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US3382088A - Method of manufacturing self-copying sheet - Google Patents

Method of manufacturing self-copying sheet Download PDF

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US3382088A
US3382088A US451439A US45143965A US3382088A US 3382088 A US3382088 A US 3382088A US 451439 A US451439 A US 451439A US 45143965 A US45143965 A US 45143965A US 3382088 A US3382088 A US 3382088A
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solid
group
sheet
layer
acid
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Noda Ryuzo
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/10—Duplicating or marking methods; Sheet materials for use therein by using carbon paper or the like
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/914—Transfer or decalcomania

Definitions

  • This invention relates to a novel self-copying sheet, for example, of paper with a transferable layer coated on one side thereof and a method of manufacturing the same. It is an object of the invention to provide a self-copying sheet which eliminates various defects in or disadvantages inherent to conventional manifolding papers including carbonized forms, spot and strip carbons.
  • a transferable layer is coated on one side of a foundation sheet. And when a plurality of such sheets is placed one over another and applying the pressure of Writing or typewriting on the top surface of the piled sheets, such writing or typewriting portions are recorded on the top surface and simultaneously the corresponding pressed portions of each transferable layer are removed to transfer to a sheet positioned therebelow.
  • the inventive self-copying sheet there is no need of carbon paper or the like to be inserted between sheets.
  • These defects or disadvantages are due to the tackiness or stickiness of the carbon ink coated as the transferable layer on the reverse of the forms.
  • the carbon ink coating becomes tacky or sticky and dirty-totouch because liquid oils or fats are employed in the color vehicle to allow the ink coating to transfer to a copy sheet positioned therebelow under the pressure of writing. When such liquid oils or fats, which exhibit sticky or fluidity characteristics, are removed from the carbon ink, tacky or stickiness and consequently dirty-totouch defects can be diminished, however, transferability is extremely decreased.
  • the present invention eliminates all the above defects or disadvantages and presents a non-tacky and clean-totouch transferable layer without using liquid oils or fats and simultaneously improves the transferability to a great extent.
  • conventional carbonized forms are coated with hot melted ink at temperatures of from 70 C. to 80 0, just as high temperature as when pigments or dyes are mixed or dispersed in waxes and oils to prepare the ink
  • this invention produces the transferable layer by coating one side of the foundation sheet with a mixture or dispersion of ingredients at normal temperature and drying such mixture or dispersion by air, likewise at normal temperature.
  • the coating agent forming the transferable-layer consists of solid fatty acid or solid fatty acid and solid wax, solid lubricant, binder, volatile solvent and coloring matter.
  • Solid fatty acid used in this invention is finely crystallized at the top surface of the transferable layer so that the top surface of the layer exhibits uniform and discontinuous layer.
  • Such solid fatty acids are, for example, stearic acid, palmitic acid, myristic acid, behenic acid 3,382,088 Patented May 7, 1968 and so on, which are easy to be crystallized with the aid of volatile solvent.
  • Solid wax in this invention assists to control the size of crystallized particles of solid fatty acid and effects on the hardness of the layer and such solid waxes are, for example, paraffin wax, carnauba wax, montan wax, beeswax and microcrystalline Wax.
  • Solid lubricant used in this invention assists to disperse coloring matter in the coating agent and tends to give smooth layer.
  • Such solid lubricants are for example, refined talc, prepared calcium carbonate and so on.
  • Binder in this invention is dissolved in the volatile solvent to bind solid fatty acid, solid wax, solid lubricant and coloring matter and further assists to bind the layer With the sheet.
  • binders are, for example, ethylcellulose of low viscosity, nitrocellulose of low viscosity, chlorinated rubber and so on.
  • Volatile solvent is used in this invention for forming the coating agent and volatile solvent dissolving or dispersing solid fatty acid, solid wax and binder is mixed together with coloring matter and solid lubricant.
  • volatile solvent When volatile solvent is vaporized during drying step, it assists in the crystallization of solid fatty acid at the top surface of the layer.
  • volatile solvents are, for example, toluol, methanol and so on.
  • Coloring matters used in this invention are such as, for example, carbon black, iron blue (pigment) and Victoria blue, rhodamine (dyestutf).
  • FIGURE 1 is a flow sheet showing an illustrative process for preparing the novel self-copying sheet having a non-tacky, smudgeless, transferable coating according to the instant invention.
  • FIGURE 2 shows a cross-section of one embodiment of the self-copying sheet made according to this invention.
  • FIGURE 1 a binder, a solid fatty acid, a solid Wax, a solid lubricant, a coloring matter and a volatile solvent are mixed, for example in a ball mill, until the solid components are dissolved and uniformly dispersed in suspension in the solvent, whereupon one side of the foundation sheet is coated at normal temperature with the coating agent so obtained.
  • the coated foundation sheet is dried at normal temperature to crystallize the solid fatty acid and to evaporate the solvent, thereby obtaining the self-copying sheet having a non-tacky smudgefree, transferable coating.
  • FIGURE 2 the constitution of the transferable layer is clearly shown.
  • non-tacky solid fatty acid or said solid fatty acid and solid wax are used as the color vehicle instead of liquid oils or fats and a solid lubricant is added thereto so as to decrease the coefficient of friction on the surface of the layer, thus protecting the layer from being damaged by scratch or rub.
  • the carbon ink transferable layer prepared by use of non-tacky solid fatty acid or solid fatty acid and solid wax as the color vehicle has the big disadvantage in that it loses the transferability.
  • this invention uses non-tacky solid fatty acid or non-tacky solid fatty acid and solid wax as the color vehicle, the solid fatty acid is crystallized at the top surface of the transferable layer thus making the layer non-continuous.
  • the layer becomes more liable to break and transfer under the pressure of writing, but, at the same time, the resistance to mechanical strength, particularly the resistance to scratch and rub, will be substantially weakened.
  • a solid lubricant is added to the ingredients of the transferable layer. Such addition of solid lubricant decreases the coefficient of friction on the surface of the layer, while permitting transferability of the layer under the pressure of pen, pencil, stylus, type bar, etc. and yet prevents the layer from being damaged or soiled by scratch or rub.
  • the inscriptions or images transferred from the layer become sharp, non smudging and cleanto-touch.
  • the prior art self copying papers comprise a transfer sheet Whose back is coated with a chemical transferable layer and an adjacent copy which has a receptive chemical layer or acceptor on the surface.
  • a transfer sheet Whose back is coated with a chemical transferable layer and an adjacent copy which has a receptive chemical layer or acceptor on the surface.
  • the two chemical coatings must be contacted, thus, a set consisting of transfer sheet and receptive sheet is required.
  • the present invention eliminates the need of such receptive coating, and no chemical interaction is involved.
  • the transferable layer coated only on the back of a sheet produces sharp, non smudging, clean-to-touch inscriptions under the pressure of writing.
  • the quantity of tale to be incorporated in the mixed ingredients of the layer should be to 50% by weight and the particle size of the tale of from 0.5 to 50 microns. It is noted, however, that there is no specific limitations on the quantities of other ingredients other than talc and those quantities may be easily selected by the persons in the art referring to the examples shown below. In the following examples, parts are designated by weight.
  • Example I Parts Ethylcellulose of low viscosity 1 Stearic acid 5 Paraffin wax 5 Iron blue 1 Toluol 80 Refined talc 30
  • Example II Parts Ethylcellulose of low viscosity 2 Stearic acid Iron blue 1 Toluol 80 Refined talc 30
  • Example III Parts Chlorinated rubber 1 Palmitic acid 8 Carnauba wax 2 Prepared calcium carbonate Carbon black 1 Toluol 70
  • the above ingredients are ground and mixed uniformly in a ball mill until solid ingredients are dispersed in suspension, the uniformly mixed ingredients presenting a suitable condition for coating at normal temperature. Then the mixture is coated evenly over one side of web or roll paper A (shown in FIG.
  • the coating is dried and the volatile agents therein are evaporated by, for example, air of normal temperature.
  • the solid fatty acid such as stearic acid is crystallized as shown in FIG. 2 as crystalline particle 1 at the top surface of the coating with the solid wax 4 such as parafiin wax scattered therebetween, while the binder 2 such as ethylcellulose of low viscosity, the solid lubricant 5 such as refined talc and coloring matter 3 are dispersed in the transferable layer with the result that the satisfactory self copying sheet with a non-tacky transferable layer is obtained.
  • a thickness of 5 to 7 microns is suitable for such layer.
  • solid fatty acid such as, for example, stearic acid is crystallized at the top surface of the transferable layer so that the top surface of the layer exhibits uniform and discontinuous layer, thereby, when applying pressure of writing or typewriting, only the pressed portions of the transferable layer are easily transfered to the sheet positioned therebelow.
  • stearic acid is crystallized at the top surface of the transferable layer so that the top surface of the layer exhibits uniform and discontinuous layer, thereby, when applying pressure of writing or typewriting, only the pressed portions of the transferable layer are easily transfered to the sheet positioned therebelow.
  • solid lubricant increases the uniformity of the transferable layer and decreases the coefiicient of friction on the surface of the layer and furthermore, decreases smudging of the transferred inscriptions or images since coloring matter, which forms such inscriptions or images, is protected by solid lubricant which decreases the coefiicient of friction from being damaged by scratch or rub.
  • the self copying sheet prepared by this method is clean-to-touch itself and provides smudge-free, sharp inscriptions and yet the method is much simpler and economical as compared with prevailing manifolding or carbonless paper because only one side of paper is coated and no chemical interaction is involved according to the present invention.
  • a method of preparing a self-copying sheet having a non-tacky, clean-to-touch, and non-smudging transferable layer coated on one side thereof which comprises mixing a solid fatty acid selected from the group consisting of stearic acid, palmitic acid, myristic acid and behenic acid, a solid wax, a solid lubricant selected from the group consisting of refined talc and prepared calcium carbonate, a coloring matter selected from the group consisting of pigment and dyestutf, a binder of low viscosity of the group consisting of ethylcellulose, nitrocellulose and chlorinated rubber and a volatile solvent of the group consisting of toluol and methanol to form a dispersion solution, coating the resulting solution on one side of the foundation sheet at normal temperature to crystallize the solid fatty acid and evaporate the solvent.
  • a solid fatty acid selected from the group consisting of stearic acid, palmitic acid, myristic acid and behenic acid
  • binder is of low viscosity and of the group consisting of ethylcellulose, nitro-cellulose and chlorinated rubber and the volatile solvent is of the group consisting of toluol and methanol, and the solid wax is of the group consisting of paraffin wax, carnauba wax, montan wax, beeswax and microcrystalline wax.
  • a method of preparing a self-copying sheet having a non-tacky, clean-to-touch, and non-smudging transferable layer coated on one side thereof which comprises mixing stearic acid, refined talc, iron blue as coloring matter, ethylcellulose of low viscosity as a binder and toluol as a volatile solvent to form a dispersion solution, the solution is composed by weight of ten parts of the stearic acid, thirty parts of refined talc, two parts of ethylcellulose of low viscosity, one part of iron blue, eighty parts of toluol, coating the resulting solution on one side of the foundation sheet at normal temperature 5 to crysatllize the solid fatty acid and evapor-ate the solvent.
  • the solid fatty acid is stearic acid
  • the solid wax is paraffin wax
  • the solid lubricant is refined talc
  • the binder is ethylcellulose of low viscosity
  • the coloring matter is iron blue
  • the volatile solvent is toluol
  • the solution is composed by weight of five parts of stcaric acid, five parts of parafiin wax, thirty parts of refined talc, one part of ethylcellulose of low viscosity, one part of iron blue and eighty parts of toluol.
  • the solid fatty acid is palmitic acid
  • the solid wax is carnauba wax
  • the solid lubricant is prepared calcium carbonate
  • the binder is chlorinated rubber
  • the coloring mater is carbon black
  • the volatile solvent is toluol and the solution is composed by weight of eight parts of palmitic acid, two parts of carnauba wax, twenty parts of prepared calcium carbonate, one part of chlorinated rubber, one part of carbon black and seventy parts of toluol.
  • a self-copying sheet with a nontacky, clean-totouch transferable layer in which one side of the sheet is coated with the transferable layer consisting of solid fatty acid selected from the group consisting of stearic acid, palmitic acid, myristic acid and behenic acid, a solid wax,
  • a solid lubricant selected from the group consisting of refined talc and prepared calcium carbonate, a coloring matter selected from the group consisting of pigment and dyestuff, a binder of low viscosity and of the group consisting of ethylcellulose, nitro-cellulose and chlorinated rubber and a volatile solvent of the group consisting of toluol and methanol, the solid fatty acid being dispersed substantially in the top surface of the layer in the crystal form with the solid wax scattered therebetween, the binder, the solid lubricant and the coloring matter are dispersed in the layer underneath the top surface thereof.
  • solid wax is of the group consisting of paratfin wax, carnauba wax, montan wax, beeswax and microcrystalline wax.

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Description

May 7, 1968 RYUZO NODA 3,382,033
METHOD OF MANUFACTURING SELFCOPYING SHEET Filed April 28, 1965 FIG. I
FLOW SHEET OF THE PROCESS SOLID D WAX LUBRICANT SOLVENT MATTER MIXING (DISSOLVING & DISPERSING) STEP I FOUNDATION SHEEfl LCOATING AeENfl COATING STEP I COATED FOUNDATION SHEET DRYING AND EVAPORATING STEP III SELF-COPYING SHEET HAVING NON-TACKY SMUDGE-FREE TRANSFERABLE COATING LAYER F I G. 2
o o o oay c? o o aoo o 90 c o O 9 58202 394?)-og g %%,2 TRANSFERABLE LAYER} TO b fl .l oll 00 000000 W /\FOUNDATION SHEET V s 2 s INVENTOR. Kym 1%04 g Amer/er United States Patent 3,382,088 METHOD OF MANUFACTURING SELF-CGPYING SHEET Ryuzo Noda, 37 2-cliome, Higashino-cho, Noe, Johto-ku, Osaka, Japan Continuation-impart of application Ser. No. 257,836,
Feb. 12, 1963. This application Apr. 28, 1965, Ser. No. 451,439
7 Claims. (Cl. 117-36.1)
This application is a continuation in part of my application 257,836, filed Feb. 12, 1963, and now abandoned by filing this application.
This invention relates to a novel self-copying sheet, for example, of paper with a transferable layer coated on one side thereof and a method of manufacturing the same. It is an object of the invention to provide a self-copying sheet which eliminates various defects in or disadvantages inherent to conventional manifolding papers including carbonized forms, spot and strip carbons.
According to the invention, a transferable layer is coated on one side of a foundation sheet. And when a plurality of such sheets is placed one over another and applying the pressure of Writing or typewriting on the top surface of the piled sheets, such writing or typewriting portions are recorded on the top surface and simultaneously the corresponding pressed portions of each transferable layer are removed to transfer to a sheet positioned therebelow. Thus, according to the inventive self-copying sheet, there is no need of carbon paper or the like to be inserted between sheets.
Carbonized forms prepared by prior processes soil the users hands on ordinary handling, and the transferred inscriptions or images tend to smudge when touched. Furthermore, even the slightest scratch and rub applied on the surface of these forms often produce unintentional dirty marks on subsequent copying sheets positioned underneath, so that the user is required to use them with utmost care. These defects or disadvantages are due to the tackiness or stickiness of the carbon ink coated as the transferable layer on the reverse of the forms. The carbon ink coating becomes tacky or sticky and dirty-totouch because liquid oils or fats are employed in the color vehicle to allow the ink coating to transfer to a copy sheet positioned therebelow under the pressure of writing. When such liquid oils or fats, which exhibit sticky or fluidity characteristics, are removed from the carbon ink, tacky or stickiness and consequently dirty-totouch defects can be diminished, however, transferability is extremely decreased.
The present invention eliminates all the above defects or disadvantages and presents a non-tacky and clean-totouch transferable layer without using liquid oils or fats and simultaneously improves the transferability to a great extent. While conventional carbonized forms are coated with hot melted ink at temperatures of from 70 C. to 80 0, just as high temperature as when pigments or dyes are mixed or dispersed in waxes and oils to prepare the ink, this invention produces the transferable layer by coating one side of the foundation sheet with a mixture or dispersion of ingredients at normal temperature and drying such mixture or dispersion by air, likewise at normal temperature. According to the invention, the coating agent forming the transferable-layer consists of solid fatty acid or solid fatty acid and solid wax, solid lubricant, binder, volatile solvent and coloring matter.
Solid fatty acid used in this invention is finely crystallized at the top surface of the transferable layer so that the top surface of the layer exhibits uniform and discontinuous layer. Such solid fatty acids are, for example, stearic acid, palmitic acid, myristic acid, behenic acid 3,382,088 Patented May 7, 1968 and so on, which are easy to be crystallized with the aid of volatile solvent.
Solid wax in this invention assists to control the size of crystallized particles of solid fatty acid and effects on the hardness of the layer and such solid waxes are, for example, paraffin wax, carnauba wax, montan wax, beeswax and microcrystalline Wax.
Solid lubricant used in this invention assists to disperse coloring matter in the coating agent and tends to give smooth layer. Such solid lubricants are for example, refined talc, prepared calcium carbonate and so on.
Binder in this invention is dissolved in the volatile solvent to bind solid fatty acid, solid wax, solid lubricant and coloring matter and further assists to bind the layer With the sheet. Such binders are, for example, ethylcellulose of low viscosity, nitrocellulose of low viscosity, chlorinated rubber and so on.
Volatile solvent is used in this invention for forming the coating agent and volatile solvent dissolving or dispersing solid fatty acid, solid wax and binder is mixed together with coloring matter and solid lubricant. When volatile solvent is vaporized during drying step, it assists in the crystallization of solid fatty acid at the top surface of the layer. Such volatile solvents are, for example, toluol, methanol and so on.
Coloring matters used in this invention are such as, for example, carbon black, iron blue (pigment) and Victoria blue, rhodamine (dyestutf).
The present invention will be more readily understood from the following description When read in conjunction with the accompanying drawing, in which:
FIGURE 1 is a flow sheet showing an illustrative process for preparing the novel self-copying sheet having a non-tacky, smudgeless, transferable coating according to the instant invention; and
FIGURE 2 shows a cross-section of one embodiment of the self-copying sheet made according to this invention.
In FIGURE 1, a binder, a solid fatty acid, a solid Wax, a solid lubricant, a coloring matter and a volatile solvent are mixed, for example in a ball mill, until the solid components are dissolved and uniformly dispersed in suspension in the solvent, whereupon one side of the foundation sheet is coated at normal temperature with the coating agent so obtained. The coated foundation sheet is dried at normal temperature to crystallize the solid fatty acid and to evaporate the solvent, thereby obtaining the self-copying sheet having a non-tacky smudgefree, transferable coating. In the section thereof shown in FIGURE 2 the constitution of the transferable layer is clearly shown.
In accordance with the present invention non-tacky solid fatty acid or said solid fatty acid and solid wax are used as the color vehicle instead of liquid oils or fats and a solid lubricant is added thereto so as to decrease the coefficient of friction on the surface of the layer, thus protecting the layer from being damaged by scratch or rub. However the carbon ink transferable layer prepared by use of non-tacky solid fatty acid or solid fatty acid and solid wax as the color vehicle has the big disadvantage in that it loses the transferability. Although this invention uses non-tacky solid fatty acid or non-tacky solid fatty acid and solid wax as the color vehicle, the solid fatty acid is crystallized at the top surface of the transferable layer thus making the layer non-continuous. As a result the layer becomes more liable to break and transfer under the pressure of writing, but, at the same time, the resistance to mechanical strength, particularly the resistance to scratch and rub, will be substantially weakened. In order to overcome this defect a solid lubricant is added to the ingredients of the transferable layer. Such addition of solid lubricant decreases the coefficient of friction on the surface of the layer, while permitting transferability of the layer under the pressure of pen, pencil, stylus, type bar, etc. and yet prevents the layer from being damaged or soiled by scratch or rub.
Furthermore, the inscriptions or images transferred from the layer become sharp, non smudging and cleanto-touch.
Recently some self copying papers, commonly known as carbonless paper or manifolding paper, have appeared on the market but the present invention is essentially different from them. The prior art self copying papers comprise a transfer sheet Whose back is coated with a chemical transferable layer and an adjacent copy which has a receptive chemical layer or acceptor on the surface. To form inscriptions or images, the two chemical coatings must be contacted, thus, a set consisting of transfer sheet and receptive sheet is required. The present invention eliminates the need of such receptive coating, and no chemical interaction is involved. The transferable layer coated only on the back of a sheet produces sharp, non smudging, clean-to-touch inscriptions under the pressure of writing. Therefore, as compared with prior art self copying papers, the manufacturing method is much simpler and economical. As lubricant in this invention, refined tale is most suitable. The quantity of tale to be incorporated in the mixed ingredients of the layer should be to 50% by weight and the particle size of the tale of from 0.5 to 50 microns. It is noted, however, that there is no specific limitations on the quantities of other ingredients other than talc and those quantities may be easily selected by the persons in the art referring to the examples shown below. In the following examples, parts are designated by weight.
Example I Parts Ethylcellulose of low viscosity 1 Stearic acid 5 Paraffin wax 5 Iron blue 1 Toluol 80 Refined talc 30 Example II Parts Ethylcellulose of low viscosity 2 Stearic acid Iron blue 1 Toluol 80 Refined talc 30 Example III Parts Chlorinated rubber 1 Palmitic acid 8 Carnauba wax 2 Prepared calcium carbonate Carbon black 1 Toluol 70 The above ingredients are ground and mixed uniformly in a ball mill until solid ingredients are dispersed in suspension, the uniformly mixed ingredients presenting a suitable condition for coating at normal temperature. Then the mixture is coated evenly over one side of web or roll paper A (shown in FIG. 2) by coating machine equipped with suitable drying apparatus, by this latter apparatus the coating is dried and the volatile agents therein are evaporated by, for example, air of normal temperature. Then the solid fatty acid such as stearic acid is crystallized as shown in FIG. 2 as crystalline particle 1 at the top surface of the coating with the solid wax 4 such as parafiin wax scattered therebetween, while the binder 2 such as ethylcellulose of low viscosity, the solid lubricant 5 such as refined talc and coloring matter 3 are dispersed in the transferable layer with the result that the satisfactory self copying sheet with a non-tacky transferable layer is obtained. A thickness of 5 to 7 microns is suitable for such layer.
In accordance with the invention, solid fatty acid such as, for example, stearic acid is crystallized at the top surface of the transferable layer so that the top surface of the layer exhibits uniform and discontinuous layer, thereby, when applying pressure of writing or typewriting, only the pressed portions of the transferable layer are easily transfered to the sheet positioned therebelow. As aforementioned, in the conventional copying sheet, use is made of sticky or liquid oils or fats with the result that the obtained images or inscriptions lack clarity due to their tacky or sticky characteristics of the transferable layer. On the contrary, in accordance with the invention, which avoids to use such sticky or liquid oils or fats, adhesion between the transferable layer and the foundation sheet and the bonding force among ingredients constituting transferable layer are weak, and consequently, only the pressed portions of the layer will be easily removed from the foundation sheet and clearly transfered to the sheet positioned therebelow. It is hereby noted that when the pressure of writing or typewriting is applied to the transferable layer, crystallines of solid fatty acid are destroyed by the pressure and thus solid fatty acid recovers its inherent adhesion to the sheet. The advantages of the use of solid lubricant are as aforementioned in detail, and such addition of solid lubricant increases the uniformity of the transferable layer and decreases the coefiicient of friction on the surface of the layer and furthermore, decreases smudging of the transferred inscriptions or images since coloring matter, which forms such inscriptions or images, is protected by solid lubricant which decreases the coefiicient of friction from being damaged by scratch or rub.
Thus the self copying sheet prepared by this method is clean-to-touch itself and provides smudge-free, sharp inscriptions and yet the method is much simpler and economical as compared with prevailing manifolding or carbonless paper because only one side of paper is coated and no chemical interaction is involved according to the present invention.
What is claimed is:
1. A method of preparing a self-copying sheet having a non-tacky, clean-to-touch, and non-smudging transferable layer coated on one side thereof, which comprises mixing a solid fatty acid selected from the group consisting of stearic acid, palmitic acid, myristic acid and behenic acid, a solid wax, a solid lubricant selected from the group consisting of refined talc and prepared calcium carbonate, a coloring matter selected from the group consisting of pigment and dyestutf, a binder of low viscosity of the group consisting of ethylcellulose, nitrocellulose and chlorinated rubber and a volatile solvent of the group consisting of toluol and methanol to form a dispersion solution, coating the resulting solution on one side of the foundation sheet at normal temperature to crystallize the solid fatty acid and evaporate the solvent.
2. A method according to claim 1, in which the binder is of low viscosity and of the group consisting of ethylcellulose, nitro-cellulose and chlorinated rubber and the volatile solvent is of the group consisting of toluol and methanol, and the solid wax is of the group consisting of paraffin wax, carnauba wax, montan wax, beeswax and microcrystalline wax.
3. A method of preparing a self-copying sheet having a non-tacky, clean-to-touch, and non-smudging transferable layer coated on one side thereof, which comprises mixing stearic acid, refined talc, iron blue as coloring matter, ethylcellulose of low viscosity as a binder and toluol as a volatile solvent to form a dispersion solution, the solution is composed by weight of ten parts of the stearic acid, thirty parts of refined talc, two parts of ethylcellulose of low viscosity, one part of iron blue, eighty parts of toluol, coating the resulting solution on one side of the foundation sheet at normal temperature 5 to crysatllize the solid fatty acid and evapor-ate the solvent.
4. The method according to claim 1 in which the solid fatty acid is stearic acid, the solid wax is paraffin wax, the solid lubricant is refined talc, the binder is ethylcellulose of low viscosity, the coloring matter is iron blue, the volatile solvent is toluol, and the solution is composed by weight of five parts of stcaric acid, five parts of parafiin wax, thirty parts of refined talc, one part of ethylcellulose of low viscosity, one part of iron blue and eighty parts of toluol.
5. The method according to claim 1 in which the solid fatty acid is palmitic acid, the solid wax is carnauba wax, the solid lubricant is prepared calcium carbonate, the binder is chlorinated rubber, the coloring mater is carbon black and the volatile solvent is toluol and the solution is composed by weight of eight parts of palmitic acid, two parts of carnauba wax, twenty parts of prepared calcium carbonate, one part of chlorinated rubber, one part of carbon black and seventy parts of toluol.
6. A self-copying sheet with a nontacky, clean-totouch transferable layer in which one side of the sheet is coated with the transferable layer consisting of solid fatty acid selected from the group consisting of stearic acid, palmitic acid, myristic acid and behenic acid, a solid wax,
a solid lubricant selected from the group consisting of refined talc and prepared calcium carbonate, a coloring matter selected from the group consisting of pigment and dyestuff, a binder of low viscosity and of the group consisting of ethylcellulose, nitro-cellulose and chlorinated rubber and a volatile solvent of the group consisting of toluol and methanol, the solid fatty acid being dispersed substantially in the top surface of the layer in the crystal form with the solid wax scattered therebetween, the binder, the solid lubricant and the coloring matter are dispersed in the layer underneath the top surface thereof.
7. A self-copying sheet according to claim 6, in which the solid wax is of the group consisting of paratfin wax, carnauba wax, montan wax, beeswax and microcrystalline wax.
References Cited UNITED STATES PATENTS 1,783,442 12/1930 Mayer et al 117-36.7 X 2,313,810 3/1943 Dalton 11736.7 X 2,665,262 1/1954 :Rolle et al 11736.7 X 3,029,157 4/1962 Sutheim et a1 117---36.1 3,169,880 2/1965 Strauss 117-363 MURRAY KATZ, Primary Examiner.

Claims (1)

1. A METHOD OF PREPARING A SELF-COPYING SHEET HAVING A NON-TACKY, CLEAN-TO-TOUCH, AND NON-SMUDGING TRANSFERABLE LAYER COATED ON ONE SIDE THEREOF, WHICH COMPRISES MIXING A SOLID FATTY ACID SELECTED FROM THE GROUP CONSISTING OF STEARIC ACID, PALMITIC ACID, MYRISTIC ACID AND BEHENIC ACID, A SOLID WAX, A SOLID LUBRICANT SELECTED FROM THE GROUP CONSISTING OF REFINED TALC AND PREPARED CALCIUM CARBONATE, A COLORING MATTER SELECTED FROM THE GROUP CONSISTING OF PIGMENT AND DYESTUFF, A BINDER OF LOW VISCOSITY OF THE GROUP CONSISTING OF ETHYLCELLULOSE, NITROCELLULOSE AND CHLORINATED RUBBER AND A VOLATILE SOLVENT OF THE GROUP CONSISTING OF TOLUOL AND METHANOL TO FORM A DISPERSION SOLUTION, COATING THE RESULTING SOLUTION ON ONE SIDE OF THE FOUNDATION SHEET AT NORMAL TEMPERATURE TO CRYSTALLIZE THE SOLID FATTY ACID AND EVAPORATE THE SOLVENT.
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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3484264A (en) * 1966-09-12 1969-12-16 Kores Mfg Corp Method of making transfer sheet
US3653944A (en) * 1969-12-11 1972-04-04 Pacific Ind Inc Pressure sensitive image transfer media
US3663278A (en) * 1970-11-30 1972-05-16 Ncr Co Thermal transfer medium for producing scratch and smudge resistant marks
US4096314A (en) * 1975-06-06 1978-06-20 Kores Holding Zug Ag Pressure-sensitive transfer sheet
US4659383A (en) * 1981-12-17 1987-04-21 Exxon Printing Systems, Inc. High molecular weight, hot melt impulse ink jet ink
US4758276A (en) * 1981-12-17 1988-07-19 Dataproducts Corporation Stearic acid-containing ink jet inks
US4793264A (en) * 1981-12-07 1988-12-27 Dataproducts Corporation Low corrosion impulse ink jet ink containing anti-oxidant
US4822418A (en) * 1981-03-27 1989-04-18 Dataproducts Corporation Drop on demand ink jet ink comprising dubutyl sebecate
US5350446A (en) * 1984-11-05 1994-09-27 Dataproducts Corporation Hot melt impulse ink jet ink with dispersed solid pigment in a hot melt vehicle
US5592204A (en) * 1981-12-17 1997-01-07 Dataproducts Corporation Hot melt impulse ink jet ink with dispersed solid pigment in a hot melt vehicle

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1783442A (en) * 1928-02-04 1930-12-02 Charles W Mayer Recording paper
US2313810A (en) * 1941-07-08 1943-03-16 Harold R Dalton Copying and recording medium
US2665262A (en) * 1950-08-04 1954-01-05 Interchem Corp Coating compositions for recording media
US3029157A (en) * 1958-11-18 1962-04-10 Audio Devices Inc Magnetizable image transfer medium
US3169880A (en) * 1960-12-23 1965-02-16 Strauss Eugen Transfer sheet and sheet assembly

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1783442A (en) * 1928-02-04 1930-12-02 Charles W Mayer Recording paper
US2313810A (en) * 1941-07-08 1943-03-16 Harold R Dalton Copying and recording medium
US2665262A (en) * 1950-08-04 1954-01-05 Interchem Corp Coating compositions for recording media
US3029157A (en) * 1958-11-18 1962-04-10 Audio Devices Inc Magnetizable image transfer medium
US3169880A (en) * 1960-12-23 1965-02-16 Strauss Eugen Transfer sheet and sheet assembly

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3484264A (en) * 1966-09-12 1969-12-16 Kores Mfg Corp Method of making transfer sheet
US3653944A (en) * 1969-12-11 1972-04-04 Pacific Ind Inc Pressure sensitive image transfer media
US3663278A (en) * 1970-11-30 1972-05-16 Ncr Co Thermal transfer medium for producing scratch and smudge resistant marks
US4096314A (en) * 1975-06-06 1978-06-20 Kores Holding Zug Ag Pressure-sensitive transfer sheet
US4822418A (en) * 1981-03-27 1989-04-18 Dataproducts Corporation Drop on demand ink jet ink comprising dubutyl sebecate
US4793264A (en) * 1981-12-07 1988-12-27 Dataproducts Corporation Low corrosion impulse ink jet ink containing anti-oxidant
US4659383A (en) * 1981-12-17 1987-04-21 Exxon Printing Systems, Inc. High molecular weight, hot melt impulse ink jet ink
US4758276A (en) * 1981-12-17 1988-07-19 Dataproducts Corporation Stearic acid-containing ink jet inks
US5592204A (en) * 1981-12-17 1997-01-07 Dataproducts Corporation Hot melt impulse ink jet ink with dispersed solid pigment in a hot melt vehicle
US5350446A (en) * 1984-11-05 1994-09-27 Dataproducts Corporation Hot melt impulse ink jet ink with dispersed solid pigment in a hot melt vehicle

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