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WO2002098966A2 - Aromatic principles for improving the stability in storage and/or for improving the solubility of polyvinyl alcohols and/or polyvinyl alcohols with bonded cellulose - Google Patents

Aromatic principles for improving the stability in storage and/or for improving the solubility of polyvinyl alcohols and/or polyvinyl alcohols with bonded cellulose Download PDF

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Publication number
WO2002098966A2
WO2002098966A2 PCT/EP2002/006246 EP0206246W WO02098966A2 WO 2002098966 A2 WO2002098966 A2 WO 2002098966A2 EP 0206246 W EP0206246 W EP 0206246W WO 02098966 A2 WO02098966 A2 WO 02098966A2
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WIPO (PCT)
Prior art keywords
oil
acetate
iso
methyl
ethyl
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PCT/EP2002/006246
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German (de)
French (fr)
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WO2002098966A3 (en
Inventor
Gerhard Meller
Hans Maier
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Drom Fragrances International Kg
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Priority to DE10292443T priority Critical patent/DE10292443D2/en
Publication of WO2002098966A2 publication Critical patent/WO2002098966A2/en
Publication of WO2002098966A3 publication Critical patent/WO2002098966A3/en

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L29/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
    • C08L29/02—Homopolymers or copolymers of unsaturated alcohols
    • C08L29/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
    • C08L1/02—Cellulose; Modified cellulose

Definitions

  • the present invention relates to the use of fragrances to improve the storage stability and / or better solubility of polyvinyl alcohol (PVAL) and / or polyvinyl alcohols with bound cellulose (PVACL).
  • PVAL polyvinyl alcohol
  • PVACL polyvinyl alcohols with bound cellulose
  • PVAL and PVACL are used industrially in a variety of ways, for example as a protective colloid, as a binder, as an additive in soaps, etc. These substances are also used in packaging films and water-soluble bags.
  • the properties of PVAL and PVACL can be controlled by acetalization or complexation or other additives.
  • the present invention has set itself the task of providing substances that make the stability of the packaging adjustable and replace or reduce commonly used solvents.
  • the invention therefore relates to the use of fragrances to improve the storage stability and / or better solubility of polyvinyl alcohol (PVAL) and / or polyvinyl alcohol with bound cellulose (PVACL).
  • PVAL polyvinyl alcohol
  • PVACL polyvinyl alcohol with bound cellulose
  • the fragrances for improving the storage stability are preferably selected from the group consisting of: Prunella Substitute; Aceteugenol; Apple Oliffac S; Aldehydes C-II; Aldehydes C-11 MOA; Aldehydes C-12 L; Aldehydes C-12 MNA; Allyl amyl glycolate; Allyl caproate; Bacdanol / Sandrol; Butyl cyclohexyl acetate PT; Cedramber; Celestolide; Chamomile oil blue; citronellal; Citronellyl oxyacetaldehydes; Costus Oliffac; Cuminyl acetate; Cyclamen aldehydes; Cycloctal; Cyclogalbanate; Damascone Alpha 937.470; Damascone Delta; Dihydro Coumarex; Dihydro eugenol 938520; Dihydro jasmones; Dihydro linalool; Dihydro ter
  • PVACL can be made more brittle using the fragrances mentioned below while maintaining its water solubility: bromostyrene replacement; Cassodrome F; Cassiflor Af 3137 drom subst;
  • Base Ylang Eco Essence Acet-iso-eugenol; Acetanisole; Alcohol C-10; Aldehydes C-18 So called; Aldehydes C-20 (IFF); Aldehydes C-8; Aldehydes C-9;
  • Algenone SP (Synarome); Ambroxane; Amyl vinyl carbinol / morillol;
  • Civette 102,035 D Civette 102,035 D
  • the compounds mentioned below can be used in a mixture with PVACL while maintaining the water-solubility of the mixture without having any negative effects on the stability of the mixture: Ambra 21750 base; Pineapple base; Bergamot Synth Base; Cassis R; Citrone 110060FCF; Citroen oil artificial Substitute 91161; Dianthos Base; Douschy base; Fir Balsam Base; Mandarin Ollifac Substitute; Rosana replacement; Acetate PA / Allyl phenoxyacetate; Agrumex / Verdox; Agrunutril / Citrinellyl Nitrile; Alcohol C-9; Aldehydes C-10; Aldehydes C-II EN; Aldehydes C-II ISO; Aldehydes Myrac; Allyl cyclohexane propionate; Amandolene; Amboryl acetates; Ambrettolide; Amyl benzoate; Amyl cinnamic aldehydes
  • Palmarosa Oil Patchuli oil; Patchuli Oil MD; Penny Royal Oil; Petigrain Oil
  • Ylang Ylang Oil III Wild srawberry; Amber core; Ambrettolide; Armoise Oil;
  • Citralva Clary Sage Oil
  • Dadecalactone Gamma Ethyl 2-methyl butyrate
  • fragrances are used in the quantity ranges known per se to the person skilled in the art.
  • the above-mentioned fragrances can be used in amounts of at least 2 ppm to adjust the solubility.
  • Table 1 shows a composition which has a plasticizing effect on PVACL.
  • Table 3 shows a formulation that acts more break-resistant on PVACL capsules:
  • the procedure for measuring the individual property changes due to the action of the fragrance mixtures was as follows: Capsules made of PVACL were completely inserted in the respective mixtures of the fragrances in accordance with Tables 1 to 3. After three or six weeks, the capsules were checked for their mechanical properties. The capsules treated with the perfume oil were then subjected to the various tests.
  • the solution test was carried out as follows: a sieve with a mesh size of 5 mm is attached about 5 cm above the bottom of the beaker in a 1 liter beaker (tall shape). Capsules are placed on the sieve and 600 ml of cold water are added to the beaker. The mixture is mixed with a magnetic stirrer and stirring fish at approx. 200 rpm. touched. If the capsules within 10 min. were dissolved without residue, the solubility of the capsules was affirmed.
  • the PVACL brittleness was measured before and after treatment with the perfume oils according to Table 2.
  • the capsules placed in the perfume oils were removed from the oils and bent in comparison to untreated capsules until they broke. The differences that occurred were assessed.
  • the examples in Tab. 4 relate to individual fragrances and their influence on PVACL after three or six weeks of exposure. Here, too, PVACL capsules were inserted into the fragrances and the properties were assessed as described above.

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Cosmetics (AREA)
  • Fats And Perfumes (AREA)

Abstract

The invention relates to the use of aromatic principles for improving the stability in storage and/or for improving the solubility of polyvinyl alcohol and/or polyvinyl alcohol with bonded cellulose.

Description

Duftstoffe zur Verbesserung der Laqerstabilität und/oder besseren Löslichkeit von Polyvinylalkoholen und/oder Polyvinylalkoholen mit gebundener Zellulose Fragrances to improve the storage stability and / or better solubility of polyvinyl alcohols and / or polyvinyl alcohols with bound cellulose
Gegenstand der vorliegenden Erfindung ist die Verwendung von Duftstoffen zur Verbesserung der Lagerstabilität und/oder besseren Löslichkeit von Polyvinylalkohol (PVAL) und/oder Polyvinylalkoholen mit gebundener Zellulose (PVACL).The present invention relates to the use of fragrances to improve the storage stability and / or better solubility of polyvinyl alcohol (PVAL) and / or polyvinyl alcohols with bound cellulose (PVACL).
PVAL und PVACL werden industriell vielfältig eingesetzt, beispielsweise als Schutzkolloid, als Bindemittel, als Zusatz in Seifen usw. Auch in Verpackungsfolien und wasserlöslichen Beuteln werden diese Stoffe eingesetzt. PVAL und PVACL sind durch Acetalisierung oder Komplexierung oder anderen Additiven in ihren Eigenschaften steuerbar.PVAL and PVACL are used industrially in a variety of ways, for example as a protective colloid, as a binder, as an additive in soaps, etc. These substances are also used in packaging films and water-soluble bags. The properties of PVAL and PVACL can be controlled by acetalization or complexation or other additives.
Um Produkte mit PVAL und PVACL für den Verbraucher attraktiver zu machen, hat sich die vorliegende Erfindung zur Aufgabe gemacht Stoffe zur Verfügung zu stellen, die die Stabilität der Verpackung einstellbar gestaltet und üblicherweise verwendete Lösungsmittel ersetzt oder reduziert.In order to make products with PVAL and PVACL more attractive to the consumer, the present invention has set itself the task of providing substances that make the stability of the packaging adjustable and replace or reduce commonly used solvents.
Überraschenderweise wurde gefunden, dass bei der Verwendung von Duftstoffen die oben genannte Aufgabe gelöst werden kann. Gegenstand der Erfindung ist mithin die Verwendung von Duftstoffen zur Verbesserung der Lagerstabilität und/oder besseren Lösiichkeit von Polyvinylalkohol (PVAL) und/oder Polyvinylalkohol mit gebundener Zellulose (PVACL).Surprisingly, it was found that the above object can be achieved when using fragrances. The invention therefore relates to the use of fragrances to improve the storage stability and / or better solubility of polyvinyl alcohol (PVAL) and / or polyvinyl alcohol with bound cellulose (PVACL).
Vorzugsweise sind die Duftstoffe zur Verbesserung der Lagerstabilität ausgewählt aus der Gruppe bestehend aus: Prunella Substitut; Aceteugenol; Apple Oliffac S; Aldehyde C-ll; Aldehyde C- 11 MOA; Aldehyde C-12 L; Aldehyde C-12 MNA; Allyl Amyl Glycolate; Allyl Caproate; Bacdanol/Sandrol; Butyl Cyclohexyl acetat P-T; Cedramber; Celestolide; Chamomile Oil Blue; Citronellal; Citronellyl Oxyacetaldehyde; Costus Oliffac; Cuminyl acetate; Cyclamen Aldehyde; Cycloctal; Cyclogalbanate; Damascone Alpha 937.470; Damascone Delta; Dihydro Coumarex; Dihydro Eugenol 938520; Dihydro Jasmone; Dihydro Linalool; Dihydro Terpineol; Dimethyl Cyclormol; Diphenyl Oxide; Ethyl Acetoacetate; Ethyl Amyl Ketone; Ethyl Benzoate; Ethyl Cinnamate; Ethyl Ortho Methoxy Benzoate; Eugenol; Exolide 941.910; Farenal/Adoxal; Fennel Oil sweet; Fleuramone/Projasmon P; Floralozone/Florazon; Florex 943.020; Florosia/ Apo Patchone; Fructone/ Herminal; Galbex 183; Geranium Mix- Eco Essence; Geranoxy Acetaldehyde; Geranyl Acetate; Hedione 964.898; Herbac; Hexyl Salicylate; Hydratropaldehyde Dimethylacetat; Ionone; Ionone Beta/ Irisone Beta 71%; Irival; Iso E Super; Iso-Amyl Caproate; Iso-Amyl Cinnamate; Iso- Amyl Salicylate; Iso- Butyl Benzoate; Iso-Butyl Caproate; Iso-Butyl Salicylate; Isoraldeine 70; Jasmin A 100.915; Kovaone; Lavender Oil 40/42%; Leaf Acetal; Lingantraal 06330; Linalool Oxide; Lyrame Super C; Mandarine Aldehyde 10 965765; Manzanate 10629; Melonal; Methyl Acetophenpne Para; Methyl Camomille; Methyl Eugenol; Methyl Octalactone; Methyl Octin Carbonate; Miel Oliffac; Myroxyde 962.608; Nectarol Sa 966418; Nerone; Neryl Acetate; Olibanol; Osmantinia Givco 140; Oxaspirane; Petiole; Petigrainoil synth.; Phenirat/Phenoxyethyl Isobutyl; Precyclemone B; Rhodinol Synth. E 9422197; Rhubafuran; Rosalva; Rose Glycol; Rose Oxide Inactive; Rosewood Oil; Sandalmysore Core; Spirambrene; Strawberry Oliffac; Styrallyl Acetate; Tamarine Base 41.310 G; Terpinyl Propionate; Tetrahydro Muguol; Thuja Oil; Tridecene 2 Nitrile; Trimofix O; Tuberose Artessence; Ultralide I 10800; Veloutone 990.257; Vernaldehyde; Vetiveryl Acetate Synth; Vetyvenal/Caryophyllene Acetat; Wormwood Oil; Methyl Octin Carbonate; Ambre 205 K PCM free; Benzyl- Iso- Eugenol; Cantryl; Cassis Body 05654; Cedarwoodoil Texas; Cedryl Acetates; Ebanol; Florhydral; Fruit See 17.907; Frutinat; Galbanum Oil; Galbanol; Herbavert; Jasmin 17.444 SA; Kephalis; Lemon Oil Terpenes; Lime Oxide; Limetol; Limettal; Loganberry; Longifolene; Mandarine Oil Light; Melone; Melonyl; Melusat; Mentha Citrata Oil; Menthol Oil; Menthone Pure; Methyl Ionone Alpha Isoraldehyde; Muscenone; Musk T 93 Ethylene Brasilate; Myristal; Nerolidol; Nonadyl; Oceano; Okoumal; Olibanum Oil; Orange Isolate; Orange Terpenes; Pelargene; Peppermint Oil Arvensis; Peranat; Pinene Alpha; Pinene Beta; Poivre Coir; Polycenide Base; Polysantol; Prenyl Acetate; Resorcinol Dimethylether; Rhodascone Base; Rholiate; Rose Oxide L-; Spike Lavender Oil; Terpinolene 90; Tree Moos Abs.; Verotyl; Vertofix Coeur; Watermelon Base. Die genannten Stoffe führen zu einer verbesserten Stabilität von PVACL im Gemenge, das auch seine Wasserlöslichkeit beibehält.The fragrances for improving the storage stability are preferably selected from the group consisting of: Prunella Substitute; Aceteugenol; Apple Oliffac S; Aldehydes C-II; Aldehydes C-11 MOA; Aldehydes C-12 L; Aldehydes C-12 MNA; Allyl amyl glycolate; Allyl caproate; Bacdanol / Sandrol; Butyl cyclohexyl acetate PT; Cedramber; Celestolide; Chamomile oil blue; citronellal; Citronellyl oxyacetaldehydes; Costus Oliffac; Cuminyl acetate; Cyclamen aldehydes; Cycloctal; Cyclogalbanate; Damascone Alpha 937.470; Damascone Delta; Dihydro Coumarex; Dihydro eugenol 938520; Dihydro jasmones; Dihydro linalool; Dihydro terpineol; Dimethyl cyclormol; Diphenyl oxides; Ethyl acetoacetate; Ethyl amyl ketones; Ethyl benzoate; Ethyl cinnamate; Ethyl ortho methoxy benzoate; eugenol; Exolide 941,910; Farenal / adoxal; Fennel oil sweet; Fleuramone / Projasmon P; Floralozone / Florazon; Florex 943.020; Florosia / Apo Patchone; Fructone / herminal; Galbex 183; Geranium Mix-Eco Essence; Geranoxy acetaldehydes; Geranyl acetates; Hedione 964,898; herbac; Hexyl salicylate; Hydratropaldehydes dimethyl acetate; Ionone; Ionone Beta / Irisone Beta 71%; Irival; Iso E Super; Iso-amyl caproate; Iso-amyl cinnamate; Iso-amyl salicylates; Isobutyl benzoate; Iso-butyl caproate; Isobutyl salicylate; Isoraldeine 70; Jasmine A 100,915; Kovaone; Lavender Oil 40/42%; Leaf acetal; Lingantraal 06330; Linalool oxides; Lyrame Super C; Mandarin aldehydes 10 965765; Manzanate 10629; melonal; Methyl acetophenpne para; Methyl camomille; Methyl eugenol; Methyl octalactone; Methyl octyne carbonate; Miel Oliffac; Myroxyde 962,608; Nectarol Sa 966418; Nerone; Neryl acetates; Olibanol; Osmantinia Givco 140; Oxaspirane; petiole; Petigrainoil synth .; Phenirate / phenoxyethyl isobutyl; Precyclemone B; Rhodinol synth. E 9422197; Rhubafuran; Rosalva; Rose glycol; Rose Oxide Inactive; Rosewood Oil; Sandal core; Spirambrene; Strawberry Oliffac; Styrallyl acetate; Tamarine base 41,310 G; Terpinyl propionate; Tetrahydro muguol; Thuja oil; Tridecene 2 nitriles; Trimofix O; Tuberose artessence; Ultralide I 10800; Veloutone 990.257; Vernaldehyde; Vetiveryl Acetate Synth; Vetyvenal / Caryophyllene Acetate; Wormwood oil; Methyl octyne carbonate; Ambre 205 K PCM free; Benzyl iso-eugenol; Cantryl; Cassis Body 05654; Cedarwoodoil Texas; Cedryl Acetates; ebanol; florhydral; Fruit See 17,907; Frutinat; Galbanum Oil; Galbanol; herbavert; Jasmine 17,444 SA; Kephalis; Lemon Oil Terpenes; Lime oxides; Limetol; Limettal; Loganberry; Longifolene; Mandarin oil light; Melon; Melonyl; Melusat; Mentha Citrata Oil; Menthol oil; Menthone Pure; Methyl ionone alpha isoraldehydes; Muscenone; Musk T 93 Ethylene Brasilate; Myristal; nerolidol; Nonadyl; Oceano; Okoumal; Olibanum oil; Orange isolates; Orange terpenes; Pelargene; Peppermint Oil Arvensis; Peranat; Pinene Alpha; Pinene beta; Poivre coir; Polycenide base; Polysantol; Prenyl acetate; Resorcinol dimethyl ether; Rhodascone Base; Rholiate; Rose Oxide L-; Spike lavender oil; Terpinolene 90; Tree Moss Abs .; Verotyl; Vertofix Coeur; Watermelon Base. The substances mentioned lead to an improved stability of PVACL in the mixture, which also retains its water solubility.
In einer weiteren Ausführungsform kann mittels der im Folgenden genannten Duftstoffe PVACL spröder eingestellt werden unter Erhalt seiner Wasserlöslichkeit: Bromstyrol Replacement; Cassodrom F; Cassiflor Af 3137 drom subst;In a further embodiment, PVACL can be made more brittle using the fragrances mentioned below while maintaining its water solubility: bromostyrene replacement; Cassodrome F; Cassiflor Af 3137 drom subst;
Chrysanthemal Base; Dromacetol; Base Frutonal 102620PCMF GeraniumChrysanthemal base; Dromacetol; Base Frutonal 102620PCMF Geranium
Bourbon Subst.Base; Muguet Base; Nitro Musk Replacer; Passion Fruit Subst;Bourbon Subst.Base; Muguet Base; Nitro Musk Replacer; Passion Fruit Subst;
Polycyciischer Musk Replacer; Rhubanil subst; Base Rose; Tonalid Replacer;Polycycian Musk Replacer; Rhubanil subst; Base rose; Tonalid Replacer;
Base Ylang Eco Essence; Acet-Iso-Eugenol; Acetanisole; Alcohol C-10; Aldehyde C-18 So called; Aldehyde C-20 (IFF); Aldehyde C-8; Aldehyde C-9;Base Ylang Eco Essence; Acet-iso-eugenol; Acetanisole; Alcohol C-10; Aldehydes C-18 So called; Aldehydes C-20 (IFF); Aldehydes C-8; Aldehydes C-9;
Algenone SP (Synarome); Ambroxane; Amyl Vinyl Carbinol/Morillol;Algenone SP (Synarome); Ambroxane; Amyl vinyl carbinol / morillol;
Andrane/Cedrene; Epoxide; Anisaldehyde-Dimethylacetal; Anisyl Acetate;Andrane / Cedrene; epoxides; Anisaldehyde dimethylacetal; Anisyl acetate;
Anisyl Alcohol; Banana D 50282 755964(H&R); Benzoin Sumatra Resin; BenzylAnisyl alcohol; Banana D 50282 755964 (H&R); Benzoin sumatra resin; benzyl
Salicylate; Bergamal; Boisantal Forte 651 (IFF); Brouts D Oranger Abs.; Buccoxime; Butyl Acetate IM; Butyl Cyclohexanone p-t; Calone 1951; Camphorsalicylates; Bergamal; Boisantal Forte 651 (IFF); Brouts D Orange Abs .; Buccoxime; Butyl acetate IM; Butyl cyclohexanone p-t; Calone 1951; Camphor
Crystals; Canthoxal; Cantofloral/Parafloral; Carvone L; Cassis Base 345F;Crystals; Canthoxal; Cantofloral / Parafloral; Carvone L; Cassis Base 345F;
Cedrenyl Formate; Cinnamic Alcohol; Cinnamic Aldehyde Chlorine Free; CistusCedrenyl formats; Cinnamic alcohol; Cinnamic Aldehyde Chlorine Free; Cistus
Abs.; Citral; Citralex; Citronellol; Citronellyl Formate; Civette 102.035 D;Section.; citral; Citralex; citronellol; Citronellyl formats; Civette 102,035 D;
Civettone 926851; Corps M E-242/CO; Cortexal SA 935.780; Coumarin; Cresyl Phenyl Acetate Para; Damascone Beta 939.692; Decahydro-Beta-NaphtolCivettone 926851; Corps M E-242 / CO; Cortexal SA 935.780; coumarin; Cresyl Phenyl Acetate Para; Damascone Beta 939.692; Decahydro-beta-naphthol
Trans; Decalactone Delta; Decalactone Gamma; Diethyl Malonate; Diheptyl Acetate/ Nopyl Acetate; Dihydro- Beta-Ionone; Dimethyl Benzyl Carbinol; Dimethyl Heptanol/Dimetol; Dimethyl Octanol/Tetrahydro G; Dimethyl Phenyl Ethyl Carbinol; Dulcinyl; Dynascone 10 939.750; Elemi Resin; Estragon Oil French; Ethyl Heptylate; Ethyl Lactate; Ethyl Linalool; Ethyl Phenylacetate; Ethyl Vanillin; Ethyl 3 Phenyl Glycidate; Evernyl; Exaltex 941.900; Fenchyl Acetate; Fenchyl Alcohol; Fiorivert FM 1372; Florascone B 942.965; Florol/ Florosa; Fragarol; Frambione; Framboson 10583 F; Galaxolide 50IPM; Galbanodor VIII; Gelsone; Geranium Oil Base B 719769; Geranyl Nitrile; Guaiacwoodoil; Heliocret 14502; Helional; Heliotropin; Heptene Cis-4-1 OL; Hexenal Trans-2; Hexenol Cis 3; Hexenyl Acetate Cis 3; Hexenyl Propionate Cis-3; Ho Leaf Oil; Hydroquinone Dimethylether; Hydroxycitronellal; Indoflor Crystals; Indole; Ionone Beta- extra 98%; Iso Amyl Acetate; Iso-Borneol Crystals; Iso- Butyl Phenylacetate; Iso-Nonyl Acetate/Neononylace; Iso-nonyl Formate; Iso-Pentyrate 951.517; Isonomilate 258E; Jasmopyrane Forte 04513; Labdanum Eal; Lemoral PCMF; Limbwood Basel09.289 B; Linalool Synth.; Lyral; Maceal Derivate a 900.550; Maderan; Magnol; Magnolan; Majantol; Maple Lactone/MCPAnhydre; Mayol 957.230; Melone AB 5304; Melone Oliffac; Mentol Crystals; Methoxy Melonal; Methyl Anthranilate; Methyl Cinnamate; Methyl Heptenone; Methyl Heptin Carbonate Substitution; Methyl Hexyl Keton; Methyl Naphtyl Ketone Beta; Methyl Quinoline Para; Methyltrans; Decalactone Delta; Decalactone gamma; Diethyl malonate; diheptyl Acetate / Nopyl Acetate; Dihydro beta ionones; Dimethyl benzyl carbinol; Dimethyl heptanol / dimetol; Dimethyl octanol / tetrahydro G; Dimethyl phenyl ethyl carbinol; Dulcinyl; Dynascone 10 939.750; Elemi Resin; Tarragon oil french; Ethyl heptylate; Ethyl lactate; Ethyl linalool; Ethyl phenylacetate; Ethyl vanillin; Ethyl 3 phenyl glycidate; Evernyl; Exaltex 941.900; Fenchyl acetates; Fenchyl alcohol; Fiorivert FM 1372; Florascone B 942.965; Florol / Florosa; Fragarol; Frambione; Framboson 10583 F; Galaxolide 50IPM; Galbanodor VIII; Gelsone; Geranium Oil Base B 719769; Geranyl nitriles; Guaiacwoodoil; Heliocret 14502; helional; heliotropin; Heptene Cis-4-1 OL; Hexenal Trans-2; Hexenol cis 3; Hexenyl acetate cis 3; Hexenyl propionate cis-3; Ho Leaf Oil; Hydroquinone dimethyl ether; Hydroxycitronellal; Indoflor crystals; indoles; Ionone beta extra 98%; Iso Amyl Acetate; Iso-Borneol Crystals; Isobutyl phenylacetate; Iso-Nonyl Acetate / Neononylace; Iso-nonyl formats; Iso-pentyrates 951,517; Isonomilate 258E; Jasmopyrane Forte 04513; Labdanum Eal; Lemoral PCMF; Limbwood Basel 09.289 B; Linalool Synth .; lyral; Maceal derivatives a 900,550; Maderan; Magnol; Magnolan; Majantol; Maple Lactone / MCPAnhydre; Mayol 957.230; Melon AB 5304; Melon oliffac; Mentol crystals; Methoxy melonal; Methyl anthranilate; Methyl cinnamate; Methyl heptenone; Methyl heptin carbonate substitution; Methyl hexyl ketone; Methyl naphthyl ketone beta; Methyl quinoline para; methyl
Salicylate; Mousse D 'Arbre Abs.5000; Mousse D 'Arbre Abs.Decoloree Mousse Resin B Solide 5000 Decoloree; Musk 144; Myrrhe Resin Washed; Nectarine 10877G; Nonadienal Trans 2 Cis 6; Norsandyl 81.157; Olibanum Resin Oliffac; Orris ABQ 5623; Patchone; Phenoxaflor; Pheπoxanol; Phenylacetaldehyde Dimethylacetat; Phenylacetic acid; Phenylethyl alcohol; Phenylethylsalicylates; Mousse D ' Arbre Paragraph 5000; Mousse D 'Arbre Abs. Decoloree Mousse Resin B Solid 5000 Decoloree; Musk 144; Myrrh resin washed; Nectarine 10877G; Nonadienal trans 2 cis 6; Norsandyl 81,157; Olibanum Resin Oliffac; Orris ABQ 5623; Patchone; Phenoxaflor; Pheπoxanol; Phenylacetaldehydes dimethyl acetate; Phenylacetic acid; Phenylethyl alcohol; phenylethyl
Cinnamate; Phenylethyl Salicylate; Pseudo Linalylacetate; Reseda Body; Rosaphen; Sandela; Scentenal 981.810; Shangralide; Sigaride; Skatol; Stemone; Tangerinol; Terpineol; Terpineol Crystals; Tetrahydro Convalol FM 1028; Terahydro Myrcenol; Thymol; Timberol; Tolyl Acetaldehyde Para 50DPG; Tonalid; Tonkarome; Top Rose ABQ 5644; Trifernal 989.007;cinnamates; Phenylethyl salicylate; Pseudo linalyl acetates; Reseda body; Rosaphen; Sandela; Scentenal 981.810; Shangralide; Sigaride; skatol; Stemone; Tangerinol; terpineol; Terpineol crystals; Tetrahydro Convalol FM 1028; Terahydro myrcenol; thymol; Timberol; Tolyl Acetaldehyde Para 50DPG; tonalide; Tonkarome; Top Rose ABQ 5644; Trifernal 989.007;
Undecavertol; Vanillin; Vanitrope; Veltol Plus; Verdol; Vertenex HC; Vertral; Vetiver Oil Terpenes; Yara Yara; Vert de Tomate; Ambreox DL 909120; Apple Oliffac s PCMF; Basil Oil Grand Vert; Benzyl Acetate; Boisantal Forte 651 (IFF); Buccovert Forte; Cetalox 922.560; Cistar Base 41444; Corps 1490; Coumariπ Subst; Cyclal C; Cyclovertal; Decenal 9; Decenal Cis 4; Decenal Trans 4; Diacetyl; Dibutyl Sulfide; Dimethyl Sulfide; Dodecalactone Delta; Dragojasimina; Fixobois 66.606; Geraniol Pure; Geranyl Acetate Pure; Habanolide; Indolarome; Iso-Bomyl Cyclohexanol; Iso Butyl Quinoline; Isopulegol; Jasmacyclat; Jasmolactone 965.414; Jasmon Cis; Ketofix Base; Mandarinal; Mevantraal; Muscolide/Cyclopentacanolid; Octalactone Gamma; Orinox 190.000; Osyrol; Oxane; Pine Oil 90 Super; Rosessence 17770 B; Rosyrance; Sandelice; Tangeril; Valspice; Veratraldehyde; Ylangfix.undecavertol; vanillin; Vanitrope; Veltol Plus; Verdol; Vertenex HC; Vertral; Vetiver Oil Terpenes; Yara Yara; Vert de tomato; Ambreox DL 909120; Apple Oliffac s PCMF; Basil Oil Grand Vert; Benzyl acetate; Boisantal Forte 651 (IFF); Buccovert Forte; Cetalox 922,560; Cistar Base 41444; Corps 1490; Coumariπ Subst; Cyclal C; Cyclovertal; Decenal 9; Decenal Cis 4; Decenal Trans 4; diacetyl; Dibutyl sulfides; Dimethyl sulfide; Dodecalactone delta; Dragojasimina; Fixobois 66,606; Geraniol Pure; Geranyl Acetate Pure; Habanolide; Indolarome; Isobomyl cyclohexanol; Iso butyl quinoline; isopulegol; Jasmacyclat; Jasmolactone 965.414; Jasmon Cis; Ketofix Base; Mandarinal; Mevantraal; Muscolide / Cyclopentacanolid; Octalactone gamma; Orinox 190,000; Osyrol; oxane; Pine Oil 90 Super; Rosessence 17770 B; Rosyrance; Sandelice; Tangeril; Valspice; Veratraldehyde; Ylangfix.
In einer anderen Ausführungsform der vorliegenden Erfindung können die im folgenden genannten Verbindungen im Gemisch mit PVACL unter Erhalt der Wasserlöslichkeit des Gemisches eingesetzt werden, ohne dass sich negative Einflüsse auf die Stabilität des Gemenges auswirken: Ambra 21750 Base; Ananas Base; Bergamot Synth Base; Cassis R; Citrone 110060FCF; Citroπenöl künstl. Substitut 91161; Dianthos Base; Douschy Base; Fir Balsam Base; Mandarine Ollifac Substitut; Rosana Ersatz; Acetate PA/ Allyl phenoxyacetat; Agrumex/ Verdox; Agrunutril/Citrinellyl Nitrile; Alcohol C-9; Aldehyde C-10; Aldehyde C-ll EN; Aldehyde C-ll ISO; Aldehyde Myrac; Allyl Cyclohexane Propionate; Amandolene; Amboryl Acetate; Ambrettolide; Amyl Benzoate; Amyl Cinnamic Aldehyde; Anethole; Animalis 1745-2; Aromel Givco 111; Baccartol Givco 141/2; Basil Oil; Beuvertate 03372; Benzophenone; Benzyl Butyrate; Benzyl Propionate; Benzyl- Iso Butyrate; Bigarage Oxiide; Bergamot Syπthess Italian; Boisal 10522 B; Boiambrene Forte; Bromelia; Buchu Leaf Oil; Calmus Oil; Camek DH; Cananga OIL; Cardamon Base; Cardamon Oil; Carrot Seed Oil; Caryophylene B; Cashmeran; Cedarleaf Oil; Cedrenyl Acetate; Celery Ketone; Cetonal; Cetone Alpha; Cetone V; Chamomille Wild Oil; Cinnamalva; Cinnamon Oil Arome 339719; Cinnamyl Acetate; Cithrathal; Citron 171; Citronella Oil Java; Citronella Oil Sri Lanka; Citronellyl Acetate; Citronellyl propionate; Citronellyl Isi Butyrate; Citronitrile; Civette Synth.; Clary Sage Identoil; Clonal; Clove Bud Oil Standard; Clove Leaf Oil; Coniferan; Copaiba Balsam; Corps Armoise 4320; Cressanther; Cresyl Acetate Para; Cresyl Methyl Ether Para; Cresyl Iso Butyrate Para; Cumin Oil; Cuminaldehyde; Cuminnitrile; Cyclabut/ Tricyclo Decenyl Butyl; Cyclapropyl TricycloDeceπylPropyl; Cyclohexyl Ethyl Acetate; Cyclohexyl Salicylate; Cymene Para; Cypress Oil; Damarose Alpha 937.449; Damascol 4; Decahydro-Beta-Naphtylacetat; Dihydro Myrcenol; Dihydro Myrcenyl Acetate; Dihydro Iso Jasmonate; Dimethyl Benzyl Carbinyl Acetat; Bimethyl Benzyl Carbinyl Butyrat; Dimethyl Octanyl Acetate; Dimethyl Octenone; Dimyrcetol; Diola; Diphenyl Methane; Dodecen 2 AL Trans; Dupical U 05481; Estragole; Ethyl Butyrate; Ethyl Caproate; Ethyl Caprylate; Ethyl Propionate; Ethyl Safranate/ Ethylrosat; Ethyl Salicylat; Eucalyptol; Eucalyptus Oil 80/85%; Eucalyptus Oil Citidora; Eugenol De Bay; Fantesal; Fir Needle Green; Fir Needle Oil Chinese; Fir Needle Oil Sibirian; Fleur de Jasmin; Fleuroxene; Florane; Floropal; Folarome G 90 9982; Fond de Fleurs; Fraistone/ Dimethyldioxolan; Fruitate; Galaxolide 50DEP; Galbanum Artess. Resin; Galbanum Resin; Gardamide; Geraldehyde; Geraniol 5020; Geraniol Tails; Geranium Bourbon Oliffac; Geranium Oil African; Geranyl Formate; Geranyl Propionate; Geranyl Tiglate; Geranyl Iso Butyrate; Ginger Oil; Givescone; Grapefruit Oil; Guaicwood Acetate; Gurjum Balsam; Gyrane 05315; Herboxane 04519; Hexyl Acetate; Hexyl Benzoate; Hexyl Cinnamic Aldehyde; Hexyl Iso Butyrate; Hyacinth Body; Hydratropaldehyde; Ionone Alpha 74%; Iralia 949.828; Iso Amyl Phenyl Acetate; Iso Amyl Iso Valeriate; Isi Bornyl Acetate; Iso Eugenol; Iso Nonyl Aldehyde; Iso Nonyl Aldehyde Dimethylacetat; Iso Propyl Quinoline 6; Isocyclemone; Isojasmone Pure 05663; Jasmal; Jasmoset; Jessemal; Labdanum Blond; Labdaπum Blond Parfüm Resin; Lavandin Oil Grosso; Lemon Gras Oil; Lemonile; Lemon Oil Messina; Lemsyn; Liffarome; Lilial; Lime Oil 410; Urne Oil Distilled; Linalyl Acetate; Litsea Cubeba Oil; Melozone; Methanyl Acetate; Methyl Benzoate; Methyl Jonone; Methyl Lavender Ketone; Methyl Naphtyl Ketone Alpha; Methyl Pampelmousse; Methyl Phenyl Ethylether; Mnethyl Phenyl Acetate; Methyl Iso Eugenol; Methyl N Methylantranilate; Milk Lactone; Mousse de Cheπe Mix Colourles; Mousse Resin B Sloide; Myraldyl Acetate; Myrcenyl Acetate; Myrrhe Resin Washed; Necraryl; Nerol; Neroli Artessence; Nonyl Acetate; Nut eg Oil; Octyl Acetate; Oncidal; Orange Juice Oil WONF; Orange Oil Brasil; Orange OilIn another embodiment of the present invention, the compounds mentioned below can be used in a mixture with PVACL while maintaining the water-solubility of the mixture without having any negative effects on the stability of the mixture: Ambra 21750 base; Pineapple base; Bergamot Synth Base; Cassis R; Citrone 110060FCF; Citroen oil artificial Substitute 91161; Dianthos Base; Douschy base; Fir Balsam Base; Mandarin Ollifac Substitute; Rosana replacement; Acetate PA / Allyl phenoxyacetate; Agrumex / Verdox; Agrunutril / Citrinellyl Nitrile; Alcohol C-9; Aldehydes C-10; Aldehydes C-II EN; Aldehydes C-II ISO; Aldehydes Myrac; Allyl cyclohexane propionate; Amandolene; Amboryl acetates; Ambrettolide; Amyl benzoate; Amyl cinnamic aldehydes; anethole; Animalis 1745-2; Aromel Givco 111; Baccartol Givco 141/2; Basil oil; Beuvertate 03372; benzophenones; Benzyl butyrate; Benzyl propionate; Benzyl iso butyrates; Bigarage oxides; Bergamot Syπthess Italian; Boisal 10522 B; Boiambrene Forte; Bromeliad; Buchu Leaf Oil; Calmus Oil; Camek DH; Cananga OIL; Cardamon Base; Cardamon Oil; Carrot Seed Oil; Caryophylene B; Cash Meran; Cedarleaf Oil; Cedrenyl Acetate; Celery Ketones; Cetonal; Cetone alpha; Cetone V; Chamomille wild oil; Cinnamalva; Cinnamon Oil Arome 339719; Cinnamyl acetate; Cithrathal; Citron 171; Citronella Oil Java; Citronella Oil Sri Lanka; Citronellyl acetates; Citronellyl propionate; Citronellyl Isi Butyrate; Citronitrile; Civette Synth .; Clary Sage Identoil; clonal; Clove Bud Oil Standard; Clove Leaf Oil; Coniferan; Copaiba balm; Corps Armoise 4320; Cressanther; Cresyl Acetate Para; Cresyl methyl ether para; Cresyl Iso Butyrate Para; Cumin oil; Cuminaldehyde; Cuminnitrile; Cyclabut / tricyclo decenyl butyl; Cyclapropyl TricycloDeceπylPropyl; Cyclohexyl ethyl acetate; Cyclohexyl salicylate; Cymene Para; Cypress oil; Damascus Alpha 937.449; Damascol 4; Decahydro-beta-naphthyl acetate; Dihydro myrcenol; Dihydro myrcenyl acetate; Dihydro Iso Jasmonate; Dimethyl benzyl carbinyl acetate; Bimethyl benzyl carbinyl butyrate; Dimethyl octanyl acetate; Dimethyl octenone; dimyrcetol; Diola; Diphenyl methanes; Dodecene 2 AL trans; Dupical U 05481; Estragole; Ethyl butyrate; Ethyl caproate; Ethyl caprylate; Ethyl propionate; Ethyl safranate / ethyl rosate; Ethyl salicylate; eucalyptol; Eucalyptus Oil 80/85%; Eucalyptus Oil Citidora; Eugenol De Bay; Fantesal; Fir Needle Green; Fir Needle Oil Chinese; Fir Needle Oil Sibirian; Fleur de jasmine; Fleuroxene; Florane; Floropal; Folarome G 90 9982; Fond de Fleurs; Fraistone / Dimethyldioxolan; Fruitate; Galaxolide 50DEP; Galbanum Artess. Resin; Galbanum resin; Gardamide; Geraldehyde; Geraniol 5020; Geraniol tails; Geranium Bourbon Oliffac; Geranium Oil African; Geranyl formats; Geranyl propionate; Geranyl Tiglate; Geranyl iso butyrates; Ginger oil; Givescone; Grapefruit oil; Guaicwood Acetate; Gurjum balm; Gyrane 05315; Herboxane 04519; Hexyl acetate; Hexyl benzoate; Hexyl cinnamic aldehydes; Hexyl iso butyrate; Hyacinth body; Hydratropaldehyde; Ionone Alpha 74%; Iralia 949.828; Iso amyl phenyl acetate; Iso amyl iso valeriate; Isi Bornyl Acetate; Iso Eugenol; Iso nonyl aldehydes; Iso nonyl aldehydes dimethyl acetate; Iso propyl quinoline 6; Isocyclemone; Isojasmone Pure 05663; jasmal; Jasmoset; Jessemal; Labdanum Blond; Labdaπum Blond Perfume Resin; Lavandin Oil Grosso; Lemon grass oil; Lemonile; Lemon Oil Messina; Lemsyn; Liffarome; lilial; Lime Oil 410; Urn Oil Distilled; Linalyl acetate; Litsea Cubeba Oil; Melozone; Methanyl acetate; Methyl benzoate; Methyl jonone; Methyl lavender ketones; Methyl naphthyl ketones alpha; Methyl grapefruit; Methyl phenyl ethyl ether; Methyl phenyl acetate; Methyl iso eugenol; Methyl N methylantranilate; Milk lactones; Mousse de Cheπe Mix Colors; Mousse Resin B Sloide; Myraldyl Acetate; Myrcenyl acetate; Myrrh resin washed; Necraryl; nerol; Neroli artessence; Nonyl acetates; Nut eg oil; Octyl acetate; Oncidal; Orange Juice Oil WONF; Orange Oil Brazil; Orange Oil
Florida; Orange Oil Terpenes; Orivone; Oryclon Extra; Oxania Base 38.230;Florida; Orange Oil Terpenes; Orivone; Oryclon Extra; Oxania Base 38.230;
Palmarosa Oil; Patchuli Oil; Patchuli Oil MD; Penny Royal Oil; Petigrain OilPalmarosa Oil; Patchuli oil; Patchuli Oil MD; Penny Royal Oil; Petigrain Oil
Paraguay; Phenyl Ethyl acetate; Phenyl Ethyl Phenylacetate; Phenylethyl-Iso Butyrate; Phenyl Ethyl Iso Valerate; Picona; Rosyril K 555.445; Sage OilParaguay; Phenyl ethyl acetate; Phenyl ethyl phenylacetate; Phenylethyl iso butyrates; Phenyl ethyl iso valerate; Picona; Rosyril K 555.445; Sage Oil
Dalmatian; Sandalore; Spearmint Oil American; Star Anise Oil; StyreneDalmatian; Sandalore; Spearmint Oil American; Star anise oil; Styrene
Stabilized; Syvertal; Terpinyl Acetate; Tetrahydro Cytral; Terahydr Linalool;stabilized; Syvertal; Terpinyl acetates; Tetrahydro cytral; Terahydr linalool;
Tetrahydro Linalyi Acetate; Thyme Oil White Nature Identica; Tiliantol; Tripilal/Tetrahydro linalyi acetate; Thyme Oil White Nature Identica; Tiliantol; Tripilal /
Hivertal; Verdoracine; Verdural F; Verdylacetat/Cyciacetat; Vertacetal; Vetival; Vetiver Oil Haiti; Vigorose 06255; Ylang Oliffac 597; Ylang Ylang Oil II;Hivertal; Verdoracine; Verdural F; Verdylacetat / Cyciacetat; vertacetal; Vetival; Vetiver Oil Haiti; Vigorose 06255; Ylang Oliffac 597; Ylang Ylang Oil II;
Ylang Ylang Oil III; Wild Srawberry; Amber Core; Ambrettolide; Armoise Oil;Ylang Ylang Oil III; Wild srawberry; Amber core; Ambrettolide; Armoise Oil;
Benzyl Acetone; Bergamot Eco Essence; Cardamome 196 D; Cedarwoodoil;Benzyl acetone; Bergamot Eco Essence; Cardamome 196 D; Cedarwoodoil;
Citralva; Clary Sage Oil; Dadecalactone Gamma; Ethyl-2-Methyl Butyrate;Citralva; Clary Sage Oil; Dadecalactone Gamma; Ethyl 2-methyl butyrate;
Freskomenthe; Fruit sec 11418-1; Grisambrol; Hexenxyl salicylate Cis-3; Isolongifolanone; Isomenthone DL; Jasmelia; Jasmophore; Jassolia 2;Freskomenthe; Fruit sec 11418-1; Grisambrol; Hexenxyl salicylate cis-3; Isolongifolanone; Isomenthone DL; Jasmelia; Jasmophore; Jassolia 2;
Karanal; labdanol; Kohinool; Mefloral; Mefranal; Phenyl Propyl Alcohol;Karanal; labdanol; Kohinool; Mefloral; Mefranal; Phenyl propyl alcohol;
Phenylacetaldehyde; Terpinolene; Vanilys.phenylacetaldehydes; terpinolenes; Vanilys.
Die Duftstoffe werden in dem Fachmann an sich bekannten Mengenbereichen eingesetzt. Insbersondere können zur Einstellung der Löslichkeit die oben genannten Duftstoffe in Mengen von mindestens 2 ppm eingesetzt werden.The fragrances are used in the quantity ranges known per se to the person skilled in the art. In particular, the above-mentioned fragrances can be used in amounts of at least 2 ppm to adjust the solubility.
Die genannten Effekte treten erfahrungsgemäß bei jeder Zugabemenge z. B. schon ab 2 ppm auf. Lediglich die Zeit, bis sie messbar sind, bzw bis sie feststellbar sind, ist konzentrationsabhängig. Je höher die Menge des entspechenden Stoffes ist, umso schneller treten die Effekte in Erscheinung. Zur Einstellung der Sprödigkeit können beispielsweise Mengen von 1 ppm bis 2 ppm des jeweiligen Duftstoffes eingesetzt werden.Experience has shown that the effects mentioned occur with every addition of z. B. from 2 ppm. Only the time until they are measurable or until they can be determined is concentration-dependent. The higher the amount of the corresponding substance, the faster the effects appear. To adjust the brittleness, for example, amounts of 1 ppm to 2 ppm of the respective fragrance can be used.
Die Erfindung wird anhand der folgenden Beispiele weiter erläutert.The invention is further illustrated by the following examples.
Tabelle 1 zeigt eine Zusammensetzung, die auf PVACL weichmachend wirkt.
Figure imgf000009_0001
Table 1 shows a composition which has a plasticizing effect on PVACL.
Figure imgf000009_0001
Figure imgf000010_0001
Figure imgf000010_0001
Tabelle 2: Formulierung mit verhärtender/versprödender Wirkung auf PVACLTable 2: Formulation with hardening / embrittling effect on PVACL
Figure imgf000010_0002
Figure imgf000011_0001
Figure imgf000012_0001
Figure imgf000010_0002
Figure imgf000011_0001
Figure imgf000012_0001
Die Tabelle 3 zeigt eine Formulierung, die auf PVACL Kapseln bruchfester wirkt:Table 3 shows a formulation that acts more break-resistant on PVACL capsules:
Tab. 3Tab. 3
Figure imgf000012_0002
Figure imgf000012_0002
Figure imgf000013_0001
Figure imgf000013_0001
Zur Messung der einzelnen Eigenschaftsänderungen durch Einwirkung der Duftstoffgemische wurde wie folgt vorgegangen: Kapseln aus PVACL wurden in den jeweiligen Gemischen der Duftstoffe gemäß Tab. 1 bis 3 vollständig eingelegt. Nach drei bzw. sechs Wochen wurden die Kapseln auf ihre mechanischen Eigenschaften überprüft. Die mit dem Parfümöl behandelten Kapseln wurden danach den verschiedenen Tests unterzogen. Beim Lösungstest wurde wie folgt vorgegangen: in einem 1-Liter-Becherglas (hohe Form) wird ein Sieb mit einer Maschenweite von 5 mm etwa 5 cm über dem Boden des Becherglases befestigt. Auf dem Sieb werden Kapseln angeordnet und in das Becherglas 600 ml kaltes Wasser gegeben. Die Mischung wird mit einem Magnetrührer und Rührfisch bei ca. 200 U/min. gerührt. Wenn die Kapseln innerhalb von 10 min. rückstandsfrei aufgelöst waren, wurde eine Löslichkeit der Kapseln bejaht.The procedure for measuring the individual property changes due to the action of the fragrance mixtures was as follows: Capsules made of PVACL were completely inserted in the respective mixtures of the fragrances in accordance with Tables 1 to 3. After three or six weeks, the capsules were checked for their mechanical properties. The capsules treated with the perfume oil were then subjected to the various tests. The solution test was carried out as follows: a sieve with a mesh size of 5 mm is attached about 5 cm above the bottom of the beaker in a 1 liter beaker (tall shape). Capsules are placed on the sieve and 600 ml of cold water are added to the beaker. The mixture is mixed with a magnetic stirrer and stirring fish at approx. 200 rpm. touched. If the capsules within 10 min. were dissolved without residue, the solubility of the capsules was affirmed.
Die PVACL-Sprödigkeit wurde vor und nach Behandlung mit den Parfumölen gemäß Tab. 2 gemessen. Die in die Parfumöle eingelegten Kapseln wurden den Ölen entnommen und im Vergleich zu unbehandelten Kapseln bis zum Zerbrechen gebogen. Die auftretenden Unterschiede wurden bewertet.
Figure imgf000014_0001
Die Beispiele der Tab. 4 betreffen einzelne Duftstoffe und ihren Einfluss auf PVACL nach drei- bzw. sechswöchiger Einwirkungszeit. Auch hier wurden PVACL Kapseln in die Duftstoffe eingelegt und die Eigenschaften wie oben beschrieben, beurteilt. The PVACL brittleness was measured before and after treatment with the perfume oils according to Table 2. The capsules placed in the perfume oils were removed from the oils and bent in comparison to untreated capsules until they broke. The differences that occurred were assessed.
Figure imgf000014_0001
The examples in Tab. 4 relate to individual fragrances and their influence on PVACL after three or six weeks of exposure. Here, too, PVACL capsules were inserted into the fragrances and the properties were assessed as described above.

Claims

Patentansprüche claims
1. Verwendung von Duftstoffen zur Verbesserung der Lagerstabilität und/oder besseren Löslichkeit von Polyvinylalkohol und/oder Polyvinylalkohol mit gebundener Zellulose.1. Use of fragrances to improve the storage stability and / or better solubility of polyvinyl alcohol and / or polyvinyl alcohol with bound cellulose.
2. Verwendung nach Anspruch 1, dadurch gekennzeichnet, dass die Duftstoffe zur Verbesserung der Lagerstabilität ausgewählt sind aus der Gruppe bestehend aus: Prunella Substitut; Aceteugenol; Apple Oliffac S; Aldehyde C-ll;2. Use according to claim 1, characterized in that the fragrances to improve the storage stability are selected from the group consisting of: Prunella substitute; Aceteugenol; Apple Oliffac S; Aldehydes C-II;
Aldehyde C-ll MOA; Aldehyde C-12 L; Aldehyde C-12 MNA; Allyl Amyl Glycolate; Allyl Caproate; Bacdanol/Sandrol; Butyl Cyclohexyl acetat P-T; Cedramber; Celestolide; Chamomile Oil Blue; Citronellal; Citronellyl Oxyacetaldehyde; Costus Oliffac; Cuminyl acetate; Cyclamen Aldehyde; Cycloctal; Cyclogalbanate; Damascone Alpha 937.470; Damascone Delta;Aldehydes C-II MOA; Aldehydes C-12 L; Aldehydes C-12 MNA; Allyl amyl glycolate; Allyl caproate; Bacdanol / Sandrol; Butyl cyclohexyl acetate P-T; Cedramber; Celestolide; Chamomile oil blue; citronellal; Citronellyl oxyacetaldehydes; Costus Oliffac; Cuminyl acetate; Cyclamen aldehydes; Cycloctal; Cyclogalbanate; Damascone Alpha 937.470; Damascone Delta;
Dihydro Coumarex; Dihydro Eugenol 938520; Dihydro Jasmone; Dihydro Linalool; Dihydro Terpineol; Dimethyl Cyclormol; Diphenyl Oxide; Ethyl Acetoacetate; Ethyl Amyl Ketone; Ethyl Benzoate; Ethyl Cinnamate; Ethyl Ortho Methoxy Benzoate; Eugenol; Exolide 941.910; Farenal/Adoxal; Fennel Oil sweet; Fleuramone/Projasmon P; Floralozone/Florazon; Florex 943.020;Dihydro Coumarex; Dihydro eugenol 938520; Dihydro jasmones; Dihydro linalool; Dihydro terpineol; Dimethyl cyclormol; Diphenyl oxides; Ethyl acetoacetate; Ethyl amyl ketones; Ethyl benzoate; Ethyl cinnamate; Ethyl ortho methoxy benzoate; eugenol; Exolide 941,910; Farenal / adoxal; Fennel oil sweet; Fleuramone / Projasmon P; Floralozone / Florazon; Florex 943.020;
Florosia/ Apo Patchone; Fructone/ Herminal; Galbex 183; Geranium Mix- Eco Essence; Geranoxy Acetaldehyde; Geranyl Acetate; Hedione 964.898; Herbac; Hexyl Salicylate; Hydratropaldehyde Dimethylacetat; Ionone; Ionone Beta/ Irisone Beta 71%; Irival; Iso E Super; Iso-Amyl Caproate; Iso-Amyl Cinnamate; Iso-Amyl Salicylate; Iso- Butyl Benzoate; Iso-ButylFlorosia / Apo Patchone; Fructone / herminal; Galbex 183; Geranium Mix-Eco Essence; Geranoxy acetaldehydes; Geranyl acetates; Hedione 964,898; herbac; Hexyl salicylate; Hydratropaldehydes dimethyl acetate; Ionone; Ionone Beta / Irisone Beta 71%; Irival; Iso E Super; Iso-amyl caproate; Iso-amyl cinnamate; Iso-amyl salicylates; Isobutyl benzoate; Iso-butyl
Caproate; Iso-Butyl Salicylate; Isoraldeine 70; Jasmin A 100.915; Kovaone; Lavender Oil 40/42%; Leaf Acetal; Lingantraal 06330; Linalool Oxide; Lyrame Super C; Mandarine Aldehyde 10 965765; Manzanate 10629; Melonal; Methyl Acetophenone Para; Methyl Camomille; Methyl Eugenol; Methyl Octalactone; Methyl Octin Carbonate; Miel Oliffac; Myroxyde caproate; Isobutyl salicylate; Isoraldeine 70; Jasmine A 100,915; Kovaone; Lavender Oil 40/42%; Leaf acetal; Lingantraal 06330; Linalool oxides; Lyrame Super C; Mandarin aldehydes 10 965765; Manzanate 10629; melonal; Methyl acetophenone para; Methyl camomille; Methyl eugenol; Methyl octalactone; Methyl octyne carbonate; Miel Oliffac; Myroxyde
962.608; Nectarol Sa 966418; Nerone; Neryl Acetate; Olibanol; Osmantinia Givco 140; Oxaspirane; Petiole; Petigrainoil synth.; Phenirat/Phenoxyethyl Isobutyl; Precyclemone B; Rhodinol Synth. E 9422197; Rhubafuran; Rosalva; Rose Glycol; Rose Oxide Inactive; Rosewood Oil; Sandalmysore Core; Spirambrene; Strawberry Oliffac; Styrallyl Acetate; Tamarine Base962,608; Nectarol Sa 966418; Nerone; Neryl acetates; Olibanol; Osmantinia Givco 140; Oxaspirane; petiole; Petigrainoil synth .; Phenirate / phenoxyethyl isobutyl; Precyclemone B; Rhodinol synth. E 9422197; Rhubafuran; Rosalva; Rose glycol; Rose Oxide Inactive; Rosewood Oil; Sandal core; Spirambrene; Strawberry Oliffac; Styrallyl acetate; Tamarine base
41.310 G; Terpinyl Propionate; Tetrahydro Muguol; Thuja Oil; Tridecene 2 Nitrile; Trimofix O; Tuberose Artessence; Ultralide I 10800; Veloutone 990.257; Vernaldehyde; Vetiveryl Acetate Synth; Vetyvenal/Caryophyllene Acetat; Wormwood Oil; Methyl Octin Carbonate; Ambre 205 K PCM free; Benzyl- Iso- Eugenol; Cantryl; Cassis Body 05654; Cedarwoodoil Texas;41,310 G; Terpinyl propionate; Tetrahydro muguol; Thuja oil; Tridecene 2 nitriles; Trimofix O; Tuberose artessence; Ultralide I 10800; Veloutone 990.257; Vernaldehyde; Vetiveryl Acetate Synth; Vetyvenal / Caryophyllene Acetate; Wormwood oil; Methyl octyne carbonate; Ambre 205 K PCM free; Benzyl iso-eugenol; Cantryl; Cassis Body 05654; Cedarwoodoil Texas;
Cedryl Acetates; Ebanol; Florhydral; Fruit See 17.907; Frutinat; Galbanum Oil; Galbanol; Herbavert; Jasmin 17.444 SA; Kephalis; Lemon Oil Terpenes; Urne Oxide; Limetol; Limettal; Loganberry; Longifolene; Mandarine Oil Light; Melone; Melonyl; Melusat; Mentha Citrata Oil; Menthol Oil; Menthone Pure; Methyl Ionone Alpha Iso/Isoaldehyd; Muscenone; Musk T 93 EthyleneCedryl Acetates; ebanol; florhydral; Fruit See 17,907; Frutinat; Galbanum Oil; Galbanol; herbavert; Jasmine 17,444 SA; Kephalis; Lemon Oil Terpenes; Urn oxides; Limetol; Limettal; Loganberry; Longifolene; Mandarin oil light; Melon; Melonyl; Melusat; Mentha Citrata Oil; Menthol oil; Menthone Pure; Methyl ionone alpha iso / isoaldehyde; Muscenone; Musk T 93 ethylene
Brasilate; Myristal; Nerolidol; Nonadyl; Oceano; Okoumal; Olibanum Oil; Orange Isolate; Orange Terpenes; Pelargene; Peppermint Oil Arvensis; Peranat; Pinene Alpha; Pinene Beta; Poivre Coir; Polycenide Base; Polysantol; Prenyl Acetate; Resorcinol Dimethylether; Rhodascone Base; Rholiate; Rose Oxide L-; Spike Lavender Oil; Terpinolene 90; Tree MoosBrasilate; Myristal; nerolidol; Nonadyl; Oceano; Okoumal; Olibanum oil; Orange isolates; Orange terpenes; Pelargene; Peppermint Oil Arvensis; Peranat; Pinene Alpha; Pinene beta; Poivre coir; Polycenide base; Polysantol; Prenyl acetate; Resorcinol dimethyl ether; Rhodascone Base; Rholiate; Rose Oxide L-; Spike lavender oil; Terpinolene 90; Tree moss
Abs.; Verotyl; Vertofix Coeur; Watermelon Base.Section.; Verotyl; Vertofix Coeur; Watermelon Base.
3. Verwendung nach Anspruch 1, dadurch gekennzeichnet, dass die Duftstoffe zur Einstellung eines Gemenges mit Duftstoffen und PVACL, das spröder eingestellt wird, unter Erhalt seiner Wasserlöslichkeit, ausgewählt sind aus der Gruppe bestehend aus:3. Use according to claim 1, characterized in that the fragrances for adjusting a mixture with fragrances and PVACL, which is brittle, while maintaining its water solubility, are selected from the group consisting of:
Bromstyrol Replacement; Cassodrom F; Cassiflor Af 3137 drom subst.; Chrysanthemal Base; Dromacetol; Base Frutonal 102620PCMF Geranium Bourbon Subst.Base; Muguet Base; Nitro Musk Replacer; Passion Fruit Subst; Polycyclischer Musk Replacer; Rhubanil subst; Base Rose; Tonalid Replacer; Base Ylang Eco Essence; Acet-Iso-Eugenol; Acetanisole; Alcohol C-10; Aldehyde C-18 So called; Aldehyde C-20 (IFF); Aldehyde C-8; Aldehyde C-9; Algenone SP (Synarome); Ambroxane; Amyl Vinyl Carbinol/Morillol; Andrane/Cedrene; Epoxide; Anisaldehyde-Dimethylacetal;Bromostyrene replacement; Cassodrome F; Cassiflor Af 3137 drom subst .; Chrysanthemal base; Dromacetol; Base Frutonal 102620PCMF Geranium Bourbon Subst.Base; Muguet Base; Nitro Musk Replacer; Passion Fruit noun; Polycyclic Musk Replacer; Rhubanil subst; Base rose; Tonalid Replacer; Base Ylang Eco Essence; Acet-iso-eugenol; Acetanisole; Alcohol C-10; Aldehydes C-18 So called; Aldehydes C-20 (IFF); Aldehydes C-8; Aldehydes C-9; Algenone SP (Synarome); Ambroxane; Amyl vinyl carbinol / morillol; Andrane / Cedrene; epoxides; Anisaldehyde dimethylacetal;
Anisyl Acetate; Anisyl Alcohol; Banana D 50282 755964(H&R); Benzoin Sumatra Resin; Benzyl Salicylate; Bergamal; Boisantal Forte 651 (IFF); Brouts D 'Oranger Abs.; Buccoxime; Butyl Acetate N; Butyl Cyclohexanone p-t; Calone 1951; Camphor Crystals; Canthoxal; Cantofloral/Parafloral; Carvone L; Cassis Base 345F; Cedrenyl Formate; Cinnamic Alcohol;Anisyl acetate; Anisyl alcohol; Banana D 50282 755964 (H&R); Benzoin sumatra resin; Benzyl salicylate; Bergamal; Boisantal Forte 651 (IFF); Brouts D 'Oranger para .; Buccoxime; Butyl acetate N; Butyl cyclohexanone pt; Calone 1951; Camphor crystals; Canthoxal; Cantofloral / Parafloral; Carvone L; Cassis Base 345F; Cedrenyl formats; Cinnamic alcohol;
Cinnamic Aldehyde Chlorine Free; Cistus Abs.; Citral; Citralex; Citronellol; Citronellyl Formate; Civette 102.035 D;Cinnamic Aldehyde Chlorine Free; Cistus Abs .; citral; Citralex; citronellol; Citronellyl formats; Civette 102,035 D;
Civettone 926851; Corps M E-242/CO; Cortexal SA 935.780; Coumarin; Cresyl Phenyl Acetate Para; Damascone Beta 939.692; Decahydro-Beta- Naphtol Trans; Decalactone Delta; Decalactone Gamma; Diethyl Malonate;Civettone 926851; Corps M E-242 / CO; Cortexal SA 935.780; coumarin; Cresyl Phenyl Acetate Para; Damascone Beta 939.692; Decahydro-beta-naphthol trans; Decalactone Delta; Decalactone gamma; Diethyl malonate;
Diheptyl Acetate/ Nopyl Acetate; Dihydro- Beta-Ionone; Dimethyl Benzyl Carbinol; Dimethyl Heptanol/Dimetol; Dimethyl Octanol/Tetrahydro G; Dimethyl Phenyl Ethyl Carbinol; Dulcinyl; Dynascone 10 939.750; Elemi Resin; Estragon Oil French; Ethyl Heptylate; Ethyl Lactate; Ethyl Linalool; Ethyl Phenylacetate; Ethyl Vanillin; Ethyl 3 Phenyl Glycidate; Evernyl;Diheptyl acetate / nopyl acetate; Dihydro beta ionones; Dimethyl benzyl carbinol; Dimethyl heptanol / dimetol; Dimethyl octanol / tetrahydro G; Dimethyl phenyl ethyl carbinol; Dulcinyl; Dynascone 10 939.750; Elemi Resin; Tarragon oil french; Ethyl heptylate; Ethyl lactate; Ethyl linalool; Ethyl phenylacetate; Ethyl vanillin; Ethyl 3 phenyl glycidate; Evernyl;
Exaltex 941.900; Fenchyl Acetate; Fenchyl Alcohol; Fiorivert FM 1372; Florascone B 942.965; Florol/ Florosa; Fragarol; Frambione; Framboson 10583 F; Galaxolide 50IPM; Galbanodor VIII; Gelsone; Geranium Oil Base B 719769; Geranyl Nitrile; Guaiacwoodoil; Heliocret 14502; Helional; Heliotropin; Heptene Cis-4-1 OL; Hexenal Trans-2; Hexenol Cis 3; HexenylExaltex 941.900; Fenchyl acetates; Fenchyl alcohol; Fiorivert FM 1372; Florascone B 942.965; Florol / Florosa; Fragarol; Frambione; Framboson 10583 F; Galaxolide 50IPM; Galbanodor VIII; Gelsone; Geranium Oil Base B 719769; Geranyl nitriles; Guaiacwoodoil; Heliocret 14502; helional; heliotropin; Heptene Cis-4-1 OL; Hexenal Trans-2; Hexenol cis 3; hexenyl
Acetate Cis 3; Hexenyl Propionate Cis-3; Ho Leaf Oil; Hydroquinone Dimethylether; Hydroxycitronellal; Indoflor Crystals; Indole; Ionone Betaextra 98%;Acetates cis 3; Hexenyl propionate cis-3; Ho Leaf Oil; Hydroquinone dimethyl ether; Hydroxycitronellal; Indoflor crystals; indoles; Ionone Beta Extra 98%;
Iso Amyl Acetate; Iso-Borneol Crystals; Iso- Butyl Phenylacetate; Iso-Nonyl Acetate/Neononylace; Iso-nonyl Formate; Iso-Peπtyrate 951.517;Iso Amyl Acetate; Iso-Borneol Crystals; Isobutyl phenylacetate; Iso-Nonyl Acetate / Neononylace; Iso-nonyl formats; Iso-Ptyrate 951.517;
Isonomilate 258E; Jasmopyrane Forte 04513; Labdanum Eal; LemoralIsonomilate 258E; Jasmopyrane Forte 04513; Labdanum Eal; Lemoral
PCMF; Limbwood Basel09.289 B; Linalool Synth.; Lyral; Maceal Derivate a PCMF; Limbwood Basel 09.289 B; Linalool Synth .; lyral; Maceal derivatives a
900.550; Maderan; Magnol; Magnolan; Majantol; Maple900,550; Maderan; Magnol; Magnolan; Majantol; Maple
Lactone/MCPAnhydre; Mayol 957.230; Melone AB 5304; Melone Oliffac; Mentol Crystals; Methoxy Melonal; Methyl Anthranilate; Methyl Cinnamate; Methyl Heptenone; Methyl Heptin Carbonate Substitution; Methyl Hexyl Keton; Methyl Naphtyl Ketone Beta; Methyl Quinoline Para; MethylLactones / MCPAnhydre; Mayol 957.230; Melon AB 5304; Melon oliffac; Mentol crystals; Methoxy melonal; Methyl anthranilate; Methyl cinnamate; Methyl heptenone; Methyl heptin carbonate substitution; Methyl hexyl ketone; Methyl naphthyl ketone beta; Methyl quinoline para; methyl
Salicylate; Mousse D 'Arbre Abs.5000; Mousse D 'Arbre Abs.Decoloree Mousse Resin B Solide 5000 Decoloree; Musk. 144; . Myrrhe Resin Washed; Nectarine 10877G; Nonadieπal Trans 2 Cis 6; Norsandyl 81.157; Olibanum Resin Oliffac; Orris ABQ 5623; Patchone; Phenoxaflor; Phenoxanol; Phenylacetaldehyde Dimethylacetat; Phenylacetic acid; Phenylethyl alcohol;salicylates; Mousse D ' Arbre Paragraph 5000; Mousse D 'Arbre Abs. Decoloree Mousse Resin B Solid 5000 Decoloree; Musk. 144; , Myrrh resin washed; Nectarine 10877G; Nonadieπal Trans 2 Cis 6; Norsandyl 81,157; Olibanum Resin Oliffac; Orris ABQ 5623; Patchone; Phenoxaflor; phenoxanol; Phenylacetaldehydes dimethyl acetate; Phenylacetic acid; Phenylethyl alcohol;
Phenylethyl Cinnamate; Phenylethyl Salicylate; Pseudo Linalylacetate; Reseda Body; Rosaphen; Sandela; Scentenal 981.810; Shangralide;Phenylethyl cinnamate; Phenylethyl salicylate; Pseudo linalyl acetates; Reseda body; Rosaphen; Sandela; Scentenal 981.810; Shangralide;
Sigaride; Skatol; Stemone; Tangerinol; Terpineol; Terpineol Crystals;Sigaride; skatol; Stemone; Tangerinol; terpineol; Terpineol crystals;
Tetrahydro Convalol FM 1028; Terahydro Myrceπol; Thymol; Timberol; Tolyl Acetaldehyde Para 50DPG; Tonalid; Tonkarome; Top Rose ABQ 5644;Tetrahydro Convalol FM 1028; Terahydro Myrceπol; thymol; Timberol; Tolyl Acetaldehyde Para 50DPG; tonalide; Tonkarome; Top Rose ABQ 5644;
Trifernal 989.007; Undecavertol; Vanillin; Vanitrope; Veltol Plus; Verdol;Trifernal 989.007; undecavertol; vanillin; Vanitrope; Veltol Plus; Verdol;
Vertenex HC; Vertral; Vetiver Oil Terpenes; Yara Yara; Vert de Tomate;Vertenex HC; Vertral; Vetiver Oil Terpenes; Yara Yara; Vert de tomato;
Ambreox DL 909120; Apple Oliffac s PCMF; Basil Oil Grand Vert; BenzylAmbreox DL 909120; Apple Oliffac s PCMF; Basil Oil Grand Vert; benzyl
Acetate; Boisantal Forte 651 (IFF); Buccovert Forte; Cetalox 922.560 Cistar Base 41444; Corps 1490; Coumarin Subst; Cyclal C; CyclovertalAcetate; Boisantal Forte 651 (IFF); Buccovert Forte; Cetalox 922,560 Cistar Base 41444; Corps 1490; Coumarin subst; Cyclal C; Cyclovertal
Decenal 9; Decenal Cis 4; Decenal Trans 4; Diacetyl; Dibutyl SulfideDecenal 9; Decenal Cis 4; Decenal Trans 4; diacetyl; Dibutyl sulfides
Dimethyl Sulfide; Dodecalactone Delta; Dragojasimina; Fixobois 66.606Dimethyl sulfide; Dodecalactone delta; Dragojasimina; Fixobois 66,606
Geraniol Pure; Geranyl Acetate Pure; Habanolide; Indolarome; Iso-BornylGeraniol Pure; Geranyl Acetate Pure; Habanolide; Indolarome; Iso-bornyl
Cyclohexanol; Iso Butyl Quinoline; Isopulegol; Jasmacyclat; Jasmolactone 9.65.414; Jasmon Cis; Ketofix Base; Mandarinal; Mevantraal;cyclohexanol; Iso butyl quinoline; isopulegol; Jasmacyclat; Jasmolactone 9.65.414; Jasmon Cis; Ketofix Base; Mandarinal; Mevantraal;
Muscolide/Cyclopentacanolid; Octalactone Gamma; Orinox 190.000; Osyrol;Muscolide / Cyclopentacanolid; Octalactone gamma; Orinox 190,000; Osyrol;
Oxane; Pine Oil 90 Super; Rosessence 17770 B; Rosyrance; Sandelice;oxane; Pine Oil 90 Super; Rosessence 17770 B; Rosyrance; Sandelice;
Tangeril; Valspice; Veratraldehyde; Ylangfix.Tangeril; Valspice; Veratraldehyde; Ylangfix.
4. Verwendung nach Anspruch 1, dadurch gekennzeichnet, dass die Duftstoffe, die im Gemenge mit PVACL, unter Erhalt der Wasserlöslichkeit des4. Use according to claim 1, characterized in that the fragrances, which are mixed with PVACL, while maintaining the water solubility of the
Gemisches, eingesetzt werden, ohne dass sich negative Einflüsse auf die Stabilität des Gemenges auswirken, ausgewählt sind aus der Gruppe bestehend aus:Mixture can be used without affecting the Impact stability of the batch, selected from the group consisting of:
Ambra 21750 Base; Ananas Base; Bergamot Synth Base; Cassis R; Citrone 110060FCF; Citronenöl künstl. Substitut 91161; Dianthos Base; Douschy Base; Fir Balsam Base; Mandarine Ollifac Substitut; Rosana Ersatz; AcetateAmbra 21750 base; Pineapple base; Bergamot Synth Base; Cassis R; Citrone 110060FCF; Artificial lemon oil Substitute 91161; Dianthos Base; Douschy base; Fir Balsam Base; Mandarin Ollifac Substitute; Rosana replacement; Acetate
PA/ Allyl phenoxyacetat; Agrumex/ Verdox; Agrunutril/Citrinellyl Nitrile; Alcohol C-9; Aldehyde C-10; Aldehyde C-ll EN; Aldehyde C-ll ISO; Aldehyde Myrac; Allyl Cyclohexane Propionate; Amandolene; Amboryl Acetate; Ambrettolide; Amyl Benzoate; Amyl Cinnamic Aldehyde; Anethole; Animalis 1745-2; Aromel Givco 111; Baccartol Givco 141/2; Basil Oil;PA / allyl phenoxyacetate; Agrumex / Verdox; Agrunutril / Citrinellyl Nitrile; Alcohol C-9; Aldehydes C-10; Aldehydes C-II EN; Aldehydes C-II ISO; Aldehydes Myrac; Allyl cyclohexane propionate; Amandolene; Amboryl acetates; Ambrettolide; Amyl benzoate; Amyl cinnamic aldehydes; anethole; Animalis 1745-2; Aromel Givco 111; Baccartol Givco 141/2; Basil oil;
Beuvertate. 03372; Benzophenone; Benzyl Butyrate; Benzyl Propionate; Benzyl- Iso Butyrate; Bigarage Oxiide; Bergamot Synthess Italian; Boisal 10522 B; Boiambrene Forte; Bromelia; Buchu Leaf Oil; Calmus Oil; Camek DH; Cananga OIL; Cardamon Base; Cardamon Oil; Carrot Seed Oil; Caryophylene B; Cashmeran; Cedarieaf Oil; Cedrenyl Acetate; CeleryBeuvertate. 03372; benzophenones; Benzyl butyrate; Benzyl propionate; Benzyl iso butyrates; Bigarage oxides; Bergamot Synthess Italian; Boisal 10522 B; Boiambrene Forte; Bromeliad; Buchu Leaf Oil; Calmus Oil; Camek DH; Cananga OIL; Cardamon Base; Cardamon Oil; Carrot Seed Oil; Caryophylene B; Cash Meran; Cedarieaf Oil; Cedrenyl Acetate; Celery
Ketone;ketones;
Cetonal; Cetone Alpha; Cetone V; Chamomille Wild Oil; Cinnamalva;Cetonal; Cetone alpha; Cetone V; Chamomille wild oil; Cinnamalva;
Cinπamon Oil Arome 339719; Cinnamyl Acetate; Cithrathal; Citron 171;Cinπamon Oil Arome 339719; Cinnamyl acetate; Cithrathal; Citron 171;
Citronella Oil Java; Citronella Oil Sri Lanka; Citronellyl Acetate; Citronellyl propionate; Citronellyl Isi Butyrate; Citronitrile; Civette Synth.; Clary SageCitronella Oil Java; Citronella Oil Sri Lanka; Citronellyl acetates; Citronellyl propionate; Citronellyl Isi Butyrate; Citronitrile; Civette Synth .; Clary Sage
Identoil; Clonal; Clove Bud Oil Standard; Clove Leaf Oil; Coniferan; CopaibaIdentoil; clonal; Clove Bud Oil Standard; Clove Leaf Oil; Coniferan; Copaiba
Balsam; Corps Armoise 4320; Cressanther; Cresyl Acetate Para; CresylBalm; Corps Armoise 4320; Cressanther; Cresyl Acetate Para; cresyl
Methyl Ether Para; Cresyl Iso Butyrate Para; Cumin Oil; Cuminaldehyde;Methyl ether para; Cresyl Iso Butyrate Para; Cumin oil; Cuminaldehyde;
Cuminnitrile; Cyclabut/ Tricyclo . Decenyl Butyl; Cyclapropyl TricycloDeceπylPropyl; Cyclohexyl Ethyl Acetate; Cyclohexyl Salicylate;Cuminnitrile; Cyclabut / tricyclo. Decenyl butyl; Cyclapropyl TricycloDeceπylPropyl; Cyclohexyl ethyl acetate; Cyclohexyl salicylate;
Cymeπe Para; Cypress Oil; Damarose Alpha 937.449; Damascol 4;Cymeπe Para; Cypress oil; Damascus Alpha 937.449; Damascol 4;
Decahydro-Beta-Naphtylacetat; Dihydro Myrcenol; Dihydro MyrcenylDecahydro-beta-naphthyl acetate; Dihydro myrcenol; Dihydro myrcenyl
Acetate; Dihydro Iso Jasmonate; Dimethyl Benzyl Carbinyl Acetat; BimethylAcetate; Dihydro Iso Jasmonate; Dimethyl benzyl carbinyl acetate; Bimethyl
Benzyl Carbinyl Butyrat; Dimethyl Octanyl Acetate; Dimethyl Octenone; Dimyrcetol; Diola; Dipheπyl Methane; Dodecen 2 AL Trans; Dupical UBenzyl carbinyl butyrate; Dimethyl octanyl acetate; Dimethyl octenone; dimyrcetol; Diola; Dipheπyl methane; Dodecene 2 AL trans; Dupical U
05481; Estragole; Ethyl Butyrate; Ethyl Caproate; Ethyl Caprylate; Ethyl05481; Estragole; Ethyl butyrate; Ethyl caproate; Ethyl caprylate; ethyl
Propionate; Ethyl Safranate/ Ethylrosat; Ethyl Salicylat; Eucalyptol; Eucalyptus Oil 80/85%; Eucalyptus Oil Citidora; Eugenol De Bay; Fantesal; Fir Needle Green; Fir Needle Oil Chinese; Fir Needle Oil Sibiriaπ; Fleur de Jasmin; Fleuroxene; Florane; Floropal; Folarome G 90 9982; Fond de Fleurs; Fraistone/ Dimethyldioxolan; Fruitate; Galaxolide 50DEP; Galbanum Artess.propionate; Ethyl safranate / ethyl rosate; Ethyl salicylate; eucalyptol; Eucalyptus Oil 80/85%; Eucalyptus Oil Citidora; Eugenol De Bay; Fantesal; Fir Needle Green; Fir Needle Oil Chinese; Fir Needle Oil Sibiriaπ; Fleur de jasmine; Fleuroxene; Florane; Floropal; Folarome G 90 9982; Fond de Fleurs; Fraistone / Dimethyldioxolan; Fruitate; Galaxolide 50DEP; Galbanum Artess.
Resin; Galbanum Resin; Gardamide; Geraldehyde; Geraniol 5020; Geraniol Tails; Geranium Bourbon Oliffac; Geranium Oil African; Geranyl Formate; Geranyl Propionate; Geranyl Tiglate; Geranyl Iso Butyrate; Ginger Oil; Givescone; Grapefruit Oil; Guaicwood Acetate; Gurjum Balsam; Gyrane 05315; Herboxane 04519; Hexyl Acetate; Hexyl Benzoate; Hexyl CinnamicResin; Galbanum resin; Gardamide; Geraldehyde; Geraniol 5020; Geraniol tails; Geranium Bourbon Oliffac; Geranium Oil African; Geranyl formats; Geranyl propionate; Geranyl Tiglate; Geranyl iso butyrates; Ginger oil; Givescone; Grapefruit oil; Guaicwood Acetate; Gurjum balm; Gyrane 05315; Herboxane 04519; Hexyl acetate; Hexyl benzoate; Hexyl cinnamic
Aldehyde; Hexyl Iso Butyrate; Hyacinth Body; Hydratropaldehyde; Ionone Alpha 74%; Iralia 949.828; Iso Amyl Phenyl Acetate; Iso Amyl Iso Valeriate; Isi Bornyl Acetate; Iso Eugenol; Iso Nonyl Aldehyde; Iso Nonyl Aldehyde Dimethylacetat; Iso Propyl Quinoline 6; Isocyclemone; Isojasmone Pure 05663; Jasmal;aldehydes; Hexyl iso butyrate; Hyacinth body; Hydratropaldehyde; Ionone Alpha 74%; Iralia 949.828; Iso amyl phenyl acetate; Iso amyl iso valeriate; Isi Bornyl Acetate; Iso Eugenol; Iso nonyl aldehydes; Iso nonyl aldehydes dimethyl acetate; Iso propyl quinoline 6; Isocyclemone; Isojasmone Pure 05663; jasmal;
Jasmoset; Jessemal; Labdanum Blond; Labdanum Blond Parfüm Resin; Lavandin Oil Grosso; Lemon Gras Oil; Lemonile; Lemon Oil Messina; Lemsyn; Liffarome; Lilial; Lime Oil 410; Lime Oil Distilled; Linalyl Acetate; Litsea Cubeba Oil; Melozone; Methanyl Acetate; Methyl Benzoate; Methyl Jonone; Methyl Lavender Ketone; Methyl Naphtyl Ketone Alpha; MethylJasmoset; Jessemal; Labdanum Blond; Labdanum Blond Perfume Resin; Lavandin Oil Grosso; Lemon grass oil; Lemonile; Lemon Oil Messina; Lemsyn; Liffarome; lilial; Lime Oil 410; Lime oil distilled; Linalyl acetate; Litsea Cubeba Oil; Melozone; Methanyl acetate; Methyl benzoate; Methyl jonone; Methyl lavender ketones; Methyl naphthyl ketones alpha; methyl
Pampelmousse; Methyl Phenyl Ethylether; Mnethyl Phenyl Acetate; Methyl Iso Eugenol; Methyl N Methylantranilate; Milk Lactone; Mousse de Chene Mix Colourles; Mousse Resin B Sloide; Myraldyi Acetate; Myrcenyl Acetate; Myrrhe Resin Washed; Necraryl; Nerol; Neroli Artessence; Nonyl Acetate; Nutmeg Oil; Octyl Acetate; Oncidal; Orange Juice Oil WONF; Orange OilPampelmousse; Methyl phenyl ethyl ether; Methyl phenyl acetate; Methyl iso eugenol; Methyl N methylantranilate; Milk lactones; Mousse de chene mix colors; Mousse Resin B Sloide; Myraldyi Acetate; Myrcenyl acetate; Myrrh resin washed; Necraryl; nerol; Neroli artessence; Nonyl acetates; Nutmeg Oil; Octyl acetate; Oncidal; Orange Juice Oil WONF; Orange Oil
Brasil; Orange Oil Florida; Orange Oil Terpenes; Orivone; Oryclon Extra; Oxania Base 38.230; Palmarosa Oil; Patchuli Oil; Patchuli Oil MD; Penny Royal Oil; Petigrain Oil Paraguay; Phenyl Ethyl acetate; Phenyl Ethyl Phenylacetate; Phenylethyl-Iso Butyrate; Phenyl Ethyl Iso Valerate; Picona; Rosyril K 555.445; Sage Oil Dalmatiaπ; Sandalore; Spearmint Oil American;Brasil; Orange Oil Florida; Orange Oil Terpenes; Orivone; Oryclon Extra; Oxania Base 38.230; Palmarosa Oil; Patchuli oil; Patchuli Oil MD; Penny Royal Oil; Petigrain Oil Paraguay; Phenyl ethyl acetate; Phenyl ethyl phenylacetate; Phenylethyl iso butyrates; Phenyl ethyl iso valerate; Picona; Rosyril K 555.445; Sage Oil Dalmatiaπ; Sandalore; Spearmint Oil American;
Star Anise Oil; Styrene Stabilized; Syvertal; Terpinyl Acetate; Tetrahydro Cytral; Terahydr Linalool; Tetrahydro Linalyl Acetate; Thyme Oil White Nature Identica; Tiliantol; Tripilal/ Hivertal; Verdoracine; Verdural F; Verdylacetat/Cydacetat; Vertacetal; Vetival; Vetiver Oil Haiti; Vigorose 06255; Ylang Oliffac 597; Ylang Ylang Oil II; Ylang Ylang Oil III; Wild Srawberry; Amber Core; Ambrettolide; Armoise Oil; Benzyl Acetone;Star anise oil; Styrene stabilized; Syvertal; Terpinyl acetates; tetrahydro- Cytral; Terahydr linalool; Tetrahydro linalyl acetate; Thyme Oil White Nature Identica; Tiliantol; Tripilal / Hivertal; Verdoracine; Verdural F; Verdylacetat / Cydacetat; vertacetal; Vetival; Vetiver Oil Haiti; Vigorose 06255; Ylang Oliffac 597; Ylang Ylang Oil II; Ylang Ylang Oil III; Wild srawberry; Amber core; Ambrettolide; Armoise Oil; Benzyl acetone;
Bergamot Eco Essence; Cardamome 196 D; Cedarwoodoil; Citralva; Clary Sage Oil; Dadecalactone Gamma; Ethyl-2-Methyl Butyrate; Freskomenthe; Fruit sec 11418-1; Grisambrol; Hexenxyl salicylate Cis-3; Isolongifolanone; Isomenthone DL; Jasmelia; Jasmophore; Jassolia 2; Karanal; labdanol; Kohinool; Mefloral; Mefranai; Phenyl Propyl Alcohol; Phenylacetaldehyde;Bergamot Eco Essence; Cardamome 196 D; Cedarwoodoil; Citralva; Clary Sage Oil; Dadecalactone Gamma; Ethyl 2-methyl butyrate; Freskomenthe; Fruit sec 11418-1; Grisambrol; Hexenxyl salicylate cis-3; Isolongifolanone; Isomenthone DL; Jasmelia; Jasmophore; Jassolia 2; Karanal; labdanol; Kohinool; Mefloral; Mefranai; Phenyl propyl alcohol; phenylacetaldehydes;
Terpinolene; Vanilys. terpinolenes; Vanilys.
PCT/EP2002/006246 2001-06-07 2002-06-07 Aromatic principles for improving the stability in storage and/or for improving the solubility of polyvinyl alcohols and/or polyvinyl alcohols with bonded cellulose WO2002098966A2 (en)

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DE10292443T DE10292443D2 (en) 2001-06-07 2002-06-07 Fragrances to improve the storage stability and / or better solubility of polyvinyl alcohols and / or polyvinyl alcohols with bound cellulose

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003074037A1 (en) * 2002-03-01 2003-09-12 Cst Medical Limited Treatment of female sexual dysfunction
WO2005044206A1 (en) * 2003-11-04 2005-05-19 The Procter & Gamble Company Fragrances comprising residual accords
WO2006095200A1 (en) * 2005-03-10 2006-09-14 Quest International Services B.V. Perfume compositions
JP2007217603A (en) * 2006-02-17 2007-08-30 Nippon Terupen Kagaku Kk Volatile binder composition
JP2008037890A (en) * 2006-08-01 2008-02-21 Kuraray Co Ltd Poly(vinylacetal) resin
WO2009066904A1 (en) * 2007-11-19 2009-05-28 Amorepacific Corporation Perfume composition for expressing the fragrance of ginseng flower (panax ginseng c.a.meyer)
DE102008018789A1 (en) * 2008-04-11 2009-10-15 Beiersdorf Ag Perfumed cosmetic preparation with citronellol
US7704932B2 (en) 2003-11-04 2010-04-27 The Procter & Gamble Company Personal cleaning compositions
EP2931854A1 (en) * 2012-12-14 2015-10-21 The Procter & Gamble Company Fragrance materials
EP4039245A1 (en) * 2014-06-30 2022-08-10 Symrise AG Flavour and fragrance compositions comprising acetophenone derivatives

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Publication number Priority date Publication date Assignee Title
EP0114301A1 (en) * 1982-12-23 1984-08-01 Henkel Kommanditgesellschaft auf Aktien Perfume or other odoriferons substance releasing packing materials
US5543439A (en) * 1994-06-02 1996-08-06 International Flavors & Fragrances Inc. Extruded fragrance-containing polyvinyl alcohol and use thereof
EP1044675A2 (en) * 1999-04-16 2000-10-18 drom fragrances international KG Fragrance application

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0114301A1 (en) * 1982-12-23 1984-08-01 Henkel Kommanditgesellschaft auf Aktien Perfume or other odoriferons substance releasing packing materials
US5543439A (en) * 1994-06-02 1996-08-06 International Flavors & Fragrances Inc. Extruded fragrance-containing polyvinyl alcohol and use thereof
EP1044675A2 (en) * 1999-04-16 2000-10-18 drom fragrances international KG Fragrance application

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003074037A1 (en) * 2002-03-01 2003-09-12 Cst Medical Limited Treatment of female sexual dysfunction
US7704932B2 (en) 2003-11-04 2010-04-27 The Procter & Gamble Company Personal cleaning compositions
WO2005044206A1 (en) * 2003-11-04 2005-05-19 The Procter & Gamble Company Fragrances comprising residual accords
US7648955B2 (en) 2003-11-04 2010-01-19 The Procter & Gamble Company Fragrances comprising residual accords
WO2006095200A1 (en) * 2005-03-10 2006-09-14 Quest International Services B.V. Perfume compositions
JP2007217603A (en) * 2006-02-17 2007-08-30 Nippon Terupen Kagaku Kk Volatile binder composition
JP2008037890A (en) * 2006-08-01 2008-02-21 Kuraray Co Ltd Poly(vinylacetal) resin
WO2009066904A1 (en) * 2007-11-19 2009-05-28 Amorepacific Corporation Perfume composition for expressing the fragrance of ginseng flower (panax ginseng c.a.meyer)
DE102008018789A1 (en) * 2008-04-11 2009-10-15 Beiersdorf Ag Perfumed cosmetic preparation with citronellol
EP2931854A1 (en) * 2012-12-14 2015-10-21 The Procter & Gamble Company Fragrance materials
US10952951B2 (en) 2012-12-14 2021-03-23 The Procter & Gamble Company Fragrance materials
US11844854B2 (en) 2012-12-14 2023-12-19 The Procter & Gamble Company Fragrance materials
EP4039245A1 (en) * 2014-06-30 2022-08-10 Symrise AG Flavour and fragrance compositions comprising acetophenone derivatives

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