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WO2002046320A2 - Boue pulverulente de couleur et/ou a effet, son procede de production et son utilisation - Google Patents

Boue pulverulente de couleur et/ou a effet, son procede de production et son utilisation Download PDF

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Publication number
WO2002046320A2
WO2002046320A2 PCT/EP2001/014018 EP0114018W WO0246320A2 WO 2002046320 A2 WO2002046320 A2 WO 2002046320A2 EP 0114018 W EP0114018 W EP 0114018W WO 0246320 A2 WO0246320 A2 WO 0246320A2
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WO
WIPO (PCT)
Prior art keywords
powder slurry
effect
powder
coloring
color
Prior art date
Application number
PCT/EP2001/014018
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German (de)
English (en)
Other versions
WO2002046320A3 (fr
Inventor
Hans-Joachim Weintz
Dieter Weber
Original Assignee
Basf Coatings Ag
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First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=7666095&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO2002046320(A2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Basf Coatings Ag filed Critical Basf Coatings Ag
Priority to AU2002233218A priority Critical patent/AU2002233218A1/en
Priority to US10/432,759 priority patent/US7151133B2/en
Priority to EP01984792A priority patent/EP1339805B1/fr
Priority to DE50108766T priority patent/DE50108766D1/de
Publication of WO2002046320A2 publication Critical patent/WO2002046320A2/fr
Publication of WO2002046320A3 publication Critical patent/WO2002046320A3/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/02—Emulsion paints including aerosols
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/80—Processes for incorporating ingredients

Definitions

  • the present invention relates to new coloring and / or effect powder slurries.
  • the present invention relates to a new ner process for producing color and / or effect powder slurries.
  • the present invention relates to a new method for the subsequent tinting of color and / or effect powder slurries.
  • the present invention relates to a new mixing system and module system for coloring and / or effect powder slurries.
  • Coloring and / or effect powder slurries i.e. Aqueous dispersions of color and / or effect powder coatings have long been known.
  • Japanese patent application JP 53 109 540 A 1 shows an unspecified coloring and / or effect powder slurry for the production of a coloring and / or effect base coat.
  • a powder slurry containing metal effect pigments based on amine-neutralized acrylate copolymers and melamine resins or of polyesters and epoxy resins is known from German published patent application DE 27 10 421 A1.
  • the well-known powder slurry provides smooth, shiny, metallic coatings.
  • Japanese patent application JP 02 014 776 A 2 discloses a multi-layer coating comprising a basecoat and a clearcoat, the basecoat of which is produced from a color and / or effect powder slurry based on hydroxyl-containing acrylate copolymers and blocked polyisocyanates.
  • a color and / or effect powder slurry based on hydroxyl-containing acrylate copolymers and blocked polyisocyanates.
  • cosolvent-free color and / or effect powder slurries based on, for example, hydroxyl-containing acrylate copolymers and blocked polyisocyanates or glycidyl-containing acrylate copolymers and long-chain alkanedioic acids are known.
  • the color and / or effect powder slurries can either be used to produce primers, ie filler coatings or stone chip protection primers, or to produce base coats.
  • Coloring and / or effect-giving powder slurries like the corresponding powder coatings, have the complete or almost complete freedom from organic solvents compared to conventional or aqueous color and / or effect-imparting wet coatings. Compared to powder coatings, they have the essential advantage that they can be stored, transported and applied like wet coatings and do not require any special devices such as powder coatings.
  • Curing takes place during or after the powder layer has melted.
  • the minimum temperature for curing is preferably above the
  • a color tone setting and / or correction via mixing or tinting steps is not possible, but the color tone is determined solely by the original weight.
  • the pigments are mixed into a powder slurry clear varnish, which often results in problems with the distribution of the coloring and / or effect pigments in the powder slurry.
  • the finished coloring and / or effect powder slurry and the coating produced from it ultimately also have the desired color and / or optical effect then depends on numerous different process parameters and on the particular implementation of the production process, so that it becomes extremely difficult determine the cause of faulty batches. It goes without saying that the powder slurries, which differ in their composition and their application-related property profile, in particular with regard to the color tones and / or the optical effects, cannot provide coatings that meet the specifications.
  • module denotes a standardized, ready-to-use commercial product whose application properties profile is precisely matched to and complements the property profiles of the other modules, so that the modules as a whole can be combined to form a module system.
  • the object of the present invention is to provide new coloring and / or effects
  • the present invention was based on the object of finding a new process for producing color and / or effect powder slurries which no longer has the disadvantages of the prior art, but which allows powder slurries of different shades and / or or produce optical effects, whereby the coloring and / or effect powder slurries always fully meet the specified specification.
  • the new method should make it possible to subsequently adjust the color and / or effect powder slurries which have been produced and which deviate from the specified specifications, so that little or no incorrect batches occur.
  • the new coloring and / or effect powder purry (A) was found, which can be prepared by one of the powder slurry (A) various coloring and / or effect powder slurry (B) or a clear lacquer powder slurry (B) mixed with at least one tinting paste (C) and which is referred to below as "inventive powder slurry (A)".
  • the new process for producing the powder slurry (A) according to the invention was found, in which a color and / or effect powder slurry (B) different from the powder slurry (A) according to the invention or a clear lacquer powder slurry (B) with at least one clay paste ( C) mixed, resulting in the powder slurry (A) according to the invention.
  • the new process for producing the powder slurry (A) according to the invention is referred to below as the "production process according to the invention”.
  • mixing system which is hereinafter referred to as "mixing system according to the invention".
  • the powder slurry (A) according to the invention can be produced by mixing a color and / or effect powder slurry (B) different from the powder slurry (A) or a clear lacquer powder slurry (B) with at least one tinting paste (C).
  • optical effects are, in particular, metallic effects and / or dichroic optical effects (cf. Römpp Lexikon Lacke und Druckmaschine, Georg Thieme Verlag, 1998, pages 176, »effect pigments « and pages 380 and 381 »metal oxide mica pigments «To» metal pigments «).
  • the powder slurry (A) according to the invention and the coloring and / or effect powder slurry (B) or the clear lacquer powder slurry (B), which are the precursor of the powder slurry (A) according to the invention, can be cured thermally and / or with actinic radiation. After curing, they form three-dimensionally cross-linked, duromeric coatings.
  • the term "self-crosslinking" denotes the property of a binder to undergo crosslinking reactions with itself.
  • a prerequisite for this is that the binders already contain both types of complementary reactive functional groups which are necessary for crosslinking, or reactive functional groups Groups that can react "with themselves” Powder slurries according to the invention referred to, wherein one type of complementary reactive functional groups in the binder, and the other type in a hardener or crosslinking agent.
  • actinic radiation means electromagnetic radiation such as near infrared, visible light, UV radiation or X-rays, in particular UN radiation, or corpuscular radiation such as electron beams.
  • the powder slurry (A) according to the invention, the color and / or effect powder slurry (B) and the clear lacquer powder slurry (B) can also be thermoplastic and not crosslinking. In other words, the curing takes place physically by coalescence of the melted powder slurry type particles and looping of the polymer molecules.
  • the thermal and / or actinic radiation curable systems are from Norteil and are therefore used with particular preference.
  • the powder slurry (A) according to the invention is prepared by the production process according to the invention from the coloring and / or effect powder slurry (B) or the clear lacquer powder slurry (B).
  • the tinting process according to the invention is directed to the powder slurry (A) according to the invention.
  • the boundary between the manufacturing process according to the invention and the tinting process according to the invention are naturally fluid.
  • the person skilled in the art will view the ner process as the production process, in which the starting product, the powder slurry, undergoes a significant change in its material composition through the addition of the tinting pastes.
  • the person skilled in the art will view the process as a tinting process, in which the starting product undergoes only a slight change in its material composition due to the addition of the tinting pastes, because it is precisely the purpose of tinting processes that reduce the color tones and / or the optical effects of the product correct the tinting paste as possible so that other valuable properties of the powder slurry do not change.
  • the powder slurry (A) according to the invention, the color and / or effect powder slurry (B) and the clear lacquer powder slurry (B) contain at least one finely divided dimensionally stable constituent, i.e. a powder coating, as a disperse phase and an aqueous medium as a continuous phase.
  • the finely divided, dimensionally stable component or powder coating of the powder slurry (A) according to the invention, the coloring and / or effect powder slurry (B) and the clear coating powder slurry (B) can be solid and / or highly viscous.
  • “highly viscous” means that the particles behave essentially like solid particles under the customary and known conditions for producing, storing and using powder slurries.
  • the powder coating material is preferably solid.
  • the individual particles of the finely divided component are also dimensionally stable.
  • “Dimensionally stable” means that the particles agglomerate only slightly, if at all, and / or disintegrate into smaller particles under the usual and known conditions of storage and use of powder slurries, but also essentially retain their original shape under the influence of shear forces.
  • the solids content of the powder slurry (A) according to the invention, the color and / or effect powder slurry (B) or the clearcoat powder slurry (B) is preferably from 10 to 80, preferably 15 to 75, particularly preferably 20 to 70, very particularly preferably 25 up to 70 and in particular 30 to 65% by weight, in each case based on the powder slurry (A) or (B).
  • the average particle size of the finely divided, dimensionally stable constituents of the powder slurry (A) according to the invention, the color and / or effect powder slurry (B) and the clearcoat powder slurry (B) is 0.8 to 40 ⁇ m, preferably 0.8 to 20 ⁇ m, and particularly preferably 2 to 6 ⁇ m.
  • the mean particle size is understood to mean the 50% median value determined by the laser diffraction method, i.e. 50% of the particles have a particle diameter ⁇ the median value and 50% of the particles have a particle diameter> the median value.
  • the upper limit of the particle size is when the size of the particles means that they can no longer run completely when they are burned in, and so that the progress of the particle is adversely affected.
  • the upper limit of 40 ⁇ m is considered to be sensible, since clogging of the rinsing channels of the highly sensitive application equipment can be expected from this particle size.
  • Powder slurry (B) and the clear lacquer powder slurry (B) are preferably free of organic solvents (cosolvents).
  • the finely divided, dimensionally stable constituent of the powder slurry (A) according to the invention and the coloring and / or effect powder slurry (B) contains at least one coloring and / or effect pigment; i.e. the total amount of pigments used is in the dispersed powder coating particles.
  • powder slurry (A) according to the invention and the coloring and / or effect powder slurry (B) contains at least one pigment-free, finely divided constituent or powder coating and at least one powder, color and / or effect pigment; i.e. all pigments are in a separate solid phase.
  • the foregoing applies analogously to their particle size.
  • the powder slurry (A) according to the invention and the coloring and / or effect powder slurry (B) contains at least one dispersed powder coating material which contains part of the pigments used, whereas the other part of the pigments as separate solid phase is present.
  • the proportion present in the powder coating particles can be the main amount, i.e. are more than 50% of the pigments used. However, there may also be less than 50% in the powder coating particles. With regard to the particle sizes, what has been said above also applies here analogously.
  • the pigments can consist of inorganic or organic compounds.
  • the powder slurry (A) according to the invention and the color and / or effect powder slurry (B) therefore ensure, owing to this large number of suitable pigments, a universal range of use and enable the realization of a large number of color tones and optical effects.
  • suitable effect pigments are metal plate pigments such as commercially available aluminum bronzes, aluminum bronzes chromated according to DE 36 36 183 A1, and commercially available stainless steel bronzes and non-metallic effect pigments such as. for example pearlescent or interference pigments, platelet-shaped effect pigments based on iron oxide, which has a color from pink to brown-red, liquid-crystalline effect pigments or fluorescent pigments (daylight pigments) such as bis (azomethine) pigments.
  • pearlescent or interference pigments platelet-shaped effect pigments based on iron oxide, which has a color from pink to brown-red, liquid-crystalline effect pigments or fluorescent pigments (daylight pigments) such as bis (azomethine) pigments.
  • fluorescent pigments daylight pigments
  • bis (azomethine) pigments bis (azomethine) pigments.
  • Römpp Lexikon Lacquers and Printing Inks Georg Thieme Verlag, 1998, pages 176, "Effect Pigments” and pages 380 and 381 "Metal Ox
  • Suitable inorganic color pigments are white pigments such as titanium dioxide, zinc white, zinc sulfide or lithopone; Black pigments such as
  • Colored pigments such as chromium oxide, chromium oxide hydrate green, cobalt green or ulframarine green, cobalt blue, Ultramarine blue or manganese blue, ultramarine violet or cobalt and manganese violet, iron oxide red, cadmium sulfoselenide, moly
  • organic coloring pigments examples include monoazo pigments, bisazo pigments, anthraquinone pigments, benzimidazole pigments,
  • Quinacridone pigments quinophthalone pigments, diketopyrrolopyrrole pigments, dioxazine pigments, indanthrone pigments, isoindoline pigments,
  • Isoindolinone pigments azomethine pigments, thioindigo pigments,
  • Metal complex pigments are Perinone pigments, perylene pigments,
  • Phthalocyanine pigments or aniline black Phthalocyanine pigments or aniline black.
  • the color and / or effect powder slurry (B) contains only color pigments. Further advantages result if the coloring powder slurry (B) has a light, in particular an achromatic, shade.
  • Achromatic colors differ from the multicolored ones in that there is no hue or chroma; they only show brightness.
  • the achromatic colors include black and white and the gray tones in between or to be mixed therefrom (see Römpp Lexikon Lacke and Druckmaschine, Georg Thieme Verlag, Stuttgart, New York, 1998 »Unbuntrios «, page 590).
  • a white powder slurry (B) is particularly preferably used.
  • coloring and / or effect powder slurry (B) and the powder slurry according to the invention (A) can also contain electrically conductive pigments, magnetically shielding pigments and / or metal powders.
  • Suitable electrically conductive pigments are titanium dioxide / tin oxide pigments.
  • magnétiqueally shielding pigments examples include pigments based on iron oxides or chromium dioxide.
  • suitable metal powders are powders made from metals and metal alloys aluminum, zinc, copper, bronze or brass.
  • the powder slurry (A) according to the invention and the coloring and / or effect powder slurry (B) can also contain organic and inorganic fillers which, like the pigments, can be present inside and outside the dispersed powder coating particles; what has been said about the pigments applies here analogously.
  • suitable organic and inorganic fillers are chalk, calcium sulfates, barium sulfate, silicates such as talc or kaolin, silicas, oxides such as aluminum hydroxide or magnesium hydroxide or organic fillers such as polyacrylonitrile powder or polyamide powder.
  • suitable fillers are known from German patent application DE 196 06 706 A1, column 8, lines 30 to 64. They are preferably used in the amounts specified therein.
  • the pigments and fillers can also be in ultra-fine, non-opaque form.
  • the proportion of pigments, including the fillers, in the powder slurry (A) according to the invention and in the color and / or effect powder slurry (B) can vary very widely and depends on the requirements of the individual case, in particular on the optical effect to be set and / or the hiding power of the pigments used in each case.
  • the pigment content is preferably 0.5 to 80, preferably 0.8 to 75, particularly preferably 1.0 to 70, very particularly preferably 1.2 to 65 and in particular 1.3 to 60% by weight, in each case based on the solid of the powder slurry (A) or (B).
  • the powder slurry (A) according to the invention and the color and / or effect powder slurry (B) can contain, in addition to the pigments described above, molecularly dispersed organic dyes.
  • molecularly disperse dyes can be present either in the dispersed powder coating particles or in the continuous phase of the powder slurry (A) according to the invention or of the color and / or effect powder slurry (B).
  • the dispersed powder coating particles can also be present in the dispersed powder coating particles or in the continuous phase.
  • the proportion present in the powder coating particles can be the main amount, ie more than 50% of the organic dyes used. However, there may also be less than 50% in the powder coating particles.
  • the distribution of the organic dyes between the phases can correspond to the mennodynamic equilibrium resulting from the solubility of the organic dyes in the phases result. The distribution can also be far from the thermodynamic equilibrium.
  • All organic dyes are suitable which are soluble in the powder slurry (A) according to the invention and the color and / or effect powder slurry (B) in the sense described above.
  • Lightfast organic dyes are well suited. Lightfast organic dyes with little or no tendency to migrate from the coatings which are produced from the powder slurry (A) according to the invention are particularly suitable. The person skilled in the art can estimate the tendency to migrate on the basis of his general specialist knowledge and / or determine it with the aid of simple preliminary tests, for example in the context of sound tests.
  • the content of the molecularly dispersed organic dyes in the powder slurry (A) according to the invention and in the color and / or effect powder slurry (B) can vary extremely widely and depends primarily on the color and the hue to be adjusted and on the amount of pigments and / or fillers present.
  • the powder slurry (A) according to the invention, the color and / or effect powder slurry (B) and the clear lacquer powder slurry (B) contain at least one binder as an essential component.
  • the binders are oligomeric and polymeric resins. Oligomers are understood to mean resins which contain at least 2 to 15 monomer units in their molecule. In the context of the present invention, polymers are understood to be resins which contain at least 10 recurring monomer units in their molecule. In addition to these terms, reference is made to Römpp Lexikon Lacke und Druckmaschine, Georg Thieme Verlag, Stuttgart, New York, 1998, »Oligomere «, page 425. According to the invention, it is advantageous if the minimum film-forming temperature of the binders is at least 10 ° C., preferably at least 20, particularly preferably at least 25, very particularly preferably at least 30 and in particular at least 35 ° C.
  • the minimum film-forming temperature can be determined by drawing the aqueous dispersion of the binder onto a glass plate using a doctor blade and heating it in a gradient oven. The temperature at which the powdery layer films is called the minimum film-forming temperature.
  • the minimum film-forming temperature can be determined by drawing the aqueous dispersion of the binder onto a glass plate using a doctor blade and heating it in a gradient oven. The temperature at which the powdery layer films.
  • Suitable binders are random, alternating and / or block-shaped linear and / or branched and / or comb-like (co) polymers of ethylenically unsaturated monomers, polyaddition resins and / or polycondensation resins. These terms are supplemented by Römpp Lexikon Lacke und Druckmaschine, Georg Thieme Verlag, Stuttgart, New York, 1998, page 457, "Polyaddition” and “Polyadditionharze (polyadducts)", and pages 463 and 464, "Polycondensates”, “Polycondensation” and “Polycondensation Resins", as well as pages 73 and 74, "Binders".
  • suitable (co) polymers are (meth) acrylate (co) polymers or partially saponified polyvinyl esters, in particular (meth) acrylate copolymers.
  • suitable polyaddition resins and / or polycondensation resins are polyesters, alkyds, polyurethanes, polylactones, polycarbonates, polyethers, epoxy resins, epoxy resin-amine adducts, polyureas, polyamides, polyimides, polyester-polyurethanes, polyether-polyurethanes or polyester-polyether-polyurethanes, in particular epoxy resins .
  • the self-crosslinking binders of the thermally curable powder slurries (A) and (B) of the dual-cure powder slurries (A) and (B) contain reactive functional groups which can undergo crosslinking reactions with groups of their type or with complementary reactive functional groups.
  • the externally crosslinking binders contain reactive functional groups which can undergo crosslinking reactions with complementary reactive functional groups which are present in crosslinking agents.
  • suitable complementary reactive functional groups to be used according to the invention are summarized in the following overview.
  • the variable R stands for an acyclic or cyclic aliphatic, an aromatic and / or an aromatic-aliphatic (araliphatic) radical; the variables R and R stand for the same or different aliphatic radicals or are linked to one another to form an aliphatic or heteroaliphatic ring.
  • the selection of the respective complementary groups depends on the one hand on the fact that they do not undergo any undesired reactions, in particular no premature crosslinking, during the production, storage, application and melting of the powder slurry (A) according to the invention and / or if necessary curing with actinic Do not disturb or inhibit radiation, and on the other hand in which temperature range the crosslinking should take place.
  • Crosslinking temperatures of 60 to 180 ° C. are preferably used in the powder slurry (A) according to the invention.
  • binders with thio, hydroxyl, N-methylolamino-N-alkoxymethylamino, imino, carbamate, allophanate, epoxy or carboxyl groups, preferably hydroxyl or epoxy groups, in particular epoxy groups, on the one hand, and preferably crosslinking agents with anhydride -, carboxyl, epoxy, blocked isocyanate, urethane, methylol, methylol ether, siloxane, carbonate, amino, hydroxy and / or beta-hydroxyalkylamide groups, preferably epoxy, hydroxy, beta-hydroxyalkylamide groups , blocked and unblocked isocyanate, urethane or alkoxymethylamino groups, particularly preferably epoxy or hydroxyl groups, in particular phenolic hydroxyl groups, used on the other hand.
  • the binders contain, in particular, methylol, methylol ether and / or N-A3koxymemylamino groups.
  • the functionality of the binders with respect to the reactive functional groups described above can vary very widely and depends in particular on the crosslinking density that is to be achieved and / or on the functionality of the crosslinking agent used in each case.
  • the acid number is preferably 10 to 100, preferably 15 to 80, particularly preferably 20 to 75, very particularly preferably 25 to 70 and in particular 30 to 65 mg KOH / g.
  • the OH number is preferably 15 to 300, preferably 20 to 250, particularly preferably 25 to 200, very particularly preferably 30 to 150 and in particular 35 to 120 mg KOH / g.
  • the epoxy equivalent weight is preferably 400 to 2,500, preferably 420 to 2,200, particularly preferably 430 to 2,100, very particularly preferably 440 to 2,000 and in particular 440 to 1,900.
  • the complementary reactive functional groups described above can be incorporated into the binders by the customary and known methods of polymer chemistry. This can be done, for example, by installing Monomers which carry the corresponding reactive functional groups and / or with the aid of polymer-analogous reactions.
  • Hydroxyalkyl esters of acrylic acid, methacrylic acid or another alpha, beta-olefinically unsaturated carboxylic acid which are derived from an alkylene glycol which is esterified with the acid, or by reacting the alpha, beta-olefinically unsaturated carboxylic acid with an alkylene oxide such as ethylene oxide or
  • Propylene oxide are available, in particular hydroxyalkyl esters of acrylic acid, methacrylic acid, ethacrylic acid, crotonic acid, maleic acid, fumaric acid or itaconic acid, in which the hydroxyalkyl group contains up to 20 carbon atoms, such as 2-hydroxyethyl, 2-hydroxypropyl, 3-hydroxypropyl, 3-
  • Hydroxybutyl 4-hydroxybutyl acrylate, methacrylate, ethacrylate, crotonate, maleate, fumarate or itaconate; or hydroxycycloalkyl esters such as 1,4-bis (hydroxymethyl) cyclohexane, octahydro-4,7-methano-1 H-indene-dimethanol or methyl propanediol monoacrylate, monomethacrylate, monoethacrylate, monocrotonate, monomaleinate, monofumarate or monoitaconate; Reaction products from cyclic esters such as epsilon-caprolactone and these hydroxyalkyl or - cycloalkyleste ⁇ i; olefinically unsaturated alcohols such as allyl alcohol;
  • Polyols such as trimethylolpropane mono- or diallyl ether or pentaerythritol mono-, di- or triallyl ether;
  • (Meth) acrylic acid amides such as (meth) acrylic acid amide, N-methyl, N-methylol, N, N-dimethylol, N-methoxymethyl, N, N-di (methoxymethyl), N-ethoxymethyl and / or N , N-Di (ethoxyethyl) - (meth) acrylic acid amide;
  • Acrylic acid methacrylic acid, ethacrylic acid, crotonic acid, maleic acid, fumaric acid or itaconic acid;
  • Vinylbenzoic acid (all isomers), alpha-methylvinylbenzoic acid (all isomers) or ninylbenzenesulfonic acid (all isomers).
  • (a3) monomers containing epoxy groups such as the glycidyl ester of acrylic acid, methacrylic acid, ethacrylic acid, crotonic acid, maleic acid,
  • Fumaric acid or itaconic acid or allyl glycidyl ether Fumaric acid or itaconic acid or allyl glycidyl ether.
  • suitable monomer units for introducing reactive functional groups into polyester or polyester polyurethanes are 2,2-dimethylolethyl- or propylamine, which are blocked with a ketone, the resulting ketoxime group being hydrolyzed again after incorporation; or compounds which contain two hydroxyl groups or two primary and / or secondary amino groups and at least one acid group, in particular at least one carboxyl group and / or at least one sulfonic acid group, such as dihydroxypropionic acid, dihydroxysuccinic acid, dihydroxybenzoic acid, 2,2-dimethylolacetic acid, 2,2-dimethylolpropionic acid , 2,2-dimethylolbutyric acid, 2,2-dimenthylolpentanoic acid, ###, ### - Dian__inovalerianklare, 3,4-
  • Diaminobenzoic acid 2,4-diaminotoluenesulfonic acid or 2,4-diamino-diphenyl ether sulfonic acid.
  • the binders of the dual-cure powder slurries (A) and (B) furthermore contain on average at least one, preferably at least two, group (s) with at least one bond which can be activated with actinic radiation per molecule.
  • the binders of the color and / or effect powder slurries curable with actinic radiation contain at least two of these groups.
  • a bond which can be activated with actinic radiation is understood to mean a bond which becomes reactive when irradiated with actinic radiation and which undergoes polymerization reactions and / or crosslinking reactions with other activated bonds of its type which take place according to radical and / or ionic mechanisms.
  • bonds are carbon-hydrogen single bonds or carbon-carbon, carbon-oxygen, carbon-nitrogen, carbon-phosphorus or carbon-silicon single bonds or double bonds.
  • carbon-carbon double bonds are particularly advantageous and are therefore used with very particular preference in accordance with the invention. For the sake of brevity, they are referred to below as "double bonds”.
  • the group preferred according to the invention contains one double bond or two, three or four double bonds. If more than one double bond is used, the double bonds can be conjugated. According to the invention, however, it is advantageous if the double bonds are isolated, in particular each individually in the group in question here. According to the invention, it is particularly advantageous to use two, in particular one, double bond.
  • the groups are structurally different from one another or of the same structure.
  • Suitable groups are (meth) acrylate, ethacrylate, crotonate, cinnamate, vinyl ether, vinyl ester, dicyclopentadienyl, norbomenyl, isoprenyl, isopropenyl, allyl or butenyl groups; Dicyclopentadienyl, norbomenyl, isoprenyl, isopropenyl, allyl or butenyl ether groups or dicyclopentadienyl, norbomenyl, isoprenyl, isopropenyl, allyl or butenyl ester groups, but especially acrylate groups.
  • the groups are preferably bonded to the respective structural structures of the binders via urethane, urea, AUophanat, ester, ether and / or amide groups, but in particular via ester groups. This is usually done by customary and known polymer-analogous reactions such as
  • the preparation of the binders has no special features in terms of method, 5 but is carried out with the aid of the customary and known methods of polymer chemistry, as described in detail, for example, in the patents listed above.
  • polyesters and alkyd resins are described, for example, in the standard work Ullmanns Encyklopadie der Technische Chemie, 3rd edition, volume 14, Urban & Schwarzenberg, Kunststoff, Berlin, 1963, pages 80 to 89 and pages 25 99 to 105, as well as in the books : "Resines Alkydes-Polyesters” by J. Bourry, Paris, Dunod Verlag, 1952, "Alkyd Resins” by CR Martens, Reinhold Publishing Corporation, New York, 1961, and “Alkyd Resin Technology” by TC Patton, Intersience Publishers, 1962 , described.
  • the production of polyurethanes and / or acrylated polyurethanes is described, for example, in patent applications EP 0 708 788 A1, DE 44 01 544 A1 or DE 195 34 361 A1.
  • the binder content of the powder slurry (A) according to the invention, of the color and / or effect powder slurry (B) and of the clear lacquer powder slurry (B) can vary very widely and depends primarily on whether they are thermally self-wetting. In this case, it can preferably be 20 to 99.5, preferably 25 to 99.2, particularly preferably 30 to 99, very particularly preferably
  • the binder content is preferably 10 to 80, preferably 15 to 75, particularly preferably 20 to 70, very particularly preferably 25 to 65 and in particular 30 to 60% by weight, based on the solids content of the powder slurry (A) or (B).
  • the externally crosslinking powder slurries (A) and (B) curable thermally or thermally and with actinic radiation contain at least one crosslinking agent which contains the reactive functional groups which are complementary to the reactive functional groups of the binders.
  • a person skilled in the art can therefore easily select the crosslinking agent suitable for a given powder slurry (A), color and / or effect powder slurry (B) and clear lacquer powder slurry (B).
  • Aminoplast resins such as those found in Römpp Lexikon Lacke und Drackmaschine, Georg Thieme Verlag, 1998, page 29, “Aminoharze”, the textbook “Lackadditive” by Johan Bieleman, Wiley-VCH, Weinheim, New York, 1998, pages 242 ff., the book “Paints, Coatings and
  • beta-hydroxyalkylamides such as N, N, N ', N'-tetrakis (2-hydroxyethyl) adipain or N, N, N', N'-tetrakis (2-hydroxypropyl) adipamide,
  • Tris (a_koxycarbonyla_nino) triazines as are described in the patents US 4,939,213 A 1, US 5,084,541 A, US 5,288,865 A or EP 0 604 922 A 1, and or or or
  • the content of the crosslinking agents in the powder slurry (A) according to the invention, in the color and / or effect powder slurry (B) and in the clearcoat powder slurry (B) can likewise vary very widely and depends on the requirements of the individual case, in particular the number of complementary reactive functional groups present in the binders and crosslinking agents. It is preferably 1 to 50, preferably 2 to 45, particularly preferably 3 to 40, very particularly preferably 4 to 35 and in particular 5 to 30% by weight, based on the solids content of the powder slurry (A) or (B).
  • the powder slurry (A) according to the invention can also contain at least one additive. Depending on its physicochemical properties and / or its function, this can be present essentially in the dispersed powder coating particles or essentially in the continuous phase.
  • thermally curable reactive diluents such as positionally isomeric diethyloctanediols or hydroxyl group-containing hyperbranched compounds or dendrimers;
  • Crosslinking catalysts such as dibutyltin dilaurate, lithium decanoate or zinc octoate, organic sulfonic acids blocked with amines, quaternary ammonium compounds, amines, imidazole and imidazole derivatives such as 2-styrylimidazole, l-benzyl-2-methylimidazole, 2-methylimidazole and 2-butylimidazole and 2-butylimidazole patent
  • phosphomum catalysts such as ethyltriphenylphosphonium iodide, ethyltriphenylphosphonium chloride, ethyltriphenylphosphoniumthiocyanate, ethyltriphenylphosphonium
  • Acetate-acetic acid complex tetrabutylphosphonium iodide, tetrabutylphosphonium bromide and tetrabutylphosphonium acetate-acetic acid complex, as described, for example, in US Pat. Nos. 3,477,990 A or 3,341,580 A;
  • thermolabile free radical initiators such as organic peroxides, organic azo compounds or C-C-cleaving initiators such as dialkyl peroxides,
  • Peroxocarboxylic acids peroxodicarbonates, peroxide esters, hydroperoxides, ketone peroxides, azodinitriles or benzpinacol silyl ethers;
  • Antioxidants such as hydrazines and phosphorus compounds
  • UV absorbers such as triazines, benzotriazoles or oxalanilides
  • Light stabilizers such as HALS compounds
  • Radical scavengers and polymerization inhibitors such as organic phosphites or 2,6 di-tert-butylphenol derivatives
  • Emulsifiers especially non-ionic emulsifiers such as alkoxylated alkanols and polyols, phenols and AUcylphenols or anionic
  • Emulsifiers such as alkali salts or ammonium salts of alkane carboxylic acids, alkane sulfonic acids, and sulfo acids of alkoxylated alkanols and polyols, phenols and acylphenols;
  • Adhesion promoters such as tricyclodecanedimethanol
  • film-forming aids such as cellulose derivatives
  • Deaerators such as diazadicycloundecane or benzoin;
  • rheology-controlling additives such as those known from patent applications WO 94/22968, EP 0 276 501 A1, EP 0 249 201 A1 or WO 97/12945; crosslinked polymeric microparticles, as disclosed, for example, in EP 0 008 127 A1; inorganic
  • Layered silicates such as aluminum-magnesium silicates, sodium-magnesium and sodium-magnesium-fluorine-lithium layered silicates
  • Montmorillonite type Silicas such as aerosils; or synthetic polymers with ionic and / or associative groups such as polyvinyl alcohol, poly (meth) acrylamide, poly (meth) acrylic acid,
  • a color and / or effect powder coating or powder clear coating is assumed, which, as in the product information from the company BASF Lacke + Weg 80, "Powder Coatings", 1990 or the company lettering from BASF Coatings AG "Powder Coatings "Powder coatings for industrial applications", January 2000, described by homogenizing and dispersing, for example by means of an extruder or screw kneader, and grinding. After the powder coatings have been produced, they are prepared for dispersion by further grinding and, if appropriate, by screening and sieving.
  • the powder and / or effect powder slurry (B) and the clear coating powder slurry (B) can then be prepared from the powder coating materials by wet grinding or by stirring in the dry ground powder coating material. Wet grinding is particularly preferred.
  • the constituents described above are emulsified in an organic solvent, which results in an emulsion of the oil-in-water type, after which the organic solvent is removed, as a result of which the emulsified droplets solidify and the coloring and / or or effect powder slurry (B) or the clear lacquer powder slurry (B) result. Possibly. they can be wet milled to improve filterability.
  • a liquid melt of the constituents described above, if appropriate together with the unmelted pigments, is placed in an emulsifying device, preferably with the addition of water and stabilizers, the emulsion obtained is cooled and filtered, so that the clearcoat powder slurry (B) to be used according to the invention and coloring and / or effect powder slurry (B) result.
  • the polymeric constituents are fed into the dispersing units as viscous resin melts.
  • the coloring and / or effect powder slurry (B) to be used according to the invention and the clear lacquer powder slurry (B) to be used according to the invention are used to produce the powder slurry (A) according to the invention.
  • the color and / or effect powder slurry (B), in particular the color powder slurry (B), or the clear lacquer powder slurry (B) are mixed with at least one tinting paste (C).
  • the mixing ratio can vary very widely and depends on the requirements of the individual case, in particular on the hue to be adjusted and its intensity.
  • the material composition of the tinting pastes (C) can also vary widely. It is essential that they are compatible with the coloring and / or effect powder slurry (B) and the clear lacquer powder slurry (B), so that there are no glossy veils in the and not for sweating out or floating out components of the clay paste (C) from the Coatings that have been produced from the powder slurry (A) according to the invention come.
  • Aqueous clay pastes (C) are preferably used.
  • the tinting pastes can contain minor amounts of organic solvents typical for lacquers, minor amounts being understood to mean amounts which do not destroy the aqueous nature of the tinting pastes (C). Examples of suitable organic solvents are alkylene glycols such as propylene glycol.
  • the aqueous tinting pastes (C) contain at least one of the coloring and / or effect pigments described above.
  • the content of pigments can vary very widely and depends on their physical properties such as dispersibility and hiding power.
  • the pigments are preferably used in an amount of 10 to 80, preferably 12 to 75, particularly preferably 14 to 70 and in particular 16 to 65% by weight, in each case based on the tinting paste (C).
  • the pigments in the aqueous tinting pastes (C) contain at least one wetting agent and or one emulsifier. Suitable wetting agents and emulsifiers are those described above.
  • the aqueous tinting pastes (C) preferably contain at least one, in particular one, customary and known water-dilutable (meth) acrylate copolymer and / or a thickener based on layered silicate and / or polyurethane.
  • Suitable thickeners are those described above.
  • the aqueous tinting pastes (C) may also contain at least one of the additives described above.
  • the preparation of the tinting pastes (C) to be used according to the invention does not offer any special features in terms of method, but instead takes place in accordance with the customary and known methods of producing tinting pastes by mixing their constituents in suitable mixing units such as stirred kettles, dissolvers, Ultraturrax or extruders.
  • suitable mixing units such as stirred kettles, dissolvers, Ultraturrax or extruders.
  • the desired fineness of the pigments is preferably set by grinding the tinting paste (C), for example in an agitator mill.
  • the mixing of the tinting pastes (C) with the color and / or effect powder slurries (B) or the clear lacquer powder slurries (B) to be used according to the invention does not offer any special features in terms of method, but instead takes place according to the methods described above, using the mixing units described above become. Mixing can also be done by hand, especially when producing small quantities.
  • the manufacturing process according to the invention and the tinting process according to the invention make it possible from the outset or subsequently to set the color tones and / or the optical effects of the powder slurries (A) according to the invention particularly easily without great effort.
  • powder slurries (A) of the most varied of colors and / or intensities of the optical effects according to the invention can be produced in the required amounts in a simple manner.
  • Another advantage of the manufacturing process and tinting process according to the invention is that excess, no longer usable color and / or effect powder slurries and powder clearcoats or faulty batches can still be used for the production of the powder slurries (A) according to the invention and do not have to be disposed of.
  • the mixing system according to the invention contains at least one, in particular one, color and / or effect powder slurry (B) and / or at least one, in particular one, clear lacquer powder slurry (B).
  • a clear lacquer powder slurry (B) or a color-giving powder slurry (B) is preferably used, which preferably has a light, in particular achromatic, shade.
  • a white powder slurry (B) is particularly preferably used.
  • the mixing system according to the invention further contains at least two tinting pastes (C) which are compatible with the coloring and / or effect powder slurry (B) and the clearcoat powder slurry (B) and with one another in the sense described above.
  • C tinting pastes
  • the basic principle of the mixing system according to the invention is that a very large number, for example several thousand, of powder slurries (A) according to the invention with different color tones and / or optical effects with a limited number of color and / or effect powder slurries (B) or clear lacquer powder slurries (B) on the one hand and tinting pastes (C) on the other hand.
  • a clear lacquer powder slurry (B) or 1 to 10 different coloring and / or effect powder slurries (B) and 10 to are sufficient 50 different tinting pastes (C) to reproduce, for example, almost all of the colors and / or optical effects common in automotive serial painting or refinishing.
  • the mixing system according to the invention is preferably traded and used in the form of a modular system.
  • the module system according to the invention comprises a powder slurry module (I) containing at least one of the color and / or effect powder slurries (B) described above and / or at least one of the clear coat powder slurries (B) described above.
  • the module system according to the invention contains at least two different tinting modules (II), each of which contains a tinting paste (C).
  • An essential functional component (III) of the module system according to the invention is the color mixing film system. This is based on the differently colored and / or effect-giving powder slurries according to the invention (A) and / or (B) or the clearcoat powder slurries (B) as well as the differently colored and / or effect-giving clay pastes (C) and in the form of formulations and of standardized samples of the coatings produced from the individual powder slurries (A) according to the invention.
  • the powder slurries (A) according to the invention are outstandingly suitable for all purposes, for coloring and / or effect powder slurries are usually used.
  • they are for the automotive OEM painting that Automotive refinishing, the painting of buildings indoors and outdoors, the painting of doors, windows and furniture as well as industrial painting, including coil coating, container coating and the impregnation and / or coating of electrical components.
  • the resulting coatings have brilliant colors and / or intense optical effects and are free from surface defects and glossy haze. They show no floating or exudation of components.
  • Production example 1 Black tint paste A black tint paste was made by mixing the following ingredients in the order given:
  • Sicomix® Black 00-6060 mixture of flame black and barium sulfate, BASF AG.
  • Production example 2 Blue tint paste A blue tint paste was prepared by mixing the following ingredients in the order given.
  • the orange tint paste was prepared by mixing the following ingredients in the order given: 20.0 parts by weight of a water-dilutable methacrylate copolymer (Parocryl® AW 51.6, from BASF Coatings AG),
  • the yellow tint paste was prepared by mixing the following ingredients in the order listed: 22.0 parts by weight of a water-dilutable methacrylate copolymer (Parocryl® AW 51.6, BASF Coatings AG),
  • Sico-Yellow L 1252 HD (azo pigment, company BASF AG).
  • a clear lacquer powder slurry (B) was prepared for Examples 1 to 3.
  • a powder coating was first made from 46.9 parts by weight of a solid epoxy resin (DOW® ER 642 U-20, 100%, from Dow, Schwalbach) and 20.85 parts by weight of a phenolic hardener, made from an epoxy resin and an excess of bisphenol A (DOW® EH 82, 100%, from Dow, Schwalbach) by extruding the components and grinding the resulting mixture.
  • the clear lacquer powder slurry (B) was prepared from the following components by mixing:
  • Disperse Ayd® W-22 anionic / nonionic wetting agent from Krahn Chemie, Hamburg; 35 percent in water / propylene glycol
  • Triton® X 100 non-ionic surfactant, octylphenoxypolyethoxyethanaol from Union Carbide
  • a white powder slurry (B) was produced for Examples 4 to 8.
  • a white powder coating was first made from 46.9 parts by weight of a solid epoxy resin (DOW® ER 642 U-20, 100%, from Dow, Schwalbach), 20.85 parts by weight of a phenolic hardener, prepared from an epoxy resin and an excess Bisphenol A (DOW® EH 82, 100%, from Dow, Schwalbach) and 31.25 parts by weight of titanium rutile 2310 (commercially available titanium dioxide pigment from Kronos International) were produced by extruding the components and grinding the resulting mixture.
  • a solid epoxy resin DOW® ER 642 U-20, 100%, from Dow, Schwalbach
  • a phenolic hardener prepared from an epoxy resin and an excess Bisphenol A
  • titanium rutile 2310 commercially available titanium dioxide pigment from Kronos International
  • the white powder slurry (B) was made from the following ingredients by mixing:
  • Disperse Ayd® W-22 anionic / nonionic wetting agent from Krahn Chemie, Hamburg; 35 percent in water / propylene glycol
  • Triton® X 100 non-ionic surfactant, octylphenoxypolyethoxyethanaol from Union Carbide
  • the powder slurries (A) according to the invention of Examples 1 to 8 were produced by mixing the clear or color-giving powder slurries (B) given in the individual examples and the suitable tinting pastes (C).
  • the powder slurries (A) according to the invention of Examples 1 to 8 were stable in storage and showed no settling of solid particles or floating of other constituents.
  • the powder slurries (A) according to the invention were made on steel panels using a customary and known electrodeposition coating had been coated, applied. The course of the resulting powder slurry layers was excellent. After baking, black, yellow, orange, beige, light beige, light yellow, light blue and light gray coatings resulted, which corresponded to the specified specifications and were free from surface defects and glossy haze and showed no floating or exudation of components. The reproducibility of the colors was excellent.

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Cosmetics (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
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Abstract

L'invention concerne une boue pulvérulente de couleur et/ou à effet (A). Pour obtenir cette boue, on mélange une boue pulvérulente de couleur ou à effet (B) qui est différente de la boue pulvérulente (A), ou une boue pulvérulente de vernis clair (B) à au moins une pâte de nuance (C). La nuance et/ou les effets visuels de la boue pulvérulente de couleur et/ou à effet (A) peuvent être corrigés ultérieurement à l'aide d'au moins une pâte de nuance.
PCT/EP2001/014018 2000-12-07 2001-11-30 Boue pulverulente de couleur et/ou a effet, son procede de production et son utilisation WO2002046320A2 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
AU2002233218A AU2002233218A1 (en) 2000-12-07 2001-11-30 Colour and/or effect-bearing powder slurry, method for producing the same and use thereof
US10/432,759 US7151133B2 (en) 2000-12-07 2001-11-30 Color and/or effect-bearing powder slurry, method for producing the same and use thereof
EP01984792A EP1339805B1 (fr) 2000-12-07 2001-11-30 Boue pulverulente de couleur et/ou a effet, son procede de production et son utilisation
DE50108766T DE50108766D1 (de) 2000-12-07 2001-11-30 Farb- und/oder effektgebende pulverslurry, verfahren zu ihrer herstellung und ihre verwendung

Applications Claiming Priority (2)

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DE10060765A DE10060765A1 (de) 2000-12-07 2000-12-07 Farb- und/oder effektgebende Pulverslurry, Verfahren zu ihrer Herstellung und ihre Verwendung
DE10060765.9 2000-12-07

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DE10066134B4 (de) * 2000-11-27 2006-09-14 Basf Coatings Ag Mischsystem für Pulverlacke
EP2384358B1 (fr) 2008-12-29 2017-05-24 BASF Coatings GmbH Composition d'électrorevêtement et procédé remplaçant un prétraitement au phosphate
US20100163423A1 (en) 2008-12-29 2010-07-01 Basf Corporation Electrocoat composition and process replacing phosphate pretreatment
US8153733B2 (en) 2008-12-29 2012-04-10 Basf Coatings Gmbh Electrocoat compositions with amine ligand
WO2012115691A1 (fr) 2011-02-22 2012-08-30 Basf Coatings Gmbh Électrorevêtement à faible brillance
CN104769051B (zh) 2012-11-09 2018-02-23 巴斯夫涂料有限公司 提高由受磷酸盐离子污染的电涂涂料组合物涂布的制品的涂层固化的方法和电涂涂料组合物

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US5840799A (en) * 1992-09-30 1998-11-24 Basf Lacke+Farben, Ag Mixer system for the production of water-thinnable coating compositions
EP0614951A2 (fr) * 1993-03-10 1994-09-14 Herberts Gesellschaft mit beschränkter Haftung Procédé de préparation de compositions de revêtement aqueuses à couleur unique en utilisant des systèmes de modules

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ES2256313T3 (es) 2006-07-16
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ATE316123T1 (de) 2006-02-15
DE10060765A1 (de) 2002-06-20
US7151133B2 (en) 2006-12-19
WO2002046320A3 (fr) 2003-03-13
EP1339805A2 (fr) 2003-09-03
AU2002233218A1 (en) 2002-06-18
US20040045480A1 (en) 2004-03-11

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