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WO1993013664A2 - Composes fongicides biheterocycliques - Google Patents

Composes fongicides biheterocycliques Download PDF

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Publication number
WO1993013664A2
WO1993013664A2 PCT/GB1993/000029 GB9300029W WO9313664A2 WO 1993013664 A2 WO1993013664 A2 WO 1993013664A2 GB 9300029 W GB9300029 W GB 9300029W WO 9313664 A2 WO9313664 A2 WO 9313664A2
Authority
WO
WIPO (PCT)
Prior art keywords
compound
optionally substituted
ring
give
carboxylate
Prior art date
Application number
PCT/GB1993/000029
Other languages
English (en)
Inventor
Michael Mellor
Peter Dominic Riordan
Original Assignee
Schering Agrochemicals Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB929200557A external-priority patent/GB9200557D0/en
Priority claimed from GB929213145A external-priority patent/GB9213145D0/en
Priority claimed from GB929213148A external-priority patent/GB9213148D0/en
Application filed by Schering Agrochemicals Limited filed Critical Schering Agrochemicals Limited
Publication of WO1993013664A2 publication Critical patent/WO1993013664A2/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D491/00—Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00
    • C07D491/02—Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00 in which the condensed system contains two hetero rings
    • C07D491/04—Ortho-condensed systems
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
    • A01N47/06—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom containing —O—CO—O— groups; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/18—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, directly attached to a heterocyclic or cycloaliphatic ring
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/34—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N55/00—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
    • A01N57/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing heterocyclic radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D495/00—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms
    • C07D495/02—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms in which the condensed system contains two hetero rings
    • C07D495/04—Ortho-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D495/00—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms
    • C07D495/12—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms in which the condensed system contains three hetero rings
    • C07D495/14—Ortho-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D513/00—Heterocyclic compounds containing in the condensed system at least one hetero ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for in groups C07D463/00, C07D477/00 or C07D499/00 - C07D507/00
    • C07D513/12—Heterocyclic compounds containing in the condensed system at least one hetero ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for in groups C07D463/00, C07D477/00 or C07D499/00 - C07D507/00 in which the condensed system contains three hetero rings
    • C07D513/14—Ortho-condensed systems

Definitions

  • heterocyclyl Especially preferred substituents are hydroxy, chloro, cyano, amino, diethylamino, methyl, methoxy, phenoxy, methylthio, isopropylthio,
  • the compounds of the invention are generally formulated in conventional compositions used for fungicides. These compositions can contain one or more additional agents.
  • naphthalene-formaldehyde condensates salts of sulfonated phenol-formaldehyde condensates; or more complex
  • Leptosphaeria nodorum glume blotch (LN)

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Dentistry (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Plant Pathology (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)

Abstract

L'invention se rapporte aux composés de la formule (I) dans laquelle le noyau A est un noyau éventuellement substitué à six membres contenant un ou deux atomes d'azote; x représente 0,5 ou -NR3-; R1 représente Q, cyano, halogène ou nitro; Q représente hydrogène, acyle, -C(=W)R5, -SR3, -C(=NR3)NR4R5, -C(=NR?3)OR4, -C(OR5)R3R4¿, alkyle éventuellement substitué, cycloalkyle éventuellement substitué, alcényle éventuellement substitué, alkynyle éventuellement substitué, aryle ou hétérocyclyle; R2 représente Q, ou -SIR3R4R5, ou lorsque X représente O ou NR3, peut également être -OR4; W représente NR?3, NOR3 ou NNR4R5¿; Z représente S(O)¿n? ou O; R?3, R4 et R5¿, qui peuvent être identiques ou différents, représentent hydrogène, alkyle éventuellement substitué, cycloalkyle éventuellement substitué, alcényle éventuellement substitué, alkynyle éventuellement substitué, aryle ou hétérocyclyle ou R?3 et R4 ou R4 et R5¿ ensemble avec l'atome auquel ils sont rattachés peuvent former un noyau; et n est 0, 1 ou 2. Ces composés peuvent être utilisés pour combattre des champignons phytopathogènes. Beaucoup de ces composés sont nouveaux.
PCT/GB1993/000029 1992-01-11 1993-01-08 Composes fongicides biheterocycliques WO1993013664A2 (fr)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
GB9200557.8 1992-01-11
GB929200557A GB9200557D0 (en) 1992-01-11 1992-01-11 Pesticides
GB929213145A GB9213145D0 (en) 1992-06-20 1992-06-20 Fungicides
GB9213148.1 1992-06-20
GB929213148A GB9213148D0 (en) 1992-06-20 1992-06-20 Fungicides
GB9213145.7 1992-06-20

Publications (1)

Publication Number Publication Date
WO1993013664A2 true WO1993013664A2 (fr) 1993-07-22

Family

ID=27265999

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB1993/000029 WO1993013664A2 (fr) 1992-01-11 1993-01-08 Composes fongicides biheterocycliques

Country Status (2)

Country Link
AU (1) AU3262593A (fr)
WO (1) WO1993013664A2 (fr)

Cited By (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0780394A1 (fr) * 1995-12-20 1997-06-25 Novartis AG Microbicides
WO2000061586A1 (fr) * 1999-04-08 2000-10-19 Akzo Nobel N.V. Composes heteroaromatiques bicycliques utiles en tant qu'agonistes de l'hormone luteinisante (lh)
WO2000073289A1 (fr) * 1999-05-28 2000-12-07 Bayer Aktiengesellschaft Alpha-phenyl-beta-cetosulfones
US6706740B2 (en) 1999-07-20 2004-03-16 Dow Agrosciences Llc Fungicidal heterocyclic aromatic amides and their compositions, methods of use and preparation
EP1493733A2 (fr) * 1999-08-20 2005-01-05 Dow AgroSciences LLC Amides hétérocycliques aromatiques fongicides, leurs compositions et mode d'emploi
WO2005034950A1 (fr) * 2003-10-10 2005-04-21 Vernalis (Cambridge) Limited Composes de pyridothiophene
WO2006068618A1 (fr) * 2004-12-23 2006-06-29 Astrazeneca Ab Nouveaux composés
WO2006119820A1 (fr) * 2005-05-12 2006-11-16 Henkel Kommanditgesellschaft Auf Aktien Agents pour colorer des fibres à base de kératine
WO2007103308A2 (fr) 2006-03-07 2007-09-13 Array Biopharma Inc. Dérivés hétérobicycliques de pyrazole et méthodes d'utilisation
USRE39991E1 (en) 1999-08-20 2008-01-01 Dow Agrosciences Llc Fungicidal heterocyclic aromatic amides and their compositions, methods of use and preparation
JP2008523087A (ja) * 2004-12-07 2008-07-03 アボット・ラボラトリーズ バニロイド受容体サブタイプ１（ｖｒ１）を抑制するチエノピリジル化合物およびこの使用
JP2008533019A (ja) * 2005-03-09 2008-08-21 シェーリング コーポレイション Ｋｓｐキネシン活性を阻害するための化合物
WO2009042607A1 (fr) 2007-09-24 2009-04-02 Genentech, Inc. Composés inhibiteurs de la pi3k à base de thiazolopyrimidine
US7521473B2 (en) 2004-02-25 2009-04-21 Wyeth Inhibitors of protein tyrosine phosphatase 1B
WO2009107850A2 (fr) 2008-02-26 2009-09-03 Takeda Pharmaceutical Company Limited Dérivé hétérocyclique fusionné et son utilisation
WO2010105008A2 (fr) 2009-03-12 2010-09-16 Genentech, Inc. Combinaisons de composés inhibiteurs de phosphoinositide 3-kinase et d'agents chimiothérapeutiques pour le traitement de tumeurs malignes hématopoïétiques
WO2010138589A1 (fr) 2009-05-27 2010-12-02 Genentech, Inc. Composés pyrimidines bicycliques inhibiteurs de pi3k sélectifs pour p110 delta, et procédés d'utilisation
WO2011130654A1 (fr) 2010-04-16 2011-10-20 Genentech, Inc. Foxo3a utilisée comme biomarqueur prédictif pour l'efficacité d'un inhibiteur de la voie des kinases p13k/akt
US8133998B2 (en) 2007-05-09 2012-03-13 Zalicus Pharmaceuticals, Ltd. Bicyclic pyrimidine derivatives as calcium channel blockers
WO2012088254A1 (fr) 2010-12-22 2012-06-28 Genentech, Inc. Polythérapie par inducteur et inhibiteur d'autophagie pour le traitement de néoplasmes
JP2012519691A (ja) * 2009-03-04 2012-08-30 イデニク プハルマセウティカルス，インコーポレイテッド ホスホチオフェン及びホスホチアゾールｈｃｖポリメラーゼ阻害剤
EP2518074A1 (fr) 2006-12-07 2012-10-31 F. Hoffmann-La Roche AG Composés inhibiteurs de phosphoinositide 3-kinase et procédés d'utilisation
WO2014130923A2 (fr) 2013-02-25 2014-08-28 Genentech, Inc. Procédés et compositions pour détecter et traiter un mutant d'akt résistant aux médicaments
CN113943308A (zh) * 2021-12-09 2022-01-18 中国科学院新疆理化技术研究所 一种三环嘧啶类衍生物及用途
US11690847B2 (en) 2016-11-30 2023-07-04 Case Western Reserve University Combinations of 15-PGDH inhibitors with corticosteroids and/or TNF inhibitors and uses thereof
US11718589B2 (en) 2017-02-06 2023-08-08 Case Western Reserve University Compositions and methods of modulating short-chain dehydrogenase

Cited By (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5814629A (en) * 1995-12-20 1998-09-29 Novartis Finance Corporation Microbicides
EP0780394A1 (fr) * 1995-12-20 1997-06-25 Novartis AG Microbicides
US6841553B2 (en) 1999-04-08 2005-01-11 Akzo Nobel N.V. Bicyclic heteroaromatic compounds useful as LH agonists
WO2000061586A1 (fr) * 1999-04-08 2000-10-19 Akzo Nobel N.V. Composes heteroaromatiques bicycliques utiles en tant qu'agonistes de l'hormone luteinisante (lh)
US6569863B1 (en) 1999-04-08 2003-05-27 Akzo Nobel Nv Bicyclic heteroamatic compounds useful as LH agonists
US6849744B2 (en) 1999-05-28 2005-02-01 Bayer Aktiengesellschaft α-phenyl-β-keto sulfones
WO2000073289A1 (fr) * 1999-05-28 2000-12-07 Bayer Aktiengesellschaft Alpha-phenyl-beta-cetosulfones
US6670385B1 (en) 1999-05-28 2003-12-30 Bayer Aktiengesellschaft α-phenyl-βketosulfone
US6706740B2 (en) 1999-07-20 2004-03-16 Dow Agrosciences Llc Fungicidal heterocyclic aromatic amides and their compositions, methods of use and preparation
USRE39991E1 (en) 1999-08-20 2008-01-01 Dow Agrosciences Llc Fungicidal heterocyclic aromatic amides and their compositions, methods of use and preparation
EP1493733A3 (fr) * 1999-08-20 2005-01-26 Dow AgroSciences LLC Amides hétérocycliques aromatiques fongicides, leurs compositions et mode d'emploi
EP1493733A2 (fr) * 1999-08-20 2005-01-05 Dow AgroSciences LLC Amides hétérocycliques aromatiques fongicides, leurs compositions et mode d'emploi
WO2005034950A1 (fr) * 2003-10-10 2005-04-21 Vernalis (Cambridge) Limited Composes de pyridothiophene
US7521473B2 (en) 2004-02-25 2009-04-21 Wyeth Inhibitors of protein tyrosine phosphatase 1B
US8501769B2 (en) 2004-12-07 2013-08-06 Abbvie Inc. Thienopyridyl compounds that inhibit vanilloid receptor subtype 1 (VR1) and uses thereof
JP2008523087A (ja) * 2004-12-07 2008-07-03 アボット・ラボラトリーズ バニロイド受容体サブタイプ１（ｖｒ１）を抑制するチエノピリジル化合物およびこの使用
WO2006068618A1 (fr) * 2004-12-23 2006-06-29 Astrazeneca Ab Nouveaux composés
JP2008533019A (ja) * 2005-03-09 2008-08-21 シェーリング コーポレイション Ｋｓｐキネシン活性を阻害するための化合物
WO2006119820A1 (fr) * 2005-05-12 2006-11-16 Henkel Kommanditgesellschaft Auf Aktien Agents pour colorer des fibres à base de kératine
WO2007103308A2 (fr) 2006-03-07 2007-09-13 Array Biopharma Inc. Dérivés hétérobicycliques de pyrazole et méthodes d'utilisation
EP2518074A1 (fr) 2006-12-07 2012-10-31 F. Hoffmann-La Roche AG Composés inhibiteurs de phosphoinositide 3-kinase et procédés d'utilisation
US8133998B2 (en) 2007-05-09 2012-03-13 Zalicus Pharmaceuticals, Ltd. Bicyclic pyrimidine derivatives as calcium channel blockers
WO2009042607A1 (fr) 2007-09-24 2009-04-02 Genentech, Inc. Composés inhibiteurs de la pi3k à base de thiazolopyrimidine
US8399449B2 (en) 2008-02-26 2013-03-19 Takeda Pharmaceutical Company Limited Fused heterocyclic derivative and use thereof
US8217176B2 (en) 2008-02-26 2012-07-10 Takeda Pharmaceutical Company Limited Fused heterocyclic derivative and use thereof
WO2009107850A2 (fr) 2008-02-26 2009-09-03 Takeda Pharmaceutical Company Limited Dérivé hétérocyclique fusionné et son utilisation
JP2012519691A (ja) * 2009-03-04 2012-08-30 イデニク プハルマセウティカルス，インコーポレイテッド ホスホチオフェン及びホスホチアゾールｈｃｖポリメラーゼ阻害剤
WO2010105008A2 (fr) 2009-03-12 2010-09-16 Genentech, Inc. Combinaisons de composés inhibiteurs de phosphoinositide 3-kinase et d'agents chimiothérapeutiques pour le traitement de tumeurs malignes hématopoïétiques
WO2010138589A1 (fr) 2009-05-27 2010-12-02 Genentech, Inc. Composés pyrimidines bicycliques inhibiteurs de pi3k sélectifs pour p110 delta, et procédés d'utilisation
WO2011130654A1 (fr) 2010-04-16 2011-10-20 Genentech, Inc. Foxo3a utilisée comme biomarqueur prédictif pour l'efficacité d'un inhibiteur de la voie des kinases p13k/akt
WO2012088254A1 (fr) 2010-12-22 2012-06-28 Genentech, Inc. Polythérapie par inducteur et inhibiteur d'autophagie pour le traitement de néoplasmes
WO2014130923A2 (fr) 2013-02-25 2014-08-28 Genentech, Inc. Procédés et compositions pour détecter et traiter un mutant d'akt résistant aux médicaments
US11690847B2 (en) 2016-11-30 2023-07-04 Case Western Reserve University Combinations of 15-PGDH inhibitors with corticosteroids and/or TNF inhibitors and uses thereof
US11718589B2 (en) 2017-02-06 2023-08-08 Case Western Reserve University Compositions and methods of modulating short-chain dehydrogenase
CN113943308A (zh) * 2021-12-09 2022-01-18 中国科学院新疆理化技术研究所 一种三环嘧啶类衍生物及用途
CN113943308B (zh) * 2021-12-09 2023-11-10 中国科学院新疆理化技术研究所 一种三环嘧啶类衍生物及用途

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