WO2000011712A1 - Method and structure for improved alignment tolerance in multiple, singularized plugs - Google Patents
Method and structure for improved alignment tolerance in multiple, singularized plugs Download PDFInfo
- Publication number
- WO2000011712A1 WO2000011712A1 PCT/US1999/019567 US9919567W WO0011712A1 WO 2000011712 A1 WO2000011712 A1 WO 2000011712A1 US 9919567 W US9919567 W US 9919567W WO 0011712 A1 WO0011712 A1 WO 0011712A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- pair
- plugs
- forming
- bitline
- storage node
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 50
- 239000000758 substrate Substances 0.000 claims description 44
- 239000004065 semiconductor Substances 0.000 claims description 39
- 239000004020 conductor Substances 0.000 claims description 38
- 125000006850 spacer group Chemical group 0.000 claims description 27
- 238000003860 storage Methods 0.000 claims description 27
- 238000002955 isolation Methods 0.000 claims description 22
- 229910021420 polycrystalline silicon Inorganic materials 0.000 claims description 11
- 229920005591 polysilicon Polymers 0.000 claims description 10
- 238000000151 deposition Methods 0.000 claims description 4
- 230000001360 synchronised effect Effects 0.000 claims description 4
- 230000008878 coupling Effects 0.000 claims 2
- 238000010168 coupling process Methods 0.000 claims 2
- 238000005859 coupling reaction Methods 0.000 claims 2
- 230000015572 biosynthetic process Effects 0.000 abstract description 3
- 238000005755 formation reaction Methods 0.000 abstract description 3
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 239000010410 layer Substances 0.000 description 34
- 239000000463 material Substances 0.000 description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 10
- 235000012431 wafers Nutrition 0.000 description 8
- 238000005229 chemical vapour deposition Methods 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 229910052581 Si3N4 Inorganic materials 0.000 description 6
- 239000012212 insulator Substances 0.000 description 6
- 229920002120 photoresistant polymer Polymers 0.000 description 6
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 6
- 239000000377 silicon dioxide Substances 0.000 description 5
- 238000001020 plasma etching Methods 0.000 description 4
- 238000005530 etching Methods 0.000 description 3
- 238000001465 metallisation Methods 0.000 description 3
- 230000002093 peripheral effect Effects 0.000 description 3
- 235000012239 silicon dioxide Nutrition 0.000 description 3
- 239000002344 surface layer Substances 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 210000000746 body region Anatomy 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000002019 doping agent Substances 0.000 description 2
- 230000005669 field effect Effects 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 230000006978 adaptation Effects 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910021419 crystalline silicon Inorganic materials 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 229910021421 monocrystalline silicon Inorganic materials 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
Definitions
- the present invention relates generally to semiconductor integrated circuits. More particularly, it pertains to a method and structure for improved alignment tolerance in multiple, singularized plugs.
- Integrated circuits the key components in thousands of electronic and computer products, are interconnected networks of electrical components fabricated on a common foundation, or substrate. Fabricators typically use various techniques, such as layering, doping, masking, and etching, to build thousands and even millions of microscopic resistors, transistors, and other electrical components on a silicon substrate, known as a wafer. The components are then wired, or interconnected, together to define a specific electric circuit, such as a computer memory.
- Interconnecting and completing the millions of microscopic components typically entails forming contact plugs, covering the plugs and components with an insulative layer of silicon dioxide, and then etching narrow, but often deep, holes in the insulative layer to expose portions of the components, or contact plugs underneath. These holes are then filled with another conductive material, or are developed into additional component parts, e.g., storage nodes for memory cells.
- IGFET insulated-gate field-effect transistor
- MOSFET metal-oxide semiconductor field-effect transistor
- IGFET electrical component requiring contact plugs and etched holes for connection to other portions of an integrated circuit.
- IGFET 's are frequently used in both logic and memory chip applications.
- An IGFET uses a gate to control an underlying surface channel joining a source and a drain. The channel, source and drain are located in a semiconductor substrate, with the source and drain being doped oppositely to the substrate. The gate is separated from the semiconductor substrate by a insulating layer such as a gate oxide.
- the operation of the IGFET involves application of an input voltage to the gate, which sets up a transverse electric field in the channel in order to modulate the longitudinal conductance of the channel. Plug contacts and contact openings are required in IGFETs to complete the conductance circuit between the source and drain regions.
- an illustrative embodiment of the present invention includes an integrated circuit device on a substrate.
- the device includes a number of semiconductor surface structures which are spaced apart along the substrate.
- a number of plugs contact to the substrate between the number of surface structures.
- the number of plugs includes an inner plug and a pair of outer plugs. Each one of the outer pair is formed adjacent to and on opposing sides of the inner plug. Each one of the outer pair has an upper portion which covers areas of the surface structures.
- An inner electrical contact couples to the inner plug and is separated from the upper portions of the outer plugs by spacers.
- a memory device in another embodiment, includes multiple insulated wordlines with top surfaces.
- the insulated wordlines are spaced apart from one another and formed on a substrate.
- a bitline plug is located between an adjacent pair of the insulated wordlines.
- the bitline plug has a top surface beneath the top surfaces of the adjacent pair.
- a pair of storage node plugs are located on the opposite side of the adjacent pair of insulated wordlines from the bitline plug.
- the pair of storage node plugs each have a top surface above the top surfaces of the insulated wordlines and are formed over portions of the adjacent wordlines.
- a buried bitline couples to the bitline plug.
- a data handling system includes a central processing unit and a memory device which are coupled together by a system bus.
- the memory device includes the memory device discussed above.
- Another embodiment of the present invention includes a method of forming plugs between multiple semiconductor surface structures on a substrate.
- the method includes forming a first opening in a first isolation layer on the semiconductor surface structures. Forming the first opening includes exposing portions of the substrate between the multiple surface structures. A first conductive material is deposited in the first opening to cover the multiple surface structures. A second isolation layer is formed across the first conductive material. A second opening is formed in the first conductive material in a source region on the substrate. Forming the second opening includes exposing portions of an adjacent pair of the multiple surface structures.
- the method further includes forming spacers on interior walls of the second opening. Forming the spacers includes separating the first conductive material into an inner plug, isolated beneath and between the adjacent pair, and a pair of outer plugs.
- the outer plugs also cover portions of the adjacent pair. Further, a second conductive material is formed in the second opening and is isolated from the outer plugs by the spacers.
- Figures 1A, IB, lC-1, ID, IE, and IF are cross-sectional views which illustrate an embodiment of an integrated circuit device including contact plugs and contact openings.
- Figure 1C-2 is a top view of the cross sectional representation shown in Figure lC-1.
- Figure 1C-3 is a top view of a peripheral section of the substrate shown in Figure 1C-2.
- Figure 2 is a cross-sectional view which illustrates an embodiment of an integrated circuit device according to the teachings of the present invention.
- Figure 3 is a block diagram which illustrates an embodiment of a data handling system according to the teachings of the present invention.
- wafer and substrate used in the following description include any structure having an exposed surface with which to form the integrated circuit (IC) structure of the invention.
- substrate is understood to include semiconductor wafers.
- substrate is also used to refer to semiconductor structures during processing, and may include other layers that have been fabricated thereupon.
- Both wafer and substrate include doped and undoped semiconductors, epitaxial semiconductor layers supported by a base semiconductor or insulator, as well as other semiconductor structures well known to one skilled in the art.
- the term conductor is understood to include semiconductors, and the term insulator is defined to include any material that is less electrically conductive than the materials referred to as conductors. The following detailed description is, therefore, not to be taken in a limiting sense.
- the term "horizontal” as used in this application is defined as a plane substantially parallel to the conventional plane or surface of a wafer or substrate, regardless of the orientation of the wafer or substrate.
- vertical refers to a direction substantially perpendicular to the horizonal as defined above.
- Prepositions such as “on,””upper,” “side” (as in “sidewall”), “higher,” “lower,” “over” and “under” are defined with respect to the conventional plane or surface being on the top surface of the wafer or substrate, regardless of the orientation of the wafer or substrate.
- n+ refers to semiconductor material that is heavily doped n-type semiconductor material, e.g., monocrystalline silicon or polycrystalline silicon.
- p+ refers to semiconductor material that is heavily doped p-type semiconductor material.
- n- and p- refer to lightly doped n and p-type semiconductor materials, respectively.
- Figures 1 A- IF are cross-sectional views which illustrate an embodiment for fabricating an integrated circuit device including contact plugs and contact openings.
- Figure 1 A illustrates the structure at the point where IGFET, or simply transistor, fabrication has been completed up through covering drain and source regions, 101 and 107, as well as multiple semiconductor surface structures 102 on a substrate 100 with a first isolation layer 104.
- the first isolation layer 104 includes an oxide layer 104 which has been applied using chemical vapor deposition (CVD).
- a photoresist is applied and exposed to pattern where a first opening 105, or active area slot 105, is to be formed in the first isolation layer 104.
- the structure is now as appears in Figure 1A.
- Figure IB illustrates the structure following the next sequence of fabrication steps.
- the first isolation layer 104 is etched using any suitable technique such as, for example, reactive ion etching (RIE). Alternatively, the isolation layer 104 can be removed using a buffered oxide etch (BOE). The photoresist is then removed using conventional photoresist stripping techniques. The etching process forms a first opening 105, or active area slot 105, in the first isolation layer 104. Forming the first opening 105 includes exposing portions of the multiple semiconductor surface structures 102, shown collectively as 109, and includes exposing portions of the substrate 100 between the exposed multiple semiconductor surface structures 102. Next, a first conductive material 106 is deposited in the first opening 105, or active area slot 105.
- RIE reactive ion etching
- BOE buffered oxide etch
- the first conductive material 106 includes polysilicon and is deposited using CVD.
- the first conductive material 106 in next planarized stopping on the first isolation layer 104 as shown in Figure IB.
- the first conductive material is planarized using any suitable technique such as, for example, chemical mechanical planarization (CMP) or, alternatively, a blanket dry etch process.
- CMP chemical mechanical planarization
- a second isolation layer 108 is formed over the first conductive material 106.
- the second isolation layer 108 can include an oxide layer 108 deposited using any suitable oxidation technique, e.g. thermal oxidation or CVD process.
- the second isolation layer 108 can include a silicon nitride (Si 3 N 4 ) layer 108 formed by CVD.
- the structure is now as is shown in Figure IB.
- Figure lC-1 illustrates the structure following the next series of process steps.
- a photoresist is applied and selectively exposed to pattern where a second opening 110, contact opening 110, or bitline opening 110, is to be formed in the first conductive material 106 over a source region in the substrate.
- forming the second opening 110 in the first conductive material will constitute a bitline region 110 for a transistor.
- the second isolation layer 108 is then removed using any suitable process such as, for example, RIE.
- the etch process is continued so that the second opening 110, or contact opening 110, continues into the first conductive material 106.
- the first conductive material is etched also using an RIE process.
- Forming the second opening 110 in the first conductive material 106 includes exposing portions of an adjacent pair 109 of the multiple surface structures 102. In one embodiment the first conductive material 106 is etched beneath the top surfaces of the adjacent pair
- Figure 1C-2 is a top view of the cross sectional representation shown in Figure lC-1.
- the first opening 105, or active area slot 105, and subsequent steps from Figure 1A covered the entire active area of an adjacent pair 109 of the multiple surface structures.
- the adjacent pair 109 of multiple surface structures includes an adjacent pair of wordlines and their surrounding spacers 109.
- the second opening 110, or contact opening 110 overlaps into alternating slot regions, shown in Figure 1C-2 as 115-1, 115-2, 115-3, . . ., 115- N.
- Figure 1C-3 is a top view of a peripheral section 119 of the substrate 100 shown in Figure 1C-2. As shown in Figure 1C-3, a first conductive material 106 has also been formed in a number of strip first openings 105 formed on the peripheral section 119 of the substrate 100.
- Figure ID illustrates the structure after the next group of processing steps.
- the photoresist is stripped using conventional photoresist stripping techniques.
- Spacers 112 are then formed on the interior walls of the second opening 110.
- the spacers 112 are formed by depositing an insulator material, such as silicon dioxide (SiO 2 ) or silicon nitride (Si 3 N 4 ), into the second opening
- the insulator material is deposited using any suitable technique, e.g., CVD.
- the insulator material is then directionally etched leaving spacers 112 formed only on the interior walls.
- Forming spacers 112 on the interior walls of the second opening 110 includes separating the first conductive material into an inner plug 111 beneath and between the adjacent pair 109.
- Forming spacers 112 on the interior walls further includes separating the first conductive material 106 into a pair of outer plugs 113.
- the outer plugs 113 also cover portions of the top surfaces of the adjacent pair 109.
- forming the inner plug 111 constitutes forming a bitline plug 111.
- forming the pair of outer plugs 113 constitutes forming a pair of storage node plugs 113.
- the structure is now as appears in Figure ID.
- Figure IE illustrates the structure after the next sequence of fabrication steps.
- a second conductive material 120 is formed in the second opening 110.
- forming the second conductive material 120 includes forming a bitline 120.
- the second conductive material 120 includes an alloy formed from a refractory metal-polysilicon salicidation process. Such salicidation processes and other metallization techniques are understood by one practicing in the field of semiconductor fabrication and thus are not recited here.
- the second conductive material 120 includes polysilicon deposited using a CVD process.
- a subsequent isolation layer, or bitline isolation layer 124 is formed using conventional techniques to isolate, or bury, the second conductive material 120 as well as to provide a surface upon which further metallization layers and semiconducting layers can be fabricated.
- the technique for doing the same do not form part of the present inventive structure and thus are not presented herein. Such techniques will be understood, however, upon reading this description by one practicing in the field of semiconductor fabrication. The structure is now as is illustrated in Figure IE.
- FIG. IF an exemplary embodiment of the structure is illustrated with the third isolation layer 126 formed. Additionally, contact regions 130, or contact openings 130, have been fabricated according to conventional semiconductor fabrication steps. The contact openings 130 provide a clearer illustration of the manner by which the larger surface area of the pair of outer plugs allows for significantly improved alignment tolerances. In example, the method and structure easily facilitate forming electrical contacts or capacitor storage nodes after the forming of a buried bitline 120 in an IGFET.
- Figure 2 is a cross-sectional view which illustrates an embodiment of an integrated circuit device 250, or memory device 250, according to the teachings of the present invention.
- the structure includes a substrate 200 with a number of semiconductor surface structures 202 spaced apart along the substrate 200.
- the substrate 200 includes a doped silicon structure.
- the substrate 200 includes an insulator layer.
- the substrate 200 may include a body region of single crystalline silicon (Si) which has been doped with a p-type dopant to form a p-type body region.
- the substrate 200 would then also consist of a first source/drain region and a second source/drain region in that substrate 200 which have been doped with an n-type dopant to form n- type source/drain regions.
- the doping types in the components just mentioned can be reversed to create alternate conduction methods in the substrate.
- the number of semiconductor surface structures include isolated wordlines 202 running along the surface of the substrate.
- the number of semiconductor surface structures include isolated flash memory cells 202.
- the number of plugs 206 include polysilicon plugs.
- the number of plugs include an inner plug 206B and a pair of outer plugs, or outer pair 206 A and 206C.
- the inner plug 206B includes a bitline plug and is formed beneath a top surface of the number of semiconductor surface structures 202.
- the pair of outer plugs 206A and 206C include storage node plugs 206A and 206C.
- Each one of the outer pair, 206A and 206C is formed adjacent to and on opposing sides of the inner plug 206B.
- each of the outer pair, 206A and 206C includes an upper portion 207. The upper portions 207 cover areas of the surface structures 202.
- an inner electrical contact 220 couples to the inner plug 206B.
- the inner electrical contact 220 includes a buried bitline 220.
- the inner electrical contact 220 is separated from the upper portions 207 of the outer pair, 206A and 206C, by a pair of opposing spacers 212.
- the pair of opposing spacers 212 includes a pair of opposing silicon dioxide (SiO 2 ) spacers 212.
- the pair of opposing spacers includes a pair of opposing silicon nitride (Si 3 N 4 ) spacers 212.
- the integrated circuit device 250 includes a pair of outer contact regions 230 which can include storage nodes 230, or storage node contacts formed from any suitable material. Likewise, the pair of outer contact regions 230 can include tapered electrical contacts 230 formed from any suitable metallization material. The contact regions 230 each individually couple to the one of the pair of outer plugs 206A and 206C through an isolation layer 226.
- the integrated circuit device 250 can, in one embodiment, include a dynamic random access memory (DRAM). And, in an alternate embodiment, the integrated circuit device 250 includes a synchronous random access memory (SRAM) or even an electronically erasable programmable read only memory (EEPROM).
- DRAM dynamic random access memory
- EEPROM electronically erasable programmable read only memory
- FIG 3 is a block diagram illustrating an data handling system 300 according to an embodiment of the present invention.
- data handling system includes a central processing unit (CPU) 304.
- the CPU 304 is communicatively coupled to a memory device 330 by a system bus 310.
- the memory device includes the memory device provided and described above in connection with Figure 2.
- CPUs 304 and system buses 310 are well known to those of ordinary skill in the art. These CPUs 304 and system buses 310 are commercially available in many suitable forms for implementation with the present invention. Those skilled in the art will recognize and be able to employ such suitable devices with the present invention. As such, a detailed description of these CPUs 304 and system buses 310 is not provided here.
- the invention discloses a novel method for forming individual plug contacts with increased surface area for improved registration between semiconducting layers. Also the improved plug contacts are particularly well suited to receiving contact formations which have any taper to them. IGFETS and other devices formed from this design can be used in a variety of beneficial applications, e.g. logic or memory.
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- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Internal Circuitry In Semiconductor Integrated Circuit Devices (AREA)
- Semiconductor Memories (AREA)
Abstract
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2000566883A JP2002523899A (en) | 1998-08-25 | 1999-08-25 | Method and structure for improving the alignment tolerance of multiple specialized plugs |
AU59018/99A AU5901899A (en) | 1998-08-25 | 1999-08-25 | Method and structure for improved alignment tolerance in multiple, singularized plugs |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/140,810 US6066552A (en) | 1998-08-25 | 1998-08-25 | Method and structure for improved alignment tolerance in multiple, singularized plugs |
US09/140,810 | 1998-08-25 | ||
US09/255,962 US6323557B1 (en) | 1998-08-25 | 1999-02-23 | Method and structure for improved alignment tolerance in multiple, singulated plugs |
US09/255,962 | 1999-02-23 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2000011712A1 true WO2000011712A1 (en) | 2000-03-02 |
WO2000011712A9 WO2000011712A9 (en) | 2000-09-08 |
Family
ID=26838500
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1999/019567 WO2000011712A1 (en) | 1998-08-25 | 1999-08-25 | Method and structure for improved alignment tolerance in multiple, singularized plugs |
Country Status (3)
Country | Link |
---|---|
JP (1) | JP2002523899A (en) |
AU (1) | AU5901899A (en) |
WO (1) | WO2000011712A1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7338867B2 (en) | 2003-02-17 | 2008-03-04 | Samsung Electronics Co., Ltd. | Semiconductor device having contact pads and method for manufacturing the same |
US7473512B2 (en) | 2004-03-09 | 2009-01-06 | Az Electronic Materials Usa Corp. | Process of imaging a deep ultraviolet photoresist with a top coating and materials thereof |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009176819A (en) * | 2008-01-22 | 2009-08-06 | Elpida Memory Inc | Semiconductor device and manufacturing method thereof |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4445796A1 (en) * | 1993-12-21 | 1995-06-22 | Hyundai Electronics Ind | Semiconductor device contg. MOSFET |
US5451546A (en) * | 1994-03-10 | 1995-09-19 | National Semiconductor Corporation | Masking method used in salicide process for improved yield by preventing damage to oxide spacers |
-
1999
- 1999-08-25 WO PCT/US1999/019567 patent/WO2000011712A1/en active IP Right Grant
- 1999-08-25 JP JP2000566883A patent/JP2002523899A/en active Pending
- 1999-08-25 AU AU59018/99A patent/AU5901899A/en not_active Abandoned
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4445796A1 (en) * | 1993-12-21 | 1995-06-22 | Hyundai Electronics Ind | Semiconductor device contg. MOSFET |
US5569948A (en) * | 1993-12-21 | 1996-10-29 | Hyundai Electronics Industries Co., Ltd. | Semiconductor device having a contact plug and contact pad |
US5451546A (en) * | 1994-03-10 | 1995-09-19 | National Semiconductor Corporation | Masking method used in salicide process for improved yield by preventing damage to oxide spacers |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7338867B2 (en) | 2003-02-17 | 2008-03-04 | Samsung Electronics Co., Ltd. | Semiconductor device having contact pads and method for manufacturing the same |
US7511340B2 (en) | 2003-02-17 | 2009-03-31 | Samsung Electronics Co., Ltd. | Semiconductor devices having gate structures and contact pads that are lower than the gate structures |
US7473512B2 (en) | 2004-03-09 | 2009-01-06 | Az Electronic Materials Usa Corp. | Process of imaging a deep ultraviolet photoresist with a top coating and materials thereof |
Also Published As
Publication number | Publication date |
---|---|
WO2000011712A9 (en) | 2000-09-08 |
AU5901899A (en) | 2000-03-14 |
JP2002523899A (en) | 2002-07-30 |
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