WO1997018077A1 - Method and device for the production of convex shells made of polystyrene foam - Google Patents
Method and device for the production of convex shells made of polystyrene foam Download PDFInfo
- Publication number
- WO1997018077A1 WO1997018077A1 PCT/EP1996/004942 EP9604942W WO9718077A1 WO 1997018077 A1 WO1997018077 A1 WO 1997018077A1 EP 9604942 W EP9604942 W EP 9604942W WO 9718077 A1 WO9718077 A1 WO 9718077A1
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- WIPO (PCT)
- Prior art keywords
- blank
- blanks
- male
- station
- female
- Prior art date
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/34—Auxiliary operations
- B29C44/56—After-treatment of articles, e.g. for altering the shape
- B29C44/5627—After-treatment of articles, e.g. for altering the shape by mechanical deformation, e.g. crushing, embossing, stretching
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B11/00—Making preforms
- B29B11/02—Making preforms by dividing preformed material, e.g. sheets, rods
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/34—Auxiliary operations
- B29C44/56—After-treatment of articles, e.g. for altering the shape
- B29C44/5627—After-treatment of articles, e.g. for altering the shape by mechanical deformation, e.g. crushing, embossing, stretching
- B29C44/5654—Subdividing foamed articles to obtain particular surface properties, e.g. on multiple modules
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C51/00—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
- B29C51/02—Combined thermoforming and manufacture of the preform
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C33/00—Moulds or cores; Details thereof or accessories therefor
- B29C33/56—Coatings, e.g. enameled or galvanised; Releasing, lubricating or separating agents
- B29C33/60—Releasing, lubricating or separating agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C51/00—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
- B29C51/08—Deep drawing or matched-mould forming, i.e. using mechanical means only
- B29C51/082—Deep drawing or matched-mould forming, i.e. using mechanical means only by shaping between complementary mould parts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2025/00—Use of polymers of vinyl-aromatic compounds or derivatives thereof as moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/04—Condition, form or state of moulded material or of the material to be shaped cellular or porous
Definitions
- the invention relates to a method for producing domed trays, in particular sales trays, from polystyrene foam.
- curved shells are to be understood as plate-like and bowl-like vessels, such as are used for example for packaging purposes, fast food, covers and insulating parts. Meat products in particular are sold on such trays.
- Curved shells are currently known which are mainly produced by the following manufacturing processes:
- Shells made of extruded polystyrene foam have skin on both main surfaces. Because of the resulting good seal against water and other non-pyrolytic liquids, they are widely used. They are made from a sheet of film by deep drawing and deformation under heat and pressure. However, a foam process that uses CFC gases is used for the raw material during manufacture. This leads to considerable ecological criticism. Many retailers therefore no longer use these packaging trays. The production price for the production of the web film is also associated with a very high investment. Since the extruder should also work as continuously as possible, this leads to high capital expenditure. Molded polystyrene foam trays
- Such foam trays are foamed in individual forms. They have a surface which consists of many contiguous polystyrene beads, but which is not closed-pore. In particular, moisture and secretions, such as blood, of the product to be packaged penetrate into the spaces between the beads, which gives rise to hygienic and aesthetic concerns.
- the production of sales trays in polystyrene single foam molds is very complex. Each shell must be manufactured individually by blowing in a multiple mold.
- the polystyrene beads are provided with a blowing agent, for example pentane. In the expanded form, the polystyrene becomes soft enough at a temperature of about 100 ° C. so that it expands due to the evaporation of the pentane. After the blowing process, the metal molds have to be cooled again in order to remove the polystyrene shell.
- This known method does result in packaging trays which are satisfactory in terms of packaging technology. However, it is energy-intensive to use and also expensive to invest.
- the process is therefore based on the energetically favorable block foaming technique, in which first a block, for example with dimensions of 1 x 1 x 1 m, or a cylinder, for example with a length of 3 m and a diameter of 3 m, is made of polystyrene that adheres Beads are made in a mold using a blowing agent at a temperature above 80 ° C. The block cools and is cut into individual plate-shaped blanks with a visible cut of the polystyrene beads located on the cut surface of the blank.
- the cooled foam cylinder is processed into one or more sheet-like blanks in the peeling process. These peeled, web-shaped blanks are then available as rolls for further continuous processing.
- the blank web can also be flattened into individual blanks after step c.
- cut blanks are preferably wetted on both opposite main surfaces with a release agent before the intermediate product plate is briefly heated at at least 125 ° C. by contacting and gently pressing both flat sides of the blank.
- a surface fusion and surface smoothing are formed in that the cut-off foam spheres form a fusion skin.
- This intermediate product plate which has already been sealed on the surface, is then deformed and punched out in a form formed from a heated male and female mold.
- the surface of the blanks is changed by the initially flat contact heating in contrast to the radiation heating so that the individual cut polystyrene beads fuse together and form a compacted mass on the surface of the plate.
- This effect can also be called “smoothing".
- the pores of the foams essentially close and optically form a closed surface on the surface, the cell structure present in the plate blank being homogenized.
- a waterproof or water-repellent surface is formed.
- the flat stamp surface for the plate-shaped blanks has a temperature of at least 110 ° C., preferably between 120 ° and 160 ° C.
- the contact time should be between 0.1 and 10 s, preferably between 0.5 and 1.5 s to get the highest possible production rate in the time unit.
- the deformation in the form formed from a heated male and female mold into a sales tray should be carried out at a temperature between 100 ° and 300 ° C., preferably between 165 ° and 185 ° C.
- the pressure exerted on the blanks should be between 1 10 s and 2-10 s Pa.
- the blanks or the blank web can be laminated on their flat side with a film web before being shaped into a shell.
- a thin, extruded polystyrene foam sheet is preferably suitable for this purpose, and can only be connected to the blank directly by thermal melting of the blank, without an additional adhesive layer.
- the film web should consist essentially of polystyrene and at least on its side that comes into contact with the blank.
- the melted, optionally laminated blanks are formed into a shell in a shaping station at a temperature between 100 ° and 300 ° C., preferably between 165 ° and 185 ° C.
- This packaging shell made from the laminated blank can even be watertight.
- a vapor-tight shell can also be produced by laminating a polystyrene aluminum foil. Also one Foil consisting essentially or purely of aluminum can be fused with a polystyrene blank or with the blank web.
- Release agents are usually used in the individual molding steps, as are customary for the pressing of polystyrene sheets. This is intended to reduce adhesion forces between the metal mold surface and the polystyrene foam surface. Silicones in the form of oils and oil emulsions in water are suitable for this. Metal soaps are also suitable, the latter also being used in particular since they are harmless to food.
- the liquid release agent is applied to the unpressed main surfaces by spraying. A part of the release agent is transferred to the mold surface, so that multiple press passes are usually possible with one release agent spray.
- the invention further relates to a device for producing curved trays, in particular sales trays, with the following individual parts:
- a pressing station which has a heatable stamp with flat stamp surfaces
- a deformation station each with an exchangeable, heated patrix and die, the deforming surface of which are compatible with one another, with a mold cavity remaining when the patrix and die are moved together,
- Figure la is a schematic representation of an inventive device in side view.
- FIG. 1b the device according to FIG. 1a with a blank web and foil feed
- FIG. 2 shows the device according to FIG. 1b seen from above, but with a blank stacking container
- FIG. 3 shows a schematic illustration of a deformation station
- FIG. 4 shows a perspective view of a sales tray manufactured according to the principle of the invention
- FIGS. 1 a, 1 b and 2 A device 100 for producing packaging trays 10 is shown in FIGS. 1 a, 1 b and 2.
- polystyrene foam blanks 1.1. ... ln cut out from a deposited foam block (not shown) in a disk-like manner.
- the foam disks or blanks 1.1 ... ln have a small thickness of approximately 4.0 mm and a size of 750 x 750 mm.
- the polystyrene foam blanks are stacked in one of the open, rectangular blank stack containers 2.
- the container 2 has two slots 3, 3 '. Through a slot 3, a sliding plate 4 always presses the lowest polystyrene foam blank cyclically with a piston-cylinder Arrangement 5 working horizontally through the other slot 3 'to the outside.
- the polystyrene foam blank leaving the container 2 is always shifted further in the course of the manufacturing process on the shifting plane (E) of a shifting table 6 in the rhythm of the cyclically driven units.
- the units described below are arranged along the sliding table 6 in technological order: a spray device 7, a press station 8 and a deformation station 9.
- the task of the spray device 7 is to uniformly wet the two surfaces of the polystyrene foam blanks 1.1... Ln with a release agent 11, for example with silicone oil.
- the spray device 7 consists of an upper and a lower spray chamber 12 and 12 ', which are each equipped with a pulse generator 13 and 13'.
- the two spray chambers 12, 12 ' are preferably arranged one above the other in a space-saving manner, although it is also possible to keep a distance between the spray chambers 12, 12'.
- the press station 8 has two smooth stamps 14,. 14 ', of which the lower 14' is provided with a perforation (not shown) for the purpose of sucking and locking the blanks.
- the locking is controlled by means of a vacuum pump 15.
- the heatable stamps 14, 14 ' consist of hardened steel or brass, and are coated on the sides facing the blank (stamp surfaces 39, 39') with an anti-adhesive, e.g. PTFE, coated.
- the subsequent deformation station 9 has two heatable metal molds 17, 17 ', the upper of which
- the deformation station 9 also has a rectangular frame 20 in which the two metal shapes, i.e. Die 17 and male 37, are attached to a piston rod 21 and correspondingly 21 'interchangeably. The shape of the male and female molds then gives the desired product shape.
- Fig. Lb shows a polystyrene foam blank sheet 111, which has been peeled out of a deposited foam cylinder (not shown) in a spiral.
- the blank web 111 has a small thickness of approximately 3.5 mm and a width of 600 mm. It is pushed forward by means of a drive roller 113.
- the blank web is always shifted further on the shifting plane (E) of a shifting table 6 in the rhythm of the cyclically driven units.
- the assemblies described below are arranged along the sliding table 6 in technological order: a spray device 7, a cutting station 112, a pressing station 8 and a deformation station 9.
- the spray device 7 is preceded by a film supply roll 29, which is arranged under the sliding table 6, from which a film web 27 is 1 motor 26 and a compensation device 31 is deducted.
- the compensating device 31 consists of deflection rollers 32, 32 'and a dance roller 33 which compensates for the tension differences of the film to be wound and always has a film supply available.
- the press station 8 the polystyrene foam blank sheet is laminated on one side, over the entire area with the film sheet, ie, is melted flat without adhesive, 10 if necessary with the omission of partial areas.
- the task of the spray device 7 is to uniformly wet the two surfaces of the polystyrene foam blank web 111 with a release agent 11, for example with silicone oil.
- the spray device 7 consists of an upper and a lower spray chamber 12 and 12 ', which are each equipped with a pulse generator 13 and 13'.
- the spray device 7 is followed by a separation station 112, which the Rohlmgs-
- a press station 8 which corresponds to that in FIG.
- the press station 8 has two smooth stamps 14,. 14 ', of which the
- the subsequent deformation station 9 has two
- the deformation station 9 also has a rectangular frame 20 in which the
- the die 17 and the die 37 are designed as heatable metal plates 22 and 22 ', optionally made of hardened steel, which are particularly suitable for a longer production run. Both the troughs 18 and the bulges 19 are provided with a wafer-thin layer of silicone oil.
- the troughs 18 and bulges are also provided with a thin elastomer layer, it being possible for at least the trough surface to be provided with a pattern in relief, for example with the brand of the manufacturer or user.
- the device 100 includes a collecting grid 30 which can be shifted to the side (cf. FIG. 2) and transversely to the direction of displacement (arrows X) in the deformation station 9.
- the bottom polystyrene foam blank 1.1 ... ln is ejected from the blank stack container 2 with the help of the sliding plate 4 through the slot 3 'in the direction of the shift table 6 and passed on to the spray device 7. There, the blanks are sufficiently wetted on both sides with a silicone oil as a release agent so that they do not adhere to the heating plates in the next processing stages.
- a food-grade composition for example an aqueous oil emulsion or a metal soap, can also be used as the non-stick agent.
- the blank provided with release agent then passes under the metal plates 14 and 14 'of the pressing station 8.
- the pressing process takes approximately 0.8 s at a temperature of the metal plates of 170 ° C. at a pressure of 1.25 10 * Pa.
- both surface areas 41 of the blanks are melted and homogenized uniformly in such a way that the pores and interspaces between the foam spheres are completely closed. In this way, a smooth intermediate product plate 40 or 40 '(with film) is produced, from which various shell-like products can be produced.
- the intermediate product plates reach the shaping station 9, where they are also briefly embossed, in this case for 0.9 s at a temperature (in the contact area with the female 17 and male 37) of approximately 180 ° C. and under pressure of about 1.4-10 s Pa.
- Sales trays 10 thus produced are punched out simultaneously during the hot stamping process by circumferential cutting 25 with which the male part 37 is provided.
- the contact surfaces 35, 35 'through the supply lines 24 and bores 23 are supplied with compressed air, whereby the compressed air is first supplied to the male 37, so that the upper female 17 still holds the packaging trays until Approaching a starting grid 30 which is arranged to be displaceable under the shifting plane E and moving the male part out of the preforming station.
- the punched-out sales trays 10 fall onto the collecting grid 30.
- the catch grid 30 and the male part 37 are displaced by means of transverse to the direction of displacement (arrows X)
- Foil supply roll 29 is pulled off a foil web 27 by means of the electric motor 26 and compensating device 31 and fed to the pressing station 8 via the spraying device 7.
- Particularly suitable as film material are all thermoplastically deformable films, including films made of pure aluminum or laminated with aluminum, in which the film web consists at least on its side that comes into contact with the blank from polystyrene.
- the tests carried out by the applicant with an extruded thin polystyrene foam film have proven to be promising.
- the polystyrene foam film is easy to deform thermally, is characterized by a silky gloss surface structure and is suitable for food.
- the film section lying against the foam blank is sucked in by means of a vacuum pump 15 and thus locked. After the 5 contact surfaces of the foam blank and the film have melted together, the excess film piece is cut off in the cutting station 34. All operations described above are coordinated with each other.
- the parameters, such as foam blank density and thickness, pressing force, temperatures and time, can be programmed and changed, so that the process can be optimally controlled with the aid of a computer.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
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- Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
- Laminated Bodies (AREA)
- Shaping Of Tube Ends By Bending Or Straightening (AREA)
Abstract
The invention relates to a method and a device for the production of convex shells (2), in particular food shells made of polystyrene foam. The method comprises the following steps: (a) cutting a foam block into individual blanks shaped like plates or strips (1.1 ...1.n); (b) mounting and moving the blanks in a row on a horizontal plane (E); (c) producing an intermediate plate from a blank by contacting and lightly pressing both flat surfaces of the blank each with with a heated, flat pressure surface (14, 14') to achieve superficial melting; (d) shaping the intermediate plate in a mould formed from a heated top die (20) and bottom die (22') to form a food shell; (e) ejection or removal of the food shell.
Description
VERFAHREN UND VORRICHTUNG ZUR HERSTELLUNG VON GEWÖLBTEN SCHALEN AUS POLYSTYROL-SCHAUMSTOFFMETHOD AND DEVICE FOR PRODUCING CURVED SHELLS FROM POLYSTYRENE FOAM
Die Erfindung betrifft ein Verfahren zur Herstellung von gewölbten Schalen, insbesondere Verkaufsschalen, aus Polystyrol-Schaumstoff.The invention relates to a method for producing domed trays, in particular sales trays, from polystyrene foam.
Unter den genannten gewölbten Schalen sollen teller- und schusselartige Gefäße verstanden werden, wie sie bei¬ spielsweise für Verpackungszwecke, Fastfood, Abdeckungen und Isolierteile verwendet werden. Insbesondere Fleisch¬ waren werden auf derartigen Schalen verkauft.The above-mentioned curved shells are to be understood as plate-like and bowl-like vessels, such as are used for example for packaging purposes, fast food, covers and insulating parts. Meat products in particular are sold on such trays.
Es sind derzeit gewölbte Schalen bekannt, die im wesent¬ lichen nach folgenden Herstellungsverfahren produziert werden:Curved shells are currently known which are mainly produced by the following manufacturing processes:
Schalen aus extradiertem PolystyrolschaumExtruded polystyrene foam trays
Schalen aus extrudiertem Polystryrolschaum besitzen auf beiden Hauptflachen eine Haut. Wegen der sich daraus ergebenden guten Dichtigkeit gegen Wasser und andere nicht-styrollosende Flüssigkeiten sind sie in weitem Einsatz. Sie werden aus einer Bahnfolie hergestellt durch Tiefziehen und Verformung bei Hitze und Druck. Allerdings wird für das Rohmaterial bei der Herstellung ein Schaumprozeß angewandt, der FCKW-Gase einsetzt. Dies fuhrt zu einer erheblichen ökologischen Kritik. Viele Handler setzen daher diese Verpackungsschalen nicht mehr ein. Auch ist der Erstellungspreis zur Herstellung der Bahnfolie mit einer sehr hohen Einsatz-Investition verbunden. Da außerdem auch noch der Extruder möglichst ununterbrochen arbeiten soll, fuhrt dies zu einem hohen Kapitalaufwand.
Schalen aus formgeschäumtem PolystyrolschaumShells made of extruded polystyrene foam have skin on both main surfaces. Because of the resulting good seal against water and other non-pyrolytic liquids, they are widely used. They are made from a sheet of film by deep drawing and deformation under heat and pressure. However, a foam process that uses CFC gases is used for the raw material during manufacture. This leads to considerable ecological criticism. Many retailers therefore no longer use these packaging trays. The production price for the production of the web film is also associated with a very high investment. Since the extruder should also work as continuously as possible, this leads to high capital expenditure. Molded polystyrene foam trays
Derartige Schaumstoffschalen werden in Einzelformen auf¬ geschäumt. Sie besitzen eine aus vielen zusammenhängen¬ den Polystyrolkügelchen bestehende Oberfläche, die jedoch nicht geschlossenporig ist. Insbesondere Feuch¬ tigkeit und Sekrete, wie Blut, des zu verpackenden Pro¬ duktes dringen in die Zwischenräume zwischen den Perlen ein, was zu hygienischen und ästhetischen Bedenken Anlaß gibt. Überdies ist die Herstellung von Verkaufsschalen in Polystyrol-Einzelschäumformen sehr aufwendig. Jede Schale muß einzeln dadurch hergestellt werden, daß in einer Mehrfachform ein Blähvorgang erfolgt. Die Poly- styrol-Perlen sind mit einem Treibmittel, beispielsweise Pentan, versehen. In der Blähform wird bei einer Tempera¬ tur von etwa 100° C das Polystyrol weich genug, so daß es sich durch das verdampfende Pentan aufbläht. Nach dem Blähvorgang müssen die Metallformen wieder abgekühlt werden, um die Polystyrol-Schale entnehmen zu können. Dieses bekannte Verfahren ergibt zwar verpackungstech¬ nisch befriedigende Verpackungsschalen. Es ist jedoch in der Anwendung energieaufwendig und von der Investition her auch teuer.Such foam trays are foamed in individual forms. They have a surface which consists of many contiguous polystyrene beads, but which is not closed-pore. In particular, moisture and secretions, such as blood, of the product to be packaged penetrate into the spaces between the beads, which gives rise to hygienic and aesthetic concerns. In addition, the production of sales trays in polystyrene single foam molds is very complex. Each shell must be manufactured individually by blowing in a multiple mold. The polystyrene beads are provided with a blowing agent, for example pentane. In the expanded form, the polystyrene becomes soft enough at a temperature of about 100 ° C. so that it expands due to the evaporation of the pentane. After the blowing process, the metal molds have to be cooled again in order to remove the polystyrene shell. This known method does result in packaging trays which are satisfactory in terms of packaging technology. However, it is energy-intensive to use and also expensive to invest.
Weiterhin ist aus der US-PS 4,239,727 bekannt, Gefäße aus einer vorgewärmten Schaumstoff-Folienbahn in einer aus einer beheizten Patrize und Matrize gebildeten Form herzustellen.Furthermore, it is known from US Pat. No. 4,239,727 to produce vessels from a preheated foam sheet in a form formed from a heated male and female mold.
Ferner ist aus der DE-AS 22 12 355 bekannt, die Ober¬ fläche von Rohlingen aus Polystyrol durch ein bis zur Temperatur von mindestens 500°C erhitztes Werkzeug zu glätten. Dies bezieht sich allerdings auf rauhe Oberflächen, die durch spannabhebende Bearbeitung von Kunststoffen entsteht.It is also known from DE-AS 22 12 355 to smooth the surface of blanks made of polystyrene using a tool heated up to a temperature of at least 500 ° C. However, this refers to rough surfaces that result from the machining of plastics.
Es stellt sich daher die Aufgabe, ein Verfahren zur
Herstellung von Verpackungsschalen aus Polystyrol-Schaum¬ stoff anzugeben, bei dem nicht in Einzelformen geschäumt werden muß und bei dem sich trotzdem eine weitgehend geschlossenporige und verschmolzene Oberfläche an der Schalenoberfläche ergibt, die vom verpackungstechnischen Standpunkt her wesentlich besser ist als eine offen¬ porige Verkaufsschale.It is therefore the task of a process for Manufacture of packaging trays made of polystyrene foam, which does not have to be foamed in individual molds and which nevertheless results in a largely closed-pore and fused surface on the tray surface, which is much better from the point of view of packaging technology than an open-pore sales tray.
Diese Aufgabe wird gelöst bei einem Verfahren der eingangs genannten Art, das folgende Verfahrensschritte besitzt:This object is achieved with a method of the type mentioned at the outset, which has the following method steps:
(a) Zerschneiden von Schaumstoff-Blöcken in einzelne plattenförmige Rohlinge oder eine Rohlingsbahn;(a) cutting foam blocks into individual plate-shaped blanks or a blank web;
(b) Auflegen und Verschieben der Rohlinge oder der Roh¬ lingsbahn auf einer horizontalen Ebene, sowie gegebe¬ nenfalls Ablängen der Rohlingsbahn zu einzelnen Rohlingen;(b) placing and shifting the blanks or the blank web on a horizontal plane and, if appropriate, cutting the blank web to individual blanks;
(c) Herstellen von Zwischenproduktplatten aus den Rohlingen durch Ausüben eines Druckes auf die beiden Flachseiten des Rohlings mit je einer erhitzten, flachen Stempelfläche, wobei die kontaktierten Bereiche des Rohlings erweicht und oberflächlich verschmolzen werden;(c) producing intermediate product plates from the blanks by exerting pressure on the two flat sides of the blank, each with a heated, flat stamp surface, the contacting regions of the blank being softened and superficially fused;
(d) Verformen der Zwischenproduktplatten in einer auε einer beheizten Patrize und Matrize gebildeten Form zu den Schalen, im wesentlichen unter Beibehaltung des Volumens der Zwischenproduktplatte;(d) shaping the intermediate product plates in a form formed from a heated male and female mold to form the shells, essentially while maintaining the volume of the intermediate product plate;
(e) Ausstoßen oder Entnehmen der Schalen.(e) ejecting or removing the shells.
Man geht daher bei dem Verfahren von der energetisch günstigen Block-Schäumtechnik aus, bei dem zunächst ein Block, beispielsweise der Abmessungen 1 x 1 x 1 m , oder ein Zylinder, beispielsweise von 1 m Länge und 3 m Durchmesser, aus untereinander haftenden Polystyrol- Perlen mit Hilfe eines Treibmittels bei einer Temperatur oberhalb von 80° C in einer Form hergestellt wird. Der
Block kühlt ab und wird in einzelne plattenförmige Roh¬ linge mit sichtbarem Anschnitt der sich an der Schnitt¬ flache des Rohlings befindenden Polystyrol-Perlen zer¬ schnitten.The process is therefore based on the energetically favorable block foaming technique, in which first a block, for example with dimensions of 1 x 1 x 1 m, or a cylinder, for example with a length of 3 m and a diameter of 3 m, is made of polystyrene that adheres Beads are made in a mold using a blowing agent at a temperature above 80 ° C. The The block cools and is cut into individual plate-shaped blanks with a visible cut of the polystyrene beads located on the cut surface of the blank.
Der abgekühlte Schaumstoff-Zylinder wird hingegen zu einem oder mehreren bahnförmigen Rohlingen im Schälver¬ fahren verarbeitet. Diese geschälten, bahnförmigen Roh¬ linge stehen dann als Rollen für eine weitere kontinuier¬ liche Verarbeitung zur Verfugung. Dabie kann das Ablan¬ gen der Rohlingsbahn in einzelne Rohlinge auch nach Schritt c erfolgen.The cooled foam cylinder, on the other hand, is processed into one or more sheet-like blanks in the peeling process. These peeled, web-shaped blanks are then available as rolls for further continuous processing. The blank web can also be flattened into individual blanks after step c.
Diese zugeschnittenen Rohlinge werden vorzugsweise auf beiden sich gegenüberliegenden Hauptflächen mit einem Trennmittel benetzt, bevor die Zwischenproduktplatte durch Kontaktieren und leichtes Drücken beider Flach¬ seiten des Rohlings bei mindestens 125° C kurzzeitig erhitzt wird. Dabei bildet sich eine Oberflächenver¬ schmelzung und Oberflachenglättung, indem die angeschnit¬ tenen Schaumstoffkügelschen eine Verschmelzungshaut bilden. Diese bereits oberflächlich gedichtete Zwischen¬ produktplatte wird dann in einer aus einer beheizten Patrize und Matrize gebildeten Form verformt und ausge¬ stanzt.These cut blanks are preferably wetted on both opposite main surfaces with a release agent before the intermediate product plate is briefly heated at at least 125 ° C. by contacting and gently pressing both flat sides of the blank. A surface fusion and surface smoothing are formed in that the cut-off foam spheres form a fusion skin. This intermediate product plate, which has already been sealed on the surface, is then deformed and punched out in a form formed from a heated male and female mold.
Die Oberfläche der Rohlinge wird durch die zunächst flachige Kontakterhitzung im Gegensatz zur Strahlungs¬ erhitzung so verändert, daß die einzelnen angeschnitte¬ nen Polystyrol-Perlen miteinander verschmelzen und eine verdichtete Masse an der Plattenoberflache bilden. Diesen Effekt kann man auch als "Glätten" bezeichnen. Die Poren der Schaumstoffe schließen sich im wesent¬ lichen und es bildet sich optisch eine an der Oberfläche geschlossene Fläche, wobei die bei dem Plattenrohling vorhandene Zellstruktur dabei homogenisiert. Es bildet sich eine wasserdichte bzw. wasserabweisende Oberfläche.
Die flache Stempelfläche für die plattenförmigen Roh¬ linge hat eine Temperatur von wenigstens 110°C, vorzugs¬ weise zwischen 120° und 160°C. Dabei soll die Kontakt¬ zeit zwischen 0,1 bzw. 10 s, vorzugsweise zwischen 0,5 und 1,5 s liegen, um eine möglichst hohe Fertigungsrate in der Zeiteinheit zu erhalten.The surface of the blanks is changed by the initially flat contact heating in contrast to the radiation heating so that the individual cut polystyrene beads fuse together and form a compacted mass on the surface of the plate. This effect can also be called "smoothing". The pores of the foams essentially close and optically form a closed surface on the surface, the cell structure present in the plate blank being homogenized. A waterproof or water-repellent surface is formed. The flat stamp surface for the plate-shaped blanks has a temperature of at least 110 ° C., preferably between 120 ° and 160 ° C. The contact time should be between 0.1 and 10 s, preferably between 0.5 and 1.5 s to get the highest possible production rate in the time unit.
Die Verformung in der aus einer beheizten Patrize und Matrize gebildeten Form zu einer Verkaufschale sollte bei einer Temperatur zwischen 100° und 300°C, vorzugsweise zwischen 165° und 185°C durchgeführt werden.The deformation in the form formed from a heated male and female mold into a sales tray should be carried out at a temperature between 100 ° and 300 ° C., preferably between 165 ° and 185 ° C.
Der auf die Rohlinge ausgeübte Druck soll zwischen l«10sund 2-10s Pa liegen.The pressure exerted on the blanks should be between 1 10 s and 2-10 s Pa.
Ein weiterer wesentlicher Vorteil ist, daß die Rohlinge oder die Rohlingsbahn vor dem Verformen zu einer Schale noch auf auf ihrer Flachseite mit einer Folienbahn laminiert werden können. Hierzu eignet sich vorzugsweise eine dünne extrudierte Polystyrol-Schaumfolie, die direkt, ohne zusätzliche Klebschicht, nur durch die thermische Anschmelzung des Rohlings mit diesem ver¬ bunden werden kann. Dazu sollte die Folienbahn im wesentlichen und zumindest auf ihrer mit dem Rohling in Kontakt kommenden Seite aus Polystyrol bestehen.Another important advantage is that the blanks or the blank web can be laminated on their flat side with a film web before being shaped into a shell. A thin, extruded polystyrene foam sheet is preferably suitable for this purpose, and can only be connected to the blank directly by thermal melting of the blank, without an additional adhesive layer. For this purpose, the film web should consist essentially of polystyrene and at least on its side that comes into contact with the blank.
Die angeschmolzenen, gegebenenfalls laminierten Rohlinge werden in einer Verformungsstation bei einer Temperatur zwischen 100° und 300°C, vorzugsweise zwischen 165° und 185°C, zu einer Schale geformt.The melted, optionally laminated blanks are formed into a shell in a shaping station at a temperature between 100 ° and 300 ° C., preferably between 165 ° and 185 ° C.
Diese, aus dem laminierten Rohling hergestellte Ver¬ packungsschale kann sogar wasserdicht sein. Durch Auflaminieren einer Polystyrol-Aluminiumfolie kann auch eine dampfdichte Schale hergestellt werden. Auch eine
Folie, die im wesentlichen oder rein aus Aluminium besteht, läßt sich mit einem Polystyrolrohling oder mit der Rohlingsbahn verschmelzen.This packaging shell made from the laminated blank can even be watertight. A vapor-tight shell can also be produced by laminating a polystyrene aluminum foil. Also one Foil consisting essentially or purely of aluminum can be fused with a polystyrene blank or with the blank web.
In den einzelnen Formschritten werden üblicherweise Trennmittel verwendet, wie sie für das Pressen von Poly¬ styrol-Platten üblich sind. Dadurch sollen Adhäsions¬ kräfte zwischen der Metallform-Oberfläche und der Poly- styrol-Schaumflache verringert werden. Hierzu eignen sich Silikone in Form von Ölen, Ölemulsionen in Wasser. Auch Metallseifen sind geeignet, wobei letztere insbe¬ sondere auch eingesetzt werden, da sie lebensmittel¬ unbedenklich sind. Das flüssige Trennmittel wird durch Sprühen auf die ungepreßten Hauptflächen aufgebracht. Ein Teil des Trennmittels überträgt sich auf die Formen¬ oberfläche, so daß üblicherweise mit einer Trennmittel- Sprühung mehrfache Preßgänge möglich sind.Release agents are usually used in the individual molding steps, as are customary for the pressing of polystyrene sheets. This is intended to reduce adhesion forces between the metal mold surface and the polystyrene foam surface. Silicones in the form of oils and oil emulsions in water are suitable for this. Metal soaps are also suitable, the latter also being used in particular since they are harmless to food. The liquid release agent is applied to the unpressed main surfaces by spraying. A part of the release agent is transferred to the mold surface, so that multiple press passes are usually possible with one release agent spray.
Die Erfindung bezieht sich ferner auf eine Vorrichtung zur Herstellung von gewölbten Schalen, insbesondere Verkaufsschalen, mit folgenden Einzelteilen:The invention further relates to a device for producing curved trays, in particular sales trays, with the following individual parts:
- einem Verschiebetisch auf dessen Verschiebeebene plattenförmige Schaumstoff-Rohlinge oder die Rohlings¬ bahn auflegbar und verschiebbar sind,plate-shaped foam blanks or the blank sheet can be placed and displaced on a displacement table,
- einer Preßstation, die einen beheizbaren Stempel mit ebenen Stempelflächen aufweist,a pressing station which has a heatable stamp with flat stamp surfaces,
- einer Verformungsstation mit je einer auswechsel baren beheizbaren Patritze und Matrize, deren verfor¬ mende Fläche miteinander kompatibel sind, wobei in zusammengefahrenem Zustand von Patrize und Matrize ein Formhohlraum verbleibt,a deformation station, each with an exchangeable, heated patrix and die, the deforming surface of which are compatible with one another, with a mold cavity remaining when the patrix and die are moved together,
- und mit einer Ausstoßvorrichtung.- And with an ejection device.
Weitere Merkmale, die sich in weiteren Unteransprüchen finden, sind in der nachfolgenden Beschreibung erläutert.
Die Beschreibung erfolgt anhand der Zeichnung, deren Figuren zeigen:Further features that can be found in further subclaims are explained in the description below. The description is based on the drawing, the figures of which show:
Fig. la eine schematische Darstellung einer erfinderischen Vorrichtung in Seitenansicht;Figure la is a schematic representation of an inventive device in side view.
Fig. lb die Vorrichtung gemäß Fig. 1 a mit einer Rohlingsbahn- und Folienzuführung;FIG. 1b the device according to FIG. 1a with a blank web and foil feed;
Fig. 2 die Vorrichtung gemäß Fig. lb von oben gesehen, jedoch mit Rohlingsstapelbehälter;FIG. 2 shows the device according to FIG. 1b seen from above, but with a blank stacking container;
Fig. 3 eine schematische Darstellung einer Verformungs¬ station;3 shows a schematic illustration of a deformation station;
Fig. 4 eine perspektivische Ansicht auf eine nach erfindungsgemäßem Prinzip hergestellte Verkaufs¬ schale und4 shows a perspective view of a sales tray manufactured according to the principle of the invention;
Fig. 5a und 5b der Durchschnitt durch eine Zwischenprodukt¬ platte.5a and 5b the average through an intermediate product plate.
In den Figuren la, lb und 2 ist eine Vorrichtung 100 zur Herstellung von Verpackungsschalen 10 dargestellt.A device 100 for producing packaging trays 10 is shown in FIGS. 1 a, 1 b and 2.
Wie an sich bekannt, werden Polystyrol-Schaumstoff- rohlinge 1.1. ... l.n aus einem abgelagerten Schaumstoff- block (nicht dargestellt) scheibenartig herausgeschnit¬ ten. Die SchaumstoffScheiben oder -rohlinge 1.1 ... l.n haben eine geringe Dicke von etwa 4,0 mm und eine Größe von 750 x 750 mm. Die Polystyrol-Schaumstoffrohlinge werden in einem von dem offenen, rechteckigen Rohlings¬ stapelbehälter 2 gestapelt. Der Behälter 2 weist zwei Schlitze 3, 3' auf. Durch den einen Schlitz 3 drückt eine Schiebeplatte 4 immer den untersten Polystyrol- Schaumstoffrohling zyklisch mit einer Kolben-Zylinder-
Anordnung 5 arbeitend horizontal durch den anderen Schlitz 3' nach außen.As is known per se, polystyrene foam blanks 1.1. ... ln cut out from a deposited foam block (not shown) in a disk-like manner. The foam disks or blanks 1.1 ... ln have a small thickness of approximately 4.0 mm and a size of 750 x 750 mm. The polystyrene foam blanks are stacked in one of the open, rectangular blank stack containers 2. The container 2 has two slots 3, 3 '. Through a slot 3, a sliding plate 4 always presses the lowest polystyrene foam blank cyclically with a piston-cylinder Arrangement 5 working horizontally through the other slot 3 'to the outside.
Der den Behälter 2 verlassende Polystyrol-Schaumstoff- rohling wird im weiteren Verlauf des Herstellungspro- zesses immer auf der Verschiebeebene (E) eines Verschie¬ betisches 6 im Rhythmus der zyklisch angetriebenen Aggregate weiter verschoben. Die im folgenden beschrie¬ benen Aggregate sind längs des Verschiebetisches 6 in technologischer Reihenfolge angeordnet: eine Sprühvor¬ richtung 7, eine Preßstation 8 und eine Verformungs¬ station 9.The polystyrene foam blank leaving the container 2 is always shifted further in the course of the manufacturing process on the shifting plane (E) of a shifting table 6 in the rhythm of the cyclically driven units. The units described below are arranged along the sliding table 6 in technological order: a spray device 7, a press station 8 and a deformation station 9.
Aufgabe der Sprühvorrichtung 7 ist es, die beiden Oberflächen der Polystyrol-Schaumstoffrohlinge 1.1 ... l.n mit einem Trennmittel 11 gleichmäßig zu benetzen, beispielsweise mit Silikonöl. Die Sprühvorrichtung 7 besteht aus einer oberen und einer unteren Sprühkammer 12 und 12', die entsprechend mit je einem Impulsgeber 13 und 13' ausgestattet sind. Vorzugsweise platzsparend sind die beiden Sprühkammern 12, 12' übereinander ange¬ ordnet, obwohl es auch möglich ist, zwischen den Sprüh¬ kammern 12, 12' einen Abstand zu halten.The task of the spray device 7 is to uniformly wet the two surfaces of the polystyrene foam blanks 1.1... Ln with a release agent 11, for example with silicone oil. The spray device 7 consists of an upper and a lower spray chamber 12 and 12 ', which are each equipped with a pulse generator 13 and 13'. The two spray chambers 12, 12 'are preferably arranged one above the other in a space-saving manner, although it is also possible to keep a distance between the spray chambers 12, 12'.
Die Preßstation 8 verfügt über zwei glatte Stempel 14,. 14', von denen der untere 14' mit einer Perforation (nicht dargestellt) zwecks Ansaugung und Arretierung der Rohlinge versehen ist. Das Arretieren wird mittels einer Vakuumpumpe 15 gesteuert. Die beheizbaren Stempel 14, 14' bestehen aus gehärtetem Stahl bzw. aus Messing, und sind an den dem Rohling zugewandten Seiten (Stempelflä¬ chen 39,39') mit einem Antihaftmittel, z.B. PTFE, beschichtet.The press station 8 has two smooth stamps 14,. 14 ', of which the lower 14' is provided with a perforation (not shown) for the purpose of sucking and locking the blanks. The locking is controlled by means of a vacuum pump 15. The heatable stamps 14, 14 'consist of hardened steel or brass, and are coated on the sides facing the blank (stamp surfaces 39, 39') with an anti-adhesive, e.g. PTFE, coated.
Es kann auch zweckmäßig sein, die Stempel 14, 14' mit einer 0.8 mm dicken, wärmebeständigen Elastomer-Schicht 16 anzuvulkanisieren, die eine ausreichende Elastizität
besitzt, um die leichten Unebenheiten der Stempelflächen und des Rohlings zu kompensieren. In der Preßstation 8 werden die Rohlinge an ihren Flachseiten erhitzt, so daß anschließend die Oberflächen homogen verschmolzen sind. Die Anwendung des Elastomers verbessert wesentlich die erforderliche Brillanz der verschmolzenen Oberflächen.It can also be expedient to vulcanize the punches 14, 14 'with a 0.8 mm thick, heat-resistant elastomer layer 16 which has sufficient elasticity has to compensate for the slight unevenness of the stamp surfaces and the blank. In the pressing station 8, the blanks are heated on their flat sides, so that the surfaces are then homogeneously fused. The use of the elastomer significantly improves the required brilliance of the fused surfaces.
Die sich anschließende Verformungsstation 9 besitzt zwei beheizbare Metallformen 17, 17', von denen die obereThe subsequent deformation station 9 has two heatable metal molds 17, 17 ', the upper of which
- Patrize 17 - mehrere Mulden 18 und die untere- Male 17 - several troughs 18 and the lower one
- Matrize 37 - zu den Mulden 18 nahezu kompatible Wölbungen 19 aufweist . Die Verformungsstation 9 besitzt weiterhin einen rechteckigen Rahmen 20, in dem die beiden Metallformen, d.h. Matrize 17 und Patrize 37, an einer Kolbenstange 21 und entsprechend 21' auswechselbar befestigt sind. Die Form der Patrize und Matrize ergibt dann die gewünschten Produktform.- Die 37 - has bulges 19 almost compatible with the troughs 18. The deformation station 9 also has a rectangular frame 20 in which the two metal shapes, i.e. Die 17 and male 37, are attached to a piston rod 21 and correspondingly 21 'interchangeably. The shape of the male and female molds then gives the desired product shape.
Fig. lb zeigt eine Polystyrol-Schaumstoffrohlingsbahn 111, die aus einem abgelagerten Schaumstoffzylinder (nicht dargestellt) in einer Spirale herausgeschält worden ist. Die Rohlingsbahn 111 hat eine geringe Dicke von etwa 3, 5 mm und eine Breite von 600 mm. Sie wird mittels einer Antriebsrolle 113 vorwärts geschoben.Fig. Lb shows a polystyrene foam blank sheet 111, which has been peeled out of a deposited foam cylinder (not shown) in a spiral. The blank web 111 has a small thickness of approximately 3.5 mm and a width of 600 mm. It is pushed forward by means of a drive roller 113.
Die Rohlingsbahn wird im weiteren Verlauf des Herstel¬ lungsprozesses immer auf der Verschiebeebene (E) eines Verschiebetisches 6 im Rhythmus der zyklisch angetrie¬ benen Aggregate weiter verschoben. Die im folgenden beschriebenen Aggregate sind längs des Verschiebetisches 6 in technologischer Reihenfolge angeordnet : eine Sprühvorrichtung 7, eine Schneidestation 112, eine Preßstation 8 und eine Verformungsstation 9.In the further course of the manufacturing process, the blank web is always shifted further on the shifting plane (E) of a shifting table 6 in the rhythm of the cyclically driven units. The assemblies described below are arranged along the sliding table 6 in technological order: a spray device 7, a cutting station 112, a pressing station 8 and a deformation station 9.
Der Sprühvorrichtung 7 ist eine Folien-Vorratsrolle 29 vorgeschaltet, die unter dem Verschiebetisch 6 angeord¬ net, von der eine Folienbahn 27 mit Hilfe eines Elektro-
1 motors 26 und einer Kompensiervomchtung 31 abgezogen wird. Die Kompensiervorrichtung 31 besteht aus Umlenk¬ rollen 32, 32' und einer Tanzerrolle 33, die die Span- 5 nungsunterschiede der anzuwickelnden Folie ausgleicht und immer einen Folienvorrat bereithalt. In der Preß- station 8 wird die Polystyrol-Schaumstoffrohlingsbahn einseitig, ganzflachig mit der Folienbahn laminiert, d.h. ohne Klebstoffzusatz flachenhaft angeschmolzen, 10 gegebenenfalls unter Auslassung von Teilflachen.The spray device 7 is preceded by a film supply roll 29, which is arranged under the sliding table 6, from which a film web 27 is 1 motor 26 and a compensation device 31 is deducted. The compensating device 31 consists of deflection rollers 32, 32 'and a dance roller 33 which compensates for the tension differences of the film to be wound and always has a film supply available. In the press station 8, the polystyrene foam blank sheet is laminated on one side, over the entire area with the film sheet, ie, is melted flat without adhesive, 10 if necessary with the omission of partial areas.
Aufgabe der Spruhvomchtung 7 ist es, die beiden Oberflachen der Polystyrol-Schaumstoffrohlingsbahn 111 mit einem Trennmittel 11 gleichmäßig zu benetzen, bei- , r spielsweise mit Silikonöl. Die Spruhvomchtung 7 besteht aus einer oberen und einer unteren Spruhkammer 12 und 12', die entsprechend mit j e einem Impulsgeber 13 und 13' ausgestattet sind. Der Sprühvorrichtung 7 ist eine Trennstation 112 nachgeschaltet, die die Rohlmgs-The task of the spray device 7 is to uniformly wet the two surfaces of the polystyrene foam blank web 111 with a release agent 11, for example with silicone oil. The spray device 7 consists of an upper and a lower spray chamber 12 and 12 ', which are each equipped with a pulse generator 13 and 13'. The spray device 7 is followed by a separation station 112, which the Rohlmgs-
20 bahn 111 m einzelne Rohlinge 1.1 ... l.n trennt.20 lane 111 m individual blanks 1.1 ... l.n separates.
An die Trennstation 112 schließt sich eine Preßstation 8 an, die der in Fig. la entspricht. Die Preßstation 8 verfugt über zwei glatte Stempel 14, . 14' , von denen derA press station 8, which corresponds to that in FIG. The press station 8 has two smooth stamps 14,. 14 ', of which the
25 untere 14' mit einer Perforation (nicht dargestellt) zwecks Ansaugung und Arretierung der Rohlinge versehen ist.25 lower 14 'is provided with a perforation (not shown) for the suction and locking of the blanks.
Die sich anschließende Verformungsεtation 9 besitzt zweiThe subsequent deformation station 9 has two
30 beheizbare Metallformen 17, 17', von denen die obere30 heatable metal molds 17, 17 ', the upper of which
- Patrize 17 - mehrere Mulden 18 und die untere- Male 17 - several troughs 18 and the lower one
- Matrize 37 - zu den Mulden 18 nahezu kompatible Wölbungen 19 aufweist. Die Verformungsstation 9 besitzt weiterhin einen rechteckigen Rahmen 20, in dem die- Die 37 - has bulges 19 almost compatible with the troughs 18. The deformation station 9 also has a rectangular frame 20 in which the
35 beiden Metallformen, d.h. Matrize 17 und Patrize 37, an einer Kolbenstange 21 und entsprechend 21' auswechselbar befestigt sind. Die Form der Patrize und Matrize ergibt dann die gewünschten Produktform.
Wie insbesondere Fig. 3 zeigt, sind die Matrize 17 und Patrize 37 als beheizbare Metallplatten 22 und 22' ausgeführt, gegebenenfalls aus gehärtetem Stahl, die sich insbesondere für einen längeren Produktionslauf eignen. Sowohl die Mulden 18 als auch die Wölbungen 19 sind mit einer hauchdünnen Silikonölschicht versehen. Es sei jedoch nicht ausgeschlossen, die Mulden 18 und Wölbungen ebenfalls mit einer dünnen Elastomerschicht versehen sind, wobei wenigstens die Muldenfläche mit einem reliefiertem Muster versehen werden kann, beispielsweise mit der Marke des Herstellers oder Verwenders.35 two metal molds, that is to say die 17 and male 37, are fastened to a piston rod 21 and correspondingly 21 'so that they can be replaced. The shape of the male and female molds then gives the desired product shape. As shown in FIG. 3 in particular, the die 17 and the die 37 are designed as heatable metal plates 22 and 22 ', optionally made of hardened steel, which are particularly suitable for a longer production run. Both the troughs 18 and the bulges 19 are provided with a wafer-thin layer of silicone oil. However, it should not be excluded that the troughs 18 and bulges are also provided with a thin elastomer layer, it being possible for at least the trough surface to be provided with a pattern in relief, for example with the brand of the manufacturer or user.
Die beiden Metallplatten 22 und 22' sind ferner mit durchgehenden Bohrungen 23 versehen, die mit Preßluft- Zufuhrleitungen 24 verbunden sind. Diese Bohrungen 23 sind möglichst gleichmäßig auf den Mulden- und Wölbungs¬ flächen verteilt, um das Ausstoßen der augestanzten Formteile einwandfrei mit einem Druckluft-Impuls zu verwirklichen.The two metal plates 22 and 22 'are also provided with through holes 23 which are connected to compressed air supply lines 24. These bores 23 are distributed as evenly as possible on the trough and bulge surfaces in order to implement the punched-out molded parts properly with a compressed air pulse.
Weiterhin gehört zur Vorrichtung 100 ein Auffanggitter 30, das seitlich (vgl. Fig. 2) und quer zur Verschiebe¬ richtung (Pfeile X) in der Verformungsstation 9 taktweise verschiebbar ist.Furthermore, the device 100 includes a collecting grid 30 which can be shifted to the side (cf. FIG. 2) and transversely to the direction of displacement (arrows X) in the deformation station 9.
FunktionsbeschreibunσFunctional description
Aus dem Rohlingsstapel-Behälter 2 wird mit Hilfe der Schiebeplatte 4 der unterste Polystyrol-Schaumstoffroh¬ ling 1.1 ... l.n durch den Schlitz 3' in Richtung Verschiebetisch 6 ausgestoßen und in die Sprühvorrich¬ tung 7 weitergegeben. Dort werden die Rohlinge beidsei¬ tig mit einem Silikonöl als Trennmittel ausreichend benetzt, damit sie in den nächsten Bearbeitungsstufen an die Heizplatten nicht haften.
Als Antihaftmittel kann auch eine lebensmittelgerechte Zusammensetzung, z.B. eine wässerige Olemulsion oder eine Metallseife, verwendet werden.The bottom polystyrene foam blank 1.1 ... ln is ejected from the blank stack container 2 with the help of the sliding plate 4 through the slot 3 'in the direction of the shift table 6 and passed on to the spray device 7. There, the blanks are sufficiently wetted on both sides with a silicone oil as a release agent so that they do not adhere to the heating plates in the next processing stages. A food-grade composition, for example an aqueous oil emulsion or a metal soap, can also be used as the non-stick agent.
Der mit Trennmittel versehene Rohling gelangt danach unter die Metallplatten 14 und 14' der Preßstation 8. Der Preßvorgang dauert zirka 0,8 s bei einer Temperatur der Metallplatten von 170° C bei einem Druck von 1,25«10* Pa. Bei diesen Parametern werden beide Ober¬ flächen-Bereiche 41 der Rohlinge gleichmäßig so ange¬ schmolzen und homogenisiert, daß sich die Poren und Zwischenräume zwischen den Schaumstoffkügelchen optisch vollkommen schließen. In dieser Weise entsteht eine glatte Zwischenproduktplatte 40 bzw. 40' (mit Folie), aus der verschiedene schalenartige Produkte hergestellt werden können.The blank provided with release agent then passes under the metal plates 14 and 14 'of the pressing station 8. The pressing process takes approximately 0.8 s at a temperature of the metal plates of 170 ° C. at a pressure of 1.25 10 * Pa. With these parameters, both surface areas 41 of the blanks are melted and homogenized uniformly in such a way that the pores and interspaces between the foam spheres are completely closed. In this way, a smooth intermediate product plate 40 or 40 '(with film) is produced, from which various shell-like products can be produced.
Nach dem Preßvorgang gelangen die Zwischenproduktplatten in die Verformungsstation 9, wo sie ebenfalls kurzzeitig geprägt werden, in diesem Fall während 0,9 s bei einer Temperatur (im Kontaktbereich mit der Matrize 17 und Patrize 37) von etwa von 180°C und unter dem Druck von etwa l,4-10s Pa.After the pressing process, the intermediate product plates reach the shaping station 9, where they are also briefly embossed, in this case for 0.9 s at a temperature (in the contact area with the female 17 and male 37) of approximately 180 ° C. and under pressure of about 1.4-10 s Pa.
In einem Heißprägevorgang werden aus einem 750 ♦ 750 mm2 großen Schaumstoffrohling mehrere Verkaufsschalen von der Größe 120 • 175 mm2 ausgeprägt (Fig. 4).In a hot stamping process, several sales trays of the size 120 • 175 mm 2 are stamped out of a 750 ♦ 750 mm 2 foam blank (FIG. 4).
So hergestellte Verkaufsschalen 10 werden gleichzeitig während des Heißprägevorganges durch Umfangsschneiden 25, mit denen die Patrize 37 versehen ist, ausgestanzt. Nach diesem Arbeitsgang wird den Kontaktflächen 35, 35' durch die Zufuhrleitungen 24 und Bohrungen 23 impuls¬ weise Preßluft zugeführt, wobei zunächst die Preßluft an die Patrize 37 gegeben wird, so daß die obenliegende Matrize 17 die Verpackungsschalen noch hält bis zum
Heranfahren eines unter der Verschiebeebene E verschieb¬ bar angeordneten Anffangsgitters 30 und Herausfahren der Patrize aus der Vorformungsstation. Nach dem nächsten Druckluft-Impuls fallen die ausgestanzten Verkaufs¬ schalen 10 auf das Auffanggitter 30.Sales trays 10 thus produced are punched out simultaneously during the hot stamping process by circumferential cutting 25 with which the male part 37 is provided. After this operation, the contact surfaces 35, 35 'through the supply lines 24 and bores 23 are supplied with compressed air, whereby the compressed air is first supplied to the male 37, so that the upper female 17 still holds the packaging trays until Approaching a starting grid 30 which is arranged to be displaceable under the shifting plane E and moving the male part out of the preforming station. After the next compressed air pulse, the punched-out sales trays 10 fall onto the collecting grid 30.
Das Verschieben des Auffanggitters 30 und der Patrize 37 wird mittels quer zur Verschieberichtung (Pfeile X)The catch grid 30 and the male part 37 are displaced by means of transverse to the direction of displacement (arrows X)
1 0 angeordneter Führungsleisten 38, 38' und einer Kolben- Zylinder-Anordnung (nicht dargestellt) realisiert (vgl. Fig. 2).1 0 arranged guide strips 38, 38 'and a piston-cylinder arrangement (not shown) realized (see. Fig. 2).
Sollen die Verkaufsschalen an ihren Nutzflächen 39 mit , ,. einer dünnen Folie beschichtet werden, wird von derShould the sales trays 39,. a thin film is coated by the
Folien-Vorratsrolle 29 mittels des Elektromotors 26 und Kompensiervorrichtung 31 eine Folienbahn 27 abgezogen und über die Sprühvorrichtung 7 der Preßstation 8 zugeführt. Als Folienmaterial eignen sich insbesondere 0 alle thermoplastisch verformbaren, einschließlich aus Reinaluminium bestehende oder mit Aluminium laminierte Folien, bei denen die Folienbahn zumindet auf ihrer mit dem Rohling in Kontakt kommenden Seite aus Polystyrol besteht.Foil supply roll 29 is pulled off a foil web 27 by means of the electric motor 26 and compensating device 31 and fed to the pressing station 8 via the spraying device 7. Particularly suitable as film material are all thermoplastically deformable films, including films made of pure aluminum or laminated with aluminum, in which the film web consists at least on its side that comes into contact with the blank from polystyrene.
2525
Die durch den Anmelder durchgeführten Versuche mit einer extrudierten dünnen Polystyrol-Schaumfolie haben sich als vielversprechend erwiesen. Die Polystyrol- Schaumfolie ist thermisch leicht verformbar, zeichnet 0 sich durch eine Seidenglanz-Oberflächenstruktur aus und ist lebensmittelgerecht.The tests carried out by the applicant with an extruded thin polystyrene foam film have proven to be promising. The polystyrene foam film is easy to deform thermally, is characterized by a silky gloss surface structure and is suitable for food.
Der dem Schaumstoffrohling anliegende Folienabschnitt wird mittels Vakuumpumpe 15 angesaugt und damit arretiert. Nach dem gegenseitigen Verschmelzen der 5 Kontaktflächen des Schaumstoffrohlings und der Folie wird das überstehende Folienstück in der Schneidestation 34 abgeschnitten.
Alle oben beschriebenen Arbeitsgänge sind miteinander koordiniert. Die Parameter, wie Schaumstoffrohlings¬ dichte und -dicke, Preßkraft, Temperaturen und Zeit sind einprogrammiert und veränderbar, wodurch der Prozeß mit Hilfe eines Computers optimal steuerbar ist.The film section lying against the foam blank is sucked in by means of a vacuum pump 15 and thus locked. After the 5 contact surfaces of the foam blank and the film have melted together, the excess film piece is cut off in the cutting station 34. All operations described above are coordinated with each other. The parameters, such as foam blank density and thickness, pressing force, temperatures and time, can be programmed and changed, so that the process can be optimally controlled with the aid of a computer.
Bei der Verwendung von Rohlingsbahnen ist ein analoges AblaufSchema vorgesehen, das sich aus der Fig. lb erschließt.
When using blank webs, an analogous flow diagram is provided, which can be seen from FIG. 1b.
Claims
1. Verfahren zur Herstellung von gewölbten Schalen, insbesondere Verkaufsschalen, aus Polystyrol- Schaumstoff, mit folgenden Verfahrensschritten:1. Process for the production of curved trays, in particular sales trays, from polystyrene foam, with the following process steps:
(a) Zerschneiden von Schaumstoff-Blöcken oder -Zylindern in plattenförmige Rohlinge oder in eine Rohlingsbahn;(a) cutting foam blocks or cylinders into sheet-like blanks or into a blank web;
(b) Auflegen und Verschieben der Rohlinge oder der Rohlingsbahn auf einer horizontalen Ebene,, sowie gegebenenfalls Ablängen der Rohlingsbahn zu einzelnen Rohlingen(b) Placing and moving the blanks or the blank web on a horizontal plane, and, if necessary, cutting the blank web to individual blanks
(c) Herstellen von Zwischenproduktplatten aus den Rohlingen durch Ausüben eines Druckes auf die beiden Flachseiten des Rohlings mit je einer erhitzten, flachen Stempelfläche, wobei die kontaktierten Bereiche des Rohlings erweicht und oberflächlich verschmolzen werden;(c) producing intermediate product plates from the blanks by exerting pressure on the two flat sides of the blank, each with a heated, flat stamp surface, the contacting regions of the blank being softened and superficially fused;
(d) Verformen der Zwischenproduktplatten in einer aus einer beheizten Patrize und Matrize gebildeten Form zu den Schalen, im wesentlichen unter Beibehaltung des Volumens der Zwischenproduktplatte;(d) deforming the intermediate product plates into the shells in a form formed by a heated male and female die, essentially while maintaining the volume of the intermediate product plate;
(e) Ausstoßen oder Entnehmen der Schalen.(e) ejecting or removing the shells.
2. Verfahren nach Anspruch 1 , dadurch gekenn¬ zeichnet, daß die flache Stempelfläche eine Temperatur von wenigstens 110°C, vorzugsweise zwischen 110° und 160°C hat .2. The method according to claim 1, characterized gekenn¬ characterized in that the flat stamp surface has a temperature of at least 110 ° C, preferably between 110 ° and 160 ° C.
3. Verfahren nach Anspruch 1 oder 2 , dadurch gekennzeichnet, daß die Kontaktzeit der Stempelfläche mit den Rohling-Flachseiten zwischen 0,1 und 10 s, vorzugsweise zwischen 0,5 und 1,5 s liegt.3. The method according to claim 1 or 2, characterized characterized in that the contact time of the stamp surface with the blank flat sides is between 0.1 and 10 s, preferably between 0.5 and 1.5 s.
4. Verfahren nach einem der vorhergehenden Ansprü¬ che, dadurch gekennzeichnet, daß der auf die Rohlinge ausgeübte Druck zwischen etwa 10s und 2»10s Pa liegt.4. The method according to any one of the preceding Ansprü¬ che, characterized in that the pressure exerted on the blanks is between about 10 s and 2 »10 s Pa.
5. Verfahren nach einem der vorhergehenden Ansprü¬ che, dadurch gekennzeichnet, daß die Verformung in der aus einer beheizten Patrize und Matrize gebildeten Form zu einer Schale bei einer Temperatur zwischen 100° und 300°C, vorzugsweise zwischen 165° und 185°C durchgeführt wird.5. The method according to any one of the preceding Ansprü¬ surface, characterized in that the deformation in the form formed from a heated male and female mold into a shell at a temperature between 100 ° and 300 ° C, preferably between 165 ° and 185 ° C. becomes.
6. Verfahren nach einem der vorhergehenden Ansprü¬ che, dadurch gekennzeichnet, daß die Rohlinge oder die Rohlingsbahn wenigstens auf einer ihrer Flachseiten mit einer Folienbahn (27) laminiert werden bzw. wird.6. The method according to any one of the preceding Ansprü¬ surface, characterized in that the blanks or the blank web are laminated at least on one of their flat sides with a film web (27).
7. Verfahren nach Anspruch 6, dadurch gekenn¬ zeichnet, daß die Folienbahn (27) aus extrudiertem Poly¬ styrol-Schaum besteht.7. The method according to claim 6, characterized gekenn¬ characterized in that the film web (27) consists of extruded poly styrene foam.
8. Verfahren nach Anspruch 6 oder 7, dadurch gekenn¬ zeichnet, daß die auflaminierte Folienbahn mit der Rohling-Oberfläche ganzflächig oder nur in Bereich von Teilflächen verbunden, vorzugsweise verschmolzen wird.8. The method according to claim 6 or 7, characterized gekenn¬ characterized in that the laminated film web is connected to the blank surface over the entire surface or only in the area of partial surfaces, preferably fused.
9. Verfahren nach Anspruch 1, 6 bis 8, dadurch gekennzeichnet, daß die Verformung in der aus einer beheizten Patrize und Matrize gebildeten Form zu einer Schale in einer Zeit von 0,2 s bis 10 s, vorzugsweise zwischen 0,8 s und 1,5 s, durchgeführt wird.9. The method according to claim 1, 6 to 8, characterized in that the deformation in the form formed from a heated male and female mold into a shell in a time of 0.2 s to 10 s, preferably between 0.8 s and 1 , 5 s, is carried out.
10. Vorrichtung zur Durchführung des Verfahrens nach den Ansprüchen 1 bis 9 mit folgenden Einzelteilen: - einem Verschiebetisch (6), auf dessen Verschiebeebene (E) platten- oder bahnförmige Schaumstoff-Rohlinge (1.1 ... l.n) oder eine entsprechende Rohlingsbahn (111) auflegbar und verschiebbar sind,10. Device for performing the method according to claims 1 to 9 with the following individual parts: - a sliding table (6), on the sliding plane (E) of which plate or sheet-shaped foam blanks (1.1 ... ln) or a corresponding blank sheet (111) can be placed and moved,
- einer Preßstation (8), die einen beheizbaren Stempel mit ebenen Stempelflächen (39; 39') aufweist,- a press station (8) which has a heatable stamp with flat stamp surfaces (39; 39 '),
- einer Verformungsstation (9) mit je einer auswechsel¬ baren, beheizbaren Patrize (37) und Matrize (17), deren verformende Fläche miteinander kompatibel sind, wobei in zusammengefahreren Zustand von Patrize und Matrize ein Formholraum verbleibt,- A deformation station (9), each with an interchangeable, heated male (37) and female (17), the deforming surface of which are compatible with one another, with a mold cavity remaining in the collapsed state of male and female,
- und mit einer Ausstoßvorrichtung (36).- And with an ejection device (36).
11. Vorrichtung nach Anspruch 10, dadurch gekenn¬ zeichnet, daß der Preßstation (8) eine Folien-Vorrats¬ rolle (29) vorgeschaltet ist, von der eine Folienbahn (27), gegebenenfalls via Kompensiervorrichtung (31), zur Verschiebeebene (E) hin abziehbar ist.11. The device according to claim 10, characterized in that the pressing station (8) is preceded by a film supply roll (29) from which a film web (27), optionally via a compensating device (31), to the displacement plane (E) is removable.
12. Vorrichtung nach Anspruch 10 oder 11, dadurch gekennzeichnet, daß der Preßstation (8) eine Schneide¬ station (34) nachgeschaltet ist.12. The apparatus of claim 10 or 11, characterized in that the pressing station (8) is followed by a cutting station (34).
13. Vorrichtung nach Anspruch 10, dadurch gekenn¬ zeichnet, daß die Kompensiervorrichtung (31) wenigstens über zwei Umlenkrollen (32, 32') und eine Tänzerrolle (33) verfügt.13. The apparatus according to claim 10, characterized gekenn¬ characterized in that the compensating device (31) has at least two deflection rollers (32, 32 ') and a dancer roller (33).
14. Vorrichtung nach einem der vorhergehenden Ansprüche 10 bis 12, dadurch gekennzeichnet, daß die Preßstation (8) mit einer Vakuumpumpe (15) verbunden ist, mit der unterhalb der Verschiebeebene (E) im Bereich der Stempelfläche (39,39') ein Vakuum erzeugbar ist.14. Device according to one of the preceding claims 10 to 12, characterized in that the pressing station (8) is connected to a vacuum pump (15) with which a vacuum is located below the displacement plane (E) in the region of the stamp surface (39, 39 ') can be generated.
15. Vorrichtung nach einem der vorhergehenden Ansprüche 10 bis 14, dadurch gekennzeichnet, daß die verformende Fläche (35') der Patrize (37) mit wenigstens einer Umfangsschneide (25) versehen ist, die dem Umfang der zu fertigenden Schale entspricht.15. Device according to one of the preceding claims 10 to 14, characterized in that the deforming surface (35 ') of the male part (37) is provided with at least one peripheral cutting edge (25) which corresponds to the circumference of the shell to be manufactured.
16. Vorrichtung nach einem der vorhergehenden Ansprüche 10 bis 15, dadurch gekennzeichnet, daß die Stempelflächen (39) der Preßstation (8) und/oder die verformenden Flächen (35; 35') der Patrize (37) bzw. Matrize (17) mit einer dünnen, hitzebeständigen Elastomerschicht oder einer Antihaftschicht versehen sind.16. Device according to one of the preceding claims 10 to 15, characterized in that the stamp surfaces (39) of the pressing station (8) and / or the deforming surfaces (35; 35 ') of the male (37) or female (17) with are provided with a thin, heat-resistant elastomer layer or a non-stick layer.
17. Vorrichtung nach einem der vorhergehenden Ansprüche 10 bis 16, dadurch gekennzeichnet, daß die verformenden Flächen (35;35') der Patrize (37) und/oder der Matrize (17) reliefiert sind.17. Device according to one of the preceding claims 10 to 16, characterized in that the deforming surfaces (35; 35 ') of the male (37) and / or the female (17) are in relief.
18. Vorrichtung nach Anspruch 10, dadurch gekenn¬ zeichnet, daß die Ausstoßvorrichtung (36) wenigstens je eine in der Patrize (37) und Matrize (17) eingearbeitete Bohrung (23) umfaßt, an die eine Preßluft-Zufuhrleitung angeschlossen ist.18. The apparatus according to claim 10, characterized gekenn¬ characterized in that the ejection device (36) comprises at least one in the male (37) and female (17) incorporated bore (23) to which a compressed air supply line is connected.
19. Vorrichtung nach einem der vorhergehenden Ansprüche 10 bis 18, dadurch gekennzeichnet, daß die Verformungsstation (9) mit einem seitlich an sie heran¬ fahrbaren Auffanggitter (30) versehen ist, und daß die Patrize (37) in der Verformungsstation ebenfalls seitlich verschiebbar ist. 19. Device according to one of the preceding claims 10 to 18, characterized in that the deformation station (9) is provided with a collecting grid (30) which can be moved laterally towards it and that the male part (37) is also laterally displaceable in the deformation station .
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU76227/96A AU7622796A (en) | 1995-11-16 | 1996-11-12 | Method and device for the production of convex shells made of polystyrene foam |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE1995142717 DE19542717C1 (en) | 1995-11-16 | 1995-11-16 | Process produces sales trays from cut polystyrene foam blanks by hot- plane and hot form stamping |
DE19542717.3 | 1995-11-16 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1997018077A1 true WO1997018077A1 (en) | 1997-05-22 |
Family
ID=7777614
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP1996/004942 WO1997018077A1 (en) | 1995-11-16 | 1996-11-12 | Method and device for the production of convex shells made of polystyrene foam |
Country Status (3)
Country | Link |
---|---|
AU (1) | AU7622796A (en) |
DE (1) | DE19542717C1 (en) |
WO (1) | WO1997018077A1 (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1815977A1 (en) * | 2005-12-28 | 2007-08-08 | DI.CO.T s.r.l. | Recyclable automotive panel, process and plant for manufacturing the same |
DE102006032830A1 (en) * | 2006-07-14 | 2008-01-17 | Schmidt & Heinzmann Gmbh & Co. Kg | Device for transporting a material strand |
US8092727B2 (en) | 2007-08-27 | 2012-01-10 | Dow Global Technologies Llc | Method of forming extruded polystyrene foams and the products made therefrom |
EP2504141A1 (en) * | 2009-11-24 | 2012-10-03 | Dow Global Technologies LLC | Process for forming a double-sided shaped foam article |
WO2012058177A1 (en) * | 2010-10-29 | 2012-05-03 | Dow Global Technologies Llc | Method of forming a shaped foam laminate article |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2781552A (en) * | 1955-10-21 | 1957-02-19 | Us Ceramic Tile Company | Process for making thin articles of polytetrafluoroethylene |
FR1468659A (en) * | 1964-08-07 | 1967-02-10 | N G T | Process for manufacturing plastic objects and installation for carrying out the process |
FR2128346A1 (en) * | 1971-03-01 | 1972-10-20 | Dow Chemical Co | |
US3923948A (en) * | 1971-09-21 | 1975-12-02 | Mobil Oil Corp | Thermoforming plastic articles |
EP0396456A1 (en) * | 1989-05-03 | 1990-11-07 | Dassault Aviation | Method and apparatus for shaping of thermoplastics materials in the form of thin sheets, especially composite materials |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2212355C2 (en) * | 1972-03-15 | 1974-03-21 | Kopperschmidt, Carl W., 2000 Hamburg | Process for producing high-gloss surfaces on bodies made of thermoplastic or thermoelastic plastic |
US4239727A (en) * | 1978-09-15 | 1980-12-16 | Mobil Oil Corporation | Method and apparatus for thermoforming thermoplastic foam articles |
-
1995
- 1995-11-16 DE DE1995142717 patent/DE19542717C1/en not_active Expired - Fee Related
-
1996
- 1996-11-12 AU AU76227/96A patent/AU7622796A/en not_active Abandoned
- 1996-11-12 WO PCT/EP1996/004942 patent/WO1997018077A1/en active Application Filing
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2781552A (en) * | 1955-10-21 | 1957-02-19 | Us Ceramic Tile Company | Process for making thin articles of polytetrafluoroethylene |
FR1468659A (en) * | 1964-08-07 | 1967-02-10 | N G T | Process for manufacturing plastic objects and installation for carrying out the process |
FR2128346A1 (en) * | 1971-03-01 | 1972-10-20 | Dow Chemical Co | |
US3923948A (en) * | 1971-09-21 | 1975-12-02 | Mobil Oil Corp | Thermoforming plastic articles |
EP0396456A1 (en) * | 1989-05-03 | 1990-11-07 | Dassault Aviation | Method and apparatus for shaping of thermoplastics materials in the form of thin sheets, especially composite materials |
Also Published As
Publication number | Publication date |
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AU7622796A (en) | 1997-06-05 |
DE19542717C1 (en) | 1997-03-20 |
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