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WO1997003820A1 - Composite tubular member having consistent strength and method - Google Patents

Composite tubular member having consistent strength and method Download PDF

Info

Publication number
WO1997003820A1
WO1997003820A1 PCT/US1996/011718 US9611718W WO9703820A1 WO 1997003820 A1 WO1997003820 A1 WO 1997003820A1 US 9611718 W US9611718 W US 9611718W WO 9703820 A1 WO9703820 A1 WO 9703820A1
Authority
WO
WIPO (PCT)
Prior art keywords
ply
fiber component
tubular
ofthe
matrix material
Prior art date
Application number
PCT/US1996/011718
Other languages
French (fr)
Inventor
Peter A. Quigley
Stephen C. Nolet
Original Assignee
Composite Development Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US08/597,088 external-priority patent/US5688571A/en
Application filed by Composite Development Corporation filed Critical Composite Development Corporation
Priority to CA002227197A priority Critical patent/CA2227197A1/en
Publication of WO1997003820A1 publication Critical patent/WO1997003820A1/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B1/00Layered products having a non-planar shape
    • B32B1/08Tubular products
    • AHUMAN NECESSITIES
    • A63SPORTS; GAMES; AMUSEMENTS
    • A63BAPPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B59/00Bats, rackets, or the like, not covered by groups A63B49/00 - A63B57/00
    • A63B59/70Bats, rackets, or the like, not covered by groups A63B49/00 - A63B57/00 with bent or angled lower parts for hitting a ball on the ground, on an ice-covered surface, or in the air, e.g. for hockey or hurling
    • AHUMAN NECESSITIES
    • A63SPORTS; GAMES; AMUSEMENTS
    • A63BAPPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B60/00Details or accessories of golf clubs, bats, rackets or the like
    • AHUMAN NECESSITIES
    • A63SPORTS; GAMES; AMUSEMENTS
    • A63BAPPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B60/00Details or accessories of golf clubs, bats, rackets or the like
    • A63B60/06Handles
    • A63B60/16Caps; Ferrules
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/06Fibrous reinforcements only
    • B29C70/08Fibrous reinforcements only comprising combinations of different forms of fibrous reinforcements incorporated in matrix material, forming one or more layers, and with or without non-reinforced layers
    • B29C70/083Combinations of continuous fibres or fibrous profiled structures oriented in one direction and reinforcements forming a two dimensional structure, e.g. mats
    • B29C70/085Combinations of continuous fibres or fibrous profiled structures oriented in one direction and reinforcements forming a two dimensional structure, e.g. mats the structure being deformed in a three dimensional configuration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/28Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer impregnated with or embedded in a plastic substance
    • AHUMAN NECESSITIES
    • A63SPORTS; GAMES; AMUSEMENTS
    • A63BAPPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B2102/00Application of clubs, bats, rackets or the like to the sporting activity ; particular sports involving the use of balls and clubs, bats, rackets, or the like
    • A63B2102/14Lacrosse
    • AHUMAN NECESSITIES
    • A63SPORTS; GAMES; AMUSEMENTS
    • A63BAPPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B2102/00Application of clubs, bats, rackets or the like to the sporting activity ; particular sports involving the use of balls and clubs, bats, rackets, or the like
    • A63B2102/22Field hockey
    • AHUMAN NECESSITIES
    • A63SPORTS; GAMES; AMUSEMENTS
    • A63BAPPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B2209/00Characteristics of used materials
    • A63B2209/02Characteristics of used materials with reinforcing fibres, e.g. carbon, polyamide fibres
    • AHUMAN NECESSITIES
    • A63SPORTS; GAMES; AMUSEMENTS
    • A63BAPPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B2209/00Characteristics of used materials
    • A63B2209/02Characteristics of used materials with reinforcing fibres, e.g. carbon, polyamide fibres
    • A63B2209/023Long, oriented fibres, e.g. wound filaments, woven fabrics, mats
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2023/00Tubular articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00Other particular articles
    • B29L2031/60Multitubular or multicompartmented articles, e.g. honeycomb
    • B29L2031/601Multi-tubular articles, i.e. composed of a plurality of tubes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2597/00Tubular articles, e.g. hoses, pipes

Definitions

  • This invention provides resin-fiber composite tubular members having unique combinations of fiber orientations in different plies, and having selected other reinforcement.
  • the composite members ofthe invention are advantageously used in various manufactured products, including sports implements such as golf clubs and hockey sticks among others.
  • Wood implements have long been made with various materials including wood and particularly wood shafts. Wood implements can have high strength as desired and can have a satisfying feel for the user.
  • One drawback of wood is significant variation from item to item, even when made to the same specifications and dimensions.
  • One object of this invention is to provide composite tubular members suited for the shaft of a sports implement. Other objects ofthe invention will in part be obvious and will in part appear hereinafter.
  • the tubular members which the invention provides have resin-fiber composite construction with improvements in durability and particularly in bending strength and in impact strength. Further, the tubular members are generally suited for relatively low cost manufacture.
  • the tubular members ofthe invention have one or more plies of fibers.
  • the multiple-ply composite members are constructed according to manufacture methods described in Attachment A, which is a copy ofthe commonly-assigned U.S. Patent Application Serial No. 08/191,856 filed 3 February 1994 and inco ⁇ orated herein by this reference.
  • an axially extending tubular composite member has a plurality of plies. At least some plies include substantially continuous fibers.
  • the composite member has a primary bending stiffness along a longitudinal axis.
  • the tubular composite member generally has at least three plies, including an inner or interior ply that commonly has at least one biaxial fiber component embedded in the matrix material.
  • a biaxially fiber component includes two sets of fibers or threads spirally wrapping in opposite directions about the axially extending composite member. The two sets of fibers thus are generally symmetrical and generally extend diagonally relative to the axis ofthe member.
  • An intermediate ply ofthe composite member typically has at least one axially extending fiber component also disposed with the resin or other matrix material.
  • the intermediate ply is disposed contiguously over the interior ply and hence is exterior to the interior ply.
  • the axial fiber component ofthe intermediate ply can be a substantially continuous set of fibers extending essentially parallel to the elongation axis ofthe composite member.
  • a set of axially extending fibers can follow a helical path, i.e., extend at an acute angle relative to the elongation axis.
  • the axial fiber is interlaced with two other sets of threads or fibers extending symmetrically in opposite directions relative to the axial fiber, to constitute so-called triaxial fiber structure.
  • the interlacing or diagonally extending sets of fibers enhance maintaining the axially extending fibers in place and they add strength, including preventing cracks and other stress failures or fractures from propagating.
  • a further ply overlying the intermediate ply has a woven fiber component.
  • the woven fiber component has the two sets of fibers, and one is oriented axially and the other transversely relative to the longitudinal axis, i.e., a so-called 0° and 90° fiber orientation relative to the elongation axis.
  • a further practice ofthe invention employs an outer ply having at least one biaxial fiber component and located over the intermediate ply and either in place of a woven fiber component as described above or beneath such a woven fiber component.
  • fiber components in woven form can be formed with continuous fiber strands drawn from spools as described in Attachment A.
  • Alternatives include applying the fibers in preformed fibrous sheets.
  • the fibers can be braided, stitched or knitted.
  • each ply can include two or more subplies.
  • the inner ply of a tubular member according to the invention can have two subplies, each with a biaxial fiber component.
  • the biaxial fibers can have different fiber angles, relative to the elongation axis, in the two subplies.
  • a typical further element of a composite member according to the invention is a surface veil, forming either the extreme outer surface ofthe member or the extreme tubular inner surface, or both.
  • Such a surface veil can facilitate the manufacture ofthe member, particularly in a pultrusion manufacture.
  • An exterior veil can enhance appearance, an interior veil can improve impact resistance.
  • a surface veil for these purposes has a relatively large proportion of resin and a relatively lesser fiber component.
  • the fibers of a composite member according to the invention are generally selected, using known criteria, from materials including carbon, aramid, glass, linear polyethylene, polyethylene, polyester, and mixtures thereof.
  • the matrix material is selected from a group of resin-based materials, such as thermoplastics and thermosets.
  • thermoplastics include: polyetherether-ketone, polyphenyiene sulfide, polyethylene, polypropylene, and Nylon-6.
  • thermosets include: urethanes, epoxy, vinylester, and polyester.
  • tubular members having a resin-fiber composite structure have improvements in durability and particularly in impact strength, and yet retain light weight, when constructed with one or more additional structural elements.
  • Such structural elements which the invention provides include selectively concave walls, selected added thickness at corners of walls, added thickness selectively in each of two opposed walls, and internal reinforcement.
  • the first three features stated above i.e., concave walls, thickened corners, and thickened walls, are applicable to members having a non-circular cross section and typically to members having a polygonal cross-section.
  • a preferred polygonal cross-section has four or more sides.
  • the foregoing structural features preferably are used in combination with one another, such as opposed concave walls combined with added wall thickness at the corners of those walls, or added thickness at opposed walls and added thickness at the corners of those walls.
  • the internal reinforcement is applicable in structures having any of various cross sections, examples of which include a polygonal cross section and a circular cross section.
  • examples of such reinforcement include an interior rib extending along at least a portion of the length ofthe member, either essentially parallel to the axis or length ofthe member or selectively angled, e.g., helical, with regard to the axis of a straight member.
  • Such a rib is preferably provided on each of two opposed walls.
  • Another example of such internal reinforcement is an interior web. or an axially spaced succession of interior braces, spanning between opposed walls or between adjacent walls.
  • an interior web or brace in a composite tubular member according to one embodiment ofthe invention and having a circular or elliptical cross section can follow the path of a chord extending between two locations spaced apart around the circumference ofthe composite member, when viewed in cross section.
  • the internal web or brace extends between adjacent walls.
  • braces or webs extending between opposed walls or wall portions, including along the path of a diameter of a member having a circular or elliptical cross section.
  • the interior reinforcement can extend along the full length ofthe member or along only part ofthe length. The latter may be preferred, for example, to decrease weight and to control stiffness.
  • the internal reinforcement is formed during the initial pultrusion fabrication ofthe composite member and accordingly is continuous along the length ofthe member, or at least along a selected portion thereof. Where such an internal reinforcing web is formed continuously along the length of a member, it can subsequently be removed, as by machining, from one or more selected portions ofthe length ofthe member. This may be desired to reduce the weight ofthe member.
  • a further alternative is to fabricate the composite member and add internal reinforcement, by inserting a preformed internal reinforcement element.
  • the internal reinforcement element preferably is added prior to final curing ofthe polymers ofthe composite member and ofthe reinforcement element to ensure a solid attachment ofthe internal reinforcement member element to the composite member.
  • the composite member and the internal reinforcing element are formed concurrently as part of a resin transfer or compression molding process. This fabrication method provides a system capable of forming a composite member integral with an internal reinforcing element, both having selective characteristics along the length ofthe member.
  • the invention accordingly comprises an article of manufacture possessing features, properties and relations of elements exemplified in the articles hereinafter described. and comprises the several steps and the relation of one or more of such steps with respect to each ofthe others for fabricating such articles, and the scope ofthe invention is indicated in the claims.
  • FIGURE 1 shows a transverse cross-section and longitudinal fragment of a composite tubular member according to one practice ofthe invention
  • FIGURE 2 shows a transverse cross-section and longitudinal fragment of a composite tubular member according to a further practice ofthe invention
  • FIGURE 3 shows a transverse cross-section and longitudinal fragment of a composite tubular member according to yet another practice ofthe invention
  • FIGURES 4 through 9 show transverse cross-section and longitudinal fragments of composite tubular members according to further practices of the invention and having selectively configured and reinforced wall portions;
  • FIGURES 10 through 15 show transverse cross-section and longitudinal fragments of composite tubular members according to further practices ofthe invention and having internal reinforcement;
  • FIGURES 16 and 17 show sports implements, namely, a hockey stick and a lacrosse stick utilizing shafts according to the invention.
  • Figure 1 shows a transverse cross section and longitudinal fragment of a composite tubular member 100 according to one preferred practice ofthe invention.
  • the illustrated member 100 has a rectangular cross section with two wide opposed walls 102 and 104 and two narrow opposed walls 106 and 108.
  • the tubular member 100 can be constructed essentially as described in Attachment A to form, for example, the shaft of a hockey stick or of a lacrosse stick.
  • Each wall 102, 104, 106 and 108 ofthe illustrated member 100 has generally uniform thickness along the length ofthe member and the four walls are of essentially the same thickness.
  • the illustrated member 100 is preferably continuous along at least a selected length, i.e., has the same cross section at successive locations along that selected length. This continuous cross sectional configuration facilitates manufacture, for example with pultrusion procedures as described in Attachment A.
  • the member 100 further has, as also shown in Figure 1, internal reinforcement in the form of a web 110 that spans between and is joined solidly to the opposed wider walls 102 and 104 ofthe member.
  • the reinforcing web 1 10 is continuous along at least a selected portion ofthe length ofthe member 100.
  • the illustrated member 100 thus has a hollow tubular interior within the walls 102-108, aside from the web 110.
  • two elongated strips of fabric 112 and 114 are formed into side-by-side closed quadrilateral tubes.
  • An elongated strip of fabric 116 is then formed into a closed tube enclosing the two side-by-side tubes formed by the fabrics 112 and 114.
  • a ply 118 of axially-extending fibers is then disposed over the layer formed by the fabric 116.
  • Another elongated strip of fabric 120 is formed into a closed tube enclosing the fiber ply 118 (and the structure therein formed by the fabrics 116, 114 and 112).
  • An outer ply of the structural member is formed by an elongated strip of fabric 122, also formed into a tubular enclosure.
  • the foregoing procedure of fabricating the member 100 can advantageously be practiced in a pultrusion system with a fixed, i.e., stationary, mandrel on which the fabric and fiber layers are formed, and within an outer die-like forming member.
  • each fabric 112 and 114 is a preformed fabric having fibers, typically of fiberglass, carbon or aramid, and oriented at zero degrees and at ninety degrees relative to the longitudinal length ofthe member 100.
  • Such a fabric commonly has a woven structure.
  • the fabric 116 in this embodiment is a preformed fabric, preferably non- woven, i.e., of stitched or knitted structure, with fibers oriented at ⁇ forty-five degrees relative to the longitudinal axis ofthe member 100.
  • a fabric 116 thus forms an inner ply ofthe member 100 and which has a biaxial fiber component.
  • the illustrated member 100 thus has an inner ply having two subplies, one formed by the fabric 116 and another formed by the fabric 112 and 114.
  • the fabric 116 can be, for example, of glass, carbon or aramid fibers.
  • the fibers in the ply 118 can be of carbon or of glass, or can be a hybrid, i.e., a combination of glass and of carbon, by way of example. These fibers form the ply 118 as an intermediate ply in the member 100 and with at least an axial fiber component.
  • the fabric 120 in the illustrated embodiment is a preformed fabric of glass and/or carbon, preferably of non- woven structure and having fibers oriented at ⁇ forty-five degrees relative to the member longitudinal axis. This fabric thus forms an outer ply ofthe member 100 and which also has a biaxial fiber component.
  • the fabric 122 that forms the illustrated outer ply ofthe member 100 is preferably a preformed fabric typically of woven structure, with fibers oriented at zero and at ninety degrees relative to the longitudinal axis ofthe member 100. This fabric 122 forms an exterior ply ofthe member, external to the outer ply formed with the fabric 120.
  • each layer in the member 100 provides internal impact resistance, particularly by forming the intemal reinforcing web 110.
  • Each fabric 116 and fabric 118 forms a ply providing torsional stiffness to the member 100.
  • the axially-oriented fibers in the ply 118 provide bending load strength, i.e., axial stiffness to the member 100.
  • the fabric 122 provides extemal wear resistance to the member 100.
  • the member 100 can be further formed, prior to curing, with one or more light gauze or surface veil plies 126 of preformed gauze or veil-like fiber that is highly resin-absorbent. These surface gauze or veil plies enhance the abrasion resistance ofthe member 100 and can provide an attractive surface finish.
  • the invention can be practiced, in one instance, with fibers oriented at angles other than those for the particular embodiment described above.
  • the fabrics 112 and 114 can be arranged with the fibers oriented generally between ⁇ 30° and between 60° and 120° relative to the longitudinal axis ofthe member 100. More preferred ranges of fiber angles for these fabrics are ⁇ 15° and between 75° and 115° relative to that axis.
  • each fabric 116 and 120 can be arranged with fibers oriented between ⁇ 30° and ⁇ 60° relative to the longitudinal axis ofthe member 100. More preferred ranges ofthe fiber angles for each of these fabrics are between ⁇ 40° and ⁇ 50°. Further, in most practices of the invention, the two sets of fibers of each fabric — which generally are orthogonal to each other within the fabric — are oriented on the member symmetrically relative to the longitudinal axis ofthe member.
  • the longitudinal seams ofthe different strips of fabric that form the several plies of the member 100 are preferably formed at different, spaced apart locations in the member 100.
  • the longitudinal seams in the tubes formed by the fabrics 112 and 114 can be disposed along opposed member walls 106 and 108.
  • the longitudinal seams ofthe fabrics 116, 120 and 122 can also be located along different walls ofthe member 100.
  • a composite member having the stracture described and shown has high bending strength and stiffness, and high torsional rigidity. It also has, through the wall thickness, durability and impact resistance. Further by way of illustrative example and without limitation, a member 100 as described above and shown in Figure 1 and suited for use as a hockey stick shaft can have a web thickness of 0.034 inch and a thickness in each wall 102, 104, 106 and 108 of 0.082 inch.
  • Figure 2 shows another construction for a member 100', which illustratively has a quadralateral cross section transverse to an elongation axis, as shown.
  • the member 100' has an inner ply 116' with a biaxial fiber component, an intermediate layer 118' with a triaxial fiber component, and an extemal ply 122' illustratively having a woven fiber component with a 0 90° fiber orientation.
  • the illustrated member 100' also has an outer ply 120' interposed between the intermediate ply 118' and the extemal ply 122', and which illustratively also has a biaxial fiber component similar to the inner ply 116'. Further, each biaxial fiber component ofthe inner and outer plies 116' and 120' includes a stitching fiber 116A' and 118 A'. The foregoing fiber components ofthe member 100' are embedded in a resin matrix that extends through all the plies to form the fiber components into a single unitary structure.
  • the member 100' of Figure 2 may have a reinforcing rib 110' as shown in phantom.
  • a surface veil 126' preferably is applied over the outer surface ofthe member 100', as
  • Another elongated reinforced composite member 130 has a web 132 secured to and spanning between opposed walls 130A and 130B. Altematively, the web 132 can span between walls ofthe composite member 130, other than 130A and 130B.
  • the illustrated web 132 has a core 134 enclosed within a fibrous sleeve 136.
  • the core 134 can be of various materials depending on the weight and strength requirements, examples of which are wood and plastic, typically rigid, synthetic resin foam.
  • the core 134 ofthe web 132 in other practices can be partially or entirely hollow and can altematively employ a laminated stracture with different layers, typically of wood and/or synthetic materials.
  • the fibrous sleeve 136 can be woven, braided or otherwise formed over the core 134. Another practice is to insert the core 134 into a preformed hose of fibrous material that constitutes the sleeve 136. In either case, the sleeve 136 can be formed of fiberglass, carbon, or kevlar, or a hybrid combination thereof.
  • Figure 3 further shows that during illustrative fabrication ofthe member 130, the web 132 formed by the core 134 within the fibrous sleeve 136 is seated between two tines or side- by-side legs 138A and 138B of a mandrel 138 having an end portion 138C that joins together the two tines or legs.
  • the several fibrous plies that form the walls ofthe member 130 are then formed, in succession, over the mandrel 138 and thus are formed or built up onto the assembled core and sleeve, which are held in place between the tines ofthe mandrel onto which the walls are formed.
  • the mandrel is removed from the member 130, typically after all the plies are applied and before the end ofthe manufacturing process.
  • Figure 4 shows a transverse cross section and longitudinal fragment of a composite tubular member 150 having walls 152, 154, 156 and 158.
  • the tubular member 150 can be constructed as described above with reference to Figures 1, 2, and 3, and as further described in Attachment A, to form, for example, the shaft of a hockey stick.
  • Each wall 152 and 154 of the member, which together form a pair of opposed walls, is concave.
  • the concavity ofthe opposed walls preferably is symmetrical, as shown.
  • One preferred construction ofthe member 150 has a magnitude of concavity ofthe opposed walls 152 and 154 such that the minimum width ofthe shaft at the mid-point ofthe concavity, designated in Figure 4 as (X), is less than the maximum width ofthe shaft, designated as (Y), by the equation y ⁇ l.Ol x (Eq. 1)
  • Figure 5 illustrates another form ofthe quadrilateral composite member 152' in which both pairs of opposed walls 152' and 154' and 156' and 158' are concave.
  • the preferred magnitude of concavity of each pair of opposed walls is in accord with equation (1).
  • the concavity ofthe opposed walls 152' and 154' is preferably symmetrical, as is the concavity of the opposed walls 156' and 158'.
  • Figure 6 shows a longitudinal fragment of a composite member 160, such as a hockey stick shaft or a lacrosse stick shaft, having a rectangular cross section with top and bottom walls 162 and 164 thicker than side walls 166 and 168.
  • a composite member 160 such as a hockey stick shaft or a lacrosse stick shaft
  • This configuration is typical in a hockey stick shaft.
  • Each wall 162, 164, 166 and 168 ofthe illustrated member 160 has uniform thickness, in the cross section shown in Figure 6, except at the comer where it joins another wall.
  • the outer periphery ofthe four walls has a right rectangular cross section, and the periphery ofthe inner surfaces is similar but with comers beveled at approximately 45° angles or with the inner surfaces ofthe comers having a radius to create the desired increased thickness in the comer.
  • Equation 2 One preferred magnitude ofthe difference in wall thickness is in accord with Equation 2 below, where the dimension (A) is the minimal thickness of a wall, e.g., at its midpoint, and the dimension (B) is the thickness of that wall as measured in the same direction, at one comer thereof.
  • a composite member 170 having five equal-width walls 172, 174, 176, 178 and 180, i.e., which is pentagonal in a cross section transverse to the length as shown in Figure 7, has a maximal wall thickness in each wall at the comers, similar to the construction ofthe member 160 of Figure 6.
  • the illustrated stracture ofthe composite member 170 is regular, in that all walls and all comers are the same as others, and all included angles ofthe pentagonal cross section are equal.
  • the maximal wall thickness at a comer, designated (B) is greater than the minimal wall thickness, designated (A), and the two thicknesses of each wall preferably are in accord with Equation (2).
  • Figure 8 shows a structure 182 similar to the member 170 of Figure 7. except that it has a hexagonal cross section, as illustrative ofthe shaft of a lacrosse stick.
  • the member is elongated along an axis 184, as are the members shown in other figures.
  • Figure 9 shows a composite member 186 having multiple features in accord with the invention.
  • the illustrated member 186 has concave walls and each wall 188 and 190 in one pair of opposed walls has a greater thickness than in the other pair of opposed walls 192 and 194.
  • the member 186 has a third feature, namely that the walls have added thickness at comers.
  • Each wall ofthe illustrated member 186 has uniform thickness along the width ofthe wall, except at each comer, where the wall thickness is larger.
  • the increased wall thickness at each comer preferably is in accord with Equation 2, which relates minimum thickness of a wall (A) to the maximal thickness (B) of that wall.
  • each member 150, 160, 170, 182 and 186 is preferably continuous along at least a selected length, i.e., has the same cross section at successive locations along that selected length.
  • This continuous cross sectional configuration facilitates manufacture, for example, with pultrusion procedures as described in Attachment A.
  • the different wall thicknesses at different locations circumferentially about the cross section of each member 150, 160, 170, 182 and 186 can be attained with added resin, and can be attained with a combination of added resin and added fibers, typically axial, i.e., longitudinal.
  • each member 150, 160, 170, 182 and 184 has a varying cross-sectional geometry along the length ofthe composite member.
  • Such members having a varying cross-section can be produced with a molding process.
  • These members with varying geometry advantageously provide a higher performance tubular member having, as compared to those members produced by a pultrusion process, an increased strength per weight ratio.
  • FIGS 10, 11, 12 and 13 illustrate, respectively, composite members 200, 202, 204 and 206, each of which incorporates intemal reinforcement.
  • each composite member 200-206 is illustrated with uniform thickness throughout the walls including comers.
  • the intemal reinforcement shown and described below preferably is combined with one or more ofthe structural features described above with reference to Figures 4 through 9.
  • the intemal reinforcement of member 200 in Figure 10 is a tube 200a that spans between and is joined solidly to opposed walls 200b and 200c ofthe member.
  • the reinforcing tube 200a is continuous along at least a selected portion ofthe length ofthe member 200.
  • the member 202 of Figure 11 has an intemal reinforcing web 202a joined to and spanning between a pair of opposed walls 202b and 202c ofthe member. These are illustrated as the wider walls ofthe member and the web 202a is preferably continuous along at least a selected length ofthe member 202.
  • the reinforcing web 202a is secured within the member 202 after each such element has been initially formed.
  • the web 202a typically has the cross section of an I beam, as illustrated.
  • the web 202a is formed during the formation ofthe member 202, as in a pultrusion or a molding fabrication, and hence is formed integrally with the walls 202b and 202c; the thickness of those walls can be increased slightly adjacent the juncture with the web 202a, to form structure corresponding to the flanges on a conventional I beam.
  • the structures described above with reference to Figures 1 , 2 and 3 are further altematives for attaining the member 202 with the web 202a.
  • the hexagonal composite member 204 of Figure 12 has a regular hexagonal cross section and has a multiple-element intemal reinforcement member 204a.
  • the illustrated reinforcement member 204a has a transverse cross section as shown, configured with six radially extending spoke-like reinforcement elements uniformly spaced around the circumference and each joined at its radially outer end to the midpoint of one wall ofthe member 204. Further, the radial elements are joined together at their intersection, at the midpoint or axial center ofthe composite member 204.
  • the composite member 204 of Figure 12 can, for example, be the shaft of a lacrosse stick, and each composite member 200, 202 of Figures 10 and 11 can be incorporated in the shaft of a hockey stick.
  • a tubular composite member can have an intemal reinforcing element that is a foam-filled tubular core.
  • Figure 13 illustrates this practice ofthe invention with a tubular composite member 206 that is internally reinforced with a tubular core element 206a, the intemal hollow of which is filled with an expanded polymer resin foam 206b.
  • Figure 14 illustrates a practice ofthe invention with a tubular composite member 210, illustratively circular in cross section, and formed as in a pultrusion process, as described in Attachment A, with one or more selectively circumferentially located intemal ribs.
  • the illustrated member 210 has four such ribs. 210a, 210b, 210c and 210d, equally spaced about the circumference ofthe circular cross section.
  • Figure 15 illustrates a practice ofthe invention with intemal reinforcement of a tubular composite member where the reinforcement is not continuous along the length ofthe member.
  • the tubular composite member 212 of Figure 15 is internally reinforced with an element 212a that is at least partially preformed, e.g., with partial curing of polymer resin and which is finally cured or cured to the final stage after assembly within the composite member.
  • the preformed reinforcement element 212a as shown, is similar to an I- beam stracture having a web spanning between end flanges. However, the web is discontinuous and has only an axially succession of web-like braces 212b that extend diametrically between opposed walls or wall portions ofthe composite member 212.
  • the discontinuous reinforcing element 212a can be formed as a discontinuous member, or it can be formed as a continuous member which is further processed to remove sections along the reinforcing element.
  • the reinforcing element 212a provides a stracture that selectively reduces the total weight ofthe composite member while providing selective reinforcement to the composite member.
  • the hockey stick 214 has a conventional blade 214a, secured at a lower end ofthe shaft 214a, and has a cap 214c secured to the upper other end ofthe shaft 214a.
  • the illustrated shaft 214a has intemal reinforcement 214d, as described above with reference to any of Figures 10, 11, 12, 13, 14 and 15, extending for a portion only ofthe length ofthe shaft.
  • the lacrosse stick 216 of Figure 17 has a conventional lacrosse net 216b secured to one end of a lacrosse handle shaft 216a.
  • the shaft has an intemal reinforcement element 216d extending at least along the lower portion, i.e., the portion to which the net 216b is secured.
  • Each shaft 214A and 216B thus is axially elongated with a handle portion at one end. At the other end. the shaft has a socket-like receptacle or other stracture for seating and thereby mounting a sports implement.
  • This implement is the hockey blade 214A in the embodiment of Figure 16 and is the lacrosse net 216B in the embodiment of Figure 17.

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Abstract

An axially extending tubular composite member (100) having a plurality of plies and extending along a longitudinal axis has at least three plies (116, 118, 120) with selectively structured fiber components in each ply. Typically an inner ply (116) has at least one biaxial fiber component, an intermediate ply (118) has at least an axial fiber component that typically is combined with two further fibers to form a triaxial fiber component. Another ply (120) typically has a woven fiber component. A further ply having a biaxial component either replaces the ply of woven fiber or is disposed beneath it over the intermediate ply. A surface veil (122) having fiber and an excess of resin material typically covers at least the innermost or outermost surface of the composite member. An internal web member (112, 114) can be provided, and typically also employs fibers and the matrix material.

Description

COMPOSITE TUBULAR MEMBER HAVING CONSISTENT STRENGTH AND METHOD
Background This invention provides resin-fiber composite tubular members having unique combinations of fiber orientations in different plies, and having selected other reinforcement.
The composite members ofthe invention are advantageously used in various manufactured products, including sports implements such as golf clubs and hockey sticks among others.
Sports implements have long been made with various materials including wood and particularly wood shafts. Wood implements can have high strength as desired and can have a satisfying feel for the user. One drawback of wood, however, is significant variation from item to item, even when made to the same specifications and dimensions.
Among the known practices regarding fiber-reinforced resin tubular materials are the bicycle frame structure disclosed in U.S. Patent No. 4,657,795 of Foret. Also in the prior art are U.S. Patents Nos. 5,048.441; 5,188,872; and No. RE 35,081.
One object of this invention is to provide composite tubular members suited for the shaft of a sports implement. Other objects ofthe invention will in part be obvious and will in part appear hereinafter.
Summarv ofthe Invention
The tubular members which the invention provides have resin-fiber composite construction with improvements in durability and particularly in bending strength and in impact strength. Further, the tubular members are generally suited for relatively low cost manufacture.
The tubular members ofthe invention have one or more plies of fibers. In one practice, the multiple-ply composite members are constructed according to manufacture methods described in Attachment A, which is a copy ofthe commonly-assigned U.S. Patent Application Serial No. 08/191,856 filed 3 February 1994 and incoφorated herein by this reference.
Typically, an axially extending tubular composite member according to the invention has a plurality of plies. At least some plies include substantially continuous fibers. The composite member has a primary bending stiffness along a longitudinal axis. The tubular composite member generally has at least three plies, including an inner or interior ply that commonly has at least one biaxial fiber component embedded in the matrix material. As used herein a biaxially fiber component includes two sets of fibers or threads spirally wrapping in opposite directions about the axially extending composite member. The two sets of fibers thus are generally symmetrical and generally extend diagonally relative to the axis ofthe member.
An intermediate ply ofthe composite member typically has at least one axially extending fiber component also disposed with the resin or other matrix material. The intermediate ply is disposed contiguously over the interior ply and hence is exterior to the interior ply. The axial fiber component ofthe intermediate ply can be a substantially continuous set of fibers extending essentially parallel to the elongation axis ofthe composite member. Alternatively, a set of axially extending fibers can follow a helical path, i.e., extend at an acute angle relative to the elongation axis. In one practice the axial fiber is interlaced with two other sets of threads or fibers extending symmetrically in opposite directions relative to the axial fiber, to constitute so-called triaxial fiber structure. The interlacing or diagonally extending sets of fibers enhance maintaining the axially extending fibers in place and they add strength, including preventing cracks and other stress failures or fractures from propagating.
In one practice ofthe invention a further ply overlying the intermediate ply has a woven fiber component. In a typical embodiment, the woven fiber component has the two sets of fibers, and one is oriented axially and the other transversely relative to the longitudinal axis, i.e., a so-called 0° and 90° fiber orientation relative to the elongation axis.
A further practice ofthe invention employs an outer ply having at least one biaxial fiber component and located over the intermediate ply and either in place of a woven fiber component as described above or beneath such a woven fiber component.
Aside from applying fiber components in woven form, they can be formed with continuous fiber strands drawn from spools as described in Attachment A. Alternatives include applying the fibers in preformed fibrous sheets. Furthermore, the fibers can be braided, stitched or knitted.
Figure imgf000004_0001
It is also to be understood that each ply can include two or more subplies. By way of example, the inner ply of a tubular member according to the invention can have two subplies, each with a biaxial fiber component. In a further example, the biaxial fibers can have different fiber angles, relative to the elongation axis, in the two subplies. A typical further element of a composite member according to the invention is a surface veil, forming either the extreme outer surface ofthe member or the extreme tubular inner surface, or both. Such a surface veil can facilitate the manufacture ofthe member, particularly in a pultrusion manufacture. An exterior veil can enhance appearance, an interior veil can improve impact resistance. As is known in the art, a surface veil for these purposes has a relatively large proportion of resin and a relatively lesser fiber component.
The fibers of a composite member according to the invention are generally selected, using known criteria, from materials including carbon, aramid, glass, linear polyethylene, polyethylene, polyester, and mixtures thereof.
The matrix material is selected from a group of resin-based materials, such as thermoplastics and thermosets. Examples of thermoplastics include: polyetherether-ketone, polyphenyiene sulfide, polyethylene, polypropylene, and Nylon-6. Examples of thermosets include: urethanes, epoxy, vinylester, and polyester.
In a further practice ofthe invention, tubular members having a resin-fiber composite structure have improvements in durability and particularly in impact strength, and yet retain light weight, when constructed with one or more additional structural elements. Such structural elements which the invention provides include selectively concave walls, selected added thickness at corners of walls, added thickness selectively in each of two opposed walls, and internal reinforcement.
The first three features stated above, i.e., concave walls, thickened corners, and thickened walls, are applicable to members having a non-circular cross section and typically to members having a polygonal cross-section. A preferred polygonal cross-section has four or more sides.
The foregoing structural features preferably are used in combination with one another, such as opposed concave walls combined with added wall thickness at the corners of those walls, or added thickness at opposed walls and added thickness at the corners of those walls.
The internal reinforcement is applicable in structures having any of various cross sections, examples of which include a polygonal cross section and a circular cross section. Examples of such reinforcement include an interior rib extending along at least a portion of the length ofthe member, either essentially parallel to the axis or length ofthe member or selectively angled, e.g., helical, with regard to the axis of a straight member. Such a rib is preferably provided on each of two opposed walls. Another example of such internal reinforcement is an interior web. or an axially spaced succession of interior braces, spanning between opposed walls or between adjacent walls. For example, an interior web or brace in a composite tubular member according to one embodiment ofthe invention and having a circular or elliptical cross section can follow the path of a chord extending between two locations spaced apart around the circumference ofthe composite member, when viewed in cross section. Correspondingly, in a structure having a polygonal cross section, the internal web or brace extends between adjacent walls. Further examples include such braces or webs extending between opposed walls or wall portions, including along the path of a diameter of a member having a circular or elliptical cross section.
The interior reinforcement can extend along the full length ofthe member or along only part ofthe length. The latter may be preferred, for example, to decrease weight and to control stiffness.
In one preferred practice, the internal reinforcement is formed during the initial pultrusion fabrication ofthe composite member and accordingly is continuous along the length ofthe member, or at least along a selected portion thereof. Where such an internal reinforcing web is formed continuously along the length of a member, it can subsequently be removed, as by machining, from one or more selected portions ofthe length ofthe member. This may be desired to reduce the weight ofthe member.
A further alternative is to fabricate the composite member and add internal reinforcement, by inserting a preformed internal reinforcement element. The internal reinforcement element preferably is added prior to final curing ofthe polymers ofthe composite member and ofthe reinforcement element to ensure a solid attachment ofthe internal reinforcement member element to the composite member. In accordance with another method of fabrication, the composite member and the internal reinforcing element are formed concurrently as part of a resin transfer or compression molding process. This fabrication method provides a system capable of forming a composite member integral with an internal reinforcing element, both having selective characteristics along the length ofthe member.
The invention accordingly comprises an article of manufacture possessing features, properties and relations of elements exemplified in the articles hereinafter described. and comprises the several steps and the relation of one or more of such steps with respect to each ofthe others for fabricating such articles, and the scope ofthe invention is indicated in the claims. Brief Description of Drawing
For a fuller understanding ofthe nature and objects ofthe invention, reference is to be made to the following detailed description and the accompanying drawing, in which:
FIGURE 1 shows a transverse cross-section and longitudinal fragment of a composite tubular member according to one practice ofthe invention;
FIGURE 2 shows a transverse cross-section and longitudinal fragment of a composite tubular member according to a further practice ofthe invention;
FIGURE 3 shows a transverse cross-section and longitudinal fragment of a composite tubular member according to yet another practice ofthe invention;
FIGURES 4 through 9 show transverse cross-section and longitudinal fragments of composite tubular members according to further practices of the invention and having selectively configured and reinforced wall portions;
FIGURES 10 through 15 show transverse cross-section and longitudinal fragments of composite tubular members according to further practices ofthe invention and having internal reinforcement; and
FIGURES 16 and 17 show sports implements, namely, a hockey stick and a lacrosse stick utilizing shafts according to the invention.
Description of Illustrated Embodiments
Figure 1 shows a transverse cross section and longitudinal fragment of a composite tubular member 100 according to one preferred practice ofthe invention. The illustrated member 100 has a rectangular cross section with two wide opposed walls 102 and 104 and two narrow opposed walls 106 and 108. The tubular member 100 can be constructed essentially as described in Attachment A to form, for example, the shaft of a hockey stick or of a lacrosse stick. Each wall 102, 104, 106 and 108 ofthe illustrated member 100 has generally uniform thickness along the length ofthe member and the four walls are of essentially the same thickness. Thus, the illustrated member 100 is preferably continuous along at least a selected length, i.e., has the same cross section at successive locations along that selected length. This continuous cross sectional configuration facilitates manufacture, for example with pultrusion procedures as described in Attachment A.
The member 100 further has, as also shown in Figure 1, internal reinforcement in the form of a web 110 that spans between and is joined solidly to the opposed wider walls 102 and 104 ofthe member. The reinforcing web 1 10 is continuous along at least a selected portion ofthe length ofthe member 100. The illustrated member 100 thus has a hollow tubular interior within the walls 102-108, aside from the web 110.
In a preferred embodiment ofthe member 100, as shown, two elongated strips of fabric 112 and 114 are formed into side-by-side closed quadrilateral tubes. The abutting walls ofthe two tubes, as formed by the fabric, form the web 110 of the member 100.
An elongated strip of fabric 116 is then formed into a closed tube enclosing the two side-by-side tubes formed by the fabrics 112 and 114.
A ply 118 of axially-extending fibers is then disposed over the layer formed by the fabric 116.
Another elongated strip of fabric 120 is formed into a closed tube enclosing the fiber ply 118 (and the structure therein formed by the fabrics 116, 114 and 112). An outer ply of the structural member is formed by an elongated strip of fabric 122, also formed into a tubular enclosure.
The foregoing assemblage of fiber plies is impregnated with resin 124, typically an epoxy resin, and the resultant composite is cured.
The foregoing procedure of fabricating the member 100 can advantageously be practiced in a pultrusion system with a fixed, i.e., stationary, mandrel on which the fabric and fiber layers are formed, and within an outer die-like forming member.
In one preferred embodiment ofthe member 100, each fabric 112 and 114 is a preformed fabric having fibers, typically of fiberglass, carbon or aramid, and oriented at zero degrees and at ninety degrees relative to the longitudinal length ofthe member 100. Such a fabric commonly has a woven structure.
The fabric 116 in this embodiment is a preformed fabric, preferably non- woven, i.e., of stitched or knitted structure, with fibers oriented at ± forty-five degrees relative to the longitudinal axis ofthe member 100. Alternatively, braided or woven fabrics oriented at ± forty-five degrees relative to the longitudinal axis ofthe member 100 may be used. Such a fabric 116 thus forms an inner ply ofthe member 100 and which has a biaxial fiber component. The fabrics 112 and 114, which are within the ply formed by the fabric 116, form another inner ply ofthe member 100. The illustrated member 100 thus has an inner ply having two subplies, one formed by the fabric 116 and another formed by the fabric 112 and 114. The fabric 116 can be, for example, of glass, carbon or aramid fibers.
The fibers in the ply 118 can be of carbon or of glass, or can be a hybrid, i.e., a combination of glass and of carbon, by way of example. These fibers form the ply 118 as an intermediate ply in the member 100 and with at least an axial fiber component.
The fabric 120 in the illustrated embodiment is a preformed fabric of glass and/or carbon, preferably of non- woven structure and having fibers oriented at ± forty-five degrees relative to the member longitudinal axis. This fabric thus forms an outer ply ofthe member 100 and which also has a biaxial fiber component.
The fabric 122 that forms the illustrated outer ply ofthe member 100 is preferably a preformed fabric typically of woven structure, with fibers oriented at zero and at ninety degrees relative to the longitudinal axis ofthe member 100. This fabric 122 forms an exterior ply ofthe member, external to the outer ply formed with the fabric 120.
The primary function of each layer in the member 100 is that the innermost fabrics 112 and 114 provide internal impact resistance, particularly by forming the intemal reinforcing web 110. Each fabric 116 and fabric 118 forms a ply providing torsional stiffness to the member 100. The axially-oriented fibers in the ply 118 provide bending load strength, i.e., axial stiffness to the member 100. The fabric 122 provides extemal wear resistance to the member 100.
The member 100 can be further formed, prior to curing, with one or more light gauze or surface veil plies 126 of preformed gauze or veil-like fiber that is highly resin-absorbent. These surface gauze or veil plies enhance the abrasion resistance ofthe member 100 and can provide an attractive surface finish.
More generally, the invention can be practiced, in one instance, with fibers oriented at angles other than those for the particular embodiment described above. For example, the fabrics 112 and 114 can be arranged with the fibers oriented generally between ± 30° and between 60° and 120° relative to the longitudinal axis ofthe member 100. More preferred ranges of fiber angles for these fabrics are ± 15° and between 75° and 115° relative to that axis.
Similarly, each fabric 116 and 120 can be arranged with fibers oriented between ± 30° and ± 60° relative to the longitudinal axis ofthe member 100. More preferred ranges ofthe fiber angles for each of these fabrics are between ± 40° and ± 50°. Further, in most practices of the invention, the two sets of fibers of each fabric — which generally are orthogonal to each other within the fabric — are oriented on the member symmetrically relative to the longitudinal axis ofthe member.
The longitudinal seams ofthe different strips of fabric that form the several plies of the member 100, as described above, are preferably formed at different, spaced apart locations in the member 100. For example, the longitudinal seams in the tubes formed by the fabrics 112 and 114 can be disposed along opposed member walls 106 and 108. The longitudinal seams ofthe fabrics 116, 120 and 122 can also be located along different walls ofthe member 100.
Features attained with a composite member having the stracture described and shown are that it has high bending strength and stiffness, and high torsional rigidity. It also has, through the wall thickness, durability and impact resistance. Further by way of illustrative example and without limitation, a member 100 as described above and shown in Figure 1 and suited for use as a hockey stick shaft can have a web thickness of 0.034 inch and a thickness in each wall 102, 104, 106 and 108 of 0.082 inch.
Figure 2 shows another construction for a member 100', which illustratively has a quadralateral cross section transverse to an elongation axis, as shown. The member 100' has an inner ply 116' with a biaxial fiber component, an intermediate layer 118' with a triaxial fiber component, and an extemal ply 122' illustratively having a woven fiber component with a 0 90° fiber orientation.
The illustrated member 100' also has an outer ply 120' interposed between the intermediate ply 118' and the extemal ply 122', and which illustratively also has a biaxial fiber component similar to the inner ply 116'. Further, each biaxial fiber component ofthe inner and outer plies 116' and 120' includes a stitching fiber 116A' and 118 A'. The foregoing fiber components ofthe member 100' are embedded in a resin matrix that extends through all the plies to form the fiber components into a single unitary structure.
Although illustrated with a hollow reinforcement-free interior, the member 100' of Figure 2 altematively can have a reinforcing rib 110' as shown in phantom.
A surface veil 126' preferably is applied over the outer surface ofthe member 100', as
Figure 2 further shows.
Another elongated reinforced composite member 130, according to the invention and as shown in Figure 3, has a web 132 secured to and spanning between opposed walls 130A and 130B. Altematively, the web 132 can span between walls ofthe composite member 130, other than 130A and 130B. The illustrated web 132 has a core 134 enclosed within a fibrous sleeve 136. The core 134 can be of various materials depending on the weight and strength requirements, examples of which are wood and plastic, typically rigid, synthetic resin foam. The core 134 ofthe web 132 in other practices can be partially or entirely hollow and can altematively employ a laminated stracture with different layers, typically of wood and/or synthetic materials.
The fibrous sleeve 136 can be woven, braided or otherwise formed over the core 134. Another practice is to insert the core 134 into a preformed hose of fibrous material that constitutes the sleeve 136. In either case, the sleeve 136 can be formed of fiberglass, carbon, or kevlar, or a hybrid combination thereof.
Figure 3 further shows that during illustrative fabrication ofthe member 130, the web 132 formed by the core 134 within the fibrous sleeve 136 is seated between two tines or side- by-side legs 138A and 138B of a mandrel 138 having an end portion 138C that joins together the two tines or legs.
The several fibrous plies that form the walls ofthe member 130 are then formed, in succession, over the mandrel 138 and thus are formed or built up onto the assembled core and sleeve, which are held in place between the tines ofthe mandrel onto which the walls are formed.
An innermost surface veil, with a fiber stracture and excess resin, preferably is the first layer formed onto the mandrel 138, to facilitate the manufacture ofthe member 130 onto the mandrel 138. The mandrel is removed from the member 130, typically after all the plies are applied and before the end ofthe manufacturing process.
Figure 4 shows a transverse cross section and longitudinal fragment of a composite tubular member 150 having walls 152, 154, 156 and 158. The tubular member 150 can be constructed as described above with reference to Figures 1, 2, and 3, and as further described in Attachment A, to form, for example, the shaft of a hockey stick. Each wall 152 and 154 of the member, which together form a pair of opposed walls, is concave. The concavity ofthe opposed walls preferably is symmetrical, as shown.
One preferred construction ofthe member 150 has a magnitude of concavity ofthe opposed walls 152 and 154 such that the minimum width ofthe shaft at the mid-point ofthe concavity, designated in Figure 4 as (X), is less than the maximum width ofthe shaft, designated as (Y), by the equation y ≥ l.Ol x (Eq. 1)
Figure 5 illustrates another form ofthe quadrilateral composite member 152' in which both pairs of opposed walls 152' and 154' and 156' and 158' are concave. The preferred magnitude of concavity of each pair of opposed walls is in accord with equation (1). The concavity ofthe opposed walls 152' and 154' is preferably symmetrical, as is the concavity of the opposed walls 156' and 158'.
Figure 6 shows a longitudinal fragment of a composite member 160, such as a hockey stick shaft or a lacrosse stick shaft, having a rectangular cross section with top and bottom walls 162 and 164 thicker than side walls 166 and 168. This configuration is typical in a hockey stick shaft. Each wall 162, 164, 166 and 168 ofthe illustrated member 160 has uniform thickness, in the cross section shown in Figure 6, except at the comer where it joins another wall. In the illustrated composite member 160, the outer periphery ofthe four walls has a right rectangular cross section, and the periphery ofthe inner surfaces is similar but with comers beveled at approximately 45° angles or with the inner surfaces ofthe comers having a radius to create the desired increased thickness in the comer. One preferred magnitude ofthe difference in wall thickness is in accord with Equation 2 below, where the dimension (A) is the minimal thickness of a wall, e.g., at its midpoint, and the dimension (B) is the thickness of that wall as measured in the same direction, at one comer thereof.
B > 1.05 A (Eq. 2)
A composite member 170 having five equal-width walls 172, 174, 176, 178 and 180, i.e., which is pentagonal in a cross section transverse to the length as shown in Figure 7, has a maximal wall thickness in each wall at the comers, similar to the construction ofthe member 160 of Figure 6. The illustrated stracture ofthe composite member 170 is regular, in that all walls and all comers are the same as others, and all included angles ofthe pentagonal cross section are equal. The maximal wall thickness at a comer, designated (B), is greater than the minimal wall thickness, designated (A), and the two thicknesses of each wall preferably are in accord with Equation (2).
Figure 8 shows a structure 182 similar to the member 170 of Figure 7. except that it has a hexagonal cross section, as illustrative ofthe shaft of a lacrosse stick. The member is elongated along an axis 184, as are the members shown in other figures.
Figure 9 shows a composite member 186 having multiple features in accord with the invention. In particular, the illustrated member 186 has concave walls and each wall 188 and 190 in one pair of opposed walls has a greater thickness than in the other pair of opposed walls 192 and 194. The member 186 has a third feature, namely that the walls have added thickness at comers. Each wall ofthe illustrated member 186 has uniform thickness along the width ofthe wall, except at each comer, where the wall thickness is larger. The increased wall thickness at each comer preferably is in accord with Equation 2, which relates minimum thickness of a wall (A) to the maximal thickness (B) of that wall.
In accordance with one aspect, each member 150, 160, 170, 182 and 186, shown in Figures 4, 5, 6, 7, 8 and 9 respectively, is preferably continuous along at least a selected length, i.e., has the same cross section at successive locations along that selected length. This continuous cross sectional configuration facilitates manufacture, for example, with pultrusion procedures as described in Attachment A. The different wall thicknesses at different locations circumferentially about the cross section of each member 150, 160, 170, 182 and 186 can be attained with added resin, and can be attained with a combination of added resin and added fibers, typically axial, i.e., longitudinal.
In another aspect ofthe invention, each member 150, 160, 170, 182 and 184, has a varying cross-sectional geometry along the length ofthe composite member. Such members having a varying cross-section can be produced with a molding process. These members with varying geometry advantageously provide a higher performance tubular member having, as compared to those members produced by a pultrusion process, an increased strength per weight ratio.
Figures 10, 11, 12 and 13 illustrate, respectively, composite members 200, 202, 204 and 206, each of which incorporates intemal reinforcement. For clarity of illustration, each composite member 200-206 is illustrated with uniform thickness throughout the walls including comers. However, the intemal reinforcement shown and described below preferably is combined with one or more ofthe structural features described above with reference to Figures 4 through 9.
The intemal reinforcement of member 200 in Figure 10 is a tube 200a that spans between and is joined solidly to opposed walls 200b and 200c ofthe member. The reinforcing tube 200a is continuous along at least a selected portion ofthe length ofthe member 200.
The member 202 of Figure 11 has an intemal reinforcing web 202a joined to and spanning between a pair of opposed walls 202b and 202c ofthe member. These are illustrated as the wider walls ofthe member and the web 202a is preferably continuous along at least a selected length ofthe member 202. The reinforcing web 202a is secured within the member 202 after each such element has been initially formed. The web 202a typically has the cross section of an I beam, as illustrated. In other practices ofthe invention, the web 202a is formed during the formation ofthe member 202, as in a pultrusion or a molding fabrication, and hence is formed integrally with the walls 202b and 202c; the thickness of those walls can be increased slightly adjacent the juncture with the web 202a, to form structure corresponding to the flanges on a conventional I beam. The structures described above with reference to Figures 1 , 2 and 3 are further altematives for attaining the member 202 with the web 202a.
The hexagonal composite member 204 of Figure 12 has a regular hexagonal cross section and has a multiple-element intemal reinforcement member 204a. The illustrated reinforcement member 204a has a transverse cross section as shown, configured with six radially extending spoke-like reinforcement elements uniformly spaced around the circumference and each joined at its radially outer end to the midpoint of one wall ofthe member 204. Further, the radial elements are joined together at their intersection, at the midpoint or axial center ofthe composite member 204.
The composite member 204 of Figure 12 can, for example, be the shaft of a lacrosse stick, and each composite member 200, 202 of Figures 10 and 11 can be incorporated in the shaft of a hockey stick.
As a further feature ofthe invention, a tubular composite member can have an intemal reinforcing element that is a foam-filled tubular core. Figure 13 illustrates this practice ofthe invention with a tubular composite member 206 that is internally reinforced with a tubular core element 206a, the intemal hollow of which is filled with an expanded polymer resin foam 206b.
Altemative to an intemal reinforcing element that spans fully between opposed walls or wall sections of a tubular element, Figure 14 illustrates a practice ofthe invention with a tubular composite member 210, illustratively circular in cross section, and formed as in a pultrusion process, as described in Attachment A, with one or more selectively circumferentially located intemal ribs. The illustrated member 210 has four such ribs. 210a, 210b, 210c and 210d, equally spaced about the circumference ofthe circular cross section. This practice in the invention, i.e., with intemal reinforcement that extends radially only part way, and not entirely, to an opposing wall portion, can provide added structural rigidity to a composite member, with a higher degree of elasticity than with an intemal reinforcement element that spans fully between opposed wall portions, as in each of Figures 10, 11, 12 and 13. Further, although illustrated with a composite member of circular cross section, the intemal reinforcement illustrated in Figure 14 can be used with composite members having other configurations, as shown in others ofthe drawings.
Figure 15 illustrates a practice ofthe invention with intemal reinforcement of a tubular composite member where the reinforcement is not continuous along the length ofthe member. In particular, the tubular composite member 212 of Figure 15 is internally reinforced with an element 212a that is at least partially preformed, e.g., with partial curing of polymer resin and which is finally cured or cured to the final stage after assembly within the composite member. The preformed reinforcement element 212a, as shown, is similar to an I- beam stracture having a web spanning between end flanges. However, the web is discontinuous and has only an axially succession of web-like braces 212b that extend diametrically between opposed walls or wall portions ofthe composite member 212. The discontinuous reinforcing element 212a can be formed as a discontinuous member, or it can be formed as a continuous member which is further processed to remove sections along the reinforcing element. The reinforcing element 212a provides a stracture that selectively reduces the total weight ofthe composite member while providing selective reinforcement to the composite member.
Figures 16 and 17, respectively, illustrate a hockey stick 214 and a lacrosse stick 216, each constructed with a shaft 214a, 216a that is a tubular composite member of the type described above in Figures 4 through 15.
In particular, the hockey stick 214 has a conventional blade 214a, secured at a lower end ofthe shaft 214a, and has a cap 214c secured to the upper other end ofthe shaft 214a. The illustrated shaft 214a has intemal reinforcement 214d, as described above with reference to any of Figures 10, 11, 12, 13, 14 and 15, extending for a portion only ofthe length ofthe shaft.
Similarly, the lacrosse stick 216 of Figure 17 has a conventional lacrosse net 216b secured to one end of a lacrosse handle shaft 216a. The shaft has an intemal reinforcement element 216d extending at least along the lower portion, i.e., the portion to which the net 216b is secured.
Each shaft 214A and 216B thus is axially elongated with a handle portion at one end. At the other end. the shaft has a socket-like receptacle or other stracture for seating and thereby mounting a sports implement. This implement is the hockey blade 214A in the embodiment of Figure 16 and is the lacrosse net 216B in the embodiment of Figure 17. It will thus be seen that the invention attains the objects set forth above, among those made apparent from the preceding description, and since certain changes may be made in carrying out the above method and in the articles set forth without departing from the scope ofthe invention, it is intended that all matter contained in the above description or shown in the accompanying drawings be interpreted as illustrative and not in a limiting sense.
It is also to be understood that the following claims are intended to cover all generic and specific features ofthe invention described herein, and all statements ofthe scope ofthe invention which, as a matter of language, might be said to fall therebetween.
Having described the invention, what is claimed as new and secured by Letters Patent is:

Claims

1. An axially extending tubular composite member having a plurality of plies and having primary bending stiffness along a longitudinal axis, said member having the improvement comprising
A. at least one interior ply having at least a biaxial fiber component with a matrix material,
B. at least one intermediate ply having at least one axially extending fiber component disposed within said matrix material, said intermediate ply being exterior to said interior ply, and
C. at least one exterior ply having a woven fiber component with threads oriented longitudinal to said longitudinal axis and threads oriented transverse to said longitudinal axis, and disposed with said matrix material, said exterior ply being exterior to said intermediate ply.
2. A tubular composite member according to claim 1 having the further improvement comprising a veil covering said exterior ply, said veil including said matrix material.
3. A tubular composite member according to claim 1 having the further improvement comprising at least one outer ply having at least a biaxial fiber component disposed with said matrix material and located between said intermediate ply and said exterior ply.
4. A tubular composite member according to claim 1 wherein said fiber component of said intermediate ply includes a first axial fiber and second and third fibers each oriented diagonally relative to said first fiber, so that said first, second, and third fibers together form a triaxial fiber component.
5. A tubular member according to claim 1 further comprising an intemal web-like reinforcement spanning across the tubular interior ofthe member between and secured to two spaced apart wall portions.
6. A tubular member according to claim 5 wherein said web-like reinforcement includes a fiber component disposed with said matrix material.
7. A tubular member according to claim 5 wherein said web-like reinforcement includes a substantially rigid core disposed between fibers disposed with said matrix material.
8. A tubular member according to claim 1 wherein said member has a cross section transverse to said longitudinal axis in the form of a closed plane figure having at least four sides, and with at least two opposed wall portions.
9. A tubular member according to claim 8 having the further improvement wherein said two opposed wall portions have a first medial thickness and have a greater thickness than said first thickness at longitudinally-extending edges thereof.
10. A tubular member according to claim 8 having the further improvement wherein said member has a lesser wall thickness at the middle of said two opposed wall portions then at axially-extending edges of said opposed wall portions.
11. A tubular member according to claim 8 wherein said two opposed wall portions are symmetrically concave.
12. A composite member according to claim 1 wherein the fiber materials of said biaxial fiber component and of said axial fiber component are selected from the group of fiber materials consisting of polyester, glass, carbon, aramid, and mixtures thereof.
13. An axially extending tubular composite member having a plurality of plies and having primary bending stiffness along a longitudinal axis, said member having the improvement comprising
A. at least one interior ply having at least a biaxial fiber component with a matrix material, B. at least one intermediate ply having at least an axial fiber component disposed with said matrix material, said intermediate ply being exterior to said interior ply,
C. at least one outer ply having at least any one of (i) a biaxial fiber component and (ii) an axial fiber component, said fiber component being disposed with said matrix material and said outer ply being exterior to said intermediate ply, and D. an intemal web-like reinforcement spanning across the tubular interior of the member between and secured to two spaced apart wall portions.
14. A tubular composite member according to claim 13 having the further improvement comprising a further ply exterior to said outer ply and having a woven fiber component.
15. A tubular composite member according to claim 13 having the further improvement comprising a surface veil coating at least one ofthe inner surfaces of said interior ply and the outer surfaces of said exterior ply.
16. A sports implement shaft elongated along an axis and having a handle portion at one axial end and having at the other axial end a seat portion for attachment to a sports head, said sports implement shaft comprising a tubular member having opposed wall portions and structured with resin and with multiple plies of substantially continuous fiber imbedded in said resin and including at least first, second, and third fibers, each disposed at selected different angles relative to said axis, and a web member within said tubular member and spanning between and secured to said opposed wall portions, said web member extending along at least a selected axial length of said tubular member.
17. A sports implement having an axially elongated shaft member with a handle portion at one axial end and a head member secured to the other axial end, said implement having the improvement wherein said shaft member comprises a tubular member having opposed wall portions and structured with resin and with multiple plies of substantially continuous fiber imbedded in said resin and including at least first, second, and third fibers, each disposed at selected different angles relative to said axis, and a web member within said tubular member and spanning between and secured to said opposed wall portions, said web member extending along at least a selected axial length of said tubular member.
18. An axially extending composite tubular member having a plurality of plies and having primary bending stiffness along a longitudinal axis, and comprising at least one interior ply having a matrix material and a first fiber component with fibers oriented at an angle relative to said longitudinal axis of between thirty degrees and sixty degrees, and more particularly between forty degrees and fifty degrees, and an intemal weblike reinforcement spanning across the tubular interior ofthe member between and secured to two spaced apart wall portions, said first fiber component being structured to provide significant torsional stiffness to the composite member and said intemal weblike reinforcement being structured to provide significant impact resistance to the composite member.
19. A method of fabricating an axially extending composite tubular member having a stracture according to claim 18 and comprising the steps of forming first and second fabric strips into axially extending side-by-side closed tubes, the abutting walls of which form said intemal weblike reinforcement, and forming a fibrous fabric into a longitudinally extending ply enclosing said first and second plies and having fibers that constitute said first fiber component of said interior ply.
20. A method of fabricating an axially extending composite member having a structure according to claim 18 and comprising the successive steps of forming said web-like reinforcement, disposing said web-like reinforcement between side-by-side mandrel members, and forming said plies of said tubular member over said mandrel members and web-like reinforcement.
21. An axially extending tubular composite member having a plurality of plies and having primary bending stiffness along a longitudinal axis, said member having the improvement comprising
A. at least one interior ply having at least a biaxial fiber component with a matrix material,
B. at least one intermediate ply having at least one axially extending fiber component disposed within said matrix material, said intermediate ply being exterior to said interior ply, and
C. at least one exterior ply having at least a biaxial fiber component disposed with said matrix material, said exterior ply being located exterior to said intermediate ply.
PCT/US1996/011718 1995-07-17 1996-07-15 Composite tubular member having consistent strength and method WO1997003820A1 (en)

Priority Applications (1)

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CA002227197A CA2227197A1 (en) 1995-07-17 1996-07-15 Composite tubular member having consistent strength and method

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US147095P 1995-07-17 1995-07-17
US60/001,470 1995-07-17
US08/597,088 1996-02-05
US08/597,088 US5688571A (en) 1994-01-07 1996-02-05 Composite tubular member with internal reinforcement and method

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EP0978367A2 (en) * 1998-08-01 2000-02-09 DORNIER GmbH Highly rigid profile reinforced with carbon fibres for fast moving vehicles and process for manufacturing it
US7862456B2 (en) 2003-05-15 2011-01-04 Easton Sports, Inc. Hockey stick
US7914403B2 (en) 2008-08-06 2011-03-29 Easton Sports, Inc. Hockey stick
US7963868B2 (en) 2000-09-15 2011-06-21 Easton Sports, Inc. Hockey stick
EP2521600A1 (en) * 2010-01-08 2012-11-14 Blmh Technologies Inc. Hockey stick
CN104769280A (en) * 2012-08-23 2015-07-08 叶片动力学有限公司 Wind turbine tower
CN112161115A (en) * 2020-09-17 2021-01-01 北京中创时代科技有限公司 Three-dimensional fiber woven composite pipeline and production method thereof

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US4900048A (en) * 1987-10-02 1990-02-13 Gleb Derujinsky Integral seamless composite bicycle frame
US4968545A (en) * 1987-11-02 1990-11-06 The Dexter Corporation Composite tube and method of manufacture
US5188872A (en) * 1989-06-15 1993-02-23 Fiberspar, Inc. Composite structural member with high bending strength
US5332606A (en) * 1992-01-22 1994-07-26 Edo Sports, Inc. Filament-wound tubular element manufacturing method and product

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0978367A2 (en) * 1998-08-01 2000-02-09 DORNIER GmbH Highly rigid profile reinforced with carbon fibres for fast moving vehicles and process for manufacturing it
EP0978367A3 (en) * 1998-08-01 2000-05-24 DORNIER GmbH Highly rigid profile reinforced with carbon fibres for fast moving vehicles and process for manufacturing it
US7963868B2 (en) 2000-09-15 2011-06-21 Easton Sports, Inc. Hockey stick
US7862456B2 (en) 2003-05-15 2011-01-04 Easton Sports, Inc. Hockey stick
US7914403B2 (en) 2008-08-06 2011-03-29 Easton Sports, Inc. Hockey stick
EP2521600A1 (en) * 2010-01-08 2012-11-14 Blmh Technologies Inc. Hockey stick
EP2521600A4 (en) * 2010-01-08 2013-09-04 Blmh Technologies Inc Hockey stick
CN104769280A (en) * 2012-08-23 2015-07-08 叶片动力学有限公司 Wind turbine tower
US9651029B2 (en) 2012-08-23 2017-05-16 Blade Dynamics Limited Wind turbine tower
CN104769280B (en) * 2012-08-23 2020-09-25 叶片动力学有限公司 Wind turbine tower
CN112161115A (en) * 2020-09-17 2021-01-01 北京中创时代科技有限公司 Three-dimensional fiber woven composite pipeline and production method thereof

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