WO2002036840A1 - Tole d"acier laminee a chaud presentant une resistance elevee a la traction et procede de fabrication - Google Patents
Tole d"acier laminee a chaud presentant une resistance elevee a la traction et procede de fabrication Download PDFInfo
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- WO2002036840A1 WO2002036840A1 PCT/JP2001/009469 JP0109469W WO0236840A1 WO 2002036840 A1 WO2002036840 A1 WO 2002036840A1 JP 0109469 W JP0109469 W JP 0109469W WO 0236840 A1 WO0236840 A1 WO 0236840A1
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/34—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the shape of the material to be treated
- C23C2/36—Elongated material
- C23C2/40—Plates; Strips
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/01—Layered products comprising a layer of metal all layers being exclusively metallic
- B32B15/013—Layered products comprising a layer of metal all layers being exclusively metallic one layer being formed of an iron alloy or steel, another layer being formed of a metal other than iron or aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/14—Ferrous alloys, e.g. steel alloys containing titanium or zirconium
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/004—Dispersions; Precipitations
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/005—Ferrite
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0226—Hot rolling
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12785—Group IIB metal-base component
- Y10T428/12792—Zn-base component
- Y10T428/12799—Next to Fe-base component [e.g., galvanized]
Definitions
- the present invention relates to a high-strength hot-rolled steel sheet suitable for undercarriage members of automobiles, particularly a high-tensile hot-rolled steel sheet having a tensile strength of 550 MPa or more, and a method for manufacturing the same.
- a high-strength hot-rolled steel sheet suitable for undercarriage members of automobiles particularly a high-tensile hot-rolled steel sheet having a tensile strength of 550 MPa or more
- a method for manufacturing the same about the method.
- Hot-rolled steel sheets for automobiles are being developed to have higher tensile strength and thinner wall thickness.
- high-tensile and thin-walled hot rolled steel sheets for undercarriage members such as wheels and suspension arms, which have a large effect.
- the undercarriage members have complicated shapes, the hot-rolled steel sheets used for them need to have high elongation as well as excellent elongation and stretch flangeability.
- Japanese Patent Application Laid-Open No. 4-329848 discloses a composite structure steel sheet having a ferrite structure and a second phase (pearlite, bainite, martensite, retained austenite, etc.) and having excellent fatigue properties and stretch flangeability. .
- a second phase pearlite, bainite, martensite, retained austenite, etc.
- Japanese Patent Application Laid-Open No. Hei 6-172924 proposes a steel sheet having a high dislocation density and having a payetic ferrite structure and excellent stretch flangeability. However, sufficient elongation cannot be obtained because of the vanitic ferrite structure having a high dislocation density.
- Japanese Patent Application Laid-Open No. 6-200351 proposes a steel sheet which is mainly made of polygonal ferrite and has excellent stretch flangeability, which is made to have a high tensile strength by utilizing precipitation strengthening by TiC and solid solution strength. ing. However, since large amounts of Ti are required, large precipitates are formed, and excellent elongation and stretch flangeability cannot be stably obtained.
- Japanese Patent Application Laid-Open No. 7-11382 proposes a steel sheet excellent in stretch flangeability having an ashes ferrite structure in which fine TiC and NbC are precipitated. However, sufficient elongation cannot be obtained because of the high dislocation density ferrite structure.
- Japanese Patent Application Laid-Open No. 11-152544 proposes a steel sheet having a fine grain size of 2 m or less by adding Ti, Nb, V, and Mo.
- excellent elongation cannot be obtained due to the fine particles having a particle size of 2 m or less.
- the present invention relates to a high-strength hot-rolled steel sheet having a tensile strength of 550 mm or more, excellent in elongation and stretch flangeability, and suitable for a member having a complicated shape such as an undercarriage member of an automobile. It is an object of the present invention to provide a method for producing the same.
- An object of the present invention is to provide a matrix containing a ferrite-set coagulant single phase and a particle size dispersed in the matrix, containing 0.15% by weight, Ti: 0.02-0.35%, and Mo: 0.05-0.7% by weight.
- This is achieved by a high-tensile hot-rolled steel sheet comprising fine precipitates of less than 10 nm. More specifically, for example, it is a high-tensile hot-rolled steel sheet comprising the following components.
- Such a high-strength hot-rolled steel sheet includes, for example, a step of hot-rolling a steel slab having the above components at an Ar3 transformation point or higher to produce a hot-rolled steel sheet, and a step of winding the hot steel sheet at 550 to 700 ° C.
- FIG. 1 is a diagram showing a relationship between the number of fine charcoal swords per unit volume and TS.
- FIG. 2 is a diagram showing the relationship between the particle diameter of Fe carbide and ⁇ .
- FIG. 3 is a diagram showing the relationship between the volume fraction of Fe carbide and ⁇ .
- FIG. 4 is a diagram showing the relationship between the amounts of Si and Mo and the surface properties.
- FIG. 5 is a diagram showing the relationship between TS XEL / ta2 and press workability.
- FIG. 6 is a graph showing the relationship between the amount of dissolved C and EL. MODES FOR CARRYING OUT THE INVENTION As a result of studying the elongation and stretch flangeability of a high-tensile hot-rolled steel sheet, the present inventors have obtained the following knowledge.
- Precipitation such as charcoal nitride becomes fine by the addition of Mo.
- the content of C ⁇ 0.15%, Ti: 0.02-0.35, Mo: 0.05-0.7% by weight% the matrix is substantially a ferrite structure single phase, and the particle size in the matrix is less than 10 nm. If fine precipitates are deposited, excellent tensile strength of 550 MPa or more and excellent It has been found that a high-strength hot-rolled steel sheet having elongation and stretch flangeability can be obtained.
- C, Ti, and Mo amounts are limited for the following reasons.
- the C content needs to be 0.15% or less.
- the Ti content is less than 0.02%, the amount of fine precipitates decreases and it is difficult to obtain a tensile strength of 550 MPa or more. If the Ti content exceeds 0.35%, the ferrite fiber becomes finer and the total elongation tends to decrease. Must be -0.35%.
- the Mo content is 0.05% or more, it forms fine composite precipitates with Ti while suppressing the pearlite transformation and strengthens the steel while maintaining excellent elongation and stretch flangeability. Can be. However, when the content exceeds 0.7%, a hard phase is formed, and the stretch flangeability decreases. Therefore, the amount of Mo needs to be 0.05-0.7%.
- the ferrite structure single phase does not need to be 100% ferrite structure, and the object of the present invention can be achieved if the ferrite composition It is 95% or more.
- the particle size of fine precipitates precipitated in the matrix is 10 nm or more, it is difficult to obtain a tensile strength of 550 MPa or more. Therefore, if a precipitate having a grain size of 10 nm or more is used, it is necessary to increase the volume fraction of the precipitate, which causes the ferrite fiber to become finer and the elongation to decrease. Therefore, the particle size of the fine precipitate is less than 10 nm, but more preferably 5 nm or less. In order to further increase the tension, the thickness is more preferably 3 nm or less.
- the fine precipitate is a composite carbide containing Ti and Mo. It is considered that the growth rate of the carbide is slowed down because Mo, which has a low diffusion rate, forms a charcoal hydride together with Ti, and a fine charcoal ridge is formed.
- steel containing C: 0.03-0.15%, Ti: 0.03-0.25%, Mo: tr.-0.7% is hot-rolled at a finishing temperature of 900 ° C. Winding at a temperature of 500-800 ° C to produce a 2.3 mm hot-rolled steel sheet, the amount of fine precipitates and the tensile strength TS The relationship was investigated. As a result, as shown in Fig.
- TS of 550 Pa or more becomes 1 ⁇ 10 5 I m 3 or more to the 700 MPa or more TS it can be seen that 2X10 5 cells / m 3 or more to the 780 MPa or more TS can be surely obtained.
- the high-strength hot-rolled steel sheet of the present invention may contain Fe carbide having a relatively large grain size in addition to fine precipitates having a size of less than 10 nm. Since the size of Fe charcoal with a large grain size is not favorable for stretch flangeability, the relationship between grain size (average grain size), volume fraction and stretch flangeability of Fe carbide was investigated using the above hot rolled steel sheet. . Here, the particle size (average particle size) and volume ratio of Fe carbide were observed by an electron microscope and determined by image analysis.
- Fig. 2 shows the relationship between the particle size of Fe carbide and the hole expansion ratio
- Fig. 3 shows the relationship between the volume ratio of Fe carbide and the hole expansion ratio.
- the particle size of the Fe charcoal dagger exceeds 1 m or the volume fraction of the Fe carbide exceeds 1%, ⁇ is less than 80%, which indicates that the stretch flangeability is deteriorated. Therefore, it is preferable that the particle size of Fe carbide be less than 1 ⁇ m and the volume fraction be 1% or less.
- the investigation of the paper weave and the fine precipitate in the present invention was performed by the following method.
- Samples were prepared by electropolishing using the jet-jet method and observed at an accelerating voltage of 200 kV using a transmission electron microscope.
- the crystal orientation of the parent phase is controlled so that the fine precipitate has a measurable contrast with respect to the parent phase, and the defocus is shifted from the normal focus to minimize the number of precipitates.
- Observation was performed by the method.
- the thickness of the sample in the area where the precipitate particles were measured was evaluated by measuring the intensity of the elastic scattering peak and the non-uniform scattering peak using electron energy loss spectroscopy. According to this method, the measurement of the number of particles and the measurement of the sample thickness can be performed in the same region.
- the number of particles was measured at four locations of 0.5 ⁇ 0.5 m on the sample and calculated as the number of particles projected and observed per 1 m 2 . From this value and the sample thickness, the number of precipitate particles per 1 m 3 was calculated. In addition, chemical analysis of precipitates was also performed by energy dispersive X-ray analysis.
- the high tensile strength hot rolled steel sheet of the present invention As a more specific example of the high tensile strength hot rolled steel sheet of the present invention, the following high tensile strength hot rolled steel sheet can be given.
- C more than 0.06% and less than 0.15% by weight, Si ⁇ 0.5%.
- Mn 0.5-2.0, P ⁇ 0.06, S ⁇ 0.005%, A1 ⁇ 0.1%, N ⁇ 0.006%, Ti : More than 0.10%, less than 0.35%, Mo: 0.3-0.7%, balance being Fe, and substantially ferrite; 5X10 4 fine precipitates with a particle size of less than 10 nm in the matrix of W single phase I / xm High-tensile hot-rolled steel sheet dispersed at a ratio of 3 or more.
- (1) and (2) are high-strength hot-rolled steel sheets with a tensile strength of 780 MPa or more, and (3) are high-tensile hot-rolled steel sheets with a tensile strength of 950 MPa or more.
- C forms charcoal swords and is effective in strengthening steel, depending on the amounts of Ti, Mo, Nb, and V described below.
- C a steel sheet having a tensile strength of 780 MPa
- C if the C force exceeds 0.06%, pearlite is formed or precipitates are coarsened to deteriorate elongation and stretch flangeability. Therefore, C ⁇ 0.06%.
- C in the case of a steel sheet with a tensile strength of 980 MPa, C needs to be 0.15% or less for the same reason, but C must exceed 0.06% to obtain the desired strength. Therefore, C is set to be more than 0.06% and 0.15% or less.
- the balance between the C amount and the Ti and Mo amounts described below is desirably 0.8 ⁇ (C 1 12) I [(Ti 1 48) + (Mo / 96)] ⁇ 1.3.
- Si is an effective element for solid solution strengthening, but if it exceeds 0.5%, precipitation of C from ferrite is promoted, and coarse Fe carbides are easily precipitated at grain boundaries, and the stretch flangeability decreases. I do. On the other hand, when the Si content exceeds 0.5%, hot rolling of thin steel sheets with a thickness of 2.5 mm or less becomes unstable. Therefore, Si ⁇ 0.5%.
- Mn Mn must be 0.5% or more from the viewpoint of strengthening the steel by solid solution strengthening. When the force exceeds 2.0%, segregation occurs or a hard phase is formed, and the stretch flangeability decreases. Therefore, Mn: 0.5-2.0%.
- P is effective for solid solution strengthening, but if it exceeds 0.06%, segregation occurs and the stretch flangeability decreases. Therefore, P ⁇ 0.06%.
- A1 is added as a deoxidizer, but if it exceeds 0.1%, both elongation and stretch flangeability decrease. Therefore, Al ⁇ 0.1%.
- N is preferably as small as possible. If it exceeds 0.006%, coarse nitrides increase and elongation flangeability decreases. Therefore, N ⁇ 0.006%.
- Ti As noted above, Ti forms fine composite carbides with Mo and strengthens the steel while maintaining excellent elongation and stretch flangeability.
- Bow 1 Ti 0.02-0.10% for steel plate with 780 MPa grade tensile strength, Ti: 0.10% to 035% for steel plate with tensile strength of 950 MPa.
- Nb 0.08% and V ⁇ 0.15% are effective for fine-grained paper weave, and form composite precipitates together with Ti and Mo to contribute to excellent elongation and improvement of stretch flangeability.
- Nb exceeds 0.08% or V exceeds 0.15%, elongation deteriorates, so Nb ⁇ 0.08% and V ⁇ 0.15%.
- Nb exceeds 0.08% or V exceeds 0.15%, elongation deteriorates, so Nb ⁇ 0.08% and V ⁇ 0.15%. From the viewpoint of reducing the grain size of the yarn II ⁇ with Nb or V, it is preferable to set 0.005% ⁇ Nb and 0.001% ⁇ V.
- high-tensile hot-rolled steel sheet of the present invention in addition to the above-mentioned three types of high-tensile hot-rolled steel sheets, the following high-tensile hot-rolled steel sheets containing W can be mentioned.
- the elongation is further improved when the solid solution C is 0.0020%, as shown in Example 7 described later.
- Fig. 4 shows the relationship between Si and Mo contents and surface properties.
- the results in the figure show the degree of scale defects caused by Si. ⁇ means very good degree of defects, ⁇ means good, and X means bad.
- the high-strength hot-rolled steel sheet of (1) above is, for example, substantially as follows: weight% ⁇ 0.06%, Si ⁇ 0.5%, Mn: 0.5-2.0%, P ⁇ 0.06, S ⁇ 0.005%, Al ⁇ 0.1 %, N ⁇ 0.006%, Mo: 0.05-0.6%, Ti: 0.02-0.10%, balance of Fe, and 0.8 ⁇ (C / 12) / [(Ti / 48) + (Mo / 96)] ⁇
- Manufacture of high-tensile hot-rolled steel sheet comprising the steps of hot-rolling a steel slab satisfying 1.3 above the Ar3 transformation point to produce a hot-rolled steel sheet and winding the hot-rolled steel sheet at 550-700 ° C It can be manufactured by a method.
- the high-strength hot-rolled steel sheet of (2) above is, for example, substantially ⁇ 0.06% by weight, Si ⁇ 0.5%, Mn: 0.5-2.0, P ⁇ 0.06%, S ⁇ 0.005%, Al ⁇ 0.1%, N ⁇ 0.006%, Mo: 0.05-0.6%, Ti: 0.02-0.10%,) ⁇ 0.08% and V 0.15 % Of at least one element, the balance being Fe, if the steel slab is manufactured under the same hot rolling conditions as the steel sheet of (1).
- the high-strength hot-rolled steel sheet of (3) above is, for example, substantially as follows: C: 0.06% to 0.15% by weight, Si ⁇ 0.5%, Mn: 0.5-2.0%, P. ⁇ 0.06%, S ⁇ 0.005%, Al ⁇ 0.1%, N ⁇ 0.006%, Ti: 0.10%, 0.35% or less, Mo: 0.3-0.7%, balance of Fe, and 0.8 ⁇ (C 1 12) I [(Ti / 48 ) + (Mo / 96)] ⁇ 1.3 if the steel slab is manufactured under the same hot rolling conditions as the steel sheet in (1).
- the hot rolling is performed at a temperature lower than the Ar3 transformation point, coarse grains are generated, the elongation is reduced, and the precipitates undergo a strain-inducing phenomenon to become coarse.
- the hot rolling is performed at a temperature higher than the Ar3 transformation point, more preferably 880%. It must be performed at ° C or higher.
- After hot rolling it is necessary to wind at a temperature of 550 ° C or higher, more preferably 600 ° C or higher, to obtain a ferrite structure single phase.
- the steel slab can be rolled by a direct rolling method in which hot rolling is performed immediately after fabrication or after heat is applied. Further, it is also possible to heat or keep the rolled material before or during the finish rolling, or to perform continuous rolling by joining the rolled materials after the rough rolling.
- the high-tensile hot-rolled steel sheets (1) to (5) can be subjected to hot-dip galvanizing. In the high-tensile hot-rolled steel sheet of the present invention, since stable fine precipitates are dispersed and precipitated, the precipitates do not change even when the hot-dip galvanizing treatment is performed, and the steel sheet softens. There is no.
- Undercarriage members such as automobile suspension arms, reinforcements, side members, seat frames, and seat rails have complex shapes, making it difficult to manufacture by press forming with conventional high-strength hot-rolled steel sheets.
- Has good workability The use of the high-tensile hot-rolled steel sheets (1) to (5) makes it possible to manufacture such members with high quality and high yield.
- a 80% or more hole expansion rate and 700 MPa or more tensile strength TS, TS, elongation EL (%), the plate thickness t (mm) is (TSXEL) / t 2> high tensile heat satisfies 12000 Rolled steel sheets are suitable for undercarriage members of automobiles for the following reasons.
- TS XEL The product of TS and EL, TS XEL, is an index of the absorbed energy of the material and is effective as an index indicating the likelihood of press cracking, but the required value differs for each TS of the steel sheet. Also, since EL is a value dependent on the sheet thickness t, there is a preferred range of TS XEL expressed as a function of t for which there is no press cracking problem due to lack of EL for each TS.
- the EL of steel sheets with different t can be converted by Oliver's formula, and is proportional to t to the power of 0.2.
- a suspension arm was made with a 1200 ton press using a hot-rolled steel sheet containing C: 0.04%, Ti: 0.09, Mo: 0.2%, thickness: 3.5-2.7 mm, TS: 710-850 MPa. and, (S XEL) / t 2 and the press workability (without cracking: OK, cracking: NG) was investigated the relationship between.
- the steel sheet 1-3 of the present invention fine precipitates having a particle size of less than 10 nm were uniformly dispersed in the matrix of the single-phase ferrite structure. These fine precipitates were carbides containing Ti and Mo. These steel plates 1-3 have a TS of 800 MPa or more, a high EL and ⁇ , and do not cause press cracking.
- the steel sheet 4 as a comparative example is bainite (B) fiber, has a low EL, and causes press cracking.
- the steel sheet 5 is ferrite + pearlite (F + P) fiber, has a low ⁇ , and causes press cracking.
- Example 1 After heating the steel AP having the chemical composition shown in Table 3 to 1250, it was hot-rolled at a finishing temperature of 880-930, and the cooling rate and winding temperature were changed to produce a 3.2 mm thick steel plate 1-16. Was. Then, the same test as in Example 1 was performed.
- the steel sheet 1-10 which is an example of the present invention has a single phase of a ferrite structure, the grain size of the precipitate is less than 10 nm, and the value of Mo / (Ti + Nb + V + Mo) by atomic% is 0.25 or more. , 550 MPa or higher TS, high EL and ⁇ . In addition, according to observation with an electron microscope, fine precipitates were uniformly dispersed in the ferrite structure.
- the precipitate has a particle size of 10 nm or more, and the TS content is less than 550 MPa due to a small amount of C and a small amount of the precipitate.
- the steel sheet 14 since the Mn content is large and segregation is remarkable, and martensite is also formed, both EL and ⁇ are low.
- TS is less than 550 MPa because the amount of precipitates is small because the amount of Ti is small.
- the value of Mo / (Ti + Nb + Mo) is 0.25 or more, high TS and EL are obtained, and the plate shape is good.
- the value of Mo / (Ti + Nb + Mo) is less than 0.25, the EL is low, and the plate shape is remarkably wavy. This is because a low-temperature transformation phase was formed after rapid rolling after hot rolling to ensure strength.
- Table 6 shows the results. 'In the steel sheet 2-4 of the present invention, a uniform material can be obtained in the width direction and the surface properties are good. In particular, in steel sheets 2 and 3 in which Si + Mo is 0.5 or less, very good surface properties can be obtained. In the steel sheet 3, according to the transmission electron microscope, fine carbides including Ti and Mo were uniformly dispersed in the ferrite structure.
- the steel sheet 1 of the comparative example with no Mo added has a ferrite + pearlite structure, and the material variation ATS in the width direction is 30 MPa or more, and the AEL is as large as 2% or more. Further, in the steel sheet 5 of the comparative example in which the amount of Mo added is large and Ti / Mo is less than 0.1, the material variation is small, but the elongation is largely reduced.
- the material properties in the direction are small and the surface properties are very good.
- the steel sheet 6 of the comparative example containing no Mo is ferrite + pearlite, and the material variation ATS is 30 MPa or more, and AEL is 2% or more, which is large.
- the steel sheet 10 of the comparative example with a large amount of Cr added the formation of the low-temperature transformation phase could not be suppressed, and the ferrite yarn was obtained! !
- the surface properties of these steel sheets are very good because the content of Si + Mo is 0.5% or less.
- the material variation in the width direction is small, and the surface properties are good.
- the material variation in the width direction is small, and the surface properties are good. is there.
- the steel sheet 16 in which Si + Mo is 0.5% or less has very good surface properties.
- the variation in material is extremely small when the finishing temperature is 880 ° C or more.
- the steel sheet 27-29 with the winding temperature of 550-700 ° C shows extremely small material fluctuation and large elongation.
- the material variation is extremely small for the steel plate 32-34 whose finishing temperature is 880 ° C or more and whose winding temperature is 550-700 ° C.
- the Mo content is large and the Ti I Mo of the precipitate is less than 0.1, and the material variation is large.
- the winding temperature is as low as 500 ° C, bainite texture occurs, and the fluctuation of TS is particularly large.
- F Ferrite
- AF Ash ferrite
- B Bainite
- BF Binic ferrite
- P H
- Steel sheets 1-3 and 5-15 which are examples of the present invention, have a high EL and ⁇ since the component composition is within the range of the present invention and are ferrite in which Ti and Mo are uniformly dispersed in a carbide.
- the steel sheet 4 as a comparative example, a bainite structure having a high dislocation density is formed due to a low winding temperature, and the EL is low.
- the comparative steel sheets 16-18 pearlite or martensite force was formed, and both EL and ⁇ were low.
- the carbon / nitrides of Ti and Nb are not fine, and ⁇ is low because there is almost no precipitation of Mo carbide.
- TS and ⁇ are low because the amount of Ti added is small and the carbide of ⁇ is small.
- Mo was not added and the amount of Ti added was large, so that the precipitates were coarse and the amount was too large, and both the EL and the fly were low.
- Figure 6 shows the relationship between the amount of dissolved C and EL.
- Steel AM having the chemical composition shown in Table 10 was heated to 1250 ° C, hot-rolled at a finishing temperature of 880-930 ° C, and then cooled and coiled at different temperatures. -13 was produced. Here, the winding temperature was varied in a temperature range exceeding 600 ° C. Then, a JIS No. 5 test piece and a hole expanding test piece were collected, and a tensile test and a hole expanding test were performed. Precipitates were examined by transmission electron microscopy.
- Each of the steel sheets 1-9 of the present invention was composed of a single phase of ferrite structure, the average grain size of the precipitate was less than 10 nm, and the composition ratio of the precipitate satisfied 0.1 ⁇ Ti / Mo ⁇ 3. Therefore, TS is higher than 950 MPa and has high EL and ⁇ .
- the amount of C is too large, pearlite is generated because Mo is not added, the precipitates are coarse, and both EL and ⁇ are low. Further, in the steel sheet 11, the precipitates were coarse due to the absence of Mo, and both EL and ⁇ were low. In steel sheet 12, segregation is remarkable because the amount of ⁇ is too large, and both EL and ⁇ are low because martensite is formed in yarn III. In steel sheet 13, although there is a composite precipitate of Ti and Mo, the amount of C is too large, pearlite is generated, and the precipitate power S is coarsened, so that both EL and ⁇ are low.
- Heat steel A-E with the components shown in Table 12 to 1250 ° C, hot-roll at a finishing temperature of 890 ° C, wind at a winding temperature of 620 ° C, and produce steel plate 1-5 with a thickness of 3.2 mm. did. Then, the same tensile strength values and hole expansion ratios of the steel sheet as in Example 4 were examined at the center and the ends in the width direction. Precipitates were examined by transmission electron microscopy.
- the material variation is extremely small.
- the steel sheet 5 as a comparative example contains only Ti as a carbon / nitride forming element, EL and ⁇ are low, and the material variation is large.
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Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
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CA002395901A CA2395901C (en) | 2000-10-31 | 2001-10-29 | High strength hot rolled steel sheet and method for manufacturing the same |
EP01980929.2A EP1338665B1 (en) | 2000-10-31 | 2001-10-29 | High tensile hot rolled steel sheet and method for production thereof |
BRPI0107389-3A BR0107389B1 (pt) | 2000-10-31 | 2001-10-29 | folha de aço laminada a quente de alta resistência, método de fabricação da mesma e folha de aço galvanizado. |
ES01980929.2T ES2690275T3 (es) | 2000-10-31 | 2001-10-29 | Chapa de acero laminado en caliente de alta resistencia y método para la fabricación de la misma |
US10/108,691 US6666932B2 (en) | 2000-10-31 | 2002-03-28 | High strength hot rolled steel sheet |
US10/686,357 US20040074573A1 (en) | 2000-10-31 | 2003-10-14 | High strength hot rolled steel sheet and method for manufacturing the same |
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JP2000331682 | 2000-10-31 | ||
JP2000-331682 | 2000-10-31 | ||
JP2000331681 | 2000-10-31 | ||
JP2000-331681 | 2000-10-31 | ||
JP2001022726 | 2001-01-31 | ||
JP2001-022726 | 2001-01-31 | ||
JP2001044351 | 2001-02-20 | ||
JP2001044354 | 2001-02-20 | ||
JP2001-044354 | 2001-02-20 | ||
JP2001044352 | 2001-02-20 | ||
JP2001-044355 | 2001-02-20 | ||
JP2001-044352 | 2001-02-20 | ||
JP2001044355 | 2001-02-20 | ||
JP2001-044351 | 2001-02-20 | ||
JP2001282774A JP3637885B2 (ja) | 2001-09-18 | 2001-09-18 | 加工性に優れた超高張力鋼板ならびにその製造方法および加工方法 |
JP2001-282774 | 2001-09-18 |
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US10/108,691 Continuation US6666932B2 (en) | 2000-10-31 | 2002-03-28 | High strength hot rolled steel sheet |
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PCT/JP2001/009469 WO2002036840A1 (fr) | 2000-10-31 | 2001-10-29 | Tole d"acier laminee a chaud presentant une resistance elevee a la traction et procede de fabrication |
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US (2) | US6666932B2 (ja) |
EP (1) | EP1338665B1 (ja) |
KR (1) | KR100486753B1 (ja) |
CN (1) | CN1153841C (ja) |
BR (1) | BR0107389B1 (ja) |
CA (1) | CA2395901C (ja) |
ES (1) | ES2690275T3 (ja) |
WO (1) | WO2002036840A1 (ja) |
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- 2001-10-29 BR BRPI0107389-3A patent/BR0107389B1/pt not_active IP Right Cessation
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- 2001-10-29 ES ES01980929.2T patent/ES2690275T3/es not_active Expired - Lifetime
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Also Published As
Publication number | Publication date |
---|---|
US20040074573A1 (en) | 2004-04-22 |
EP1338665A1 (en) | 2003-08-27 |
EP1338665B1 (en) | 2018-09-05 |
US6666932B2 (en) | 2003-12-23 |
EP1338665A4 (en) | 2005-11-23 |
KR100486753B1 (ko) | 2005-05-03 |
ES2690275T3 (es) | 2018-11-20 |
CN1394237A (zh) | 2003-01-29 |
CA2395901A1 (en) | 2002-05-10 |
US20030063996A1 (en) | 2003-04-03 |
BR0107389A (pt) | 2002-09-10 |
KR20020070282A (ko) | 2002-09-05 |
CN1153841C (zh) | 2004-06-16 |
BR0107389B1 (pt) | 2011-02-22 |
CA2395901C (en) | 2006-07-18 |
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