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WO2004063295A1 - Depot de nanoparticules par jet d'encre - Google Patents

Depot de nanoparticules par jet d'encre Download PDF

Info

Publication number
WO2004063295A1
WO2004063295A1 PCT/GB2004/000040 GB2004000040W WO2004063295A1 WO 2004063295 A1 WO2004063295 A1 WO 2004063295A1 GB 2004000040 W GB2004000040 W GB 2004000040W WO 2004063295 A1 WO2004063295 A1 WO 2004063295A1
Authority
WO
WIPO (PCT)
Prior art keywords
ink
ink composition
solvent
binder
solid loading
Prior art date
Application number
PCT/GB2004/000040
Other languages
English (en)
Inventor
Laura Diane Walker
Original Assignee
Qinetiq Nanomaterials Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Qinetiq Nanomaterials Limited filed Critical Qinetiq Nanomaterials Limited
Priority to GB0512793A priority Critical patent/GB2411406B/en
Publication of WO2004063295A1 publication Critical patent/WO2004063295A1/fr

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/88—Processes of manufacture
    • H01M4/8825—Methods for deposition of the catalytic active composition
    • H01M4/8828—Coating with slurry or ink
    • H01M4/8832—Ink jet printing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
    • B29C64/10—Processes of additive manufacturing
    • B29C64/106—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
    • B29C64/112—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using individual droplets, e.g. from jetting heads
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
    • B29C64/10—Processes of additive manufacturing
    • B29C64/141—Processes of additive manufacturing using only solid materials
    • B29C64/153—Processes of additive manufacturing using only solid materials using layers of powder being selectively joined, e.g. by selective laser sintering or melting
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/30—Inkjet printing inks
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/30—Inkjet printing inks
    • C09D11/38—Inkjet printing inks characterised by non-macromolecular additives other than solvents, pigments or dyes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M8/124—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the process of manufacturing or by the material of the electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0402—Methods of deposition of the material
    • H01M4/0404—Methods of deposition of the material by coating on electrode collectors
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Definitions

  • the present invention relates to a composition, method and apparatus for ink jet deposition, particularly, although not exclusively, of sub-micron sized structures.
  • Ink jet printing has applications as a deposition technique for materials consisting of particles greater than one micron in diameter (>1 ⁇ m).
  • direct ink jet printing is under investigation by some researchers, the structures which can be produced are very limited in terms of the type of materials which can be deposited and the accuracy of the structures which can be produced.
  • Direct printing uses an ink containing a solid loading of the material to be printed, much in the same way that a graphical ink contains the required pigment.
  • a derivative of the required material such as a salt, oxide or complex, can be used in suspension and printed, for later conversion to the required material.
  • an ink composition for use with ink jet deposition apparatus comprising a solid loading having a particle size of less than one micron, a solvent, a dispersant or surfactant and a binder material wherein the ink is in a liquid state at ambient temperature.
  • a surfactant or a dispersant will depend on the, nature of the interface which is to be formed between the constituents of the composition.
  • a dispersant is, of course,, capable of forming interfaces between solid and liquid phases only, whereas a surfactant can not only form interfaces between solid and liquid phases but also between solid and solid, solid and liquid, solid and gas, liquid and liquid and liquid and gas phases.
  • a method of ink production comprising homogenous mixing of a dispersant or surfactant and a solid loading having a particle size of less than one micron, followed by subsequent addition and homogenous mixing with a solvent .carrier before addition of a binder and subsequent homogeneous mixing thereof.
  • a method of ink production comprising homogenous mixing of a solvent and a solid loading having a particle size of less than one micron, followed by subsequent addition and homogenous mixing with a dispersant or surfactant before addition of a binder and subsequent homogeneous mixing thereof.
  • the particulate size of the sold loading is known at the outset of the formulation process and is amenable to analysis. Unlike other methods, particularly those utilising precursor materials, this provides more confidence to those who might utilise such a composition in the production of tightly specified structures, for example.
  • Figure 1 is a schematic diagram showing an ink jet printer for use with an ink in accordance with one aspect of the present invention
  • Figure 2 is a schematic diagram showing a print head for use with the printer of Figure 1 ;
  • Figure 3 is a flow chart illustrative of a method of ink formulation in accordance with an aspect of the invention
  • Figure 4 is a flow chart illustrative of an alternative method of ink formulation ⁇ in accordance with another aspect of the invention.
  • Figures 5a and 5b are respectively elevation and plan views of an example structure deposited using the ink of Figure 3 or Figure 4;
  • Figures 6a and 6b are respectively elevation and plan views of a further example deposited using the ink of Figure 3 or Figure 4;
  • Figures 7a to 7d illustrate further examples of structures deposited using the ink of Figure 3 or Figure 4.
  • an ink jet printer 1 under software control which' in this case is provided by a computer 2.
  • the printer 1 is capable of delivering ink to a surface 3 of media 5 which in this case is a polymeric release film.
  • the printer 1 is provided with a fixed bed 7 whilst each of a pair of print heads 9a,9b is capable of movement in the z-plane in addition to movement in the x and y plane.
  • Each of the print heads 9 is of the piezo-electric type as exemplified by a commercially available Siemens P2 print head.
  • ink jet deposition print heads may be utilised including not only those where the ejection of ink is brought about as a result of a piezo-electric distortion of an ink cavity but also print heads having thermal or shock wave based ejection mechanisms.
  • the print heads 9 are fed by separate reservoirs 11a,11 b to facilitate delivery of different inks without having to repeatedly flush and refill each reservoir 11 and print head 9 more than necessary.
  • Each print head 9 operates in accordance with a drop on demand process whereby ink is ejected by the print head 9 solely when it is required for deposition on a media surface.
  • FIG 2 this illustrates in more detail the print head 9 which includes a nozzle 13 of around 18 ⁇ m in diameter through which droplets of ink are ejected so as to impinge on the surface 3 of the media 5.
  • a print head 9 is selected with a nozzle diameter which provides the desired characteristics in both shape and volume of ejected ink.
  • the composition and processing steps required to form an ink suitable for printing with the printer 1 are described in detail below.
  • an ink containing nano-sized particles i.e. individual particles having a maximum dimension less than 1 ⁇ m, is formulated by firstly selecting 100 a solid starting material such as, but not limited to, a metal powder, metal salts, metal oxides and ceramic material.
  • a solid starting material such as, but not limited to, a metal powder, metal salts, metal oxides and ceramic material.
  • metals include silver, silver/palladium and platinum whilst examples of ceramics include lead zirconate titanate, zirconia and alumina.
  • the individual particles typically have a size in the range of 2 ⁇ m to 10nm.
  • the solvent carrier will contain between 5 and 60% by volume starting material.
  • the solvent carrier must be selected so that it will not destructively interfere with the print head 9 as a result of a chemical process and/or tribological action. Consequently, a solvent such as toluene or acetone should be avoided as should certain types of starting material which have a tribolgical impact, unless, of course, such wear is deemed acceptable.
  • the starting material should be selected such that it does not exhibit electrostatic or Van der Waals forces which are sufficient to bring about agglomerations of the starting material which might interfere with the operation of the print head 9 through the formation of blockages, for example.
  • the solvent should also be selected for its ability to wet the print head 9 and also with a view to defining the drying time of the ink once in contact with the media 5.
  • the choice of an aqueous or non-aqueous solvent will, again, depend on the nature of the starting material.
  • non-aqueous dispersants include ethyl-lactate and those which are alcohol based including combinations of ethanol and propan-2-ol, ethylene glycol and other alcohols.
  • an aqueous solution it has been found necessary to add a small amount of an alcohol such as ethanol to provide the wetting characteristics necessary to ensure the final ink composition is capable of wetting the print head 9.
  • a dispersant or a surfactant to the mixture of the solid material and solvent.
  • a surfactant is particularly suitable, of course, for use with an aqueous solvent.
  • the molecular structure of the dispersant or surfactant is such that each molecule has one end compatible with the material and another end which is compatible with the solvent. As a result, the dispersant or surfactant binds the solvent to the material.
  • One example of a formulation which has achieved favourable results is one containing 5% by volume silver oxide, EFHK 440 as a dispersant at 2% by weight of the silver oxide mass and t e remainder being an ethanol/propanol solvent carrier.
  • the viscosity of the ink will be in the range of 10-60cPs at ambient temperature, namely in the range of around 16°C to 35°C. More preferably, the viscosity will be selected to be in the range of 20-50cPs.
  • the reservoir 11 of the printer 1 is filled with ink prepared in accordance with the above procedure.
  • the printer 1 itself, as has been mentioned, is capable of delivering ink to a medium 5 placed on the bed 7 at a particular position defined by the x and y co-ordinates. Furthermore, because the bed 7 itself may be moved in the z direction it is possible to deposit ink onto the medium 5 at a number of x and y coordinates and at a fixed z position before displacing the bed 7 in the z direction and again depositing material at selected x and y co-ordinates. In this manner, it is possible to build up a structure 500 on the medium 5 having a three-dimensional structure ( Figures 5a and 5b). Clearly, a two dimensional structure 600 ( Figures 6a and 6b) can be created by depositing the ink over the medium 5 with the bed 7 held in a fixed position relative to the print head 9.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Optics & Photonics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Organic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Ink Jet (AREA)
  • Medicines Containing Antibodies Or Antigens For Use As Internal Diagnostic Agents (AREA)

Abstract

Une technique de dépôt par jet d'encre utilise une formulation d'encre contenant une matière de grosseur nanométrique. La matière ou la charge de grosseur nanométrique est formulée pour avoir une grosseur particulière moyenne inférieure à 1 micron. La charge peut comprendre une poudre métallique, un sel métal, un oxyde métallique ou une matière céramique. La formulation d'encre est particulièrement adaptée au dépôt de structures tridimensionnelles complexes de petite échelle.
PCT/GB2004/000040 2003-01-10 2004-01-08 Depot de nanoparticules par jet d'encre WO2004063295A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB0512793A GB2411406B (en) 2003-01-10 2004-01-08 Ink jet deposition of nanoparticles

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB0300529.5 2003-01-10
GBGB0300529.5A GB0300529D0 (en) 2003-01-10 2003-01-10 Improvements in and relating to ink jet deposition

Publications (1)

Publication Number Publication Date
WO2004063295A1 true WO2004063295A1 (fr) 2004-07-29

Family

ID=9950917

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB2004/000040 WO2004063295A1 (fr) 2003-01-10 2004-01-08 Depot de nanoparticules par jet d'encre

Country Status (2)

Country Link
GB (2) GB0300529D0 (fr)
WO (1) WO2004063295A1 (fr)

Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007055443A1 (fr) * 2005-11-09 2007-05-18 Advanced Nano Products Co., Ltd. Encre métallique, procédé de fabrication d’une électrode l’utilisant et substrat
KR100819904B1 (ko) * 2007-02-12 2008-04-08 주식회사 나노신소재 금속성 잉크, 그리고 이를 이용한 전극형성방법 및 기판
WO2008077850A2 (fr) * 2006-12-21 2008-07-03 Agfa Graphics Nv Procédés d'impression à jet d'encre en 3d
WO2009017648A1 (fr) * 2007-07-26 2009-02-05 The Ex One Company, Llc Suspensions de nanoparticules utilisées dans l'impression tridimensionnelle
US7674300B2 (en) 2006-12-28 2010-03-09 Kimberly-Clark Worldwide, Inc. Process for dyeing a textile web
US7740666B2 (en) 2006-12-28 2010-06-22 Kimberly-Clark Worldwide, Inc. Process for dyeing a textile web
US7749299B2 (en) 2005-01-14 2010-07-06 Cabot Corporation Production of metal nanoparticles
EP2305761A1 (fr) * 2009-10-05 2011-04-06 Österreichische Staatsdruckerei GmbH Encre pour jet d'encre
FR2964664A1 (fr) * 2010-09-13 2012-03-16 Commissariat Energie Atomique Encre aqueuse pour la realisation d'electrodes de cellule electrochimique haute temperature
US8167393B2 (en) 2005-01-14 2012-05-01 Cabot Corporation Printable electronic features on non-uniform substrate and processes for making same
US8182552B2 (en) 2006-12-28 2012-05-22 Kimberly-Clark Worldwide, Inc. Process for dyeing a textile web
CN101563208B (zh) * 2006-12-21 2012-10-17 爱克发印艺公司 3d-喷墨印刷法
US8334464B2 (en) 2005-01-14 2012-12-18 Cabot Corporation Optimized multi-layer printing of electronics and displays
US8383014B2 (en) 2010-06-15 2013-02-26 Cabot Corporation Metal nanoparticle compositions
US8597397B2 (en) 2005-01-14 2013-12-03 Cabot Corporation Production of metal nanoparticles
US8632613B2 (en) 2007-12-27 2014-01-21 Kimberly-Clark Worldwide, Inc. Process for applying one or more treatment agents to a textile web
CN106009918A (zh) * 2016-06-07 2016-10-12 陈剑锋 一种陶瓷喷墨打印用氧化锆粉体及其制备方法
KR20200003300A (ko) * 2018-06-15 2020-01-09 경북대학교 산학협력단 재료분사방식의 3d 프린터 및 이를 이용한 3d 모델 프린팅 방법
US11241828B2 (en) 2016-04-28 2022-02-08 Hewlett-Packard Development Company, L.P. 3-dimensional printing
US11427725B2 (en) 2016-04-28 2022-08-30 Hewlett-Packard Development Company, L.P. Photoluminescent material sets
US11465341B2 (en) 2016-04-28 2022-10-11 Hewlett-Packard Development Company, L.P. 3-dimensional printed parts

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998051749A1 (fr) * 1997-05-12 1998-11-19 The General Electric Company, Plc Composition pour jet d'encre ne presentant pas de sedimentation
US6110266A (en) * 1997-11-06 2000-08-29 Bayer Aktiengesellschaft Ink-jet inks containing nanometer-size inorganic pigments
WO2003038002A1 (fr) * 2001-11-01 2003-05-08 Yissum Research Development Company Of The Hebrew University Of Jerusalem Encres pour jet d'encre contenant des nanoparticules metalliques
WO2003106573A1 (fr) * 2002-06-13 2003-12-24 Nanopowders Industries Ltd. Procede de fabrication de nano-revetements, de nano-encres et de revetements et de nano-poudres conducteurs et transparents et encres ainsi produites
WO2003107359A1 (fr) * 2002-06-14 2003-12-24 Hyperion Catalysis International, Inc. Encres et revetements a base de fibrilles de carbone electro-onducteurs

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004005413A1 (fr) * 2002-07-03 2004-01-15 Nanopowders Industries Ltd. Nano-encres conductrices frittees a basses temperatures et procede de production de ces dernieres
GB0225202D0 (en) * 2002-10-30 2002-12-11 Hewlett Packard Co Electronic components

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998051749A1 (fr) * 1997-05-12 1998-11-19 The General Electric Company, Plc Composition pour jet d'encre ne presentant pas de sedimentation
US6110266A (en) * 1997-11-06 2000-08-29 Bayer Aktiengesellschaft Ink-jet inks containing nanometer-size inorganic pigments
WO2003038002A1 (fr) * 2001-11-01 2003-05-08 Yissum Research Development Company Of The Hebrew University Of Jerusalem Encres pour jet d'encre contenant des nanoparticules metalliques
WO2003106573A1 (fr) * 2002-06-13 2003-12-24 Nanopowders Industries Ltd. Procede de fabrication de nano-revetements, de nano-encres et de revetements et de nano-poudres conducteurs et transparents et encres ainsi produites
WO2003107359A1 (fr) * 2002-06-14 2003-12-24 Hyperion Catalysis International, Inc. Encres et revetements a base de fibrilles de carbone electro-onducteurs

Cited By (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8668848B2 (en) 2005-01-14 2014-03-11 Cabot Corporation Metal nanoparticle compositions for reflective features
US8597397B2 (en) 2005-01-14 2013-12-03 Cabot Corporation Production of metal nanoparticles
US8334464B2 (en) 2005-01-14 2012-12-18 Cabot Corporation Optimized multi-layer printing of electronics and displays
US7749299B2 (en) 2005-01-14 2010-07-06 Cabot Corporation Production of metal nanoparticles
US8167393B2 (en) 2005-01-14 2012-05-01 Cabot Corporation Printable electronic features on non-uniform substrate and processes for making same
KR100768341B1 (ko) 2005-11-09 2007-10-17 주식회사 나노신소재 금속성 잉크, 그리고 이를 이용한 전극형성방법 및 기판
WO2007055443A1 (fr) * 2005-11-09 2007-05-18 Advanced Nano Products Co., Ltd. Encre métallique, procédé de fabrication d’une électrode l’utilisant et substrat
US8142860B2 (en) 2006-12-21 2012-03-27 Agfa Graphics Nv 3D-inkjet printing methods
WO2008077850A2 (fr) * 2006-12-21 2008-07-03 Agfa Graphics Nv Procédés d'impression à jet d'encre en 3d
WO2008077850A3 (fr) * 2006-12-21 2008-10-09 Agfa Graphics Nv Procédés d'impression à jet d'encre en 3d
CN101563208B (zh) * 2006-12-21 2012-10-17 爱克发印艺公司 3d-喷墨印刷法
US8182552B2 (en) 2006-12-28 2012-05-22 Kimberly-Clark Worldwide, Inc. Process for dyeing a textile web
US7740666B2 (en) 2006-12-28 2010-06-22 Kimberly-Clark Worldwide, Inc. Process for dyeing a textile web
US7674300B2 (en) 2006-12-28 2010-03-09 Kimberly-Clark Worldwide, Inc. Process for dyeing a textile web
KR100819904B1 (ko) * 2007-02-12 2008-04-08 주식회사 나노신소재 금속성 잉크, 그리고 이를 이용한 전극형성방법 및 기판
WO2009017648A1 (fr) * 2007-07-26 2009-02-05 The Ex One Company, Llc Suspensions de nanoparticules utilisées dans l'impression tridimensionnelle
US8632613B2 (en) 2007-12-27 2014-01-21 Kimberly-Clark Worldwide, Inc. Process for applying one or more treatment agents to a textile web
EP2305761A1 (fr) * 2009-10-05 2011-04-06 Österreichische Staatsdruckerei GmbH Encre pour jet d'encre
US8383014B2 (en) 2010-06-15 2013-02-26 Cabot Corporation Metal nanoparticle compositions
US9005488B2 (en) 2010-09-13 2015-04-14 Commissariat A L'energie Atomique Et Aux Energies Alternatives Aqueous ink for producing high-temperature electrochemical cell electrodes
WO2012035226A1 (fr) * 2010-09-13 2012-03-22 Commissariat A L'energie Atomique Et Aux Energies Alternatives Encre aqueuse pour la realisation d'electrodes de cellule electrochimique haute temperature
FR2964664A1 (fr) * 2010-09-13 2012-03-16 Commissariat Energie Atomique Encre aqueuse pour la realisation d'electrodes de cellule electrochimique haute temperature
US11241828B2 (en) 2016-04-28 2022-02-08 Hewlett-Packard Development Company, L.P. 3-dimensional printing
US11427725B2 (en) 2016-04-28 2022-08-30 Hewlett-Packard Development Company, L.P. Photoluminescent material sets
US11465341B2 (en) 2016-04-28 2022-10-11 Hewlett-Packard Development Company, L.P. 3-dimensional printed parts
US11981075B2 (en) 2016-04-28 2024-05-14 Hewlett-Packard Development Company, L.P. 3-dimensional printed parts
CN106009918A (zh) * 2016-06-07 2016-10-12 陈剑锋 一种陶瓷喷墨打印用氧化锆粉体及其制备方法
KR20200003300A (ko) * 2018-06-15 2020-01-09 경북대학교 산학협력단 재료분사방식의 3d 프린터 및 이를 이용한 3d 모델 프린팅 방법
KR102120732B1 (ko) 2018-06-15 2020-06-10 경북대학교 산학협력단 재료분사방식의 3d 프린터 및 이를 이용한 3d 모델 프린팅 방법

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