US4472437A - Dicalcium phosphate as gum base filler - Google Patents
Dicalcium phosphate as gum base filler Download PDFInfo
- Publication number
- US4472437A US4472437A US06/471,074 US47107483A US4472437A US 4472437 A US4472437 A US 4472437A US 47107483 A US47107483 A US 47107483A US 4472437 A US4472437 A US 4472437A
- Authority
- US
- United States
- Prior art keywords
- gum base
- composition
- filler
- gum
- dicalcium phosphate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G4/00—Chewing gum
- A23G4/06—Chewing gum characterised by the composition containing organic or inorganic compounds
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G4/00—Chewing gum
- A23G4/06—Chewing gum characterised by the composition containing organic or inorganic compounds
- A23G4/064—Chewing gum characterised by the composition containing organic or inorganic compounds containing inorganic compounds
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G4/00—Chewing gum
- A23G4/06—Chewing gum characterised by the composition containing organic or inorganic compounds
- A23G4/08—Chewing gum characterised by the composition containing organic or inorganic compounds of the chewing gum base
Definitions
- Mineral materials such as calcium carbonate, magnesium silicate and magnesium carbonate, among others, have long been known to be effective additives for chewing gum compositions. Ordinarily, these materials are used as fillers for the chewing gum composition for the purpose of reducing cost, texturizing and softening the rubber in the gum base. Additionally, it is been known to use fillers for the purpose of holding in flavor.
- U.S. Pat. No. 2,076,112 discloses the use of mineral ingredients such as anhydrous magnesium silicate, commonly known as talc, for the purpose of improving the consistency of the chewing gum as a whole, and helping to hold in the flavor as the chewing gum is masticated.
- dicalcium phosphate has been added to the chewing gum composition as an anticariogenic agent.
- U.S. Pat. No. 3,011,949 discloses chewing gum compositions containing solid powder fillers such as dicalcium phosphate, for the purpose of supplementing the supply of calcium and phosphate in saliva. This supplement helps to aid against decay-producing acids that are produced and exist in the saliva.
- the patentee discloses the effectiveness of the dicalcium phosphate to be easily released from the chewing gum during mastication to provide this effect.
- the dicalcium phosphate is disclosed as an improved source of calcium and phosphate over other possible sources.
- U.S. Pat. No. 3,655,866 discloses a releasable form of dicalcium phosphate dihydrate prepared for sugarless gum.
- the dicalcium phosphate is coated with a water-soluble polyol or mixture of polyols, for example, sorbitol, xylitol, mannitol prior to the incorporation of the mineral material into the gum composition.
- This patent also discloses and claims a process for incorporation of the dicalcium phosphate dihydrate.
- U.S. Pat. No. 3,085,048 teaches an improved process for coating dicalcium phosphate with sugar such that the dicalcium phosphate will be gradually released into the saliva to contribute to an anticariogenic effect.
- the dicalcium phosphate is added to the gum composition and released slowly when the chewing gum is masticated.
- Film forming is particularly important in chewing gum compositions intended to form bubbles.
- the ease and quality of the bubble are significant considerations and are obviously dependent on the combination of ingredients in the gum base.
- the gum base filler is known to play a part in the overall film-forming (bubble-producing) capability of the chewing gum composition as a whole. Films which are too thick may be difficult to form and blow into bubbles, whereas films which are very thin may produce a bubble which breaks too easily.
- One objective in the present invention is to formulate a gum base which when incorporated into a chewing gum composition, e.g. in a bubble gum composition, allows for large, easily formed bubbles to be blown, while maintaining good flavor impact and release and a delicate chew balance.
- Another object of this invention is to prepare a chewing gum composition which maintains an excellent chew for ten to fifteen minutes or longer.
- Another object of this invention is to overcome the stability disadvantages of the prior art acid-containing chewing gums where the filler tended to react with the acid.
- the instant invention incorporates dicalcium phosphate anhydrous as a filler into the gum base of the composition.
- Dicalcium phosphate anhydrous when incorporated into the gum base of a chewing gum composition, in the amounts specified below, produced excellent film-forming, stability and chew characteristics, in addition to good flavor impact and release.
- the instant invention concerns a novel chewing gum base to be used in a chewing gum composition, having improved film forming capabilities, flavor release and chew characteristics and excellent stability, comprising a natural or synthetic rubber and a dicalcium phosphate anhydrous filler present in the amounts of about 4% to about 30% by weight of the gum base.
- this invention relates to a stable chewing gum composition which comprises a gum base, a flavor, acidulent and a sweetener, the improvement which comprises having about 4% to about 30% by weight of the gum base of dicalcium phosphate anhydrous filler for said gum base whereby flavor release, film forming capability and chew characteristics are improved.
- the applicants have unexpectedly discovered that significantly improved film-forming capability results when dicalcium phosphate is added as a filler to the gum base of the chewing gum composition.
- the filler of the instant invention are particularly useful where the gum base is to be formulated into a chewing gum composition which contains food acidulents. More particularly the dicalcium phosphate anhydrate fillers of the instant invention are extremely useful in gum bases to be used in sour chewing gum compositions, e.g. citrus flavored chewing gums and the like, where acidulents are prevalent.
- Dicalcium phosphate anhydrate can be used in gum bases for chewing gum compositions in the same amounts as traditional fillers, that is, in the general range of about 4% to about 30% by weight of the gum base. It is preferred, however, that dicalcium phosphate anhydrous be present in the gum base in the range of about 5% to 20% and more preferably in the range of about 5% to about 13% by weight of the gum base.
- the applicants have discovered that the anhydrous form of the dicalcium phosphate filler has advantages over the dihydrous form when incorporated into a gum base.
- the anhydrous form is less temperature sensitive during the gum base manufacturing process than the dihydrate. This is because the dihydrate form tends to lose its moisture at a non-controlled and non-predictable rate during processing of the gum base. This results in unacceptable variability in base processing and in the finished gum processing and chew characteristics.
- the anhydrous form generally has a larger, harder and coarser particle than the dihydrate, all of which contribute to the chew characteristics of the overall chewing gum composition. Particle size and abrasion generally affect the way in which the filler modifies the texture of the gum base and imparts a particular film forming capability.
- the particle size, hardness and abrasiveness of the anhydrous form is at least in part responsible for the excellent properties of the instant gum bases and chewing gum compositions.
- a comparison of physical properties of the anhydrate and dihydrate forms of dicalcium phosphate are indicated below. These values were taken from the manufacturer's product specification sheets (Monsanto Co.).
- Loss of moisture on ignition is an indication of the extent of water loss during high temperature exposure. As previously mentioned, the dihydrate form loses a significantly higher percentage of water which cannot be controlled or predicted.
- Dicalcium phosphate used as a gum base filler in a food acid-containing chewing gum, for instance, a fruit flavor gum, yields a stable product without compromising the quality of taste or texture. That is, the advantages over other filler materials traditionally used in the art, is that it combines the excellent chew properties with stability and flavor release characteristics which no previous mineral filler was in itself capable of providing in food containing acidulents.
- Gum bases using dicalcium phosphate anhydrate can be incorporated into sugar or sugarless chewing gum compositions, which can be made into a variety of products, e.g. stick or bubble gum products.
- the dicalcium phosphate anhydrate can be mixed with the gum base when the base is made, or alternatively added to the gum base just prior to incorporation of the base into the chewing gum composition.
- Bases containing the filler of this invention can be formulated into regular or non-adhering type formulations of chewing gums as well, without detracting from their properties.
- the dicalcium phosphate filled gum bases of the instant invention can be used with any compatible chewing gum composition, but it is most effective and demonstrates its fullest advantages when incorporated into acidic chewing gum compositions, e.g. citrus flavored chewing gums.
- the amount of gum base employed will vary greatly depending on various factors such as the type of base used, consistency desired and other components used to make the final product. In general, amounts of about 5% to about 45% by weight of the final chewing gum composition are acceptable for use in chewing gum compositions with preferred amounts of about 15% to about 25% by weight.
- the gum base used in this invention may be any water-insoluble gum base well known in the art.
- suitable polymers in gum bases include both natural and synthetic elastomers and rubbers.
- those polymers which are suitable in gum bases include, without limitation, substances of vegetable origin such as chicle, jelutong, gutta percha and crown gum.
- Synthetic elastomers such as butadiene-styrene copolymers, isobutylene-isoprene copolymers, polyethylene, polyisobutylene and polyvinylacetate and mixtures thereof, are particularly useful.
- the gum base composition may contain elastomer solvents to aid in softening the rubber component.
- elastomer solvents may comprise methyl, glycerol or pentaerythritol esters of rosins or modified rosins, such as hydrogenated, dimerized or polymerized rosins or mixtures thereof.
- elastomer solvents suitable for use herein include pentaerythritol ester of partially hydrogenated wood rosin, pentaerythritol ester of wood rosin, glycerol ester of partially dimerized rosin, glycerol ester of polymerized rosin, glycerol ester of tall oil rosin, glycerol ester of wood rosin and partially hydrogenated wood rosin, and partially hydrogenated methyl ester of rosin and mixtures thereof.
- the solvent may be employed in an amount ranging from about 10% to about 75% and preferably about 45% to about 70% by weight of the gum base.
- a variety of traditional ingredients used as plasticizers or softeners such as lanolin, stearic acid, sodium stearate, potassium stearate, glyceryl triacetate, glycerine and the like, may also be incorporated into the gum base to obtain a variety of desirable textures and consistency properties.
- additional materials are generally employed in amounts of up to about 30% by weight and preferably in amounts of from about 3% to about 7% by weight of the final gum base composition.
- the chewing gum compositions employing the instant gum bases generally contain sweetening agents.
- the sweetening agent may be selected from a wide range of materials including water-soluble agents, water-soluble artificial sweeteners, and dipeptide based sweeteners, including mixtures thereof. Without being limited to particular sweeteners, representative illustrations encompass:
- Water-soluble sweetening agents such as monosaccharides, disaccharides, and polysaccharides such as xylose, ribose, glucose, mannose, galactose, fructose, dextrose, sucrose, sugar, maltose, partially hydrolyzed starch or corn syrup solids and sugar alcohols such as sorbitol, xylitol, mannitol and mixtures thereof.
- Water-soluble artificial sweeteners such as the soluble saccharine salts, i.e., sodium or calcium saccharin salts, cyclamate salts, acesulfame-K and the like, and the free acid form of saccharin.
- Dipeptide based sweeteners such as L-aspartyl-L-phenylalanine methyl ester and material described in U.S. Pat. No. 3,492,131 and the like.
- the amount of sweetener will vary with the desired amount of sweetners selected for a particular chewing gum composition. This amount will normally be 0.01% to about 90% by weight when using an easily extractable sweetener.
- the dicalcium phosphate anhydrous filler used in the gum base in amounts within the scope of this invention, help to effectively release the sweetening agents over time. This is an additional benefit to the film forming improvement of his invention.
- the water-soluble sweeteners described in category A above are preferably used in amounts of about 25% to about 75% by weight, and most preferably from about 50% to about 65% by weight of the final chewing gum composition.
- the artificial sweeteners described in categories B and C are used in amounts of about 0.005% to about 5.0% and most preferably about 0.05% to about 2.5% by weight of the final chewing gum composition. These amounts are ordinarily necessary to achieve a desired level of sweetness independent from the flavor level achieved from flavor oils.
- the chewing gum composition of this invention may additionally include the conventional additives of coloring agents such as titanium dioxide; emulsifiers such as lecithin and glyceryl monostearate; and additional fillers such as aluminum hydroxide, alumina, aluminum silicates, and talc and combinations thereof.
- additional fillers may also be used in the gum base in various amounts along with the dicalcium phosphate anhydrous, provided the total amount of fillers present remains between about 4% and 30% by weight.
- the amount of additional fillers when used will vary from about 25% to about 75% of the total fillers present in the gum base. By doing so, the chew characteristics and texture are varied as desired without destroying the advantages of the dicalcium phosphate anhydrous.
- the improvement in film forming capability and stability in the presence of food acidulents is directly related to the amount of dicalcium phosphate anhydrous filler present in the gum base.
- Flavoring agents well known to the chewing gum art may be added to the chewing gum compositions of the instant invention.
- These flavoring agents may be chosen from synthetic flavor oils and/or oils derived from plants, leaves, flowers, fruits and so forth, and combinations thereof.
- Representative flavor oils include: spearmint oil, cinnamon oil, oil of wintergreen (methylsalicylate) and peppermint oils.
- artificial, natural or synthetic fruit flavors such as citrus oil including lemon, orange, grape, lime and grapefruit and fruit essences including apple, strawberry, cherry, pineapple and so forth.
- the amount of flavoring agent employed is normally a matter of preference subject to such factors as flavor type, base type and strength desired. In general, amounts of about 0.05% to about 3.0% by weight of the final chewing gum composition are useable with amounts of about 0.3% to about 1.5% being preferred and about 0.7% to about 1.2% being most preferred.
- the chewing gum composition is a tart gum, i.e. a food containing chewing gum such as one containing a citrus flavor.
- Gum bases were prepared using the formulations given below. As indicated, formulations A and B are typical of those prior art gum bases containing talc as a filler. Formulations C&D have only dicalcium phosphate anhydrate as a gum base filler. A mixture of talc and dicalcium phosphate anhydrous was used in gum bases E, F, and G.
- dicalcium phosphate anhydrous is preferred over the dihydrate form due to its process advantages and advantageous chew, texture and flavor release properties.
- Combination of talc and dicalcium phosphate anhydrous have been found to be particularly useful in that chew, texture, flavor release and film forming properties can still be maintained while having the added advantage of cost saving due to the less expensive talc filler. All values in Table I are in % by weight of the gum base.
- the gum bases above were used in formulating chewing gum composition for the purpose of evaluating the chew properties, film forming ability and flavor release capability of the resultant chewing gums. All ingredients for each of the chewing gum compositions were identical except for the gum base.
- the formulation given below, in % by weight of the total chewing gum composition was formulated in a manner well known in the chewing gum art, substituting each of the gum bases in Table I to make a total of seven chewing gum compositions.
- compositions containing dicalcium phosphate anhydrous alone (C & D) or in admixture with talc (E & F) received significantly higher ratings than those compositions which do not contain them.
- Their chew rating ranged from 6.57 to 7.14 and the bubble rating ranged from 6.57 to 7.00, which is in contrast to the prior art composition (A & B) ranges of 3.00 to 3.63 and 4.86 to 5.88 for chew and bubble respectively.
- flavor release was acceptable in all compositions, except composition E which was excellent.
- chewing gum compositions containing gum bases which comprise as a filler dicalcium phosphate anhydrate, either alone, or in combination with a small amount of another filler, e.g. alumina hydroxide, alumina, aluminum silicates, or dicalcium phosphate dihydrate, exhibit the improved properties described and explained herein.
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- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Confectionery (AREA)
Abstract
Description
______________________________________ Dicalcium Dicalcium Phosphate Phosphate Anhydrate Dihydrate ______________________________________ Loss of moisture 6.6-8.5% 24.5-26.5% on ignition MOHS hardness 3.5 2.5 Radioactive 1250 350 Dentin Abrasion (RDA) Mean Particle 15-16 9-10 Diameter (Coulter micrometers micrometers Counter, Volume Average) Particle Size* 200 screen 1.0% maximum 0.1 maximum 325 screen 98.0% maximum 98.1% maximum ______________________________________ *Indicates % of particles passing through a 200 size and 325 size screen. This confirms the mean particle diameter measurement.
TABLE I __________________________________________________________________________ GUM BASE FORMULATIONS (% by wt) Ingredient A B C D E F G __________________________________________________________________________ Styrene Butadiene elastomer 10.29 11.79 11.2 11.2 11.2 10.3 11.8 Glycerol Ester of partially 33.72 36.51 29.50 34.68 34.7 33.7 36.5 hydrogenated wood rosin Hydrogenated oil 4.90 5.62 5.3 5.3 5.4 4.9 5.6 Glycerol Ester of 23.39 23.39 27.5 22.2 22.2 23.4 23.4 Polymerized wood rosin Lecithin 1.17 1.17 1.10 1.11 1.2 1.2 1.2 Glycerol Monostearate 5.66 5.66 5.30 5.41 5.40 5.653 5.66 Butylated Hydroxyanisole 0.08 0.070 0.10 0.100 0.099 0.047 0.040 Talc 20.79 15.79 -- -- 6.90 12.70 10.20 Dicalcium Phosphate Anhydrous -- -- 20 20 12.90 8.1 5.6 __________________________________________________________________________
TABLE II ______________________________________ Ingredient % by weight of chewing gum composition ______________________________________ gum base 16.9 high DE corn syrup 24.9 caramel paste 1.9 pulverized sugar 53.7 malic acid 1.0 flavor 0.8 wesson oil 0.1 coloring 0.1 glycerin 0.3 water potable 0.3 ______________________________________
TABLE III ______________________________________ Gum Base Chew Bubble Flavor Release ______________________________________ A (prior art) 3.63 5.88 acceptable B (prior art) 3.00 4.86 acceptable C 7.10 6.57 acceptable D 6.57 7.00 acceptable E 7.57 6.86 excellent F 7.14 6.80 acceptable G 5.57 6.14 acceptable ______________________________________
TABLE IV ______________________________________ Formulation Ingredient ONE TWO THREE ______________________________________ Gum Base E 17.0 17.0 17. High DE Corn Syrup 24.53 24.53 24.53 Caramel Paste 2.0 2.0 2.0 Pulverized Sugar 54.45 54.20 53.94 Malic Acid .49 .74 1.0 Citrus flavor .79 .79 0.79 Wesson oil .09 0.9 0.9 Color .05 0.05 0.05 Glycerin 0.3 0.3 0.3 Water Potable 0.3 0.3 0.3 ______________________________________
Claims (12)
Priority Applications (10)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/471,074 US4472437A (en) | 1983-03-01 | 1983-03-01 | Dicalcium phosphate as gum base filler |
ZA84766A ZA84766B (en) | 1983-03-01 | 1984-02-01 | Dicalcium phosphate as gum base filler |
AU24424/84A AU570030B2 (en) | 1983-03-01 | 1984-02-09 | Dicalcium phosphate as gum base filler |
DE8484301001T DE3480761D1 (en) | 1983-03-01 | 1984-02-16 | BUBBLE GUM COMPOSITIONS. |
EP84301001A EP0117685B1 (en) | 1983-03-01 | 1984-02-16 | Bubble gum compositions |
CA000447798A CA1198927A (en) | 1983-03-01 | 1984-02-20 | Dicalcium phosphate as gum base filler |
ES530105A ES8602369A1 (en) | 1983-03-01 | 1984-02-28 | Bubble gum compositions. |
JP59036362A JPS59166039A (en) | 1983-03-01 | 1984-02-29 | Dicalcium phosphate as filler |
SG1046/91A SG104691G (en) | 1983-03-01 | 1991-12-12 | Bubble gum compositions |
HK142/92A HK14292A (en) | 1983-03-01 | 1992-02-20 | Bubble gum compositions |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/471,074 US4472437A (en) | 1983-03-01 | 1983-03-01 | Dicalcium phosphate as gum base filler |
Publications (1)
Publication Number | Publication Date |
---|---|
US4472437A true US4472437A (en) | 1984-09-18 |
Family
ID=23870147
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US06/471,074 Expired - Lifetime US4472437A (en) | 1983-03-01 | 1983-03-01 | Dicalcium phosphate as gum base filler |
Country Status (10)
Country | Link |
---|---|
US (1) | US4472437A (en) |
EP (1) | EP0117685B1 (en) |
JP (1) | JPS59166039A (en) |
AU (1) | AU570030B2 (en) |
CA (1) | CA1198927A (en) |
DE (1) | DE3480761D1 (en) |
ES (1) | ES8602369A1 (en) |
HK (1) | HK14292A (en) |
SG (1) | SG104691G (en) |
ZA (1) | ZA84766B (en) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4820506A (en) * | 1987-05-01 | 1989-04-11 | Research Foundation, State University Of New York | Salivary stimulant |
US4908211A (en) * | 1986-09-08 | 1990-03-13 | Paz Armando F | Chewing gum and ingredients to chemically inhibit formation of plaque and calculus |
US5139797A (en) * | 1990-04-27 | 1992-08-18 | Leaf, Inc. | Stabilized sweetener compositions, chewing gum compositions containing same and methods for their preparation |
US5286500A (en) * | 1992-03-03 | 1994-02-15 | Wm. Wrigley Jr. Company | Wax-free chewing gum base |
EP1262105A1 (en) * | 2001-05-31 | 2002-12-04 | Nattermann Phospholipid GmbH | Phospholipid composition and use thereof |
US20050214348A1 (en) * | 2003-11-21 | 2005-09-29 | Cadbury Adams Usa Llc | Delivery system for active components as part of an edible composition having preselected tensile strength |
US20110104238A1 (en) * | 2008-02-15 | 2011-05-05 | Haas Michael S | Wettable fillers for improved release of hydrophilic materials from chewing gum compositions |
US10334867B2 (en) | 2014-03-03 | 2019-07-02 | Intercontinental Great Brands Llc | Method for manufacturing a comestible |
US10973238B2 (en) | 2011-03-11 | 2021-04-13 | Intercontinental Great Brands Llc | System and method of forming multilayer confectionery |
US11122815B2 (en) | 2011-07-21 | 2021-09-21 | Intercontinental Great Brands Llc | System and method for forming and cooling chewing gum |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4948595A (en) * | 1989-06-30 | 1990-08-14 | Wm. Wrigley Jr. Company | Spearmint enhanced peppermint flavored chewing gum with improved stability |
US5833954A (en) * | 1996-08-20 | 1998-11-10 | American Dental Association Health Foundation | Anti-carious chewing gums, candies, gels, toothpastes and dentifrices |
GB2464752B (en) * | 2008-10-24 | 2010-09-08 | Anna Louise Bullus | Chewing gum composition |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3085048A (en) * | 1960-03-25 | 1963-04-09 | American Sugar Refining Co | Method of preparing sugar-coated dicalcium phosphate particles |
US3655866A (en) * | 1970-01-26 | 1972-04-11 | Warner Lambert Co | Sugarless gum containing dicalcium phosphate dihydrate |
US4248894A (en) * | 1979-01-17 | 1981-02-03 | Life Savers, Inc. | Long-lasting flavored chewing gum containing non-sugar sweetener codried on chalk or other filler and method |
US4252830A (en) * | 1979-06-18 | 1981-02-24 | Life Savers, Inc. | Chewable calorie-free chewing gum base |
US4317837A (en) * | 1980-11-25 | 1982-03-02 | Life Savers, Inc. | Tobacco-flavored chewing gum |
US4357354A (en) * | 1980-11-25 | 1982-11-02 | Nabisco Brands, Inc. | Reduced calorie chewing gum |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB934596A (en) * | 1961-05-08 | 1963-08-21 | Warner Lambert Pharmaceutical | Chewing gum |
GB963518A (en) * | 1962-07-31 | 1964-07-08 | Warner Lambert Pharmaceutical | Slab chewing gum |
US3590120A (en) * | 1969-04-16 | 1971-06-29 | Indiana University Foundation | Chewing gum |
ZA823715B (en) * | 1981-06-05 | 1983-03-30 | Nabisco Brands Inc | Gum base and chewing gum containing same |
ZA836230B (en) * | 1982-08-30 | 1984-04-25 | Nabisco Brands Inc | Reduced-shrink bubble gum |
-
1983
- 1983-03-01 US US06/471,074 patent/US4472437A/en not_active Expired - Lifetime
-
1984
- 1984-02-01 ZA ZA84766A patent/ZA84766B/en unknown
- 1984-02-09 AU AU24424/84A patent/AU570030B2/en not_active Ceased
- 1984-02-16 EP EP84301001A patent/EP0117685B1/en not_active Expired
- 1984-02-16 DE DE8484301001T patent/DE3480761D1/en not_active Expired - Lifetime
- 1984-02-20 CA CA000447798A patent/CA1198927A/en not_active Expired
- 1984-02-28 ES ES530105A patent/ES8602369A1/en not_active Expired
- 1984-02-29 JP JP59036362A patent/JPS59166039A/en active Granted
-
1991
- 1991-12-12 SG SG1046/91A patent/SG104691G/en unknown
-
1992
- 1992-02-20 HK HK142/92A patent/HK14292A/en not_active IP Right Cessation
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3085048A (en) * | 1960-03-25 | 1963-04-09 | American Sugar Refining Co | Method of preparing sugar-coated dicalcium phosphate particles |
US3655866A (en) * | 1970-01-26 | 1972-04-11 | Warner Lambert Co | Sugarless gum containing dicalcium phosphate dihydrate |
US4248894A (en) * | 1979-01-17 | 1981-02-03 | Life Savers, Inc. | Long-lasting flavored chewing gum containing non-sugar sweetener codried on chalk or other filler and method |
US4252830A (en) * | 1979-06-18 | 1981-02-24 | Life Savers, Inc. | Chewable calorie-free chewing gum base |
US4317837A (en) * | 1980-11-25 | 1982-03-02 | Life Savers, Inc. | Tobacco-flavored chewing gum |
US4357354A (en) * | 1980-11-25 | 1982-11-02 | Nabisco Brands, Inc. | Reduced calorie chewing gum |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4908211A (en) * | 1986-09-08 | 1990-03-13 | Paz Armando F | Chewing gum and ingredients to chemically inhibit formation of plaque and calculus |
US4820506A (en) * | 1987-05-01 | 1989-04-11 | Research Foundation, State University Of New York | Salivary stimulant |
US5139797A (en) * | 1990-04-27 | 1992-08-18 | Leaf, Inc. | Stabilized sweetener compositions, chewing gum compositions containing same and methods for their preparation |
US5286500A (en) * | 1992-03-03 | 1994-02-15 | Wm. Wrigley Jr. Company | Wax-free chewing gum base |
EP1262105A1 (en) * | 2001-05-31 | 2002-12-04 | Nattermann Phospholipid GmbH | Phospholipid composition and use thereof |
US20100028452A1 (en) * | 2003-11-21 | 2010-02-04 | Cadbury Adams Usa Llc | Delivery system for active components as part of an edible composition having preselected tensile strength |
US20050214348A1 (en) * | 2003-11-21 | 2005-09-29 | Cadbury Adams Usa Llc | Delivery system for active components as part of an edible composition having preselected tensile strength |
US8828423B2 (en) | 2003-11-21 | 2014-09-09 | Intercontinental Great Brands Llc | Delivery system for active components as part of an edible composition having preselected tensile strength |
US20110104238A1 (en) * | 2008-02-15 | 2011-05-05 | Haas Michael S | Wettable fillers for improved release of hydrophilic materials from chewing gum compositions |
US10973238B2 (en) | 2011-03-11 | 2021-04-13 | Intercontinental Great Brands Llc | System and method of forming multilayer confectionery |
US11930830B2 (en) | 2011-03-11 | 2024-03-19 | Intercontinental Great Brands Llc | System and method of forming multilayer confectionery |
US11122815B2 (en) | 2011-07-21 | 2021-09-21 | Intercontinental Great Brands Llc | System and method for forming and cooling chewing gum |
US10334867B2 (en) | 2014-03-03 | 2019-07-02 | Intercontinental Great Brands Llc | Method for manufacturing a comestible |
Also Published As
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---|---|
HK14292A (en) | 1992-02-28 |
EP0117685A3 (en) | 1987-04-01 |
EP0117685B1 (en) | 1989-12-20 |
JPS59166039A (en) | 1984-09-19 |
ES530105A0 (en) | 1985-12-01 |
EP0117685A2 (en) | 1984-09-05 |
ES8602369A1 (en) | 1985-12-01 |
SG104691G (en) | 1992-02-14 |
ZA84766B (en) | 1984-09-26 |
DE3480761D1 (en) | 1990-01-25 |
JPS6225015B2 (en) | 1987-06-01 |
AU570030B2 (en) | 1988-03-03 |
CA1198927A (en) | 1986-01-07 |
AU2442484A (en) | 1984-09-06 |
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