74 is formed so as to cover the light reflecting film 72 so that the surface of the light reflecting film 72 is not exposed.
- the insulating layer 74 since the insulating layer 74 is formed by a photosensitive resin, the insulating layer 74 having a highly flat surface can be obtained, and the organic electroluminescent element is formed on the highly flat surface. Can be formed.
- an ITO film 78 having a thickness of, for example, 70 nm is formed on the insulating layer 74 by, for example, a sputtering method (see FIG. 17C).
- the ITO film 78 is patterned into a predetermined shape by photolithography and etching.
- an anode electrode 76 composed of the ITO film 78 is formed on the insulating layer 74 (see FIG. 18A).
- the light reflection film 72 made of the A1 film is covered with the insulating layer 74, and the surface thereof is not exposed. Therefore, corrosion of the light reflection film 72 due to the battery effect can be prevented.
- a 2-nm TNATA film having a thickness of, for example, 140 nm is formed on the insulating layer 74 on which the anode electrode 76 is formed, for example, by a vacuum evaporation method through a vapor deposition mask opened to a predetermined size.
- a 0.5 nm LiF film is sequentially formed.
- a hole transport layer made of a- NPD film, t (npa) py consisting A 1 q 3 film doped with the light emitting layer and , an electron transport layer consisting of a 1 alpha 3 film, to form a L i F organic electret Toro luminescent layer 1 8 having an electronic note sintering bed consisting of film (see Figure 1 8 B).
- an A1 film having a thickness of, for example, 1.5 nm is formed on the organic electroluminescence layer 18 by, for example, a vacuum deposition method and a sputtering method, through a mask having an opening in a predetermined shape.
- An Ag film having a thickness of 15 nm and an ITO film having a thickness of, for example, 35 nm are sequentially formed to form an A 1 / AgZlTO laminated film.
- the cathode electrode 20 made of the A 1 / AgZ ITO laminated film is formed (see FIG. 18C).
- the display device shown in FIG. 14 is manufactured.
- the organic electroluminescent element is used.
- a light-reflecting film 72 having light reflectivity is formed under an anode electrode 76 made of a transparent conductive film via an insulating layer 74 having light transmissivity. Can be realized. Further, since the light reflecting film 72 is covered with the insulating layer 74, deterioration of device characteristics due to corrosion of the light reflecting film 72 can be suppressed.
- the organic electroluminescence layer 18 is formed on the anode electrode 76 made of a transparent conductive film similarly to the conventional organic electroluminescence element, the conventional organic electroluminescence layer 18 is used as the organic electroluminescence layer 18.
- An organic electroluminescent layer having the same material and structure as the element can be used as it is.
- the region where the light reflection film 72 is formed and the light reflection film 72 are not formed in the same pixel.
- the top-emission type area and the two-sided emission type area are flush with each other. It may be provided inside the element.
- smooth irregularities are formed on the surface of the insulating substrate 10, and the light reflecting film 7 2 is formed on the insulating substrate 10 on which the smooth irregularities are formed.
- the insulating layer 74 and the organic electroluminescence element may be formed.
- smooth unevenness may be formed on the surface of the insulating layer 74, and the organic electroluminescence element may be formed on the insulating layer 74 on which the smooth unevenness is formed. Due to the smooth unevenness formed on the surface of the insulating substrate 10 or the insulating layer 74, the anode electrode 76, the organic electroluminescent layer 18, and the force source electrode are formed similarly to the display device according to the fourth embodiment.
- the area of 20 is larger than that of the case where the surface is formed on the insulating substrate 10 having a flat surface without any unevenness, and the luminous efficiency can be further improved.
- FIG. 19 is a sectional view showing the structure of the display device according to the present embodiment
- FIGS. 20 to 22 are process sectional views showing the method of manufacturing the display device according to the present embodiment.
- Figure 1 0, the same components as those of the display device according to the fifth and sixth embodiments and the method of manufacturing the same according to the fifth and sixth embodiments shown in FIGS. Omitted or simplified.
- the display device according to the present embodiment is provided with an organic electroluminescence element similar to the display device according to the sixth embodiment, and a thin film transistor as a switching element similarly to the display device according to the fifth embodiment.
- This is an active matrix type display device that controls a driving voltage applied to an organic electroluminescent device.
- FIG. 19 shows the structure of one pixel, a plurality of pixels are actually arranged in a matrix.
- the gate electrode 52 and the channel layer 48 are formed on the insulating substrate 10 made of a glass substrate via a buffer layer 46 made of a silicon oxide film, as in the display device according to the fifth embodiment.
- a thin film transistor having the formed source region 54 and drain region 56 and controlling a drive voltage applied to the organic electroluminescence element is formed.
- an interlayer insulating film 58 is formed on the insulating substrate 10 on which the thin film transistors are formed.
- a source electrode 62 connected to the source region 54 via the contact hole 60 and a drain electrode 66 connected to the drain region 56 via the contact hole 64 are formed respectively.
- an interlayer insulating film 80 is formed on the interlayer insulating film 58 on which the source electrode 62 and the drain electrode 66 are formed.
- a light reflecting film 72 made of an A1 film having light reflectivity is formed on the interlayer insulating film 80.
- an opening 82 exposing a region of the interlayer insulating film 80 on the thin film transistor is formed in the light reflecting film 72.
- the opening 82 formed in the light reflection film 72 does not necessarily need to expose the region of the interlayer insulating film 80 where the thin film transistor is formed, and at least the source electrode of the interlayer insulating film 80. Anything that exposes the area above 62 may be used.
- the light reflecting film 72 having such an opening 82 may be formed in a predetermined shape for each pixel, or may be formed on the entire surface of the display area in which the pixels are arranged. You may.
- An insulating layer 74 made of a light-transmissive photosensitive resin is formed on the interlayer insulating film 80 exposed from the light reflecting film 72 and the opening 82.
- the photosensitive resin that is a material of the insulating layer 74 for example, an acrylic resin is used.
- the insulating layer 74 is formed so as to cover the light reflecting film 72 so that the surface of the light reflecting film 72 is not exposed.
- a contact hole 70 reaching the source electrode 62 is formed on the insulating layer 74 and the interlayer insulating film 80.
- an anode electrode 76 made of a transparent conductive film of ITO having light transmittance is formed in a region including the contact hole 70.
- the anode electrode 76 is electrically connected to the source electrode 62 of the thin film transistor via a contact hole 70 formed in the insulating layer 74 and the interlayer insulating film 80.
- an organic electroluminescent layer 18 formed by sequentially stacking a hole injection layer, a hole transport layer, a light emitting layer, an electron transport layer, and an electron injection layer is formed. I have.
- a cathode electrode 20 is formed by sequentially laminating a transparent conductive film made of a metal.
- an organic electroluminescence element having an anode electrode 76, an organic electroluminescence layer 18 and a power source electrode 20 is formed on the light reflection film 72 via the insulating layer 74. Is formed.
- the presence of the light reflection film 72 formed through the light-transmitting insulating layer 74 under the anode electrode 76 made of a transparent conductive film makes the insulating substrate 10 Is a top emission type in which light is extracted from the force electrode electrode 20 on the opposite side. Therefore, the light emitting area is not limited by the thin film transistor formed on the insulating substrate 10, and high light emitting efficiency can be realized. '
- the light reflecting film 72 has at least an opening 82 exposing a region of the interlayer insulating film 80 on the source electrode 62, and the anode electrode 7 made of a transparent conductive film is formed. 6 is directly connected to the source electrode 62 through the contact hole 70 It is electrically connected. As a result, holes are formed from the light reflecting film 72 electrically connected to the source electrode 62 of the thin film transistor without passing through the conductive film, which makes it difficult to secure the electrical connection with the anode electrode 76, and the organic electroluminescence is formed. It can be injected into the noreluminescence layer 18.
- the light blocking layer 72 is formed so as to cover the light reflecting film 72, corrosion of the light reflecting film 72 can be prevented.
- the organic electroluminescence layer 18 an organic electroluminescence layer having the same material and structure as the organic electroluminescence layer of the conventional organic electroluminescence element can be used as it is.
- the light reflecting film 72 When the light reflecting film 72 having a predetermined shape is formed for each pixel, the light reflecting film 72 is formed wider than the light emitting region where the anode electrode 76 and the cathode electrode 20 overlap. It is desirable to do. By thus forming the light reflecting film 72 wide, it is possible to prevent the light emission of the organic electroluminescent element from affecting the characteristics of the thin film transistor.
- a thin film transistor, a source electrode 62, and a drain electrode are formed on an insulating substrate 10 in the same manner as in the method of manufacturing the display device according to the fifth embodiment shown in FIGS. 12A to 12C and 13A. Form up to 6 (see Figure 2 OA).
- an inter-layer insulating film 80 made of, for example, a 300-nm-thick silicon oxide film is formed on the interlayer insulating film 58 on which the source electrode 62 and the drain electrode 66 have been formed by, for example, a CVD method. (See Figure 20B).
- an inorganic insulating film such as a silicon nitride film or an insulating film made of resin can be used in addition to a silicon oxide film.
- an A1 film 84 having a thickness of, for example, 150 ⁇ m is formed on the interlayer insulating film 80 by, for example, a sputtering method.
- the A1 film 84 is patterned into a predetermined shape by lithography, and an opening 82 is formed in the A1 film 84 so as to expose at least a region on the source electrode 62 of the interlayer insulating film 80. I do.
- the A1 film 84 may be patterned so as to have a predetermined shape for each pixel, or may be left over the entire display region in which the pixels are arranged.
- a light reflection Jl 72 composed of the A 1 film 84 is formed (see FIG. 21A).
- FIG. 21A shows a case where an opening 82 exposing a region of the inter-glove insulating film 80 on the purple film transistor is formed in the light reflecting film 72.
- a photosensitive resin is spread on the interlayer insulating film 80 exposed from the light reflecting film 72 and the opening 82 by, for example, a spin coating method to form a photosensitive resin layer 86 (FIG. 21B). See).
- the exposed photosensitive resin layer 86 is developed using a predetermined developing solution to form a layer on the source electrode 62 of the interlayer insulating film 80.
- An opening 88 exposing the region is formed in the photosensitive resin layer 86.
- an insulating layer 74 composed of a light-transmissive photosensitive resin layer 86 having an opening 88 formed therein is formed by photolithography (see FIG. 21C).
- the insulating layer 74 is formed so as to cover the light reflecting film 72 so that the surface of the light reflecting film 72 is not exposed.
- an opening 90 reaching the source electrode 62 is formed in the interlayer insulating film 80 by using, for example, the dry lip 74 in which the opening 88 is formed as a mask by dry etching.
- a contact hole 70 formed by connecting the opening 90 formed in the interlayer insulating film 80 and the opening 88 formed in the insulating layer 74 is formed (see FIG. 22). See).
- the size of the opening 82 of the light reflecting film 72, the size of the opening 88 of the insulating layer 74, the etching conditions, etc., so that the light reflecting film 72 is not exposed to the contact hole 70. Is preferably set in advance as appropriate. This is for the following reasons. That is, when the light-emitting film 72 is exposed to the contact hole 70, the anode electrode 76 and the light-reflecting film 72 formed thereafter come into contact with each other, and a parasitic capacitance is formed between the two.
- the insulating layer 74 is formed of a photosensitive resin, and the color edge layer 74 is used as a mask when etching the interlayer insulating film 80.
- Contact holes up to 70 can be formed by the number of steps.
- a light-transmitting inorganic insulating film such as a silicon oxide film can also be used as the insulating layer 74.
- the insulating layer 74 made of an inorganic insulating film is formed.
- a step of forming a resist film used as an etching mask for forming a contact hole 70 in the insulating layer 74 and the interlayer insulating film 80 and a step of removing the resist film are also required. Therefore, the number of steps is increased as compared with the case where the insulating layer 74 is formed of a photosensitive resin.
- an anode electrode connected to the source electrode 62 via the contact hole 70 is formed on the insulating film 74 on which the contact hole 70 is formed, in the same manner as in the method of manufacturing the display device according to the sixth embodiment.
- an organic electroluminescent layer 18 and a force source electrode 20 are formed (see FIG. 22B).
- the display device according to the present embodiment shown in FIG. 19 is manufactured.
- the light is transmitted through the light-transmitting insulating layer 74 below the anode electrode 76 made of the transparent conductive film. Since the light reflecting film 72 having reflectivity is formed, a top emission type display device with high luminous efficiency is realized without being restricted by the thin film transistor formed under the organic electroluminescence device. can do.
- the light reflecting film 72 is covered with the insulating layer 74, deterioration of device characteristics due to corrosion of the light reflecting film 72 can be suppressed.
- the organic electroluminescent layer 18 is formed on the anode electrode 76 made of a transparent conductive film similarly to the conventional organic electroluminescent element, the organic electroluminescent layer 18 is formed as the conventional organic electroluminescent layer 18.
- An organic electroluminescence layer having the same material and structure as that of the tronoluminescence element can be used as it is.
- the insulating substrate 10 is not limited to a glass substrate.
- a resin film such as polycarbonate or polyethylene terephthalate may be used as the insulating substrate 10.
- the insulating substrate 10 does not necessarily need to have a light transmitting property like a glass substrate or the like.
- the light-transmitting substrate is replaced with an insulating substrate.
- the intervening film 30 is formed on the peripheral portion _b of the light reflecting film 12 .
- the intervening film 30 is necessarily formed on the peripheral portion of the light reflecting film 12. It need not be formed, but may be formed partially on a predetermined area of the light reflection film 12.
- the A1 film is used as the light reflecting films 12 and 72 for reflecting the light generated in the light emitting layer of the organic electroluminescence layer 18 to the force source electrode 20 side.
- the light reflecting films 12 and 72 are not limited to the A1 film.
- As the light reflecting films 12 and 72 in addition to A1 or an alloy containing A1 as a main component, for example, Ag, Nd (neodymium), Si (silicon), Ti, W (tungsten) ) ⁇ ⁇
- the intervening film 30 is not limited to the Mo film.
- the intervening film 30 in addition to an alloy mainly containing Mo or f or Mo, for example, W, Ta, Ti, Cr, or at least one of these as a main component
- a conductive film made of a high melting point metal such as an alloy can be used.
- the transparent conductive film 14 and the anode electrode 76 formed on the light reflection film 12 have been described.
- the transparent conductive film 14 and the anode electrode 76 are used. Is not limited to ITO films.
- a light-transmitting conductive film such as an IZO (indium oxide doped with zinc) film and a Z ⁇ (zinc oxide) film can be used.
- the organic electroluminescent layer 18 has the following composition: And consisting TNATA film hole injection layer, a hole transport layer made of one NPD film shed and, t (npa) and light emitting layer made of doped A 1 q 3 film py, A 1 d 3 film than made electronic
- TNATA film hole injection layer TNATA film hole injection layer
- a hole transport layer made of one NPD film shed and, t (npa) and light emitting layer made of doped A 1 q 3 film py, A 1 d 3 film than made electronic
- the structure of the organic-emission-port luminescent layer 18 includes a single-layer structure consisting of only a light-emitting layer, a two-layer structure consisting of a hole-transport layer and a light-emitting layer or a two-layer structure consisting of a 5fe layer and an electron-transport layer, and a hole-transport layer and a light-emitting layer A three-layer structure of a semiconductor and an electron transport layer can be used.
- a certain organic electroluminescent material may be used for the material of the IE hole injection layer, the hole transport layer, the light emitting layer, the electron transport layer, and the electron injection layer that constitute the organic electroluminescence layer 18. it can.
- the cathode electrode 20 is the A1 / 1TO laminated film and the A1 / Ag_ However, it is not limited to the ITO laminated film.
- the A1 / Ag / IITO laminated film for example, an ITO single film, an IZO film, a ZnO film, an A1 single film, A light-transmitting conductive film such as a single Ag film or a stacked film of these materials can be used.
- an A1 film, an Ag film, or the like is used as the force source electrode 20, these films need to be formed thin so as to have light transmittance.
- the insulating layer 74 is limited to a material made of a photosensitive resin as long as it has a light transmitting property but is O. Not something.
- a light-transmitting inorganic insulating film such as a silicon oxide film, a silicon nitride film, or a silicon nitride oxide film can be used in addition to a material made of a photosensitive resin.
- the insulating layer 74 does not need to be colorless as long as it has a light-transmitting property, and the insulating layer 74 can be made of a colored resin such as polyimide.
- a top gate type thin film transistor is used has been described, but a bottom gate type thin film transistor may be used.
- a polysilicon film for the channel layer 48!
- an amorphous silicon film may be used for the channel layer 48.
- the case where the thin film transistor is used as the switching element has been described, but another switching element may be used.
- a switching element having a MIM (metal-insulating-film-metal) structure using a diode that is a two-terminal element may be used.
- the organic electroluminescent device according to the present invention a method for manufacturing the same, and a display device realize an organic electroluminescent device excellent in luminous efficiency, a method for manufacturing the same, and a display device using such an organic electroluminescent device. . Therefore, it has excellent display characteristics and is useful for application to a display device with low power consumption.
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Abstract
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Priority Applications (6)
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PCT/JP2004/004415 WO2005094134A1 (ja) | 2004-03-29 | 2004-03-29 | 有機エレクトロルミネッセンス素子及びその製造方法並びに表示装置 |
EP04724179.9A EP1742515B1 (en) | 2004-03-29 | 2004-03-29 | Organic electroluminescent display device |
US10/594,603 US7888856B2 (en) | 2004-03-29 | 2004-03-29 | Organic electroluminescence device and display apparatus containing the same, method for making organic electroluminescence device and method for making display apparatus |
JP2006511374A JP4637831B2 (ja) | 2004-03-29 | 2004-03-29 | 有機エレクトロルミネッセンス素子及びその製造方法並びに表示装置 |
CN2004800426579A CN1961617B (zh) | 2004-03-29 | 2004-03-29 | 有机电致发光元件及其制造方法和显示装置 |
TW093108728A TWI232589B (en) | 2004-03-29 | 2004-03-30 | Electroluminescent element, and method for fabricating the same and display apparatus |
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Publication number | Priority date | Publication date | Assignee | Title |
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JP2008159438A (ja) * | 2006-12-25 | 2008-07-10 | Kyocera Corp | 有機elディスプレイの製造方法 |
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US20210351266A1 (en) * | 2018-11-19 | 2021-11-11 | Sony Group Corporation | Light-emitting element, display device, and electronic equipment |
JP7414730B2 (ja) * | 2018-11-20 | 2024-01-16 | ソニーセミコンダクタソリューションズ株式会社 | 表示装置および表示装置の製造方法、並びに、電子機器 |
CN111668381B (zh) * | 2020-06-19 | 2023-01-24 | 京东方科技集团股份有限公司 | 显示基板及其制备方法、显示装置 |
KR20220033650A (ko) * | 2020-09-09 | 2022-03-17 | 삼성디스플레이 주식회사 | 반사 전극 및 이를 포함하는 표시 장치 |
CN113299708B (zh) * | 2021-05-12 | 2022-09-09 | 武汉华星光电技术有限公司 | 双面显示面板及其制备方法 |
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007280677A (ja) * | 2006-04-04 | 2007-10-25 | Seiko Epson Corp | 発光装置および電子機器 |
JP2008159438A (ja) * | 2006-12-25 | 2008-07-10 | Kyocera Corp | 有機elディスプレイの製造方法 |
US20080309232A1 (en) * | 2007-06-12 | 2008-12-18 | Casio Computer Co., Ltd. | Display apparatus and method of manufacturing the same |
JP2009032553A (ja) * | 2007-07-27 | 2009-02-12 | Casio Comput Co Ltd | 表示装置 |
US8174175B2 (en) | 2007-07-27 | 2012-05-08 | Casio Computer Co., Ltd. | Light-emitting device and method for manufacturing same |
JP2010123439A (ja) * | 2008-11-20 | 2010-06-03 | Fujifilm Corp | 有機電界発光素子 |
CN107674021A (zh) * | 2017-10-13 | 2018-02-09 | 中国科学院化学研究所 | 鼎状四胺芘及制备方法、鼎状四胺芘薄膜修饰的电极及制备方法 |
CN107674021B (zh) * | 2017-10-13 | 2019-05-14 | 中国科学院化学研究所 | 鼎状四胺芘及制备方法、鼎状四胺芘薄膜修饰的电极及制备方法 |
Also Published As
Publication number | Publication date |
---|---|
EP1742515A4 (en) | 2011-12-21 |
CN1961617B (zh) | 2010-04-28 |
CN1961617A (zh) | 2007-05-09 |
EP1742515B1 (en) | 2019-11-20 |
TWI232589B (en) | 2005-05-11 |
TW200532919A (en) | 2005-10-01 |
EP1742515A1 (en) | 2007-01-10 |
US7888856B2 (en) | 2011-02-15 |
US20080036366A1 (en) | 2008-02-14 |
JP4637831B2 (ja) | 2011-02-23 |
JPWO2005094134A1 (ja) | 2008-02-14 |
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