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US7838578B2 - Functional cornstalk board and preparation method thereof - Google Patents

Functional cornstalk board and preparation method thereof Download PDF

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Publication number
US7838578B2
US7838578B2 US10/579,864 US57986406D US7838578B2 US 7838578 B2 US7838578 B2 US 7838578B2 US 57986406 D US57986406 D US 57986406D US 7838578 B2 US7838578 B2 US 7838578B2
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Prior art keywords
cornstalk
board
flame retardant
functional
phosphoric acid
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US20090104458A1 (en
Inventor
Hai-il Ryu
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RYU HAIL-IL
Hong Hook
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Individual
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Priority claimed from PCT/KR2006/001060 external-priority patent/WO2007069807A1/en
Assigned to RYU, HAIL-IL, HONG, HOOK reassignment RYU, HAIL-IL ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: RYU, HAI-IL
Publication of US20090104458A1 publication Critical patent/US20090104458A1/en
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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
    • B27N3/00—Manufacture of substantially flat articles, e.g. boards, from particles or fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K9/00—Chemical or physical treatment of reed, straw, or similar material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/16—Inorganic impregnating agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/52—Impregnating agents containing mixtures of inorganic and organic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C08L23/0853—Vinylacetate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C08L23/0869—Acids or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C08L61/22—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds
    • C08L61/24—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds with urea or thiourea
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C08L61/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
    • C08L61/28—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds with melamine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/34—Condensation polymers of aldehydes or ketones with monomers covered by at least two of the groups C08L61/04, C08L61/18 and C08L61/20
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31725—Of polyamide
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31942—Of aldehyde or ketone condensation product
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31971—Of carbohydrate
    • Y10T428/31975—Of cellulosic next to another carbohydrate
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31971—Of carbohydrate
    • Y10T428/31975—Of cellulosic next to another carbohydrate
    • Y10T428/31978—Cellulosic next to another cellulosic

Definitions

  • the present invention relates to a functional cornstalk board and a preparation method thereof, and more specifically to a functional cornstalk board obtained by molding a raw material under a predetermined molding condition using a semiautomatic or multistage automatic heat press device, wherein the raw material includes a curing agent in a mixture of cornstalk and a binder or silicate.
  • the functional cornstalk board of the present invention is a cornstalk plywood material maintaining an excellent bending strength and an excellent density, and capable of manufacturing the cornstalk plywood material into various shapes and desired standards of a woodcut, scantling, plywood, construction materials and a slate due to its easy molding by the pressure and the extrusion, and therefore the functional cornstalk board may be environment-friendly, mass-produced and economical since the cornstalk is used as the unlimited resource without adversely affecting the forests so as to obtain woods or plywoods, and particularly it may be light in weight, easily processed in molding and cutting, and also used for application products into which the colors are added.
  • Maize is an annual plant that is widely distributed over the world and approximately 1.5 to 2.5 m tall, and the ear of maize, which may be used as a fruit, has been widely cultivated for the edible plant or the plant for animals.
  • the cornstalk by-produced in the maize is produced after harvesting the ear of maize, and therefore it was simply wasted as the farmyard manure in the past, or partially used as a domestic animal feed, a food additive material.
  • the cornstalk is used as the interior/exterior materials, a specific binder should be suitably required for the main component “cornstalk”, as well as the final product has no practical use as the board or the interior/exterior materials because the molding method and the molding condition of the cornstalk are complicated owing to its essential characteristics. Accordingly, there has been an attempt to develop the cornstalk as the construction materials since it is slightly employed in spite of the enormous recycling value.
  • the functional cornstalk board has an easy molding property and an excellent mechanical property since a binder and a curing agent are mixed with the cornstalk, and then molded under a suitable condition.
  • the present invention provides a functional cornstalk board obtained by molding a raw material under a predetermined molding condition using a semiautomatic or multistage automatic heat press device, wherein the raw material includes a curing agent in a mixture of cornstalk and a binder or silicate.
  • the functional cornstalk board of the present invention includes 1 to 10 parts by weight of a curing agent, based on the total weight of a mixture of 6 to 10 parts by weight of cornstalk and 0.2 to 2 parts by weight of a binder or silicate, wherein the functional cornstalk board is obtained by molding the raw material at a molding temperature of 120 to 210° C. and a molding pressure of 10 to 30,000 kgf/cm 2 for a molding time of 0.5 to 20 minutes in a semiautomatic or multistage automatic heat press device.
  • the content of the cornstalk is less than 6 parts by weight, then the addition effect of the cornstalk is poor, as well as it is difficult to give a desired mechanical property, while if its content exceeds 10 parts by weight, then it is difficult to mold it into the product due to its very high content.
  • the functional board of the present invention has an advantage of very high economic value by selecting the unlimited resource of cornstalk belonging to an annual plant since its preparation method is similar to the method for preparing MDF, etc., but the grinded cornstalk or the mechanically pulped fibrous maize material is used as its components, instead of the conventional materials such as wood chip or wood remnants.
  • a chemical structure of cornstalk is hydrophilic because the cornstalk is composed of cellulose such as wood, and therefore various binders is used herein for binding them, wherein the binders is selected from the group consisting of melamine formaldehyde glue, urea formaldehyde glue, phenol formaldehyde glue, urea & mixed formaldehyde glue, phenol& urea & mixed formaldehyde glue, urea melamine formaldehyde glue, poly-lauylacrylate, poly-2-ethylhexylacrylate, vinyl acrylic resin, vinyl acetate resin, glues, EVA resin, etc., each easily bound with a —OH group of organic aromatics and celluloses.
  • the binders is selected from the group consisting of melamine formaldehyde glue, urea formaldehyde glue, phenol formaldehyde glue, urea & mixed formaldehyde glue, phenol& urea & mixed formalde
  • the curing agent used herein may include ammonium hydroxide, ammonium chloride, magnesium chloride, aluminum chloride, ammonium phosphate, etc.
  • lignin is particularly removed from the cornstalk
  • its product having the better mechanical property, for example strength may be prepared when then the raw material is steam-heated at about 180° C. using the conventional MDF production process, and then processed and molded through the mechanical pulping process.
  • a mixed board may be prepared by adding 2 to 10 parts by weight of each of a phosphoric acid-including flame retardant such as triethylphosphate, etc., a halide-including flame retardant such as bromotriallylphosphate, etc., a sulfur-including flame retardant such as sulfamic acid, etc., an inorganic flame retardant such as ammonium borate, phosphoric acid, sodium silicate, calcium carbonate, titanium oxide, etc., and an electromagnetic shielding component such as alkaline metal salts, alkaline earth metal salts, graphite, activated carbon, carbon fibers, etc., based on 6 to 10 parts by weight of the cornstalk.
  • cornstalk board or plywood made of an adhesive resin may be prepared by fusing stearic acid to polyethylene such as PP, PE, etc. to co-polymerize each other.
  • the raw material may be used in various shapes, or as a substitute of wood having the desired standard, or in the form of a desk, a chair, a dresser, furniture, plywood, scantling, material woods, construction materials, gardening materials, road installations, and farming and fishing equipment, and slate, and be changed with soundproofing materials.
  • the composition may be provided with various physical properties according to the condition such as cutting, grinding, mixing, heating and cooling, depending on its desired nature.
  • the molded product has a wooden feel, and therefore hand sawing, mechanical wood processing, planning, nailing, screw nailing, punching, assembling like wood, and handling are easy in the working spots since it does not have brittleness at all.
  • the functional board of the present invention is a cornstalk plywood material having a bending strength of 300 to 750 kgf/cm3 and a density of 0.5 to 0.8 g/cm3, wherein the functional board has the characteristics as the construction material, such as cold resistance, a soundproofing property, stiffness, a flame-retarding property, a property to absorb electromagnetic, etc.
  • 7.5 kg of cornstalk grinded in a suitable size was mixed with 1.5 kg of melamine resin, and then 135 g of the curing agent, ammonium chloride, was added thereto to prepare a raw material.
  • the resultant raw material was molded at a temperature of 160° C. and a pressure of 50 kgf/cm 2 for 6 minutes to prepare a cornstalk board. It was revealed that the prepared cornstalk board had a bending strength of 320 kg f /cm 3 and a density of 0.65 g/cm 3 .
  • the raw material prepared in Embodiment 6 was used, but the functional cornstalk board is prepared using, as the preparation of the raw material and the molding method, the conventional MDF manufacturing process consisting of a process for grinding cornstalk, a cooking process, mechanical pulping process, a process for adding resin, a fluidized drying process, a process for storing hopper, an air filtering process, a mat molding process, a process for pressing with a heat press, a cooling process, a cutting process, etc.
  • the prepared cornstalk board had a bending strength of 390 kg f /cm 3 and a density of 0.78 g/cm 3 .
  • the predetermined resin binder and the curing agent was used in combination with the grinded cornstalk to prepare a raw material, and then the prepared raw material was molded at a temperature of 120 to 210° C. and a molding pressure of 10 to 30,000 kgf/cm 2 for a molding time of 0.5 to 20 minutes to prepare various cornstalk boards, which have a bending strength of 300 to 750 kg f /cm 3 and a density of 0.4 to 0.85 g/cm 3 , as described in the embodiments.
  • the cornstalk board of the present invention may be used as the substitute of wood, medium-density fiberboards (MDF), particle boards, and glued laminated timber (GLT), etc.
  • the content of the binder is limited in the present invention, but the raw material has the higher density as the content of the resin is the higher, if necessary.
  • the design of the related chemical apparatus caused by the product development, and the know-hows about production technique may be also maintained by the inventors, as well as a new environment-friendly material may be prepared which prevails over the competitive pricing and its demand, and is very exceptionally environment-friendly. Accordingly, a method for developing a functional material using the cornstalk of the present invention belongs to a new production technique capable of being substituted since the cornstalk may be freely prepared into the various conventional shapes of woods, synthetic plastics, construction materials, etc. in its application.
  • the cornstalk of the present invention has an advantage that the competitiveness in infrastructural industries of the nations is strengthened due to conservation of the environment and reuse of the resources, as well as it may substitute for the environmentally hazardous materials such as MDF, and plastic boards, etc., and be recycled semi-permanently.
  • the method of the present invention may be widely spread into the world since it has the advantage that its components have the same cellulose structure as the pulp and it has an absolute advantage over biodegradation and environmental pollution, as well as it has the advantage that the natural forest may be protected from being lumbered for use of the wood owing to this present invention.
  • the functional cornstalk board of the present invention and the preparation method thereof may be useful to be a plywood material obtained by molding a raw material under a predetermined molding condition using a semiautomatic or multistage automatic heat press device, wherein the raw material includes a curing agent in a mixture of cornstalk and a binder or silicate, wherein the functional cornstalk board may maintain an excellent bending strength and an excellent density, and manufacture the cornstalk plywood material into various shapes and desired standards of a woodcut, scantling, plywood, construction materials and a slate due to its easy molding by the pressure and the extrusion, and therefore the functional cornstalk board may be environment-friendly, mass-produced and economical since the cornstalk is used as the unlimited resource without adversely affecting the forests so as to obtain woods or plywoods, and particularly it may be light in weight, easily processed in molding and cutting, and also used for application products into which the colors are added.

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Forests & Forestry (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Dry Formation Of Fiberboard And The Like (AREA)

Abstract

Disclosed is a functional cornstalk board and a preparation method thereof. The functional cornstalk board includes 1 to 10 parts by weight of a curing agent, based on the total weight of the mixture of 6 to 10 parts by weight of cornstalk and 0.2 to 2 parts by weight of a binder or silicate. It is obtained by molding the raw material at a molding temperature of 120 to 210° C. and a molding pressure of 10 to 30,000 kgf/cm2 for 0.5 to 20 minutes using a semiautomatic or multistage automatic heat press device.

Description

TECHNICAL FIELD
The present invention relates to a functional cornstalk board and a preparation method thereof, and more specifically to a functional cornstalk board obtained by molding a raw material under a predetermined molding condition using a semiautomatic or multistage automatic heat press device, wherein the raw material includes a curing agent in a mixture of cornstalk and a binder or silicate.
BACKGROUND ART
The functional cornstalk board of the present invention is a cornstalk plywood material maintaining an excellent bending strength and an excellent density, and capable of manufacturing the cornstalk plywood material into various shapes and desired standards of a woodcut, scantling, plywood, construction materials and a slate due to its easy molding by the pressure and the extrusion, and therefore the functional cornstalk board may be environment-friendly, mass-produced and economical since the cornstalk is used as the unlimited resource without adversely affecting the forests so as to obtain woods or plywoods, and particularly it may be light in weight, easily processed in molding and cutting, and also used for application products into which the colors are added.
Maize is an annual plant that is widely distributed over the world and approximately 1.5 to 2.5 m tall, and the ear of maize, which may be used as a fruit, has been widely cultivated for the edible plant or the plant for animals.
The cornstalk by-produced in the maize is produced after harvesting the ear of maize, and therefore it was simply wasted as the farmyard manure in the past, or partially used as a domestic animal feed, a food additive material. However, there have been recently many studies in such various fields as in generating the various substitute energy sources such as ethanol, manufacturing the pulp.
The study on the cornstalk has been conducted in the field of construction materials, and partially tested by adding the cornstalk into interior/exterior materials.
However, if the cornstalk is used as the interior/exterior materials, a specific binder should be suitably required for the main component “cornstalk”, as well as the final product has no practical use as the board or the interior/exterior materials because the molding method and the molding condition of the cornstalk are complicated owing to its essential characteristics. Accordingly, there has been an attempt to develop the cornstalk as the construction materials since it is slightly employed in spite of the enormous recycling value.
DISCLOSURE OF INVENTION
Technical Problem
To solve the above-described problems, it is an objective of the present invention to provide a functional board capable of developing an environment-friendly cornstalk board using cornstalk having cellulose as the main component by searching a binder or silicate and a curing agent the most suitable for the cornstalk and adding them at a specific mixing ratio, and therefore of reducing the environmental pollution and employing it as new construction materials.
Also, it is an objective of the present invention to provide a method for preparing the functional cornstalk board, wherein the functional cornstalk board has an easy molding property and an excellent mechanical property since a binder and a curing agent are mixed with the cornstalk, and then molded under a suitable condition.
Best Mode
Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings.
The present invention provides a functional cornstalk board obtained by molding a raw material under a predetermined molding condition using a semiautomatic or multistage automatic heat press device, wherein the raw material includes a curing agent in a mixture of cornstalk and a binder or silicate.
That is, the functional cornstalk board of the present invention includes 1 to 10 parts by weight of a curing agent, based on the total weight of a mixture of 6 to 10 parts by weight of cornstalk and 0.2 to 2 parts by weight of a binder or silicate, wherein the functional cornstalk board is obtained by molding the raw material at a molding temperature of 120 to 210° C. and a molding pressure of 10 to 30,000 kgf/cm2 for a molding time of 0.5 to 20 minutes in a semiautomatic or multistage automatic heat press device.
Herein, if the content of the cornstalk is less than 6 parts by weight, then the addition effect of the cornstalk is poor, as well as it is difficult to give a desired mechanical property, while if its content exceeds 10 parts by weight, then it is difficult to mold it into the product due to its very high content.
The functional board of the present invention has an advantage of very high economic value by selecting the unlimited resource of cornstalk belonging to an annual plant since its preparation method is similar to the method for preparing MDF, etc., but the grinded cornstalk or the mechanically pulped fibrous maize material is used as its components, instead of the conventional materials such as wood chip or wood remnants.
Especially, a chemical structure of cornstalk is hydrophilic because the cornstalk is composed of cellulose such as wood, and therefore various binders is used herein for binding them, wherein the binders is selected from the group consisting of melamine formaldehyde glue, urea formaldehyde glue, phenol formaldehyde glue, urea & mixed formaldehyde glue, phenol& urea & mixed formaldehyde glue, urea melamine formaldehyde glue, poly-lauylacrylate, poly-2-ethylhexylacrylate, vinyl acrylic resin, vinyl acetate resin, glues, EVA resin, etc., each easily bound with a —OH group of organic aromatics and celluloses.
Also, the curing agent used herein may include ammonium hydroxide, ammonium chloride, magnesium chloride, aluminum chloride, ammonium phosphate, etc.
In the present invention, if lignin is particularly removed from the cornstalk, its product having the better mechanical property, for example strength may be prepared when then the raw material is steam-heated at about 180° C. using the conventional MDF production process, and then processed and molded through the mechanical pulping process.
In order to give noncombustibility, flame-retarding property and an ability to absorb electromagnetic wave in the certain case,
A mixed board may be prepared by adding 2 to 10 parts by weight of each of a phosphoric acid-including flame retardant such as triethylphosphate, etc., a halide-including flame retardant such as bromotriallylphosphate, etc., a sulfur-including flame retardant such as sulfamic acid, etc., an inorganic flame retardant such as ammonium borate, phosphoric acid, sodium silicate, calcium carbonate, titanium oxide, etc., and an electromagnetic shielding component such as alkaline metal salts, alkaline earth metal salts, graphite, activated carbon, carbon fibers, etc., based on 6 to 10 parts by weight of the cornstalk. Also, cornstalk board or plywood made of an adhesive resin may be prepared by fusing stearic acid to polyethylene such as PP, PE, etc. to co-polymerize each other.
According to the present invention, the raw material may be used in various shapes, or as a substitute of wood having the desired standard, or in the form of a desk, a chair, a dresser, furniture, plywood, scantling, material woods, construction materials, gardening materials, road installations, and farming and fishing equipment, and slate, and be changed with soundproofing materials.
Also, the composition may be provided with various physical properties according to the condition such as cutting, grinding, mixing, heating and cooling, depending on its desired nature. Particularly, the molded product has a wooden feel, and therefore hand sawing, mechanical wood processing, planning, nailing, screw nailing, punching, assembling like wood, and handling are easy in the working spots since it does not have brittleness at all.
In particular, the functional board of the present invention is a cornstalk plywood material having a bending strength of 300 to 750 kgf/cm3 and a density of 0.5 to 0.8 g/cm3, wherein the functional board has the characteristics as the construction material, such as cold resistance, a soundproofing property, stiffness, a flame-retarding property, a property to absorb electromagnetic, etc.
BEST MODES FOR CARRYING OUT THE INVENTION
Hereinafter, the present invention will be described in detail referring to preferred embodiments.
Embodiment 1
7 kg of cornstalk grinded in a suitable size was mixed with 1 kg of urea resin, and then 80 g of the curing agent, ammonium chloride, was added thereto to prepare a raw material. The resultant raw material was molded at a temperature of 150° C. and a pressure of 10 kgf/cm2 for 10 minutes to prepare a cornstalk board. It was revealed that the prepared cornstalk board had a bending strength of 300 kg/cm3 and a density of 0.6 g/cm3.
Embodiment 2
7.5 kg of cornstalk grinded in a suitable size was mixed with 1.5 kg of melamine resin, and then 135 g of the curing agent, ammonium chloride, was added thereto to prepare a raw material. The resultant raw material was molded at a temperature of 160° C. and a pressure of 50 kgf/cm2 for 6 minutes to prepare a cornstalk board. It was revealed that the prepared cornstalk board had a bending strength of 320 kgf/cm3 and a density of 0.65 g/cm3.
Embodiment 3
8 kg of cornstalk grinded in a suitable size was mixed with 1.0 kg of phenol resin, and then 180 g of the curing agent, magnesium chloride, was added thereto to prepare a raw material. The resultant raw material was molded at a temperature of 180° C. and a pressure of 100 kgf/cm2 for 4 minutes to prepare a cornstalk board. It was revealed that the prepared cornstalk board had a bending strength of 340 kgf/cm3 and a density of 0.7 g/cm3.
Embodiment 4
9 kg of cornstalk grinded in a suitable size was mixed with 1.5 kg of a resin material composed of urea and phenol resins, and then 262.5 g of the curing agent, ammonium chloride, was added thereto to prepare a raw material. The resultant raw material was molded at a temperature of 200° C. and a pressure of 11 ton/cm2 for 2 minutes to prepare a cornstalk board. It was revealed that the prepared cornstalk board had a bending strength of 370 kgf/cm3 and a density of 0.75 g/cm3.
Embodiment 5
10 kg of cornstalk grinded in a suitable size was mixed with 2 kg of urea resin, and then 360 g of the curing agent, ammonium chloride, was added thereto to prepare a raw material. The resultant raw material was molded at a temperature of 210° C. and a pressure of 12 ton/cm2 for 2 minutes to prepare a cornstalk board. It was revealed that the prepared cornstalk board had a bending strength of 400 kgf/cm3 and a density of 0.8 g/cm3.
Embodiment 6
10 kg of cornstalk grinded in a suitable size was mixed with 2 kg of a resin material composed of urea and melamine resins, and then 360 g of the curing agent, ammonium chloride, was added thereto to prepare a raw material. The resultant raw material was molded at a temperature of 210° C. and a pressure of 30 ton/cm2 for 1 minute to prepare a cornstalk board. It was revealed that the prepared cornstalk board had a bending strength of 400 kgf/cm3 and a density of 0.8 g/cm3.
Embodiment 7
The raw material prepared in Embodiment 6 was used, but the functional cornstalk board is prepared using, as the preparation of the raw material and the molding method, the conventional MDF manufacturing process consisting of a process for grinding cornstalk, a cooking process, mechanical pulping process, a process for adding resin, a fluidized drying process, a process for storing hopper, an air filtering process, a mat molding process, a process for pressing with a heat press, a cooling process, a cutting process, etc. At this time, it was revealed that the prepared cornstalk board had a bending strength of 390 kgf/cm3 and a density of 0.78 g/cm3.
Embodiment 8
In the material prepared in Embodiment 6, 15 wt. % of sodium silicate (Na2SiO3·10H2O) instead of the resin binder was mixed with 4 wt. % of carbon material on the basis of 100 wt. % of the cornstalk, and molded at a molding temperature of 130° C. and a molding pressure of 1 to 30 ton for a molding time of 2 to 7 minutes, and then the prepared cornstalk board was measured for the physical properties such as density, moisture content, thermal conductivity, strength, adiabatic property, adsorptivity on floating dust, etc. As a result, it was seen that the cornstalk board had the more excellent strength and adiabatic property than those of woods or medium-density fiberboards, as well as the very excellent physical property as the construction material
Embodiment 9
As the additives added to the material prepared in Embodiment 6, 3 wt. % of each of a phosphoric acid-including flame retardant (triethylphosphate), a halide-including flame retardant (bromo triallylphosphate), a sulfur-including flame retardant (sulfamic acid), an inorganic flame retardant (ammonium borate), and an electromagnetic shielding component (alkaline metal salt) was mixed with 8 wt. % of the cornstalk, and molded at a molding temperature of 140° C. and a molding pressure of 1 to 30 ton for a molding time of 2 to 7 minutes to prepare a board, which may be used for a specific purpose.
In the present invention, the predetermined resin binder and the curing agent was used in combination with the grinded cornstalk to prepare a raw material, and then the prepared raw material was molded at a temperature of 120 to 210° C. and a molding pressure of 10 to 30,000 kgf/cm2 for a molding time of 0.5 to 20 minutes to prepare various cornstalk boards, which have a bending strength of 300 to 750 kgf/cm3 and a density of 0.4 to 0.85 g/cm3, as described in the embodiments. As a result, the cornstalk board of the present invention may be used as the substitute of wood, medium-density fiberboards (MDF), particle boards, and glued laminated timber (GLT), etc.
Meanwhile, the content of the binder is limited in the present invention, but the raw material has the higher density as the content of the resin is the higher, if necessary.
In the functional board and the preparation method thereof according to the present invention, the design of the related chemical apparatus caused by the product development, and the know-hows about production technique may be also maintained by the inventors, as well as a new environment-friendly material may be prepared which prevails over the competitive pricing and its demand, and is very exceptionally environment-friendly. Accordingly, a method for developing a functional material using the cornstalk of the present invention belongs to a new production technique capable of being substituted since the cornstalk may be freely prepared into the various conventional shapes of woods, synthetic plastics, construction materials, etc. in its application. The cornstalk of the present invention has an advantage that the competitiveness in infrastructural industries of the nations is strengthened due to conservation of the environment and reuse of the resources, as well as it may substitute for the environmentally hazardous materials such as MDF, and plastic boards, etc., and be recycled semi-permanently.
Especially, the method of the present invention may be widely spread into the world since it has the advantage that its components have the same cellulose structure as the pulp and it has an absolute advantage over biodegradation and environmental pollution, as well as it has the advantage that the natural forest may be protected from being lumbered for use of the wood owing to this present invention.
INDUSTRIAL APPLICABILITY
As described above, the functional cornstalk board of the present invention and the preparation method thereof may be useful to be a plywood material obtained by molding a raw material under a predetermined molding condition using a semiautomatic or multistage automatic heat press device, wherein the raw material includes a curing agent in a mixture of cornstalk and a binder or silicate, wherein the functional cornstalk board may maintain an excellent bending strength and an excellent density, and manufacture the cornstalk plywood material into various shapes and desired standards of a woodcut, scantling, plywood, construction materials and a slate due to its easy molding by the pressure and the extrusion, and therefore the functional cornstalk board may be environment-friendly, mass-produced and economical since the cornstalk is used as the unlimited resource without adversely affecting the forests so as to obtain woods or plywoods, and particularly it may be light in weight, easily processed in molding and cutting, and also used for application products into which the colors are added.
Although a few embodiments of the present invention have been shown and described, it would be appreciated by those skilled in the art that various modification and changes might be made in this embodiment without departing from the principles and spirit of the invention, the scope of which is defined in the claims and their equivalents.

Claims (12)

1. A functional cornstalk board comprising cornstalk, silicate, a curing agent, and 2 to 10 parts by weight of each of a phosphoric acid-including flame retardant, bromotriallylphosphate, a sulfur-including flame retardant, and an inorganic flame retardant based on 6 to 10 parts by weight of the cornstalk; wherein the cornstalk is 6-10 parts by weight and the silicate is 0.2-2 parts by weight, and the curing agent is 1 to 10 parts by weight based on 100 parts by weight of the mixture of the cornstalk and the silicate.
2. The functional cornstalk board according to claim 1, wherein the curing agent is at least one selected from the group consisting of ammonium hydroxide, ammonium chloride, magnesium chloride, aluminium chloride and ammonium phosphate.
3. The functional cornstalk board of claim 1, further comprising 2 to 10 parts by weight of an electromagnetic shielding component based on 6 to 10 parts by weight of the cornstalk.
4. The functional cornstalk board of claim 3, wherein the electromagnetic shielding component is alkaline metal salts, alkaline earth metal salts, graphite, activated carbon, or carbon fibers.
5. The functional cornstalk board of claim 3, wherein the phosphoric acid-including flame retardant is triethylphosphate.
6. The functional cornstalk board of claim 3, wherein the inorganic flame retardant is ammonium borate, phosphoric acid, calcium carbonate, or titanium oxide.
7. The functional cornstalk board of claim 3, wherein the phosphoric acid-including flame retardant is triethylphosphate and the inorganic flame retardant is ammonium borate, phosphoric acid, calcium carbonate, or titanium oxide.
8. The functional cornstalk board of claim 3, wherein the phosphoric acid-including flame retardant is triethylphosphate, the inorganic flame retardant is ammonium borate, phosphoric acid, calcium carbonate, or titanium oxide, and the electromagnetic shielding component is alkaline metal salts, alkaline earth metal salts, graphite, activated carbon, or carbon fibers.
9. The functional cornstalk board of claim 1, wherein the phosphoric acid-including flame retardant is triethylphosphate.
10. The functional cornstalk board of claim 1, wherein the inorganic flame retardant is ammonium borate, phosphoric acid, calcium carbonate, or titanium oxide.
11. The functional cornstalk board of claim 1, wherein the phosphoric acid-including flame retardant is triethylphosphate and the inorganic flame retardant is ammonium borate, phosphoric acid, calcium carbonate, or titanium oxide.
12. A method for preparing the functional cornstalk board as defined in said claim 1, comprising steps of: mixing of ground cornstalk with silicate; adding a curing agent a phosphoric acid-including flame retardant, bromotriallylphosphate, a sulfur-including flame retardant, and an inorganic flame retardant to the resultant mixture to prepare a raw material; and molding the prepared raw material at a molding temperature of 120 to 210° C. and a molding pressure of 10 to 30,000 kg /cm for a molding time of 0.5 to 20 minutes in a semiautomatic or multistage automatic heat press device.
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