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WO1994026236A1 - Agents de traitement capillaire - Google Patents

Agents de traitement capillaire Download PDF

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Publication number
WO1994026236A1
WO1994026236A1 PCT/EP1994/001425 EP9401425W WO9426236A1 WO 1994026236 A1 WO1994026236 A1 WO 1994026236A1 EP 9401425 W EP9401425 W EP 9401425W WO 9426236 A1 WO9426236 A1 WO 9426236A1
Authority
WO
WIPO (PCT)
Prior art keywords
groups
polymers
hair
acid
anionic
Prior art date
Application number
PCT/EP1994/001425
Other languages
German (de)
English (en)
Inventor
Adolf Klenk
Karl Giede
Detlef Hollenberg
Original Assignee
Henkel Kommanditgesellschaft Auf Aktien
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel Kommanditgesellschaft Auf Aktien filed Critical Henkel Kommanditgesellschaft Auf Aktien
Publication of WO1994026236A1 publication Critical patent/WO1994026236A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8147—Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8164—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least one other carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers, e.g. poly (methyl vinyl ether-co-maleic anhydride)
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • A61K8/8182—Copolymers of vinyl-pyrrolidones. Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring

Definitions

  • the invention relates to hair treatment compositions which contain polymers neutralized with special bases.
  • polymeric compounds as film formers to increase the volume and bounce of the hair and to support special hairstyle shapes. These are either added to the usual treatment agents such as shampoos or rinses as further active ingredients, or formulated into a basis for optimal application in special products such as hair sprays.
  • Both neutralizable and non-neutralizable polymers can be used as film formers.
  • the development is clearly in the direction of neutralizable connections. This includes justified by the fact that, for example, hair fixers and hair sprays are increasingly used on an alcoholic or aqueous-alcoholic basis instead of e.g. Methylene chloride as a solvent and with lower alkanes or dimethyl ether instead of CFCs as propellants.
  • degree of neutralization and base used for neutralization in the case of neutralizable polymers, both the properties of the film resulting on the hair and the compatibility of the neutralizable polymers with the components customary for the selected form of application can be improved.
  • the invention therefore relates to a hair treatment composition
  • a hair treatment composition comprising, in addition to conventional cosmetic components, anionic (A) and / or zwitterionic polymers (Z), the anionic groups of which are 50-100% neutralized by amphoteric bases (B), characterized in that that
  • anionic polymers (A) are selected from
  • Copolymers of acrylic acid or methacrylic acid with acrylic acid and / or methacrylic acid esters and / or acrylamides and / or methacrylamides and / or vinyl pyrrolidone
  • the zwitterionic polymers (Z) contain quaternary ammonium groups of the type -N + R1R2R3 as cationic groups, where R *, R ⁇ and R-3 independently of one another represent alkyl groups with 1 to 4 carbon atoms or hydroxyalkyl groups with 2 to 4 carbon atoms , and
  • the amphoteric bases (B) contain at least 2 basic groups and at least one acidic group, provided that the number of basic groups is greater than the number of acidic groups.
  • the hair treated with the agents according to the invention has a very natural, long-lasting bounce. Even in high humidity there is no reduction in hair volume and the hair does not become sticky.
  • the polymer film adheres better to the hair when dry, while it swells slightly when wet; depending on the type of formulation, the film can be removed by rinsing with pure water if desired.
  • a water-alcoholic formulation in particular creates a highly elastic film that dries without sticking.
  • anionic polymers suitable according to the invention are:
  • Polyoxycarboxylic acids such as polyketo- and polyaldehydocarboxylic acids and their salts, such as, for example, P0C R HS 5060 and P0C R AS5050.
  • Vinyl acetate / crotonic acid copolymers which are commercially available, for example, under the names Resyn R and Gafset, and
  • a preferred polymer is the vinylpyrrolidone / acrylate terpolymer available under the name Luviflex R VBM-35.
  • Zwitterionic polymers suitable according to the invention contain both cationic and anionic groups, where they contain, as cationic groups, quaternary ammonium groups of the type -N + R * R2R3, in which R *, R ⁇ and R3 independently of one another for alkyl groups with 1 to 4 carbon atoms or Hydroxyalkyl groups with 2 to 4 carbon atoms are available.
  • Suitable anionic groups are, for example, carbon, sulfone and phosphoric acid groups in free form or in salt form.
  • the carboxylic acid groups and their alkali, alkaline earth, aluminum and ammonium salts are preferred anionic groups.
  • the zwitterionic polymers used according to the invention can be constructed from monomers which contain both cationic and anionic groups.
  • the polymers can consist of a single monomer type.
  • copolymers of the monomers mentioned and other nonionic monomers can be, for example, vinyl-based esters and amides, such as methyl acrylate, ethyl acrylate, methyl methacrylate, ethyl methacrylate, hydroxypropyl methacrylate, acrylamide, vinyl pyrrolidone and vinyl alcohol.
  • These copolymers preferably contain at least 20%, in particular at least 50%, of ionic monomers.
  • Zwitterionic polymers preferred in the context of the invention are built up from at least 2 ionic monomers, one cationic and one anionic monomer.
  • Cationic and anionic monomers can be present in a molar ratio of 1: 1.
  • cationic and anionic monomers are used in a ratio of 95: 5 to 60:40.
  • the polymers can contain nonionic monomers of the type mentioned above in amounts of up to 50 mol%, in particular up to 20 mol%.
  • preferred zwitterionic polymers are the zwitterionic polymers described in DE-A-39 29 973, which essentially consist of monomers with quaternary ammonium groups of the general formula (I),
  • R 1 -CH CR 2 -C0-Z- (C n H2n) -N ( + ) R 3 R 4 R 5 A ( " ) (I) in which R * and R 2 independently of one another represent hydrogen or a methyl group and R 3 , R 4 and R5 independently of one another for alkyl groups with 1 to 4 carbon atoms, Z an NH group or an oxygen atom, n an integer from 2 to 5 and A ( ⁇ ) the anion of an organic or inorganic Acid is and monomeric carboxylic acids of the general formula (II), R 6 -CH R7-C00H (II) in which R-5 and R- 7 are independently hydrogen or methyl groups, or alkali metal, alkaline earth metal, aluminum or ammonium salts of these acids .
  • Acrylamidopropyltrimethylamonium chloride is a very particularly preferred monomer of formula (I).
  • Monomeric carboxylic acids of the general formula (II) are acrylic acid, methacrylic acid, crotonic acid and 2-methyl-crotonic acid.
  • Acrylic or methacrylic acid, in particular acrylic acid are preferably used.
  • Salts of these carboxylic acids which are preferably used are the lithium, sodium, potassium, magnesium, calcium and aluminum salts.
  • the sodium salt is particularly preferred.
  • the ammonium salts can be used in which the ammonium ion can have one to three alkyl groups with 1-4 carbon atoms or hydroxyalkyl groups with 2-4 carbon atoms as substituents. Salts with unsubstituted ammonium ions and triethanolammonium ions are preferred.
  • Suitable zwitterionic polymers are also methacrylethylbetaine / methacrylate copolymers, which are commercially available under the name Amersette R , and polysiloxane-polyorganobetaine copolymers.
  • anionic or zwitterionic polymers are used in salt form, they are the alkali, alkaline earth, ammonium or mono-, di- or trialkanolammonium salts.
  • the alkali metal salts in particular the sodium salts, are preferred.
  • the anionic or zwitterionic polymers are preferably 80 to 100% neutralized with amphoteric bases (B).
  • B amphoteric bases
  • the person skilled in the art can set the desired degree of neutralization in the specific case within the usual concentration ranges for polymer and base.
  • the polymers mentioned are preferably present in the agents according to the invention in amounts of 0.5 to 10% by weight, based on the total agent. Amounts of 1 to 8% by weight are particularly preferred.
  • amphoteric bases (B) which can be used according to the invention contain both acidic and basic groups.
  • the condition is that the number of basic groups is greater than the number of acidic groups.
  • the bases usually contain two to four basic groups; Bases with 2 or three basic groups are preferred.
  • the number of acidic groups is generally 1 to 3, bases with one or two acidic groups being preferred.
  • the basic groups preferably contain a nitrogen atom.
  • Amino, imino and heterocyclic nitrogen-containing groups are particularly preferred.
  • Basic groups which are preferably suitable according to the invention are, for example, amino, aminoalkyl, aminohydroxyalkyl such as aminohydroxyethyl and aminohydroxypropyl, aminocarboxyalkyl such as aminocarboxymethyl, guanidyl, piperidyl and pyridinium groups.
  • Amido groups such as amidoacyl groups are also basic groups in the sense of the invention.
  • amphoteric bases according to the invention can contain, for example, carboxyl, sulfate and phosphate groups as acid groups. Carboxyl groups are preferred.
  • amphoteric bases are amino acids with several basic groups. Examples of such amino acids are lysine, arginine, histidine, tryptophan and asparagine.
  • amphoteric bases are the so-called betaines, ie peralkylated zwitterions of the formula R 1 R 2 R 3 N + - (CH2) X -C00 ".
  • R 1 to R 3 are, for example, alkyl, hydroxyalkyl, aminoalkyl- and carboxyalkyl groups with 1 to 22 carbon atoms and two or three of these groups can also represent a heterocyclic radical such as pyridinium or piperidinium, and x represents a number from 1 to 3.
  • the carbon chains in these groups can be linear or branched, saturated or mono- or polyunsaturated Furthermore, the chain lengths can be both uniform and represent mixtures, such as they occur during the processing of native raw materials, e.g.
  • the chains can be alkoxylated, in particular ethoxylated or propoxylated, the mean degree of alkoxylation preferably being between 1 and 10.
  • betaines which can be used according to the invention are aminopropyl betaine, 2-N-pyridinium-5-aminocapronate and N-carboxymethyl-N-aminopropylpiperidinium betaine.
  • the agents according to the invention can contain one of the amphoteric bases mentioned as well as mixtures of these bases.
  • the bases normally used for neutralizing the polymers can also be used.
  • these bases known to those skilled in the art, 2-amino-2-methyl-l-propanol and 2-amino-2-methyl-1,3-propanediol are preferred.
  • the quantitative ratio of the bases (B) according to the invention to these bases is preferably 10: 1 to 1: 2, in particular 5: 1 to 1: 1.
  • amphoteric bases are preferably present in amounts of 0.05 to 2% by weight, also based on the total agent. Amounts of 0.2 to 1.0% by weight are particularly preferred.
  • the other components of the agents according to the invention are determined by the type of agent. If it is * a shampoo, for example, surfactants are included as further main components.
  • anionic surface-active substances suitable for use on the human body are suitable as anionic surfactants. These are characterized by a water-solubilizing, anionic group such as. B. a carboxylate, sulfate, sulfonate or phosphate group and a lipophilic alkyl group with about 10 to 22 carbon atoms.
  • the molecule can contain glycol or polyglycol ether groups, ester, ether and amide groups and hydroxyl groups.
  • suitable anionic surfactants are, in each case in the form of the sodium, potassium and ammonium as well as the mono-, di- and trialkanolammonium salts with 2 or 3 carbon atoms in the alkanol group,
  • Alkyl sulfates and alkyl polyglycol ether sulfates of the formula R-0 (CH2-CH20) X -0S03H, in which R is a preferably linear alkyl group having 10 to 18 carbon atoms and x 0 or 1 to 12,
  • esters of tartaric acid and citric acid with alcohols which are attached products of about 2-15 molecules of ethylene oxide and / or propylemoxide to fatty alcohols with 8 to 22 carbon atoms.
  • Preferred anionic surfactants are alkyl sulfates, alkyl polyglycol ether sulfates and ether carboxylic acids with 10 to 18 carbon atoms in the alkyl group and up to 12 glycol ether groups in the molecule, and sulfosuccinic acid and dialkyl esters with 8 to 18 carbon atoms in the alkyl group and sulfosuccinic acid mono- alkyl polyoxyethyl esters with 8 to 18 carbon atoms in the alkyl group and 1 to 6 oxyethyl groups.
  • Zwitterionic surfactants are those surface-active compounds which carry at least one quaternary ammonium group and at least one -COO ( ⁇ ) - or -S03 ( ⁇ ) group in the molecule.
  • Particularly suitable zwitterionic surfactants are the so-called betaines such as the H-alkyl-N, N-dimethylammonium glycinate, for example the cocoalkyl-dimethylammonium glycinate, N-acyl-aminopropyl-N, N-dimethylammonium glycinate, for example the cocoacylaminopropyl-dimethylammonium glycinate.
  • a preferred zwitterionic surfactant is the fatty acid amide derivative known under the CTFA name Cocamidopropyl Betaine.
  • Ampholytic surfactants are understood to mean those surface-active compounds which, in addition to a C 6 -C 16 -alkyl or acyl group, contain at least one free amino group and at least one -C00H or -SO3H group in the molecule and are capable of forming internal salts.
  • ampholytic surfactants are N-alkylglycines, N-alkylpropionic acids, N-alkylaminobutyric acids, N-alkyliminodipropionic acids, N-hydroxyethyl-N-alkylamidopropylglycines, N-alkyltaurines, N-alkyl sarcosines, 2-alkyla inopropionic acids and alkylamino acetic acids, each with about 8 to 18 carbon atoms in the alkyl group.
  • Particularly preferred ampholytic surfactants are N-cocoalkylaminopropionate, cocoacylaminoethyl aminopropionate and Ci2-18 "A c Sarcos yl, - n *
  • Non-ionic surfactants contain z.
  • B a polyol group, a polyalkylene glycol ether group or a combination of polyol and polyglycol ether group.
  • Such connections are, for example
  • the compounds with alkyl groups used as surfactants can each be uniform substances. However, it is in the Gel is preferred to start from natural vegetable or animal raw materials in the production of these substances, so that substance mixtures with different alkyl chain lengths depending on the respective raw material are obtained.
  • both products with a "normal" homolog distribution and those with a narrowed homolog distribution can be used.
  • "Normal" homolog distribution is understood to mean mixtures of homologs which are obtained as a catalyst from the reaction of fatty alcohol and alkylene oxide using alkali metals, alkali metal hydroxides or alkali metal alcoholates.
  • narrow homolog distributions are obtained if, for example, hydrotalide, alkaline earth metal salts of ether carboxylic acids, alkaline earth metal oxides, hydroxides or alcoholates are used as catalysts. The use of products with a narrow homolog distribution can be preferred.
  • agents according to the invention are cationic surfactants and cationic polymers.
  • quaternary ammonium compounds such as alkyltrimethylammonium chlorides, dialkyldimethylammonium chlorides and trialkylmethylammonium chlorides, eg.
  • cetyltrimethylammonium chloride stearyltrimethylammonium chloride, distearyldimethylammonium chloride, lauryldimethylammonium chloride, lauryldimethylbenzylammonium chloride and tricetylmethyl amonium chloride can be included.
  • further suitable cationic surfactants are cetyl pyridinium chloride and tallow alkyl tris (oligooxy alkyl) ammonium phosphate and quaternized protein hydrolyzates.
  • Suitable cationic polymers usually contain a quaternary nitrogen atom, for example in the form of an ammonium group.
  • Preferred cationic polymers are, for example
  • Polyquaternium 27 known polymers with quaternary nitrogen atoms in the main polymer chain.
  • the preparations according to the invention preferably contain the surface-active compounds A in amounts of 0.5 to 30% by weight, based on the respective preparation.
  • the agents according to the invention are particularly preferably formulated as hair fixatives.
  • water and lower alcohols such as ethanol and isopropanol are the main components of the agents.
  • blowing agents e.g. Dimethyl ether, lower alkanes such as propane and butane, air, nitrogen, carbon dioxide and nitrous oxide are added.
  • nonionic polymers such as polysiloxanes, polyvinylpyrrolidone and vinylpyrrolidone copolymers e.g. with vinyl acetate
  • Thickeners such as agar agar, guar gum, alginates and xanthan gum,
  • Structurants such as glucose and maleic acid
  • Protein hydrolyzates in particular elastin, collagen, keratin, milk protein, soy protein and wheat protein hydrolyzates, their condensation products with fatty acids and quaternized protein hydrolyzates,
  • Solubilizers such as ethanol, isopropanol, ethylene glycol, propylene glycol, glycerol and diethylene glycol,
  • Fats and waxes such as walrus, beeswax, montan wax, paraffins and fatty alcohols,
  • Superfatting agents such as polyethoxylated lanolin derivatives, lecithin derivatives and fatty acid alkanolamides,
  • Swelling and penetration substances such as glycerol, propylene glycol monoethyl ether, carbonates, hydrogen carbonates, guanidines, ureas and also primary, secondary and tertiary phosphates,
  • Opacifiers e.g. polymer dispersions
  • the invention also relates to a method for treating the hair, in which an agent according to claims 1 to 7 is used.
  • a method is particularly preferred in which the hair is no longer rinsed after application of the agent according to the invention.
  • CTFA name PEG-60-Hydrogenated-Castor-Oil (BASF)
  • Crolastin R 9 0.5
  • Ethoxylated castor oil (CTFA name: PEG-40 Castor Oil) (HENKEL)

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Cosmetics (AREA)

Abstract

Des agents de traitement capillaire renferment, dans de nombreux cas, des polymères anioniques et/ou zwitterioniques filmogènes. Avec certains polymères, les propriétés des films formés sur les cheveux sont notablement améliorées lorsque les groupes anioniques de ces polymères sont neutralisés à 50 - 100 % par des bases amphotères. Celles-ci renferment au moins deux groupes basiques et au moins un groupe acide, à la condition que le nombre de groupes basiques soit supérieur au nombre de groupes acides.
PCT/EP1994/001425 1993-05-14 1994-05-05 Agents de traitement capillaire WO1994026236A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19934316242 DE4316242A1 (de) 1993-05-14 1993-05-14 Haarbehandlungsmittel
DEP4316242.8 1993-05-14

Publications (1)

Publication Number Publication Date
WO1994026236A1 true WO1994026236A1 (fr) 1994-11-24

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WO (1) WO1994026236A1 (fr)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5614173A (en) * 1995-12-08 1997-03-25 Isp Investments Inc. Hair spray composition having 80% or less VOC and advantageous physical and performance characteristics
FR2786392B1 (fr) * 1998-11-26 2006-08-25 Oreal Composition de coiffage comprenant un polymere aux caracteristiques particulieres et un polymere non ionique
FR2786391B1 (fr) * 1998-11-26 2002-08-02 Oreal Composition de coiffage comprenant un polymere aux caracteristiques particulieres et un polymere filmogene ionique
DE10027391B4 (de) * 2000-06-02 2006-05-04 Wella Ag Oligomere und Polymere aus Crotonbetain oder Crotonbetainderivaten
EP1192931B1 (fr) * 2001-12-01 2003-09-03 Wella Aktiengesellschaft Composition de traitement capillaire comprenant une combinaison de trois polymers
DE10160992A1 (de) * 2001-12-12 2003-06-18 Beiersdorf Ag Haarfestiger mit anionischem und/oder amphoterem Filmpolymer
DE10251122A1 (de) * 2002-11-02 2004-05-19 Beiersdorf Ag Haarbehandlungsmittel mit verbesserten Film- und Geruchseigenschaften
US7279153B2 (en) 2003-01-23 2007-10-09 Wella Ag Hair treatment composition containing a combination of three different film-forming hair-fixing polymers

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2350834A1 (fr) * 1976-05-10 1977-12-09 Oreal Nouvelles laques et lotions de mises en plis a base de copolymeres anhydride/ester allylique ou methallylique monoesterifies et/ou monoamidifies
JPS61287992A (ja) * 1985-06-14 1986-12-18 株式会社資生堂 洗浄剤組成物
JPS62161711A (ja) * 1986-01-08 1987-07-17 Sunstar Inc 弱酸性ゲル状化粧料
WO1989012438A1 (fr) * 1988-06-23 1989-12-28 S.C. Johnson & Son, Inc. Laque a cheveux qui adhere mieux et s'elimine mieux au lavage
EP0470381A2 (fr) * 1990-07-10 1992-02-12 Kao Corporation Composition pour le traitement des cheveux et composition pour la teinture des cheveux
EP0524434A2 (fr) * 1991-06-24 1993-01-27 Helene Curtis, Inc. Shampooing conditionnant doux ayant une action moussante élevée

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2350834A1 (fr) * 1976-05-10 1977-12-09 Oreal Nouvelles laques et lotions de mises en plis a base de copolymeres anhydride/ester allylique ou methallylique monoesterifies et/ou monoamidifies
JPS61287992A (ja) * 1985-06-14 1986-12-18 株式会社資生堂 洗浄剤組成物
JPS62161711A (ja) * 1986-01-08 1987-07-17 Sunstar Inc 弱酸性ゲル状化粧料
WO1989012438A1 (fr) * 1988-06-23 1989-12-28 S.C. Johnson & Son, Inc. Laque a cheveux qui adhere mieux et s'elimine mieux au lavage
EP0470381A2 (fr) * 1990-07-10 1992-02-12 Kao Corporation Composition pour le traitement des cheveux et composition pour la teinture des cheveux
EP0524434A2 (fr) * 1991-06-24 1993-01-27 Helene Curtis, Inc. Shampooing conditionnant doux ayant une action moussante élevée

Non-Patent Citations (2)

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Title
DATABASE WPI Week 8705, Derwent World Patents Index; AN 87-032285 *
DATABASE WPI Week 8734, Derwent World Patents Index; AN 87-238756 *

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